TY  - JOUR
AU  - Milanković, Vedran
AU  - Tasić, Tamara
AU  - Brković, Snežana M.
AU  - Potkonjak, Nebojša I.
AU  - Unterweger, C.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Pašti, Igor A.
AU  - Lazarević-Pašti, Tamara
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13261
AB  - Environmental contamination from various industrial sources poses a significant global concern, demanding effective remediation strategies. This study investigates the efficacy of spent coffee grounds-derived carbon material in removing various contaminants, including organophosphate pesticides, pharmaceutical residues, and cationic dyes from aqueous solutions. Adsorption experiments were conducted at different temperatures (25 °C, 30 °C, and 35 °C), and the adsorption behavior was analyzed using various kinetic (pseudo-first-order, pseudo-second-order, Elovich, intraparticle diffusion) and isotherm models (Freundlich, Langmuir, Temkin, Dubinin-Radushkevich). Our findings reveal a complex adsorption process involving both monolayer and multilayer adsorption on the heterogeneous surface of the material. Temperature significantly influenced adsorption behavior, affecting maximum capacities and interactions. Using a material concentration of 0.5 mg mL−1 increases adsorption capacities for both pesticides, reaching 92.0 mg g−1 for malathion and 259 mg g−1 for chlorpyrifos adsorption. At a material concentration of 0.1 mg mL−1, the carbon material exhibited high adsorption capacities for methylene blue, rhodamine B, amoxicillin, and ceftriaxone, reaching values of 2085 mg g−1, 8250 mg g−1, 82 mg g−1, and 181 mg g−1, respectively. The adsorbent was successfully regenerated using 25 % ethanol solution and reused for at least 10 cycles without significantly impacting the adsorption capacity. These results underscore the potential of spent coffee grounds-derived carbon material as an efficient adsorbent for diverse contaminants, highlighting its promising role in environmental remediation efforts.
T2  - Journal of Water Process Engineering
T1  - Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study
VL  - 63
SP  - 105507
DO  - 10.1016/j.jwpe.2024.105507
ER  - 

@article{
author = "Milanković, Vedran and Tasić, Tamara and Brković, Snežana M. and Potkonjak, Nebojša I. and Unterweger, C. and Bajuk-Bogdanović, Danica V. and Pašti, Igor A. and Lazarević-Pašti, Tamara",
year = "2024",
abstract = "Environmental contamination from various industrial sources poses a significant global concern, demanding effective remediation strategies. This study investigates the efficacy of spent coffee grounds-derived carbon material in removing various contaminants, including organophosphate pesticides, pharmaceutical residues, and cationic dyes from aqueous solutions. Adsorption experiments were conducted at different temperatures (25 °C, 30 °C, and 35 °C), and the adsorption behavior was analyzed using various kinetic (pseudo-first-order, pseudo-second-order, Elovich, intraparticle diffusion) and isotherm models (Freundlich, Langmuir, Temkin, Dubinin-Radushkevich). Our findings reveal a complex adsorption process involving both monolayer and multilayer adsorption on the heterogeneous surface of the material. Temperature significantly influenced adsorption behavior, affecting maximum capacities and interactions. Using a material concentration of 0.5 mg mL−1 increases adsorption capacities for both pesticides, reaching 92.0 mg g−1 for malathion and 259 mg g−1 for chlorpyrifos adsorption. At a material concentration of 0.1 mg mL−1, the carbon material exhibited high adsorption capacities for methylene blue, rhodamine B, amoxicillin, and ceftriaxone, reaching values of 2085 mg g−1, 8250 mg g−1, 82 mg g−1, and 181 mg g−1, respectively. The adsorbent was successfully regenerated using 25 % ethanol solution and reused for at least 10 cycles without significantly impacting the adsorption capacity. These results underscore the potential of spent coffee grounds-derived carbon material as an efficient adsorbent for diverse contaminants, highlighting its promising role in environmental remediation efforts.",
journal = "Journal of Water Process Engineering",
title = "Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study",
volume = "63",
pages = "105507",
doi = "10.1016/j.jwpe.2024.105507"
}

Milanković, V., Tasić, T., Brković, S. M., Potkonjak, N. I., Unterweger, C., Bajuk-Bogdanović, D. V., Pašti, I. A.,& Lazarević-Pašti, T.. (2024). Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study. in Journal of Water Process Engineering, 63, 105507.
https://doi.org/10.1016/j.jwpe.2024.105507

Milanković V, Tasić T, Brković SM, Potkonjak NI, Unterweger C, Bajuk-Bogdanović DV, Pašti IA, Lazarević-Pašti T. Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study. in Journal of Water Process Engineering. 2024;63:105507.
doi:10.1016/j.jwpe.2024.105507 .

Milanković, Vedran, Tasić, Tamara, Brković, Snežana M., Potkonjak, Nebojša I., Unterweger, C., Bajuk-Bogdanović, Danica V., Pašti, Igor A., Lazarević-Pašti, Tamara, "Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study" in Journal of Water Process Engineering, 63 (2024):105507,
https://doi.org/10.1016/j.jwpe.2024.105507 . .