TY  - JOUR
AU  - Soldatovic, Tanja
AU  - Vasić, Vesna M.
AU  - Bugarčić, Živadin D.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3153
AB  - Substitution reactions of [PtCl(dien)](+) (dien = diethylenetriamine) with some biologically relevant ligands, such as L-methionine ((L)-Met), glutathione (GSH), and guanosine 5-nionophosphate (5-GMP), were studied in aqueous 0.10, 0.05, and 0.01 M NaClO4 Solutions at pH 2.5 using UV-vis spectrophotometry. The kinetics and mechanism of the complex-formation reactions were Studied as I function of nucleophile concentration and temperature. These reactions were also Studied in the presence and absence of micelles of sodium dodecyl sulfate (SIDS). The presence of anionic micelles accelerated complex-forination. The largest effect of micelles has been observed in the case of L-methionine. On the other hand, all increase in the ionic strength in the presence of micelles caused a decrease in the rate. The negative entropies of activation support all associative complex-formation mechanism.
T2  - Bulletin of the Chemical Society of Japan
T1  - Effects of micelles on the complex formation of [PtCl(dien)](+) with biologically relevant ligands
VL  - 79
IS  - 12
SP  - 1889
EP  - 1893
DO  - 10.1246/bcsj.79.1889
ER  - 

@article{
author = "Soldatovic, Tanja and Vasić, Vesna M. and Bugarčić, Živadin D.",
year = "2006",
abstract = "Substitution reactions of [PtCl(dien)](+) (dien = diethylenetriamine) with some biologically relevant ligands, such as L-methionine ((L)-Met), glutathione (GSH), and guanosine 5-nionophosphate (5-GMP), were studied in aqueous 0.10, 0.05, and 0.01 M NaClO4 Solutions at pH 2.5 using UV-vis spectrophotometry. The kinetics and mechanism of the complex-formation reactions were Studied as I function of nucleophile concentration and temperature. These reactions were also Studied in the presence and absence of micelles of sodium dodecyl sulfate (SIDS). The presence of anionic micelles accelerated complex-forination. The largest effect of micelles has been observed in the case of L-methionine. On the other hand, all increase in the ionic strength in the presence of micelles caused a decrease in the rate. The negative entropies of activation support all associative complex-formation mechanism.",
journal = "Bulletin of the Chemical Society of Japan",
title = "Effects of micelles on the complex formation of [PtCl(dien)](+) with biologically relevant ligands",
volume = "79",
number = "12",
pages = "1889-1893",
doi = "10.1246/bcsj.79.1889"
}

Soldatovic, T., Vasić, V. M.,& Bugarčić, Ž. D.. (2006). Effects of micelles on the complex formation of [PtCl(dien)](+) with biologically relevant ligands. in Bulletin of the Chemical Society of Japan, 79(12), 1889-1893.
https://doi.org/10.1246/bcsj.79.1889

Soldatovic T, Vasić VM, Bugarčić ŽD. Effects of micelles on the complex formation of [PtCl(dien)](+) with biologically relevant ligands. in Bulletin of the Chemical Society of Japan. 2006;79(12):1889-1893.
doi:10.1246/bcsj.79.1889 .

Soldatovic, Tanja, Vasić, Vesna M., Bugarčić, Živadin D., "Effects of micelles on the complex formation of [PtCl(dien)](+) with biologically relevant ligands" in Bulletin of the Chemical Society of Japan, 79, no. 12 (2006):1889-1893,
https://doi.org/10.1246/bcsj.79.1889 . .