TY  - JOUR
AU  - Vuksanović, Marija M.
AU  - Milošević, Milena
AU  - Dimitrijević, Ivan
AU  - Milentijević, Gordana
AU  - Babincev, Ljiljana
AU  - Gržetić, Jelena
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12939
AB  - The increase in waste polymer recycling has helped in promoting sustainability, and together with the use of renewable raw materials, it has become a widespread concept with positive effects on both the economy and ecology. Accordingly, the aim of this study was the synthesis of “green” plasticizers, marked as LA/PG/PET/EG/LA, formed from waste poly(ethylene terephthalate) (PET) and bio-based platform chemicals propylene glycol (PG) and levulinic acid (LA). The structure of the obtained plasticizers was complex, as confirmed by results from nuclear magnetic resonance (NMR) and Fourier-transform infrared spectroscopy (FTIR) analysis. The LA/PG/PET/EG/LA plasticizers and waste poly(vinyl chloride) (PVC) were used in an optimized technology for PVC re-granulate production. The hardness of the PVC-based material with “green” plasticizers, in comparison to commercial plasticizer dioctyl terephthalate (DOTP), increased by 11.3%, while migration decreased. An improved material homogeneity and wettability of the fibers by the matrix were observed using SEM analysis of the material’s fracture surface, with a higher efficiency of intermolecular interactions leading to better mechanical performances of the newly designed materials. Thus, LA/PG/PET/EG/LA are unique materials with good compounding and plasticizing potential for PVC, as revealed by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). In that manner, the use of bio-renewable resources and recycled polymers will contribute to diminishing waste polymer generation, contributing to a lower carbon footprint.
T2  - Processes
T1  - Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation
VL  - 12
IS  - 3
SP  - 520
DO  - 10.3390/pr12030520
ER  - 

@article{
author = "Vuksanović, Marija M. and Milošević, Milena and Dimitrijević, Ivan and Milentijević, Gordana and Babincev, Ljiljana and Gržetić, Jelena and Marinković, Aleksandar and Milosavljević, Milutin",
year = "2024",
abstract = "The increase in waste polymer recycling has helped in promoting sustainability, and together with the use of renewable raw materials, it has become a widespread concept with positive effects on both the economy and ecology. Accordingly, the aim of this study was the synthesis of “green” plasticizers, marked as LA/PG/PET/EG/LA, formed from waste poly(ethylene terephthalate) (PET) and bio-based platform chemicals propylene glycol (PG) and levulinic acid (LA). The structure of the obtained plasticizers was complex, as confirmed by results from nuclear magnetic resonance (NMR) and Fourier-transform infrared spectroscopy (FTIR) analysis. The LA/PG/PET/EG/LA plasticizers and waste poly(vinyl chloride) (PVC) were used in an optimized technology for PVC re-granulate production. The hardness of the PVC-based material with “green” plasticizers, in comparison to commercial plasticizer dioctyl terephthalate (DOTP), increased by 11.3%, while migration decreased. An improved material homogeneity and wettability of the fibers by the matrix were observed using SEM analysis of the material’s fracture surface, with a higher efficiency of intermolecular interactions leading to better mechanical performances of the newly designed materials. Thus, LA/PG/PET/EG/LA are unique materials with good compounding and plasticizing potential for PVC, as revealed by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). In that manner, the use of bio-renewable resources and recycled polymers will contribute to diminishing waste polymer generation, contributing to a lower carbon footprint.",
journal = "Processes",
title = "Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation",
volume = "12",
number = "3",
pages = "520",
doi = "10.3390/pr12030520"
}

Vuksanović, M. M., Milošević, M., Dimitrijević, I., Milentijević, G., Babincev, L., Gržetić, J., Marinković, A.,& Milosavljević, M.. (2024). Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation. in Processes, 12(3), 520.
https://doi.org/10.3390/pr12030520

Vuksanović MM, Milošević M, Dimitrijević I, Milentijević G, Babincev L, Gržetić J, Marinković A, Milosavljević M. Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation. in Processes. 2024;12(3):520.
doi:10.3390/pr12030520 .

Vuksanović, Marija M., Milošević, Milena, Dimitrijević, Ivan, Milentijević, Gordana, Babincev, Ljiljana, Gržetić, Jelena, Marinković, Aleksandar, Milosavljević, Milutin, "Green Plasticizer for Poly(vinyl chloride) Re-Granulate Production: Case Study of Sustainability Concept Implementation" in Processes, 12, no. 3 (2024):520,
https://doi.org/10.3390/pr12030520 . .

Marinković, A., Milošević, M., Knežević, N., Jovanović, A. A., Gržetić, J., Nikolić, Ž.,& Vuksanović, M. M.. (2023). Postupak dobijanja regranulata PVC-a sa dodatkom modifikovanog etilenvinilacetata (EVA) za meke proizvode. .
https://hdl.handle.net/21.15107/rcub_vinar_12492

Marinković A, Milošević M, Knežević N, Jovanović AA, Gržetić J, Nikolić Ž, Vuksanović MM. Postupak dobijanja regranulata PVC-a sa dodatkom modifikovanog etilenvinilacetata (EVA) za meke proizvode. 2023;.
https://hdl.handle.net/21.15107/rcub_vinar_12492 .

Marinković, Aleksandar, Milošević, Milena, Knežević, Nataša, Jovanović, Aleksandra A., Gržetić, Jelena, Nikolić, Željko, Vuksanović, Marija M., "Postupak dobijanja regranulata PVC-a sa dodatkom modifikovanog etilenvinilacetata (EVA) za meke proizvode" (2023),
https://hdl.handle.net/21.15107/rcub_vinar_12492 .

Marinković, A., Vuksanović, M., Bogdanović, A., Milošević, M., Bugarčić, M., Egelja, A.,& Tomić, N.. (2022). Postupak dobijanja ekspandirajućeg materijala sa plastifikatorima iz recikliranog poli(etilen terefatalata) (PET). in Univerzitet u Beogradu : Tehnološko-metalurški fakultet.
https://hdl.handle.net/21.15107/rcub_vinar_13005

Marinković A, Vuksanović M, Bogdanović A, Milošević M, Bugarčić M, Egelja A, Tomić N. Postupak dobijanja ekspandirajućeg materijala sa plastifikatorima iz recikliranog poli(etilen terefatalata) (PET). in Univerzitet u Beogradu : Tehnološko-metalurški fakultet. 2022;.
https://hdl.handle.net/21.15107/rcub_vinar_13005 .

Marinković, Aleksandar, Vuksanović, Marija, Bogdanović, Aleksandra, Milošević, Milena, Bugarčić, Mladen, Egelja, Adela, Tomić, Nataša, "Postupak dobijanja ekspandirajućeg materijala sa plastifikatorima iz recikliranog poli(etilen terefatalata) (PET)" in Univerzitet u Beogradu : Tehnološko-metalurški fakultet (2022),
https://hdl.handle.net/21.15107/rcub_vinar_13005 .

Marinković, A., Tomić, N., Prlainović, N., Radovanović, Ž., Bošnjaković, J.,& Vuksanović, M.. (2021). Postupak proizvodnje plastifikatora iz otpadnog PET-a za poboljšanu termostabilnost ekspandirajućih protivpožarnih materijala. .
https://doi.org/10.5281/zenodo.8366862

Marinković A, Tomić N, Prlainović N, Radovanović Ž, Bošnjaković J, Vuksanović M. Postupak proizvodnje plastifikatora iz otpadnog PET-a za poboljšanu termostabilnost ekspandirajućih protivpožarnih materijala. 2021;.
doi:10.5281/zenodo.8366862 .

Marinković, Aleksandar, Tomić, Nataša, Prlainović, Nevena, Radovanović, Željko, Bošnjaković, Jovana, Vuksanović, Marija, "Postupak proizvodnje plastifikatora iz otpadnog PET-a za poboljšanu termostabilnost ekspandirajućih protivpožarnih materijala" (2021),
https://doi.org/10.5281/zenodo.8366862 . .

Jančić Heinemann, R., Vuksanović, M. M., Tomić, N., Petrović, M., Spasojević, P., Radišić, M., Radojević, V., Trifunović, D.,& Marinković, A.. (2018). Kompozitni materijali na bazi PMMA modifikovan dimetil itakonatom sa poboljšanom žilavosti i smanjenom količinom zaostalog monomera. .
https://hdl.handle.net/21.15107/rcub_vinar_13003

Jančić Heinemann R, Vuksanović MM, Tomić N, Petrović M, Spasojević P, Radišić M, Radojević V, Trifunović D, Marinković A. Kompozitni materijali na bazi PMMA modifikovan dimetil itakonatom sa poboljšanom žilavosti i smanjenom količinom zaostalog monomera. 2018;.
https://hdl.handle.net/21.15107/rcub_vinar_13003 .

Jančić Heinemann, Radmila, Vuksanović, Marija M., Tomić, Nataša, Petrović, Miloš, Spasojević, Pavle, Radišić, Marina, Radojević, Vesna, Trifunović, Dejan, Marinković, Aleksandar, "Kompozitni materijali na bazi PMMA modifikovan dimetil itakonatom sa poboljšanom žilavosti i smanjenom količinom zaostalog monomera" (2018),
https://hdl.handle.net/21.15107/rcub_vinar_13003 .