TY  - JOUR
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Milica
AU  - Bukumira, Marta
AU  - Tomić, Nina
AU  - Tomić, Miloš
AU  - Mančić, Lidija
AU  - Ignjatović, Nenad
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12299
AB  - Y0.8−xGdxF3 :Yb/Er mesocrystals with a biocompatible surface and diverse morphological characteristics were successfully synthesized using chitosan-assisted solvothermal processing. Their structural properties, studied using X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy and energy dispersive X-ray analysis, were further correlated with the up-conversion emission (λexc = 976 nm) recorded in function of temperature. Based on the change in the visible green emissions originating from the thermally coupled 2H11/2 and 4S3/2 levels of Er3+, the corresponding LIR was acquired in the physiologically relevant range of temperatures (25–50 ◦C). The detected absolute sensitivity of about 0.0042 ◦C −1 , along with the low cytotoxicity toward both normal human lung fibroblasts (MRC-5) and cancerous lung epithelial (A549) cells, indicate a potential for use in temperature sensing in biomedicine. Additionally, their enhanced internalization in cells, without suppression of cell viability, enabled in vitro labeling of cancer and healthy cells upon 976 nm laser irradiation.
T2  - Journal of Functional Biomaterials
T1  - Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals
VL  - 15
IS  - 1
SP  - 6
DO  - 10.3390/jfb15010006
ER  - 

@article{
author = "Dinić, Ivana and Vuković, Marina and Rabanal, Maria Eugenia and Milošević, Milica and Bukumira, Marta and Tomić, Nina and Tomić, Miloš and Mančić, Lidija and Ignjatović, Nenad",
year = "2024",
abstract = "Y0.8−xGdxF3 :Yb/Er mesocrystals with a biocompatible surface and diverse morphological characteristics were successfully synthesized using chitosan-assisted solvothermal processing. Their structural properties, studied using X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy and energy dispersive X-ray analysis, were further correlated with the up-conversion emission (λexc = 976 nm) recorded in function of temperature. Based on the change in the visible green emissions originating from the thermally coupled 2H11/2 and 4S3/2 levels of Er3+, the corresponding LIR was acquired in the physiologically relevant range of temperatures (25–50 ◦C). The detected absolute sensitivity of about 0.0042 ◦C −1 , along with the low cytotoxicity toward both normal human lung fibroblasts (MRC-5) and cancerous lung epithelial (A549) cells, indicate a potential for use in temperature sensing in biomedicine. Additionally, their enhanced internalization in cells, without suppression of cell viability, enabled in vitro labeling of cancer and healthy cells upon 976 nm laser irradiation.",
journal = "Journal of Functional Biomaterials",
title = "Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals",
volume = "15",
number = "1",
pages = "6",
doi = "10.3390/jfb15010006"
}

Dinić, I., Vuković, M., Rabanal, M. E., Milošević, M., Bukumira, M., Tomić, N., Tomić, M., Mančić, L.,& Ignjatović, N.. (2024). Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals. in Journal of Functional Biomaterials, 15(1), 6.
https://doi.org/10.3390/jfb15010006

Dinić I, Vuković M, Rabanal ME, Milošević M, Bukumira M, Tomić N, Tomić M, Mančić L, Ignjatović N. Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals. in Journal of Functional Biomaterials. 2024;15(1):6.
doi:10.3390/jfb15010006 .

Dinić, Ivana, Vuković, Marina, Rabanal, Maria Eugenia, Milošević, Milica, Bukumira, Marta, Tomić, Nina, Tomić, Miloš, Mančić, Lidija, Ignjatović, Nenad, "Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals" in Journal of Functional Biomaterials, 15, no. 1 (2024):6,
https://doi.org/10.3390/jfb15010006 . .

TY  - JOUR
AU  - Mančić, Lidija
AU  - Dugandžić, Ivan
AU  - Milošević, Olivera
AU  - Jovanović, Dragana J.
AU  - Šaponjić, Zoran
AU  - Rabanal, Maria Eugenia
AU  - Gómez-Villalba, Luz Stella
PY  - 2015
UR  - http://dais.sanu.ac.rs/123456789/645
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7503
AB  - Hierarchically assembled TiO2 nanoparticles into larger spherical ones were obtained using aerosol-assisted processing method. Unagglomerated particles with the mean size of 440 nm were obtained from colloidal solution of TiO2 nanoparticles (~4.5 nm) using ultrasonic spray pyrolysis at 550°C. Their morphological complexity and structural polymorphism were investigated by using X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED) analysis. Pronounced evolution of nanocrystalline TiO2(B) phase assembled together with the anatase building units (sized ~15 nm) in uniform submicrometric particles implicate their feasibility to be used in dye-sensitised solar cells and lithium ion batteries.
PB  - Bucks, UK : INDERSCIENCE Publishers
T2  - International Journal of Materials and Product Technology
T1  - Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles
SP  - 221
EP  - 229
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7503
ER  - 

@article{
author = "Mančić, Lidija and Dugandžić, Ivan and Milošević, Olivera and Jovanović, Dragana J. and Šaponjić, Zoran and Rabanal, Maria Eugenia and Gómez-Villalba, Luz Stella",
year = "2015",
abstract = "Hierarchically assembled TiO2 nanoparticles into larger spherical ones were obtained using aerosol-assisted processing method. Unagglomerated particles with the mean size of 440 nm were obtained from colloidal solution of TiO2 nanoparticles (~4.5 nm) using ultrasonic spray pyrolysis at 550°C. Their morphological complexity and structural polymorphism were investigated by using X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED) analysis. Pronounced evolution of nanocrystalline TiO2(B) phase assembled together with the anatase building units (sized ~15 nm) in uniform submicrometric particles implicate their feasibility to be used in dye-sensitised solar cells and lithium ion batteries.",
publisher = "Bucks, UK : INDERSCIENCE Publishers",
journal = "International Journal of Materials and Product Technology",
title = "Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles",
pages = "221-229",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7503"
}

Mančić, L., Dugandžić, I., Milošević, O., Jovanović, D. J., Šaponjić, Z., Rabanal, M. E.,& Gómez-Villalba, L. S.. (2015). Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles. in International Journal of Materials and Product Technology
Bucks, UK : INDERSCIENCE Publishers., 221-229.
https://hdl.handle.net/21.15107/rcub_vinar_7503

Mančić L, Dugandžić I, Milošević O, Jovanović DJ, Šaponjić Z, Rabanal ME, Gómez-Villalba LS. Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles. in International Journal of Materials and Product Technology. 2015;:221-229.
https://hdl.handle.net/21.15107/rcub_vinar_7503 .

Mančić, Lidija, Dugandžić, Ivan, Milošević, Olivera, Jovanović, Dragana J., Šaponjić, Zoran, Rabanal, Maria Eugenia, Gómez-Villalba, Luz Stella, "Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles" in International Journal of Materials and Product Technology (2015):221-229,
https://hdl.handle.net/21.15107/rcub_vinar_7503 .

TY  - JOUR
AU  - Mančić, Lidija
AU  - Dugandžić, Ivan
AU  - Milošević, Olivera
AU  - Jovanović, Dragana J.
AU  - Šaponjić, Zoran
AU  - Rabanal, Maria Eugenia
AU  - Gomez Villalba, Luz S.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/500
AB  - Hierarchically assembled TiO2 nanoparticles into larger spherical ones were obtained using aerosol-assisted processing method. Unagglomerated particles with the mean size of 440 nm were obtained from colloidal solution of TiO2 nanoparticles (similar to 4.5 nm) using ultrasonic spray pyrolysis at 550 degrees C. Their morphological complexity and structural polymorphism were investigated by using X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED) analysis. Pronounced evolution of nanocrystalline TiO2(B) phase assembled together with the anatase building units (sized similar to 15 nm) in uniform submicrometric particles implicate their feasibility to be used in dye-sensitised solar cells and lithium ion batteries.
T2  - International Journal of Materials and Product Technology
T1  - Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles
VL  - 50
IS  - 3-4
SP  - 221
EP  - 229
DO  - 10.1504/IJMPT.2015.068530
ER  - 

@article{
author = "Mančić, Lidija and Dugandžić, Ivan and Milošević, Olivera and Jovanović, Dragana J. and Šaponjić, Zoran and Rabanal, Maria Eugenia and Gomez Villalba, Luz S.",
year = "2015",
abstract = "Hierarchically assembled TiO2 nanoparticles into larger spherical ones were obtained using aerosol-assisted processing method. Unagglomerated particles with the mean size of 440 nm were obtained from colloidal solution of TiO2 nanoparticles (similar to 4.5 nm) using ultrasonic spray pyrolysis at 550 degrees C. Their morphological complexity and structural polymorphism were investigated by using X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED) analysis. Pronounced evolution of nanocrystalline TiO2(B) phase assembled together with the anatase building units (sized similar to 15 nm) in uniform submicrometric particles implicate their feasibility to be used in dye-sensitised solar cells and lithium ion batteries.",
journal = "International Journal of Materials and Product Technology",
title = "Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles",
volume = "50",
number = "3-4",
pages = "221-229",
doi = "10.1504/IJMPT.2015.068530"
}

Mančić, L., Dugandžić, I., Milošević, O., Jovanović, D. J., Šaponjić, Z., Rabanal, M. E.,& Gomez Villalba, L. S.. (2015). Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles. in International Journal of Materials and Product Technology, 50(3-4), 221-229.
https://doi.org/10.1504/IJMPT.2015.068530

Mančić L, Dugandžić I, Milošević O, Jovanović DJ, Šaponjić Z, Rabanal ME, Gomez Villalba LS. Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles. in International Journal of Materials and Product Technology. 2015;50(3-4):221-229.
doi:10.1504/IJMPT.2015.068530 .

Mančić, Lidija, Dugandžić, Ivan, Milošević, Olivera, Jovanović, Dragana J., Šaponjić, Zoran, Rabanal, Maria Eugenia, Gomez Villalba, Luz S., "Aerosol-assisted processing of hierarchically organised TiO2 nanoparticles" in International Journal of Materials and Product Technology, 50, no. 3-4 (2015):221-229,
https://doi.org/10.1504/IJMPT.2015.068530 . .

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Vulic, P.
AU  - Dramićanin, Miroslav
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Olivera
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5839
AB  - Sub-micronic, spherical Y2O3:Yb/Er particles comprising clustered nano-units (70 nm) were prepared via ultrasonic spray pyrolysis from pure nitrate precursor solutions with different Yb/Er dopant ratios. The particles were additionally thermally treated at 1100 degrees C for 12, 24 and 48 h. The structural and morphological characteristics of particles were studied by X-ray powder diffraction, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, energy dispersive X-ray analysis and specific surface area (BET) and were further correlated with their advanced optical properties. For the recorded up-conversion emissions, originating from the following Er3+ transitions: [H-2(9/2) - GT I-4(15/2)] in blue (407-420 nm); [H-2(11/2), S-4(3/2) - GT I-4(15/2)] green: 510-590 nm; and [F-4(9/2) - GT I-4(15/2)] in red (640-720 nm) spectral region, the corresponding lifetimes were acquired in the wide temperature range (10-300 K). The most intense green up-conversion emission with the long decay of 550 ms is recorded for Y1.97Yb0.02Er0.01O3 particles thermally treated at 1100 degrees C for 24 h. (c) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Structural, morphological and up-converting luminescence characteristics of nanocrystalline Y2O3:Yb/Er powders obtained via spray pyrolysis
VL  - 40
IS  - 2
SP  - 3089
EP  - 3095
DO  - 10.1016/j.ceramint.2013.10.002
ER  - 

@article{
author = "Lojpur, Vesna and Mančić, Lidija and Vulic, P. and Dramićanin, Miroslav and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2014",
abstract = "Sub-micronic, spherical Y2O3:Yb/Er particles comprising clustered nano-units (70 nm) were prepared via ultrasonic spray pyrolysis from pure nitrate precursor solutions with different Yb/Er dopant ratios. The particles were additionally thermally treated at 1100 degrees C for 12, 24 and 48 h. The structural and morphological characteristics of particles were studied by X-ray powder diffraction, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, energy dispersive X-ray analysis and specific surface area (BET) and were further correlated with their advanced optical properties. For the recorded up-conversion emissions, originating from the following Er3+ transitions: [H-2(9/2) - GT I-4(15/2)] in blue (407-420 nm); [H-2(11/2), S-4(3/2) - GT I-4(15/2)] green: 510-590 nm; and [F-4(9/2) - GT I-4(15/2)] in red (640-720 nm) spectral region, the corresponding lifetimes were acquired in the wide temperature range (10-300 K). The most intense green up-conversion emission with the long decay of 550 ms is recorded for Y1.97Yb0.02Er0.01O3 particles thermally treated at 1100 degrees C for 24 h. (c) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Structural, morphological and up-converting luminescence characteristics of nanocrystalline Y2O3:Yb/Er powders obtained via spray pyrolysis",
volume = "40",
number = "2",
pages = "3089-3095",
doi = "10.1016/j.ceramint.2013.10.002"
}

Lojpur, V., Mančić, L., Vulic, P., Dramićanin, M., Rabanal, M. E.,& Milošević, O.. (2014). Structural, morphological and up-converting luminescence characteristics of nanocrystalline Y2O3:Yb/Er powders obtained via spray pyrolysis. in Ceramics International, 40(2), 3089-3095.
https://doi.org/10.1016/j.ceramint.2013.10.002

Lojpur V, Mančić L, Vulic P, Dramićanin M, Rabanal ME, Milošević O. Structural, morphological and up-converting luminescence characteristics of nanocrystalline Y2O3:Yb/Er powders obtained via spray pyrolysis. in Ceramics International. 2014;40(2):3089-3095.
doi:10.1016/j.ceramint.2013.10.002 .

Lojpur, Vesna, Mančić, Lidija, Vulic, P., Dramićanin, Miroslav, Rabanal, Maria Eugenia, Milošević, Olivera, "Structural, morphological and up-converting luminescence characteristics of nanocrystalline Y2O3:Yb/Er powders obtained via spray pyrolysis" in Ceramics International, 40, no. 2 (2014):3089-3095,
https://doi.org/10.1016/j.ceramint.2013.10.002 . .

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Rabanal Jiménez, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Tan, Z.
AU  - Hashishin, Takeshi
AU  - Ohara, Satoshi
AU  - Milošević, Olivera
AU  - Mančić, Lidija
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7992
AB  - Nanocrystalline up-converting Y₂ O₃Yb³⁺ Er³⁺ phosphor particles were processed in a dispersed system-aerosol, generated ultrasonically at 1.3 MHz from common nitrate precursor solution having fixed ytterbium-to-erbium concentration ratio. The appropriate process parameters: residence time 21 s, carrier gas (air) flow rate 1.6 dm3/min, synthesis temperature 900 °C, led to the formation of un-agglomerated spherical nanostructured secondary particles, having mean particle size of approx 450 nm, composed of primary nanoscaled (20 nm) subunits. In order to reach targeting phase crystallinity, the as-prepared particles were additionally annealed at 1100 °C in air for 12, 24 and 48 h, respectively. Particle structure, morphology and purity were analyzed by X-ray powder diffraction (XRPD), scanning electron microscopy (FESEM/SEM), analytical and high resolution transmission electron microscopy (TEM/HRTEM) in combination with energy dispersive X-ray analysis and Fourier Transform Infrared Spectroscopy (FTIR). All samples crystallized in a cubic bixbyte-structure, space group Ia-3. The crystallite size changed with annealing time from 30 nm in as-prepared sample to 135 nm in sample annealed for 48 h, respectively. Emission spectra were assigned to the following trivalent erbium f–f electronic transitions: ²H₉/₂ → ⁴I₁₅/₂ (blue: 407–420 nm), (²H₁₁/₂̦ ⁴S₃/₂) → ⁴I₁₅/₂ (green: 510–590 nm), and ⁴F₉/₂ → ⁴I₁₅/₂ (red: 640–720 nm). The significant improvement of the emission decay times were observed after thermal treatment and this effect is correlated further with the structural and morphological particles characteristics. For the anneal-ing time of 12 h a quite high emission decay times were achieved (blue: 0.14 ms, green: 0.32 ms and red: 0.39 ms).
T2  - Journal of Alloys and Compounds
T1  - Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route
VL  - 580
SP  - 584
EP  - 591
DO  - 10.1016/j.jallcom.2013.07.125
ER  - 

@article{
author = "Lojpur, Vesna and Rabanal Jiménez, Maria Eugenia and Dramićanin, Miroslav and Tan, Z. and Hashishin, Takeshi and Ohara, Satoshi and Milošević, Olivera and Mančić, Lidija",
year = "2013",
abstract = "Nanocrystalline up-converting Y₂ O₃Yb³⁺ Er³⁺ phosphor particles were processed in a dispersed system-aerosol, generated ultrasonically at 1.3 MHz from common nitrate precursor solution having fixed ytterbium-to-erbium concentration ratio. The appropriate process parameters: residence time 21 s, carrier gas (air) flow rate 1.6 dm3/min, synthesis temperature 900 °C, led to the formation of un-agglomerated spherical nanostructured secondary particles, having mean particle size of approx 450 nm, composed of primary nanoscaled (20 nm) subunits. In order to reach targeting phase crystallinity, the as-prepared particles were additionally annealed at 1100 °C in air for 12, 24 and 48 h, respectively. Particle structure, morphology and purity were analyzed by X-ray powder diffraction (XRPD), scanning electron microscopy (FESEM/SEM), analytical and high resolution transmission electron microscopy (TEM/HRTEM) in combination with energy dispersive X-ray analysis and Fourier Transform Infrared Spectroscopy (FTIR). All samples crystallized in a cubic bixbyte-structure, space group Ia-3. The crystallite size changed with annealing time from 30 nm in as-prepared sample to 135 nm in sample annealed for 48 h, respectively. Emission spectra were assigned to the following trivalent erbium f–f electronic transitions: ²H₉/₂ → ⁴I₁₅/₂ (blue: 407–420 nm), (²H₁₁/₂̦ ⁴S₃/₂) → ⁴I₁₅/₂ (green: 510–590 nm), and ⁴F₉/₂ → ⁴I₁₅/₂ (red: 640–720 nm). The significant improvement of the emission decay times were observed after thermal treatment and this effect is correlated further with the structural and morphological particles characteristics. For the anneal-ing time of 12 h a quite high emission decay times were achieved (blue: 0.14 ms, green: 0.32 ms and red: 0.39 ms).",
journal = "Journal of Alloys and Compounds",
title = "Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route",
volume = "580",
pages = "584-591",
doi = "10.1016/j.jallcom.2013.07.125"
}

Lojpur, V., Rabanal Jiménez, M. E., Dramićanin, M., Tan, Z., Hashishin, T., Ohara, S., Milošević, O.,& Mančić, L.. (2013). Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route. in Journal of Alloys and Compounds, 580, 584-591.
https://doi.org/10.1016/j.jallcom.2013.07.125

Lojpur V, Rabanal Jiménez ME, Dramićanin M, Tan Z, Hashishin T, Ohara S, Milošević O, Mančić L. Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route. in Journal of Alloys and Compounds. 2013;580:584-591.
doi:10.1016/j.jallcom.2013.07.125 .

Lojpur, Vesna, Rabanal Jiménez, Maria Eugenia, Dramićanin, Miroslav, Tan, Z., Hashishin, Takeshi, Ohara, Satoshi, Milošević, Olivera, Mančić, Lidija, "Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route" in Journal of Alloys and Compounds, 580 (2013):584-591,
https://doi.org/10.1016/j.jallcom.2013.07.125 . .

TY  - JOUR
AU  - Dugandžić, Ivan
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Dramićanin, Miroslav
AU  - Rabanal, Maria Eugenia
AU  - Hashishin, T.
AU  - Tan, Z.
AU  - Ohara, S.
AU  - Milošević, Olivera
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5679
AB  - The opportunities of the hot wall aerosol synthesis, i.e. conventional spray pyrolysis (CSP) method are demonstrated for the generation of highly spherical three-dimensional (3D) nanostructured phosphor particles with uniformly distributed components, phases and nano-clustered inner structure. With the presumption that certain particle morphology is formed during the evaporation/drying stage, the aerosol transport properties and powder generation are correlated with the particles structural and morphological features. With the help of various analyzing techniques like Field Emission Scanning Electron Microscopy (FE-SEM), Transmission Electron Microscopy (TEM) coupled with energy dispersive X-ray Analysis and STEM mode (TEM/EDS), X-ray Powder Diffraction (XRPD) and fluorescence measurements the feasible processing of up-conversion rare-earth Y2O3:Er, Yb phosphors powders are discussed. (C) 2013 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
T2  - Advanced Powder Technology
T1  - Aerosol route as a feasible bottom-up chemical approach for up-converting phosphor particles processing
VL  - 24
IS  - 5
SP  - 852
EP  - 857
DO  - 10.1016/j.apt.2013.02.011
ER  - 

@article{
author = "Dugandžić, Ivan and Lojpur, Vesna and Mančić, Lidija and Dramićanin, Miroslav and Rabanal, Maria Eugenia and Hashishin, T. and Tan, Z. and Ohara, S. and Milošević, Olivera",
year = "2013",
abstract = "The opportunities of the hot wall aerosol synthesis, i.e. conventional spray pyrolysis (CSP) method are demonstrated for the generation of highly spherical three-dimensional (3D) nanostructured phosphor particles with uniformly distributed components, phases and nano-clustered inner structure. With the presumption that certain particle morphology is formed during the evaporation/drying stage, the aerosol transport properties and powder generation are correlated with the particles structural and morphological features. With the help of various analyzing techniques like Field Emission Scanning Electron Microscopy (FE-SEM), Transmission Electron Microscopy (TEM) coupled with energy dispersive X-ray Analysis and STEM mode (TEM/EDS), X-ray Powder Diffraction (XRPD) and fluorescence measurements the feasible processing of up-conversion rare-earth Y2O3:Er, Yb phosphors powders are discussed. (C) 2013 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.",
journal = "Advanced Powder Technology",
title = "Aerosol route as a feasible bottom-up chemical approach for up-converting phosphor particles processing",
volume = "24",
number = "5",
pages = "852-857",
doi = "10.1016/j.apt.2013.02.011"
}

Dugandžić, I., Lojpur, V., Mančić, L., Dramićanin, M., Rabanal, M. E., Hashishin, T., Tan, Z., Ohara, S.,& Milošević, O.. (2013). Aerosol route as a feasible bottom-up chemical approach for up-converting phosphor particles processing. in Advanced Powder Technology, 24(5), 852-857.
https://doi.org/10.1016/j.apt.2013.02.011

Dugandžić I, Lojpur V, Mančić L, Dramićanin M, Rabanal ME, Hashishin T, Tan Z, Ohara S, Milošević O. Aerosol route as a feasible bottom-up chemical approach for up-converting phosphor particles processing. in Advanced Powder Technology. 2013;24(5):852-857.
doi:10.1016/j.apt.2013.02.011 .

Dugandžić, Ivan, Lojpur, Vesna, Mančić, Lidija, Dramićanin, Miroslav, Rabanal, Maria Eugenia, Hashishin, T., Tan, Z., Ohara, S., Milošević, Olivera, "Aerosol route as a feasible bottom-up chemical approach for up-converting phosphor particles processing" in Advanced Powder Technology, 24, no. 5 (2013):852-857,
https://doi.org/10.1016/j.apt.2013.02.011 . .

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Tan, Z.
AU  - Hashishin, T.
AU  - Ohara, S.
AU  - Milošević, Olivera
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5685
AB  - Nanocrystalline up-converting Y2O3:Yb3+, Er3+ phosphor particles were processed in a dispersed system-aerosol, generated ultrasonically at 1.3 MHz from common nitrate precursor solution having fixed ytterbium-to-erbium concentration ratio. The appropriate process parameters: residence time 21 s, carrier gas (air) flow rate 1.6 dm(3)/min, synthesis temperature 900 degrees C, led to the formation of un-agglomerated spherical nanostructured secondary particles, having mean particle size of approx 450 nm, composed of primary nanoscaled (20 nm) subunits. In order to reach targeting phase crystallinity, the as-prepared particles were additionally annealed at 1100 degrees C in air for 12, 24 and 48 h, respectively. Particle structure, morphology and purity were analyzed by X-ray powder diffraction (XRPD), scanning electron microscopy (FESEM/SEM), analytical and high resolution transmission electron microscopy (TEM/HRTEM) in combination with energy dispersive X-ray analysis and Fourier Transform Infrared Spectroscopy (FTIR). All samples crystallized in a cubic bixbyte-structure, space group Ia-3. The crystallite size changed with annealing time from 30 nm in as-prepared sample to 135 nm in sample annealed for 48 h, respectively. Emission spectra were assigned to the following trivalent erbium f-f electronic transitions: H-2(9/2) - GT I-4(15/2) (blue: 407-420 nm), (H-2(11/2), S-4(3/2)) - GT I-4(15/2) (green: 510-590 nm), and F-4(9/2) - GT I-4(15/2) (red: 640-720 nm). The significant improvement of the emission decay times were observed after thermal treatment and this effect is correlated further with the structural and morphological particles characteristics. For the annealing time of 12 h a quite high emission decay times were achieved (blue: 0.14 ms, green: 0.32 ms and red: 0.39 ms).
T2  - Journal of Alloys and Compounds
T1  - Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route
VL  - 580
SP  - 584
EP  - 591
DO  - 10.1016/j.jallcom.2013.07.125
ER  - 

@article{
author = "Lojpur, Vesna and Mančić, Lidija and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Tan, Z. and Hashishin, T. and Ohara, S. and Milošević, Olivera",
year = "2013",
abstract = "Nanocrystalline up-converting Y2O3:Yb3+, Er3+ phosphor particles were processed in a dispersed system-aerosol, generated ultrasonically at 1.3 MHz from common nitrate precursor solution having fixed ytterbium-to-erbium concentration ratio. The appropriate process parameters: residence time 21 s, carrier gas (air) flow rate 1.6 dm(3)/min, synthesis temperature 900 degrees C, led to the formation of un-agglomerated spherical nanostructured secondary particles, having mean particle size of approx 450 nm, composed of primary nanoscaled (20 nm) subunits. In order to reach targeting phase crystallinity, the as-prepared particles were additionally annealed at 1100 degrees C in air for 12, 24 and 48 h, respectively. Particle structure, morphology and purity were analyzed by X-ray powder diffraction (XRPD), scanning electron microscopy (FESEM/SEM), analytical and high resolution transmission electron microscopy (TEM/HRTEM) in combination with energy dispersive X-ray analysis and Fourier Transform Infrared Spectroscopy (FTIR). All samples crystallized in a cubic bixbyte-structure, space group Ia-3. The crystallite size changed with annealing time from 30 nm in as-prepared sample to 135 nm in sample annealed for 48 h, respectively. Emission spectra were assigned to the following trivalent erbium f-f electronic transitions: H-2(9/2) - GT I-4(15/2) (blue: 407-420 nm), (H-2(11/2), S-4(3/2)) - GT I-4(15/2) (green: 510-590 nm), and F-4(9/2) - GT I-4(15/2) (red: 640-720 nm). The significant improvement of the emission decay times were observed after thermal treatment and this effect is correlated further with the structural and morphological particles characteristics. For the annealing time of 12 h a quite high emission decay times were achieved (blue: 0.14 ms, green: 0.32 ms and red: 0.39 ms).",
journal = "Journal of Alloys and Compounds",
title = "Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route",
volume = "580",
pages = "584-591",
doi = "10.1016/j.jallcom.2013.07.125"
}

Lojpur, V., Mančić, L., Rabanal, M. E., Dramićanin, M., Tan, Z., Hashishin, T., Ohara, S.,& Milošević, O.. (2013). Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route. in Journal of Alloys and Compounds, 580, 584-591.
https://doi.org/10.1016/j.jallcom.2013.07.125

Lojpur V, Mančić L, Rabanal ME, Dramićanin M, Tan Z, Hashishin T, Ohara S, Milošević O. Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route. in Journal of Alloys and Compounds. 2013;580:584-591.
doi:10.1016/j.jallcom.2013.07.125 .

Lojpur, Vesna, Mančić, Lidija, Rabanal, Maria Eugenia, Dramićanin, Miroslav, Tan, Z., Hashishin, T., Ohara, S., Milošević, Olivera, "Structural, morphological and luminescence properties of nanocrystalline up-converting Y1.89Yb0.1Er0.01O3 phosphor particles synthesized through aerosol route" in Journal of Alloys and Compounds, 580 (2013):584-591,
https://doi.org/10.1016/j.jallcom.2013.07.125 . .

TY  - CONF
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/535
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7474
AB  - Sub-micronic, spherical Y203:Yb/Er particles comprising clustered nano-units were prepared through ultrasonic spray pyrolysis of pure nitrate precursor solutions that contain different Yb/Er dopants ratio (10, 5 and 2). The particles obtained were additionally heat-treated at 1100°C for 12, 24 and 48 hours. Detailed structural and morphological analyses were done through X-ray powder diffraction (XRPD), scanning and transmission electron microscopy (SEM/TEM), specific surface area (BET), particle size distribution (LPS) and Fourier Transform Infrared Spectroscopy (FTIR). Obtained results are further correlated with advanced powder optical properties confirmed by efficient up-conversion emissions of Er3+in: blue (407-420 nm, 2H9/2→4I15/2), green (510-590 nm, 2H11/2, 4S3/2→4I15/2) and red (640-720 nm, 4F9/2→4I15/2) spectra. The corresponding lifetimes in the function of temperature will be also presented and discussed.
PB  - Univerzitet u Beogradu, Tehnološko-metalurški fakultet
C3  - Characterization and Applications of Nanostructured Materials and Nanotechnology : 1st International Conference Processing, NanoBelgrade 2012 : program and the book of abstracts : Belgrade
T1  - Up-converting characteristics of Y203:Yb/Er nanocrystalline powders obtained through spray pyrolysis
SP  - 63
EP  - 63
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7474
ER  - 

@conference{
author = "Mančić, Lidija and Lojpur, Vesna and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2012",
abstract = "Sub-micronic, spherical Y203:Yb/Er particles comprising clustered nano-units were prepared through ultrasonic spray pyrolysis of pure nitrate precursor solutions that contain different Yb/Er dopants ratio (10, 5 and 2). The particles obtained were additionally heat-treated at 1100°C for 12, 24 and 48 hours. Detailed structural and morphological analyses were done through X-ray powder diffraction (XRPD), scanning and transmission electron microscopy (SEM/TEM), specific surface area (BET), particle size distribution (LPS) and Fourier Transform Infrared Spectroscopy (FTIR). Obtained results are further correlated with advanced powder optical properties confirmed by efficient up-conversion emissions of Er3+in: blue (407-420 nm, 2H9/2→4I15/2), green (510-590 nm, 2H11/2, 4S3/2→4I15/2) and red (640-720 nm, 4F9/2→4I15/2) spectra. The corresponding lifetimes in the function of temperature will be also presented and discussed.",
publisher = "Univerzitet u Beogradu, Tehnološko-metalurški fakultet",
journal = "Characterization and Applications of Nanostructured Materials and Nanotechnology : 1st International Conference Processing, NanoBelgrade 2012 : program and the book of abstracts : Belgrade",
title = "Up-converting characteristics of Y203:Yb/Er nanocrystalline powders obtained through spray pyrolysis",
pages = "63-63",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7474"
}

Mančić, L., Lojpur, V., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2012). Up-converting characteristics of Y203:Yb/Er nanocrystalline powders obtained through spray pyrolysis. in Characterization and Applications of Nanostructured Materials and Nanotechnology : 1st International Conference Processing, NanoBelgrade 2012 : program and the book of abstracts : Belgrade
Univerzitet u Beogradu, Tehnološko-metalurški fakultet., 63-63.
https://hdl.handle.net/21.15107/rcub_vinar_7474

Mančić L, Lojpur V, Rabanal ME, Dramićanin M, Milošević O. Up-converting characteristics of Y203:Yb/Er nanocrystalline powders obtained through spray pyrolysis. in Characterization and Applications of Nanostructured Materials and Nanotechnology : 1st International Conference Processing, NanoBelgrade 2012 : program and the book of abstracts : Belgrade. 2012;:63-63.
https://hdl.handle.net/21.15107/rcub_vinar_7474 .

Mančić, Lidija, Lojpur, Vesna, Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Up-converting characteristics of Y203:Yb/Er nanocrystalline powders obtained through spray pyrolysis" in Characterization and Applications of Nanostructured Materials and Nanotechnology : 1st International Conference Processing, NanoBelgrade 2012 : program and the book of abstracts : Belgrade (2012):63-63,
https://hdl.handle.net/21.15107/rcub_vinar_7474 .

TY  - JOUR
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Barroso, Ignacio
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Olivera
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7448
AB  - Polycrystalline fine powders of yttrium aluminate doped with Ce3+ were synthesised by spray pyrolysis of a polymeric precursor, which was obtained by dissolving the corresponding nitrates in a solution of ethylenediaminetetraacetic acid (EDTA) in ethylene glycol (EG). Aerosol decomposition was performed at 550 °C followed by an additional thermal treatment (900–1100 °C). The yield of either a single yttrium aluminium perovskite (YAP) phase or a single yttrium aluminium garnet (YAG) phase was investigated as a function of the predefined yttrium/aluminium ratio, the cerium doping concentration, the processing temperature, and the thermal-treatment regime, which included the variation of the heating and cooling rates (dT/dt), the residence time (τ), and the atmosphere. Changes in the composition and structure of the precursor during thermal decomposition were investigated by thermogravimetric and differential thermal analysis (TGA/DTA) and FTIR spectroscopy. The particle morphology and structure were analysed by a combination of scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDS) and by high-resolution transmission electron microscopy (HR-TEM). The structural refinement was based on the phase identification performed by X-ray powder diffraction (XRPD). The emission spectra were recorded within the range 325–800 nm by applying excitation wavelengths of 297 (YAP) and 450 nm (YAG). The employed synthesis conditions assured the formation of spherical, non-agglomerated particles with well-developed surfaces and diameters between 200 and 800 nm. For a predefined Y/Al ratio of 1:1, lower processing temperatures combined with longer heat treatments under stationary conditions resulted in a multiphase system, composed of YAP, YAG, and monoclinic yttrium aluminate (YAM) phases. However, a short heat treatment with a high heating rate (200 °C/min) at higher temperatures results in the formation of a kinetically favoured pure YAP hexagonal phase. On the other hand, for a predefined Y/Al ratio of 3:5, the generation of a thermodynamically favoured pure YAG phase has been confirmed, regardless of the applied heat-treatment conditions. Although incomplete, Ce3+ introduction into the host matrix has been detected by XRPD and luminescence measurements.
T2  - European Journal of Inorganic Chemistry
T1  - Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route
SP  - 2716
EP  - 2724
DO  - 10.1002/ejic.201101053
ER  - 

@article{
author = "Mančić, Lidija and Lojpur, Vesna and Barroso, Ignacio and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2012",
abstract = "Polycrystalline fine powders of yttrium aluminate doped with Ce3+ were synthesised by spray pyrolysis of a polymeric precursor, which was obtained by dissolving the corresponding nitrates in a solution of ethylenediaminetetraacetic acid (EDTA) in ethylene glycol (EG). Aerosol decomposition was performed at 550 °C followed by an additional thermal treatment (900–1100 °C). The yield of either a single yttrium aluminium perovskite (YAP) phase or a single yttrium aluminium garnet (YAG) phase was investigated as a function of the predefined yttrium/aluminium ratio, the cerium doping concentration, the processing temperature, and the thermal-treatment regime, which included the variation of the heating and cooling rates (dT/dt), the residence time (τ), and the atmosphere. Changes in the composition and structure of the precursor during thermal decomposition were investigated by thermogravimetric and differential thermal analysis (TGA/DTA) and FTIR spectroscopy. The particle morphology and structure were analysed by a combination of scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDS) and by high-resolution transmission electron microscopy (HR-TEM). The structural refinement was based on the phase identification performed by X-ray powder diffraction (XRPD). The emission spectra were recorded within the range 325–800 nm by applying excitation wavelengths of 297 (YAP) and 450 nm (YAG). The employed synthesis conditions assured the formation of spherical, non-agglomerated particles with well-developed surfaces and diameters between 200 and 800 nm. For a predefined Y/Al ratio of 1:1, lower processing temperatures combined with longer heat treatments under stationary conditions resulted in a multiphase system, composed of YAP, YAG, and monoclinic yttrium aluminate (YAM) phases. However, a short heat treatment with a high heating rate (200 °C/min) at higher temperatures results in the formation of a kinetically favoured pure YAP hexagonal phase. On the other hand, for a predefined Y/Al ratio of 3:5, the generation of a thermodynamically favoured pure YAG phase has been confirmed, regardless of the applied heat-treatment conditions. Although incomplete, Ce3+ introduction into the host matrix has been detected by XRPD and luminescence measurements.",
journal = "European Journal of Inorganic Chemistry",
title = "Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route",
pages = "2716-2724",
doi = "10.1002/ejic.201101053"
}

Mančić, L., Lojpur, V., Barroso, I., Rabanal, M. E.,& Milošević, O.. (2012). Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route. in European Journal of Inorganic Chemistry, 2716-2724.
https://doi.org/10.1002/ejic.201101053

Mančić L, Lojpur V, Barroso I, Rabanal ME, Milošević O. Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route. in European Journal of Inorganic Chemistry. 2012;:2716-2724.
doi:10.1002/ejic.201101053 .

Mančić, Lidija, Lojpur, Vesna, Barroso, Ignacio, Rabanal, Maria Eugenia, Milošević, Olivera, "Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route" in European Journal of Inorganic Chemistry (2012):2716-2724,
https://doi.org/10.1002/ejic.201101053 . .

TY  - CONF
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Marinković, Bojan A.
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/514
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7464
AB  - Synthesis of nanostructured rare earth oxide-based phosphor particles with enhanced optical characteristics leads to the creation of the new photonic devices with diverse applications. Tailoring of the phosphors quality depends on our ability to utilize the best of their intrinsic structure through the control of nucleation and growth process of the desired phase. A large number of works have contributed to the better control of particle shape and crystal growth in soft-chemistry routes. Here, examples from (Y2O3-Gd2O3): Eu3+ and Y2O3:(Yb3+/Er3+) will be presented to highlight the controlled synthesis of 1D and 2D nanostructures through simple hydrothermal method. Conversion of the starting nitrates mixture into carbonate hydrate phase is performed with the help of ammonium hydrogen carbonate solution during hydrothermal treatment at 200oC/3h. Morphological architectures of rare earth oxides obtained after subsequent thermal treatment and their correlation with the optical characteristics will be discussed based on X-ray powder diffractometry, particle size analysis, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy and photoluminescence measurements.
PB  - Belgrade : Agencija FORMAT
C3  - ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract
T1  - Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors
SP  - 8
EP  - 8
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7464
ER  - 

@conference{
author = "Mančić, Lidija and Lojpur, Vesna and Marinković, Bojan A. and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2012",
abstract = "Synthesis of nanostructured rare earth oxide-based phosphor particles with enhanced optical characteristics leads to the creation of the new photonic devices with diverse applications. Tailoring of the phosphors quality depends on our ability to utilize the best of their intrinsic structure through the control of nucleation and growth process of the desired phase. A large number of works have contributed to the better control of particle shape and crystal growth in soft-chemistry routes. Here, examples from (Y2O3-Gd2O3): Eu3+ and Y2O3:(Yb3+/Er3+) will be presented to highlight the controlled synthesis of 1D and 2D nanostructures through simple hydrothermal method. Conversion of the starting nitrates mixture into carbonate hydrate phase is performed with the help of ammonium hydrogen carbonate solution during hydrothermal treatment at 200oC/3h. Morphological architectures of rare earth oxides obtained after subsequent thermal treatment and their correlation with the optical characteristics will be discussed based on X-ray powder diffractometry, particle size analysis, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy and photoluminescence measurements.",
publisher = "Belgrade : Agencija FORMAT",
journal = "ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract",
title = "Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors",
pages = "8-8",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7464"
}

Mančić, L., Lojpur, V., Marinković, B. A., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2012). Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors. in ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract
Belgrade : Agencija FORMAT., 8-8.
https://hdl.handle.net/21.15107/rcub_vinar_7464

Mančić L, Lojpur V, Marinković BA, Rabanal ME, Dramićanin M, Milošević O. Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors. in ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract. 2012;:8-8.
https://hdl.handle.net/21.15107/rcub_vinar_7464 .

Mančić, Lidija, Lojpur, Vesna, Marinković, Bojan A., Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Hydrothermal synthesis of nanostructured rare earth oxide – based phosphors" in ICOM 2012: The 3rd International Conference on the Physics of Optical Materials and Devices: Book of Abstract (2012):8-8,
https://hdl.handle.net/21.15107/rcub_vinar_7464 .

TY  - JOUR
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
AU  - Barroso, Ignacio
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Olivera
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7568
AB  - Polycrystalline fine powders of yttrium aluminate doped with Ce3+ were synthesised by spray pyrolysis of a polymeric precursor, which was obtained by dissolving the corresponding nitrates in a solution of ethylenediaminetetraacetic acid (EDTA) in ethylene glycol (EG). Aerosol decomposition was performed at 550 °C followed by an additional thermal treatment (900–1100 °C). The yield of either a single yttrium aluminium perovskite (YAP) phase or a single yttrium aluminium garnet (YAG) phase was investigated as a function of the predefined yttrium/aluminium ratio, the cerium doping concentration, the processing temperature, and the thermal-treatment regime, which included the variation of the heating and cooling rates (dT/dt), the residence time (τ), and the atmosphere. Changes in the composition and structure of the precursor during thermal decomposition were investigated by thermogravimetric and differential thermal analysis (TGA/DTA) and FTIR spectroscopy. The particle morphology and structure were analysed by a combination of scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDS) and by high-resolution transmission electron microscopy (HR-TEM). The structural refinement was based on the phase identification performed by X-ray powder diffraction (XRPD). The emission spectra were recorded within the range 325–800 nm by applying excitation wavelengths of 297 (YAP) and 450 nm (YAG). The employed synthesis conditions assured the formation of spherical, non-agglomerated particles with well-developed surfaces and diameters between 200 and 800 nm. For a predefined Y/Al ratio of 1:1, lower processing temperatures combined with longer heat treatments under stationary conditions resulted in a multiphase system, composed of YAP, YAG, and monoclinic yttrium aluminate (YAM) phases. However, a short heat treatment with a high heating rate (200 °C/min) at higher temperatures results in the formation of a kinetically favoured pure YAP hexagonal phase. On the other hand, for a predefined Y/Al ratio of 3:5, the generation of a thermodynamically favoured pure YAG phase has been confirmed, regardless of the applied heat-treatment conditions. Although incomplete, Ce3+ introduction into the host matrix has been detected by XRPD and luminescence measurements.
T2  - European Journal of Inorganic Chemistry
T1  - Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route
VL  - 16
SP  - 2716
EP  - 2724
DO  - 10.1002/ejic.201101053
ER  - 

@article{
author = "Mančić, Lidija and Lojpur, Vesna and Barroso, Ignacio and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2012",
abstract = "Polycrystalline fine powders of yttrium aluminate doped with Ce3+ were synthesised by spray pyrolysis of a polymeric precursor, which was obtained by dissolving the corresponding nitrates in a solution of ethylenediaminetetraacetic acid (EDTA) in ethylene glycol (EG). Aerosol decomposition was performed at 550 °C followed by an additional thermal treatment (900–1100 °C). The yield of either a single yttrium aluminium perovskite (YAP) phase or a single yttrium aluminium garnet (YAG) phase was investigated as a function of the predefined yttrium/aluminium ratio, the cerium doping concentration, the processing temperature, and the thermal-treatment regime, which included the variation of the heating and cooling rates (dT/dt), the residence time (τ), and the atmosphere. Changes in the composition and structure of the precursor during thermal decomposition were investigated by thermogravimetric and differential thermal analysis (TGA/DTA) and FTIR spectroscopy. The particle morphology and structure were analysed by a combination of scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDS) and by high-resolution transmission electron microscopy (HR-TEM). The structural refinement was based on the phase identification performed by X-ray powder diffraction (XRPD). The emission spectra were recorded within the range 325–800 nm by applying excitation wavelengths of 297 (YAP) and 450 nm (YAG). The employed synthesis conditions assured the formation of spherical, non-agglomerated particles with well-developed surfaces and diameters between 200 and 800 nm. For a predefined Y/Al ratio of 1:1, lower processing temperatures combined with longer heat treatments under stationary conditions resulted in a multiphase system, composed of YAP, YAG, and monoclinic yttrium aluminate (YAM) phases. However, a short heat treatment with a high heating rate (200 °C/min) at higher temperatures results in the formation of a kinetically favoured pure YAP hexagonal phase. On the other hand, for a predefined Y/Al ratio of 3:5, the generation of a thermodynamically favoured pure YAG phase has been confirmed, regardless of the applied heat-treatment conditions. Although incomplete, Ce3+ introduction into the host matrix has been detected by XRPD and luminescence measurements.",
journal = "European Journal of Inorganic Chemistry",
title = "Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route",
volume = "16",
pages = "2716-2724",
doi = "10.1002/ejic.201101053"
}

Mančić, L., Lojpur, V., Barroso, I., Rabanal, M. E.,& Milošević, O.. (2012). Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route. in European Journal of Inorganic Chemistry, 16, 2716-2724.
https://doi.org/10.1002/ejic.201101053

Mančić L, Lojpur V, Barroso I, Rabanal ME, Milošević O. Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route. in European Journal of Inorganic Chemistry. 2012;16:2716-2724.
doi:10.1002/ejic.201101053 .

Mančić, Lidija, Lojpur, Vesna, Barroso, Ignacio, Rabanal, Maria Eugenia, Milošević, Olivera, "Synthesis of Cerium-Activated Yttrium Aluminate Based Fine Phosphors by an Aerosol Route" in European Journal of Inorganic Chemistry, 16 (2012):2716-2724,
https://doi.org/10.1002/ejic.201101053 . .

TY  - CONF
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Olivera
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/682
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7509
AB  - The yttrium aluminum system (Y2O3-Al2O3) includes three compounds: yttrium aluminum garnet (Y3Al5O12, YAG), yttrium aluminum perovskite (YAlO3, YAP) and yttrium aluminum monoclinic (Y4Al2O9, YAM). YAP doped with Ce is well known optical material used as a fast scintillator for synchrotron X-ray experiments. Synthesizing single YAP phase is difficult even through wet chemical processing because of the possible allocations of other phases. Here, we synthesized fine powders of YAlO3:Ce3+ via spray pyrolysis of polymeric precursor obtained by dissolving the corresponding nitrates in ethylenediaminetetraacetic acid (EDTA) and ethylene glycol (EG) solution. Aerosol droplets are decomposed at 550 °C in argon atmosphere. In order to get a pure YAP:Ce phase as-prepared particles were additionally thermally treated in the range from 900 °C to 1100 °C for 12 hours in the air atmosphere. Energy dispersive analysis (EDS) confirmed high particle purity and desirable Y:Al ratio. Also, scanning electron microscopy (SEM) showed changing morphology with increasing the heating temperature. Inner particle structure is analysed by transmission electron microscopy (TEM) while phase identification is performed by X-ray powder diffraction (XRD). Detailed structural analysis is performed through Rietveld refinement in Topas Academic software.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts
T1  - Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution
SP  - 97
EP  - 97
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7509
ER  - 

@conference{
author = "Lojpur, Vesna and Mančić, Lidija and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2011",
abstract = "The yttrium aluminum system (Y2O3-Al2O3) includes three compounds: yttrium aluminum garnet (Y3Al5O12, YAG), yttrium aluminum perovskite (YAlO3, YAP) and yttrium aluminum monoclinic (Y4Al2O9, YAM). YAP doped with Ce is well known optical material used as a fast scintillator for synchrotron X-ray experiments. Synthesizing single YAP phase is difficult even through wet chemical processing because of the possible allocations of other phases. Here, we synthesized fine powders of YAlO3:Ce3+ via spray pyrolysis of polymeric precursor obtained by dissolving the corresponding nitrates in ethylenediaminetetraacetic acid (EDTA) and ethylene glycol (EG) solution. Aerosol droplets are decomposed at 550 °C in argon atmosphere. In order to get a pure YAP:Ce phase as-prepared particles were additionally thermally treated in the range from 900 °C to 1100 °C for 12 hours in the air atmosphere. Energy dispersive analysis (EDS) confirmed high particle purity and desirable Y:Al ratio. Also, scanning electron microscopy (SEM) showed changing morphology with increasing the heating temperature. Inner particle structure is analysed by transmission electron microscopy (TEM) while phase identification is performed by X-ray powder diffraction (XRD). Detailed structural analysis is performed through Rietveld refinement in Topas Academic software.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts",
title = "Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution",
pages = "97-97",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7509"
}

Lojpur, V., Mančić, L., Rabanal, M. E.,& Milošević, O.. (2011). Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution. in The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 97-97.
https://hdl.handle.net/21.15107/rcub_vinar_7509

Lojpur V, Mančić L, Rabanal ME, Milošević O. Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution. in The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts. 2011;:97-97.
https://hdl.handle.net/21.15107/rcub_vinar_7509 .

Lojpur, Vesna, Mančić, Lidija, Rabanal, Maria Eugenia, Milošević, Olivera, "Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution" in The Thirteenth Annual Conference YUCOMAT 2011: Programme and the Book of Abstracts (2011):97-97,
https://hdl.handle.net/21.15107/rcub_vinar_7509 .

TY  - CONF
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/695
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7516
AB  - The upconverting phosphors are materials of great interest for optoelectronics operating in the near infrared region. The preparation of highly spherical Y2O3:Yb,Er particles are synthesized via spray pyrolysis from common nitrate solution with fixed dopants ratio of Yb/Er=10. The processing conditions are as follows: precursor concentration 0.1M, atomization frequency 1.3 MHz, temperature regime 200-900-900°C and air flow rate 1,6 dm3/min. The as-prepared particles collected in the electrostatic precipitator are additionally thermally treated at 1100 °C for 12, 24 and 48 hours. Detailed structural analyses are performed by X-ray powder diffraction (XRPD) based on which the structural refinement is done using Topas Academic Software. The results imply that with the increase of calcination time crystallite size increasing along with microstrain diminishing. The particle morphological characteristics are studied by scanning electron microscopy (SEM) and are further correlated with specific surface area (BET), size distribution (LPS) and optical properties followed through photoluminescence measurements (PL).
PB  - Belgrade : Institute of Technical Sciences of the Serbian Academy of Sciences and Arts
C3  - Program and the Book of Abstracts / Tenth Young Researchers' Conference Materials Science and Engineering, December 21-23, 2011, Belgrade, Serbia
T1  - Influence of thermal treatment on structural, morphological and optical characteristics of upconvertors
SP  - 38
EP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7516
ER  - 

@conference{
author = "Lojpur, Vesna and Mančić, Lidija and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2011",
abstract = "The upconverting phosphors are materials of great interest for optoelectronics operating in the near infrared region. The preparation of highly spherical Y2O3:Yb,Er particles are synthesized via spray pyrolysis from common nitrate solution with fixed dopants ratio of Yb/Er=10. The processing conditions are as follows: precursor concentration 0.1M, atomization frequency 1.3 MHz, temperature regime 200-900-900°C and air flow rate 1,6 dm3/min. The as-prepared particles collected in the electrostatic precipitator are additionally thermally treated at 1100 °C for 12, 24 and 48 hours. Detailed structural analyses are performed by X-ray powder diffraction (XRPD) based on which the structural refinement is done using Topas Academic Software. The results imply that with the increase of calcination time crystallite size increasing along with microstrain diminishing. The particle morphological characteristics are studied by scanning electron microscopy (SEM) and are further correlated with specific surface area (BET), size distribution (LPS) and optical properties followed through photoluminescence measurements (PL).",
publisher = "Belgrade : Institute of Technical Sciences of the Serbian Academy of Sciences and Arts",
journal = "Program and the Book of Abstracts / Tenth Young Researchers' Conference Materials Science and Engineering, December 21-23, 2011, Belgrade, Serbia",
title = "Influence of thermal treatment on structural, morphological and optical characteristics of upconvertors",
pages = "38-38",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7516"
}

Lojpur, V., Mančić, L., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2011). Influence of thermal treatment on structural, morphological and optical characteristics of upconvertors. in Program and the Book of Abstracts / Tenth Young Researchers' Conference Materials Science and Engineering, December 21-23, 2011, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of the Serbian Academy of Sciences and Arts., 38-38.
https://hdl.handle.net/21.15107/rcub_vinar_7516

Lojpur V, Mančić L, Rabanal ME, Dramićanin M, Milošević O. Influence of thermal treatment on structural, morphological and optical characteristics of upconvertors. in Program and the Book of Abstracts / Tenth Young Researchers' Conference Materials Science and Engineering, December 21-23, 2011, Belgrade, Serbia. 2011;:38-38.
https://hdl.handle.net/21.15107/rcub_vinar_7516 .

Lojpur, Vesna, Mančić, Lidija, Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Influence of thermal treatment on structural, morphological and optical characteristics of upconvertors" in Program and the Book of Abstracts / Tenth Young Researchers' Conference Materials Science and Engineering, December 21-23, 2011, Belgrade, Serbia (2011):38-38,
https://hdl.handle.net/21.15107/rcub_vinar_7516 .

TY  - CONF
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Olivera
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/156
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7354
AB  - Poster presented at the 13th Annual Conference of the Materials Research Society of Serbia - YUCOMAT 2011, Herceg Novi, Montenegro, September 5–9, 2011
T1  - Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7354
ER  - 

@conference{
author = "Lojpur, Vesna and Mančić, Lidija and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2011",
abstract = "Poster presented at the 13th Annual Conference of the Materials Research Society of Serbia - YUCOMAT 2011, Herceg Novi, Montenegro, September 5–9, 2011",
title = "Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7354"
}

Lojpur, V., Mančić, L., Rabanal, M. E.,& Milošević, O.. (2011). Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution. .
https://hdl.handle.net/21.15107/rcub_vinar_7354

Lojpur V, Mančić L, Rabanal ME, Milošević O. Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution. 2011;.
https://hdl.handle.net/21.15107/rcub_vinar_7354 .

Lojpur, Vesna, Mančić, Lidija, Rabanal, Maria Eugenia, Milošević, Olivera, "Synthesis of the Nanostructured YAP:Ce via Spray Pyrolysis by Polymeric Precursor Solution" (2011),
https://hdl.handle.net/21.15107/rcub_vinar_7354 .

TY  - CONF
AU  - Dugandžić, Ivan
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Olivera
PY  - 2010
UR  - http://dais.sanu.ac.rs/123456789/220
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7366
AB  - Poster presented at 12th Annual Conference of the Materials Research Society of Serbia - YUCOMAT 2010, Herceg Novi, Montenegro, September 6–10, 2010.
T1  - Dense spherical rare earth oxide particles synthesis via spray pyrolysis of polimeric precursor solution
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7366
ER  - 

@conference{
author = "Dugandžić, Ivan and Lojpur, Vesna and Mančić, Lidija and Rabanal, Maria Eugenia and Milošević, Olivera",
year = "2010",
abstract = "Poster presented at 12th Annual Conference of the Materials Research Society of Serbia - YUCOMAT 2010, Herceg Novi, Montenegro, September 6–10, 2010.",
title = "Dense spherical rare earth oxide particles synthesis via spray pyrolysis of polimeric precursor solution",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7366"
}

Dugandžić, I., Lojpur, V., Mančić, L., Rabanal, M. E.,& Milošević, O.. (2010). Dense spherical rare earth oxide particles synthesis via spray pyrolysis of polimeric precursor solution. .
https://hdl.handle.net/21.15107/rcub_vinar_7366

Dugandžić I, Lojpur V, Mančić L, Rabanal ME, Milošević O. Dense spherical rare earth oxide particles synthesis via spray pyrolysis of polimeric precursor solution. 2010;.
https://hdl.handle.net/21.15107/rcub_vinar_7366 .

Dugandžić, Ivan, Lojpur, Vesna, Mančić, Lidija, Rabanal, Maria Eugenia, Milošević, Olivera, "Dense spherical rare earth oxide particles synthesis via spray pyrolysis of polimeric precursor solution" (2010),
https://hdl.handle.net/21.15107/rcub_vinar_7366 .

TY  - CONF
AU  - Marinkovic, Katarina R.
AU  - Mančić, Lidija
AU  - Rabanal, Maria Eugenia
AU  - Gomez, Luz S.
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6903
AB  - In this study, nanophase, spherical, polycrystalline (Y1-xGdx)(2)O-3:Eu3+ phosphor particles were synthesized from aerosols of corresponding nitrate solutions, ultrasonically generated at 1.3 MHz frequency, and thermally decomposed at 900 and 1100 degrees C. Structural and morphological analyses done by X-ray powder diffraction (XRPD) and transmission electron microscopy analysis (TEM) implied the formation of non-aggregated spherical, submicronic particles with smooth particle surfaces and filled morphology. The phase development and structural changes, determined using the Topas program, implied a nanocrystalline inner structure (crystallites LT 20 nm), that was also confirmed by SAED analysis. A bcc Ia-3 cubic phase was identified in all as-prepared samples, apart from the mixed oxide with the gadolinium content GT 75%, where the existence of a secondary, fcc Fm-3m cubic phase is determined. Only Ia-3 cubic phase was identified in thermally treated samples (1100 degrees C), while the powder morphological features were maintained, followed by increase in powder crystallinity and phase homogeneity. Functional properties were analyzed by means of photoluminescent analysis. Emission spectra showed typical Eu3+ D-5(0) - GT (7)Fi (i = 0, 1, 2, 3, 4) transitions with the dominant red emission peak at 611 nm.
T1  - Nanostructured (Y1-Xgdx)(2)O-3:Eu3+ Powders Obtained Through Aerosol Synthesis
VL  - 219
SP  - 83
EP  - +
UR  - https://hdl.handle.net/21.15107/rcub_vinar_6903
ER  - 

@conference{
author = "Marinkovic, Katarina R. and Mančić, Lidija and Rabanal, Maria Eugenia and Gomez, Luz S. and Dramićanin, Miroslav and Milošević, Olivera",
year = "2010",
abstract = "In this study, nanophase, spherical, polycrystalline (Y1-xGdx)(2)O-3:Eu3+ phosphor particles were synthesized from aerosols of corresponding nitrate solutions, ultrasonically generated at 1.3 MHz frequency, and thermally decomposed at 900 and 1100 degrees C. Structural and morphological analyses done by X-ray powder diffraction (XRPD) and transmission electron microscopy analysis (TEM) implied the formation of non-aggregated spherical, submicronic particles with smooth particle surfaces and filled morphology. The phase development and structural changes, determined using the Topas program, implied a nanocrystalline inner structure (crystallites LT 20 nm), that was also confirmed by SAED analysis. A bcc Ia-3 cubic phase was identified in all as-prepared samples, apart from the mixed oxide with the gadolinium content GT 75%, where the existence of a secondary, fcc Fm-3m cubic phase is determined. Only Ia-3 cubic phase was identified in thermally treated samples (1100 degrees C), while the powder morphological features were maintained, followed by increase in powder crystallinity and phase homogeneity. Functional properties were analyzed by means of photoluminescent analysis. Emission spectra showed typical Eu3+ D-5(0) - GT (7)Fi (i = 0, 1, 2, 3, 4) transitions with the dominant red emission peak at 611 nm.",
title = "Nanostructured (Y1-Xgdx)(2)O-3:Eu3+ Powders Obtained Through Aerosol Synthesis",
volume = "219",
pages = "83-+",
url = "https://hdl.handle.net/21.15107/rcub_vinar_6903"
}

Marinkovic, K. R., Mančić, L., Rabanal, M. E., Gomez, L. S., Dramićanin, M.,& Milošević, O.. (2010). Nanostructured (Y1-Xgdx)(2)O-3:Eu3+ Powders Obtained Through Aerosol Synthesis. , 219, 83-+.
https://hdl.handle.net/21.15107/rcub_vinar_6903

Marinkovic KR, Mančić L, Rabanal ME, Gomez LS, Dramićanin M, Milošević O. Nanostructured (Y1-Xgdx)(2)O-3:Eu3+ Powders Obtained Through Aerosol Synthesis. 2010;219:83-+.
https://hdl.handle.net/21.15107/rcub_vinar_6903 .

Marinkovic, Katarina R., Mančić, Lidija, Rabanal, Maria Eugenia, Gomez, Luz S., Dramićanin, Miroslav, Milošević, Olivera, "Nanostructured (Y1-Xgdx)(2)O-3:Eu3+ Powders Obtained Through Aerosol Synthesis", 219 (2010):83-+,
https://hdl.handle.net/21.15107/rcub_vinar_6903 .

TY  - JOUR
AU  - Marinkovic, K.
AU  - Mančić, Lidija
AU  - Gomez, Luz S.
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6891
AB  - Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 degrees C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size similar to 20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 degrees C. A bcc la-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion D-5(0) and D-5(1) levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ D-5(0)- GT F-7(i) (i = 0, 1, 2, 3, 4) transitions with dominant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. (C) 2010 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis
VL  - 32
IS  - 12
SP  - 1606
EP  - 1611
DO  - 10.1016/j.optmat.2010.05.023
ER  - 

@article{
author = "Marinkovic, K. and Mančić, Lidija and Gomez, Luz S. and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2010",
abstract = "Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 degrees C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size similar to 20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 degrees C. A bcc la-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion D-5(0) and D-5(1) levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ D-5(0)- GT F-7(i) (i = 0, 1, 2, 3, 4) transitions with dominant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. (C) 2010 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis",
volume = "32",
number = "12",
pages = "1606-1611",
doi = "10.1016/j.optmat.2010.05.023"
}

Marinkovic, K., Mančić, L., Gomez, L. S., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2010). Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis. in Optical Materials, 32(12), 1606-1611.
https://doi.org/10.1016/j.optmat.2010.05.023

Marinkovic K, Mančić L, Gomez LS, Rabanal ME, Dramićanin M, Milošević O. Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis. in Optical Materials. 2010;32(12):1606-1611.
doi:10.1016/j.optmat.2010.05.023 .

Marinkovic, K., Mančić, Lidija, Gomez, Luz S., Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis" in Optical Materials, 32, no. 12 (2010):1606-1611,
https://doi.org/10.1016/j.optmat.2010.05.023 . .

TY  - CONF
AU  - Marinković, Katarina
AU  - Mančić, Lidija
AU  - Gómez, Luz Stella
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7379
AB  - Poster presented at the ICOM 2009 – The International Conference on Physics of Optical Materials and Devices, Herceg Novi, Montenegro, 27th August – 30th August, 2009.
PB  - Belgrade : Vinča Institute of Nuclear Sciences
C3  - ICOM 2009 : International Conference of Phosphor Thermometry : Book of abstracts
T1  - Photoluminescent Properties of Nanostructured Y2O3:Eu3+ and (Y1-xGdx)2O3:Eu3+ Powders Obtained by Aerosol Synthesis
SP  - 82
EP  - 82
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7379
ER  - 

@conference{
author = "Marinković, Katarina and Mančić, Lidija and Gómez, Luz Stella and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2009",
abstract = "Poster presented at the ICOM 2009 – The International Conference on Physics of Optical Materials and Devices, Herceg Novi, Montenegro, 27th August – 30th August, 2009.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences",
journal = "ICOM 2009 : International Conference of Phosphor Thermometry : Book of abstracts",
title = "Photoluminescent Properties of Nanostructured Y2O3:Eu3+ and (Y1-xGdx)2O3:Eu3+ Powders Obtained by Aerosol Synthesis",
pages = "82-82",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7379"
}

Marinković, K., Mančić, L., Gómez, L. S., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2009). Photoluminescent Properties of Nanostructured Y2O3:Eu3+ and (Y1-xGdx)2O3:Eu3+ Powders Obtained by Aerosol Synthesis. in ICOM 2009 : International Conference of Phosphor Thermometry : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences., 82-82.
https://hdl.handle.net/21.15107/rcub_vinar_7379

Marinković K, Mančić L, Gómez LS, Rabanal ME, Dramićanin M, Milošević O. Photoluminescent Properties of Nanostructured Y2O3:Eu3+ and (Y1-xGdx)2O3:Eu3+ Powders Obtained by Aerosol Synthesis. in ICOM 2009 : International Conference of Phosphor Thermometry : Book of abstracts. 2009;:82-82.
https://hdl.handle.net/21.15107/rcub_vinar_7379 .

Marinković, Katarina, Mančić, Lidija, Gómez, Luz Stella, Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Photoluminescent Properties of Nanostructured Y2O3:Eu3+ and (Y1-xGdx)2O3:Eu3+ Powders Obtained by Aerosol Synthesis" in ICOM 2009 : International Conference of Phosphor Thermometry : Book of abstracts (2009):82-82,
https://hdl.handle.net/21.15107/rcub_vinar_7379 .