TY  - CONF
AU  - Montone, A.
AU  - Antisari, M. Vittori
AU  - Abazović, Nadica
AU  - Grbović-Novaković, Jasmina
AU  - Pasquini, L.
AU  - Bonetti, E.
AU  - Forini, A. L.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6693
AB  - Hydrogen, being a regenerative and environmentally harmless fuel, can play a crucial role in the energetic scenario of the near future. In recent years several systems for solid-state hydrogen storage have been investigated, among which a few metals and metal alloys show the most promising properties. Mg and Mg-based micro and nanocomposites are widely studied for this application owing to the high gravimetric storage capacity, even if a proper microstructure, mainly at the material surface, has to be setup in order to overtake kinetic constraints often related to the high surface reactivity. In this paper, we present our approach to this problem and report the main findings. We have examined the influence on hydrogenation/dehydrogenation characteristics of different modifications of the bulk and surface microstructure of MgH2 powders processed by ball milling, which appears to be one the most useful methods for preparing powders suitable for hydrogen storage.
C3  - Materials Science Forum
T1  - Reaction with hydrogen of micro and nano composites based on Mg
VL  - 555
SP  - 335
EP  - +
DO  - 10.4028/www.scientific.net/MSF.555.335
ER  - 

@conference{
author = "Montone, A. and Antisari, M. Vittori and Abazović, Nadica and Grbović-Novaković, Jasmina and Pasquini, L. and Bonetti, E. and Forini, A. L.",
year = "2007",
abstract = "Hydrogen, being a regenerative and environmentally harmless fuel, can play a crucial role in the energetic scenario of the near future. In recent years several systems for solid-state hydrogen storage have been investigated, among which a few metals and metal alloys show the most promising properties. Mg and Mg-based micro and nanocomposites are widely studied for this application owing to the high gravimetric storage capacity, even if a proper microstructure, mainly at the material surface, has to be setup in order to overtake kinetic constraints often related to the high surface reactivity. In this paper, we present our approach to this problem and report the main findings. We have examined the influence on hydrogenation/dehydrogenation characteristics of different modifications of the bulk and surface microstructure of MgH2 powders processed by ball milling, which appears to be one the most useful methods for preparing powders suitable for hydrogen storage.",
journal = "Materials Science Forum",
title = "Reaction with hydrogen of micro and nano composites based on Mg",
volume = "555",
pages = "335-+",
doi = "10.4028/www.scientific.net/MSF.555.335"
}

Montone, A., Antisari, M. V., Abazović, N., Grbović-Novaković, J., Pasquini, L., Bonetti, E.,& Forini, A. L.. (2007). Reaction with hydrogen of micro and nano composites based on Mg. in Materials Science Forum, 555, 335-+.
https://doi.org/10.4028/www.scientific.net/MSF.555.335

Montone A, Antisari MV, Abazović N, Grbović-Novaković J, Pasquini L, Bonetti E, Forini AL. Reaction with hydrogen of micro and nano composites based on Mg. in Materials Science Forum. 2007;555:335-+.
doi:10.4028/www.scientific.net/MSF.555.335 .

Montone, A., Antisari, M. Vittori, Abazović, Nadica, Grbović-Novaković, Jasmina, Pasquini, L., Bonetti, E., Forini, A. L., "Reaction with hydrogen of micro and nano composites based on Mg" in Materials Science Forum, 555 (2007):335-+,
https://doi.org/10.4028/www.scientific.net/MSF.555.335 . .

TY  - JOUR
AU  - Montone, A.
AU  - Grbović, Jasmina
AU  - Bassetti, A.
AU  - Mirenghi, Luciana
AU  - Rotolo, P.
AU  - Bonetti, E.
AU  - Pasquini, L.
AU  - Antisari, M. Vittori
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3117
AB  - Mg-graphite composites, suitable for hydrogen storage, have been synthesized by ball milling metallic Mg with different amounts of graphite and benzene. The microstructure and the surface chemical composition have been characterized in order to explain the kinetics of reaction with hydrogen. The presence of benzene in the milled blends induces a finer powder particle size, helps to preserve the structural integrity of the graphite crystals and results to be necessary for a complete transformation of the milled powder to the hydride phase by thermal reaction with hydrogen gas. On the other hand, it induces a more pronounced reaction of the milled Mg-C composites with the air. The transport properties of the resulting surface contamination layer appear to control the kinetics of thermal decomposition of the MgH2 phase, so that the addition of benzene induces a higher reaction temperature owing to a larger thickness of the surface compound. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene
VL  - 31
IS  - 14
SP  - 2088
EP  - 2096
DO  - 10.1016/j.ijhydene.2006.01.020
ER  - 

@article{
author = "Montone, A. and Grbović, Jasmina and Bassetti, A. and Mirenghi, Luciana and Rotolo, P. and Bonetti, E. and Pasquini, L. and Antisari, M. Vittori",
year = "2006",
abstract = "Mg-graphite composites, suitable for hydrogen storage, have been synthesized by ball milling metallic Mg with different amounts of graphite and benzene. The microstructure and the surface chemical composition have been characterized in order to explain the kinetics of reaction with hydrogen. The presence of benzene in the milled blends induces a finer powder particle size, helps to preserve the structural integrity of the graphite crystals and results to be necessary for a complete transformation of the milled powder to the hydride phase by thermal reaction with hydrogen gas. On the other hand, it induces a more pronounced reaction of the milled Mg-C composites with the air. The transport properties of the resulting surface contamination layer appear to control the kinetics of thermal decomposition of the MgH2 phase, so that the addition of benzene induces a higher reaction temperature owing to a larger thickness of the surface compound. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene",
volume = "31",
number = "14",
pages = "2088-2096",
doi = "10.1016/j.ijhydene.2006.01.020"
}

Montone, A., Grbović, J., Bassetti, A., Mirenghi, L., Rotolo, P., Bonetti, E., Pasquini, L.,& Antisari, M. V.. (2006). Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene. in International Journal of Hydrogen Energy, 31(14), 2088-2096.
https://doi.org/10.1016/j.ijhydene.2006.01.020

Montone A, Grbović J, Bassetti A, Mirenghi L, Rotolo P, Bonetti E, Pasquini L, Antisari MV. Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene. in International Journal of Hydrogen Energy. 2006;31(14):2088-2096.
doi:10.1016/j.ijhydene.2006.01.020 .

Montone, A., Grbović, Jasmina, Bassetti, A., Mirenghi, Luciana, Rotolo, P., Bonetti, E., Pasquini, L., Antisari, M. Vittori, "Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene" in International Journal of Hydrogen Energy, 31, no. 14 (2006):2088-2096,
https://doi.org/10.1016/j.ijhydene.2006.01.020 . .

TY  - JOUR
AU  - Montone, A.
AU  - Grbović, Jasmina
AU  - Stamenković, Ljiljana Lj.
AU  - Fiorini, A. L.
AU  - Pasquini, L.
AU  - Bonetti, E.
AU  - Antisari, M. Vittori
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6596
AB  - The influence of the Co addition and synthesis route on desorption properties of MgH2 were investigated. Ball milling of MgH2-Co blends was performed under Ar using different milling intensities and different weight ratios. Micro structural and morphological characterization, performed by XRD and SEM, show a huge correlation with thermal stability and hydrogen desorption properties investigated by DSC. A complex desorption behaviour is correlated with the dispersion of the catalytic particles that appears to play a main role in desorption performances. The optimum catalyst concentration was found to be around 10 wt.%, while the optimum value of the ball to powder ratio was 10:1.
T2  - Materials Science Forum
T1  - Desorption behaviour in nanostructured MgH2-CO
VL  - 518
SP  - 79
EP  - 84
DO  - 10.4028/www.scientific.net/MSF.518.79
ER  - 

@article{
author = "Montone, A. and Grbović, Jasmina and Stamenković, Ljiljana Lj. and Fiorini, A. L. and Pasquini, L. and Bonetti, E. and Antisari, M. Vittori",
year = "2006",
abstract = "The influence of the Co addition and synthesis route on desorption properties of MgH2 were investigated. Ball milling of MgH2-Co blends was performed under Ar using different milling intensities and different weight ratios. Micro structural and morphological characterization, performed by XRD and SEM, show a huge correlation with thermal stability and hydrogen desorption properties investigated by DSC. A complex desorption behaviour is correlated with the dispersion of the catalytic particles that appears to play a main role in desorption performances. The optimum catalyst concentration was found to be around 10 wt.%, while the optimum value of the ball to powder ratio was 10:1.",
journal = "Materials Science Forum",
title = "Desorption behaviour in nanostructured MgH2-CO",
volume = "518",
pages = "79-84",
doi = "10.4028/www.scientific.net/MSF.518.79"
}

Montone, A., Grbović, J., Stamenković, L. Lj., Fiorini, A. L., Pasquini, L., Bonetti, E.,& Antisari, M. V.. (2006). Desorption behaviour in nanostructured MgH2-CO. in Materials Science Forum, 518, 79-84.
https://doi.org/10.4028/www.scientific.net/MSF.518.79

Montone A, Grbović J, Stamenković LL, Fiorini AL, Pasquini L, Bonetti E, Antisari MV. Desorption behaviour in nanostructured MgH2-CO. in Materials Science Forum. 2006;518:79-84.
doi:10.4028/www.scientific.net/MSF.518.79 .

Montone, A., Grbović, Jasmina, Stamenković, Ljiljana Lj., Fiorini, A. L., Pasquini, L., Bonetti, E., Antisari, M. Vittori, "Desorption behaviour in nanostructured MgH2-CO" in Materials Science Forum, 518 (2006):79-84,
https://doi.org/10.4028/www.scientific.net/MSF.518.79 . .