Dramićanin, Miroslav

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Authority KeyName Variants
orcid::0000-0003-4750-5359
  • Dramićanin, Miroslav (290)
Projects
Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites
Physics of amorphous and nanostructural materials Thin films of single wall carbon nanotubes and graphene for electronic application
Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology Graphitic and Inorganic Low-dimensional Nanostructures
Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals NanoTBTech - Nanoparticles-based 2D thermal bioimaging technologies
Studies of enzyme interactions with toxic and pharmacologically active molecules Ministry of Education, Science and Technological Development of the Republic of Serbia
SASPRO - Mobility Programme of Slovak Academy of Sciences: Supportive Fund for Excellent Scientists Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions
Molecular determinants for tumor marker design Modulation of intracellular energy balance-controlling signalling pathways in therapy of cancer and neuro-immuno-endocrine disorders
National Recruitment Program of High-end Foreign Experts [GDT20185200479] APV Provincial Secretariat for Science and Technological Development of the Republic of Serbia [114-451-1850/2014-03]
Canada Excellence Research Chairs (CERC) program European Regional Development Fund [TK141]
LUMINET - European Network on Luminescent Materials Programme for the Foreign Experts [W2017011]
Science and Technology Planning Project of Guangzhou City [201704030020] Special Fund of Guangdong Province Project for Applied Science and Technology Research and Development [2017B090917001]
APV Provincial Secretariat for Science of the Republic of Serbia [114-451-3583] Estonian Research Council [PUT PRG111]
Directed synthesis, structure and properties of multifunctional materials The role of autophagy in regulation of cancer cell death
Molecular determinants of innate immunity in autoimmunity and tumorogenesis Developing infrastructure for priority research fields
Magmatism and geodynamics of the Balkan Peninsula from Mesozoic to present day: significance for the formation of metallic and non-metallic mineral deposits Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes

Author's Bibliography

Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence

Ćirić, Aleksandar; Stojadinović, Stevan; Ristić, Zoran; Zeković, Ivana Lj.; Kuzman, Sanja; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Ristić, Zoran
AU  - Zeković, Ivana Lj.
AU  - Kuzman, Sanja
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9140
AB  - The introduction of additional functionalities to materials is exceptionally important as it opens new applications for them. Aluminum, one of the most abundant and important materials, is coated with luminescent Sm2+-doped γ-aluminium oxide to impart thermometric functionality. Considering the potential industrial applications, two of the most widely used aluminum alloys, 6061 and 7075, are also coated. For this purpose, plasma electrolytic oxidation (PEO), an effective technique for producing hard ceramic coatings on various metal surfaces, is used. It is shown that thermometric coatings can be produced on aluminum in one-step process by adding the raw precursor to the electrolyte. The valence reduction of Ln3+ to Ln2+ is achieved during the PEO process. The intense and broad (orange to deep red) emission from the coating shows supersensitivity to temperature changes over the 100–648 K range. The temperature is obtained from the coating emission using i) the emission intensity ratio method, ii) emission lifetime, and iii) emission band position with sensitivities of 4.8% K−1, 1.2% K−1, and 8 cm−1 K−1, respectively. Several applications would benefit from the thermometric coating's excellent temperature resolution of 0.04 K and the choice of three temperature read-outs that facilitate the coating's use in different luminescence thermometry setups. © 2021 Wiley-VCH GmbH
T2  - Advanced Materials Technologies
T1  - Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence
VL  - 6
IS  - 4
SP  - 2001201
DO  - 10.1002/admt.202001201
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Ristić, Zoran and Zeković, Ivana Lj. and Kuzman, Sanja and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9140",
abstract = "The introduction of additional functionalities to materials is exceptionally important as it opens new applications for them. Aluminum, one of the most abundant and important materials, is coated with luminescent Sm2+-doped γ-aluminium oxide to impart thermometric functionality. Considering the potential industrial applications, two of the most widely used aluminum alloys, 6061 and 7075, are also coated. For this purpose, plasma electrolytic oxidation (PEO), an effective technique for producing hard ceramic coatings on various metal surfaces, is used. It is shown that thermometric coatings can be produced on aluminum in one-step process by adding the raw precursor to the electrolyte. The valence reduction of Ln3+ to Ln2+ is achieved during the PEO process. The intense and broad (orange to deep red) emission from the coating shows supersensitivity to temperature changes over the 100–648 K range. The temperature is obtained from the coating emission using i) the emission intensity ratio method, ii) emission lifetime, and iii) emission band position with sensitivities of 4.8% K−1, 1.2% K−1, and 8 cm−1 K−1, respectively. Several applications would benefit from the thermometric coating's excellent temperature resolution of 0.04 K and the choice of three temperature read-outs that facilitate the coating's use in different luminescence thermometry setups. © 2021 Wiley-VCH GmbH",
journal = "Advanced Materials Technologies",
title = "Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence",
volume = "6",
number = "4",
pages = "2001201",
doi = "10.1002/admt.202001201"
}
Ćirić, A., Stojadinović, S., Ristić, Z., Zeković, I. Lj., Kuzman, S., Antić, Ž.,& Dramićanin, M. (2021). Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence.
Advanced Materials Technologies, 6(4), 2001201.
https://doi.org/10.1002/admt.202001201
Ćirić A, Stojadinović S, Ristić Z, Zeković IL, Kuzman S, Antić Ž, Dramićanin M. Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence. Advanced Materials Technologies. 2021;6(4):2001201
Ćirić Aleksandar, Stojadinović Stevan, Ristić Zoran, Zeković Ivana Lj., Kuzman Sanja, Antić Željka, Dramićanin Miroslav, "Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence" Advanced Materials Technologies, 6, no. 4 (2021):2001201,
https://doi.org/10.1002/admt.202001201 .
2
2
1

Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects

Porobić, Slavica; Božić, Bojan Đ.; Dramićanin, Miroslav; Vitnik, Vesna; Vitnik, Željko J.; Marinović-Cincović, Milena; Mijin, Dušan Ž.

(2020)

TY  - JOUR
AU  - Porobić, Slavica
AU  - Božić, Bojan Đ.
AU  - Dramićanin, Miroslav
AU  - Vitnik, Vesna
AU  - Vitnik, Željko J.
AU  - Marinović-Cincović, Milena
AU  - Mijin, Dušan Ž.
PY  - 2020
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8475
AB  - A series of nine 5-(4-substituted phenylazo)-3-amido-6-hydroxy-4-methyl-2-pyridones were synthesized and characterized by FT–IR, 1H and 13C NMR, UV–Vis, and PL spectroscopy. Photophysical properties of the dyes were examined in solvents of various polarities and at different pH values. The solvent effects on the absorbance and emission spectral shift were analyzed using Lippert–Mataga, Reichardt–Dimroth and Kamlet-Taft equations. Moreover, UV–Vis absorption and emission frequencies were correlated with Hammett substituent constants applying the linear free energy relationships. DFT calculations of the investigated dyes were accomplished to determine their structural and electronic properties. © 2019
T2  - Dyes and Pigments
T1  - Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects
VL  - 175
SP  - 108139
DO  - 10.1016/j.dyepig.2019.108139
ER  - 
@article{
author = "Porobić, Slavica and Božić, Bojan Đ. and Dramićanin, Miroslav and Vitnik, Vesna and Vitnik, Željko J. and Marinović-Cincović, Milena and Mijin, Dušan Ž.",
year = "2020",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8475",
abstract = "A series of nine 5-(4-substituted phenylazo)-3-amido-6-hydroxy-4-methyl-2-pyridones were synthesized and characterized by FT–IR, 1H and 13C NMR, UV–Vis, and PL spectroscopy. Photophysical properties of the dyes were examined in solvents of various polarities and at different pH values. The solvent effects on the absorbance and emission spectral shift were analyzed using Lippert–Mataga, Reichardt–Dimroth and Kamlet-Taft equations. Moreover, UV–Vis absorption and emission frequencies were correlated with Hammett substituent constants applying the linear free energy relationships. DFT calculations of the investigated dyes were accomplished to determine their structural and electronic properties. © 2019",
journal = "Dyes and Pigments",
title = "Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects",
volume = "175",
pages = "108139",
doi = "10.1016/j.dyepig.2019.108139"
}
Porobić, S., Božić, B. Đ., Dramićanin, M., Vitnik, V., Vitnik, Ž. J., Marinović-Cincović, M.,& Mijin, D. Ž. (2020). Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects.
Dyes and Pigments, 175, 108139.
https://doi.org/10.1016/j.dyepig.2019.108139
Porobić S, Božić BĐ, Dramićanin M, Vitnik V, Vitnik ŽJ, Marinović-Cincović M, Mijin DŽ. Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects. Dyes and Pigments. 2020;175:108139
Porobić Slavica, Božić Bojan Đ., Dramićanin Miroslav, Vitnik Vesna, Vitnik Željko J., Marinović-Cincović Milena, Mijin Dušan Ž., "Absorption and fluorescence spectral properties of azo dyes based on 3-amido-6-hydroxy-4-methyl-2-pyridone: Solvent and substituent effects" Dyes and Pigments, 175 (2020):108139,
https://doi.org/10.1016/j.dyepig.2019.108139 .
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Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures

Papan, Jelena; Ristić, Zoran; Ćirić, Aleksandar; Kuzman, Sanja; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Papan, Jelena
AU  - Ristić, Zoran
AU  - Ćirić, Aleksandar
AU  - Kuzman, Sanja
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8901
AB  - The red phosphor Y2Mo4O15:Eu3+ calcined at different temperatures is obtained by a solid-state method, and is investigated in this article. Usage of solid-state method with the combination of five different calcination temperatures (500, 550, 600, 650, and 700 °C) leads to the formation of pure monoclinic phase in all samples apart from the one calcined at the lowest temperature. Crystallite size obtained by Rietveld refinement is in the range of 38–55 nm. Scanning electron microscopy analysis confirms the presence of agglomerates. Luminescence emission spectra and emission decay curves are measured for all pure samples, and parameters derived from these measurements are used for Judd–Ofelt analysis. International commission on illumination (CIE) chromaticity diagram confirms the presence of pure red emission and high quantum efficiency. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Physica Status Solidi. B: Basic Research
T1  - Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures
VL  - 257
IS  - 8
SP  - 1900454
DO  - 10.1002/pssb.201900454
ER  - 
@article{
author = "Papan, Jelena and Ristić, Zoran and Ćirić, Aleksandar and Kuzman, Sanja and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8901",
abstract = "The red phosphor Y2Mo4O15:Eu3+ calcined at different temperatures is obtained by a solid-state method, and is investigated in this article. Usage of solid-state method with the combination of five different calcination temperatures (500, 550, 600, 650, and 700 °C) leads to the formation of pure monoclinic phase in all samples apart from the one calcined at the lowest temperature. Crystallite size obtained by Rietveld refinement is in the range of 38–55 nm. Scanning electron microscopy analysis confirms the presence of agglomerates. Luminescence emission spectra and emission decay curves are measured for all pure samples, and parameters derived from these measurements are used for Judd–Ofelt analysis. International commission on illumination (CIE) chromaticity diagram confirms the presence of pure red emission and high quantum efficiency. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Physica Status Solidi. B: Basic Research",
title = "Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures",
volume = "257",
number = "8",
pages = "1900454",
doi = "10.1002/pssb.201900454"
}
Papan, J., Ristić, Z., Ćirić, A., Kuzman, S.,& Dramićanin, M. (2020). Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures.
Physica Status Solidi. B: Basic Research, 257(8), 1900454.
https://doi.org/10.1002/pssb.201900454
Papan J, Ristić Z, Ćirić A, Kuzman S, Dramićanin M. Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures. Physica Status Solidi. B: Basic Research. 2020;257(8):1900454
Papan Jelena, Ristić Zoran, Ćirić Aleksandar, Kuzman Sanja, Dramićanin Miroslav, "Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures" Physica Status Solidi. B: Basic Research, 257, no. 8 (2020):1900454,
https://doi.org/10.1002/pssb.201900454 .
1
1
1

Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level

Ćirić, Aleksandar; Stojadinović, Stevan; Brik, Mikhail G.; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Brik, Mikhail G.
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8496
AB  - Traditional applications of the Judd-Ofelt (JO) theory to the analysis of the Eu3+ optical spectra make use of the emission transitions originating from the 5D0 manifold. In the present paper, we report an alternative method of evaluating the JO intensity parameters from the Eu3+ emission spectra based on the 5D1 → 7F0,1 transitions. The reduced matrix elements of the unit tensor operators are re-calculated for the 5D0,1,2 → 7F0,1,…,6 Eu3+ transitions in the intermediate coupling approximation using the average electrostatic and spin-orbit coupling parameters. The suggested method was tested by analyzing the emission spectra of the Eu3+ doped GdAlO3, LaF3, NaYF4, Y2O3, ZrO2, YNbO4, ZBLA and PIGLZ hosts. It is shown that the developed method is more accurate for the hosts with relatively high 5D1 level population, which emphasizes its high potential and applicability. In addition to the JO analysis, the CIE chromaticity coordinates are calculated for the investigated spectra. © 2019 Elsevier B.V.
T2  - Chemical Physics
T1  - Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level
VL  - 528
SP  - 110513
DO  - 10.1016/j.chemphys.2019.110513
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Brik, Mikhail G. and Dramićanin, Miroslav",
year = "2020",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8496",
abstract = "Traditional applications of the Judd-Ofelt (JO) theory to the analysis of the Eu3+ optical spectra make use of the emission transitions originating from the 5D0 manifold. In the present paper, we report an alternative method of evaluating the JO intensity parameters from the Eu3+ emission spectra based on the 5D1 → 7F0,1 transitions. The reduced matrix elements of the unit tensor operators are re-calculated for the 5D0,1,2 → 7F0,1,…,6 Eu3+ transitions in the intermediate coupling approximation using the average electrostatic and spin-orbit coupling parameters. The suggested method was tested by analyzing the emission spectra of the Eu3+ doped GdAlO3, LaF3, NaYF4, Y2O3, ZrO2, YNbO4, ZBLA and PIGLZ hosts. It is shown that the developed method is more accurate for the hosts with relatively high 5D1 level population, which emphasizes its high potential and applicability. In addition to the JO analysis, the CIE chromaticity coordinates are calculated for the investigated spectra. © 2019 Elsevier B.V.",
journal = "Chemical Physics",
title = "Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level",
volume = "528",
pages = "110513",
doi = "10.1016/j.chemphys.2019.110513"
}
Ćirić, A., Stojadinović, S., Brik, M. G.,& Dramićanin, M. (2020). Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level.
Chemical Physics, 528, 110513.
https://doi.org/10.1016/j.chemphys.2019.110513
Ćirić A, Stojadinović S, Brik MG, Dramićanin M. Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level. Chemical Physics. 2020;528:110513
Ćirić Aleksandar, Stojadinović Stevan, Brik Mikhail G., Dramićanin Miroslav, "Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level" Chemical Physics, 528 (2020):110513,
https://doi.org/10.1016/j.chemphys.2019.110513 .
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11

Preparation of beechwood/polymer composites using the method of lyophilization and gamma irradiation

Vujčić, Ivica; Mašić, Slobodan; Obradović, Nataša; Dramićanin, Miroslav

(2020)

TY  - CONF
AU  - Vujčić, Ivica
AU  - Mašić, Slobodan
AU  - Obradović, Nataša
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8519
AB  - Wooden cultural heritage serves as a very important source of information for historians and researchers. Also, it imposes an obligation on the science to keep this legacy for future generations in a proper condition. Among other techniques of conservation of wooden cultural heritage, a very suitable method is impregnation of the wood with the polymer, whereby the wood/polymer composites are formed. This paper describes the method of preparing the wood/polymer composites based on beechwood, using five different monomer systems. The method of lyophilization and subsequent polymerization by gamma radiation was used. After lyophilization and immersing in the monomer solutions, the wood samples were dried and irradiated with a dose of 25 kGy and different gamma irradiation dose rates. The weight of the samples before and after this procedure was measured. Also, changes in the mechanical properties of wood (compression test) before and after treatment were examined. We also examined the effect of radiation dose rate on polymerization. Based on the weight differences, dose rates and materials characterization we determined which of the monomer solution and dose rate are the most suitable for making beechwood/polymer composites. © 2019 Elsevier Ltd
C3  - Radiation Physics and Chemistry
T1  - Preparation of beechwood/polymer composites using the method of lyophilization and gamma irradiation
VL  - 166
SP  - 108505
DO  - 10.1016/j.radphyschem.2019.108505
ER  - 
@conference{
author = "Vujčić, Ivica and Mašić, Slobodan and Obradović, Nataša and Dramićanin, Miroslav",
year = "2020",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8519",
abstract = "Wooden cultural heritage serves as a very important source of information for historians and researchers. Also, it imposes an obligation on the science to keep this legacy for future generations in a proper condition. Among other techniques of conservation of wooden cultural heritage, a very suitable method is impregnation of the wood with the polymer, whereby the wood/polymer composites are formed. This paper describes the method of preparing the wood/polymer composites based on beechwood, using five different monomer systems. The method of lyophilization and subsequent polymerization by gamma radiation was used. After lyophilization and immersing in the monomer solutions, the wood samples were dried and irradiated with a dose of 25 kGy and different gamma irradiation dose rates. The weight of the samples before and after this procedure was measured. Also, changes in the mechanical properties of wood (compression test) before and after treatment were examined. We also examined the effect of radiation dose rate on polymerization. Based on the weight differences, dose rates and materials characterization we determined which of the monomer solution and dose rate are the most suitable for making beechwood/polymer composites. © 2019 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "Preparation of beechwood/polymer composites using the method of lyophilization and gamma irradiation",
volume = "166",
pages = "108505",
doi = "10.1016/j.radphyschem.2019.108505"
}
Vujčić, I., Mašić, S., Obradović, N.,& Dramićanin, M. (2020). Preparation of beechwood/polymer composites using the method of lyophilization and gamma irradiation.
Radiation Physics and Chemistry, 166, 108505.
https://doi.org/10.1016/j.radphyschem.2019.108505
Vujčić I, Mašić S, Obradović N, Dramićanin M. Preparation of beechwood/polymer composites using the method of lyophilization and gamma irradiation. Radiation Physics and Chemistry. 2020;166:108505
Vujčić Ivica, Mašić Slobodan, Obradović Nataša, Dramićanin Miroslav, "Preparation of beechwood/polymer composites using the method of lyophilization and gamma irradiation" Radiation Physics and Chemistry, 166 (2020):108505,
https://doi.org/10.1016/j.radphyschem.2019.108505 .
1
1

Temperature and concentration dependent Judd-Ofelt analysis of Y2O3:Eu3+ and YVO4:Eu3+

Ćirić, Aleksandar; Stojadinović, Stevan; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8745
AB  - Judd-Ofelt analysis has been performed from the photoluminescence emission spectra of Y2O3:Eu3+ with 3%, 1% and 0.1% doping concentration and YVO4:Eu3+ with 1% doping concentration, in temperature range from 40 °C to 460 °C. For precise calculation, an extended Sellmeier equation that accounts for the doping concentration and temperature dependence of the refractive index of Y2O3 doped with lanthanides is estimated. The temperature dependence of Ω2 and Ω4 parameters are fitted with quadratic and linear regression, respectively. Judd-Ofelt intensity parameters uniformly drop with increasing temperature, but at a different rate for different doping concentrations. From the Judd-Ofelt parameters radiative lifetimes and emission cross-sections were calculated. The cross-sections show a linear decrease with increasing temperature. © 2019 Elsevier B.V.
T2  - Physica B: Condensed Matter
T1  - Temperature and concentration dependent Judd-Ofelt analysis of Y2O3:Eu3+ and YVO4:Eu3+
VL  - 579
SP  - 411891
DO  - 10.1016/j.physb.2019.411891
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Dramićanin, Miroslav",
year = "2020",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8745",
abstract = "Judd-Ofelt analysis has been performed from the photoluminescence emission spectra of Y2O3:Eu3+ with 3%, 1% and 0.1% doping concentration and YVO4:Eu3+ with 1% doping concentration, in temperature range from 40 °C to 460 °C. For precise calculation, an extended Sellmeier equation that accounts for the doping concentration and temperature dependence of the refractive index of Y2O3 doped with lanthanides is estimated. The temperature dependence of Ω2 and Ω4 parameters are fitted with quadratic and linear regression, respectively. Judd-Ofelt intensity parameters uniformly drop with increasing temperature, but at a different rate for different doping concentrations. From the Judd-Ofelt parameters radiative lifetimes and emission cross-sections were calculated. The cross-sections show a linear decrease with increasing temperature. © 2019 Elsevier B.V.",
journal = "Physica B: Condensed Matter",
title = "Temperature and concentration dependent Judd-Ofelt analysis of Y2O3:Eu3+ and YVO4:Eu3+",
volume = "579",
pages = "411891",
doi = "10.1016/j.physb.2019.411891"
}
Ćirić, A., Stojadinović, S.,& Dramićanin, M. (2020). Temperature and concentration dependent Judd-Ofelt analysis of Y2O3:Eu3+ and YVO4:Eu3+.
Physica B: Condensed Matter, 579, 411891.
https://doi.org/10.1016/j.physb.2019.411891
Ćirić A, Stojadinović S, Dramićanin M. Temperature and concentration dependent Judd-Ofelt analysis of Y2O3:Eu3+ and YVO4:Eu3+. Physica B: Condensed Matter. 2020;579:411891
Ćirić Aleksandar, Stojadinović Stevan, Dramićanin Miroslav, "Temperature and concentration dependent Judd-Ofelt analysis of Y2O3:Eu3+ and YVO4:Eu3+" Physica B: Condensed Matter, 579 (2020):411891,
https://doi.org/10.1016/j.physb.2019.411891 .
4
1
4

Single‐Crystal Red Phosphors: Enhanced Optical Efficiency and Improved Chemical Stability for wLEDs

Wang, Zhengliang; Yang, Zhiyu; Wang, Nan; Zhou, Qiang; Zhou, Jianbang; Ma, Li; Wang, Xiaojun; Xu, Yiqing; Brik, Mikhail G.; Dramićanin, Miroslav; Wu, Mingmei

(2020)

TY  - JOUR
AU  - Wang, Zhengliang
AU  - Yang, Zhiyu
AU  - Wang, Nan
AU  - Zhou, Qiang
AU  - Zhou, Jianbang
AU  - Ma, Li
AU  - Wang, Xiaojun
AU  - Xu, Yiqing
AU  - Brik, Mikhail G.
AU  - Dramićanin, Miroslav
AU  - Wu, Mingmei
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8791
AB  - Crystal phosphors have many unique advantages compared with powdery ones. Herein, room-temperature-grown millimeter-sized single-crystal phosphors of Cs2XF6:Mn4+ (X = Ge, Si, and Ti) with remarkably higher external quantum efficiency than the corresponding powdery samples are reported. In addition, as compared with the powdery ones, the crystal samples exhibit much better stability toward water under different pH conditions. The red light-emitting diodes (LEDs) based on Cs2XF6:Mn4+ crystals show significantly improved luminous efficiency than those based on their corresponding powders. An assembled white LED device composed of the two layers of phosphors, i.e., the crystal (such as Cs2GeF6:Mn4+) and commercial Y3Al5O12:Ce3+, on a blue chip exhibits intense warm white light with high luminous efficiency (up to 193 lm W−1), high color rendering indexes (88), and low correlated color temperatures (3107 K). Hence, these crystals with greatly improved efficiency and stability can be potentially applied in high-quality LED backlighting display and white LED lighting, especially inside the micro-LED devices. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Advanced Optical Materials
T1  - Single‐Crystal Red Phosphors: Enhanced Optical Efficiency and Improved Chemical Stability for wLEDs
VL  - 8
IS  - 6
SP  - 1901512
DO  - 10.1002/adom.201901512
ER  - 
@article{
author = "Wang, Zhengliang and Yang, Zhiyu and Wang, Nan and Zhou, Qiang and Zhou, Jianbang and Ma, Li and Wang, Xiaojun and Xu, Yiqing and Brik, Mikhail G. and Dramićanin, Miroslav and Wu, Mingmei",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8791",
abstract = "Crystal phosphors have many unique advantages compared with powdery ones. Herein, room-temperature-grown millimeter-sized single-crystal phosphors of Cs2XF6:Mn4+ (X = Ge, Si, and Ti) with remarkably higher external quantum efficiency than the corresponding powdery samples are reported. In addition, as compared with the powdery ones, the crystal samples exhibit much better stability toward water under different pH conditions. The red light-emitting diodes (LEDs) based on Cs2XF6:Mn4+ crystals show significantly improved luminous efficiency than those based on their corresponding powders. An assembled white LED device composed of the two layers of phosphors, i.e., the crystal (such as Cs2GeF6:Mn4+) and commercial Y3Al5O12:Ce3+, on a blue chip exhibits intense warm white light with high luminous efficiency (up to 193 lm W−1), high color rendering indexes (88), and low correlated color temperatures (3107 K). Hence, these crystals with greatly improved efficiency and stability can be potentially applied in high-quality LED backlighting display and white LED lighting, especially inside the micro-LED devices. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Advanced Optical Materials",
title = "Single‐Crystal Red Phosphors: Enhanced Optical Efficiency and Improved Chemical Stability for wLEDs",
volume = "8",
number = "6",
pages = "1901512",
doi = "10.1002/adom.201901512"
}
Wang, Z., Yang, Z., Wang, N., Zhou, Q., Zhou, J., Ma, L., Wang, X., Xu, Y., Brik, M. G., Dramićanin, M.,& Wu, M. (2020). Single‐Crystal Red Phosphors: Enhanced Optical Efficiency and Improved Chemical Stability for wLEDs.
Advanced Optical Materials, 8(6), 1901512.
https://doi.org/10.1002/adom.201901512
Wang Z, Yang Z, Wang N, Zhou Q, Zhou J, Ma L, Wang X, Xu Y, Brik MG, Dramićanin M, Wu M. Single‐Crystal Red Phosphors: Enhanced Optical Efficiency and Improved Chemical Stability for wLEDs. Advanced Optical Materials. 2020;8(6):1901512
Wang Zhengliang, Yang Zhiyu, Wang Nan, Zhou Qiang, Zhou Jianbang, Ma Li, Wang Xiaojun, Xu Yiqing, Brik Mikhail G., Dramićanin Miroslav, Wu Mingmei, "Single‐Crystal Red Phosphors: Enhanced Optical Efficiency and Improved Chemical Stability for wLEDs" Advanced Optical Materials, 8, no. 6 (2020):1901512,
https://doi.org/10.1002/adom.201901512 .
20
13
16

Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry

Suta, Markus; Antić, Željka; Đorđević, Vesna R.; Kuzman, Sanja; Dramićanin, Miroslav; Meijerink, Andries

(2020)

TY  - JOUR
AU  - Suta, Markus
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Kuzman, Sanja
AU  - Dramićanin, Miroslav
AU  - Meijerink, Andries
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8909
AB  - Ratiometric luminescence thermometry employing luminescence within the biological transparency windows provides high potential for biothermal imaging. Nd3+ is a promising candidate for that purpose due to its intense radiative transitions within biological windows (BWs) I and II and the simultaneous efficient excitability within BW I. This makes Nd3+ almost unique among all lanthanides. Typically, emission from the two 4F3/2 crystal field levels is used for thermometry but the small ~100 cm−1 energy separation limits the sensitivity. A higher sensitivity for physiological temperatures is possible using the luminescence intensity ratio (LIR) of the emissive transitions from the 4F5/2 and 4F3/2 excited spin-orbit levels. Herein, we demonstrate and discuss various pitfalls that can occur in Boltzmann thermometry if this particular LIR is used for physiological temperature sensing. Both microcrystalline, dilute (0.1%) Nd3+-doped LaPO4 and LaPO4: x% Nd3+ (x = 2, 5, 10, 25, 100) nanocrystals serve as an illustrative example. Besides structural and optical characterization of those luminescent thermometers, the impact and consequences of the Nd3+ concentration on their luminescence and performance as Boltzmann-based thermometers are analyzed. For low Nd3+ concentrations, Boltzmann equilibrium starts just around 300 K. At higher Nd3+ concentrations, cross-relaxation processes enhance the decay rates of the 4F3/2 and 4F5/2 levels making the decay faster than the equilibration rates between the levels. It is shown that the onset of the useful temperature sensing range shifts to higher temperatures, even above ~ 450 K for Nd concentrations over 5%. A microscopic explanation for pitfalls in Boltzmann thermometry with Nd3+ is finally given and guidelines for the usability of this lanthanide ion in the field of physiological temperature sensing are elaborated. Insight in competition between thermal coupling through non-radiative transitions and population decay through cross-relaxation of the 4F5/2 and 4F3/2 spin-orbit levels of Nd3+ makes it possible to tailor the thermometric performance of Nd3+ to enable physiological temperature sensing.
T2  - Nanomaterials
T1  - Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry
VL  - 10
IS  - 3
SP  - 543
DO  - 10.3390/nano10030543
ER  - 
@article{
author = "Suta, Markus and Antić, Željka and Đorđević, Vesna R. and Kuzman, Sanja and Dramićanin, Miroslav and Meijerink, Andries",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8909",
abstract = "Ratiometric luminescence thermometry employing luminescence within the biological transparency windows provides high potential for biothermal imaging. Nd3+ is a promising candidate for that purpose due to its intense radiative transitions within biological windows (BWs) I and II and the simultaneous efficient excitability within BW I. This makes Nd3+ almost unique among all lanthanides. Typically, emission from the two 4F3/2 crystal field levels is used for thermometry but the small ~100 cm−1 energy separation limits the sensitivity. A higher sensitivity for physiological temperatures is possible using the luminescence intensity ratio (LIR) of the emissive transitions from the 4F5/2 and 4F3/2 excited spin-orbit levels. Herein, we demonstrate and discuss various pitfalls that can occur in Boltzmann thermometry if this particular LIR is used for physiological temperature sensing. Both microcrystalline, dilute (0.1%) Nd3+-doped LaPO4 and LaPO4: x% Nd3+ (x = 2, 5, 10, 25, 100) nanocrystals serve as an illustrative example. Besides structural and optical characterization of those luminescent thermometers, the impact and consequences of the Nd3+ concentration on their luminescence and performance as Boltzmann-based thermometers are analyzed. For low Nd3+ concentrations, Boltzmann equilibrium starts just around 300 K. At higher Nd3+ concentrations, cross-relaxation processes enhance the decay rates of the 4F3/2 and 4F5/2 levels making the decay faster than the equilibration rates between the levels. It is shown that the onset of the useful temperature sensing range shifts to higher temperatures, even above ~ 450 K for Nd concentrations over 5%. A microscopic explanation for pitfalls in Boltzmann thermometry with Nd3+ is finally given and guidelines for the usability of this lanthanide ion in the field of physiological temperature sensing are elaborated. Insight in competition between thermal coupling through non-radiative transitions and population decay through cross-relaxation of the 4F5/2 and 4F3/2 spin-orbit levels of Nd3+ makes it possible to tailor the thermometric performance of Nd3+ to enable physiological temperature sensing.",
journal = "Nanomaterials",
title = "Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry",
volume = "10",
number = "3",
pages = "543",
doi = "10.3390/nano10030543"
}
Suta, M., Antić, Ž., Đorđević, V. R., Kuzman, S., Dramićanin, M.,& Meijerink, A. (2020). Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry.
Nanomaterials, 10(3), 543.
https://doi.org/10.3390/nano10030543
Suta M, Antić Ž, Đorđević VR, Kuzman S, Dramićanin M, Meijerink A. Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry. Nanomaterials. 2020;10(3):543
Suta Markus, Antić Željka, Đorđević Vesna R., Kuzman Sanja, Dramićanin Miroslav, Meijerink Andries, "Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry" Nanomaterials, 10, no. 3 (2020):543,
https://doi.org/10.3390/nano10030543 .
4
35
17
27

Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders

Kuzman, Sanja; Medić, Mina M.; Đorđević, Vesna R.; Zeković, Ivana Lj.; Ristić, Zoran; Đačanin Far, Ljubica; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Medić, Mina M.
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Ristić, Zoran
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8936
AB  - When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.
T2  - Journal of Electronic Materials
T1  - Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders
VL  - 49
IS  - 6
SP  - 4002
EP  - 4009
DO  - 10.1007/s11664-020-08109-7
ER  - 
@article{
author = "Kuzman, Sanja and Medić, Mina M. and Đorđević, Vesna R. and Zeković, Ivana Lj. and Ristić, Zoran and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8936",
abstract = "When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.",
journal = "Journal of Electronic Materials",
title = "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders",
volume = "49",
number = "6",
pages = "4002-4009",
doi = "10.1007/s11664-020-08109-7"
}
Kuzman, S., Medić, M. M., Đorđević, V. R., Zeković, I. Lj., Ristić, Z., Đačanin Far, L.,& Dramićanin, M. (2020). Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders.
Journal of Electronic Materials, 49(6), 4002-4009.
https://doi.org/10.1007/s11664-020-08109-7
Kuzman S, Medić MM, Đorđević VR, Zeković IL, Ristić Z, Đačanin Far L, Dramićanin M. Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. Journal of Electronic Materials. 2020;49(6):4002-4009
Kuzman Sanja, Medić Mina M., Đorđević Vesna R., Zeković Ivana Lj., Ristić Zoran, Đačanin Far Ljubica, Dramićanin Miroslav, "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders" Journal of Electronic Materials, 49, no. 6 (2020):4002-4009,
https://doi.org/10.1007/s11664-020-08109-7 .

Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission

Ćirić, Aleksandar; Aleksić, Jelena; Barudžija, Tanja; Antić, Željka; Đorđević, Vesna R.; Medić, Mina M.; Periša, Jovana; Zeković, Ivana Lj.; Mitrić, Miodrag; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Aleksić, Jelena
AU  - Barudžija, Tanja
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Medić, Mina M.
AU  - Periša, Jovana
AU  - Zeković, Ivana Lj.
AU  - Mitrić, Miodrag
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8938
AB  - The emission of Er3+ provides three combinations of emission bands suitable for ratiometric luminescence thermometry. Two combinations utilize ratios of visible emissions (2H11/2→4I15/2 at 523 nm/ 4S3/2→4I15/2 at 542 nm and 4F7/2→4I15/2 at 485 nm/ 4S3/2→4I15/2 at 545 nm), while emissions from the third combination are located in near-infrared, e.g., in the first biological window (2H11/2→4I13/2 at 793 nm/ 4S3/2→4I13/2 at 840 nm). Herein, we aimed to compare thermometric performances of these three different ratiometric readouts on account of their relative sensitivities, resolutions, and repeatability of measurements. For this aim, we prepared Yb3+,Er3+:YF3 nanopowders by oxide fluorination. The structure of the materials was confirmed by X-ray diffraction analysis and particle morphology was evaluated from FE-SEM measurements. Upconversion emission spectra were measured over the 293–473 K range upon excitation by 980 nm radiation. The obtained relative sensitivities on temperature for 523/542, 485/542, and 793/840 emission intensity ratios were 1.06 ± 0.02, 2.03 ± 0.23, and 0.98 ± 0.10%K−1 with temperature resolutions of 0.3, 0.7, and 1.8 K, respectively. The study showed that the higher relative temperature sensitivity does not necessarily lead to the more precise temperature measurement and better resolution, since it may be compromised by a larger uncertainty in measurement of low-intensity emission bands.
T2  - Nanomaterials
T1  - Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission
VL  - 10
IS  - 4
SP  - 627
DO  - 10.3390/nano10040627
ER  - 
@article{
author = "Ćirić, Aleksandar and Aleksić, Jelena and Barudžija, Tanja and Antić, Željka and Đorđević, Vesna R. and Medić, Mina M. and Periša, Jovana and Zeković, Ivana Lj. and Mitrić, Miodrag and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8938",
abstract = "The emission of Er3+ provides three combinations of emission bands suitable for ratiometric luminescence thermometry. Two combinations utilize ratios of visible emissions (2H11/2→4I15/2 at 523 nm/ 4S3/2→4I15/2 at 542 nm and 4F7/2→4I15/2 at 485 nm/ 4S3/2→4I15/2 at 545 nm), while emissions from the third combination are located in near-infrared, e.g., in the first biological window (2H11/2→4I13/2 at 793 nm/ 4S3/2→4I13/2 at 840 nm). Herein, we aimed to compare thermometric performances of these three different ratiometric readouts on account of their relative sensitivities, resolutions, and repeatability of measurements. For this aim, we prepared Yb3+,Er3+:YF3 nanopowders by oxide fluorination. The structure of the materials was confirmed by X-ray diffraction analysis and particle morphology was evaluated from FE-SEM measurements. Upconversion emission spectra were measured over the 293–473 K range upon excitation by 980 nm radiation. The obtained relative sensitivities on temperature for 523/542, 485/542, and 793/840 emission intensity ratios were 1.06 ± 0.02, 2.03 ± 0.23, and 0.98 ± 0.10%K−1 with temperature resolutions of 0.3, 0.7, and 1.8 K, respectively. The study showed that the higher relative temperature sensitivity does not necessarily lead to the more precise temperature measurement and better resolution, since it may be compromised by a larger uncertainty in measurement of low-intensity emission bands.",
journal = "Nanomaterials",
title = "Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission",
volume = "10",
number = "4",
pages = "627",
doi = "10.3390/nano10040627"
}
Ćirić, A., Aleksić, J., Barudžija, T., Antić, Ž., Đorđević, V. R., Medić, M. M., Periša, J., Zeković, I. Lj., Mitrić, M.,& Dramićanin, M. (2020). Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission.
Nanomaterials, 10(4), 627.
https://doi.org/10.3390/nano10040627
Ćirić A, Aleksić J, Barudžija T, Antić Ž, Đorđević VR, Medić MM, Periša J, Zeković IL, Mitrić M, Dramićanin M. Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission. Nanomaterials. 2020;10(4):627
Ćirić Aleksandar, Aleksić Jelena, Barudžija Tanja, Antić Željka, Đorđević Vesna R., Medić Mina M., Periša Jovana, Zeković Ivana Lj., Mitrić Miodrag, Dramićanin Miroslav, "Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission" Nanomaterials, 10, no. 4 (2020):627,
https://doi.org/10.3390/nano10040627 .
18
7
15

Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles

Antić, Željka; Prashanthi, Kovur; Kuzman, Sanja; Periša, Jovana; Ristić, Zoran; Palkar, Vaijayanti R.; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Antić, Željka
AU  - Prashanthi, Kovur
AU  - Kuzman, Sanja
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Palkar, Vaijayanti R.
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8998
AB  - A strategy for optical nanothermometry using the negative thermal quenching behavior of intrinsic BiFeO3semiconductor nanoparticles has been reported here. X-ray diffraction measurement shows polycrystalline BiFeO3nanoparticles with a rhombohedral distorted perovskite structure. Transmission electron microscopy shows agglomerated crystalline nanoparticles around 20 nm in size. Photoluminescence measurements show that intensity of the defect level emission increases significantly with temperature, while the intensity of near band emission and other defect levels emissions show an opposite trend. The most important figures of merit for luminescence nanothermometry: the absolute (Sa) and the relative sensor sensitivity (Sr) and the temperature resolution (?Tm) were effectively resolved and calculated. The relative sensitivity and temperature resolution values are found to be 2.5% K-1and 0.2 K, respectively which are among the highest reported values observed so far for semiconductors.
T2  - RSC Advances
T1  - Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles
VL  - 10
IS  - 29
SP  - 16982
EP  - 16986
DO  - 10.1039/D0RA01896A
ER  - 
@article{
author = "Antić, Željka and Prashanthi, Kovur and Kuzman, Sanja and Periša, Jovana and Ristić, Zoran and Palkar, Vaijayanti R. and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8998",
abstract = "A strategy for optical nanothermometry using the negative thermal quenching behavior of intrinsic BiFeO3semiconductor nanoparticles has been reported here. X-ray diffraction measurement shows polycrystalline BiFeO3nanoparticles with a rhombohedral distorted perovskite structure. Transmission electron microscopy shows agglomerated crystalline nanoparticles around 20 nm in size. Photoluminescence measurements show that intensity of the defect level emission increases significantly with temperature, while the intensity of near band emission and other defect levels emissions show an opposite trend. The most important figures of merit for luminescence nanothermometry: the absolute (Sa) and the relative sensor sensitivity (Sr) and the temperature resolution (?Tm) were effectively resolved and calculated. The relative sensitivity and temperature resolution values are found to be 2.5% K-1and 0.2 K, respectively which are among the highest reported values observed so far for semiconductors.",
journal = "RSC Advances",
title = "Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles",
volume = "10",
number = "29",
pages = "16982-16986",
doi = "10.1039/D0RA01896A"
}
Antić, Ž., Prashanthi, K., Kuzman, S., Periša, J., Ristić, Z., Palkar, V. R.,& Dramićanin, M. (2020). Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles.
RSC Advances, 10(29), 16982-16986.
https://doi.org/10.1039/D0RA01896A
Antić Ž, Prashanthi K, Kuzman S, Periša J, Ristić Z, Palkar VR, Dramićanin M. Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles. RSC Advances. 2020;10(29):16982-16986
Antić Željka, Prashanthi Kovur, Kuzman Sanja, Periša Jovana, Ristić Zoran, Palkar Vaijayanti R., Dramićanin Miroslav, "Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles" RSC Advances, 10, no. 29 (2020):16982-16986,
https://doi.org/10.1039/D0RA01896A .

Judd-Ofelt modelling of the dual-excited single band ratiometric luminescence thermometry

Ćirić, Aleksandar; Zeković, Ivana Lj.; Medić, Mina; Antić, Željka; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Zeković, Ivana Lj.
AU  - Medić, Mina
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9004
AB  - The Judd-Ofelt model, already verified for the luminescence intensity ratio (also called fluorescence intensity ratio, FIR) thermometry from the emission spectra, is modified and tested for the dual-excited single band luminescence thermometry. The adapted model has been tested on Lu2O3:Eu3+, with a 99.9% match of the temperature invariant parameter to the experimental value. The absolute sensitivity obtained experimentally and predicted by the model are almost indistinguishable. The model is proven to be adequate for inaugural phosphor quality evaluation, as it can reveal the approximate figures of merit of luminescence thermometry solely from the single emission spectrum.
T2  - Journal of Luminescence
T1  - Judd-Ofelt modelling of the dual-excited single band ratiometric luminescence thermometry
VL  - 225
SP  - 117369
DO  - 10.1016/j.jlumin.2020.117369
ER  - 
@article{
author = "Ćirić, Aleksandar and Zeković, Ivana Lj. and Medić, Mina and Antić, Željka and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9004",
abstract = "The Judd-Ofelt model, already verified for the luminescence intensity ratio (also called fluorescence intensity ratio, FIR) thermometry from the emission spectra, is modified and tested for the dual-excited single band luminescence thermometry. The adapted model has been tested on Lu2O3:Eu3+, with a 99.9% match of the temperature invariant parameter to the experimental value. The absolute sensitivity obtained experimentally and predicted by the model are almost indistinguishable. The model is proven to be adequate for inaugural phosphor quality evaluation, as it can reveal the approximate figures of merit of luminescence thermometry solely from the single emission spectrum.",
journal = "Journal of Luminescence",
title = "Judd-Ofelt modelling of the dual-excited single band ratiometric luminescence thermometry",
volume = "225",
pages = "117369",
doi = "10.1016/j.jlumin.2020.117369"
}
Ćirić, A., Zeković, I. Lj., Medić, M., Antić, Ž.,& Dramićanin, M. (2020). Judd-Ofelt modelling of the dual-excited single band ratiometric luminescence thermometry.
Journal of Luminescence, 225, 117369.
https://doi.org/10.1016/j.jlumin.2020.117369
Ćirić A, Zeković IL, Medić M, Antić Ž, Dramićanin M. Judd-Ofelt modelling of the dual-excited single band ratiometric luminescence thermometry. Journal of Luminescence. 2020;225:117369
Ćirić Aleksandar, Zeković Ivana Lj., Medić Mina, Antić Željka, Dramićanin Miroslav, "Judd-Ofelt modelling of the dual-excited single band ratiometric luminescence thermometry" Journal of Luminescence, 225 (2020):117369,
https://doi.org/10.1016/j.jlumin.2020.117369 .
12
4
10

Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors

Li, Xiaohui; Zhou, Lei; Hong, Junyu; He, Shiman; Jing, Xiping; Dramićanin, Miroslav; Shi, Jianxin; Wu, Mingmei

(2020)

TY  - JOUR
AU  - Li, Xiaohui
AU  - Zhou, Lei
AU  - Hong, Junyu
AU  - He, Shiman
AU  - Jing, Xiping
AU  - Dramićanin, Miroslav
AU  - Shi, Jianxin
AU  - Wu, Mingmei
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9016
AB  - Modulation of structural order-disorder transition and structural oxygen defects can provide fundamental insights in the optimization of luminescence performances of phosphors. In this study, the luminescence of Ba3ZnTa2O9(BZT) was systematically elucidated, including the emission arising from the charge transfer (Nb5+/Ta5+ O2-) and anti-site oxygen defect emission due to the B-site disordering (defect type: [2ZnNb3-+ 3Vo2+]), as corroborated by the electronic structural calculations and detailed experiments. We present a two-step design for the optimization of luminescence properties of Ba3ZnTa2O9phosphor. In the first step, the B-site equivalent doping (Ta5+substituted by Nb5+) was used to modulate the B-site atomic arrangement, which induced the formation of the cubic phase with B-site full disordering. In the second step, the A-site nonequivalent doping (Ba2+substituted by Eu3+) was used to decrease the oxygen defect concentration. After the two-step optimization, the photoluminescence excitation spectrum of Ba3-yEuyZnNb2O9(y= 0.1) shows a broad band excitation (300-400 nm), which is a good match with the near-UV LED chip emission. Even more importantly, the emission spectrum covers the entire visible spectral region and exhibits a remarkably enhanced emission intensity (a 40 times enhancement when compared to that of the intrinsic BZT). The fabricated LED device comprising an n-UV chip (= 370 nm) and a single-component Ba3-yEuyZnNb2O9(y= 0.1) phosphor coating emits a warm white light with a low correlated color temperature (CCT = 4813 K) and a good color rendering index (Ra= 82.36).
T2  - Journal of Materials Chemistry C
T1  - Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors
VL  - 8
IS  - 20
SP  - 6715
EP  - 6723
DO  - 10.1039/D0TC01201G
ER  - 
@article{
author = "Li, Xiaohui and Zhou, Lei and Hong, Junyu and He, Shiman and Jing, Xiping and Dramićanin, Miroslav and Shi, Jianxin and Wu, Mingmei",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9016",
abstract = "Modulation of structural order-disorder transition and structural oxygen defects can provide fundamental insights in the optimization of luminescence performances of phosphors. In this study, the luminescence of Ba3ZnTa2O9(BZT) was systematically elucidated, including the emission arising from the charge transfer (Nb5+/Ta5+ O2-) and anti-site oxygen defect emission due to the B-site disordering (defect type: [2ZnNb3-+ 3Vo2+]), as corroborated by the electronic structural calculations and detailed experiments. We present a two-step design for the optimization of luminescence properties of Ba3ZnTa2O9phosphor. In the first step, the B-site equivalent doping (Ta5+substituted by Nb5+) was used to modulate the B-site atomic arrangement, which induced the formation of the cubic phase with B-site full disordering. In the second step, the A-site nonequivalent doping (Ba2+substituted by Eu3+) was used to decrease the oxygen defect concentration. After the two-step optimization, the photoluminescence excitation spectrum of Ba3-yEuyZnNb2O9(y= 0.1) shows a broad band excitation (300-400 nm), which is a good match with the near-UV LED chip emission. Even more importantly, the emission spectrum covers the entire visible spectral region and exhibits a remarkably enhanced emission intensity (a 40 times enhancement when compared to that of the intrinsic BZT). The fabricated LED device comprising an n-UV chip (= 370 nm) and a single-component Ba3-yEuyZnNb2O9(y= 0.1) phosphor coating emits a warm white light with a low correlated color temperature (CCT = 4813 K) and a good color rendering index (Ra= 82.36).",
journal = "Journal of Materials Chemistry C",
title = "Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors",
volume = "8",
number = "20",
pages = "6715-6723",
doi = "10.1039/D0TC01201G"
}
Li, X., Zhou, L., Hong, J., He, S., Jing, X., Dramićanin, M., Shi, J.,& Wu, M. (2020). Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors.
Journal of Materials Chemistry C, 8(20), 6715-6723.
https://doi.org/10.1039/D0TC01201G
Li X, Zhou L, Hong J, He S, Jing X, Dramićanin M, Shi J, Wu M. Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors. Journal of Materials Chemistry C. 2020;8(20):6715-6723
Li Xiaohui, Zhou Lei, Hong Junyu, He Shiman, Jing Xiping, Dramićanin Miroslav, Shi Jianxin, Wu Mingmei, "Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors" Journal of Materials Chemistry C, 8, no. 20 (2020):6715-6723,
https://doi.org/10.1039/D0TC01201G .
6
2
6

Luminescence temperature sensing using thin-films of undoped Gd2O3 and doped with Ho3+, Eu3+ and Er3+ prepared by plasma electrolytic oxidation

Ćirić, Aleksandar; Stojadinović, Stevan; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9060
AB  - The steady-state luminescence thermometry analysis was performed on thin-films of undoped Gd2O3 and Gd2O3 doped with Ho3+, Eu3+ and Er3+, created by the plasma electrolytic oxidation process. The experimental setup for luminescent measurements closely resembles the practical luminescent fiber-optic thermometer. The visible PL from Gd3+ was utilized for the luminescence intensity ratio method, exceling over the traditional method by using the thermally coupled levels, as it is superior by either better sensitivities, widened temperature range or improved temperature resolution. The relative uncertainty by our method is ~300 times lower @ 300 K for Gd2O3:Eu3+. The maximum relative sensitivities by the luminescence intensity ratio (LIR) of Gd2O3:Ho3+, Gd2O3:Eu3+ and Gd2O3:Er3+ are 0.12% @ 295 K, 0.44% @ 580 K and 1.1% @ 290 K, respectively. Line-shift showed a significant change solely for Eu3+ doped sample, by 0.076 cm−1 K−1. The full-width-half-maximum (FWHM) changes of undoped Gd2O3 and doped by Eu3+ at the high rate of 0.3 cm−1 K−1 @ 573 K and 0.53 cm−1 K−1 @ 300 K, respectively, but was marked impractical for other samples.
T2  - Ceramics International
T1  - Luminescence temperature sensing using thin-films of undoped Gd2O3 and doped with Ho3+, Eu3+ and Er3+ prepared by plasma electrolytic oxidation
VL  - 46
IS  - 14
SP  - 23223
EP  - 23231
DO  - 10.1016/j.ceramint.2020.06.106
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9060",
abstract = "The steady-state luminescence thermometry analysis was performed on thin-films of undoped Gd2O3 and Gd2O3 doped with Ho3+, Eu3+ and Er3+, created by the plasma electrolytic oxidation process. The experimental setup for luminescent measurements closely resembles the practical luminescent fiber-optic thermometer. The visible PL from Gd3+ was utilized for the luminescence intensity ratio method, exceling over the traditional method by using the thermally coupled levels, as it is superior by either better sensitivities, widened temperature range or improved temperature resolution. The relative uncertainty by our method is ~300 times lower @ 300 K for Gd2O3:Eu3+. The maximum relative sensitivities by the luminescence intensity ratio (LIR) of Gd2O3:Ho3+, Gd2O3:Eu3+ and Gd2O3:Er3+ are 0.12% @ 295 K, 0.44% @ 580 K and 1.1% @ 290 K, respectively. Line-shift showed a significant change solely for Eu3+ doped sample, by 0.076 cm−1 K−1. The full-width-half-maximum (FWHM) changes of undoped Gd2O3 and doped by Eu3+ at the high rate of 0.3 cm−1 K−1 @ 573 K and 0.53 cm−1 K−1 @ 300 K, respectively, but was marked impractical for other samples.",
journal = "Ceramics International",
title = "Luminescence temperature sensing using thin-films of undoped Gd2O3 and doped with Ho3+, Eu3+ and Er3+ prepared by plasma electrolytic oxidation",
volume = "46",
number = "14",
pages = "23223-23231",
doi = "10.1016/j.ceramint.2020.06.106"
}
Ćirić, A., Stojadinović, S.,& Dramićanin, M. (2020). Luminescence temperature sensing using thin-films of undoped Gd2O3 and doped with Ho3+, Eu3+ and Er3+ prepared by plasma electrolytic oxidation.
Ceramics International, 46(14), 23223-23231.
https://doi.org/10.1016/j.ceramint.2020.06.106
Ćirić A, Stojadinović S, Dramićanin M. Luminescence temperature sensing using thin-films of undoped Gd2O3 and doped with Ho3+, Eu3+ and Er3+ prepared by plasma electrolytic oxidation. Ceramics International. 2020;46(14):23223-23231
Ćirić Aleksandar, Stojadinović Stevan, Dramićanin Miroslav, "Luminescence temperature sensing using thin-films of undoped Gd2O3 and doped with Ho3+, Eu3+ and Er3+ prepared by plasma electrolytic oxidation" Ceramics International, 46, no. 14 (2020):23223-23231,
https://doi.org/10.1016/j.ceramint.2020.06.106 .
3
1
2

Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles

Kuzman, Sanja; Periša, Jovana; Đorđević, Vesna R.; Zeković, Ivana Lj.; Vukoje, Ivana D.; Antić, Željka; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Periša, Jovana
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Vukoje, Ivana D.
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9098
AB  - A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La0.95Eu0.05PO4) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu3+) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu3+ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La0.95Eu0.05PO4 host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La0.95Eu0.05PO4 from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La0.95Eu0.05PO4 increases more than three times when the Eu3+ excitation is supported by the localized surface plasmon resonance in the Ag/La0.95Eu0.05PO4 nanostructures.
T2  - Materials
T1  - Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles
VL  - 13
IS  - 14
SP  - 3071
DO  - 10.3390/ma13143071
ER  - 
@article{
author = "Kuzman, Sanja and Periša, Jovana and Đorđević, Vesna R. and Zeković, Ivana Lj. and Vukoje, Ivana D. and Antić, Željka and Dramićanin, Miroslav",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9098",
abstract = "A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La0.95Eu0.05PO4) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu3+) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu3+ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La0.95Eu0.05PO4 host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La0.95Eu0.05PO4 from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La0.95Eu0.05PO4 increases more than three times when the Eu3+ excitation is supported by the localized surface plasmon resonance in the Ag/La0.95Eu0.05PO4 nanostructures.",
journal = "Materials",
title = "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles",
volume = "13",
number = "14",
pages = "3071",
doi = "10.3390/ma13143071"
}
Kuzman, S., Periša, J., Đorđević, V. R., Zeković, I. Lj., Vukoje, I. D., Antić, Ž.,& Dramićanin, M. (2020). Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles.
Materials, 13(14), 3071.
https://doi.org/10.3390/ma13143071
Kuzman S, Periša J, Đorđević VR, Zeković IL, Vukoje ID, Antić Ž, Dramićanin M. Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles. Materials. 2020;13(14):3071
Kuzman Sanja, Periša Jovana, Đorđević Vesna R., Zeković Ivana Lj., Vukoje Ivana D., Antić Željka, Dramićanin Miroslav, "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles" Materials, 13, no. 14 (2020):3071,
https://doi.org/10.3390/ma13143071 .
3

Photoluminescence properties of nano-sized (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) phosphor powders

Kahouadji, Badis; Guerbous, Lakhdar; Jovanović, Dragana J.; Dramićanin, Miroslav; Souici, Abdelhafid

(2020)

TY  - JOUR
AU  - Kahouadji, Badis
AU  - Guerbous, Lakhdar
AU  - Jovanović, Dragana J.
AU  - Dramićanin, Miroslav
AU  - Souici, Abdelhafid
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9114
AB  - Herein we present the enhancement of photoluminescence properties of nano-sized LuPO4:Pr3+ phosphor powders synthesized by sol gel process with incorporation of yttrium ions inside of this single matrix to obtain (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) powders. Under UV excitation at 270 nm the emission spectra of LuPO4:Pr3+ nanopowder do not present any characteristics emission band attributed to 4f15d1→4f2 transitions of Pr3+ ions, while a large emission band has been observed which due to defects created in LuPO4 cell by doping considering the ionic radius of Pr3+ is larger compared to the ionic radius of Lu3+, this band extinguishes gradually at the time insertion of the Y3+ ions until its total disappearance (for x = 40 at. %).It was found that the emission spectra of (Lu1-xYx)PO4:Pr3+ nanopowders under λex = 230 nm presents only the characteristics emission bands of Pr3+ ions with a remarkable influence of the rate of Y3+ ions on the intensity of this bands. Furthermore, it was observed that the improvement in the luminescence properties of (Lu1-xYx)PO4:Pr3+ nanopowders is very remarkable in visible range.
T2  - Optical Materials
T1  - Photoluminescence properties of nano-sized (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) phosphor powders
VL  - 109
SP  - 110252
DO  - 10.1016/j.optmat.2020.110252
ER  - 
@article{
author = "Kahouadji, Badis and Guerbous, Lakhdar and Jovanović, Dragana J. and Dramićanin, Miroslav and Souici, Abdelhafid",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9114",
abstract = "Herein we present the enhancement of photoluminescence properties of nano-sized LuPO4:Pr3+ phosphor powders synthesized by sol gel process with incorporation of yttrium ions inside of this single matrix to obtain (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) powders. Under UV excitation at 270 nm the emission spectra of LuPO4:Pr3+ nanopowder do not present any characteristics emission band attributed to 4f15d1→4f2 transitions of Pr3+ ions, while a large emission band has been observed which due to defects created in LuPO4 cell by doping considering the ionic radius of Pr3+ is larger compared to the ionic radius of Lu3+, this band extinguishes gradually at the time insertion of the Y3+ ions until its total disappearance (for x = 40 at. %).It was found that the emission spectra of (Lu1-xYx)PO4:Pr3+ nanopowders under λex = 230 nm presents only the characteristics emission bands of Pr3+ ions with a remarkable influence of the rate of Y3+ ions on the intensity of this bands. Furthermore, it was observed that the improvement in the luminescence properties of (Lu1-xYx)PO4:Pr3+ nanopowders is very remarkable in visible range.",
journal = "Optical Materials",
title = "Photoluminescence properties of nano-sized (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) phosphor powders",
volume = "109",
pages = "110252",
doi = "10.1016/j.optmat.2020.110252"
}
Kahouadji, B., Guerbous, L., Jovanović, D. J., Dramićanin, M.,& Souici, A. (2020). Photoluminescence properties of nano-sized (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) phosphor powders.
Optical Materials, 109, 110252.
https://doi.org/10.1016/j.optmat.2020.110252
Kahouadji B, Guerbous L, Jovanović DJ, Dramićanin M, Souici A. Photoluminescence properties of nano-sized (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) phosphor powders. Optical Materials. 2020;109:110252
Kahouadji Badis, Guerbous Lakhdar, Jovanović Dragana J., Dramićanin Miroslav, Souici Abdelhafid, "Photoluminescence properties of nano-sized (Lu1-xYx)PO4:Pr3+ (x = 10, 20, 30, 40, 50 at. %) phosphor powders" Optical Materials, 109 (2020):110252,
https://doi.org/10.1016/j.optmat.2020.110252 .

Annealing effect on the photoluminescence properties of Ce3+ doped YPO4 nanophosphors

Kahouadji, Badis; Guerbous, Lakhdar; Jovanović, Dragana J.; Dramićanin, Miroslav; Samah, Madani; Lamiri, Lyes; Benchallal, Lotfi; Marinović-Cincović, Milena

(2019)

TY  - JOUR
AU  - Kahouadji, Badis
AU  - Guerbous, Lakhdar
AU  - Jovanović, Dragana J.
AU  - Dramićanin, Miroslav
AU  - Samah, Madani
AU  - Lamiri, Lyes
AU  - Benchallal, Lotfi
AU  - Marinović-Cincović, Milena
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0925346719301624
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8105
AB  - This work explores the influence of annealing temperature on microstructural and optical characteristics of Ce 3+ - doped YPO 4 nanopowders prepared by sol gel method. Samples were annealed at various temperatures (T = 300, 500, 700, 900, 1050 °C), their structure, morphology, and photoluminescent properties were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), TGA-DTA analysis and Photoluminescence spectroscopy (PL). X-ray diffraction analyses confirmed their pure tetragonal zircon structure with average grain size from 5 nm up to 30 nm in dependence on the calcination temperature. The SEM image shows quasi-spherical agglomerated nanoparticles with no heterogenic size. Photoluminescence emission spectra of powders were recorded using excitation wavelength at 245 nm. We investigated the influence of annealing temperature on the optical properties, for samples annealed up to 700 °C no emission has been observed, but the emission increased with annealing temperature above 700° and the characteristic Ce 3+ emission bands (4f 1 →4f 0 5d 1 ) have been observed. Emission intensity increased with annealing temperature due to beter crystallinity and incorporation of Ce 3+ ions in Y 3+ site.
T2  - Optical Materials
T1  - Annealing effect on the photoluminescence properties of Ce3+ doped YPO4 nanophosphors
VL  - 91
SP  - 35
EP  - 41
DO  - 10.1016/j.optmat.2019.02.052
ER  - 
@article{
author = "Kahouadji, Badis and Guerbous, Lakhdar and Jovanović, Dragana J. and Dramićanin, Miroslav and Samah, Madani and Lamiri, Lyes and Benchallal, Lotfi and Marinović-Cincović, Milena",
year = "2019",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0925346719301624, http://vinar.vin.bg.ac.rs/handle/123456789/8105",
abstract = "This work explores the influence of annealing temperature on microstructural and optical characteristics of Ce 3+ - doped YPO 4 nanopowders prepared by sol gel method. Samples were annealed at various temperatures (T = 300, 500, 700, 900, 1050 °C), their structure, morphology, and photoluminescent properties were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), TGA-DTA analysis and Photoluminescence spectroscopy (PL). X-ray diffraction analyses confirmed their pure tetragonal zircon structure with average grain size from 5 nm up to 30 nm in dependence on the calcination temperature. The SEM image shows quasi-spherical agglomerated nanoparticles with no heterogenic size. Photoluminescence emission spectra of powders were recorded using excitation wavelength at 245 nm. We investigated the influence of annealing temperature on the optical properties, for samples annealed up to 700 °C no emission has been observed, but the emission increased with annealing temperature above 700° and the characteristic Ce 3+ emission bands (4f 1 →4f 0 5d 1 ) have been observed. Emission intensity increased with annealing temperature due to beter crystallinity and incorporation of Ce 3+ ions in Y 3+ site.",
journal = "Optical Materials",
title = "Annealing effect on the photoluminescence properties of Ce3+ doped YPO4 nanophosphors",
volume = "91",
pages = "35-41",
doi = "10.1016/j.optmat.2019.02.052"
}
Kahouadji, B., Guerbous, L., Jovanović, D. J., Dramićanin, M., Samah, M., Lamiri, L., Benchallal, L.,& Marinović-Cincović, M. (2019). Annealing effect on the photoluminescence properties of Ce3+ doped YPO4 nanophosphors.
Optical Materials, 91, 35-41.
https://doi.org/10.1016/j.optmat.2019.02.052
Kahouadji B, Guerbous L, Jovanović DJ, Dramićanin M, Samah M, Lamiri L, Benchallal L, Marinović-Cincović M. Annealing effect on the photoluminescence properties of Ce3+ doped YPO4 nanophosphors. Optical Materials. 2019;91:35-41
Kahouadji Badis, Guerbous Lakhdar, Jovanović Dragana J., Dramićanin Miroslav, Samah Madani, Lamiri Lyes, Benchallal Lotfi, Marinović-Cincović Milena, "Annealing effect on the photoluminescence properties of Ce3+ doped YPO4 nanophosphors" Optical Materials, 91 (2019):35-41,
https://doi.org/10.1016/j.optmat.2019.02.052 .
3
1
3

Structure and enhanced antimicrobial activity of mechanically activated nano TiO2

Pavlović, Vera P.; Vujančević, Jelena; Mašković, Pavle Z.; Ćirković, Jovana; Papan, Jelena; Kosanović, Darko; Dramićanin, Miroslav; Petrović, Predrag B.; Vlahović, Branislav; Pavlović, Vladimir B.

(2019)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Mašković, Pavle Z.
AU  - Ćirković, Jovana
AU  - Papan, Jelena
AU  - Kosanović, Darko
AU  - Dramićanin, Miroslav
AU  - Petrović, Predrag B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8384
AB  - Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.
T2  - Journal of the American Ceramic Society
T1  - Structure and enhanced antimicrobial activity of mechanically activated nano TiO2
VL  - 102
IS  - 12
SP  - 7735
EP  - 7745
DO  - 10.1111/jace.16668
ER  - 
@article{
author = "Pavlović, Vera P. and Vujančević, Jelena and Mašković, Pavle Z. and Ćirković, Jovana and Papan, Jelena and Kosanović, Darko and Dramićanin, Miroslav and Petrović, Predrag B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8384",
abstract = "Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.",
journal = "Journal of the American Ceramic Society",
title = "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2",
volume = "102",
number = "12",
pages = "7735-7745",
doi = "10.1111/jace.16668"
}
Pavlović, V. P., Vujančević, J., Mašković, P. Z., Ćirković, J., Papan, J., Kosanović, D., Dramićanin, M., Petrović, P. B., Vlahović, B.,& Pavlović, V. B. (2019). Structure and enhanced antimicrobial activity of mechanically activated nano TiO2.
Journal of the American Ceramic Society, 102(12), 7735-7745.
https://doi.org/10.1111/jace.16668
Pavlović VP, Vujančević J, Mašković PZ, Ćirković J, Papan J, Kosanović D, Dramićanin M, Petrović PB, Vlahović B, Pavlović VB. Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. Journal of the American Ceramic Society. 2019;102(12):7735-7745
Pavlović Vera P., Vujančević Jelena, Mašković Pavle Z., Ćirković Jovana, Papan Jelena, Kosanović Darko, Dramićanin Miroslav, Petrović Predrag B., Vlahović Branislav, Pavlović Vladimir B., "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2" Journal of the American Ceramic Society, 102, no. 12 (2019):7735-7745,
https://doi.org/10.1111/jace.16668 .
7
2
2

Structure and enhanced antimicrobial activity of mechanically activated nano TiO2

Pavlović, Vera P.; Vujančević, Jelena; Mašković, Pavle Z.; Ćirković, Jovana; Papan, Jelena; Kosanović, Darko; Dramićanin, Miroslav; Petrović, Predrag B.; Vlahović, Branislav; Pavlović, Vladimir B.

(2019)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Vujančević, Jelena
AU  - Mašković, Pavle Z.
AU  - Ćirković, Jovana
AU  - Papan, Jelena
AU  - Kosanović, Darko
AU  - Dramićanin, Miroslav
AU  - Petrović, Predrag B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8380
AB  - Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.
T2  - Journal of the American Ceramic Society
T1  - Structure and enhanced antimicrobial activity of mechanically activated nano TiO2
VL  - 102
IS  - 12
SP  - 7735
EP  - 7745
DO  - 10.1111/jace.16668
ER  - 
@article{
author = "Pavlović, Vera P. and Vujančević, Jelena and Mašković, Pavle Z. and Ćirković, Jovana and Papan, Jelena and Kosanović, Darko and Dramićanin, Miroslav and Petrović, Predrag B. and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2019",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8380",
abstract = "Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (Eg) and, consequently, to investigate changes in the Eg value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.",
journal = "Journal of the American Ceramic Society",
title = "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2",
volume = "102",
number = "12",
pages = "7735-7745",
doi = "10.1111/jace.16668"
}
Pavlović, V. P., Vujančević, J., Mašković, P. Z., Ćirković, J., Papan, J., Kosanović, D., Dramićanin, M., Petrović, P. B., Vlahović, B.,& Pavlović, V. B. (2019). Structure and enhanced antimicrobial activity of mechanically activated nano TiO2.
Journal of the American Ceramic Society, 102(12), 7735-7745.
https://doi.org/10.1111/jace.16668
Pavlović VP, Vujančević J, Mašković PZ, Ćirković J, Papan J, Kosanović D, Dramićanin M, Petrović PB, Vlahović B, Pavlović VB. Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. Journal of the American Ceramic Society. 2019;102(12):7735-7745
Pavlović Vera P., Vujančević Jelena, Mašković Pavle Z., Ćirković Jovana, Papan Jelena, Kosanović Darko, Dramićanin Miroslav, Petrović Predrag B., Vlahović Branislav, Pavlović Vladimir B., "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2" Journal of the American Ceramic Society, 102, no. 12 (2019):7735-7745,
https://doi.org/10.1111/jace.16668 .
7
2
2

Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry

Dramićanin, Miroslav; Milićević, Bojana R.; Đorđević, Vesna R.; Ristić, Zoran; Zhou, Jianbang; Milivojević, Dušan; Papan, Jelena; Brik, Mikhail G.; Ma, Chong‐Geng; Srivastava, Alok M; Wu, Mingmei

(2019)

TY  - JOUR
AU  - Dramićanin, Miroslav
AU  - Milićević, Bojana R.
AU  - Đorđević, Vesna R.
AU  - Ristić, Zoran
AU  - Zhou, Jianbang
AU  - Milivojević, Dušan
AU  - Papan, Jelena
AU  - Brik, Mikhail G.
AU  - Ma, Chong‐Geng
AU  - Srivastava, Alok M
AU  - Wu, Mingmei
PY  - 2019
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201901590
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8360
AB  - Luminescence of monoclinic lithium metatitanate (Li2TiO3) powders activated with different quantities of Mn4+ is studied in detail. Its strong deep-red emission arising from the Mn4+ 2Eg → 4A2g spin forbidden transition is centered at around 688 nm and is suitable for luminescence thermometry. Structural and electron paramagnetic resonance analyses show that Mn4+ ions are equally distributed in two almost identical Ti4+ sites in which they are octahedrally coordinated by six oxygen ions. Calculations based on the exchange charge model of the crystal field provided values of Racah parameters (B=760 cm−1, C= 2993 cm−1), crystal-field splitting Dq= 2043 cm−1, and the nephelauxetic parameter β1=0.9775. The maximal quantum efficiency of 24.1% at room temperature is found for 0.126% Mn4+ concentration. Temperature quenching of emission occurs by a cross-over via 4T2 excited state of the Mn4+ ions with T1/2=262 K and is quite favorable for the application in the lifetime-based luminescence thermometry since relative changes in emission decay values are exceptionally-large (around 3.21% at room temperature). We derived theoretical expressions for the temperature dependence of the absolute and relative sensitivities and discuss the influence of host material properties on lifetime sensitivities. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - ChemistrySelect
T1  - Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry
VL  - 4
IS  - 24
SP  - 7067
EP  - 7075
DO  - 10.1002/slct.201901590
ER  - 
@article{
author = "Dramićanin, Miroslav and Milićević, Bojana R. and Đorđević, Vesna R. and Ristić, Zoran and Zhou, Jianbang and Milivojević, Dušan and Papan, Jelena and Brik, Mikhail G. and Ma, Chong‐Geng and Srivastava, Alok M and Wu, Mingmei",
year = "2019",
url = "https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201901590, http://vinar.vin.bg.ac.rs/handle/123456789/8360",
abstract = "Luminescence of monoclinic lithium metatitanate (Li2TiO3) powders activated with different quantities of Mn4+ is studied in detail. Its strong deep-red emission arising from the Mn4+ 2Eg → 4A2g spin forbidden transition is centered at around 688 nm and is suitable for luminescence thermometry. Structural and electron paramagnetic resonance analyses show that Mn4+ ions are equally distributed in two almost identical Ti4+ sites in which they are octahedrally coordinated by six oxygen ions. Calculations based on the exchange charge model of the crystal field provided values of Racah parameters (B=760 cm−1, C= 2993 cm−1), crystal-field splitting Dq= 2043 cm−1, and the nephelauxetic parameter β1=0.9775. The maximal quantum efficiency of 24.1% at room temperature is found for 0.126% Mn4+ concentration. Temperature quenching of emission occurs by a cross-over via 4T2 excited state of the Mn4+ ions with T1/2=262 K and is quite favorable for the application in the lifetime-based luminescence thermometry since relative changes in emission decay values are exceptionally-large (around 3.21% at room temperature). We derived theoretical expressions for the temperature dependence of the absolute and relative sensitivities and discuss the influence of host material properties on lifetime sensitivities. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "ChemistrySelect",
title = "Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry",
volume = "4",
number = "24",
pages = "7067-7075",
doi = "10.1002/slct.201901590"
}
Dramićanin, M., Milićević, B. R., Đorđević, V. R., Ristić, Z., Zhou, J., Milivojević, D., Papan, J., Brik, M. G., Ma, C., Srivastava, A. M.,& Wu, M. (2019). Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry.
ChemistrySelect, 4(24), 7067-7075.
https://doi.org/10.1002/slct.201901590
Dramićanin M, Milićević BR, Đorđević VR, Ristić Z, Zhou J, Milivojević D, Papan J, Brik MG, Ma C, Srivastava AM, Wu M. Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry. ChemistrySelect. 2019;4(24):7067-7075
Dramićanin Miroslav, Milićević Bojana R., Đorđević Vesna R., Ristić Zoran, Zhou Jianbang, Milivojević Dušan, Papan Jelena, Brik Mikhail G., Ma Chong‐Geng, Srivastava Alok M, Wu Mingmei, "Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry" ChemistrySelect, 4, no. 24 (2019):7067-7075,
https://doi.org/10.1002/slct.201901590 .
1
20
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19

Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study

Papan, Jelena; Jovanović, Dragana J.; Sekulić, Milica; Glais, Estelle; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Papan, Jelena
AU  - Jovanović, Dragana J.
AU  - Sekulić, Milica
AU  - Glais, Estelle
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0032591019301093
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8057
AB  - Defect-fluorite structured Eu 3+ -doped Y 2 Sn 2 O 7 nanoparticles (30–40 nm) were successfully prepared through a facile co-precipitation method without any organic additives or templates followed by calcination in air. Luminescent properties of the as-prepared Y 2-x Eu x Sn 2 O 7 (0.02 ≤ x ≤ 0.6) nanophosphors were fully characterized from an experimental and theoretical point of view (excitation, emission, lifetime, critical concentration, temperature-dependent luminescence and thermal stability, type of interactions and the Judd-Ofelt analysis). The nanophosphors showed relatively sharp excitation bands from 360 to 530 nm and exhibited characteristic emission bands with the most intensive emission centered at 612 nm. In addition, Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 samples were prepared in order to study how substitution of RE 3+ (Y 3+ with Gd 3+ and Lu 3+ ions) influences on luminescent properties of RE 1.98 Eu 0.02 Sn 2 O 7 and thermal stability of their luminescence. In order to understand better luminescent properties, the Judd–Ofelt analysis was applied to all the synthesized powders. The highest value of quantum efficiency, ~96%, was estimated for Lu 1.98 Eu 0.02 Sn 2 O 7 . To assess potential application in high-power LEDs, the temperature-dependent emission spectra of Y 1.98 Eu 0.02 Sn 2 O 7 , Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 nanophosphors were studied. © 2019 Elsevier B.V.
T2  - Powder Technology
T1  - Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study
VL  - 346
SP  - 150
EP  - 159
DO  - 10.1016/j.powtec.2019.02.013
ER  - 
@article{
author = "Papan, Jelena and Jovanović, Dragana J. and Sekulić, Milica and Glais, Estelle and Dramićanin, Miroslav",
year = "2019",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0032591019301093, http://vinar.vin.bg.ac.rs/handle/123456789/8057",
abstract = "Defect-fluorite structured Eu 3+ -doped Y 2 Sn 2 O 7 nanoparticles (30–40 nm) were successfully prepared through a facile co-precipitation method without any organic additives or templates followed by calcination in air. Luminescent properties of the as-prepared Y 2-x Eu x Sn 2 O 7 (0.02 ≤ x ≤ 0.6) nanophosphors were fully characterized from an experimental and theoretical point of view (excitation, emission, lifetime, critical concentration, temperature-dependent luminescence and thermal stability, type of interactions and the Judd-Ofelt analysis). The nanophosphors showed relatively sharp excitation bands from 360 to 530 nm and exhibited characteristic emission bands with the most intensive emission centered at 612 nm. In addition, Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 samples were prepared in order to study how substitution of RE 3+ (Y 3+ with Gd 3+ and Lu 3+ ions) influences on luminescent properties of RE 1.98 Eu 0.02 Sn 2 O 7 and thermal stability of their luminescence. In order to understand better luminescent properties, the Judd–Ofelt analysis was applied to all the synthesized powders. The highest value of quantum efficiency, ~96%, was estimated for Lu 1.98 Eu 0.02 Sn 2 O 7 . To assess potential application in high-power LEDs, the temperature-dependent emission spectra of Y 1.98 Eu 0.02 Sn 2 O 7 , Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 nanophosphors were studied. © 2019 Elsevier B.V.",
journal = "Powder Technology",
title = "Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study",
volume = "346",
pages = "150-159",
doi = "10.1016/j.powtec.2019.02.013"
}
Papan, J., Jovanović, D. J., Sekulić, M., Glais, E.,& Dramićanin, M. (2019). Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study.
Powder Technology, 346, 150-159.
https://doi.org/10.1016/j.powtec.2019.02.013
Papan J, Jovanović DJ, Sekulić M, Glais E, Dramićanin M. Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study. Powder Technology. 2019;346:150-159
Papan Jelena, Jovanović Dragana J., Sekulić Milica, Glais Estelle, Dramićanin Miroslav, "Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study" Powder Technology, 346 (2019):150-159,
https://doi.org/10.1016/j.powtec.2019.02.013 .
8
4
6

The influence of gamma irradiation on the color change of wool, linen, silk, and cotton fabrics used in cultural heritage artifacts

Vujčić, Ivica; Mašić, Slobodan; Medić, Mina M.; Milićević, Bojana R.; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Vujčić, Ivica
AU  - Mašić, Slobodan
AU  - Medić, Mina M.
AU  - Milićević, Bojana R.
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0969806X18307163
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8003
AB  - Fabrics made of wool, linen, silk, and cotton, which are used in the making of artifacts of cultural heritage, were divided into three groups. The first group wasn't dyed, the second group was dyed with natural dye (using sour cherry), and the third one was dyed with artificial aniline dye. For the conservation purposes, all samples were exposed at ambient temperature to gamma radiation doses, from 0.5 to 25 kGy, using a Co-60 irradiator. The influence of gamma irradiation treatment on the color changes was investigated. The obtained results revealed that the irradiation affects the color changes in all samples. All samples became more or less darker under the influence of gamma irradiation. This change in darkness is most pronounced in samples dyed with natural colors. Also, the highest differences in color change and darkness were observed in linen samples. © 2018 Elsevier Ltd
T2  - Radiation Physics and Chemistry
T1  - The influence of gamma irradiation on the color change of wool, linen, silk, and cotton fabrics used in cultural heritage artifacts
VL  - 156
SP  - 307
EP  - 313
DO  - 10.1016/j.radphyschem.2018.12.001
ER  - 
@article{
author = "Vujčić, Ivica and Mašić, Slobodan and Medić, Mina M. and Milićević, Bojana R. and Dramićanin, Miroslav",
year = "2019",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0969806X18307163, http://vinar.vin.bg.ac.rs/handle/123456789/8003",
abstract = "Fabrics made of wool, linen, silk, and cotton, which are used in the making of artifacts of cultural heritage, were divided into three groups. The first group wasn't dyed, the second group was dyed with natural dye (using sour cherry), and the third one was dyed with artificial aniline dye. For the conservation purposes, all samples were exposed at ambient temperature to gamma radiation doses, from 0.5 to 25 kGy, using a Co-60 irradiator. The influence of gamma irradiation treatment on the color changes was investigated. The obtained results revealed that the irradiation affects the color changes in all samples. All samples became more or less darker under the influence of gamma irradiation. This change in darkness is most pronounced in samples dyed with natural colors. Also, the highest differences in color change and darkness were observed in linen samples. © 2018 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "The influence of gamma irradiation on the color change of wool, linen, silk, and cotton fabrics used in cultural heritage artifacts",
volume = "156",
pages = "307-313",
doi = "10.1016/j.radphyschem.2018.12.001"
}
Vujčić, I., Mašić, S., Medić, M. M., Milićević, B. R.,& Dramićanin, M. (2019). The influence of gamma irradiation on the color change of wool, linen, silk, and cotton fabrics used in cultural heritage artifacts.
Radiation Physics and Chemistry, 156, 307-313.
https://doi.org/10.1016/j.radphyschem.2018.12.001
Vujčić I, Mašić S, Medić MM, Milićević BR, Dramićanin M. The influence of gamma irradiation on the color change of wool, linen, silk, and cotton fabrics used in cultural heritage artifacts. Radiation Physics and Chemistry. 2019;156:307-313
Vujčić Ivica, Mašić Slobodan, Medić Mina M., Milićević Bojana R., Dramićanin Miroslav, "The influence of gamma irradiation on the color change of wool, linen, silk, and cotton fabrics used in cultural heritage artifacts" Radiation Physics and Chemistry, 156 (2019):307-313,
https://doi.org/10.1016/j.radphyschem.2018.12.001 .
1
4
2
2

Judd-Ofelt and chromaticity analysis of hafnia doped with trivalent europium as a potential white LED phosphor

Ćirić, Aleksandar; Stojadinović, Stevan; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0925346718308073
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8008
AB  - Judd-Ofelt analysis of HfO2:Eu3+ with various europium doping concentrations, formed by plasma electrolytic oxidation, had been investigated. Ω2 parameter is increasing, while Ω4 parameter shows no concentration dependence. For the highest europium doping concentration of 0.62 at% Ω2 = 4.03·10−20 cm2 and Ω4 = 2.26·10−20 cm2. Radiative transition probabilities of each allowed emitting level were calculated. The radiative lifetime of 5D0 emitting level and a relatively high cross section of emission 5D0→7F2 were estimated: 1.58 ms and 13.49·10−22 cm2, respectively. CIELUV coordinates of photoluminescence of HfO2 doped with various europium concentrations and by excitation with UV 270 nm and 395 nm beam had been calculated and plotted to the CIE 1976 diagram. For low concentrations HfO2:Eu3+ and UV excitation the material gives almost pure white luminescence, which is an indication for its potential use as a white LED phosphor. © 2018 Elsevier B.V.
T2  - Optical Materials
T1  - Judd-Ofelt and chromaticity analysis of hafnia doped with trivalent europium as a potential white LED phosphor
VL  - 88
SP  - 392
EP  - 395
DO  - 10.1016/j.optmat.2018.11.056
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Dramićanin, Miroslav",
year = "2019",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0925346718308073, http://vinar.vin.bg.ac.rs/handle/123456789/8008",
abstract = "Judd-Ofelt analysis of HfO2:Eu3+ with various europium doping concentrations, formed by plasma electrolytic oxidation, had been investigated. Ω2 parameter is increasing, while Ω4 parameter shows no concentration dependence. For the highest europium doping concentration of 0.62 at% Ω2 = 4.03·10−20 cm2 and Ω4 = 2.26·10−20 cm2. Radiative transition probabilities of each allowed emitting level were calculated. The radiative lifetime of 5D0 emitting level and a relatively high cross section of emission 5D0→7F2 were estimated: 1.58 ms and 13.49·10−22 cm2, respectively. CIELUV coordinates of photoluminescence of HfO2 doped with various europium concentrations and by excitation with UV 270 nm and 395 nm beam had been calculated and plotted to the CIE 1976 diagram. For low concentrations HfO2:Eu3+ and UV excitation the material gives almost pure white luminescence, which is an indication for its potential use as a white LED phosphor. © 2018 Elsevier B.V.",
journal = "Optical Materials",
title = "Judd-Ofelt and chromaticity analysis of hafnia doped with trivalent europium as a potential white LED phosphor",
volume = "88",
pages = "392-395",
doi = "10.1016/j.optmat.2018.11.056"
}
Ćirić, A., Stojadinović, S.,& Dramićanin, M. (2019). Judd-Ofelt and chromaticity analysis of hafnia doped with trivalent europium as a potential white LED phosphor.
Optical Materials, 88, 392-395.
https://doi.org/10.1016/j.optmat.2018.11.056
Ćirić A, Stojadinović S, Dramićanin M. Judd-Ofelt and chromaticity analysis of hafnia doped with trivalent europium as a potential white LED phosphor. Optical Materials. 2019;88:392-395
Ćirić Aleksandar, Stojadinović Stevan, Dramićanin Miroslav, "Judd-Ofelt and chromaticity analysis of hafnia doped with trivalent europium as a potential white LED phosphor" Optical Materials, 88 (2019):392-395,
https://doi.org/10.1016/j.optmat.2018.11.056 .
12
11
11

Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles

Periša, Jovana; Lenhardt Acković, Lea; Jovanović, Dragana J.; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Periša, Jovana
AU  - Lenhardt Acković, Lea
AU  - Jovanović, Dragana J.
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0925346719300345
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8043
AB  - EuPO4 and Eu3+-activated REPO4 (RE = La, Dy, Er) ultrasmall fluorescent nanoparticles (NPs) with an average diameter of 2.1 nm were prepared via colloidal synthesis and tested for sensing Cu2+ and other heavy-metal ions. The pure monoclinic monazite crystal structure (space group P121/n1) of the synthesized particles was confirmed using X-ray diffraction measurements, and transmission electron microscopy images showed round particles with a narrow particle-size distribution. The NPs exhibited intense red emission, which is characteristic of the f-f electronic transition of Eu3+, and the quenching of their emission in the presence of heavy-metal ions was revealed by dispersing colloidal particles in a TRIS buffer and then performing photoluminescence measurements. Strong quenching of the emission (at a rate of 0.195 μM−1) was observed upon the addition of Cu2+ ions over the concentration range of 0–10 μM with a limit of detection of 60 nM for Cu2+. The recovery of nearly 90% of the original emission intensity of the probe was achieved via the addition of ethylendiaminetetraacetic acid and was possible in five quenching/recovery cycles. © 2019
T2  - Optical Materials
T1  - Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles
VL  - 89
SP  - 142
EP  - 148
DO  - 10.1016/j.optmat.2018.12.059
ER  - 
@article{
author = "Periša, Jovana and Lenhardt Acković, Lea and Jovanović, Dragana J. and Dramićanin, Miroslav",
year = "2019",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0925346719300345, http://vinar.vin.bg.ac.rs/handle/123456789/8043",
abstract = "EuPO4 and Eu3+-activated REPO4 (RE = La, Dy, Er) ultrasmall fluorescent nanoparticles (NPs) with an average diameter of 2.1 nm were prepared via colloidal synthesis and tested for sensing Cu2+ and other heavy-metal ions. The pure monoclinic monazite crystal structure (space group P121/n1) of the synthesized particles was confirmed using X-ray diffraction measurements, and transmission electron microscopy images showed round particles with a narrow particle-size distribution. The NPs exhibited intense red emission, which is characteristic of the f-f electronic transition of Eu3+, and the quenching of their emission in the presence of heavy-metal ions was revealed by dispersing colloidal particles in a TRIS buffer and then performing photoluminescence measurements. Strong quenching of the emission (at a rate of 0.195 μM−1) was observed upon the addition of Cu2+ ions over the concentration range of 0–10 μM with a limit of detection of 60 nM for Cu2+. The recovery of nearly 90% of the original emission intensity of the probe was achieved via the addition of ethylendiaminetetraacetic acid and was possible in five quenching/recovery cycles. © 2019",
journal = "Optical Materials",
title = "Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles",
volume = "89",
pages = "142-148",
doi = "10.1016/j.optmat.2018.12.059"
}
Periša, J., Lenhardt Acković, L., Jovanović, D. J.,& Dramićanin, M. (2019). Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles.
Optical Materials, 89, 142-148.
https://doi.org/10.1016/j.optmat.2018.12.059
Periša J, Lenhardt Acković L, Jovanović DJ, Dramićanin M. Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles. Optical Materials. 2019;89:142-148
Periša Jovana, Lenhardt Acković Lea, Jovanović Dragana J., Dramićanin Miroslav, "Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles" Optical Materials, 89 (2019):142-148,
https://doi.org/10.1016/j.optmat.2018.12.059 .
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Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement

Li, Xiaohui; Milićević, Bojana R.; Dramićanin, Miroslav; Jing, Xiping; Tang, Qiang; Shi, Jianxin; Wu, Mingmei

(2019)

TY  - JOUR
AU  - Li, Xiaohui
AU  - Milićević, Bojana R.
AU  - Dramićanin, Miroslav
AU  - Jing, Xiping
AU  - Tang, Qiang
AU  - Shi, Jianxin
AU  - Wu, Mingmei
PY  - 2019
UR  - http://xlink.rsc.org/?DOI=C9TC00159J
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8087
AB  - Single-component white light phosphors with a broad and full color spectrum are urgently required to overcome residual problems with commercial phosphors. In this paper, we describe how Eu3+, as the dopant of Sr3ZnTa2O9 (SZT), plays an important role in structural modulation (including structural order-disorder and intrinsic oxygen defects), as demonstrated by electronic structural calculations and systematic experiments. Furthermore, D-5(0) F-7(2) emission of Eu3+ provides the red component of the emission spectrum and increases the color rendering index of SZT:Eu3+ phosphors. Consequently, the resulting phosphor SZT:10%Eu3+ shows significantly enhanced emission intensity, and its broadband emission covers the entire visible region from 400 nm to 720 nm. A fabricated LED device using a near-ultraviolet 370 nm chip coated with a single-component, the SZT:10%Eu3+ phosphor, shows warm white emission with a high color rendering index (R-a = 82).
T2  - Journal of Materials Chemistry C
T1  - Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement
VL  - 7
IS  - 9
SP  - 2596
EP  - 2603
DO  - 10.1039/C9TC00159J
ER  - 
@article{
author = "Li, Xiaohui and Milićević, Bojana R. and Dramićanin, Miroslav and Jing, Xiping and Tang, Qiang and Shi, Jianxin and Wu, Mingmei",
year = "2019",
url = "http://xlink.rsc.org/?DOI=C9TC00159J, http://vinar.vin.bg.ac.rs/handle/123456789/8087",
abstract = "Single-component white light phosphors with a broad and full color spectrum are urgently required to overcome residual problems with commercial phosphors. In this paper, we describe how Eu3+, as the dopant of Sr3ZnTa2O9 (SZT), plays an important role in structural modulation (including structural order-disorder and intrinsic oxygen defects), as demonstrated by electronic structural calculations and systematic experiments. Furthermore, D-5(0) F-7(2) emission of Eu3+ provides the red component of the emission spectrum and increases the color rendering index of SZT:Eu3+ phosphors. Consequently, the resulting phosphor SZT:10%Eu3+ shows significantly enhanced emission intensity, and its broadband emission covers the entire visible region from 400 nm to 720 nm. A fabricated LED device using a near-ultraviolet 370 nm chip coated with a single-component, the SZT:10%Eu3+ phosphor, shows warm white emission with a high color rendering index (R-a = 82).",
journal = "Journal of Materials Chemistry C",
title = "Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement",
volume = "7",
number = "9",
pages = "2596-2603",
doi = "10.1039/C9TC00159J"
}
Li, X., Milićević, B. R., Dramićanin, M., Jing, X., Tang, Q., Shi, J.,& Wu, M. (2019). Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement.
Journal of Materials Chemistry C, 7(9), 2596-2603.
https://doi.org/10.1039/C9TC00159J
Li X, Milićević BR, Dramićanin M, Jing X, Tang Q, Shi J, Wu M. Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement. Journal of Materials Chemistry C. 2019;7(9):2596-2603
Li Xiaohui, Milićević Bojana R., Dramićanin Miroslav, Jing Xiping, Tang Qiang, Shi Jianxin, Wu Mingmei, "Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement" Journal of Materials Chemistry C, 7, no. 9 (2019):2596-2603,
https://doi.org/10.1039/C9TC00159J .
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