TY  - JOUR
AU  - Tot, Nataša
AU  - Despotović, Vesna
AU  - Panić, Sanja
AU  - Kordić, Branko
AU  - Finčur, Nina
AU  - Prekodravac, Jovana
AU  - Jakimov, Dimitar
AU  - Putnik, Predrag
AU  - Abramović, Biljana
AU  - Šojić Merkulov, Daniela
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13126
AB  - This study aimed to compare the effectiveness of adsorption and photocatalysis techniques at removing the herbicide clomazone (CLO) and the antidepressant known as amitriptyline (AMI) from water. This study employed kinetic models to analyze the removal processes and assess the potential toxicity of the treated water. The structure and morphology of the prepared multi-walled carbon nanotubes were characterized as adsorbents by transmission electron microscopy, X-ray diffraction, Fourier transform infrared techniques, and Raman spectroscopy. The adsorption kinetics of CLO and AMI were studied on the pristine and functionalized multi-walled carbon nanotubes. Kinetic studies were performed by modeling the obtained experimental data using three kinetic models: pseudo-first-order, pseudo-second-order, and Elovich kinetic models. On the other hand, the efficiency of CLO and AMI photodegradation was examined as a function of the type of irradiation (UV and simulated solar irradiation) and type of TiO2 photocatalyst (Aeroxide and Kronos). Under the experimental conditions employed, the reaction followed pseudo-first-order kinetics. Additionally, in order to assess the toxicity of water containing CLO, AMI, and their intermediates, toxicity assessments were conducted using human fetal lung fibroblast cells. The results obtained indicate the effectiveness of both methods and provide valuable insights into their removal mechanisms, contributing to the advancement of sustainable water treatment strategies.
T2  - Materials
T1  - Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment
VL  - 17
IS  - 6
SP  - 1369
DO  - 10.3390/ma17061369
ER  - 

@article{
author = "Tot, Nataša and Despotović, Vesna and Panić, Sanja and Kordić, Branko and Finčur, Nina and Prekodravac, Jovana and Jakimov, Dimitar and Putnik, Predrag and Abramović, Biljana and Šojić Merkulov, Daniela",
year = "2024",
abstract = "This study aimed to compare the effectiveness of adsorption and photocatalysis techniques at removing the herbicide clomazone (CLO) and the antidepressant known as amitriptyline (AMI) from water. This study employed kinetic models to analyze the removal processes and assess the potential toxicity of the treated water. The structure and morphology of the prepared multi-walled carbon nanotubes were characterized as adsorbents by transmission electron microscopy, X-ray diffraction, Fourier transform infrared techniques, and Raman spectroscopy. The adsorption kinetics of CLO and AMI were studied on the pristine and functionalized multi-walled carbon nanotubes. Kinetic studies were performed by modeling the obtained experimental data using three kinetic models: pseudo-first-order, pseudo-second-order, and Elovich kinetic models. On the other hand, the efficiency of CLO and AMI photodegradation was examined as a function of the type of irradiation (UV and simulated solar irradiation) and type of TiO2 photocatalyst (Aeroxide and Kronos). Under the experimental conditions employed, the reaction followed pseudo-first-order kinetics. Additionally, in order to assess the toxicity of water containing CLO, AMI, and their intermediates, toxicity assessments were conducted using human fetal lung fibroblast cells. The results obtained indicate the effectiveness of both methods and provide valuable insights into their removal mechanisms, contributing to the advancement of sustainable water treatment strategies.",
journal = "Materials",
title = "Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment",
volume = "17",
number = "6",
pages = "1369",
doi = "10.3390/ma17061369"
}

Tot, N., Despotović, V., Panić, S., Kordić, B., Finčur, N., Prekodravac, J., Jakimov, D., Putnik, P., Abramović, B.,& Šojić Merkulov, D.. (2024). Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment. in Materials, 17(6), 1369.
https://doi.org/10.3390/ma17061369

Tot N, Despotović V, Panić S, Kordić B, Finčur N, Prekodravac J, Jakimov D, Putnik P, Abramović B, Šojić Merkulov D. Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment. in Materials. 2024;17(6):1369.
doi:10.3390/ma17061369 .

Tot, Nataša, Despotović, Vesna, Panić, Sanja, Kordić, Branko, Finčur, Nina, Prekodravac, Jovana, Jakimov, Dimitar, Putnik, Predrag, Abramović, Biljana, Šojić Merkulov, Daniela, "Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment" in Materials, 17, no. 6 (2024):1369,
https://doi.org/10.3390/ma17061369 . .

TY  - CONF
AU  - Čomor, Mirjana
AU  - Abazović, Nadica
AU  - Savić, T. D.
AU  - Šojić Merkulov, Daniela
AU  - Despotović, Vesna
AU  - Armaković, Sanja
AU  - Finčur, Nina
AU  - Lazarević, Marina
AU  - Uzelac, Maria
AU  - Abramović, Biljana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12379
AB  - Hydrothermally synthesized zirconia nanopowders: pure and doped with Si4+ ions were spectroscopically characterized and used as photocatalysts for degradation of herbicides sulcotrione and fluroxypyr. Zirconia is wide band gap ceramic (Eg ~ 5 eV) however, synthesized nanopowders showed unexpected, modest absorbance in visible light range. That fact inspired photocatalytical degradation of herbicides with wide utilization, using solar irradiation (SI) in laboratory conditions. In the scope of this study, degradation of herbicides was only slightly achieved (irradiation time 2h).
C3  - PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry
T1  - Zirconia based photocatalysts in degradation of selected herbicides
SP  - 147
EP  - 150
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10711
ER  - 

@conference{
author = "Čomor, Mirjana and Abazović, Nadica and Savić, T. D. and Šojić Merkulov, Daniela and Despotović, Vesna and Armaković, Sanja and Finčur, Nina and Lazarević, Marina and Uzelac, Maria and Abramović, Biljana",
year = "2021",
abstract = "Hydrothermally synthesized zirconia nanopowders: pure and doped with Si4+ ions were spectroscopically characterized and used as photocatalysts for degradation of herbicides sulcotrione and fluroxypyr. Zirconia is wide band gap ceramic (Eg ~ 5 eV) however, synthesized nanopowders showed unexpected, modest absorbance in visible light range. That fact inspired photocatalytical degradation of herbicides with wide utilization, using solar irradiation (SI) in laboratory conditions. In the scope of this study, degradation of herbicides was only slightly achieved (irradiation time 2h).",
journal = "PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry",
title = "Zirconia based photocatalysts in degradation of selected herbicides",
pages = "147-150",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10711"
}

Čomor, M., Abazović, N., Savić, T. D., Šojić Merkulov, D., Despotović, V., Armaković, S., Finčur, N., Lazarević, M., Uzelac, M.,& Abramović, B.. (2021). Zirconia based photocatalysts in degradation of selected herbicides. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry, 147-150.
https://hdl.handle.net/21.15107/rcub_vinar_10711

Čomor M, Abazović N, Savić TD, Šojić Merkulov D, Despotović V, Armaković S, Finčur N, Lazarević M, Uzelac M, Abramović B. Zirconia based photocatalysts in degradation of selected herbicides. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry. 2021;:147-150.
https://hdl.handle.net/21.15107/rcub_vinar_10711 .

Čomor, Mirjana, Abazović, Nadica, Savić, T. D., Šojić Merkulov, Daniela, Despotović, Vesna, Armaković, Sanja, Finčur, Nina, Lazarević, Marina, Uzelac, Maria, Abramović, Biljana, "Zirconia based photocatalysts in degradation of selected herbicides" in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry (2021):147-150,
https://hdl.handle.net/21.15107/rcub_vinar_10711 .

TY  - JOUR
AU  - Šojić Merkulov, Daniela V.
AU  - Lazarević, Marina J.
AU  - Đorđević, Aleksandar N.
AU  - Náfrádi, Máté
AU  - Alapi, Tünde
AU  - Putnik, Predrag
AU  - Rakočević, Zlatko Lj.
AU  - Novaković, Mirjana M.
AU  - Miljević, Bojan
AU  - Bognár, Szabolcs
AU  - Abramović, Biljana F.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9588
AB  - Nowadays, great focus is given to the contamination of surface and groundwater because of the extensive usage of pesticides in agriculture. The improvements of commercial catalyst TiO2 activity using different Au nanoparticles were investigated for mesotrione photocatalytic degradation under simulated sunlight. The selected system was 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) that was studied by transmission electron microscopy and ultraviolet-visible (UV-Vis) spectroscopy. It was found that TiO2 particles size was ~20 nm and ~50 nm, respectively. The Au nanoparticles were below 10 nm and were well distributed within the framework of TiO2 . For 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L), band gap energy was 2.45 eV. In comparison to the pure TiO2, addition of Au nanoparticles generally enhanced photocatalytic removal of mesotrione. By examining the degree of mineralization, it was found that 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) system was the most efficient for the removal of the mesotrione and intermediates. The effect of tert-butanol, NaF and ethylenediaminetetraacetic acid disodium salt on the transformation rate suggested that the relative contribution of various reactive species changed in following order: h+ >•OHads >•OHbulk. Finally, several intermediates that were formed during the photocatalytic treatment of mesotrione were identified. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
T2  - Nanomaterials
T1  - Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight
VL  - 10
IS  - 8
SP  - 1
EP  - 15
DO  - 10.3390/nano10081591
ER  - 

@article{
author = "Šojić Merkulov, Daniela V. and Lazarević, Marina J. and Đorđević, Aleksandar N. and Náfrádi, Máté and Alapi, Tünde and Putnik, Predrag and Rakočević, Zlatko Lj. and Novaković, Mirjana M. and Miljević, Bojan and Bognár, Szabolcs and Abramović, Biljana F.",
year = "2020",
abstract = "Nowadays, great focus is given to the contamination of surface and groundwater because of the extensive usage of pesticides in agriculture. The improvements of commercial catalyst TiO2 activity using different Au nanoparticles were investigated for mesotrione photocatalytic degradation under simulated sunlight. The selected system was 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) that was studied by transmission electron microscopy and ultraviolet-visible (UV-Vis) spectroscopy. It was found that TiO2 particles size was ~20 nm and ~50 nm, respectively. The Au nanoparticles were below 10 nm and were well distributed within the framework of TiO2 . For 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L), band gap energy was 2.45 eV. In comparison to the pure TiO2, addition of Au nanoparticles generally enhanced photocatalytic removal of mesotrione. By examining the degree of mineralization, it was found that 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) system was the most efficient for the removal of the mesotrione and intermediates. The effect of tert-butanol, NaF and ethylenediaminetetraacetic acid disodium salt on the transformation rate suggested that the relative contribution of various reactive species changed in following order: h+ >•OHads >•OHbulk. Finally, several intermediates that were formed during the photocatalytic treatment of mesotrione were identified. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.",
journal = "Nanomaterials",
title = "Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight",
volume = "10",
number = "8",
pages = "1-15",
doi = "10.3390/nano10081591"
}

Šojić Merkulov, D. V., Lazarević, M. J., Đorđević, A. N., Náfrádi, M., Alapi, T., Putnik, P., Rakočević, Z. Lj., Novaković, M. M., Miljević, B., Bognár, S.,& Abramović, B. F.. (2020). Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight. in Nanomaterials, 10(8), 1-15.
https://doi.org/10.3390/nano10081591

Šojić Merkulov DV, Lazarević MJ, Đorđević AN, Náfrádi M, Alapi T, Putnik P, Rakočević ZL, Novaković MM, Miljević B, Bognár S, Abramović BF. Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight. in Nanomaterials. 2020;10(8):1-15.
doi:10.3390/nano10081591 .

Šojić Merkulov, Daniela V., Lazarević, Marina J., Đorđević, Aleksandar N., Náfrádi, Máté, Alapi, Tünde, Putnik, Predrag, Rakočević, Zlatko Lj., Novaković, Mirjana M., Miljević, Bojan, Bognár, Szabolcs, Abramović, Biljana F., "Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight" in Nanomaterials, 10, no. 8 (2020):1-15,
https://doi.org/10.3390/nano10081591 . .

TY  - JOUR
AU  - Banić, Nemanja D.
AU  - Abramović, Biljana F.
AU  - Krstić, Jugoslav B.
AU  - Šojić Merkulov, Daniela V.
AU  - Finčur, Nina L.
AU  - Mitrić, Miodrag
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8446
AB  - This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed. © 2018 The Korean Society of Industrial and Engineering Chemistry
T2  - Journal of Industrial and Engineering Chemistry
T1  - Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation
VL  - 70
SP  - 264
EP  - 275
DO  - 10.1016/j.jiec.2018.10.025
ER  - 

@article{
author = "Banić, Nemanja D. and Abramović, Biljana F. and Krstić, Jugoslav B. and Šojić Merkulov, Daniela V. and Finčur, Nina L. and Mitrić, Miodrag",
year = "2019",
abstract = "This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed. © 2018 The Korean Society of Industrial and Engineering Chemistry",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation",
volume = "70",
pages = "264-275",
doi = "10.1016/j.jiec.2018.10.025"
}

Banić, N. D., Abramović, B. F., Krstić, J. B., Šojić Merkulov, D. V., Finčur, N. L.,& Mitrić, M.. (2019). Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry, 70, 264-275.
https://doi.org/10.1016/j.jiec.2018.10.025

Banić ND, Abramović BF, Krstić JB, Šojić Merkulov DV, Finčur NL, Mitrić M. Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry. 2019;70:264-275.
doi:10.1016/j.jiec.2018.10.025 .

Banić, Nemanja D., Abramović, Biljana F., Krstić, Jugoslav B., Šojić Merkulov, Daniela V., Finčur, Nina L., Mitrić, Miodrag, "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation" in Journal of Industrial and Engineering Chemistry, 70 (2019):264-275,
https://doi.org/10.1016/j.jiec.2018.10.025 . .

TY  - JOUR
AU  - Šojić Merkulov, Daniela V.
AU  - Despotović, Vesna N.
AU  - Banić, Nemanja D.
AU  - Armaković, Sanja J.
AU  - Finčur, Nina L.
AU  - Lazarević, Marina J.
AU  - Četojević-Simin, Dragana D.
AU  - Orčić, Dejan Z.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Čomor, Mirjana
AU  - Abramović, Biljana F.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0269749117352053
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7699
AB  - A comprehensive study of the removal of selected biologically active compounds (pharmaceuticals and pesticides) from different water types was conducted using bare TiO2nanoparticles and TiO2/polyaniline (TP-50, TP-100, and TP-150) nanocomposite powders. In order to investigate how molecular structure of the substrate influences the rate of its removal, we compared degradation efficiency of the initial substrates and degree of mineralization for the active components of pharmaceuticals (propranolol, and amitriptyline) and pesticides (sulcotrione, and clomazone) in double distilled (DDW) and environmental waters. The results indicate that the efficiency of photocatalytic degradation of propranolol and amitriptyline was higher in environmental waters: rivers (Danube, Tisa, and Begej) and lakes (Moharač, and Sot) in comparison with DDW. On the contrary, degradation efficacy of sulcotrione and clomazone was lower in environmental waters. Further, of the all catalysts applied, bare TiO2and TP-100 were found to be most effective in the mineralization of propranolol and amitriptyline, respectively, while TP-150 appeared to be the most efficient in terms of sulcotrione and clomazone mineralization. Also, there was no significant toxicity observed after the irradiation of pharmaceuticals or pesticides solutions using appropriate catalysts on rat hepatoma (H-4-II-E), mouse neuroblastoma (Neuro-2a), human colon adenocarcinoma (HT-29), and human fetal lung (MRC-5) cell lines. Subsequently, detection and identification of the formed intermediates in the case of sulcotrione photocatalytic degradation using bare TiO2and TP-150 showed slightly different pathways of degradation. Furthermore, tentative pathways of sulcotrione photocatalytic degradation were proposed and discussed. Kinetics, toxicity and intermediates assessment of biologically active compounds (pesticides and pharmaceuticals) in environmental waters.
T2  - Environmental Pollution
T1  - Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment
VL  - 239
SP  - 457
EP  - 465
DO  - 10.1016/j.envpol.2018.04.039
ER  - 

@article{
author = "Šojić Merkulov, Daniela V. and Despotović, Vesna N. and Banić, Nemanja D. and Armaković, Sanja J. and Finčur, Nina L. and Lazarević, Marina J. and Četojević-Simin, Dragana D. and Orčić, Dejan Z. and Radoičić, Marija B. and Šaponjić, Zoran and Čomor, Mirjana and Abramović, Biljana F.",
year = "2018",
abstract = "A comprehensive study of the removal of selected biologically active compounds (pharmaceuticals and pesticides) from different water types was conducted using bare TiO2nanoparticles and TiO2/polyaniline (TP-50, TP-100, and TP-150) nanocomposite powders. In order to investigate how molecular structure of the substrate influences the rate of its removal, we compared degradation efficiency of the initial substrates and degree of mineralization for the active components of pharmaceuticals (propranolol, and amitriptyline) and pesticides (sulcotrione, and clomazone) in double distilled (DDW) and environmental waters. The results indicate that the efficiency of photocatalytic degradation of propranolol and amitriptyline was higher in environmental waters: rivers (Danube, Tisa, and Begej) and lakes (Moharač, and Sot) in comparison with DDW. On the contrary, degradation efficacy of sulcotrione and clomazone was lower in environmental waters. Further, of the all catalysts applied, bare TiO2and TP-100 were found to be most effective in the mineralization of propranolol and amitriptyline, respectively, while TP-150 appeared to be the most efficient in terms of sulcotrione and clomazone mineralization. Also, there was no significant toxicity observed after the irradiation of pharmaceuticals or pesticides solutions using appropriate catalysts on rat hepatoma (H-4-II-E), mouse neuroblastoma (Neuro-2a), human colon adenocarcinoma (HT-29), and human fetal lung (MRC-5) cell lines. Subsequently, detection and identification of the formed intermediates in the case of sulcotrione photocatalytic degradation using bare TiO2and TP-150 showed slightly different pathways of degradation. Furthermore, tentative pathways of sulcotrione photocatalytic degradation were proposed and discussed. Kinetics, toxicity and intermediates assessment of biologically active compounds (pesticides and pharmaceuticals) in environmental waters.",
journal = "Environmental Pollution",
title = "Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment",
volume = "239",
pages = "457-465",
doi = "10.1016/j.envpol.2018.04.039"
}

Šojić Merkulov, D. V., Despotović, V. N., Banić, N. D., Armaković, S. J., Finčur, N. L., Lazarević, M. J., Četojević-Simin, D. D., Orčić, D. Z., Radoičić, M. B., Šaponjić, Z., Čomor, M.,& Abramović, B. F.. (2018). Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment. in Environmental Pollution, 239, 457-465.
https://doi.org/10.1016/j.envpol.2018.04.039

Šojić Merkulov DV, Despotović VN, Banić ND, Armaković SJ, Finčur NL, Lazarević MJ, Četojević-Simin DD, Orčić DZ, Radoičić MB, Šaponjić Z, Čomor M, Abramović BF. Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment. in Environmental Pollution. 2018;239:457-465.
doi:10.1016/j.envpol.2018.04.039 .

Šojić Merkulov, Daniela V., Despotović, Vesna N., Banić, Nemanja D., Armaković, Sanja J., Finčur, Nina L., Lazarević, Marina J., Četojević-Simin, Dragana D., Orčić, Dejan Z., Radoičić, Marija B., Šaponjić, Zoran, Čomor, Mirjana, Abramović, Biljana F., "Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment" in Environmental Pollution, 239 (2018):457-465,
https://doi.org/10.1016/j.envpol.2018.04.039 . .

TY  - JOUR
AU  - Tomić, Nataša
AU  - Grujić-Brojčin, Mirjana
AU  - Finčur, Nina L.
AU  - Abramović, Biljana F.
AU  - Simović, Bojana
AU  - Krstić, Jugoslav B.
AU  - Matović, Branko
AU  - Šćepanović, Maja
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/821
AB  - Two series of nanocrystalline brookite-type powders have been synthesized by using combined sal gel hydrothermal method with titanium tetrachloride (TiCI4) as a precursor and hydrothermal temperature and reaction time varied in the range of 120-200 degrees C and 12-48 h, respectively. The effects of chosen synthesis parameters on structural, morphological and optical properties of synthesized powders have been investigated by the XRPD, SEM, EDS and BET measurements, as well Raman spectroscopy and spectroscopic ellipsometry. The XRPD results have shown that pure brookite phase, with mean crystallite size of -33 nm, has been obtained only in the sample synthesized at 200 degrees C, after 24 h of hydrothermal process. In all other samples anatase phase also appears, whereas rutile and sodium titanate phases have been noticed in the samples synthesized at lower temperatures. The presence of different titania phases has also been confirmed and analyzed by Raman scattering measurements. The SEM measurements have shown spindle-like particles in brookite-rich samples synthesized at 200 degrees C, whereas BET measurements have detected mesoporous structure in these samples. The properties of synthesized powders have been correlated to their photocatalytic efficiency, tested in degradation of alprazolam, one of the 5th generation benzodiazepines. The sample consisted of pure brookite has shown the highest efficiency in the photodegradation of alprazolam, practically equal to the activity of Degussa P25. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Materials Chemistry and Physics
T1  - Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route
VL  - 163
SP  - 518
EP  - 528
DO  - 10.1016/j.matchemphys.2015.08.008
ER  - 

@article{
author = "Tomić, Nataša and Grujić-Brojčin, Mirjana and Finčur, Nina L. and Abramović, Biljana F. and Simović, Bojana and Krstić, Jugoslav B. and Matović, Branko and Šćepanović, Maja",
year = "2015",
abstract = "Two series of nanocrystalline brookite-type powders have been synthesized by using combined sal gel hydrothermal method with titanium tetrachloride (TiCI4) as a precursor and hydrothermal temperature and reaction time varied in the range of 120-200 degrees C and 12-48 h, respectively. The effects of chosen synthesis parameters on structural, morphological and optical properties of synthesized powders have been investigated by the XRPD, SEM, EDS and BET measurements, as well Raman spectroscopy and spectroscopic ellipsometry. The XRPD results have shown that pure brookite phase, with mean crystallite size of -33 nm, has been obtained only in the sample synthesized at 200 degrees C, after 24 h of hydrothermal process. In all other samples anatase phase also appears, whereas rutile and sodium titanate phases have been noticed in the samples synthesized at lower temperatures. The presence of different titania phases has also been confirmed and analyzed by Raman scattering measurements. The SEM measurements have shown spindle-like particles in brookite-rich samples synthesized at 200 degrees C, whereas BET measurements have detected mesoporous structure in these samples. The properties of synthesized powders have been correlated to their photocatalytic efficiency, tested in degradation of alprazolam, one of the 5th generation benzodiazepines. The sample consisted of pure brookite has shown the highest efficiency in the photodegradation of alprazolam, practically equal to the activity of Degussa P25. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Materials Chemistry and Physics",
title = "Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route",
volume = "163",
pages = "518-528",
doi = "10.1016/j.matchemphys.2015.08.008"
}

Tomić, N., Grujić-Brojčin, M., Finčur, N. L., Abramović, B. F., Simović, B., Krstić, J. B., Matović, B.,& Šćepanović, M.. (2015). Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route. in Materials Chemistry and Physics
Elsevier., 163, 518-528.
https://doi.org/10.1016/j.matchemphys.2015.08.008

Tomić N, Grujić-Brojčin M, Finčur NL, Abramović BF, Simović B, Krstić JB, Matović B, Šćepanović M. Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route. in Materials Chemistry and Physics. 2015;163:518-528.
doi:10.1016/j.matchemphys.2015.08.008 .

Tomić, Nataša, Grujić-Brojčin, Mirjana, Finčur, Nina L., Abramović, Biljana F., Simović, Bojana, Krstić, Jugoslav B., Matović, Branko, Šćepanović, Maja, "Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route" in Materials Chemistry and Physics, 163 (2015):518-528,
https://doi.org/10.1016/j.matchemphys.2015.08.008 . .

TY  - JOUR
AU  - Grujić-Brojčin, Mirjana
AU  - Armaković, Sanja J.
AU  - Tomić, Nataša
AU  - Abramović, Biljana F.
AU  - Golubavic, A.
AU  - Stojadinovic, B.
AU  - Kremenović, Aleksandar S.
AU  - Babić, Biljana M.
AU  - Dohcevic-Mitrovic, Z.
AU  - Šćepanović, Maja
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5881
AB  - The influence of La-doping in the range of 0.5-6.0 mol% on structural and morphological properties of TiO2 nanopowders synthesized by sol-gel routine has been investigated by XRPD, AFM, EDS and BET measurements, as well as Raman spectroscopy. The XRPD and Raman measurements have revealed the anatase phase as dominant in all nanopowders, with crystallite size decreasing from similar to 15 nm in pure TiO2 to similar to 12 nm in La-doped samples. The BET data suggest that all samples are fully mesoporous, with mean pore diameters in the range of similar to 6-8 nm. The specific surface area and the complexity of pore structure are greater in doped samples than in pure TiO2 sample. The spectroscopic ellipsometry has apparently shown that the band gap has been gradually increased with the increase of La content. The STM and STS techniques have been used successfully to evaluate the surface morphology and electronic properties of La-doped nanopowders. All investigated properties have been related to photocatalytic activity, tested in degradation of a metoprolol tartrate salt (0.05 mM), and induced by UV-radiation. All doped samples showed increased photocatalytic activity compared to pure TiO2, among which the 0.65 mol% La-doped sample appeared to be the most efficient. (C) 2013 Elsevier Inc. All rights reserved.
T2  - Materials Characterization
T1  - Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping
VL  - 88
SP  - 30
EP  - 41
DO  - 10.1016/j.matchar.2013.12.002
ER  - 

@article{
author = "Grujić-Brojčin, Mirjana and Armaković, Sanja J. and Tomić, Nataša and Abramović, Biljana F. and Golubavic, A. and Stojadinovic, B. and Kremenović, Aleksandar S. and Babić, Biljana M. and Dohcevic-Mitrovic, Z. and Šćepanović, Maja",
year = "2014",
abstract = "The influence of La-doping in the range of 0.5-6.0 mol% on structural and morphological properties of TiO2 nanopowders synthesized by sol-gel routine has been investigated by XRPD, AFM, EDS and BET measurements, as well as Raman spectroscopy. The XRPD and Raman measurements have revealed the anatase phase as dominant in all nanopowders, with crystallite size decreasing from similar to 15 nm in pure TiO2 to similar to 12 nm in La-doped samples. The BET data suggest that all samples are fully mesoporous, with mean pore diameters in the range of similar to 6-8 nm. The specific surface area and the complexity of pore structure are greater in doped samples than in pure TiO2 sample. The spectroscopic ellipsometry has apparently shown that the band gap has been gradually increased with the increase of La content. The STM and STS techniques have been used successfully to evaluate the surface morphology and electronic properties of La-doped nanopowders. All investigated properties have been related to photocatalytic activity, tested in degradation of a metoprolol tartrate salt (0.05 mM), and induced by UV-radiation. All doped samples showed increased photocatalytic activity compared to pure TiO2, among which the 0.65 mol% La-doped sample appeared to be the most efficient. (C) 2013 Elsevier Inc. All rights reserved.",
journal = "Materials Characterization",
title = "Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping",
volume = "88",
pages = "30-41",
doi = "10.1016/j.matchar.2013.12.002"
}

Grujić-Brojčin, M., Armaković, S. J., Tomić, N., Abramović, B. F., Golubavic, A., Stojadinovic, B., Kremenović, A. S., Babić, B. M., Dohcevic-Mitrovic, Z.,& Šćepanović, M.. (2014). Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping. in Materials Characterization, 88, 30-41.
https://doi.org/10.1016/j.matchar.2013.12.002

Grujić-Brojčin M, Armaković SJ, Tomić N, Abramović BF, Golubavic A, Stojadinovic B, Kremenović AS, Babić BM, Dohcevic-Mitrovic Z, Šćepanović M. Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping. in Materials Characterization. 2014;88:30-41.
doi:10.1016/j.matchar.2013.12.002 .

Grujić-Brojčin, Mirjana, Armaković, Sanja J., Tomić, Nataša, Abramović, Biljana F., Golubavic, A., Stojadinovic, B., Kremenović, Aleksandar S., Babić, Biljana M., Dohcevic-Mitrovic, Z., Šćepanović, Maja, "Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping" in Materials Characterization, 88 (2014):30-41,
https://doi.org/10.1016/j.matchar.2013.12.002 . .

TY  - JOUR
AU  - Vranješ, Mila
AU  - Šaponjić, Zoran
AU  - Živković, Ljiljana
AU  - Despotović, Vesna N.
AU  - Šojić, Daniela V.
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/75
AB  - Titanium dioxide nanotubes (TNT) were synthesized via hydrothermal method and calcined at various temperatures. The obtained calcined TiO2 nanomaterials with specific elongation orientation were characterized by transmission and scanning electron microscopy (TEM, SEM), X-ray diffraction (XRD), UV/Vis diffuse reflection spectroscopy (DRS), Laser Doppler electrophoresis (LDE) and their textural properties were evaluated. The photocatalytic activity of obtained nanopowders was evaluated considering photodegradation rate of herbicide clomazone, rarely studied herbicide. The influence of calcination temperature of catalysts with elongated morphology on their photocatalytic activity was evaluated. The best results were obtained with TNT annealed at 700 degrees C, which can be assigned to the best balance between crystal structure, morphology and surface properties of nanoparticles induced by annealing. Also, the photocatalytic degradation rates of another two herbicides (picloram, and mecoprop) were compared, due to possibility that the efficiency of photo catalytic degradation is greatly influenced by the molecular structure. The mineralization degree of selected herbicides in the presence of TiO2 based photocatalysts was evaluated applying total organic carbon (TOC) measurements. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. B: Environmental
T1  - Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides
VL  - 160
SP  - 589
EP  - 596
DO  - 10.1016/j.apcatb.2014.06.005
ER  - 

@article{
author = "Vranješ, Mila and Šaponjić, Zoran and Živković, Ljiljana and Despotović, Vesna N. and Šojić, Daniela V. and Abramović, Biljana F. and Čomor, Mirjana",
year = "2014",
abstract = "Titanium dioxide nanotubes (TNT) were synthesized via hydrothermal method and calcined at various temperatures. The obtained calcined TiO2 nanomaterials with specific elongation orientation were characterized by transmission and scanning electron microscopy (TEM, SEM), X-ray diffraction (XRD), UV/Vis diffuse reflection spectroscopy (DRS), Laser Doppler electrophoresis (LDE) and their textural properties were evaluated. The photocatalytic activity of obtained nanopowders was evaluated considering photodegradation rate of herbicide clomazone, rarely studied herbicide. The influence of calcination temperature of catalysts with elongated morphology on their photocatalytic activity was evaluated. The best results were obtained with TNT annealed at 700 degrees C, which can be assigned to the best balance between crystal structure, morphology and surface properties of nanoparticles induced by annealing. Also, the photocatalytic degradation rates of another two herbicides (picloram, and mecoprop) were compared, due to possibility that the efficiency of photo catalytic degradation is greatly influenced by the molecular structure. The mineralization degree of selected herbicides in the presence of TiO2 based photocatalysts was evaluated applying total organic carbon (TOC) measurements. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. B: Environmental",
title = "Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides",
volume = "160",
pages = "589-596",
doi = "10.1016/j.apcatb.2014.06.005"
}

Vranješ, M., Šaponjić, Z., Živković, L., Despotović, V. N., Šojić, D. V., Abramović, B. F.,& Čomor, M.. (2014). Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides. in Applied Catalysis. B: Environmental, 160, 589-596.
https://doi.org/10.1016/j.apcatb.2014.06.005

Vranješ M, Šaponjić Z, Živković L, Despotović VN, Šojić DV, Abramović BF, Čomor M. Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides. in Applied Catalysis. B: Environmental. 2014;160:589-596.
doi:10.1016/j.apcatb.2014.06.005 .

Vranješ, Mila, Šaponjić, Zoran, Živković, Ljiljana, Despotović, Vesna N., Šojić, Daniela V., Abramović, Biljana F., Čomor, Mirjana, "Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides" in Applied Catalysis. B: Environmental, 160 (2014):589-596,
https://doi.org/10.1016/j.apcatb.2014.06.005 . .

TY  - JOUR
AU  - Golubović, Aleksandar V.
AU  - Tomić, Nataša
AU  - Finčur, Nina L.
AU  - Abramović, Biljana F.
AU  - Veljkovic, I.
AU  - Zdravkovic, J.
AU  - Grujić-Brojčin, Mirjana
AU  - Babić, Biljana M.
AU  - Stojadinovic, B.
AU  - Šćepanović, Maja
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/127
AB  - Pure and La3+ doped titanium dioxide (TiO2) nanopowders were obtained by sol gel and hydrothermal methods. A precursor was titanium tetrachloride and concentrations of dopants were 0.5 and 1.0 mol%. Procedures of both methods were the same, up to the last part of synthesis (the transformation from the mother liquor to oxide nanopowders), in order to find the influence of applied methods on the properties of nanopowders. XRD results have shown that all synthesized nanopowders were in the anatase phase. It was seen from DSC measurements that anatase to rutile phase transition took place at a higher temperature with a higher concentration of dopant (La3+). The samples obtained by the sol gel method had a higher temperature of phase transition than related samples obtained by the hydrothermal method. Nanopowder properties have been related to the photocatalytic activity, tested in degradation of the pharmaceutical alprazolam. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam
VL  - 40
IS  - 8
SP  - 13409
EP  - 13418
DO  - 10.1016/j.ceramint.2014.05.060
ER  - 

@article{
author = "Golubović, Aleksandar V. and Tomić, Nataša and Finčur, Nina L. and Abramović, Biljana F. and Veljkovic, I. and Zdravkovic, J. and Grujić-Brojčin, Mirjana and Babić, Biljana M. and Stojadinovic, B. and Šćepanović, Maja",
year = "2014",
abstract = "Pure and La3+ doped titanium dioxide (TiO2) nanopowders were obtained by sol gel and hydrothermal methods. A precursor was titanium tetrachloride and concentrations of dopants were 0.5 and 1.0 mol%. Procedures of both methods were the same, up to the last part of synthesis (the transformation from the mother liquor to oxide nanopowders), in order to find the influence of applied methods on the properties of nanopowders. XRD results have shown that all synthesized nanopowders were in the anatase phase. It was seen from DSC measurements that anatase to rutile phase transition took place at a higher temperature with a higher concentration of dopant (La3+). The samples obtained by the sol gel method had a higher temperature of phase transition than related samples obtained by the hydrothermal method. Nanopowder properties have been related to the photocatalytic activity, tested in degradation of the pharmaceutical alprazolam. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam",
volume = "40",
number = "8",
pages = "13409-13418",
doi = "10.1016/j.ceramint.2014.05.060"
}

Golubović, A. V., Tomić, N., Finčur, N. L., Abramović, B. F., Veljkovic, I., Zdravkovic, J., Grujić-Brojčin, M., Babić, B. M., Stojadinovic, B.,& Šćepanović, M.. (2014). Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam. in Ceramics International, 40(8), 13409-13418.
https://doi.org/10.1016/j.ceramint.2014.05.060

Golubović AV, Tomić N, Finčur NL, Abramović BF, Veljkovic I, Zdravkovic J, Grujić-Brojčin M, Babić BM, Stojadinovic B, Šćepanović M. Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam. in Ceramics International. 2014;40(8):13409-13418.
doi:10.1016/j.ceramint.2014.05.060 .

Golubović, Aleksandar V., Tomić, Nataša, Finčur, Nina L., Abramović, Biljana F., Veljkovic, I., Zdravkovic, J., Grujić-Brojčin, Mirjana, Babić, Biljana M., Stojadinovic, B., Šćepanović, Maja, "Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam" in Ceramics International, 40, no. 8 (2014):13409-13418,
https://doi.org/10.1016/j.ceramint.2014.05.060 . .

TY  - JOUR
AU  - Radoičić, Marija B.
AU  - Janković, Ivana A.
AU  - Despotović, Vesna N.
AU  - Šojić, Daniela V.
AU  - Savić, Tatjana D.
AU  - Šaponjić, Zoran
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5511
AB  - A study of photocatalytic activity of bare as prepared, bare aged and dopamine surface modified colloidal TiO2 nanoparticles was obtained following degradation reaction of herbicide RS-2-(4-chloro-o-tolyloxy)propionic acid under UV light irradiation. Results showed that the most active photocatalyst is bare aged TiO2 and the least active are dopamine modified nanoparticles. Results are discussed in the light of surface structure of TiO2 nanoparticles. The study of surface modification of TiO2 nanoparticles (4.5 nm, TiO2 NPs) with dopamine was also performed. The formation of inner-sphere charge-transfer complexes results in red shift of semiconductor absorption threshold (600 nm), compared to bare TiO2 NPs (380 nm). Effective band gap energy of 3.2 eV for bare TiO2 NPs is reduced to 2.1 eV for TiO2/dopamine charge transfer complexes. The binding structure was investigated by UV-vis and FTIR spectroscopy. The obtained optimal geometry for binding of dopamine to surface Ti atoms was binuclear bidentate-bridging. From the Benesi-Hildebrand plot, stability constant of the order 10(3) M-1 has been determined. (C) 2013 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. B: Environmental
T1  - The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification
VL  - 138
SP  - 122
EP  - 127
DO  - 10.1016/j.apcatb.2013.02.032
ER  - 

@article{
author = "Radoičić, Marija B. and Janković, Ivana A. and Despotović, Vesna N. and Šojić, Daniela V. and Savić, Tatjana D. and Šaponjić, Zoran and Abramović, Biljana F. and Čomor, Mirjana",
year = "2013",
abstract = "A study of photocatalytic activity of bare as prepared, bare aged and dopamine surface modified colloidal TiO2 nanoparticles was obtained following degradation reaction of herbicide RS-2-(4-chloro-o-tolyloxy)propionic acid under UV light irradiation. Results showed that the most active photocatalyst is bare aged TiO2 and the least active are dopamine modified nanoparticles. Results are discussed in the light of surface structure of TiO2 nanoparticles. The study of surface modification of TiO2 nanoparticles (4.5 nm, TiO2 NPs) with dopamine was also performed. The formation of inner-sphere charge-transfer complexes results in red shift of semiconductor absorption threshold (600 nm), compared to bare TiO2 NPs (380 nm). Effective band gap energy of 3.2 eV for bare TiO2 NPs is reduced to 2.1 eV for TiO2/dopamine charge transfer complexes. The binding structure was investigated by UV-vis and FTIR spectroscopy. The obtained optimal geometry for binding of dopamine to surface Ti atoms was binuclear bidentate-bridging. From the Benesi-Hildebrand plot, stability constant of the order 10(3) M-1 has been determined. (C) 2013 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. B: Environmental",
title = "The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification",
volume = "138",
pages = "122-127",
doi = "10.1016/j.apcatb.2013.02.032"
}

Radoičić, M. B., Janković, I. A., Despotović, V. N., Šojić, D. V., Savić, T. D., Šaponjić, Z., Abramović, B. F.,& Čomor, M.. (2013). The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification. in Applied Catalysis. B: Environmental, 138, 122-127.
https://doi.org/10.1016/j.apcatb.2013.02.032

Radoičić MB, Janković IA, Despotović VN, Šojić DV, Savić TD, Šaponjić Z, Abramović BF, Čomor M. The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification. in Applied Catalysis. B: Environmental. 2013;138:122-127.
doi:10.1016/j.apcatb.2013.02.032 .

Radoičić, Marija B., Janković, Ivana A., Despotović, Vesna N., Šojić, Daniela V., Savić, Tatjana D., Šaponjić, Zoran, Abramović, Biljana F., Čomor, Mirjana, "The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification" in Applied Catalysis. B: Environmental, 138 (2013):122-127,
https://doi.org/10.1016/j.apcatb.2013.02.032 . .

TY  - JOUR
AU  - Golubović, Aleksandar V.
AU  - Abramović, Biljana F.
AU  - Šćepanović, Maja
AU  - Grujić-Brojčin, Mirjana
AU  - Armaković, Sanja J.
AU  - Veljkovic, I.
AU  - Babić, Biljana M.
AU  - Dohcevic-Mitrovic, Z.
AU  - Popović, Zoran V.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5421
AB  - The structural and morphological properties of mesoporous anatase nanopowders, synthesized by sol-gel method, have been modified by varying the duration of calcination, in order to obtain more efficient photocatalyst than Degussa P25 in the degradation of relatively large pollutant molecules ( GT 1 nm in size). According to X-ray diffraction analysis, the crystallite size was increased from 13 to 17.5 nm with the increase of calcination time from 1 to 7 h. The analysis of nitrogen sorption experimental data revealed that all samples were mesoporous, with a mean pore diameters in the range of similar to 5-9 nm. The corrugated pore structure model was employed to evaluate pore structure tortuosity. Nanopowder properties have been related to the photocatalytic activity, tested in the degradation of metoprolol tartrate salt, selective beta(1)-blocker used in a variety of cardiovascular diseases, with molecular size of 0.610 nm x 1.347 nm. The study has demonstrated that samples calcined for 4 and 5 h have displayed higher photocatalytic performance than Degussa P25, whereas the sample calcined for 3 h has shown comparable activity. (C) 2013 Published by Elsevier Ltd.
T2  - Materials Research Bulletin
T1  - Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol
VL  - 48
IS  - 4
SP  - 1363
EP  - 1371
DO  - 10.1016/j.materresbull.2012.11.098
ER  - 

@article{
author = "Golubović, Aleksandar V. and Abramović, Biljana F. and Šćepanović, Maja and Grujić-Brojčin, Mirjana and Armaković, Sanja J. and Veljkovic, I. and Babić, Biljana M. and Dohcevic-Mitrovic, Z. and Popović, Zoran V.",
year = "2013",
abstract = "The structural and morphological properties of mesoporous anatase nanopowders, synthesized by sol-gel method, have been modified by varying the duration of calcination, in order to obtain more efficient photocatalyst than Degussa P25 in the degradation of relatively large pollutant molecules ( GT 1 nm in size). According to X-ray diffraction analysis, the crystallite size was increased from 13 to 17.5 nm with the increase of calcination time from 1 to 7 h. The analysis of nitrogen sorption experimental data revealed that all samples were mesoporous, with a mean pore diameters in the range of similar to 5-9 nm. The corrugated pore structure model was employed to evaluate pore structure tortuosity. Nanopowder properties have been related to the photocatalytic activity, tested in the degradation of metoprolol tartrate salt, selective beta(1)-blocker used in a variety of cardiovascular diseases, with molecular size of 0.610 nm x 1.347 nm. The study has demonstrated that samples calcined for 4 and 5 h have displayed higher photocatalytic performance than Degussa P25, whereas the sample calcined for 3 h has shown comparable activity. (C) 2013 Published by Elsevier Ltd.",
journal = "Materials Research Bulletin",
title = "Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol",
volume = "48",
number = "4",
pages = "1363-1371",
doi = "10.1016/j.materresbull.2012.11.098"
}

Golubović, A. V., Abramović, B. F., Šćepanović, M., Grujić-Brojčin, M., Armaković, S. J., Veljkovic, I., Babić, B. M., Dohcevic-Mitrovic, Z.,& Popović, Z. V.. (2013). Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol. in Materials Research Bulletin, 48(4), 1363-1371.
https://doi.org/10.1016/j.materresbull.2012.11.098

Golubović AV, Abramović BF, Šćepanović M, Grujić-Brojčin M, Armaković SJ, Veljkovic I, Babić BM, Dohcevic-Mitrovic Z, Popović ZV. Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol. in Materials Research Bulletin. 2013;48(4):1363-1371.
doi:10.1016/j.materresbull.2012.11.098 .

Golubović, Aleksandar V., Abramović, Biljana F., Šćepanović, Maja, Grujić-Brojčin, Mirjana, Armaković, Sanja J., Veljkovic, I., Babić, Biljana M., Dohcevic-Mitrovic, Z., Popović, Zoran V., "Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol" in Materials Research Bulletin, 48, no. 4 (2013):1363-1371,
https://doi.org/10.1016/j.materresbull.2012.11.098 . .

TY  - CHAP
AU  - Čomor, Mirjana
AU  - Abazović, Nadica
AU  - Janković, Ivana A.
AU  - Jovanović, Dragana J.
AU  - Stoiljković, Milovan
AU  - Šojić, Daniela V.
AU  - Abramović, Biljana F.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9744
AB  - Titanium dioxide is one of the most studied semiconductors because of its wide range of potential technological applications including pigments, cosmetics, photovoltaic cells and catalysis. TiO2 has three most commonly encountered crystalline polymorphs: anatase, brookite and rutile. The possible application of TiO2 critically depends on crystalline structure, size and shape of the particles. Rutile has the highest density and refractive index and is widely employed in pigments and cosmetic industry. TiO2 is transparent in the visible light region; its band gap is 3.0 eV for rutile and 3.2 eV for anatase crystalline phase. By doping or sensitization, it is possible to improve the optical activity of TiO2 and to move its absorption threshold into the visible light region. The subject of this chapter is different rutile nanostructures of pure and Fe3+- doped titania which were synthesized by co-precipitation in acidic aqueous solution. Obtained materials were characterized by structural (XRD), morphological (TEM and HRTEM), optical (UV/vis absorption, reflection, and photoluminescence), and analytical (XPS and ICP-OES) techniques. Also, photo-catalytic activity measurements were performed, using photo-degradation of specific herbicides as model systems. Applied synthetic procedure resulted in formation of flower like agglomerates of 200-400 nm in diameter. Agglomerates represent assembly of nano-rods consisted of “chains” of spherical particles, 5-7 nm in diameter, most likely interconnected through the so-called oriented attachment or grain-rotation induced-grain coalescence (GRIGC) process. The presence of dopant iron ions didn’t distract morphology of rutile nano-particles, nor agglomerates, but significantly changed optical properties of titania compared to pure material. The photoluminescence of pure and Fe-doped rutile nano-particles is characterized with several well-resolved peaks extending in the visible spectral region. Photon energy upconversion from rutile TiO2 nano-particles was also observed at low excitation intensities. The energy of up-converted photoluminescence spans the range of emission of normal photoluminescence. The explanation of photon energy up-conversion involves mid-gap energy levels originating from oxygen vacancies. © 2012 by Nova Science Publishers, Inc.
T2  - Rutile: Properties, Synthesis and Applications
T1  - Rutile nanostructures: Synthesis, characterization and potential application in photocatalytic processes
SP  - 29
EP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9744
ER  - 

@inbook{
author = "Čomor, Mirjana and Abazović, Nadica and Janković, Ivana A. and Jovanović, Dragana J. and Stoiljković, Milovan and Šojić, Daniela V. and Abramović, Biljana F.",
year = "2012",
abstract = "Titanium dioxide is one of the most studied semiconductors because of its wide range of potential technological applications including pigments, cosmetics, photovoltaic cells and catalysis. TiO2 has three most commonly encountered crystalline polymorphs: anatase, brookite and rutile. The possible application of TiO2 critically depends on crystalline structure, size and shape of the particles. Rutile has the highest density and refractive index and is widely employed in pigments and cosmetic industry. TiO2 is transparent in the visible light region; its band gap is 3.0 eV for rutile and 3.2 eV for anatase crystalline phase. By doping or sensitization, it is possible to improve the optical activity of TiO2 and to move its absorption threshold into the visible light region. The subject of this chapter is different rutile nanostructures of pure and Fe3+- doped titania which were synthesized by co-precipitation in acidic aqueous solution. Obtained materials were characterized by structural (XRD), morphological (TEM and HRTEM), optical (UV/vis absorption, reflection, and photoluminescence), and analytical (XPS and ICP-OES) techniques. Also, photo-catalytic activity measurements were performed, using photo-degradation of specific herbicides as model systems. Applied synthetic procedure resulted in formation of flower like agglomerates of 200-400 nm in diameter. Agglomerates represent assembly of nano-rods consisted of “chains” of spherical particles, 5-7 nm in diameter, most likely interconnected through the so-called oriented attachment or grain-rotation induced-grain coalescence (GRIGC) process. The presence of dopant iron ions didn’t distract morphology of rutile nano-particles, nor agglomerates, but significantly changed optical properties of titania compared to pure material. The photoluminescence of pure and Fe-doped rutile nano-particles is characterized with several well-resolved peaks extending in the visible spectral region. Photon energy upconversion from rutile TiO2 nano-particles was also observed at low excitation intensities. The energy of up-converted photoluminescence spans the range of emission of normal photoluminescence. The explanation of photon energy up-conversion involves mid-gap energy levels originating from oxygen vacancies. © 2012 by Nova Science Publishers, Inc.",
journal = "Rutile: Properties, Synthesis and Applications",
booktitle = "Rutile nanostructures: Synthesis, characterization and potential application in photocatalytic processes",
pages = "29-52",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9744"
}

Čomor, M., Abazović, N., Janković, I. A., Jovanović, D. J., Stoiljković, M., Šojić, D. V.,& Abramović, B. F.. (2012). Rutile nanostructures: Synthesis, characterization and potential application in photocatalytic processes. in Rutile: Properties, Synthesis and Applications, 29-52.
https://hdl.handle.net/21.15107/rcub_vinar_9744

Čomor M, Abazović N, Janković IA, Jovanović DJ, Stoiljković M, Šojić DV, Abramović BF. Rutile nanostructures: Synthesis, characterization and potential application in photocatalytic processes. in Rutile: Properties, Synthesis and Applications. 2012;:29-52.
https://hdl.handle.net/21.15107/rcub_vinar_9744 .

Čomor, Mirjana, Abazović, Nadica, Janković, Ivana A., Jovanović, Dragana J., Stoiljković, Milovan, Šojić, Daniela V., Abramović, Biljana F., "Rutile nanostructures: Synthesis, characterization and potential application in photocatalytic processes" in Rutile: Properties, Synthesis and Applications (2012):29-52,
https://hdl.handle.net/21.15107/rcub_vinar_9744 .

TY  - JOUR
AU  - Šćepanović, Maja
AU  - Abramović, Biljana F.
AU  - Golubović, Aleksandar V.
AU  - Kler, Sanja
AU  - Grujić-Brojčin, Mirjana
AU  - Dohčević-Mitrović, Zorana 
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Popović, Zoran V.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4656
AB  - Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy, in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation.
T2  - Journal of Sol-gel Science and Technology
T1  - Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route
VL  - 61
IS  - 2
SP  - 390
EP  - 402
DO  - 10.1007/s10971-011-2639-9
ER  - 

@article{
author = "Šćepanović, Maja and Abramović, Biljana F. and Golubović, Aleksandar V. and Kler, Sanja and Grujić-Brojčin, Mirjana and Dohčević-Mitrović, Zorana  and Babić, Biljana M. and Matović, Branko and Popović, Zoran V.",
year = "2012",
abstract = "Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy, in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation.",
journal = "Journal of Sol-gel Science and Technology",
title = "Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route",
volume = "61",
number = "2",
pages = "390-402",
doi = "10.1007/s10971-011-2639-9"
}

Šćepanović, M., Abramović, B. F., Golubović, A. V., Kler, S., Grujić-Brojčin, M., Dohčević-Mitrović, Z., Babić, B. M., Matović, B.,& Popović, Z. V.. (2012). Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route. in Journal of Sol-gel Science and Technology, 61(2), 390-402.
https://doi.org/10.1007/s10971-011-2639-9

Šćepanović M, Abramović BF, Golubović AV, Kler S, Grujić-Brojčin M, Dohčević-Mitrović Z, Babić BM, Matović B, Popović ZV. Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route. in Journal of Sol-gel Science and Technology. 2012;61(2):390-402.
doi:10.1007/s10971-011-2639-9 .

Šćepanović, Maja, Abramović, Biljana F., Golubović, Aleksandar V., Kler, Sanja, Grujić-Brojčin, Mirjana, Dohčević-Mitrović, Zorana , Babić, Biljana M., Matović, Branko, Popović, Zoran V., "Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route" in Journal of Sol-gel Science and Technology, 61, no. 2 (2012):390-402,
https://doi.org/10.1007/s10971-011-2639-9 . .

TY  - CONF
AU  - Radoičić, Marija B.
AU  - Janković, Ivana A.
AU  - Despotović, Vesna N.
AU  - Šojić, Daniela V.
AU  - Šaponjić, Zoran
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9289
AB  - Photocatalytic activity of bare colloidal TiO2 nanoparticles (NPs, d~45Å) and
surface modified with dopamine was obtained following degradation reaction of
herbicide RS-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop, MCPP, C10H11ClO3)
under UV light irradiation. Results indicated that inner sphere charge transfer (CT)
complex is formed on the surface of TiO2 NPs due to modification with dopamine
which induced decreasing of the photocatalytic efficacy of TiO2 NPs.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry
T1  - Photocatalytic activity of TiO2 nanoparticles modified with dopamine
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9289
ER  - 

@conference{
author = "Radoičić, Marija B. and Janković, Ivana A. and Despotović, Vesna N. and Šojić, Daniela V. and Šaponjić, Zoran and Abramović, Biljana F. and Čomor, Mirjana",
year = "2010",
abstract = "Photocatalytic activity of bare colloidal TiO2 nanoparticles (NPs, d~45Å) and
surface modified with dopamine was obtained following degradation reaction of
herbicide RS-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop, MCPP, C10H11ClO3)
under UV light irradiation. Results indicated that inner sphere charge transfer (CT)
complex is formed on the surface of TiO2 NPs due to modification with dopamine
which induced decreasing of the photocatalytic efficacy of TiO2 NPs.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry",
title = "Photocatalytic activity of TiO2 nanoparticles modified with dopamine",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9289"
}

Radoičić, M. B., Janković, I. A., Despotović, V. N., Šojić, D. V., Šaponjić, Z., Abramović, B. F.,& Čomor, M.. (2010). Photocatalytic activity of TiO2 nanoparticles modified with dopamine. in Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia..
https://hdl.handle.net/21.15107/rcub_vinar_9289

Radoičić MB, Janković IA, Despotović VN, Šojić DV, Šaponjić Z, Abramović BF, Čomor M. Photocatalytic activity of TiO2 nanoparticles modified with dopamine. in Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry. 2010;.
https://hdl.handle.net/21.15107/rcub_vinar_9289 .

Radoičić, Marija B., Janković, Ivana A., Despotović, Vesna N., Šojić, Daniela V., Šaponjić, Zoran, Abramović, Biljana F., Čomor, Mirjana, "Photocatalytic activity of TiO2 nanoparticles modified with dopamine" in Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry (2010),
https://hdl.handle.net/21.15107/rcub_vinar_9289 .

TY  - JOUR
AU  - Šojić, Daniela V.
AU  - Despotović, Vesna N.
AU  - Abazović, Nadica
AU  - Čomor, Mirjana
AU  - Abramović, Biljana F.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4014
AB  - The aim of this work was to study the efficiency of Fe- and N-doped titania suspensions in the photocatalytic degradation of the herbicides RS-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop, MCPP), (4-chloro-2-methylphenoxy)acetic acid (MCPA), and 3,6-dichloropyridine-2-carboxylic acid (clopyralid, CP) under the visible light (lambda GT = 400 nm) irradiation. The obtained results were compared with those of the corresponding undoped TiO(2) (rutile/anatase) and of the most frequently used TiO(2) Degussa P25. Computational modeling procedures were used to optimize geometry and molecular electrostatic potentials of MCPP, MCPA and CP and discuss the obtained results. The results indicate that the efficiency of photocatalytic degradation is greatly influenced by the molecular structure of the compound. Lowering of the band gap of titanium dioxide by doping is not always favorable for increasing photocatalytic efficiency of degradation. (C) 2010 Elsevier B.V. All rights reserved.
T2  - Journal of Hazardous Materials
T1  - Photocatalytic degradation of selected herbicides in aqueous suspensions of doped titania under visible light irradiation
VL  - 179
IS  - 1-3
SP  - 49
EP  - 56
DO  - 10.1016/j.jhazmat.2010.02.055
ER  - 

@article{
author = "Šojić, Daniela V. and Despotović, Vesna N. and Abazović, Nadica and Čomor, Mirjana and Abramović, Biljana F.",
year = "2010",
abstract = "The aim of this work was to study the efficiency of Fe- and N-doped titania suspensions in the photocatalytic degradation of the herbicides RS-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop, MCPP), (4-chloro-2-methylphenoxy)acetic acid (MCPA), and 3,6-dichloropyridine-2-carboxylic acid (clopyralid, CP) under the visible light (lambda GT = 400 nm) irradiation. The obtained results were compared with those of the corresponding undoped TiO(2) (rutile/anatase) and of the most frequently used TiO(2) Degussa P25. Computational modeling procedures were used to optimize geometry and molecular electrostatic potentials of MCPP, MCPA and CP and discuss the obtained results. The results indicate that the efficiency of photocatalytic degradation is greatly influenced by the molecular structure of the compound. Lowering of the band gap of titanium dioxide by doping is not always favorable for increasing photocatalytic efficiency of degradation. (C) 2010 Elsevier B.V. All rights reserved.",
journal = "Journal of Hazardous Materials",
title = "Photocatalytic degradation of selected herbicides in aqueous suspensions of doped titania under visible light irradiation",
volume = "179",
number = "1-3",
pages = "49-56",
doi = "10.1016/j.jhazmat.2010.02.055"
}

Šojić, D. V., Despotović, V. N., Abazović, N., Čomor, M.,& Abramović, B. F.. (2010). Photocatalytic degradation of selected herbicides in aqueous suspensions of doped titania under visible light irradiation. in Journal of Hazardous Materials, 179(1-3), 49-56.
https://doi.org/10.1016/j.jhazmat.2010.02.055

Šojić DV, Despotović VN, Abazović N, Čomor M, Abramović BF. Photocatalytic degradation of selected herbicides in aqueous suspensions of doped titania under visible light irradiation. in Journal of Hazardous Materials. 2010;179(1-3):49-56.
doi:10.1016/j.jhazmat.2010.02.055 .

Šojić, Daniela V., Despotović, Vesna N., Abazović, Nadica, Čomor, Mirjana, Abramović, Biljana F., "Photocatalytic degradation of selected herbicides in aqueous suspensions of doped titania under visible light irradiation" in Journal of Hazardous Materials, 179, no. 1-3 (2010):49-56,
https://doi.org/10.1016/j.jhazmat.2010.02.055 . .

TY  - JOUR
AU  - Abramović, Biljana F.
AU  - Šojić, Daniela V.
AU  - Anderluh, Vesna B.
AU  - Abazović, Nadica
AU  - Čomor, Mirjana
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3741
AB  - The work describes a study of the oxidation power of nitrogen-doped titanium dioxide (TiO2) suspensions for photocatalytic degradation of the herbicides RS-2-(4-chloro-o-tolyloxy) prop ionic acid (mecoprop) and (4-chloro-2methylphenoxy)acetic acid (MCPA) using various light sources. The nitrogen-doped TiO2 crystalline nanopowder was synthesized by calcination of the hydrolysis product of titanium tetraisopropoxide in ammonia. The product was an anatase crystal phase with mean particle diameter 7-15 nm and specific surface area of 121 +/- 1 m(2) g(-1). It showed visible-light photocatalytic activity at about 530 rim. Although nitrogen concentration in nitrogen-doped TiO2 is low ( LT 1 atomic %), it appeared to be about 1.5 times more efficient than TiO2 Degussa P25 when artificial visible light was used for mecoprop and MCPA degradation, and about six times compared to direct photolysis. It was found that the optimal content of nitrogen-doped TiO2 was 4 mg cm(-3). The photodegradation of the herbicide aromatic ring takes place simultaneously with chloride evolution, whereby the reaction in both cases follows first-order kinetics.
T2  - Desalination
T1  - Nitrogen-doped TiO2 suspensions in photocatalytic degradation of mecoprop and (4-chloro-2-methylphenoxy)acetic acid herbicides using various light sources
VL  - 244
IS  - 1-3
SP  - 293
EP  - 302
DO  - 10.1016/j.desal.2008.06.008
ER  - 

@article{
author = "Abramović, Biljana F. and Šojić, Daniela V. and Anderluh, Vesna B. and Abazović, Nadica and Čomor, Mirjana",
year = "2009",
abstract = "The work describes a study of the oxidation power of nitrogen-doped titanium dioxide (TiO2) suspensions for photocatalytic degradation of the herbicides RS-2-(4-chloro-o-tolyloxy) prop ionic acid (mecoprop) and (4-chloro-2methylphenoxy)acetic acid (MCPA) using various light sources. The nitrogen-doped TiO2 crystalline nanopowder was synthesized by calcination of the hydrolysis product of titanium tetraisopropoxide in ammonia. The product was an anatase crystal phase with mean particle diameter 7-15 nm and specific surface area of 121 +/- 1 m(2) g(-1). It showed visible-light photocatalytic activity at about 530 rim. Although nitrogen concentration in nitrogen-doped TiO2 is low ( LT 1 atomic %), it appeared to be about 1.5 times more efficient than TiO2 Degussa P25 when artificial visible light was used for mecoprop and MCPA degradation, and about six times compared to direct photolysis. It was found that the optimal content of nitrogen-doped TiO2 was 4 mg cm(-3). The photodegradation of the herbicide aromatic ring takes place simultaneously with chloride evolution, whereby the reaction in both cases follows first-order kinetics.",
journal = "Desalination",
title = "Nitrogen-doped TiO2 suspensions in photocatalytic degradation of mecoprop and (4-chloro-2-methylphenoxy)acetic acid herbicides using various light sources",
volume = "244",
number = "1-3",
pages = "293-302",
doi = "10.1016/j.desal.2008.06.008"
}

Abramović, B. F., Šojić, D. V., Anderluh, V. B., Abazović, N.,& Čomor, M.. (2009). Nitrogen-doped TiO2 suspensions in photocatalytic degradation of mecoprop and (4-chloro-2-methylphenoxy)acetic acid herbicides using various light sources. in Desalination, 244(1-3), 293-302.
https://doi.org/10.1016/j.desal.2008.06.008

Abramović BF, Šojić DV, Anderluh VB, Abazović N, Čomor M. Nitrogen-doped TiO2 suspensions in photocatalytic degradation of mecoprop and (4-chloro-2-methylphenoxy)acetic acid herbicides using various light sources. in Desalination. 2009;244(1-3):293-302.
doi:10.1016/j.desal.2008.06.008 .

Abramović, Biljana F., Šojić, Daniela V., Anderluh, Vesna B., Abazović, Nadica, Čomor, Mirjana, "Nitrogen-doped TiO2 suspensions in photocatalytic degradation of mecoprop and (4-chloro-2-methylphenoxy)acetic acid herbicides using various light sources" in Desalination, 244, no. 1-3 (2009):293-302,
https://doi.org/10.1016/j.desal.2008.06.008 . .

TY  - JOUR
AU  - Abazović, Nadica
AU  - Mirenghi, Luciana
AU  - Janković, Ivana A.
AU  - Bibić, Nataša M.
AU  - Šojić, Daniela V.
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3705
AB  - Titanium dioxide nanopowders doped with different amounts of Fe ions were prepared by coprecipitation method. Obtained materials were characterized by structural (XRD), morphological (TEM and SEM), optical (UV/vis reflection and photoluminescence, and Raman), and analytical techniques (XPS and ICP-OES). XRD analysis revealed rutile crystalline phase for doped and undoped titanium dioxide obtained in the same manner. Diameter of the particles was 5-7 nm. The presence of iron ions was confirmed by XPS and ICP-OES. Doping process moved absorption threshold of TiO2 into visible spectrum range. Photocatalytic activity was also checked. Doped nanopowders showed normal and up-converted photoluminescence.
T2  - Nanoscale Research Letters
T1  - Synthesis and Characterization of Rutile TiO2 Nanopowders Doped with Iron Ions
VL  - 4
IS  - 6
SP  - 518
EP  - 525
DO  - 10.1007/s11671-009-9274-1
ER  - 

@article{
author = "Abazović, Nadica and Mirenghi, Luciana and Janković, Ivana A. and Bibić, Nataša M. and Šojić, Daniela V. and Abramović, Biljana F. and Čomor, Mirjana",
year = "2009",
abstract = "Titanium dioxide nanopowders doped with different amounts of Fe ions were prepared by coprecipitation method. Obtained materials were characterized by structural (XRD), morphological (TEM and SEM), optical (UV/vis reflection and photoluminescence, and Raman), and analytical techniques (XPS and ICP-OES). XRD analysis revealed rutile crystalline phase for doped and undoped titanium dioxide obtained in the same manner. Diameter of the particles was 5-7 nm. The presence of iron ions was confirmed by XPS and ICP-OES. Doping process moved absorption threshold of TiO2 into visible spectrum range. Photocatalytic activity was also checked. Doped nanopowders showed normal and up-converted photoluminescence.",
journal = "Nanoscale Research Letters",
title = "Synthesis and Characterization of Rutile TiO2 Nanopowders Doped with Iron Ions",
volume = "4",
number = "6",
pages = "518-525",
doi = "10.1007/s11671-009-9274-1"
}

Abazović, N., Mirenghi, L., Janković, I. A., Bibić, N. M., Šojić, D. V., Abramović, B. F.,& Čomor, M.. (2009). Synthesis and Characterization of Rutile TiO2 Nanopowders Doped with Iron Ions. in Nanoscale Research Letters, 4(6), 518-525.
https://doi.org/10.1007/s11671-009-9274-1

Abazović N, Mirenghi L, Janković IA, Bibić NM, Šojić DV, Abramović BF, Čomor M. Synthesis and Characterization of Rutile TiO2 Nanopowders Doped with Iron Ions. in Nanoscale Research Letters. 2009;4(6):518-525.
doi:10.1007/s11671-009-9274-1 .

Abazović, Nadica, Mirenghi, Luciana, Janković, Ivana A., Bibić, Nataša M., Šojić, Daniela V., Abramović, Biljana F., Čomor, Mirjana, "Synthesis and Characterization of Rutile TiO2 Nanopowders Doped with Iron Ions" in Nanoscale Research Letters, 4, no. 6 (2009):518-525,
https://doi.org/10.1007/s11671-009-9274-1 . .

TY  - CONF
AU  - Šojić, Daniela V.
AU  - Abazović, Nadica
AU  - Anderluh, Vesna B.
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9468
AB  - In this study, the nitrogen-doped TiO2 crystalline nanopowder was synthesized by calcination of the hydrolysis product of titanium tetraisopropoxide in ammonia. Obtained nanopowder was characterized by XRD and UV-Vis reflection techniques. The kinetics of visible-light (400-800 nm) photocatalytic degradation of herbicide mecoprop in N-doped TiO2 nanopowder aqueous suspensions was investigated and compared to results obtained for undoped TiO2.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry
T1  - Visible-light photocatalytic degradation of herbicide mecoprop in n-doped TiO2 suspensions
SP  - 657
EP  - 659
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9468
ER  - 

@conference{
author = "Šojić, Daniela V. and Abazović, Nadica and Anderluh, Vesna B. and Abramović, Biljana F. and Čomor, Mirjana",
year = "2006",
abstract = "In this study, the nitrogen-doped TiO2 crystalline nanopowder was synthesized by calcination of the hydrolysis product of titanium tetraisopropoxide in ammonia. Obtained nanopowder was characterized by XRD and UV-Vis reflection techniques. The kinetics of visible-light (400-800 nm) photocatalytic degradation of herbicide mecoprop in N-doped TiO2 nanopowder aqueous suspensions was investigated and compared to results obtained for undoped TiO2.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry",
title = "Visible-light photocatalytic degradation of herbicide mecoprop in n-doped TiO2 suspensions",
pages = "657-659",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9468"
}

Šojić, D. V., Abazović, N., Anderluh, V. B., Abramović, B. F.,& Čomor, M.. (2006). Visible-light photocatalytic degradation of herbicide mecoprop in n-doped TiO2 suspensions. in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry
Society of Physical Chemists of Serbia., 657-659.
https://hdl.handle.net/21.15107/rcub_vinar_9468

Šojić DV, Abazović N, Anderluh VB, Abramović BF, Čomor M. Visible-light photocatalytic degradation of herbicide mecoprop in n-doped TiO2 suspensions. in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry. 2006;:657-659.
https://hdl.handle.net/21.15107/rcub_vinar_9468 .

Šojić, Daniela V., Abazović, Nadica, Anderluh, Vesna B., Abramović, Biljana F., Čomor, Mirjana, "Visible-light photocatalytic degradation of herbicide mecoprop in n-doped TiO2 suspensions" in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry (2006):657-659,
https://hdl.handle.net/21.15107/rcub_vinar_9468 .

TY  - JOUR
AU  - Topalov, Anđelka S.
AU  - Šojić, Daniela V.
AU  - Molnár-Gábor, Dora
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2816
AB  - The kinetics and possible mechanism of the photocatalytic degradation of herbicide mecoprop, in UV illuminated aqueous colloids of synthesized nanosized TiO2 were investigated. The rate of degradation was studied by H-1 NMR, UV spectrometry, as well as by potentiometric titrimetric determination of generated chloride. The catalyst dosage and effects of other kinetic factors on the photocatalytic degradation, such as initial substrate concentration, temperature and type of TiO2 were investigated as well. The degradation rates were found to be strongly influenced by the above parameters. It was found that photocatalytic efficiency is lower and that a smaller number of observed organic intermediates (only 4-chloro-2-methylphenol and acetic acid) was detected than those observed in the presence of TiO2 (Degussa P-25). Kinetics of the degradation were also monitored for direct photolysis, as well as for solar degradation in the presence and in the absence of TiO2. (C) 2004 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. B: Environmental
T1  - Photocatalytic activity of synthesized nanosized TiO2 towards the degradation of herbicide mecoprop
VL  - 54
IS  - 2
SP  - 125
EP  - 133
DO  - 10.1016/j.apcatb.2004.06.012
ER  - 

@article{
author = "Topalov, Anđelka S. and Šojić, Daniela V. and Molnár-Gábor, Dora and Abramović, Biljana F. and Čomor, Mirjana",
year = "2004",
abstract = "The kinetics and possible mechanism of the photocatalytic degradation of herbicide mecoprop, in UV illuminated aqueous colloids of synthesized nanosized TiO2 were investigated. The rate of degradation was studied by H-1 NMR, UV spectrometry, as well as by potentiometric titrimetric determination of generated chloride. The catalyst dosage and effects of other kinetic factors on the photocatalytic degradation, such as initial substrate concentration, temperature and type of TiO2 were investigated as well. The degradation rates were found to be strongly influenced by the above parameters. It was found that photocatalytic efficiency is lower and that a smaller number of observed organic intermediates (only 4-chloro-2-methylphenol and acetic acid) was detected than those observed in the presence of TiO2 (Degussa P-25). Kinetics of the degradation were also monitored for direct photolysis, as well as for solar degradation in the presence and in the absence of TiO2. (C) 2004 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. B: Environmental",
title = "Photocatalytic activity of synthesized nanosized TiO2 towards the degradation of herbicide mecoprop",
volume = "54",
number = "2",
pages = "125-133",
doi = "10.1016/j.apcatb.2004.06.012"
}

Topalov, A. S., Šojić, D. V., Molnár-Gábor, D., Abramović, B. F.,& Čomor, M.. (2004). Photocatalytic activity of synthesized nanosized TiO2 towards the degradation of herbicide mecoprop. in Applied Catalysis. B: Environmental, 54(2), 125-133.
https://doi.org/10.1016/j.apcatb.2004.06.012

Topalov AS, Šojić DV, Molnár-Gábor D, Abramović BF, Čomor M. Photocatalytic activity of synthesized nanosized TiO2 towards the degradation of herbicide mecoprop. in Applied Catalysis. B: Environmental. 2004;54(2):125-133.
doi:10.1016/j.apcatb.2004.06.012 .

Topalov, Anđelka S., Šojić, Daniela V., Molnár-Gábor, Dora, Abramović, Biljana F., Čomor, Mirjana, "Photocatalytic activity of synthesized nanosized TiO2 towards the degradation of herbicide mecoprop" in Applied Catalysis. B: Environmental, 54, no. 2 (2004):125-133,
https://doi.org/10.1016/j.apcatb.2004.06.012 . .

TY  - JOUR
AU  - Abramović, Biljana F.
AU  - Guzsvany, VJ
AU  - Gaal, FF
AU  - Laušević, Zoran
PY  - 2001
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2421
AB  - A comparative study was carried out of the potentiometric application of boron- and phosphorus-doped and undoped glassy carbon samples prepared at the same heal treatment temperature (HTT 1000 degreesC). The electrochemical activities of the obtained electrode materials were investigated on the example of argentometric titrations. It was found that the electrochemical behaviour of the doped glassy carbon samples are very similar to a Sigri (undoped) glassy carbon sample (HTT 2400 degreesC). The experiments showed that the potentiometric response depends on the polarization mode, the nature of the sample, the pretreatment of the electrode surface, and the nature of the supporting electro lyre. The amounts of iodide, bromide, and of chloride were determined to be 1.27 mg, 0.80 mg and 0.54 mg, respectively, with a maximum relative standard deviation of less than 1.1 %. The obtained results are in good agreement with the results of comparative potentiometric titrations using a silver indicator electrode. The titration method was applied to the indirect determination of pyridoxine hydrochloride, i.e., vitamin B-6.
T2  - Journal of the Serbian Chemical Society
T1  - Potentiometric application of boron- and phosphorus-doped glassy carbon electrodes
VL  - 66
IS  - 3
SP  - 179
EP  - 188
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2421
ER  - 

@article{
author = "Abramović, Biljana F. and Guzsvany, VJ and Gaal, FF and Laušević, Zoran",
year = "2001",
abstract = "A comparative study was carried out of the potentiometric application of boron- and phosphorus-doped and undoped glassy carbon samples prepared at the same heal treatment temperature (HTT 1000 degreesC). The electrochemical activities of the obtained electrode materials were investigated on the example of argentometric titrations. It was found that the electrochemical behaviour of the doped glassy carbon samples are very similar to a Sigri (undoped) glassy carbon sample (HTT 2400 degreesC). The experiments showed that the potentiometric response depends on the polarization mode, the nature of the sample, the pretreatment of the electrode surface, and the nature of the supporting electro lyre. The amounts of iodide, bromide, and of chloride were determined to be 1.27 mg, 0.80 mg and 0.54 mg, respectively, with a maximum relative standard deviation of less than 1.1 %. The obtained results are in good agreement with the results of comparative potentiometric titrations using a silver indicator electrode. The titration method was applied to the indirect determination of pyridoxine hydrochloride, i.e., vitamin B-6.",
journal = "Journal of the Serbian Chemical Society",
title = "Potentiometric application of boron- and phosphorus-doped glassy carbon electrodes",
volume = "66",
number = "3",
pages = "179-188",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2421"
}

Abramović, B. F., Guzsvany, V., Gaal, F.,& Laušević, Z.. (2001). Potentiometric application of boron- and phosphorus-doped glassy carbon electrodes. in Journal of the Serbian Chemical Society, 66(3), 179-188.
https://hdl.handle.net/21.15107/rcub_vinar_2421

Abramović BF, Guzsvany V, Gaal F, Laušević Z. Potentiometric application of boron- and phosphorus-doped glassy carbon electrodes. in Journal of the Serbian Chemical Society. 2001;66(3):179-188.
https://hdl.handle.net/21.15107/rcub_vinar_2421 .

Abramović, Biljana F., Guzsvany, VJ, Gaal, FF, Laušević, Zoran, "Potentiometric application of boron- and phosphorus-doped glassy carbon electrodes" in Journal of the Serbian Chemical Society, 66, no. 3 (2001):179-188,
https://hdl.handle.net/21.15107/rcub_vinar_2421 .