Dinić, Ivana

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orcid::0000-0002-0909-8230
  • Dinić, Ivana (8)
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Author's Bibliography

Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals

Dinić, Ivana; Vuković, Marina; Rabanal, Maria Eugenia; Milošević, Milica; Bukumira, Marta; Tomić, Nina; Tomić, Miloš; Mančić, Lidija; Ignjatović, Nenad

(2024)

TY  - JOUR
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Milica
AU  - Bukumira, Marta
AU  - Tomić, Nina
AU  - Tomić, Miloš
AU  - Mančić, Lidija
AU  - Ignjatović, Nenad
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12299
AB  - Y0.8−xGdxF3 :Yb/Er mesocrystals with a biocompatible surface and diverse morphological characteristics were successfully synthesized using chitosan-assisted solvothermal processing. Their structural properties, studied using X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy and energy dispersive X-ray analysis, were further correlated with the up-conversion emission (λexc = 976 nm) recorded in function of temperature. Based on the change in the visible green emissions originating from the thermally coupled 2H11/2 and 4S3/2 levels of Er3+, the corresponding LIR was acquired in the physiologically relevant range of temperatures (25–50 ◦C). The detected absolute sensitivity of about 0.0042 ◦C −1 , along with the low cytotoxicity toward both normal human lung fibroblasts (MRC-5) and cancerous lung epithelial (A549) cells, indicate a potential for use in temperature sensing in biomedicine. Additionally, their enhanced internalization in cells, without suppression of cell viability, enabled in vitro labeling of cancer and healthy cells upon 976 nm laser irradiation.
T2  - Journal of Functional Biomaterials
T1  - Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals
VL  - 15
IS  - 1
SP  - 6
DO  - 10.3390/jfb15010006
ER  - 
@article{
author = "Dinić, Ivana and Vuković, Marina and Rabanal, Maria Eugenia and Milošević, Milica and Bukumira, Marta and Tomić, Nina and Tomić, Miloš and Mančić, Lidija and Ignjatović, Nenad",
year = "2024",
abstract = "Y0.8−xGdxF3 :Yb/Er mesocrystals with a biocompatible surface and diverse morphological characteristics were successfully synthesized using chitosan-assisted solvothermal processing. Their structural properties, studied using X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy and energy dispersive X-ray analysis, were further correlated with the up-conversion emission (λexc = 976 nm) recorded in function of temperature. Based on the change in the visible green emissions originating from the thermally coupled 2H11/2 and 4S3/2 levels of Er3+, the corresponding LIR was acquired in the physiologically relevant range of temperatures (25–50 ◦C). The detected absolute sensitivity of about 0.0042 ◦C −1 , along with the low cytotoxicity toward both normal human lung fibroblasts (MRC-5) and cancerous lung epithelial (A549) cells, indicate a potential for use in temperature sensing in biomedicine. Additionally, their enhanced internalization in cells, without suppression of cell viability, enabled in vitro labeling of cancer and healthy cells upon 976 nm laser irradiation.",
journal = "Journal of Functional Biomaterials",
title = "Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals",
volume = "15",
number = "1",
pages = "6",
doi = "10.3390/jfb15010006"
}
Dinić, I., Vuković, M., Rabanal, M. E., Milošević, M., Bukumira, M., Tomić, N., Tomić, M., Mančić, L.,& Ignjatović, N.. (2024). Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals. in Journal of Functional Biomaterials, 15(1), 6.
https://doi.org/10.3390/jfb15010006
Dinić I, Vuković M, Rabanal ME, Milošević M, Bukumira M, Tomić N, Tomić M, Mančić L, Ignjatović N. Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals. in Journal of Functional Biomaterials. 2024;15(1):6.
doi:10.3390/jfb15010006 .
Dinić, Ivana, Vuković, Marina, Rabanal, Maria Eugenia, Milošević, Milica, Bukumira, Marta, Tomić, Nina, Tomić, Miloš, Mančić, Lidija, Ignjatović, Nenad, "Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals" in Journal of Functional Biomaterials, 15, no. 1 (2024):6,
https://doi.org/10.3390/jfb15010006 . .

Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion

Stamenković, Tijana; Radmilović, Nadežda; Prekajski-Đorđević, Marija D.; Rabasović, Mihailo; Dinić, Ivana; Tomić, Miloš; Lojpur, Vesna; Mančić, Lidija

(2023)

TY  - JOUR
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Prekajski-Đorđević, Marija D.
AU  - Rabasović, Mihailo
AU  - Dinić, Ivana
AU  - Tomić, Miloš
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10499
AB  - Nanopowders of up-conversion SrGd2O4 orthorhombic (Pnma) phase co-doped with different Yb3+ (1, 2.5 and 5 at%) and constant Er3+ (0.5 at%) ions were successfully prepared via sol-gel assisted combustion. Rietveld refinement indicated unit cell lattice parameters increase with Yb3+ and Er3+ ions doping. Scanning transmission electron microscopy with corresponding energy-dispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the up-conversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum yield of 0.055% is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc = 976 nm, power density 200 W/cm2).
T2  - Journal of Luminescence
T1  - Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion
VL  - 253
SP  - 119491
DO  - 10.1016/j.jlumin.2022.119491
ER  - 
@article{
author = "Stamenković, Tijana and Radmilović, Nadežda and Prekajski-Đorđević, Marija D. and Rabasović, Mihailo and Dinić, Ivana and Tomić, Miloš and Lojpur, Vesna and Mančić, Lidija",
year = "2023",
abstract = "Nanopowders of up-conversion SrGd2O4 orthorhombic (Pnma) phase co-doped with different Yb3+ (1, 2.5 and 5 at%) and constant Er3+ (0.5 at%) ions were successfully prepared via sol-gel assisted combustion. Rietveld refinement indicated unit cell lattice parameters increase with Yb3+ and Er3+ ions doping. Scanning transmission electron microscopy with corresponding energy-dispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the up-conversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum yield of 0.055% is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc = 976 nm, power density 200 W/cm2).",
journal = "Journal of Luminescence",
title = "Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion",
volume = "253",
pages = "119491",
doi = "10.1016/j.jlumin.2022.119491"
}
Stamenković, T., Radmilović, N., Prekajski-Đorđević, M. D., Rabasović, M., Dinić, I., Tomić, M., Lojpur, V.,& Mančić, L.. (2023). Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion. in Journal of Luminescence, 253, 119491.
https://doi.org/10.1016/j.jlumin.2022.119491
Stamenković T, Radmilović N, Prekajski-Đorđević MD, Rabasović M, Dinić I, Tomić M, Lojpur V, Mančić L. Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion. in Journal of Luminescence. 2023;253:119491.
doi:10.1016/j.jlumin.2022.119491 .
Stamenković, Tijana, Radmilović, Nadežda, Prekajski-Đorđević, Marija D., Rabasović, Mihailo, Dinić, Ivana, Tomić, Miloš, Lojpur, Vesna, Mančić, Lidija, "Quantum yield and energy transfer in up-conversion SrGd2O4:Yb, Er nanoparticles obtained via sol-gel assisted combustion" in Journal of Luminescence, 253 (2023):119491,
https://doi.org/10.1016/j.jlumin.2022.119491 . .
4
3

Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles

Stamenković, Tijana; Radmilović, Nadežda; Dinić, Ivana; Vuković, Marina; Barudžija, Tanja; Čebela, Maria; Lojpur, Vesna

(Belgrade : Institute for Multidisciplinary Research, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Barudžija, Tanja
AU  - Čebela, Maria
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11483
AB  - In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles
SP  - 113
EP  - 114
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11483
ER  - 
@conference{
author = "Stamenković, Tijana and Radmilović, Nadežda and Dinić, Ivana and Vuković, Marina and Barudžija, Tanja and Čebela, Maria and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles",
pages = "113-114",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11483"
}
Stamenković, T., Radmilović, N., Dinić, I., Vuković, M., Barudžija, T., Čebela, M.,& Lojpur, V.. (2023). Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 113-114.
https://hdl.handle.net/21.15107/rcub_vinar_11483
Stamenković T, Radmilović N, Dinić I, Vuković M, Barudžija T, Čebela M, Lojpur V. Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;:113-114.
https://hdl.handle.net/21.15107/rcub_vinar_11483 .
Stamenković, Tijana, Radmilović, Nadežda, Dinić, Ivana, Vuković, Marina, Barudžija, Tanja, Čebela, Maria, Lojpur, Vesna, "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023):113-114,
https://hdl.handle.net/21.15107/rcub_vinar_11483 .

Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus

Stamenković, Tijana; Ranđelović, Marjan; Čebela, Maria; Vuković, Marina; Dinić, Ivana; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Institute for Multidisciplinary Research, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Ranđelović, Marjan
AU  - Čebela, Maria
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11484
AB  - The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus
SP  - 107
EP  - 107
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11484
ER  - 
@conference{
author = "Stamenković, Tijana and Ranđelović, Marjan and Čebela, Maria and Vuković, Marina and Dinić, Ivana and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus",
pages = "107-107",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11484"
}
Stamenković, T., Ranđelović, M., Čebela, M., Vuković, M., Dinić, I., Mančić, L.,& Lojpur, V.. (2023). Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 107-107.
https://hdl.handle.net/21.15107/rcub_vinar_11484
Stamenković T, Ranđelović M, Čebela M, Vuković M, Dinić I, Mančić L, Lojpur V. Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;:107-107.
https://hdl.handle.net/21.15107/rcub_vinar_11484 .
Stamenković, Tijana, Ranđelović, Marjan, Čebela, Maria, Vuković, Marina, Dinić, Ivana, Mančić, Lidija, Lojpur, Vesna, "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023):107-107,
https://hdl.handle.net/21.15107/rcub_vinar_11484 .

Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase

Stamenković, Tijana; Dinić, Ivana; Vuković, Marina; Radmilović, Nadežda; Barudžija, Tanja; Tomić, Miloš; Mančić, Lidija; Lojpur, Vesna

(2023)

TY  - JOUR
AU  - Stamenković, Tijana
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Radmilović, Nadežda
AU  - Barudžija, Tanja
AU  - Tomić, Miloš
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11579
AB  - In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation.
T2  - Ceramics International
T1  - Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase
DO  - 10.1016/j.ceramint.2023.09.103
ER  - 
@article{
author = "Stamenković, Tijana and Dinić, Ivana and Vuković, Marina and Radmilović, Nadežda and Barudžija, Tanja and Tomić, Miloš and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation.",
journal = "Ceramics International",
title = "Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase",
doi = "10.1016/j.ceramint.2023.09.103"
}
Stamenković, T., Dinić, I., Vuković, M., Radmilović, N., Barudžija, T., Tomić, M., Mančić, L.,& Lojpur, V.. (2023). Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase. in Ceramics International.
https://doi.org/10.1016/j.ceramint.2023.09.103
Stamenković T, Dinić I, Vuković M, Radmilović N, Barudžija T, Tomić M, Mančić L, Lojpur V. Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase. in Ceramics International. 2023;.
doi:10.1016/j.ceramint.2023.09.103 .
Stamenković, Tijana, Dinić, Ivana, Vuković, Marina, Radmilović, Nadežda, Barudžija, Tanja, Tomić, Miloš, Mančić, Lidija, Lojpur, Vesna, "Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase" in Ceramics International (2023),
https://doi.org/10.1016/j.ceramint.2023.09.103 . .

Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material

Stamenković, Tijana; Ranđelović, Marjan; Dinić, Ivana; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Institute of Technical Sciences of SASA, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Ranđelović, Marjan
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12318
AB  - In this work we present new up-conversion materials, consisted of SrGd2O4 doped with different concentration of Yb3+ (2, 4, 6 at%) ions and constant concentration of Tm3+ (1 at%), prepared by the combustion method. X-ray powder diffraction (XRPD) showed that assynthesized nanoparticles have orthorhombic structure (Pnma), assigned to the JCPDS Card No:01-072-6387. Scanning electron microscopy (SEM) revealed that obtained nanostructure is composed of porous agglomerated nanoparticles, while energy dispersive spectroscopy (EDS) confirmed presence and uniform distribution of all constituting elements accross the sample. Luminescent properties were evaluated and discovered two blue emission bands at 450 nm and 474 nm, and one red emission band at 650 nm. The sample co-doped with 4 at% Tm3+ showed the most intense photoluminescent emission, and because of that was used in the photocatalytic exiperiment. UV-VIS Diffuse Reflectance Spectroscopy was performed in order to examine materials bandgap, and value of 4.3 eV was obtained as well as the additional values from the bands at lower energies, which indicate potentially good photocatalytic properties. X-ray photoelectron spectroscopy (XPS) revealed presence of OHgroups on the surface which also have positive impact on the photocatalytic performances of the material. UV-VIS Absorption Spectroscopy was used to measure changes of the methylene blue concentration during the photocatalytic degradation process. After 4 h of exposure to the simulating Sun irradiation, the results indicate successful dye decomposition rate. Reaction parameters (MB concentration and catalyst mass) were altered in order to achieve the best photocatalytic performances of this newly synthesized materials.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material
SP  - 45
EP  - 45
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12318
ER  - 
@conference{
author = "Stamenković, Tijana and Ranđelović, Marjan and Dinić, Ivana and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "In this work we present new up-conversion materials, consisted of SrGd2O4 doped with different concentration of Yb3+ (2, 4, 6 at%) ions and constant concentration of Tm3+ (1 at%), prepared by the combustion method. X-ray powder diffraction (XRPD) showed that assynthesized nanoparticles have orthorhombic structure (Pnma), assigned to the JCPDS Card No:01-072-6387. Scanning electron microscopy (SEM) revealed that obtained nanostructure is composed of porous agglomerated nanoparticles, while energy dispersive spectroscopy (EDS) confirmed presence and uniform distribution of all constituting elements accross the sample. Luminescent properties were evaluated and discovered two blue emission bands at 450 nm and 474 nm, and one red emission band at 650 nm. The sample co-doped with 4 at% Tm3+ showed the most intense photoluminescent emission, and because of that was used in the photocatalytic exiperiment. UV-VIS Diffuse Reflectance Spectroscopy was performed in order to examine materials bandgap, and value of 4.3 eV was obtained as well as the additional values from the bands at lower energies, which indicate potentially good photocatalytic properties. X-ray photoelectron spectroscopy (XPS) revealed presence of OHgroups on the surface which also have positive impact on the photocatalytic performances of the material. UV-VIS Absorption Spectroscopy was used to measure changes of the methylene blue concentration during the photocatalytic degradation process. After 4 h of exposure to the simulating Sun irradiation, the results indicate successful dye decomposition rate. Reaction parameters (MB concentration and catalyst mass) were altered in order to achieve the best photocatalytic performances of this newly synthesized materials.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material",
pages = "45-45",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12318"
}
Stamenković, T., Ranđelović, M., Dinić, I., Mančić, L.,& Lojpur, V.. (2023). Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 45-45.
https://hdl.handle.net/21.15107/rcub_vinar_12318
Stamenković T, Ranđelović M, Dinić I, Mančić L, Lojpur V. Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:45-45.
https://hdl.handle.net/21.15107/rcub_vinar_12318 .
Stamenković, Tijana, Ranđelović, Marjan, Dinić, Ivana, Mančić, Lidija, Lojpur, Vesna, "Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):45-45,
https://hdl.handle.net/21.15107/rcub_vinar_12318 .

Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles

Dinić, Ivana; Stamenković, Tijana; Radmilović, Nadežda; Vuković, Marina; Rabasović, Mihailo; Lojpur, Vesna; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2022)

TY  - CONF
AU  - Dinić, Ivana
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Vuković, Marina
AU  - Rabasović, Mihailo
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10794
AB  - Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm ( 2 H11/2, 4 S3/2 → 4 I15/2) as well as a red emission at 661 nm (4 F9/2 → 4 I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2 ).
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade
T1  - Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles
SP  - 59
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10794
ER  - 
@conference{
author = "Dinić, Ivana and Stamenković, Tijana and Radmilović, Nadežda and Vuković, Marina and Rabasović, Mihailo and Lojpur, Vesna and Mančić, Lidija",
year = "2022",
abstract = "Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm ( 2 H11/2, 4 S3/2 → 4 I15/2) as well as a red emission at 661 nm (4 F9/2 → 4 I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2 ).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade",
title = "Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles",
pages = "59",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10794"
}
Dinić, I., Stamenković, T., Radmilović, N., Vuković, M., Rabasović, M., Lojpur, V.,& Mančić, L.. (2022). Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles. in Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade
Belgrade : Serbian Ceramic Society., 59.
https://hdl.handle.net/21.15107/rcub_vinar_10794
Dinić I, Stamenković T, Radmilović N, Vuković M, Rabasović M, Lojpur V, Mančić L. Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles. in Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade. 2022;:59.
https://hdl.handle.net/21.15107/rcub_vinar_10794 .
Dinić, Ivana, Stamenković, Tijana, Radmilović, Nadežda, Vuković, Marina, Rabasović, Mihailo, Lojpur, Vesna, Mančić, Lidija, "Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles" in Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade (2022):59,
https://hdl.handle.net/21.15107/rcub_vinar_10794 .

Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping

Stamenković, Tijana; Lojpur, Vesna; Radmilović, Nadežda; Vuković, Marina; Dinić, Ivana; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2022)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Lojpur, Vesna
AU  - Radmilović, Nadežda
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Mančić, Lidija
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10807
AB  - Optically active materials have a wide range of applications. The phenomenon of light conversion includes two main types: up-conversion, which is the ability of convertion lower energy photons into the ones with the higher energy, and down-conversion, which is vice versa. Orthorhorhombic SrGd2O4 doped with rare earth elements is established to have promising optical characteristics, but rarely explored until nowadays as up-converting material. Due to the phonon energy of around 475 cm-1, which is lower than in many other compounds commonly used hosts, this one has a great perspective as an optically active material. Here, for the first time two combinations of rare earth dopant ions, Yb3+/Ho3+ and Yb3+/Tm3+, with different mutual ratios were chosen as pairs for inducing up-conversion. Sol-gel assisted combustion synthesis, which comprises citric acid as chelator and glycine as fuel, was used to obtain powdered samples that are subsequently thermally treated for 3.5 h at 1100°C. X-ray powder diffraction analysis (XRPD) was performed to determine crystal structure. Morphology characteristics were observed by scanning and transmission electron microscopy (SEM/TEM). Photoluminescent up-converting properties were measured in function of laser power (976 nm) in order to define optimal doping concentration and upconversion mechanism.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade
T1  - Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping
SP  - 76
EP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10807
ER  - 
@conference{
author = "Stamenković, Tijana and Lojpur, Vesna and Radmilović, Nadežda and Vuković, Marina and Dinić, Ivana and Mančić, Lidija",
year = "2022",
abstract = "Optically active materials have a wide range of applications. The phenomenon of light conversion includes two main types: up-conversion, which is the ability of convertion lower energy photons into the ones with the higher energy, and down-conversion, which is vice versa. Orthorhorhombic SrGd2O4 doped with rare earth elements is established to have promising optical characteristics, but rarely explored until nowadays as up-converting material. Due to the phonon energy of around 475 cm-1, which is lower than in many other compounds commonly used hosts, this one has a great perspective as an optically active material. Here, for the first time two combinations of rare earth dopant ions, Yb3+/Ho3+ and Yb3+/Tm3+, with different mutual ratios were chosen as pairs for inducing up-conversion. Sol-gel assisted combustion synthesis, which comprises citric acid as chelator and glycine as fuel, was used to obtain powdered samples that are subsequently thermally treated for 3.5 h at 1100°C. X-ray powder diffraction analysis (XRPD) was performed to determine crystal structure. Morphology characteristics were observed by scanning and transmission electron microscopy (SEM/TEM). Photoluminescent up-converting properties were measured in function of laser power (976 nm) in order to define optimal doping concentration and upconversion mechanism.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade",
title = "Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping",
pages = "76-77",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10807"
}
Stamenković, T., Lojpur, V., Radmilović, N., Vuković, M., Dinić, I.,& Mančić, L.. (2022). Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping. in Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade
Belgrade : Serbian Ceramic Society., 76-77.
https://hdl.handle.net/21.15107/rcub_vinar_10807
Stamenković T, Lojpur V, Radmilović N, Vuković M, Dinić I, Mančić L. Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping. in Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade. 2022;:76-77.
https://hdl.handle.net/21.15107/rcub_vinar_10807 .
Stamenković, Tijana, Lojpur, Vesna, Radmilović, Nadežda, Vuković, Marina, Dinić, Ivana, Mančić, Lidija, "Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping" in Advanced Ceramics and Application : 10th Serbian Ceramic Society Conference : program and the book of abstracts; September 26-27, 2022; Belgrade (2022):76-77,
https://hdl.handle.net/21.15107/rcub_vinar_10807 .