Barjaktarević, Dragana R.

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8905ad8b-196a-4537-9732-f67ff5bc96e1
  • Barjaktarević, Dragana R. (5)
  • Barjaktarević, Dragana (3)
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Author's Bibliography

Tensile and Corrosion Properties of Anodized Ultrafne‑Grained Ti–13Nb–13Zr Biomedical Alloy Obtained by High‑Pressure Torsion

Barjaktarević, Dragana; Međo, Bojan; Štefane, Primož; Gubeljak, Nenad; Cvijović-Alagić, Ivana; Đokić, Veljko; Rakin, Marko

(2021)

TY  - JOUR
AU  - Barjaktarević, Dragana
AU  - Međo, Bojan
AU  - Štefane, Primož
AU  - Gubeljak, Nenad
AU  - Cvijović-Alagić, Ivana
AU  - Đokić, Veljko
AU  - Rakin, Marko
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9606
AB  - Severe plastic deformation (SPD) is a popular group of techniques applied to achieve the nanostructuring of the metallic biomaterials and improvement of their mechanical characteristics. One of the most commonly used SPD methods is the high-pressure torsion (HPT) technique which enables the obtainment of the microstructure with small grains and high strength. In the present study, the influence of the plastic deformation and surface modification treatment on the tensile and corrosion properties of the Ti–13Nb–13Zr (wt%) alloy is investigated. In that purpose, the coarse-grained (CG) Ti–13Nb–13Zr (TNZ) alloy was subjected to the HPT processing by applying a pressure of 4.1 GPa with a rotational speed of 0.2 rpm and 5 revolutions at room temperature to obtain the ultrafine-grained (UFG) microstructure. The alloy microstructure before and after HPT processing was analysed using the scanning electron microscopy (SEM) and the X-ray diffraction (XRD). The homogeneity of the UFG TNZ alloy was determined by microhardness testing and microscopic observations. The nanotubular oxide layer on the surface of the TNZ alloy, both in CG and UFG condition, was formed by electrochemical anodization in 1 M H3PO4 + NaF electrolyte for 90 min. SEM analysis was used to characterise the morphology of the anodized surfaces, while energy dispersive spectroscopy was applied to determine the chemical composition of the nanostructured layers formed at the alloy surfaces. Mechanical properties of the TNZ alloy, before and after HPT processing and electrochemical anodization, were determined by tensile testing. After tensile testing, the fractographic analysis was conducted to identify the fracture mechanisms. The potentiodynamic polarization technique was used to determine the corrosion resistance of the alloy before and after plastic deformation and surface modification treatment. The obtained results showed that the alloy is reasonably homogeneous after the HPT processing. The XRD analyses reviled the presence of α′ and β phases in the CG TNZ alloy microstructure, while the additional ω phase was detected in the microstructure of the UFG TNZ alloy. The HPT obtained alloy exhibits higher hardness and improved tensile properties than the alloy in the as-received CG condition, while the electrochemical anodization leads to a decrease of its mechanical properties. Both CG and UFG alloys show excellent corrosion stability in Ringer’s solution. Moreover, electrochemical anodization leads to a decrease or an increase of the corrosion resistance of these materials, depending on the morphology of the formed nanotubular surface layers. The results indicate that the anodized CG TNZ alloy is characterized by a lower modulus of elasticity and better corrosion resistance properties than the anodized UFG TNZ alloy. Graphic Abstract: [Figure not available: see fulltext.] © 2020, The Korean Institute of Metals and Materials.
T2  - Metals and Materials International
T1  - Tensile and Corrosion Properties of Anodized Ultrafne‑Grained
Ti–13Nb–13Zr Biomedical Alloy Obtained by High‑Pressure Torsion
VL  - 27
IS  - 9
SP  - 3325
EP  - 3341
DO  - 10.1007/s12540-020-00837-z
ER  - 
@article{
author = "Barjaktarević, Dragana and Međo, Bojan and Štefane, Primož and Gubeljak, Nenad and Cvijović-Alagić, Ivana and Đokić, Veljko and Rakin, Marko",
year = "2021",
abstract = "Severe plastic deformation (SPD) is a popular group of techniques applied to achieve the nanostructuring of the metallic biomaterials and improvement of their mechanical characteristics. One of the most commonly used SPD methods is the high-pressure torsion (HPT) technique which enables the obtainment of the microstructure with small grains and high strength. In the present study, the influence of the plastic deformation and surface modification treatment on the tensile and corrosion properties of the Ti–13Nb–13Zr (wt%) alloy is investigated. In that purpose, the coarse-grained (CG) Ti–13Nb–13Zr (TNZ) alloy was subjected to the HPT processing by applying a pressure of 4.1 GPa with a rotational speed of 0.2 rpm and 5 revolutions at room temperature to obtain the ultrafine-grained (UFG) microstructure. The alloy microstructure before and after HPT processing was analysed using the scanning electron microscopy (SEM) and the X-ray diffraction (XRD). The homogeneity of the UFG TNZ alloy was determined by microhardness testing and microscopic observations. The nanotubular oxide layer on the surface of the TNZ alloy, both in CG and UFG condition, was formed by electrochemical anodization in 1 M H3PO4 + NaF electrolyte for 90 min. SEM analysis was used to characterise the morphology of the anodized surfaces, while energy dispersive spectroscopy was applied to determine the chemical composition of the nanostructured layers formed at the alloy surfaces. Mechanical properties of the TNZ alloy, before and after HPT processing and electrochemical anodization, were determined by tensile testing. After tensile testing, the fractographic analysis was conducted to identify the fracture mechanisms. The potentiodynamic polarization technique was used to determine the corrosion resistance of the alloy before and after plastic deformation and surface modification treatment. The obtained results showed that the alloy is reasonably homogeneous after the HPT processing. The XRD analyses reviled the presence of α′ and β phases in the CG TNZ alloy microstructure, while the additional ω phase was detected in the microstructure of the UFG TNZ alloy. The HPT obtained alloy exhibits higher hardness and improved tensile properties than the alloy in the as-received CG condition, while the electrochemical anodization leads to a decrease of its mechanical properties. Both CG and UFG alloys show excellent corrosion stability in Ringer’s solution. Moreover, electrochemical anodization leads to a decrease or an increase of the corrosion resistance of these materials, depending on the morphology of the formed nanotubular surface layers. The results indicate that the anodized CG TNZ alloy is characterized by a lower modulus of elasticity and better corrosion resistance properties than the anodized UFG TNZ alloy. Graphic Abstract: [Figure not available: see fulltext.] © 2020, The Korean Institute of Metals and Materials.",
journal = "Metals and Materials International",
title = "Tensile and Corrosion Properties of Anodized Ultrafne‑Grained
Ti–13Nb–13Zr Biomedical Alloy Obtained by High‑Pressure Torsion",
volume = "27",
number = "9",
pages = "3325-3341",
doi = "10.1007/s12540-020-00837-z"
}
Barjaktarević, D., Međo, B., Štefane, P., Gubeljak, N., Cvijović-Alagić, I., Đokić, V.,& Rakin, M.. (2021). Tensile and Corrosion Properties of Anodized Ultrafne‑Grained
Ti–13Nb–13Zr Biomedical Alloy Obtained by High‑Pressure Torsion. in Metals and Materials International, 27(9), 3325-3341.
https://doi.org/10.1007/s12540-020-00837-z
Barjaktarević D, Međo B, Štefane P, Gubeljak N, Cvijović-Alagić I, Đokić V, Rakin M. Tensile and Corrosion Properties of Anodized Ultrafne‑Grained
Ti–13Nb–13Zr Biomedical Alloy Obtained by High‑Pressure Torsion. in Metals and Materials International. 2021;27(9):3325-3341.
doi:10.1007/s12540-020-00837-z .
Barjaktarević, Dragana, Međo, Bojan, Štefane, Primož, Gubeljak, Nenad, Cvijović-Alagić, Ivana, Đokić, Veljko, Rakin, Marko, "Tensile and Corrosion Properties of Anodized Ultrafne‑Grained
Ti–13Nb–13Zr Biomedical Alloy Obtained by High‑Pressure Torsion" in Metals and Materials International, 27, no. 9 (2021):3325-3341,
https://doi.org/10.1007/s12540-020-00837-z . .
13
4
11

Experimental and numerical analysis of tensile properties of Ti-13Nb-13Zr alloy and determination of influence of anodization process

Barjaktarević, Dragana; Međo, Bojan; Gubeljak, Nenad; Cvijović-Alagić, Ivana; Štefane, Primož; Đokić, Veljko; Rakin, Marko

(2020)

TY  - JOUR
AU  - Barjaktarević, Dragana
AU  - Međo, Bojan
AU  - Gubeljak, Nenad
AU  - Cvijović-Alagić, Ivana
AU  - Štefane, Primož
AU  - Đokić, Veljko
AU  - Rakin, Marko
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9557
AB  - Due to their excellent mechanical properties and corrosion resistance, titanium-based materials are widely represented in aeronautics, chemical industry and medicine, where they are considered the best replacement for damaged hard tissues. In order to obtain optimal properties for medical applications, commercially pure titanium (cpTi) is often alloyed. The ß-type titanium alloys containing Nb, Zr, Ta, Mo, Sn have attracted considerable attention, due to their unique combinations of high strength, low modulus of elasticity, superior corrosion resistance and biocompatibility. Also, titanium-based materials can be processed by surface modifications, including the anodization, which belongs to the group of chemical nanostructured surface modifications. Analysis of microstructure of two-phase Ti-13Nb-13Zr (TNZ) alloy was done by Scanning Electron Microscopy (SEM). Characterisation of surface, obtained by anodization in the H3PO4 + NaF solution, during 90 minutes process, was performed by SEM. Micro Tensile Specimens (MTS) were cut from TNZ and anodized TNZ disks and were subjected to the tensile test using servo-hydraulic testing machine Instron 1255. Stereometric measurement of strain at the surface of the MTS during tension was done using the Aramis system. Results showed that anodization process led to a creation of heterogeneous layer of nanotubes. Anodized TNZ alloy had lower elastic modulus and tensile strength comparing to the initial alloy. In order to better understand tensile behaviour, numerical analysis of non-anodized alloy was done. The 3D numerical model of MTS, which simulated the tensile test, was made in Abaqus software package. Good correlation between experimental and numerical results was obtained. © 2020 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (https://creativecommons.org/licenses/by-nc-nd/4.0)
T2  - Procedia Structural Integrity
T1  - Experimental and numerical analysis of tensile properties of Ti-13Nb-13Zr alloy and determination of influence of anodization process
VL  - 28
SP  - 2187
EP  - 2194
DO  - 10.1016/j.prostr.2020.11.047
ER  - 
@article{
author = "Barjaktarević, Dragana and Međo, Bojan and Gubeljak, Nenad and Cvijović-Alagić, Ivana and Štefane, Primož and Đokić, Veljko and Rakin, Marko",
year = "2020",
abstract = "Due to their excellent mechanical properties and corrosion resistance, titanium-based materials are widely represented in aeronautics, chemical industry and medicine, where they are considered the best replacement for damaged hard tissues. In order to obtain optimal properties for medical applications, commercially pure titanium (cpTi) is often alloyed. The ß-type titanium alloys containing Nb, Zr, Ta, Mo, Sn have attracted considerable attention, due to their unique combinations of high strength, low modulus of elasticity, superior corrosion resistance and biocompatibility. Also, titanium-based materials can be processed by surface modifications, including the anodization, which belongs to the group of chemical nanostructured surface modifications. Analysis of microstructure of two-phase Ti-13Nb-13Zr (TNZ) alloy was done by Scanning Electron Microscopy (SEM). Characterisation of surface, obtained by anodization in the H3PO4 + NaF solution, during 90 minutes process, was performed by SEM. Micro Tensile Specimens (MTS) were cut from TNZ and anodized TNZ disks and were subjected to the tensile test using servo-hydraulic testing machine Instron 1255. Stereometric measurement of strain at the surface of the MTS during tension was done using the Aramis system. Results showed that anodization process led to a creation of heterogeneous layer of nanotubes. Anodized TNZ alloy had lower elastic modulus and tensile strength comparing to the initial alloy. In order to better understand tensile behaviour, numerical analysis of non-anodized alloy was done. The 3D numerical model of MTS, which simulated the tensile test, was made in Abaqus software package. Good correlation between experimental and numerical results was obtained. © 2020 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (https://creativecommons.org/licenses/by-nc-nd/4.0)",
journal = "Procedia Structural Integrity",
title = "Experimental and numerical analysis of tensile properties of Ti-13Nb-13Zr alloy and determination of influence of anodization process",
volume = "28",
pages = "2187-2194",
doi = "10.1016/j.prostr.2020.11.047"
}
Barjaktarević, D., Međo, B., Gubeljak, N., Cvijović-Alagić, I., Štefane, P., Đokić, V.,& Rakin, M.. (2020). Experimental and numerical analysis of tensile properties of Ti-13Nb-13Zr alloy and determination of influence of anodization process. in Procedia Structural Integrity, 28, 2187-2194.
https://doi.org/10.1016/j.prostr.2020.11.047
Barjaktarević D, Međo B, Gubeljak N, Cvijović-Alagić I, Štefane P, Đokić V, Rakin M. Experimental and numerical analysis of tensile properties of Ti-13Nb-13Zr alloy and determination of influence of anodization process. in Procedia Structural Integrity. 2020;28:2187-2194.
doi:10.1016/j.prostr.2020.11.047 .
Barjaktarević, Dragana, Međo, Bojan, Gubeljak, Nenad, Cvijović-Alagić, Ivana, Štefane, Primož, Đokić, Veljko, Rakin, Marko, "Experimental and numerical analysis of tensile properties of Ti-13Nb-13Zr alloy and determination of influence of anodization process" in Procedia Structural Integrity, 28 (2020):2187-2194,
https://doi.org/10.1016/j.prostr.2020.11.047 . .
2
2
2

The influence of the surface nanostructured modification on the corrosion resistance of the ultrafine-grained Ti–13Nb–13Zr alloy in artificial saliva

Barjaktarević, Dragana R.; Đokić, Veljko R.; Bajat, Jelena B.; Dimić, Ivana D.; Cvijović-Alagić, Ivana; Rakin, Marko P.

(2019)

TY  - JOUR
AU  - Barjaktarević, Dragana R.
AU  - Đokić, Veljko R.
AU  - Bajat, Jelena B.
AU  - Dimić, Ivana D.
AU  - Cvijović-Alagić, Ivana
AU  - Rakin, Marko P.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8411
AB  - On the surface of the ultrafine-grained Ti–13Nb–13Zr alloy and the coarse-grained Ti–13Nb–13Zr alloy nanotubular oxide layers were formed by electrochemical anodization in the 1 M H3PO4 + NaF electrolyte in order to evaluate the electrochemical behaviour in the artificial saliva. SEM images showed that homogeneous nanotubular oxide layers could be formed by anodic oxidation of titanium alloys in an electrolyte with fluoride ions. These two titanium alloys, like other materials developed to replace the bone tissue in the human body, have to be highly corrosion resistant, which is one of the most common requirement in terms of the biocompatibility, damage and fracture prevention. The alloys were analysed by means of the electrochemical impedance spectroscopy and potentiodynamic polarization. The analyzed alloys had good corrosion stability, while nanotubular oxide layer improved their corrosion resistance. © 2019 Elsevier Ltd
T2  - Theoretical and Applied Fracture Mechanics
T1  - The influence of the surface nanostructured modification on the corrosion resistance of the ultrafine-grained Ti–13Nb–13Zr alloy in artificial saliva
VL  - 103
SP  - 102307
DO  - 10.1016/j.tafmec.2019.102307
ER  - 
@article{
author = "Barjaktarević, Dragana R. and Đokić, Veljko R. and Bajat, Jelena B. and Dimić, Ivana D. and Cvijović-Alagić, Ivana and Rakin, Marko P.",
year = "2019",
abstract = "On the surface of the ultrafine-grained Ti–13Nb–13Zr alloy and the coarse-grained Ti–13Nb–13Zr alloy nanotubular oxide layers were formed by electrochemical anodization in the 1 M H3PO4 + NaF electrolyte in order to evaluate the electrochemical behaviour in the artificial saliva. SEM images showed that homogeneous nanotubular oxide layers could be formed by anodic oxidation of titanium alloys in an electrolyte with fluoride ions. These two titanium alloys, like other materials developed to replace the bone tissue in the human body, have to be highly corrosion resistant, which is one of the most common requirement in terms of the biocompatibility, damage and fracture prevention. The alloys were analysed by means of the electrochemical impedance spectroscopy and potentiodynamic polarization. The analyzed alloys had good corrosion stability, while nanotubular oxide layer improved their corrosion resistance. © 2019 Elsevier Ltd",
journal = "Theoretical and Applied Fracture Mechanics",
title = "The influence of the surface nanostructured modification on the corrosion resistance of the ultrafine-grained Ti–13Nb–13Zr alloy in artificial saliva",
volume = "103",
pages = "102307",
doi = "10.1016/j.tafmec.2019.102307"
}
Barjaktarević, D. R., Đokić, V. R., Bajat, J. B., Dimić, I. D., Cvijović-Alagić, I.,& Rakin, M. P.. (2019). The influence of the surface nanostructured modification on the corrosion resistance of the ultrafine-grained Ti–13Nb–13Zr alloy in artificial saliva. in Theoretical and Applied Fracture Mechanics, 103, 102307.
https://doi.org/10.1016/j.tafmec.2019.102307
Barjaktarević DR, Đokić VR, Bajat JB, Dimić ID, Cvijović-Alagić I, Rakin MP. The influence of the surface nanostructured modification on the corrosion resistance of the ultrafine-grained Ti–13Nb–13Zr alloy in artificial saliva. in Theoretical and Applied Fracture Mechanics. 2019;103:102307.
doi:10.1016/j.tafmec.2019.102307 .
Barjaktarević, Dragana R., Đokić, Veljko R., Bajat, Jelena B., Dimić, Ivana D., Cvijović-Alagić, Ivana, Rakin, Marko P., "The influence of the surface nanostructured modification on the corrosion resistance of the ultrafine-grained Ti–13Nb–13Zr alloy in artificial saliva" in Theoretical and Applied Fracture Mechanics, 103 (2019):102307,
https://doi.org/10.1016/j.tafmec.2019.102307 . .
15
9
14

The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion

Barjaktarević, Dragana; Bajat, Jelena; Cvijović-Alagić, Ivana; Dimić, Ivana; Hohenwarter, Anton; Đokić, Veljko; Rakin, Marko

(2018)

TY  - JOUR
AU  - Barjaktarević, Dragana
AU  - Bajat, Jelena
AU  - Cvijović-Alagić, Ivana
AU  - Dimić, Ivana
AU  - Hohenwarter, Anton
AU  - Đokić, Veljko
AU  - Rakin, Marko
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11334
AB  - In order to optimize and enhance the implant material properties, metallic materials may be modified by severe plastic deformation (SPD) procedures. One of the most attracting SPD methods is high-pressure torsion (HPT), which is method where deformation is obtained mainly by simple shear. In the present study ultrafine-grained titanium (UFG cpTi) and ultrafine-grained Ti-13Nb-13Zr (UFG TNZ) alloy were obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm up to 5 rotations at room temperature. In order to analyse microstructure of materials before and after HPT process, scanning electron microscope (SEM) was used. The aim of this study was to determine the corrosion resistance of titanium and its alloy after HPT process. Electrochemical measurements were performed in artificial saliva with a pH value of 5.5 at 37 degrees C, in order to simulate the oral environment. The materials were analysed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. All examined materials showed good corrosion resistance, but results indicate that HPT process can improves corrosion resistance.
T2  - Procedia Structural Integrity
T1  - The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion
VL  - 13
SP  - 1834
EP  - 1839
DO  - 10.1016/j.prostr.2018.12.332
ER  - 
@article{
author = "Barjaktarević, Dragana and Bajat, Jelena and Cvijović-Alagić, Ivana and Dimić, Ivana and Hohenwarter, Anton and Đokić, Veljko and Rakin, Marko",
year = "2018",
abstract = "In order to optimize and enhance the implant material properties, metallic materials may be modified by severe plastic deformation (SPD) procedures. One of the most attracting SPD methods is high-pressure torsion (HPT), which is method where deformation is obtained mainly by simple shear. In the present study ultrafine-grained titanium (UFG cpTi) and ultrafine-grained Ti-13Nb-13Zr (UFG TNZ) alloy were obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm up to 5 rotations at room temperature. In order to analyse microstructure of materials before and after HPT process, scanning electron microscope (SEM) was used. The aim of this study was to determine the corrosion resistance of titanium and its alloy after HPT process. Electrochemical measurements were performed in artificial saliva with a pH value of 5.5 at 37 degrees C, in order to simulate the oral environment. The materials were analysed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. All examined materials showed good corrosion resistance, but results indicate that HPT process can improves corrosion resistance.",
journal = "Procedia Structural Integrity",
title = "The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion",
volume = "13",
pages = "1834-1839",
doi = "10.1016/j.prostr.2018.12.332"
}
Barjaktarević, D., Bajat, J., Cvijović-Alagić, I., Dimić, I., Hohenwarter, A., Đokić, V.,& Rakin, M.. (2018). The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion. in Procedia Structural Integrity, 13, 1834-1839.
https://doi.org/10.1016/j.prostr.2018.12.332
Barjaktarević D, Bajat J, Cvijović-Alagić I, Dimić I, Hohenwarter A, Đokić V, Rakin M. The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion. in Procedia Structural Integrity. 2018;13:1834-1839.
doi:10.1016/j.prostr.2018.12.332 .
Barjaktarević, Dragana, Bajat, Jelena, Cvijović-Alagić, Ivana, Dimić, Ivana, Hohenwarter, Anton, Đokić, Veljko, Rakin, Marko, "The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion" in Procedia Structural Integrity, 13 (2018):1834-1839,
https://doi.org/10.1016/j.prostr.2018.12.332 . .
4
3
5

The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion

Barjaktarević, Dragana R.; Bajat, Jelena B.; Cvijović-Alagić, Ivana; Dimić, Ivana; Hohenwarter, Anton; Đokić, Veljko R.; Rakin, Marko P.

(2018)

TY  - CONF
AU  - Barjaktarević, Dragana R.
AU  - Bajat, Jelena B.
AU  - Cvijović-Alagić, Ivana
AU  - Dimić, Ivana
AU  - Hohenwarter, Anton
AU  - Đokić, Veljko R.
AU  - Rakin, Marko P.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S2452321618305730
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8164
AB  - In order to optimize and enhance the implant material properties, metallic materials may be modified by severe plastic deformation (SPD) procedures. One of the most attracting SPD methods is high-pressure torsion (HPT), which is method where deformation is obtained mainly by simple shear. In the present study ultrafine-grained titanium (UFG cpTi) and ultrafine-grained Ti-13Nb-13Zr (UFG TNZ) alloy were obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm up to 5 rotations at room temperature. In order to analyse microstructure of materials before and after HPT process, scanning electron microscope (SEM) was used. The aim of this study was to determine the corrosion resistance of titanium and its alloy after HPT process. Electrochemical measurements were performed in artificial saliva with a pH value of 5.5 at 37°C, in order to simulate the oral environment. The materials were analysed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. All examined materials showed good corrosion resistance, but results indicate that HPT process can improves corrosion resistance. © 2018 The Authors.
C3  - Procedia Structural Integrity
T1  - The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion
VL  - 13
SP  - 1834
EP  - 1839
DO  - 10.1016/j.prostr.2018.12.332
ER  - 
@conference{
author = "Barjaktarević, Dragana R. and Bajat, Jelena B. and Cvijović-Alagić, Ivana and Dimić, Ivana and Hohenwarter, Anton and Đokić, Veljko R. and Rakin, Marko P.",
year = "2018",
abstract = "In order to optimize and enhance the implant material properties, metallic materials may be modified by severe plastic deformation (SPD) procedures. One of the most attracting SPD methods is high-pressure torsion (HPT), which is method where deformation is obtained mainly by simple shear. In the present study ultrafine-grained titanium (UFG cpTi) and ultrafine-grained Ti-13Nb-13Zr (UFG TNZ) alloy were obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm up to 5 rotations at room temperature. In order to analyse microstructure of materials before and after HPT process, scanning electron microscope (SEM) was used. The aim of this study was to determine the corrosion resistance of titanium and its alloy after HPT process. Electrochemical measurements were performed in artificial saliva with a pH value of 5.5 at 37°C, in order to simulate the oral environment. The materials were analysed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. All examined materials showed good corrosion resistance, but results indicate that HPT process can improves corrosion resistance. © 2018 The Authors.",
journal = "Procedia Structural Integrity",
title = "The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion",
volume = "13",
pages = "1834-1839",
doi = "10.1016/j.prostr.2018.12.332"
}
Barjaktarević, D. R., Bajat, J. B., Cvijović-Alagić, I., Dimić, I., Hohenwarter, A., Đokić, V. R.,& Rakin, M. P.. (2018). The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion. in Procedia Structural Integrity, 13, 1834-1839.
https://doi.org/10.1016/j.prostr.2018.12.332
Barjaktarević DR, Bajat JB, Cvijović-Alagić I, Dimić I, Hohenwarter A, Đokić VR, Rakin MP. The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion. in Procedia Structural Integrity. 2018;13:1834-1839.
doi:10.1016/j.prostr.2018.12.332 .
Barjaktarević, Dragana R., Bajat, Jelena B., Cvijović-Alagić, Ivana, Dimić, Ivana, Hohenwarter, Anton, Đokić, Veljko R., Rakin, Marko P., "The corrosion resistance in artificial saliva of titanium and Ti-13Nb-13Zr alloy processed by high pressure torsion" in Procedia Structural Integrity, 13 (2018):1834-1839,
https://doi.org/10.1016/j.prostr.2018.12.332 . .
4
3
5

Morphology of Nanotubular Oxide Layer Formation on Titanium and Titanium Alloy Using Electrochemical Anodization

Barjaktarević, Dragana R.; Dimić, Ivana D.; Cvijović-Alagić, Ivana; Đokić, Veljko R.; Rakin, Marko P.

(Belgrade : Serbian Academy of Sciences and Arts, 2018)

TY  - CONF
AU  - Barjaktarević, Dragana R.
AU  - Dimić, Ivana D.
AU  - Cvijović-Alagić, Ivana
AU  - Đokić, Veljko R.
AU  - Rakin, Marko P.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8736
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
T1  - Morphology of Nanotubular Oxide Layer Formation on Titanium and Titanium Alloy Using Electrochemical Anodization
SP  - 160
EP  - 162
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8736
ER  - 
@conference{
author = "Barjaktarević, Dragana R. and Dimić, Ivana D. and Cvijović-Alagić, Ivana and Đokić, Veljko R. and Rakin, Marko P.",
year = "2018",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia",
title = "Morphology of Nanotubular Oxide Layer Formation on Titanium and Titanium Alloy Using Electrochemical Anodization",
pages = "160-162",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8736"
}
Barjaktarević, D. R., Dimić, I. D., Cvijović-Alagić, I., Đokić, V. R.,& Rakin, M. P.. (2018). Morphology of Nanotubular Oxide Layer Formation on Titanium and Titanium Alloy Using Electrochemical Anodization. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
Belgrade : Serbian Academy of Sciences and Arts., 160-162.
https://hdl.handle.net/21.15107/rcub_vinar_8736
Barjaktarević DR, Dimić ID, Cvijović-Alagić I, Đokić VR, Rakin MP. Morphology of Nanotubular Oxide Layer Formation on Titanium and Titanium Alloy Using Electrochemical Anodization. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia. 2018;:160-162.
https://hdl.handle.net/21.15107/rcub_vinar_8736 .
Barjaktarević, Dragana R., Dimić, Ivana D., Cvijović-Alagić, Ivana, Đokić, Veljko R., Rakin, Marko P., "Morphology of Nanotubular Oxide Layer Formation on Titanium and Titanium Alloy Using Electrochemical Anodization" in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia (2018):160-162,
https://hdl.handle.net/21.15107/rcub_vinar_8736 .

Corrosion Resistance of High Pressure Torsion Obtained Commercially Pure Titanium in Acidic Solution

Barjaktarević, Dragana R.; Dimić, Ivana ; Cvijović-Alagić, Ivana; Veljović, Đorđe N.; Rakin, Marko P.

(2017)

TY  - JOUR
AU  - Barjaktarević, Dragana R.
AU  - Dimić, Ivana 
AU  - Cvijović-Alagić, Ivana
AU  - Veljović, Đorđe N.
AU  - Rakin, Marko P.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1854
AB  - The enhancement of commercially pure titanium (cpTi) mechanical properties, which is required for its medical application, can be achieved by grain refinement obtained by severe plastic deformation. In addition to mechanical properties improvement, excellent corrosion resistance of ultrafine-grained (UFG) cpTi in contact with human body fluids is required. Therefore, the aim of this study was to estimate electrochemical behavior of UFG cpTi obtained by high pressure torsion (HPT) under a pressure of 7,8 GPa at room temperature and up to 5 rotations. Electrochemical measurements were performed in artificial saliva at 37 degrees C in order to simulate oral environment, since development of UFG cpTi is primarily aimed for dental implant applications. Electrochemical behavior of UFG cpTi was investigated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. The obtained results indicate that HPT process, through significant grain size reduction, increases corrosion resistance of cpTi.
T2  - Tehnički vjesnik - Technical Gazette
T1  - Corrosion Resistance of High Pressure Torsion Obtained Commercially Pure Titanium in Acidic Solution
VL  - 24
IS  - 6
SP  - 1689
EP  - 1695
DO  - 10.17559/TV-20160303141534
ER  - 
@article{
author = "Barjaktarević, Dragana R. and Dimić, Ivana  and Cvijović-Alagić, Ivana and Veljović, Đorđe N. and Rakin, Marko P.",
year = "2017",
abstract = "The enhancement of commercially pure titanium (cpTi) mechanical properties, which is required for its medical application, can be achieved by grain refinement obtained by severe plastic deformation. In addition to mechanical properties improvement, excellent corrosion resistance of ultrafine-grained (UFG) cpTi in contact with human body fluids is required. Therefore, the aim of this study was to estimate electrochemical behavior of UFG cpTi obtained by high pressure torsion (HPT) under a pressure of 7,8 GPa at room temperature and up to 5 rotations. Electrochemical measurements were performed in artificial saliva at 37 degrees C in order to simulate oral environment, since development of UFG cpTi is primarily aimed for dental implant applications. Electrochemical behavior of UFG cpTi was investigated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. The obtained results indicate that HPT process, through significant grain size reduction, increases corrosion resistance of cpTi.",
journal = "Tehnički vjesnik - Technical Gazette",
title = "Corrosion Resistance of High Pressure Torsion Obtained Commercially Pure Titanium in Acidic Solution",
volume = "24",
number = "6",
pages = "1689-1695",
doi = "10.17559/TV-20160303141534"
}
Barjaktarević, D. R., Dimić, I., Cvijović-Alagić, I., Veljović, Đ. N.,& Rakin, M. P.. (2017). Corrosion Resistance of High Pressure Torsion Obtained Commercially Pure Titanium in Acidic Solution. in Tehnički vjesnik - Technical Gazette, 24(6), 1689-1695.
https://doi.org/10.17559/TV-20160303141534
Barjaktarević DR, Dimić I, Cvijović-Alagić I, Veljović ĐN, Rakin MP. Corrosion Resistance of High Pressure Torsion Obtained Commercially Pure Titanium in Acidic Solution. in Tehnički vjesnik - Technical Gazette. 2017;24(6):1689-1695.
doi:10.17559/TV-20160303141534 .
Barjaktarević, Dragana R., Dimić, Ivana , Cvijović-Alagić, Ivana, Veljović, Đorđe N., Rakin, Marko P., "Corrosion Resistance of High Pressure Torsion Obtained Commercially Pure Titanium in Acidic Solution" in Tehnički vjesnik - Technical Gazette, 24, no. 6 (2017):1689-1695,
https://doi.org/10.17559/TV-20160303141534 . .
6
3
6

Anodization of Ti-Based Materials for Biomedical Applications: a Review

Barjaktarević, Dragana R.; Cvijović-Alagić, Ivana; Dimić, Ivana; Đokić, Veljko R.; Rakin, Marko P.

(2016)

TY  - JOUR
AU  - Barjaktarević, Dragana R.
AU  - Cvijović-Alagić, Ivana
AU  - Dimić, Ivana
AU  - Đokić, Veljko R.
AU  - Rakin, Marko P.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1709
AB  - Commercially pure titanium (cpTi) and titanium alloys are the most commonly used metallic biomaterials. Biomedical requirements for the successful usage of metallic implant materials include their high mechanical strength, low elastic modulus, excellent biocompatibility and high corrosion resistance. It is evident that the response of a biomaterial implanted into the human body depends entirely on its biocompatibility and surface properties. Therefore, in order to improve the performance of biomaterials in biological systems modification of their surface is necessary. One of most commonly used method of implant materials surface modification is electrochemical anodization and this method is reviewed in the present work. Aim of the presented review article is to explain the electrochemical anodization process and the way in which the nanotubes are formed by anodization on the metallic material surface. Influence of anodizing parameters on the nanotubes characteristics, such as nanotube diameter, length and nanotubular layer thickness, are described, as well as the anodized nanotubes influence on the material surface properties, corrosion resistance and biocompatibility.
T2  - Metallurgical and Materials Engineering
T1  - Anodization of Ti-Based Materials for Biomedical Applications: a Review
VL  - 22
IS  - 3
SP  - 129
EP  - 143
DO  - 10.30544/209
UR  - https://hdl.handle.net/21.15107/rcub_vinar_1709
ER  - 
@article{
author = "Barjaktarević, Dragana R. and Cvijović-Alagić, Ivana and Dimić, Ivana and Đokić, Veljko R. and Rakin, Marko P.",
year = "2016",
abstract = "Commercially pure titanium (cpTi) and titanium alloys are the most commonly used metallic biomaterials. Biomedical requirements for the successful usage of metallic implant materials include their high mechanical strength, low elastic modulus, excellent biocompatibility and high corrosion resistance. It is evident that the response of a biomaterial implanted into the human body depends entirely on its biocompatibility and surface properties. Therefore, in order to improve the performance of biomaterials in biological systems modification of their surface is necessary. One of most commonly used method of implant materials surface modification is electrochemical anodization and this method is reviewed in the present work. Aim of the presented review article is to explain the electrochemical anodization process and the way in which the nanotubes are formed by anodization on the metallic material surface. Influence of anodizing parameters on the nanotubes characteristics, such as nanotube diameter, length and nanotubular layer thickness, are described, as well as the anodized nanotubes influence on the material surface properties, corrosion resistance and biocompatibility.",
journal = "Metallurgical and Materials Engineering",
title = "Anodization of Ti-Based Materials for Biomedical Applications: a Review",
volume = "22",
number = "3",
pages = "129-143",
doi = "10.30544/209",
url = "https://hdl.handle.net/21.15107/rcub_vinar_1709"
}
Barjaktarević, D. R., Cvijović-Alagić, I., Dimić, I., Đokić, V. R.,& Rakin, M. P.. (2016). Anodization of Ti-Based Materials for Biomedical Applications: a Review. in Metallurgical and Materials Engineering, 22(3), 129-143.
https://doi.org/10.30544/209
https://hdl.handle.net/21.15107/rcub_vinar_1709
Barjaktarević DR, Cvijović-Alagić I, Dimić I, Đokić VR, Rakin MP. Anodization of Ti-Based Materials for Biomedical Applications: a Review. in Metallurgical and Materials Engineering. 2016;22(3):129-143.
doi:10.30544/209
https://hdl.handle.net/21.15107/rcub_vinar_1709 .
Barjaktarević, Dragana R., Cvijović-Alagić, Ivana, Dimić, Ivana, Đokić, Veljko R., Rakin, Marko P., "Anodization of Ti-Based Materials for Biomedical Applications: a Review" in Metallurgical and Materials Engineering, 22, no. 3 (2016):129-143,
https://doi.org/10.30544/209 .,
https://hdl.handle.net/21.15107/rcub_vinar_1709 .
8