Petrović, Marija S.

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Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study

Kojić, Marija; Petrović, Jelena T.; Petrović, Marija S.; Stanković, Slavka M.; Porobić, Slavica; Marinović-Cincović, Milena; Mihajlović, Marija

(2021)

TY  - JOUR
AU  - Kojić, Marija
AU  - Petrović, Jelena T.
AU  - Petrović, Marija S.
AU  - Stanković, Slavka M.
AU  - Porobić, Slavica
AU  - Marinović-Cincović, Milena
AU  - Mihajlović, Marija
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9625
AB  - Hydrothermal carbonization (HTC) was employed for the conversion of the spent mushroom substrate (SMS) into a carbonaceous hydrochar. The effect of operating temperature (180, 200, 220, 240, and 260 °C) on the physicochemical, structural, and combustion properties of the obtained hydrochars was analyzed. The HTC treatment caused the increase of the higher heating value (HHV) and the lower heating value (LHV) of hydrochars for 58 % and 65 % in comparison with SMS, respectively. Analysis of morphology and functional groups showed the formation of microspheres and cracks on the hydrochar surface, which are predominantly dominated by aromatic and oxygen-rich functional groups. Thermal and kinetics analysis showed that HTC treatment improves the combustion behavior of the obtained solids. Combustion kinetic parameters of SMS and hydrochars were determined by the methods of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The thermodynamic parameters and pre-exponential factors reveal a complex mechanism of SMS and hydrochars decomposition process. © 2021 Elsevier B.V.
T2  - Journal of Analytical and Applied Pyrolysis
T1  - Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study
VL  - 155
SP  - 105028
DO  - 10.1016/j.jaap.2021.105028
ER  - 
@article{
author = "Kojić, Marija and Petrović, Jelena T. and Petrović, Marija S. and Stanković, Slavka M. and Porobić, Slavica and Marinović-Cincović, Milena and Mihajlović, Marija",
year = "2021",
abstract = "Hydrothermal carbonization (HTC) was employed for the conversion of the spent mushroom substrate (SMS) into a carbonaceous hydrochar. The effect of operating temperature (180, 200, 220, 240, and 260 °C) on the physicochemical, structural, and combustion properties of the obtained hydrochars was analyzed. The HTC treatment caused the increase of the higher heating value (HHV) and the lower heating value (LHV) of hydrochars for 58 % and 65 % in comparison with SMS, respectively. Analysis of morphology and functional groups showed the formation of microspheres and cracks on the hydrochar surface, which are predominantly dominated by aromatic and oxygen-rich functional groups. Thermal and kinetics analysis showed that HTC treatment improves the combustion behavior of the obtained solids. Combustion kinetic parameters of SMS and hydrochars were determined by the methods of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The thermodynamic parameters and pre-exponential factors reveal a complex mechanism of SMS and hydrochars decomposition process. © 2021 Elsevier B.V.",
journal = "Journal of Analytical and Applied Pyrolysis",
title = "Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study",
volume = "155",
pages = "105028",
doi = "10.1016/j.jaap.2021.105028"
}
Kojić, M., Petrović, J. T., Petrović, M. S., Stanković, S. M., Porobić, S., Marinović-Cincović, M.,& Mihajlović, M.. (2021). Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study. in Journal of Analytical and Applied Pyrolysis, 155, 105028.
https://doi.org/10.1016/j.jaap.2021.105028
Kojić M, Petrović JT, Petrović MS, Stanković SM, Porobić S, Marinović-Cincović M, Mihajlović M. Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study. in Journal of Analytical and Applied Pyrolysis. 2021;155:105028.
doi:10.1016/j.jaap.2021.105028 .
Kojić, Marija, Petrović, Jelena T., Petrović, Marija S., Stanković, Slavka M., Porobić, Slavica, Marinović-Cincović, Milena, Mihajlović, Marija, "Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study" in Journal of Analytical and Applied Pyrolysis, 155 (2021):105028,
https://doi.org/10.1016/j.jaap.2021.105028 . .
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