Antonijević-Nikolić, Mirjana

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  • Antonijević-Nikolić, Mirjana (1)
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Thermal stability of new Copper(II) cyclam complex with aminocarboxylate Co-ligand

Antonijević-Nikolić, Mirjana; Marinović-Cincović, Milena; Tanasković, Slađana; Dražić, Branka

(University in Banjaluka : Faculty of Technology, 2022)

TY  - CONF
AU  - Antonijević-Nikolić, Mirjana
AU  - Marinović-Cincović, Milena
AU  - Tanasković, Slađana
AU  - Dražić, Branka
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11665
AB  - The aim of this study was to investigate thermal behavior of the new complex with formula [Cu(ala)cyc](ClO4)2∙2.5H2O. The complex was isolated and previously characterized by: elemental analysis (C, H, N), molar conductivity, UV/Vis and FTIR spectroscopy and magnetic measurements at room temperature. The sixcoordinate octahedral geometry around Cu(II) complexes was proposed. The experimental data suggested that the tetradentate ligand cyclam was coordinated to metals through four N donors and the amino carboxylate ligand coordinated via carboxylate ion. Investigate of thermal stability can be crucial in confirming the structure as well as in assessing the applicability of new compounds. The thermal properties of these complex have been investigated by thermogravimetric (TG) and differential thermal analysis (DTA). Therefore, TG-DTA analysis indicates that investigated complex decomposes exothermally in a single step in the range of 310 - 400 °C.
PB  - University in Banjaluka : Faculty of Technology
C3  - 14th Conference of chemists, technologists and environmentalists of Republic of Srpska : the book of abstracts; Oct 21-22, Banja Luka, Republic of Srpska
T1  - Thermal stability of new Copper(II) cyclam complex with
aminocarboxylate Co-ligand
SP  - 25
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11665
ER  - 
@conference{
author = "Antonijević-Nikolić, Mirjana and Marinović-Cincović, Milena and Tanasković, Slađana and Dražić, Branka",
year = "2022",
abstract = "The aim of this study was to investigate thermal behavior of the new complex with formula [Cu(ala)cyc](ClO4)2∙2.5H2O. The complex was isolated and previously characterized by: elemental analysis (C, H, N), molar conductivity, UV/Vis and FTIR spectroscopy and magnetic measurements at room temperature. The sixcoordinate octahedral geometry around Cu(II) complexes was proposed. The experimental data suggested that the tetradentate ligand cyclam was coordinated to metals through four N donors and the amino carboxylate ligand coordinated via carboxylate ion. Investigate of thermal stability can be crucial in confirming the structure as well as in assessing the applicability of new compounds. The thermal properties of these complex have been investigated by thermogravimetric (TG) and differential thermal analysis (DTA). Therefore, TG-DTA analysis indicates that investigated complex decomposes exothermally in a single step in the range of 310 - 400 °C.",
publisher = "University in Banjaluka : Faculty of Technology",
journal = "14th Conference of chemists, technologists and environmentalists of Republic of Srpska : the book of abstracts; Oct 21-22, Banja Luka, Republic of Srpska",
title = "Thermal stability of new Copper(II) cyclam complex with
aminocarboxylate Co-ligand",
pages = "25",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11665"
}
Antonijević-Nikolić, M., Marinović-Cincović, M., Tanasković, S.,& Dražić, B.. (2022). Thermal stability of new Copper(II) cyclam complex with
aminocarboxylate Co-ligand. in 14th Conference of chemists, technologists and environmentalists of Republic of Srpska : the book of abstracts; Oct 21-22, Banja Luka, Republic of Srpska
University in Banjaluka : Faculty of Technology., 25.
https://hdl.handle.net/21.15107/rcub_vinar_11665
Antonijević-Nikolić M, Marinović-Cincović M, Tanasković S, Dražić B. Thermal stability of new Copper(II) cyclam complex with
aminocarboxylate Co-ligand. in 14th Conference of chemists, technologists and environmentalists of Republic of Srpska : the book of abstracts; Oct 21-22, Banja Luka, Republic of Srpska. 2022;:25.
https://hdl.handle.net/21.15107/rcub_vinar_11665 .
Antonijević-Nikolić, Mirjana, Marinović-Cincović, Milena, Tanasković, Slađana, Dražić, Branka, "Thermal stability of new Copper(II) cyclam complex with
aminocarboxylate Co-ligand" in 14th Conference of chemists, technologists and environmentalists of Republic of Srpska : the book of abstracts; Oct 21-22, Banja Luka, Republic of Srpska (2022):25,
https://hdl.handle.net/21.15107/rcub_vinar_11665 .