TY  - JOUR
AU  - Milićević, Jelena S.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Zarubica, Aleksandra R.
AU  - Mofarah, Sajjad S.
AU  - Matović, Branko
AU  - Sorrel, Charles C.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9068
AB  - A glassy carbon electrode was functionalized by MoO2 nanoparticle–decorated multiwalled carbon nanotubes (MWCNTs) and examined as a working electrode in oxyfluorfen (OXY) detection by differential pulse stripping voltammetry (DPSV). Measurement parameters were as follows: initial potential − 0.1 V, end potential + 0.5 V, accumulation potential − 0.15 V, accumulation time 80 s, and scan rate 50 mV s−1. A stripping potential of + 0.315 V vs. Ag/AgCl was employed. The pPesticide oxyfluorfen was determined in model samples by DPSV with good reproducibility (RSD <2.4%) in the concentration range 2.5 to 34.5 ng mL−1, with r = 0.99 and a limit of detection of 1.5 ng mL−1. These results are in the same range as those of HPLC/DAD, which is used as the comparative method. Recovery for OXY determination in a real river water sample was 102%. Analyses in Briton-Robinson buffer has shown to be pH dependent with the best response at pH 6.0. Structural characterization of MoO2-MWCNT by Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray crystallography revealed a preserved MWCNT structure decorated with firmly attached clusters of MoO2 nanoparticles.
T2  - Microchimica Acta
T1  - Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen
VL  - 187
IS  - 8
SP  - 429
DO  - 10.1007/s00604-020-04406-4
ER  - 

@article{
author = "Milićević, Jelena S. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Zarubica, Aleksandra R. and Mofarah, Sajjad S. and Matović, Branko and Sorrel, Charles C.",
year = "2020",
abstract = "A glassy carbon electrode was functionalized by MoO2 nanoparticle–decorated multiwalled carbon nanotubes (MWCNTs) and examined as a working electrode in oxyfluorfen (OXY) detection by differential pulse stripping voltammetry (DPSV). Measurement parameters were as follows: initial potential − 0.1 V, end potential + 0.5 V, accumulation potential − 0.15 V, accumulation time 80 s, and scan rate 50 mV s−1. A stripping potential of + 0.315 V vs. Ag/AgCl was employed. The pPesticide oxyfluorfen was determined in model samples by DPSV with good reproducibility (RSD <2.4%) in the concentration range 2.5 to 34.5 ng mL−1, with r = 0.99 and a limit of detection of 1.5 ng mL−1. These results are in the same range as those of HPLC/DAD, which is used as the comparative method. Recovery for OXY determination in a real river water sample was 102%. Analyses in Briton-Robinson buffer has shown to be pH dependent with the best response at pH 6.0. Structural characterization of MoO2-MWCNT by Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray crystallography revealed a preserved MWCNT structure decorated with firmly attached clusters of MoO2 nanoparticles.",
journal = "Microchimica Acta",
title = "Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen",
volume = "187",
number = "8",
pages = "429",
doi = "10.1007/s00604-020-04406-4"
}

Milićević, J. S., Ranđelović, M. S., Momčilović, M. Z., Zarubica, A. R., Mofarah, S. S., Matović, B.,& Sorrel, C. C.. (2020). Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen. in Microchimica Acta, 187(8), 429.
https://doi.org/10.1007/s00604-020-04406-4

Milićević JS, Ranđelović MS, Momčilović MZ, Zarubica AR, Mofarah SS, Matović B, Sorrel CC. Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen. in Microchimica Acta. 2020;187(8):429.
doi:10.1007/s00604-020-04406-4 .

Milićević, Jelena S., Ranđelović, Marjan S., Momčilović, Milan Z., Zarubica, Aleksandra R., Mofarah, Sajjad S., Matović, Branko, Sorrel, Charles C., "Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen" in Microchimica Acta, 187, no. 8 (2020):429,
https://doi.org/10.1007/s00604-020-04406-4 . .

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Milićević, Jelena S.
AU  - Đurović-Pejčev, Rada
AU  - Mofarah, Sajjad S.
AU  - Sorrel, Charles C.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8619
AB  - Novel electrochemical sensor based on Pt supported multiwalled carbon nanotubes is used for determination of pesticide clomazone in aqueous media via differential pulse stripping voltammetry (DPSV). Since clomazone is stable and readily soluble in water, it is often found in water sources. Hence, its determination in the environment is of utmost importance. Herein, clomazone is determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range of 0.61–20.56 ng cm−3, with LOQ = 0.61 and LOD = 0.38. These results are in the same range with HPLC/DAD, which is used as comparative method. It is shown that DPSV is a facile and efficient way for determination of clomazone in contrast to precise but field-impractical HPLC. Mechanistic approach in explaining electrode processes is correlated to structural aspects of the synthesized sensor. HRTEM data reveals a uniform distribution of Pt nanoparticles on the MWCNT support as a source of crucial, structural and electronic changes. Furthermore, characterisation of Raman results indicates the existence of structural defects, which is believed to be the leading reason for improvement in sensing response. © 2019 Taiwan Institute of Chemical Engineers
T2  - Journal of the Taiwan Institute of Chemical Engineers
T1  - Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples
VL  - 105
SP  - 115
EP  - 123
DO  - 10.1016/j.jtice.2019.10.013
ER  - 

@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Milićević, Jelena S. and Đurović-Pejčev, Rada and Mofarah, Sajjad S. and Sorrel, Charles C.",
year = "2019",
abstract = "Novel electrochemical sensor based on Pt supported multiwalled carbon nanotubes is used for determination of pesticide clomazone in aqueous media via differential pulse stripping voltammetry (DPSV). Since clomazone is stable and readily soluble in water, it is often found in water sources. Hence, its determination in the environment is of utmost importance. Herein, clomazone is determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range of 0.61–20.56 ng cm−3, with LOQ = 0.61 and LOD = 0.38. These results are in the same range with HPLC/DAD, which is used as comparative method. It is shown that DPSV is a facile and efficient way for determination of clomazone in contrast to precise but field-impractical HPLC. Mechanistic approach in explaining electrode processes is correlated to structural aspects of the synthesized sensor. HRTEM data reveals a uniform distribution of Pt nanoparticles on the MWCNT support as a source of crucial, structural and electronic changes. Furthermore, characterisation of Raman results indicates the existence of structural defects, which is believed to be the leading reason for improvement in sensing response. © 2019 Taiwan Institute of Chemical Engineers",
journal = "Journal of the Taiwan Institute of Chemical Engineers",
title = "Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples",
volume = "105",
pages = "115-123",
doi = "10.1016/j.jtice.2019.10.013"
}

Ranđelović, M. S., Momčilović, M. Z., Milićević, J. S., Đurović-Pejčev, R., Mofarah, S. S.,& Sorrel, C. C.. (2019). Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples. in Journal of the Taiwan Institute of Chemical Engineers, 105, 115-123.
https://doi.org/10.1016/j.jtice.2019.10.013

Ranđelović MS, Momčilović MZ, Milićević JS, Đurović-Pejčev R, Mofarah SS, Sorrel CC. Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples. in Journal of the Taiwan Institute of Chemical Engineers. 2019;105:115-123.
doi:10.1016/j.jtice.2019.10.013 .

Ranđelović, Marjan S., Momčilović, Milan Z., Milićević, Jelena S., Đurović-Pejčev, Rada, Mofarah, Sajjad S., Sorrel, Charles C., "Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples" in Journal of the Taiwan Institute of Chemical Engineers, 105 (2019):115-123,
https://doi.org/10.1016/j.jtice.2019.10.013 . .