TY  - JOUR
AU  - Rmuš Mravik, Jelena
AU  - Milanović, Igor
AU  - Milošević Govedarović, Sanja
AU  - Mraković, Ana
AU  - Korneeva, Ekaterina
AU  - Stojković Simatović, Ivana
AU  - Kurko, Sandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11187
AB  - Molybdenum disulfide (MoS2) is considered promising noble metal-free catalysts for the hydrogen evolution reaction (HER). Whereas the bulk MoS2 does not exhibit significant activity, the catalytic properties of various nanostructures are noticeable. Therefore we synthesized flower-like molybdenum disulfide with the simple, one-step hydrothermal method. To enhance the catalytic activity of the material, low-energy ion irradiation is employed. As-prepared MoS2 is irradiated with hydrogen and carbon ions of various energies (20–40 keV) and fluences (1014-1017 ion/cm2). Our results show that irradiation has beneficial influence on MoS2 catalytic activity toward hydrogen evolution reaction. By producing morphological changes and defects in the structure, ion irradiation also impacts the conductivity of the material, which shows predominant effect on hydrogen evolution. The increase of current density at an overpotential of 300 mV with hydrogen ion irradiation is even 6 times higher than for as-synthesized catalyst.
T2  - International Journal of Hydrogen Energy
T1  - Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation
VL  - 48
IS  - 98
SP  - 38676
EP  - 38685
DO  - 10.1016/j.ijhydene.2023.06.178
ER  - 

@article{
author = "Rmuš Mravik, Jelena and Milanović, Igor and Milošević Govedarović, Sanja and Mraković, Ana and Korneeva, Ekaterina and Stojković Simatović, Ivana and Kurko, Sandra",
year = "2023",
abstract = "Molybdenum disulfide (MoS2) is considered promising noble metal-free catalysts for the hydrogen evolution reaction (HER). Whereas the bulk MoS2 does not exhibit significant activity, the catalytic properties of various nanostructures are noticeable. Therefore we synthesized flower-like molybdenum disulfide with the simple, one-step hydrothermal method. To enhance the catalytic activity of the material, low-energy ion irradiation is employed. As-prepared MoS2 is irradiated with hydrogen and carbon ions of various energies (20–40 keV) and fluences (1014-1017 ion/cm2). Our results show that irradiation has beneficial influence on MoS2 catalytic activity toward hydrogen evolution reaction. By producing morphological changes and defects in the structure, ion irradiation also impacts the conductivity of the material, which shows predominant effect on hydrogen evolution. The increase of current density at an overpotential of 300 mV with hydrogen ion irradiation is even 6 times higher than for as-synthesized catalyst.",
journal = "International Journal of Hydrogen Energy",
title = "Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation",
volume = "48",
number = "98",
pages = "38676-38685",
doi = "10.1016/j.ijhydene.2023.06.178"
}

Rmuš Mravik, J., Milanović, I., Milošević Govedarović, S., Mraković, A., Korneeva, E., Stojković Simatović, I.,& Kurko, S.. (2023). Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation. in International Journal of Hydrogen Energy, 48(98), 38676-38685.
https://doi.org/10.1016/j.ijhydene.2023.06.178

Rmuš Mravik J, Milanović I, Milošević Govedarović S, Mraković A, Korneeva E, Stojković Simatović I, Kurko S. Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation. in International Journal of Hydrogen Energy. 2023;48(98):38676-38685.
doi:10.1016/j.ijhydene.2023.06.178 .

Rmuš Mravik, Jelena, Milanović, Igor, Milošević Govedarović, Sanja, Mraković, Ana, Korneeva, Ekaterina, Stojković Simatović, Ivana, Kurko, Sandra, "Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation" in International Journal of Hydrogen Energy, 48, no. 98 (2023):38676-38685,
https://doi.org/10.1016/j.ijhydene.2023.06.178 . .

TY  - CONF
AU  - Rmuš Mravik, Jelena
AU  - Rajić, Vladimir
AU  - Belec, Blaž
AU  - Mravik, Željko
AU  - Jovanović, Zoran
AU  - Stojković Simatović, Ivana
AU  - Kurko, Sandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11657
AB  - Hydrogen production can be outlined as an important aspect of the modern economy. In order to be more clean and renewable, green hydrogen is most desirable, where expensive catalysts for water electrolysis are usually used. As alternative, transition metal dichalcogenides represent potentially good material, with room for further improvement. Molybdenum disulfide is a stable material with a reasonable amount of it available. The properties of the material can be easily tuned in order to increase its charge transport and create more active sites. The incorporation of defects and additives can be beneficial for the catalytic activity of MoS2. Graphene oxide (GO) is carbon nanomaterial, with a large surface area and when reduced, it could be used as a conductive additive. Furthermore, ball milling is a known low-cost, simple and scalable method to introduce defects in the structure. Therefore, combining these two approaches should result in a material with enhanced catalytic activity for hydrogen evolution reaction. The molybdenum disulfide was prepared by easy one-step hydrothermal synthesis. The graphene oxide was first obtained by modified Hummers’ method and after that reduced by thermal treatment at 200 °C. Thus prepared constituents are combined in different mass ratios and composites were obtained by milling with a high-energy ball mill. The various milling parameters were optimized. The prepared composites were analyzed as catalysts for hydrogen evolution reaction in an acidic solution.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
T1  - Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application
SP  - 156
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11657
ER  - 

@conference{
author = "Rmuš Mravik, Jelena and Rajić, Vladimir and Belec, Blaž and Mravik, Željko and Jovanović, Zoran and Stojković Simatović, Ivana and Kurko, Sandra",
year = "2023",
abstract = "Hydrogen production can be outlined as an important aspect of the modern economy. In order to be more clean and renewable, green hydrogen is most desirable, where expensive catalysts for water electrolysis are usually used. As alternative, transition metal dichalcogenides represent potentially good material, with room for further improvement. Molybdenum disulfide is a stable material with a reasonable amount of it available. The properties of the material can be easily tuned in order to increase its charge transport and create more active sites. The incorporation of defects and additives can be beneficial for the catalytic activity of MoS2. Graphene oxide (GO) is carbon nanomaterial, with a large surface area and when reduced, it could be used as a conductive additive. Furthermore, ball milling is a known low-cost, simple and scalable method to introduce defects in the structure. Therefore, combining these two approaches should result in a material with enhanced catalytic activity for hydrogen evolution reaction. The molybdenum disulfide was prepared by easy one-step hydrothermal synthesis. The graphene oxide was first obtained by modified Hummers’ method and after that reduced by thermal treatment at 200 °C. Thus prepared constituents are combined in different mass ratios and composites were obtained by milling with a high-energy ball mill. The various milling parameters were optimized. The prepared composites were analyzed as catalysts for hydrogen evolution reaction in an acidic solution.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro",
title = "Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application",
pages = "156",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11657"
}

Rmuš Mravik, J., Rajić, V., Belec, B., Mravik, Ž., Jovanović, Z., Stojković Simatović, I.,& Kurko, S.. (2023). Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
Belgrade : Materials Research Society of Serbia., 156.
https://hdl.handle.net/21.15107/rcub_vinar_11657

Rmuš Mravik J, Rajić V, Belec B, Mravik Ž, Jovanović Z, Stojković Simatović I, Kurko S. Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro. 2023;:156.
https://hdl.handle.net/21.15107/rcub_vinar_11657 .

Rmuš Mravik, Jelena, Rajić, Vladimir, Belec, Blaž, Mravik, Željko, Jovanović, Zoran, Stojković Simatović, Ivana, Kurko, Sandra, "Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application" in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro (2023):156,
https://hdl.handle.net/21.15107/rcub_vinar_11657 .

TY  - CONF
AU  - Mravik, Željko
AU  - Pejčić, Milica
AU  - Rmuš Mravik, Jelena
AU  - Belec, Blaž
AU  - Bajuk-Bogdanović, Danica
AU  - Jovanović, Sonja
AU  - Marković, Smilja
AU  - Gavrilov, Nemanja
AU  - Skuratov, Vladimir
AU  - Jovanović, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11637
AB  - In recent years graphene oxide (GO)/12-tungstophosphoric acid (WPA) nanocomposites have demonstrated promising potential for electrochemical supercapacitors. However, to enhance their performance, it is necessary to modify the surface chemistry of GO to minimize the influence of basal plane oxygen groups, which hinder the material's conductivity. Additionally, some degree of structural modification of WPA is desired. In this regard, ion beam irradiation presents a promising method to simultaneously optimize surface chemistry of GO and structurally modify WPA. To accomplish this, ion beam irradiation is employed for modification of individual components as well as their nanocomposites with varying mass ratios. Different ion species, fluences and energies were utilized depending on the sample type, ranging from 10 keV C to 710 MeV Bi. Spectroscopy methods were employed to gain insight into the type and degree of structural modification in WPA. A direct correlation is observed between the parameters of the ion beams and the resulting structural changes. As the disordering increases, the structure transitions from partially modified to increased bond breaking, ultimately leading to reconnected bronze-like structures. By increasing the fluence, a gradual modification of the structure and surface chemistry of GO was possible. The effects of irradiation on GO and WPA are particularly pronounced in irradiated composites, where higher capacitance is measured.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
T1  - Graphene oxide/12 tungstophosphoric acid nanocomposites – achieving favorable properties with ion beams for electrochemical supercapacitors
SP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11637
ER  - 

@conference{
author = "Mravik, Željko and Pejčić, Milica and Rmuš Mravik, Jelena and Belec, Blaž and Bajuk-Bogdanović, Danica and Jovanović, Sonja and Marković, Smilja and Gavrilov, Nemanja and Skuratov, Vladimir and Jovanović, Zoran",
year = "2023",
abstract = "In recent years graphene oxide (GO)/12-tungstophosphoric acid (WPA) nanocomposites have demonstrated promising potential for electrochemical supercapacitors. However, to enhance their performance, it is necessary to modify the surface chemistry of GO to minimize the influence of basal plane oxygen groups, which hinder the material's conductivity. Additionally, some degree of structural modification of WPA is desired. In this regard, ion beam irradiation presents a promising method to simultaneously optimize surface chemistry of GO and structurally modify WPA. To accomplish this, ion beam irradiation is employed for modification of individual components as well as their nanocomposites with varying mass ratios. Different ion species, fluences and energies were utilized depending on the sample type, ranging from 10 keV C to 710 MeV Bi. Spectroscopy methods were employed to gain insight into the type and degree of structural modification in WPA. A direct correlation is observed between the parameters of the ion beams and the resulting structural changes. As the disordering increases, the structure transitions from partially modified to increased bond breaking, ultimately leading to reconnected bronze-like structures. By increasing the fluence, a gradual modification of the structure and surface chemistry of GO was possible. The effects of irradiation on GO and WPA are particularly pronounced in irradiated composites, where higher capacitance is measured.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade",
title = "Graphene oxide/12 tungstophosphoric acid nanocomposites – achieving favorable properties with ion beams for electrochemical supercapacitors",
pages = "50",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11637"
}

Mravik, Ž., Pejčić, M., Rmuš Mravik, J., Belec, B., Bajuk-Bogdanović, D., Jovanović, S., Marković, S., Gavrilov, N., Skuratov, V.,& Jovanović, Z.. (2023). Graphene oxide/12 tungstophosphoric acid nanocomposites – achieving favorable properties with ion beams for electrochemical supercapacitors. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
Belgrade : Serbian Ceramic Society., 50.
https://hdl.handle.net/21.15107/rcub_vinar_11637

Mravik Ž, Pejčić M, Rmuš Mravik J, Belec B, Bajuk-Bogdanović D, Jovanović S, Marković S, Gavrilov N, Skuratov V, Jovanović Z. Graphene oxide/12 tungstophosphoric acid nanocomposites – achieving favorable properties with ion beams for electrochemical supercapacitors. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade. 2023;:50.
https://hdl.handle.net/21.15107/rcub_vinar_11637 .

Mravik, Željko, Pejčić, Milica, Rmuš Mravik, Jelena, Belec, Blaž, Bajuk-Bogdanović, Danica, Jovanović, Sonja, Marković, Smilja, Gavrilov, Nemanja, Skuratov, Vladimir, Jovanović, Zoran, "Graphene oxide/12 tungstophosphoric acid nanocomposites – achieving favorable properties with ion beams for electrochemical supercapacitors" in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade (2023):50,
https://hdl.handle.net/21.15107/rcub_vinar_11637 .

TY  - CONF
AU  - Mravik, Željko
AU  - Pejčić, Milica
AU  - Rmuš Mravik, Jelena
AU  - Belec, Blaž
AU  - Bajuk-Bogdanović, Danica
AU  - Jovanović, Sonja
AU  - Marković, Smilja
AU  - Gavrilov, Nemanja
AU  - Skuratov, Vladimir
AU  - Jovanović, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11651
AB  - Ion beam modification of materials is notable method for achieving their unique structural, electronic, and other physicochemical properties. In the case of graphene oxide (GO) such modification of structure and surface chemistry is known to yield properties interesting for electrochemical supercapacitors. The performance of GO supercapacitors can be additionally improved by incorporating components with attractive redox properties. In this work, the influence of ion beam irradiation on synergy of GO and 12-tungstophosphoric acid (WPA) in their nanocomposite was investigated. For that, both components and their composites with different mass ratios were irradiated using different ion species, fluences and energies (from 10 keV C to 710 MeV Bi). For the irradiated WPA, results showed clear correlation between ion beam parameters, degree of structural modification and electrochemical properties. With increasing structural modification, bond breaking is first induced giving higher catalytic activity toward HER. Further irradiation resulted in an increased interconnection of polytungstate species producing lower catalytic activity and lower lithiation capacity. Irradiated GO showed modified surface chemistry, with preferable reduction of alkoxy and epoxy groups, changes in morphology and electric properties due to increased number of defects with increasing fluence, synergic effect of ion beam irradiated GO and WPA resulted in higher capacitance of irradiated composites compared to GO presumably because of interaction of structurally modified WPA with defect sites on GO thus reducing electrolyte flow along ion tracks.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
T1  - Ion-beam irradiated graphene oxide, 12-tungstophosphoric acid and their nanocomposites for electrochemical supercapacitors
SP  - 36
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11651
ER  - 

@conference{
author = "Mravik, Željko and Pejčić, Milica and Rmuš Mravik, Jelena and Belec, Blaž and Bajuk-Bogdanović, Danica and Jovanović, Sonja and Marković, Smilja and Gavrilov, Nemanja and Skuratov, Vladimir and Jovanović, Zoran",
year = "2023",
abstract = "Ion beam modification of materials is notable method for achieving their unique structural, electronic, and other physicochemical properties. In the case of graphene oxide (GO) such modification of structure and surface chemistry is known to yield properties interesting for electrochemical supercapacitors. The performance of GO supercapacitors can be additionally improved by incorporating components with attractive redox properties. In this work, the influence of ion beam irradiation on synergy of GO and 12-tungstophosphoric acid (WPA) in their nanocomposite was investigated. For that, both components and their composites with different mass ratios were irradiated using different ion species, fluences and energies (from 10 keV C to 710 MeV Bi). For the irradiated WPA, results showed clear correlation between ion beam parameters, degree of structural modification and electrochemical properties. With increasing structural modification, bond breaking is first induced giving higher catalytic activity toward HER. Further irradiation resulted in an increased interconnection of polytungstate species producing lower catalytic activity and lower lithiation capacity. Irradiated GO showed modified surface chemistry, with preferable reduction of alkoxy and epoxy groups, changes in morphology and electric properties due to increased number of defects with increasing fluence, synergic effect of ion beam irradiated GO and WPA resulted in higher capacitance of irradiated composites compared to GO presumably because of interaction of structurally modified WPA with defect sites on GO thus reducing electrolyte flow along ion tracks.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro",
title = "Ion-beam irradiated graphene oxide, 12-tungstophosphoric acid and their nanocomposites for electrochemical supercapacitors",
pages = "36",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11651"
}

Mravik, Ž., Pejčić, M., Rmuš Mravik, J., Belec, B., Bajuk-Bogdanović, D., Jovanović, S., Marković, S., Gavrilov, N., Skuratov, V.,& Jovanović, Z.. (2023). Ion-beam irradiated graphene oxide, 12-tungstophosphoric acid and their nanocomposites for electrochemical supercapacitors. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
Belgrade : Materials Research Society of Serbia., 36.
https://hdl.handle.net/21.15107/rcub_vinar_11651

Mravik Ž, Pejčić M, Rmuš Mravik J, Belec B, Bajuk-Bogdanović D, Jovanović S, Marković S, Gavrilov N, Skuratov V, Jovanović Z. Ion-beam irradiated graphene oxide, 12-tungstophosphoric acid and their nanocomposites for electrochemical supercapacitors. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro. 2023;:36.
https://hdl.handle.net/21.15107/rcub_vinar_11651 .

Mravik, Željko, Pejčić, Milica, Rmuš Mravik, Jelena, Belec, Blaž, Bajuk-Bogdanović, Danica, Jovanović, Sonja, Marković, Smilja, Gavrilov, Nemanja, Skuratov, Vladimir, Jovanović, Zoran, "Ion-beam irradiated graphene oxide, 12-tungstophosphoric acid and their nanocomposites for electrochemical supercapacitors" in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro (2023):36,
https://hdl.handle.net/21.15107/rcub_vinar_11651 .

TY  - CONF
AU  - Jovanović, Sonja
AU  - Rmuš Mravik, Jelena
AU  - Grujičić, Marija
AU  - Petković, Darija
AU  - Pejčić, Milica
AU  - Jovanović, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11659
AB  - In the past two decades spinel ferrites nanoparticles have been extensively investigated due to their potential applications in a variety of fields (data storage, catalysis, energy, environment, biomedicine, etc.). In the present work, zinc ferrite nanoparticles with different copper content (Zn(1-x)CuxFe2O4; x=0, 0.2, 0.4, 0.6, and 0.8) but with the same particle size distribution and amount of oleic acid as capping agent were prepared by solvothermal synthesis and the physicochemical properties of as-prepared samples were investigated. The prepared samples were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and vibrating sample magnetometry (VSM). The XRD results show that all the diffraction maxima correspond to the cubic spinel structure, while TEM images reviled that samples are consisted of sphere-like particles, 5-7 nm in size. The presence of oleic acid on the surface of nanoparticles was confirmed by FTIR analysis. The magnetic measurements revealed superparamagnetic behavior of obtained powders, with gradual increase of saturation magnetization.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
T1  - Physicochemical properties of solvothermaly synthesized zinc copper ferrite nanoparticles
SP  - 157
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11659
ER  - 

@conference{
author = "Jovanović, Sonja and Rmuš Mravik, Jelena and Grujičić, Marija and Petković, Darija and Pejčić, Milica and Jovanović, Zoran",
year = "2023",
abstract = "In the past two decades spinel ferrites nanoparticles have been extensively investigated due to their potential applications in a variety of fields (data storage, catalysis, energy, environment, biomedicine, etc.). In the present work, zinc ferrite nanoparticles with different copper content (Zn(1-x)CuxFe2O4; x=0, 0.2, 0.4, 0.6, and 0.8) but with the same particle size distribution and amount of oleic acid as capping agent were prepared by solvothermal synthesis and the physicochemical properties of as-prepared samples were investigated. The prepared samples were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and vibrating sample magnetometry (VSM). The XRD results show that all the diffraction maxima correspond to the cubic spinel structure, while TEM images reviled that samples are consisted of sphere-like particles, 5-7 nm in size. The presence of oleic acid on the surface of nanoparticles was confirmed by FTIR analysis. The magnetic measurements revealed superparamagnetic behavior of obtained powders, with gradual increase of saturation magnetization.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro",
title = "Physicochemical properties of solvothermaly synthesized zinc copper ferrite nanoparticles",
pages = "157",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11659"
}

Jovanović, S., Rmuš Mravik, J., Grujičić, M., Petković, D., Pejčić, M.,& Jovanović, Z.. (2023). Physicochemical properties of solvothermaly synthesized zinc copper ferrite nanoparticles. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
Belgrade : Materials Research Society of Serbia., 157.
https://hdl.handle.net/21.15107/rcub_vinar_11659

Jovanović S, Rmuš Mravik J, Grujičić M, Petković D, Pejčić M, Jovanović Z. Physicochemical properties of solvothermaly synthesized zinc copper ferrite nanoparticles. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro. 2023;:157.
https://hdl.handle.net/21.15107/rcub_vinar_11659 .

Jovanović, Sonja, Rmuš Mravik, Jelena, Grujičić, Marija, Petković, Darija, Pejčić, Milica, Jovanović, Zoran, "Physicochemical properties of solvothermaly synthesized zinc copper ferrite nanoparticles" in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro (2023):157,
https://hdl.handle.net/21.15107/rcub_vinar_11659 .

TY  - CONF
AU  - Pejčić, Milica
AU  - Mravik, Željko
AU  - Bajuk-Bogdanović, Danica
AU  - Grujičić, Marija
AU  - Rmuš Mravik, Jelena
AU  - Jovanović, Sonja
AU  - Jovanović, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12316
AB  - Different hierarchical ordering of nanomaterials, either as individual components or in the form of nanocomposites, is one of the approaches used for the development of supercapacitors. In this work, the effect of hydrothermal treatment on oxygen functional groups of nanocomposites between graphene oxide (GO), 12-tungstophosphoric acid (WPA), and 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) was examined. The mentioned materials were hydrothermally treated for 4, 8 and 12 hours at 180 °C in order to understand how interaction between the components is influencing development of surface chemistry. The results of Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy (Raman), and temperature-programmed desorption (TPD) are showing the surface and structural changes of GO (individually and in nanocomposite) as a result of hydrothermal treatment. Both FTIR and RAMAN confirm the presence of WPA and PTCDA. Additionally, it appears that hydrothermal treatment has no impact on the structural changes in PTCDA, which is consistent across various temperature conditions. TPD results indicate that prolonged hydrothermal treatment leads to a gradual increase of the number of functional groups of GO. However, the number of desorbed groups is influenced by the WPA and PTDCA components. This research offers new insights into GO, WPA, and PTCDA interactions which can have useful implications for development of electrochemical supercapacitors.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Investigating the influence of hydrothermal treatment on oxygen functional groups in graphene oxide-based nanocomposites
SP  - 43
EP  - 43
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12316
ER  - 

@conference{
author = "Pejčić, Milica and Mravik, Željko and Bajuk-Bogdanović, Danica and Grujičić, Marija and Rmuš Mravik, Jelena and Jovanović, Sonja and Jovanović, Zoran",
year = "2023",
abstract = "Different hierarchical ordering of nanomaterials, either as individual components or in the form of nanocomposites, is one of the approaches used for the development of supercapacitors. In this work, the effect of hydrothermal treatment on oxygen functional groups of nanocomposites between graphene oxide (GO), 12-tungstophosphoric acid (WPA), and 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) was examined. The mentioned materials were hydrothermally treated for 4, 8 and 12 hours at 180 °C in order to understand how interaction between the components is influencing development of surface chemistry. The results of Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy (Raman), and temperature-programmed desorption (TPD) are showing the surface and structural changes of GO (individually and in nanocomposite) as a result of hydrothermal treatment. Both FTIR and RAMAN confirm the presence of WPA and PTCDA. Additionally, it appears that hydrothermal treatment has no impact on the structural changes in PTCDA, which is consistent across various temperature conditions. TPD results indicate that prolonged hydrothermal treatment leads to a gradual increase of the number of functional groups of GO. However, the number of desorbed groups is influenced by the WPA and PTDCA components. This research offers new insights into GO, WPA, and PTCDA interactions which can have useful implications for development of electrochemical supercapacitors.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Investigating the influence of hydrothermal treatment on oxygen functional groups in graphene oxide-based nanocomposites",
pages = "43-43",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12316"
}

Pejčić, M., Mravik, Ž., Bajuk-Bogdanović, D., Grujičić, M., Rmuš Mravik, J., Jovanović, S.,& Jovanović, Z.. (2023). Investigating the influence of hydrothermal treatment on oxygen functional groups in graphene oxide-based nanocomposites. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 43-43.
https://hdl.handle.net/21.15107/rcub_vinar_12316

Pejčić M, Mravik Ž, Bajuk-Bogdanović D, Grujičić M, Rmuš Mravik J, Jovanović S, Jovanović Z. Investigating the influence of hydrothermal treatment on oxygen functional groups in graphene oxide-based nanocomposites. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:43-43.
https://hdl.handle.net/21.15107/rcub_vinar_12316 .

Pejčić, Milica, Mravik, Željko, Bajuk-Bogdanović, Danica, Grujičić, Marija, Rmuš Mravik, Jelena, Jovanović, Sonja, Jovanović, Zoran, "Investigating the influence of hydrothermal treatment on oxygen functional groups in graphene oxide-based nanocomposites" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):43-43,
https://hdl.handle.net/21.15107/rcub_vinar_12316 .

TY  - CONF
AU  - Jovanović, Zoran
AU  - Jovanović, Sonja
AU  - Mravik, Željko
AU  - Rmuš, Jelena
AU  - Jelić, Marko
AU  - Pejčić, Milica
AU  - Grujičić, Marija
AU  - Petković, Darija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12334
AB  - Elektrohemijska istraživanja su prethodnih godina dala ključni podstrek globalnim stremljenjima ka obnovljivim izvorima energije. Višegeneracijski napori, u početku motivisani željom za fundamentalnim razumevanjem procesa, aktuelizovani su očekivanim nedostatkom fosilnih goriva i pratećim nepovoljnim uticajem na životnu sredinu. Nanomaterijali su omogućili spektakularan skok u tehnološkim inovacijama i neosporan je njihov doprinos obnovljivim izvorima energije. Zahvaljujući novim svojstvima nanomaterijala i njihovoj sinergiji, omogućeno je dalje unapređenje i integracija različitih funkcionalnosti. Pri tome, postalo je jasno da atomski precizan dizajn materijala postaje kritičan za razvoj naprava sledeće generacije. Ovo je posebno važno u slučaju nanokompozita gde interakcija komponenti pojačava moguće sinergijske doprinose. U izlaganju će biti dat osvrt na napredne metode sinteze i modifikacije materijala – od tradicionalnih, do tankih filmova, 0D i 2D nanomaterijala i njihovih kompozita – posmatranih kroz prizmu obnovljivih izvora energije i održivosti (elektrohemijski superkondenzatori, razgradnja vode, senzori, i dr.). Razvoj novih materijala i unapređenje elektrohemijskih sistema ima potencijal da suštinski učini obnovljivu energiju održivijom i dostupnijom, time otvarajući put ka održivoj budućnosti.
C3  - Savremena stremljenja u elektrohemiji u proceu prelaska na obnovljive izvore energije: Naučni skup posvećen 100 - godišnjici rođenja inostranog člana SANU Dž. O'M. Bokrisa : Knjiga izvoda
T1  - Sinteza i modifikacija naprednih nanomaterijala - pogled kroz prizmu obnovljivih izvora energije
SP  - 19
EP  - 19
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12334
ER  - 

@conference{
author = "Jovanović, Zoran and Jovanović, Sonja and Mravik, Željko and Rmuš, Jelena and Jelić, Marko and Pejčić, Milica and Grujičić, Marija and Petković, Darija",
year = "2023",
abstract = "Elektrohemijska istraživanja su prethodnih godina dala ključni podstrek globalnim stremljenjima ka obnovljivim izvorima energije. Višegeneracijski napori, u početku motivisani željom za fundamentalnim razumevanjem procesa, aktuelizovani su očekivanim nedostatkom fosilnih goriva i pratećim nepovoljnim uticajem na životnu sredinu. Nanomaterijali su omogućili spektakularan skok u tehnološkim inovacijama i neosporan je njihov doprinos obnovljivim izvorima energije. Zahvaljujući novim svojstvima nanomaterijala i njihovoj sinergiji, omogućeno je dalje unapređenje i integracija različitih funkcionalnosti. Pri tome, postalo je jasno da atomski precizan dizajn materijala postaje kritičan za razvoj naprava sledeće generacije. Ovo je posebno važno u slučaju nanokompozita gde interakcija komponenti pojačava moguće sinergijske doprinose. U izlaganju će biti dat osvrt na napredne metode sinteze i modifikacije materijala – od tradicionalnih, do tankih filmova, 0D i 2D nanomaterijala i njihovih kompozita – posmatranih kroz prizmu obnovljivih izvora energije i održivosti (elektrohemijski superkondenzatori, razgradnja vode, senzori, i dr.). Razvoj novih materijala i unapređenje elektrohemijskih sistema ima potencijal da suštinski učini obnovljivu energiju održivijom i dostupnijom, time otvarajući put ka održivoj budućnosti.",
journal = "Savremena stremljenja u elektrohemiji u proceu prelaska na obnovljive izvore energije: Naučni skup posvećen 100 - godišnjici rođenja inostranog člana SANU Dž. O'M. Bokrisa : Knjiga izvoda",
title = "Sinteza i modifikacija naprednih nanomaterijala - pogled kroz prizmu obnovljivih izvora energije",
pages = "19-19",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12334"
}

Jovanović, Z., Jovanović, S., Mravik, Ž., Rmuš, J., Jelić, M., Pejčić, M., Grujičić, M.,& Petković, D.. (2023). Sinteza i modifikacija naprednih nanomaterijala - pogled kroz prizmu obnovljivih izvora energije. in Savremena stremljenja u elektrohemiji u proceu prelaska na obnovljive izvore energije: Naučni skup posvećen 100 - godišnjici rođenja inostranog člana SANU Dž. O'M. Bokrisa : Knjiga izvoda, 19-19.
https://hdl.handle.net/21.15107/rcub_vinar_12334

Jovanović Z, Jovanović S, Mravik Ž, Rmuš J, Jelić M, Pejčić M, Grujičić M, Petković D. Sinteza i modifikacija naprednih nanomaterijala - pogled kroz prizmu obnovljivih izvora energije. in Savremena stremljenja u elektrohemiji u proceu prelaska na obnovljive izvore energije: Naučni skup posvećen 100 - godišnjici rođenja inostranog člana SANU Dž. O'M. Bokrisa : Knjiga izvoda. 2023;:19-19.
https://hdl.handle.net/21.15107/rcub_vinar_12334 .

Jovanović, Zoran, Jovanović, Sonja, Mravik, Željko, Rmuš, Jelena, Jelić, Marko, Pejčić, Milica, Grujičić, Marija, Petković, Darija, "Sinteza i modifikacija naprednih nanomaterijala - pogled kroz prizmu obnovljivih izvora energije" in Savremena stremljenja u elektrohemiji u proceu prelaska na obnovljive izvore energije: Naučni skup posvećen 100 - godišnjici rođenja inostranog člana SANU Dž. O'M. Bokrisa : Knjiga izvoda (2023):19-19,
https://hdl.handle.net/21.15107/rcub_vinar_12334 .

TY  - CONF
AU  - Grbović Novaković,  Jasmina
AU  - Mitrović Rajić, Anđela
AU  - Pantić, T.
AU  - Milošević Govedarović, Sanja
AU  - Novaković, Nikola
AU  - Rmuš Mravik, Jelena
AU  - Paskaš-Mamula, Bojana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12738
AB  - The main goal is to develop electrode material for the detection of traces of pesticides in food and water in a wide range of pH values. The leading idea is to use natural clay pyrophyllite to modify carbon paste electrode. SPEX Mixer/Mill 5100 is used for mechanochemical modification. The changes in the structure of pyrophyllite before and after the grinding process were studied by means of PSD, XRD, FTIR, and DTA-TG [1]. The electrochemical behavior of the sensor was followed using differential pulse stripping voltammetry (DPSV). It is shown that obtained material can be used as electrodes in electrochemical sensors for pesticide detection in a wide range of pH.
PB  - Zagreb, Croatia : Ruđer Bošković Institute
C3  - Solid-State Science & Research Meeting : Book of abstracts and programme
T1  - Pyrophyllite modified carbon-based electrode
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12738
ER  - 

@conference{
author = "Grbović Novaković,  Jasmina and Mitrović Rajić, Anđela and Pantić, T. and Milošević Govedarović, Sanja and Novaković, Nikola and Rmuš Mravik, Jelena and Paskaš-Mamula, Bojana",
year = "2023",
abstract = "The main goal is to develop electrode material for the detection of traces of pesticides in food and water in a wide range of pH values. The leading idea is to use natural clay pyrophyllite to modify carbon paste electrode. SPEX Mixer/Mill 5100 is used for mechanochemical modification. The changes in the structure of pyrophyllite before and after the grinding process were studied by means of PSD, XRD, FTIR, and DTA-TG [1]. The electrochemical behavior of the sensor was followed using differential pulse stripping voltammetry (DPSV). It is shown that obtained material can be used as electrodes in electrochemical sensors for pesticide detection in a wide range of pH.",
publisher = "Zagreb, Croatia : Ruđer Bošković Institute",
journal = "Solid-State Science & Research Meeting : Book of abstracts and programme",
title = "Pyrophyllite modified carbon-based electrode",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12738"
}

Grbović Novaković, J., Mitrović Rajić, A., Pantić, T., Milošević Govedarović, S., Novaković, N., Rmuš Mravik, J.,& Paskaš-Mamula, B.. (2023). Pyrophyllite modified carbon-based electrode. in Solid-State Science & Research Meeting : Book of abstracts and programme
Zagreb, Croatia : Ruđer Bošković Institute..
https://hdl.handle.net/21.15107/rcub_vinar_12738

Grbović Novaković J, Mitrović Rajić A, Pantić T, Milošević Govedarović S, Novaković N, Rmuš Mravik J, Paskaš-Mamula B. Pyrophyllite modified carbon-based electrode. in Solid-State Science & Research Meeting : Book of abstracts and programme. 2023;.
https://hdl.handle.net/21.15107/rcub_vinar_12738 .

Grbović Novaković,  Jasmina, Mitrović Rajić, Anđela, Pantić, T., Milošević Govedarović, Sanja, Novaković, Nikola, Rmuš Mravik, Jelena, Paskaš-Mamula, Bojana, "Pyrophyllite modified carbon-based electrode" in Solid-State Science & Research Meeting : Book of abstracts and programme (2023),
https://hdl.handle.net/21.15107/rcub_vinar_12738 .

TY  - CONF
AU  - Mravik, Željko
AU  - Pejčić, Milica
AU  - Grujičić, Marija
AU  - Rmuš Mravik, Jelena
AU  - Stević, Miša
AU  - Stević, Zoran
AU  - Jovanović, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12314
AB  - In sensor devices the material of choice should be highly dependent on perturbation of environmental parameters. In order to achieve good sensitivity and selectivity of sensing devices to temperature, humidity or concentration of different gasses, the materials with adjustable properties are highly desirable. Electric properties of graphene oxide (GO) can be easily tuned by modification of surface chemistry and anchoring of functional compounds onto its two-dimensional structure. Prior to application of sensing device, research and development of materials system is the most essential step. In this work, the formation of GO and GO/12-tungstophosphoric acid (WPA) films with 6 wt.% of WPA on interdigital electrodes was investigated by variation of dip-coating parameters (receding angle and time between steps). Obtained films were thermally reduced in argon atmosphere after which optical microscopy was used to evaluate morphology and stability of deposited GO and GO/WPA films. Impedance spectroscopy was used to investigate the electric properties of the obtained films in range from 10 Hz to 100 kHz. Measured impedance values were correlated to the degree of material detachment and deposition parameters i.e. films showing the lowest impedance values had the smallest area of detached film. Additionally, impedance values were measured depending on the environment temperature which showed that GO/WPA films exhibit the lowest impedance values and good sensitivity to changes of temperature making it good a candidate for sensing devices.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Temperature dependence of electric properties of GO and GO/WPA films on interdigital electrodes
SP  - 40
EP  - 40
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12314
ER  - 

@conference{
author = "Mravik, Željko and Pejčić, Milica and Grujičić, Marija and Rmuš Mravik, Jelena and Stević, Miša and Stević, Zoran and Jovanović, Zoran",
year = "2023",
abstract = "In sensor devices the material of choice should be highly dependent on perturbation of environmental parameters. In order to achieve good sensitivity and selectivity of sensing devices to temperature, humidity or concentration of different gasses, the materials with adjustable properties are highly desirable. Electric properties of graphene oxide (GO) can be easily tuned by modification of surface chemistry and anchoring of functional compounds onto its two-dimensional structure. Prior to application of sensing device, research and development of materials system is the most essential step. In this work, the formation of GO and GO/12-tungstophosphoric acid (WPA) films with 6 wt.% of WPA on interdigital electrodes was investigated by variation of dip-coating parameters (receding angle and time between steps). Obtained films were thermally reduced in argon atmosphere after which optical microscopy was used to evaluate morphology and stability of deposited GO and GO/WPA films. Impedance spectroscopy was used to investigate the electric properties of the obtained films in range from 10 Hz to 100 kHz. Measured impedance values were correlated to the degree of material detachment and deposition parameters i.e. films showing the lowest impedance values had the smallest area of detached film. Additionally, impedance values were measured depending on the environment temperature which showed that GO/WPA films exhibit the lowest impedance values and good sensitivity to changes of temperature making it good a candidate for sensing devices.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Temperature dependence of electric properties of GO and GO/WPA films on interdigital electrodes",
pages = "40-40",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12314"
}

Mravik, Ž., Pejčić, M., Grujičić, M., Rmuš Mravik, J., Stević, M., Stević, Z.,& Jovanović, Z.. (2023). Temperature dependence of electric properties of GO and GO/WPA films on interdigital electrodes. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 40-40.
https://hdl.handle.net/21.15107/rcub_vinar_12314

Mravik Ž, Pejčić M, Grujičić M, Rmuš Mravik J, Stević M, Stević Z, Jovanović Z. Temperature dependence of electric properties of GO and GO/WPA films on interdigital electrodes. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:40-40.
https://hdl.handle.net/21.15107/rcub_vinar_12314 .

Mravik, Željko, Pejčić, Milica, Grujičić, Marija, Rmuš Mravik, Jelena, Stević, Miša, Stević, Zoran, Jovanović, Zoran, "Temperature dependence of electric properties of GO and GO/WPA films on interdigital electrodes" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):40-40,
https://hdl.handle.net/21.15107/rcub_vinar_12314 .

TY  - JOUR
AU  - Rmuš, Jelena
AU  - Belec, Blaž
AU  - Milanović, Igor
AU  - Fanetti, Mattia
AU  - Gardonio, Sandra
AU  - Valant, Matjaž
AU  - Kurko, Sandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11096
AB  - To produce materials with enhanced catalytic activity toward hydrogen evolution reaction we combined MoS2 as transition metal dichalcogenide and Bi2Se3 as topological insulator. The composites were produced by three methods: mechanical milling, high power sonication and spin-coating. MoS2 and Bi2Se3 as precursors in composites preparation were synthesized by hydrothermal method. The structure and morphology of various composites were correlated with their electrochemical properties obtained by impedance spectroscopy, linear sweep and cyclic voltammetry. Mechanical milling provided composites with the most pronounced activity improvement as a result of the largest damage and amount of introduced defects into the materials structure. The potential required to achieve the current density of 10 mA/cm2 in these samples is lowered up to 50 mV compared to as-synthesized material. Bi2Se3 in composite materials promotes the electron transfer to MoS2 which leads to the decrease of charge transfer resistance by 25 Ω.
T2  - Journal of Energy Storage
T1  - Composites of transition metal dichalcogenides and topological insulators as catalytic materials for HER
VL  - 68
SP  - 107719
DO  - 10.1016/j.est.2023.107719
ER  - 

@article{
author = "Rmuš, Jelena and Belec, Blaž and Milanović, Igor and Fanetti, Mattia and Gardonio, Sandra and Valant, Matjaž and Kurko, Sandra",
year = "2023",
abstract = "To produce materials with enhanced catalytic activity toward hydrogen evolution reaction we combined MoS2 as transition metal dichalcogenide and Bi2Se3 as topological insulator. The composites were produced by three methods: mechanical milling, high power sonication and spin-coating. MoS2 and Bi2Se3 as precursors in composites preparation were synthesized by hydrothermal method. The structure and morphology of various composites were correlated with their electrochemical properties obtained by impedance spectroscopy, linear sweep and cyclic voltammetry. Mechanical milling provided composites with the most pronounced activity improvement as a result of the largest damage and amount of introduced defects into the materials structure. The potential required to achieve the current density of 10 mA/cm2 in these samples is lowered up to 50 mV compared to as-synthesized material. Bi2Se3 in composite materials promotes the electron transfer to MoS2 which leads to the decrease of charge transfer resistance by 25 Ω.",
journal = "Journal of Energy Storage",
title = "Composites of transition metal dichalcogenides and topological insulators as catalytic materials for HER",
volume = "68",
pages = "107719",
doi = "10.1016/j.est.2023.107719"
}

Rmuš, J., Belec, B., Milanović, I., Fanetti, M., Gardonio, S., Valant, M.,& Kurko, S.. (2023). Composites of transition metal dichalcogenides and topological insulators as catalytic materials for HER. in Journal of Energy Storage, 68, 107719.
https://doi.org/10.1016/j.est.2023.107719

Rmuš J, Belec B, Milanović I, Fanetti M, Gardonio S, Valant M, Kurko S. Composites of transition metal dichalcogenides and topological insulators as catalytic materials for HER. in Journal of Energy Storage. 2023;68:107719.
doi:10.1016/j.est.2023.107719 .

Rmuš, Jelena, Belec, Blaž, Milanović, Igor, Fanetti, Mattia, Gardonio, Sandra, Valant, Matjaž, Kurko, Sandra, "Composites of transition metal dichalcogenides and topological insulators as catalytic materials for HER" in Journal of Energy Storage, 68 (2023):107719,
https://doi.org/10.1016/j.est.2023.107719 . .

TY  - CONF
AU  - Babić, Bojana
AU  - Prvulović, Milica
AU  - Rmuš, Jelena
AU  - Mitrović Rajić, Anđela
AU  - Milošević Govedarović, Sanja
AU  - Milanović, Igor
AU  - Kurko, Sandra
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12765
AB  - Metal and complex light hydrides are the best fitted materials for hydrogen storage within the concept of hydrogen based economy [1]. They meet the basic application requirements: low-cost, safety and they are environmentally friendly. Beside their benefits, as relatively stable compounds, these materials exhibit also some undesirable properties like sluggish kinetics and high temperature of hydrogen desorption. LiAlH4 has emerged as a potential material for solid-state hydrogen storage because of its high hydrogen gravimetric capacity (10.5 wt%). It decomposes in three steps, according to the reactions [2]: 3LiAlH4 → Li3AlH6 + 2Al + H2                             (R1) Li3AlH6 → 3LiH + Al + 3/2H2               (R2) 3LiH+3Al → 3LiAl + 3/2H2                              (R3) The temperature of the first reaction is between 150-175°C, of the second between 180-220°C and the third between 400420°C. The first two reactions (R1 and R2) are very important from the hydrogen storage point of view: (i) both take place at a reasonable low temperatures and (ii) overall sum of theirs gravimetric hydrogen capacity is 7.8 wt.%, so the reactions (R1) and (R2) are accessible for practical hydrogen storage. However, the slow dehydrogenation kinetics and irreversibility under moderate condition hinder its imminent application.  Particle refinement and catalyst or additive introduction by mechanical milling led to the significant improvement of LiAlH4 hydrogen storage properties [2].  However, during the milling process, the temperature in the milling chamber can significantly increase reaching the temperature of R1 or even R2 leading to the degradation of hydride, change in the hydrogen desorption mechanism (figure 1) and decrease in the hydrogen storage capacity of material [3]. So, in this work the impact of metallic (V, Mn an Cr) and metal oxide (Fe2O3 and Nb2O5) additives on the LiAlH4 hydrogen desorption properties with the emphasis on the hydride degradation process during milling and a consequent hydrogen desorption reaction mechanism was studied. The aim was to improve the hydrogen desorption kinetics without hydrogen capacity deterioration.
PB  - Split : University of Split
C3  - mESC-IS 2022 : 6th International Symposium on Materials for Energy Storage and Conversion : Book of abstracts
T1  - Effect of metalic and metal-oxide catalysts on LiAlH4 decomposition
SP  - 23
EP  - 23
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12765
ER  - 

@conference{
author = "Babić, Bojana and Prvulović, Milica and Rmuš, Jelena and Mitrović Rajić, Anđela and Milošević Govedarović, Sanja and Milanović, Igor and Kurko, Sandra",
year = "2022",
abstract = "Metal and complex light hydrides are the best fitted materials for hydrogen storage within the concept of hydrogen based economy [1]. They meet the basic application requirements: low-cost, safety and they are environmentally friendly. Beside their benefits, as relatively stable compounds, these materials exhibit also some undesirable properties like sluggish kinetics and high temperature of hydrogen desorption. LiAlH4 has emerged as a potential material for solid-state hydrogen storage because of its high hydrogen gravimetric capacity (10.5 wt%). It decomposes in three steps, according to the reactions [2]: 3LiAlH4 → Li3AlH6 + 2Al + H2                             (R1) Li3AlH6 → 3LiH + Al + 3/2H2               (R2) 3LiH+3Al → 3LiAl + 3/2H2                              (R3) The temperature of the first reaction is between 150-175°C, of the second between 180-220°C and the third between 400420°C. The first two reactions (R1 and R2) are very important from the hydrogen storage point of view: (i) both take place at a reasonable low temperatures and (ii) overall sum of theirs gravimetric hydrogen capacity is 7.8 wt.%, so the reactions (R1) and (R2) are accessible for practical hydrogen storage. However, the slow dehydrogenation kinetics and irreversibility under moderate condition hinder its imminent application.  Particle refinement and catalyst or additive introduction by mechanical milling led to the significant improvement of LiAlH4 hydrogen storage properties [2].  However, during the milling process, the temperature in the milling chamber can significantly increase reaching the temperature of R1 or even R2 leading to the degradation of hydride, change in the hydrogen desorption mechanism (figure 1) and decrease in the hydrogen storage capacity of material [3]. So, in this work the impact of metallic (V, Mn an Cr) and metal oxide (Fe2O3 and Nb2O5) additives on the LiAlH4 hydrogen desorption properties with the emphasis on the hydride degradation process during milling and a consequent hydrogen desorption reaction mechanism was studied. The aim was to improve the hydrogen desorption kinetics without hydrogen capacity deterioration.",
publisher = "Split : University of Split",
journal = "mESC-IS 2022 : 6th International Symposium on Materials for Energy Storage and Conversion : Book of abstracts",
title = "Effect of metalic and metal-oxide catalysts on LiAlH4 decomposition",
pages = "23-23",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12765"
}

Babić, B., Prvulović, M., Rmuš, J., Mitrović Rajić, A., Milošević Govedarović, S., Milanović, I.,& Kurko, S.. (2022). Effect of metalic and metal-oxide catalysts on LiAlH4 decomposition. in mESC-IS 2022 : 6th International Symposium on Materials for Energy Storage and Conversion : Book of abstracts
Split : University of Split., 23-23.
https://hdl.handle.net/21.15107/rcub_vinar_12765

Babić B, Prvulović M, Rmuš J, Mitrović Rajić A, Milošević Govedarović S, Milanović I, Kurko S. Effect of metalic and metal-oxide catalysts on LiAlH4 decomposition. in mESC-IS 2022 : 6th International Symposium on Materials for Energy Storage and Conversion : Book of abstracts. 2022;:23-23.
https://hdl.handle.net/21.15107/rcub_vinar_12765 .

Babić, Bojana, Prvulović, Milica, Rmuš, Jelena, Mitrović Rajić, Anđela, Milošević Govedarović, Sanja, Milanović, Igor, Kurko, Sandra, "Effect of metalic and metal-oxide catalysts on LiAlH4 decomposition" in mESC-IS 2022 : 6th International Symposium on Materials for Energy Storage and Conversion : Book of abstracts (2022):23-23,
https://hdl.handle.net/21.15107/rcub_vinar_12765 .

TY  - JOUR
AU  - Mravik, Željko
AU  - Bajuk-Bogdanović, Danica V.
AU  - Jovanović, Sonja
AU  - Rmuš, Jelena
AU  - Olejniczak, Andrzej
AU  - Mraković, Ana Đ.
AU  - Lazarević, Jasmina
AU  - Uskoković-Marković, Snežana
AU  - Lazarević, Nenad
AU  - Skuratov, Vladimir A.
AU  - Jovanović, Zoran
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10376
AB  - Ion beam irradiation is a versatile tool for structural modification andengineering of new materials. In this study, 12-tungstophosphoric acid (WPA)films of different thickness were spin-coated on platinized silicon substrate andirradiated with low energy hydrogen ions (10 keV) and swift heavy ions (Bi,Xe, and V) with energies up to 710 MeV. The different energy/fluence combi-nations allowed controllable structural changes that were investigated in detailusing Raman and Infrared spectroscopy. For 120-nm-thick WPA samples, theirradiation led to the decrease of intensity of the skeletal and W-Oc-W bands ofKeggin anion in order: Bi < V < Xe (for their applied energy/fluence combina-tion). Also, symmetry change of Keggin anion similar to the one observed inthe case of Keggin anions interacting with the supports was observed. For theselected ion beam irradiation parameters, xenon ion beam induced transforma-tion of WPA to polytungstate. For 20-μm-thick WPA samples, the irradiationwith hydrogen ion beam induced changes of skeletal vibrations and increasedindividualistic behavior of Keggin anions. As the fluence increased, theamount of the Keggin anions partially transformed to bronze also increased.Irradiation with vanadium also caused transformation to bronze-like structurebut with higher ratio of terminal W=Odbonds. The overall results show clearReceived: 9 February 2022Revised: 17 June 2022Accepted: 5 July 2022DOI: 10.1002/jrs.6423J Raman Spectrosc.2022;1–11.wileyonlinelibrary.com/journal/jrs© 2022 John Wiley & Sons Ltd.1correlation between degree of structural modification of WPA and thecalculated displacement per atom value. These results open possibilities forengineering new catalytically active structures of polyoxometalates with thehelp of ion beams.
T2  - Journal of Raman Spectroscopy
T1  - Modification of Keggin anion structure with ion beams—A new spectroscopic insights into the effects of keV- and MeV-ion beam irradiation on 12-tungstophosphoric acid
DO  - 10.1002/jrs.6423
ER  - 

@article{
author = "Mravik, Željko and Bajuk-Bogdanović, Danica V. and Jovanović, Sonja and Rmuš, Jelena and Olejniczak, Andrzej and Mraković, Ana Đ. and Lazarević, Jasmina and Uskoković-Marković, Snežana and Lazarević, Nenad and Skuratov, Vladimir A. and Jovanović, Zoran",
year = "2022",
abstract = "Ion beam irradiation is a versatile tool for structural modification andengineering of new materials. In this study, 12-tungstophosphoric acid (WPA)films of different thickness were spin-coated on platinized silicon substrate andirradiated with low energy hydrogen ions (10 keV) and swift heavy ions (Bi,Xe, and V) with energies up to 710 MeV. The different energy/fluence combi-nations allowed controllable structural changes that were investigated in detailusing Raman and Infrared spectroscopy. For 120-nm-thick WPA samples, theirradiation led to the decrease of intensity of the skeletal and W-Oc-W bands ofKeggin anion in order: Bi < V < Xe (for their applied energy/fluence combina-tion). Also, symmetry change of Keggin anion similar to the one observed inthe case of Keggin anions interacting with the supports was observed. For theselected ion beam irradiation parameters, xenon ion beam induced transforma-tion of WPA to polytungstate. For 20-μm-thick WPA samples, the irradiationwith hydrogen ion beam induced changes of skeletal vibrations and increasedindividualistic behavior of Keggin anions. As the fluence increased, theamount of the Keggin anions partially transformed to bronze also increased.Irradiation with vanadium also caused transformation to bronze-like structurebut with higher ratio of terminal W=Odbonds. The overall results show clearReceived: 9 February 2022Revised: 17 June 2022Accepted: 5 July 2022DOI: 10.1002/jrs.6423J Raman Spectrosc.2022;1–11.wileyonlinelibrary.com/journal/jrs© 2022 John Wiley & Sons Ltd.1correlation between degree of structural modification of WPA and thecalculated displacement per atom value. These results open possibilities forengineering new catalytically active structures of polyoxometalates with thehelp of ion beams.",
journal = "Journal of Raman Spectroscopy",
title = "Modification of Keggin anion structure with ion beams—A new spectroscopic insights into the effects of keV- and MeV-ion beam irradiation on 12-tungstophosphoric acid",
doi = "10.1002/jrs.6423"
}

Mravik, Ž., Bajuk-Bogdanović, D. V., Jovanović, S., Rmuš, J., Olejniczak, A., Mraković, A. Đ., Lazarević, J., Uskoković-Marković, S., Lazarević, N., Skuratov, V. A.,& Jovanović, Z.. (2022). Modification of Keggin anion structure with ion beams—A new spectroscopic insights into the effects of keV- and MeV-ion beam irradiation on 12-tungstophosphoric acid. in Journal of Raman Spectroscopy.
https://doi.org/10.1002/jrs.6423

Mravik Ž, Bajuk-Bogdanović DV, Jovanović S, Rmuš J, Olejniczak A, Mraković AĐ, Lazarević J, Uskoković-Marković S, Lazarević N, Skuratov VA, Jovanović Z. Modification of Keggin anion structure with ion beams—A new spectroscopic insights into the effects of keV- and MeV-ion beam irradiation on 12-tungstophosphoric acid. in Journal of Raman Spectroscopy. 2022;.
doi:10.1002/jrs.6423 .

Mravik, Željko, Bajuk-Bogdanović, Danica V., Jovanović, Sonja, Rmuš, Jelena, Olejniczak, Andrzej, Mraković, Ana Đ., Lazarević, Jasmina, Uskoković-Marković, Snežana, Lazarević, Nenad, Skuratov, Vladimir A., Jovanović, Zoran, "Modification of Keggin anion structure with ion beams—A new spectroscopic insights into the effects of keV- and MeV-ion beam irradiation on 12-tungstophosphoric acid" in Journal of Raman Spectroscopy (2022),
https://doi.org/10.1002/jrs.6423 . .

TY  - JOUR
AU  - Milanović, Igor
AU  - Milošević Govedarović, Sanja S.
AU  - Lukić, Miodrag
AU  - Jovanović, Zoran
AU  - Rmuš, Jelena
AU  - Mitrović-Rajić, Anđela
AU  - Grbović-Novaković, Jasmina
AU  - Kurko, Sandra V.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10504
AB  - LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15min, and depending on the milling time, various phenomena took place. Up to a milling time of 5min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15min. Moreover, the mechanical milling process leads to the transformation of AlH - 4 to AlH 3 - 6 structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements.Mechanical milling with the addition of Fe2O3 for up to 15min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.
T2  - Processing and Application of Ceramics
T1  - Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites
VL  - 16
IS  - 3
SP  - 259
EP  - 266
DO  - 10.2298/PAC2203259M
ER  - 

@article{
author = "Milanović, Igor and Milošević Govedarović, Sanja S. and Lukić, Miodrag and Jovanović, Zoran and Rmuš, Jelena and Mitrović-Rajić, Anđela and Grbović-Novaković, Jasmina and Kurko, Sandra V.",
year = "2022",
abstract = "LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15min, and depending on the milling time, various phenomena took place. Up to a milling time of 5min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15min. Moreover, the mechanical milling process leads to the transformation of AlH - 4 to AlH 3 - 6 structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements.Mechanical milling with the addition of Fe2O3 for up to 15min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.",
journal = "Processing and Application of Ceramics",
title = "Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites",
volume = "16",
number = "3",
pages = "259-266",
doi = "10.2298/PAC2203259M"
}

Milanović, I., Milošević Govedarović, S. S., Lukić, M., Jovanović, Z., Rmuš, J., Mitrović-Rajić, A., Grbović-Novaković, J.,& Kurko, S. V.. (2022). Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. in Processing and Application of Ceramics, 16(3), 259-266.
https://doi.org/10.2298/PAC2203259M

Milanović I, Milošević Govedarović SS, Lukić M, Jovanović Z, Rmuš J, Mitrović-Rajić A, Grbović-Novaković J, Kurko SV. Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. in Processing and Application of Ceramics. 2022;16(3):259-266.
doi:10.2298/PAC2203259M .

Milanović, Igor, Milošević Govedarović, Sanja S., Lukić, Miodrag, Jovanović, Zoran, Rmuš, Jelena, Mitrović-Rajić, Anđela, Grbović-Novaković, Jasmina, Kurko, Sandra V., "Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites" in Processing and Application of Ceramics, 16, no. 3 (2022):259-266,
https://doi.org/10.2298/PAC2203259M . .

TY  - CONF
AU  - Kurko, Sandra
AU  - Milošević Govedarović, Sanja
AU  - Rmuš, Jelena
AU  - Batalović, Katarina
AU  - Pantić, Tijana
AU  - Prvulović, Milica
AU  - Milanović, Igor
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11245
AB  - Mechanical milling of pure lithium alanate (LiAlH4) was done with addition of 5 weigh percent of Fe2O3 using different milling time ranging from 1 to 15 minutes [1]. Mechanical milling of composites causes destabilization of LiAlH4 structure as it observed by XRD measurements. Particle size distribution results reveals that composite particle size decrease with milling time up to 3 minutes, and then increase almost to the original size, for 15 min sample. Mechanical mailing cause phase transformation from AlH4- to AlH63-. As a consequence of structural and chemical changes, desorption properties of composites are change kinetic of desorption is improved in comparison to unmilled LiAlH4. The shifting of hydrogen desorption temperature to lower temperatures is observed together with change from multi-step desorption to one-step hydrogen desorption is also observed. This caused decrease in activation energy of composites from Ea = 665 kJ/mol for unmilled LiAlH4, Ea = 279 kJ/mol for 3 min milled composite.
PB  - Zagreb : "Ruđer Bošković" Institute
C3  - Solid-State Science & Research 2021 : Book of Abstracts and Program
T1  - Mechanochemical activation of LiAlH4-Fe2O3 composites-a method to enhance kinetics of hydrogen desorption
SP  - 49
EP  - 49
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11245
ER  - 

@conference{
author = "Kurko, Sandra and Milošević Govedarović, Sanja and Rmuš, Jelena and Batalović, Katarina and Pantić, Tijana and Prvulović, Milica and Milanović, Igor",
year = "2021",
abstract = "Mechanical milling of pure lithium alanate (LiAlH4) was done with addition of 5 weigh percent of Fe2O3 using different milling time ranging from 1 to 15 minutes [1]. Mechanical milling of composites causes destabilization of LiAlH4 structure as it observed by XRD measurements. Particle size distribution results reveals that composite particle size decrease with milling time up to 3 minutes, and then increase almost to the original size, for 15 min sample. Mechanical mailing cause phase transformation from AlH4- to AlH63-. As a consequence of structural and chemical changes, desorption properties of composites are change kinetic of desorption is improved in comparison to unmilled LiAlH4. The shifting of hydrogen desorption temperature to lower temperatures is observed together with change from multi-step desorption to one-step hydrogen desorption is also observed. This caused decrease in activation energy of composites from Ea = 665 kJ/mol for unmilled LiAlH4, Ea = 279 kJ/mol for 3 min milled composite.",
publisher = "Zagreb : "Ruđer Bošković" Institute",
journal = "Solid-State Science & Research 2021 : Book of Abstracts and Program",
title = "Mechanochemical activation of LiAlH4-Fe2O3 composites-a method to enhance kinetics of hydrogen desorption",
pages = "49-49",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11245"
}

Kurko, S., Milošević Govedarović, S., Rmuš, J., Batalović, K., Pantić, T., Prvulović, M.,& Milanović, I.. (2021). Mechanochemical activation of LiAlH4-Fe2O3 composites-a method to enhance kinetics of hydrogen desorption. in Solid-State Science & Research 2021 : Book of Abstracts and Program
Zagreb : "Ruđer Bošković" Institute., 49-49.
https://hdl.handle.net/21.15107/rcub_vinar_11245

Kurko S, Milošević Govedarović S, Rmuš J, Batalović K, Pantić T, Prvulović M, Milanović I. Mechanochemical activation of LiAlH4-Fe2O3 composites-a method to enhance kinetics of hydrogen desorption. in Solid-State Science & Research 2021 : Book of Abstracts and Program. 2021;:49-49.
https://hdl.handle.net/21.15107/rcub_vinar_11245 .

Kurko, Sandra, Milošević Govedarović, Sanja, Rmuš, Jelena, Batalović, Katarina, Pantić, Tijana, Prvulović, Milica, Milanović, Igor, "Mechanochemical activation of LiAlH4-Fe2O3 composites-a method to enhance kinetics of hydrogen desorption" in Solid-State Science & Research 2021 : Book of Abstracts and Program (2021):49-49,
https://hdl.handle.net/21.15107/rcub_vinar_11245 .

TY  - JOUR
AU  - Kurko, Sandra V.
AU  - Paskaš Mamula, Bojana
AU  - Rmuš, Jelena
AU  - Grbović-Novaković, Jasmina
AU  - Novaković, Nikola
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8560
AB  - The impact of boron doping on MgH2 bonding mechanism, hydrogen diffusion and desorption was calculated using density functional theory (DFT). Atomic interactions in doped and non-doped system and its influence on hydrogen and vacancy diffusion were studied in bulk hydride. Slab calculations were performed to study hydrogen desorption energies from (110) boron doped surface and its dependence on the surface configuration and depth position. To study kinetics of hydrogen diffusion in boron vicinity and hydrogen molecule desorption activation energies from boron doped and non-doped (110) MgH2 surface Nudged Elastic Band (NEB) method was used. Results showed that boron forms stronger, covalent bonds with hydrogen causing the destabilization in its first and second coordination. This leads to lower hydrogen desorption energies and improved hydrogen diffusion, while the impact on the energy barriers for H2 desorption from hydride (110) surface is less pronounced. © 2019 Hydrogen Energy Publications LLC
T2  - International Journal of Hydrogen Energy
T1  - DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption
VL  - 45
IS  - 14
SP  - 7947
EP  - 7957
DO  - 10.1016/j.ijhydene.2019.05.015
ER  - 

@article{
author = "Kurko, Sandra V. and Paskaš Mamula, Bojana and Rmuš, Jelena and Grbović-Novaković, Jasmina and Novaković, Nikola",
year = "2020",
abstract = "The impact of boron doping on MgH2 bonding mechanism, hydrogen diffusion and desorption was calculated using density functional theory (DFT). Atomic interactions in doped and non-doped system and its influence on hydrogen and vacancy diffusion were studied in bulk hydride. Slab calculations were performed to study hydrogen desorption energies from (110) boron doped surface and its dependence on the surface configuration and depth position. To study kinetics of hydrogen diffusion in boron vicinity and hydrogen molecule desorption activation energies from boron doped and non-doped (110) MgH2 surface Nudged Elastic Band (NEB) method was used. Results showed that boron forms stronger, covalent bonds with hydrogen causing the destabilization in its first and second coordination. This leads to lower hydrogen desorption energies and improved hydrogen diffusion, while the impact on the energy barriers for H2 desorption from hydride (110) surface is less pronounced. © 2019 Hydrogen Energy Publications LLC",
journal = "International Journal of Hydrogen Energy",
title = "DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption",
volume = "45",
number = "14",
pages = "7947-7957",
doi = "10.1016/j.ijhydene.2019.05.015"
}

Kurko, S. V., Paskaš Mamula, B., Rmuš, J., Grbović-Novaković, J.,& Novaković, N.. (2020). DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption. in International Journal of Hydrogen Energy, 45(14), 7947-7957.
https://doi.org/10.1016/j.ijhydene.2019.05.015

Kurko SV, Paskaš Mamula B, Rmuš J, Grbović-Novaković J, Novaković N. DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption. in International Journal of Hydrogen Energy. 2020;45(14):7947-7957.
doi:10.1016/j.ijhydene.2019.05.015 .

Kurko, Sandra V., Paskaš Mamula, Bojana, Rmuš, Jelena, Grbović-Novaković, Jasmina, Novaković, Nikola, "DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7947-7957,
https://doi.org/10.1016/j.ijhydene.2019.05.015 . .

TY  - CONF
AU  - Mitrović, Anđela I.
AU  - Milićević, Jelena
AU  - Milošević Govedarović, Sanja S.
AU  - Kurko, Sandra
AU  - Pantić, Tijana B.
AU  - Rmuš, Jelena
AU  - Mravik, Željko
AU  - Grbović-Novaković, Jasmina
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11182
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - Electrochemical sensors based on pyrophyllite
SP  - 97
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11182
ER  - 

@conference{
author = "Mitrović, Anđela I. and Milićević, Jelena and Milošević Govedarović, Sanja S. and Kurko, Sandra and Pantić, Tijana B. and Rmuš, Jelena and Mravik, Željko and Grbović-Novaković, Jasmina",
year = "2019",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "Electrochemical sensors based on pyrophyllite",
pages = "97",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11182"
}

Mitrović, A. I., Milićević, J., Milošević Govedarović, S. S., Kurko, S., Pantić, T. B., Rmuš, J., Mravik, Ž.,& Grbović-Novaković, J.. (2019). Electrochemical sensors based on pyrophyllite. in Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 97.
https://hdl.handle.net/21.15107/rcub_vinar_11182

Mitrović AI, Milićević J, Milošević Govedarović SS, Kurko S, Pantić TB, Rmuš J, Mravik Ž, Grbović-Novaković J. Electrochemical sensors based on pyrophyllite. in Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:97.
https://hdl.handle.net/21.15107/rcub_vinar_11182 .

Mitrović, Anđela I., Milićević, Jelena, Milošević Govedarović, Sanja S., Kurko, Sandra, Pantić, Tijana B., Rmuš, Jelena, Mravik, Željko, Grbović-Novaković, Jasmina, "Electrochemical sensors based on pyrophyllite" in Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):97,
https://hdl.handle.net/21.15107/rcub_vinar_11182 .

TY  - JOUR
AU  - Grbović-Novaković, Jasmina
AU  - Novaković, Nikola
AU  - Kurko, Sandra V.
AU  - Milošević Govedarović, Sanja S.
AU  - Pantić, Tijana
AU  - Paskaš Mamula, Bojana
AU  - Batalović, Katarina
AU  - Radaković, Jana
AU  - Rmuš, Jelena
AU  - Shelyapina, Marina
AU  - Skryabina, Nataliya
AU  - de Rango, Patricia
AU  - Fruchart, Daniel
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8161
AB  - This review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated. Theoretical studies, mainly carried out within various implementations of DFT, are a powerful tool to study mostly MgH 2 based materials. By providing an insight on metal-hydrogen bonding that governs both thermodynamics and hydrogen kinetics, they allow us to describe phenomena to which experimental methods have a limited access or do not have it at all: to follow the hydrogen sorption reaction on a specific metal surface and hydrogen induced phase transformations, to describe structure of phase boundaries or to explain the impact of defects or various additives on MgH 2 stability and hydrogen sorption kinetics. In several cases theoretical calculations reveal themselves as being able to predict new properties of materials, including the ways to modify Mg or MgH 2 that would lead to better characteristics in terms of hydrogen storage. The influence of ion irradiation and mechanical milling with and without additives has been discussed. Ion irradiation is the way to introduce a well-defined concentration of defects (Frankel pairs) at the surface and sub-surface layers of a material. Defects at the surface play the main role in sorption reaction since they enhance the dissociation of hydrogen. On the other hand, ball-milling introduce defects through the entire sample volume, refine the structure and thus decrease the path for hydrogen diffusion. Two Severe Plastic Deformation techniques were used to better understand the hydrogenation/dehydrogenation kinetics of Mg- and Mg 2 Ni-based alloys: Equal-Angular-Channel-Pressing and Fast-Forging. Successive ECAP passes leads to refinement of the microstructure of AZ31 ingots and to instalment therein of high densities of defects. Depending on mode, number and temperature of ECAP passes, the H-sorption kinetics have been improved satisfactorily without any additive for mass H-storage applications considering the relative speed of the shaping procedure. A qualitative understanding of the kinetic advanced principles has been built. Fast-Forging was used for a “quasi-instantaneous” synthesis of Mg/Mg 2 Ni-based composites. Hydrogenation of the as-received almost bi-phased materials remains rather slow as generally observed elsewhere, whatever are multiple and different techniques used to deliver the composite alloys. However, our preliminary results suggest that a synergic hydrogenation / dehydrogenation process should assist hydrogen transfers from Mg/Mg 2 Ni on one side to MgH 2 /Mg 2 NiH 4 on the other side via the rather stable a-Mg 2 NiH 0.3 , acting as in-situ catalyser. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - ChemPhysChem
T1  - Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides
VL  - 20
IS  - 10
SP  - 1216
EP  - 1247
DO  - 10.1002/cphc.201801125
ER  - 

@article{
author = "Grbović-Novaković, Jasmina and Novaković, Nikola and Kurko, Sandra V. and Milošević Govedarović, Sanja S. and Pantić, Tijana and Paskaš Mamula, Bojana and Batalović, Katarina and Radaković, Jana and Rmuš, Jelena and Shelyapina, Marina and Skryabina, Nataliya and de Rango, Patricia and Fruchart, Daniel",
year = "2019",
abstract = "This review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated. Theoretical studies, mainly carried out within various implementations of DFT, are a powerful tool to study mostly MgH 2 based materials. By providing an insight on metal-hydrogen bonding that governs both thermodynamics and hydrogen kinetics, they allow us to describe phenomena to which experimental methods have a limited access or do not have it at all: to follow the hydrogen sorption reaction on a specific metal surface and hydrogen induced phase transformations, to describe structure of phase boundaries or to explain the impact of defects or various additives on MgH 2 stability and hydrogen sorption kinetics. In several cases theoretical calculations reveal themselves as being able to predict new properties of materials, including the ways to modify Mg or MgH 2 that would lead to better characteristics in terms of hydrogen storage. The influence of ion irradiation and mechanical milling with and without additives has been discussed. Ion irradiation is the way to introduce a well-defined concentration of defects (Frankel pairs) at the surface and sub-surface layers of a material. Defects at the surface play the main role in sorption reaction since they enhance the dissociation of hydrogen. On the other hand, ball-milling introduce defects through the entire sample volume, refine the structure and thus decrease the path for hydrogen diffusion. Two Severe Plastic Deformation techniques were used to better understand the hydrogenation/dehydrogenation kinetics of Mg- and Mg 2 Ni-based alloys: Equal-Angular-Channel-Pressing and Fast-Forging. Successive ECAP passes leads to refinement of the microstructure of AZ31 ingots and to instalment therein of high densities of defects. Depending on mode, number and temperature of ECAP passes, the H-sorption kinetics have been improved satisfactorily without any additive for mass H-storage applications considering the relative speed of the shaping procedure. A qualitative understanding of the kinetic advanced principles has been built. Fast-Forging was used for a “quasi-instantaneous” synthesis of Mg/Mg 2 Ni-based composites. Hydrogenation of the as-received almost bi-phased materials remains rather slow as generally observed elsewhere, whatever are multiple and different techniques used to deliver the composite alloys. However, our preliminary results suggest that a synergic hydrogenation / dehydrogenation process should assist hydrogen transfers from Mg/Mg 2 Ni on one side to MgH 2 /Mg 2 NiH 4 on the other side via the rather stable a-Mg 2 NiH 0.3 , acting as in-situ catalyser. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "ChemPhysChem",
title = "Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides",
volume = "20",
number = "10",
pages = "1216-1247",
doi = "10.1002/cphc.201801125"
}

Grbović-Novaković, J., Novaković, N., Kurko, S. V., Milošević Govedarović, S. S., Pantić, T., Paskaš Mamula, B., Batalović, K., Radaković, J., Rmuš, J., Shelyapina, M., Skryabina, N., de Rango, P.,& Fruchart, D.. (2019). Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides. in ChemPhysChem, 20(10), 1216-1247.
https://doi.org/10.1002/cphc.201801125

Grbović-Novaković J, Novaković N, Kurko SV, Milošević Govedarović SS, Pantić T, Paskaš Mamula B, Batalović K, Radaković J, Rmuš J, Shelyapina M, Skryabina N, de Rango P, Fruchart D. Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides. in ChemPhysChem. 2019;20(10):1216-1247.
doi:10.1002/cphc.201801125 .

Grbović-Novaković, Jasmina, Novaković, Nikola, Kurko, Sandra V., Milošević Govedarović, Sanja S., Pantić, Tijana, Paskaš Mamula, Bojana, Batalović, Katarina, Radaković, Jana, Rmuš, Jelena, Shelyapina, Marina, Skryabina, Nataliya, de Rango, Patricia, Fruchart, Daniel, "Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides" in ChemPhysChem, 20, no. 10 (2019):1216-1247,
https://doi.org/10.1002/cphc.201801125 . .

TY  - JOUR
AU  - Grbović-Novaković, Jasmina
AU  - Novaković, Nikola
AU  - Kurko, Sandra V.
AU  - Milošević Govedarović, Sanja S.
AU  - Pantić, Tijana
AU  - Paskaš Mamula, Bojana
AU  - Batalović, Katarina
AU  - Radaković, Jana
AU  - Rmuš, Jelena
AU  - Shelyapina, Marina
AU  - Skryabina, Nataliya
AU  - de Rango, Patricia
AU  - Fruchart, Daniel
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8169
AB  - This review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated. Theoretical studies, mainly carried out within various implementations of DFT, are a powerful tool to study mostly MgH 2 based materials. By providing an insight on metal-hydrogen bonding that governs both thermodynamics and hydrogen kinetics, they allow us to describe phenomena to which experimental methods have a limited access or do not have it at all: to follow the hydrogen sorption reaction on a specific metal surface and hydrogen induced phase transformations, to describe structure of phase boundaries or to explain the impact of defects or various additives on MgH 2 stability and hydrogen sorption kinetics. In several cases theoretical calculations reveal themselves as being able to predict new properties of materials, including the ways to modify Mg or MgH 2 that would lead to better characteristics in terms of hydrogen storage. The influence of ion irradiation and mechanical milling with and without additives has been discussed. Ion irradiation is the way to introduce a well-defined concentration of defects (Frankel pairs) at the surface and sub-surface layers of a material. Defects at the surface play the main role in sorption reaction since they enhance the dissociation of hydrogen. On the other hand, ball-milling introduce defects through the entire sample volume, refine the structure and thus decrease the path for hydrogen diffusion. Two Severe Plastic Deformation techniques were used to better understand the hydrogenation/dehydrogenation kinetics of Mg- and Mg 2 Ni-based alloys: Equal-Angular-Channel-Pressing and Fast-Forging. Successive ECAP passes leads to refinement of the microstructure of AZ31 ingots and to instalment therein of high densities of defects. Depending on mode, number and temperature of ECAP passes, the H-sorption kinetics have been improved satisfactorily without any additive for mass H-storage applications considering the relative speed of the shaping procedure. A qualitative understanding of the kinetic advanced principles has been built. Fast-Forging was used for a “quasi-instantaneous” synthesis of Mg/Mg 2 Ni-based composites. Hydrogenation of the as-received almost bi-phased materials remains rather slow as generally observed elsewhere, whatever are multiple and different techniques used to deliver the composite alloys. However, our preliminary results suggest that a synergic hydrogenation / dehydrogenation process should assist hydrogen transfers from Mg/Mg 2 Ni on one side to MgH 2 /Mg 2 NiH 4 on the other side via the rather stable a-Mg 2 NiH 0.3 , acting as in-situ catalyser. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - ChemPhysChem
T1  - Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides
VL  - 20
IS  - 10
SP  - 1216
EP  - 1247
DO  - 10.1002/cphc.201801125
ER  - 

@article{
author = "Grbović-Novaković, Jasmina and Novaković, Nikola and Kurko, Sandra V. and Milošević Govedarović, Sanja S. and Pantić, Tijana and Paskaš Mamula, Bojana and Batalović, Katarina and Radaković, Jana and Rmuš, Jelena and Shelyapina, Marina and Skryabina, Nataliya and de Rango, Patricia and Fruchart, Daniel",
year = "2019",
abstract = "This review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated. Theoretical studies, mainly carried out within various implementations of DFT, are a powerful tool to study mostly MgH 2 based materials. By providing an insight on metal-hydrogen bonding that governs both thermodynamics and hydrogen kinetics, they allow us to describe phenomena to which experimental methods have a limited access or do not have it at all: to follow the hydrogen sorption reaction on a specific metal surface and hydrogen induced phase transformations, to describe structure of phase boundaries or to explain the impact of defects or various additives on MgH 2 stability and hydrogen sorption kinetics. In several cases theoretical calculations reveal themselves as being able to predict new properties of materials, including the ways to modify Mg or MgH 2 that would lead to better characteristics in terms of hydrogen storage. The influence of ion irradiation and mechanical milling with and without additives has been discussed. Ion irradiation is the way to introduce a well-defined concentration of defects (Frankel pairs) at the surface and sub-surface layers of a material. Defects at the surface play the main role in sorption reaction since they enhance the dissociation of hydrogen. On the other hand, ball-milling introduce defects through the entire sample volume, refine the structure and thus decrease the path for hydrogen diffusion. Two Severe Plastic Deformation techniques were used to better understand the hydrogenation/dehydrogenation kinetics of Mg- and Mg 2 Ni-based alloys: Equal-Angular-Channel-Pressing and Fast-Forging. Successive ECAP passes leads to refinement of the microstructure of AZ31 ingots and to instalment therein of high densities of defects. Depending on mode, number and temperature of ECAP passes, the H-sorption kinetics have been improved satisfactorily without any additive for mass H-storage applications considering the relative speed of the shaping procedure. A qualitative understanding of the kinetic advanced principles has been built. Fast-Forging was used for a “quasi-instantaneous” synthesis of Mg/Mg 2 Ni-based composites. Hydrogenation of the as-received almost bi-phased materials remains rather slow as generally observed elsewhere, whatever are multiple and different techniques used to deliver the composite alloys. However, our preliminary results suggest that a synergic hydrogenation / dehydrogenation process should assist hydrogen transfers from Mg/Mg 2 Ni on one side to MgH 2 /Mg 2 NiH 4 on the other side via the rather stable a-Mg 2 NiH 0.3 , acting as in-situ catalyser. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "ChemPhysChem",
title = "Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides",
volume = "20",
number = "10",
pages = "1216-1247",
doi = "10.1002/cphc.201801125"
}

Grbović-Novaković, J., Novaković, N., Kurko, S. V., Milošević Govedarović, S. S., Pantić, T., Paskaš Mamula, B., Batalović, K., Radaković, J., Rmuš, J., Shelyapina, M., Skryabina, N., de Rango, P.,& Fruchart, D.. (2019). Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides. in ChemPhysChem, 20(10), 1216-1247.
https://doi.org/10.1002/cphc.201801125

Grbović-Novaković J, Novaković N, Kurko SV, Milošević Govedarović SS, Pantić T, Paskaš Mamula B, Batalović K, Radaković J, Rmuš J, Shelyapina M, Skryabina N, de Rango P, Fruchart D. Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides. in ChemPhysChem. 2019;20(10):1216-1247.
doi:10.1002/cphc.201801125 .

Grbović-Novaković, Jasmina, Novaković, Nikola, Kurko, Sandra V., Milošević Govedarović, Sanja S., Pantić, Tijana, Paskaš Mamula, Bojana, Batalović, Katarina, Radaković, Jana, Rmuš, Jelena, Shelyapina, Marina, Skryabina, Nataliya, de Rango, Patricia, Fruchart, Daniel, "Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides" in ChemPhysChem, 20, no. 10 (2019):1216-1247,
https://doi.org/10.1002/cphc.201801125 . .