Tošić, Miloš S.

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orcid::0000-0002-6159-379X
  • Tošić, Miloš S. (4)
  • Tošić, Miloš (2)

Author's Bibliography

Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran

Tošić, Miloš; Rajić, Vladimir; Pjević, Dejan; Stojadinović, Stevan; Krstulović, Nikša; Dimitrijević-Branković, Suzana; Momčilović, Miloš

(2024)

TY  - JOUR
AU  - Tošić, Miloš
AU  - Rajić, Vladimir
AU  - Pjević, Dejan
AU  - Stojadinović, Stevan
AU  - Krstulović, Nikša
AU  - Dimitrijević-Branković, Suzana
AU  - Momčilović, Miloš
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13091
AB  - This study proposes a simple and controlled method for producing TiO2 with phase junction, oxygen vacancies, and Ti3+ by combining picosecond pulsed laser irradiation and electrochemical anodization. Ti mesh was pretreated by irradiating with a picosecond pulsed laser technique using an Nd:YAG laser (1064 nm) at two fluencies, 15 J/cm2 and 30 J/cm2 . The samples were then subjected to electrochemical anodization to form TiO2 nanotube arrays on the previously laser-treated surface. This study will investigate the possibility of forming TiO2 nanotube arrays on a pre-laser-treated Ti substrate and determine their physicochemical and photocatalytic properties. The samples were characterized by FESEM, XRD, Raman, XPS, and UV-Vis DRS. UV-Vis spectroscopy was used to observe the progress of photocatalytic degradation for all samples, and degradation products were determined using GC-MS. With the synergistic effects of phase junction, oxygen vacancies, and Ti3+, the laser-treated TiO2 with 30 J/cm2 showed a higher photocatalytic degradation rate (85.1%) of the pesticide carbofuran compared to non-laser-treated TiO2 (54.8%), remaining stable during successive degradation cycles, which has promising practical applications.
T2  - Photonics
T1  - Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran
VL  - 11
IS  - 3
SP  - 284
DO  - 10.3390/photonics11030284
ER  - 
@article{
author = "Tošić, Miloš and Rajić, Vladimir and Pjević, Dejan and Stojadinović, Stevan and Krstulović, Nikša and Dimitrijević-Branković, Suzana and Momčilović, Miloš",
year = "2024",
abstract = "This study proposes a simple and controlled method for producing TiO2 with phase junction, oxygen vacancies, and Ti3+ by combining picosecond pulsed laser irradiation and electrochemical anodization. Ti mesh was pretreated by irradiating with a picosecond pulsed laser technique using an Nd:YAG laser (1064 nm) at two fluencies, 15 J/cm2 and 30 J/cm2 . The samples were then subjected to electrochemical anodization to form TiO2 nanotube arrays on the previously laser-treated surface. This study will investigate the possibility of forming TiO2 nanotube arrays on a pre-laser-treated Ti substrate and determine their physicochemical and photocatalytic properties. The samples were characterized by FESEM, XRD, Raman, XPS, and UV-Vis DRS. UV-Vis spectroscopy was used to observe the progress of photocatalytic degradation for all samples, and degradation products were determined using GC-MS. With the synergistic effects of phase junction, oxygen vacancies, and Ti3+, the laser-treated TiO2 with 30 J/cm2 showed a higher photocatalytic degradation rate (85.1%) of the pesticide carbofuran compared to non-laser-treated TiO2 (54.8%), remaining stable during successive degradation cycles, which has promising practical applications.",
journal = "Photonics",
title = "Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran",
volume = "11",
number = "3",
pages = "284",
doi = "10.3390/photonics11030284"
}
Tošić, M., Rajić, V., Pjević, D., Stojadinović, S., Krstulović, N., Dimitrijević-Branković, S.,& Momčilović, M.. (2024). Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran. in Photonics, 11(3), 284.
https://doi.org/10.3390/photonics11030284
Tošić M, Rajić V, Pjević D, Stojadinović S, Krstulović N, Dimitrijević-Branković S, Momčilović M. Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran. in Photonics. 2024;11(3):284.
doi:10.3390/photonics11030284 .
Tošić, Miloš, Rajić, Vladimir, Pjević, Dejan, Stojadinović, Stevan, Krstulović, Nikša, Dimitrijević-Branković, Suzana, Momčilović, Miloš, "Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran" in Photonics, 11, no. 3 (2024):284,
https://doi.org/10.3390/photonics11030284 . .

Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete

Savić, Branislava; Mihajlović, Ivana; Milutinović, Slobodan M.; Seović, Mina M.; Nikolić, Željka; Tošić, Miloš S.; Brdarić, Tanja

(2019)

TY  - JOUR
AU  - Savić, Branislava
AU  - Mihajlović, Ivana
AU  - Milutinović, Slobodan M.
AU  - Seović, Mina M.
AU  - Nikolić, Željka
AU  - Tošić, Miloš S.
AU  - Brdarić, Tanja
PY  - 2019
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0352-51391800106S
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8199
AB  - Organic contaminants from building materials negatively affect the health of people. This study presents an analytical method for the simultaneous identification and quantification of 9 phenolic compounds, i.e., phenol, 2-chloro-phenol, 2,4-dimethylphenol, 2,4-dichlorophenol, 2,6-dichlorophenol, 4-chloro-3-methylphenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrahlorophenol and pentachlorophenol, in concrete by a gas chromatographic method with mass spectrometric detection (GC–MS). By comparing the MS spectra of the test compounds with MS spectra of analytical standards, reliable identification was achieved. The method could be applied in a given range (from 0.01 to 7.5 mg kg -1 ) with appropriate parameters of precision, accuracy, repeatability and linearity. The developed method could be used for quality control testing of phenols in concrete during the construction of new buildings, old residences and construction waste. The measurement uncertainty of the phenolic compounds in concrete was evaluated using two approaches, i.e., GUM recommendations and a Monte Carlo method. Disagreement of those methods was observed. The Monte Carlo method could be used in the evaluation of combined measurement uncertainty for the determination of phenolic compounds in concrete. © 2019 Serbian Chemical Society. All rights reserved.
T2  - Journal of the Serbian Chemical Society
T1  - Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete
VL  - 84
IS  - 1
SP  - 55
EP  - 68
DO  - 10.2298/JSC180518106S
ER  - 
@article{
author = "Savić, Branislava and Mihajlović, Ivana and Milutinović, Slobodan M. and Seović, Mina M. and Nikolić, Željka and Tošić, Miloš S. and Brdarić, Tanja",
year = "2019",
abstract = "Organic contaminants from building materials negatively affect the health of people. This study presents an analytical method for the simultaneous identification and quantification of 9 phenolic compounds, i.e., phenol, 2-chloro-phenol, 2,4-dimethylphenol, 2,4-dichlorophenol, 2,6-dichlorophenol, 4-chloro-3-methylphenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrahlorophenol and pentachlorophenol, in concrete by a gas chromatographic method with mass spectrometric detection (GC–MS). By comparing the MS spectra of the test compounds with MS spectra of analytical standards, reliable identification was achieved. The method could be applied in a given range (from 0.01 to 7.5 mg kg -1 ) with appropriate parameters of precision, accuracy, repeatability and linearity. The developed method could be used for quality control testing of phenols in concrete during the construction of new buildings, old residences and construction waste. The measurement uncertainty of the phenolic compounds in concrete was evaluated using two approaches, i.e., GUM recommendations and a Monte Carlo method. Disagreement of those methods was observed. The Monte Carlo method could be used in the evaluation of combined measurement uncertainty for the determination of phenolic compounds in concrete. © 2019 Serbian Chemical Society. All rights reserved.",
journal = "Journal of the Serbian Chemical Society",
title = "Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete",
volume = "84",
number = "1",
pages = "55-68",
doi = "10.2298/JSC180518106S"
}
Savić, B., Mihajlović, I., Milutinović, S. M., Seović, M. M., Nikolić, Ž., Tošić, M. S.,& Brdarić, T.. (2019). Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete. in Journal of the Serbian Chemical Society, 84(1), 55-68.
https://doi.org/10.2298/JSC180518106S
Savić B, Mihajlović I, Milutinović SM, Seović MM, Nikolić Ž, Tošić MS, Brdarić T. Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete. in Journal of the Serbian Chemical Society. 2019;84(1):55-68.
doi:10.2298/JSC180518106S .
Savić, Branislava, Mihajlović, Ivana, Milutinović, Slobodan M., Seović, Mina M., Nikolić, Željka, Tošić, Miloš S., Brdarić, Tanja, "Validation and uncertainty estimation of an analytical method for the determination of phenolic compounds in concrete" in Journal of the Serbian Chemical Society, 84, no. 1 (2019):55-68,
https://doi.org/10.2298/JSC180518106S . .
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Characterization analysis of Poplar fluff pyrolysis products. Multi-component kinetic study

Janković, Bojan Ž.; Manić, Nebojša G.; Dodevski, Vladimir; Popović, Jasmina G.; Rusmirović, Jelena D.; Tošić, Miloš S.

(2019)

TY  - JOUR
AU  - Janković, Bojan Ž.
AU  - Manić, Nebojša G.
AU  - Dodevski, Vladimir
AU  - Popović, Jasmina G.
AU  - Rusmirović, Jelena D.
AU  - Tošić, Miloš S.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0016236118317770
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7925
AB  - This paper describes the pyrolysis of Poplar fluff (from Populus alba) using on-line apparatus, and carbonization process at 850 °C using the fixed bed reactor. Characteristics of pyrolysis products were examined. Elemental and chemical analyses were shown that Poplar fluff has higher energy content characterized by increased content of fibrous structure (particularly cellulose). Independent parallel reactions model very well describes devolatilization process. It was found that increased amount of extractives can significantly affect on increased release of light gaseous products, but declining hydrocarbons, mostly the alkanes. Liquid product is mainly composed of phenolics, aldehydes, acids, esters and ketones. The carbonization process produces the great abundance of polycyclic aromatic hydrocarbons (PAH's), where naphthalene is the most abundant. Mechanism for PAH's formation was suggested. This study represents the first step in a much wider and more comprehensive way in thermal conversion processes of this type of fuel. © 2018 Elsevier Ltd
T2  - Fuel
T1  - Characterization analysis of Poplar fluff pyrolysis products. Multi-component kinetic study
VL  - 238
SP  - 111
EP  - 128
DO  - 10.1016/j.fuel.2018.10.064
ER  - 
@article{
author = "Janković, Bojan Ž. and Manić, Nebojša G. and Dodevski, Vladimir and Popović, Jasmina G. and Rusmirović, Jelena D. and Tošić, Miloš S.",
year = "2019",
abstract = "This paper describes the pyrolysis of Poplar fluff (from Populus alba) using on-line apparatus, and carbonization process at 850 °C using the fixed bed reactor. Characteristics of pyrolysis products were examined. Elemental and chemical analyses were shown that Poplar fluff has higher energy content characterized by increased content of fibrous structure (particularly cellulose). Independent parallel reactions model very well describes devolatilization process. It was found that increased amount of extractives can significantly affect on increased release of light gaseous products, but declining hydrocarbons, mostly the alkanes. Liquid product is mainly composed of phenolics, aldehydes, acids, esters and ketones. The carbonization process produces the great abundance of polycyclic aromatic hydrocarbons (PAH's), where naphthalene is the most abundant. Mechanism for PAH's formation was suggested. This study represents the first step in a much wider and more comprehensive way in thermal conversion processes of this type of fuel. © 2018 Elsevier Ltd",
journal = "Fuel",
title = "Characterization analysis of Poplar fluff pyrolysis products. Multi-component kinetic study",
volume = "238",
pages = "111-128",
doi = "10.1016/j.fuel.2018.10.064"
}
Janković, B. Ž., Manić, N. G., Dodevski, V., Popović, J. G., Rusmirović, J. D.,& Tošić, M. S.. (2019). Characterization analysis of Poplar fluff pyrolysis products. Multi-component kinetic study. in Fuel, 238, 111-128.
https://doi.org/10.1016/j.fuel.2018.10.064
Janković BŽ, Manić NG, Dodevski V, Popović JG, Rusmirović JD, Tošić MS. Characterization analysis of Poplar fluff pyrolysis products. Multi-component kinetic study. in Fuel. 2019;238:111-128.
doi:10.1016/j.fuel.2018.10.064 .
Janković, Bojan Ž., Manić, Nebojša G., Dodevski, Vladimir, Popović, Jasmina G., Rusmirović, Jelena D., Tošić, Miloš S., "Characterization analysis of Poplar fluff pyrolysis products. Multi-component kinetic study" in Fuel, 238 (2019):111-128,
https://doi.org/10.1016/j.fuel.2018.10.064 . .
7
18
16
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Određivanja sadržaja BTEX jedinjenja u uzorcima građevinskog materijala i otpada sa mineralnim uljima kao glavnom komponentom, metodom GC/FID Headspace

Tošić, Miloš; Nikolić, Željka; Georgijević, Jelena M.; Brdarić, Tanja; Tasić, Gvozden; Nikolić, Vladimir; Milovanović, Dubravka; Marčeta Kaninski, Milica

(Belgrade : Serbian Chemical Society, 2018)

TY  - CONF
AU  - Tošić, Miloš
AU  - Nikolić, Željka
AU  - Georgijević, Jelena M.
AU  - Brdarić, Tanja
AU  - Tasić, Gvozden
AU  - Nikolić, Vladimir
AU  - Milovanović, Dubravka
AU  - Marčeta Kaninski, Milica
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12695
AB  - BTEX jedinjenja su lako isparlјiva aromatična jedinjenja, klasifikovana kao toksična jedinjenja i kao takva su opasna po zdravlje ljudii životnu sredinu. Predmet istraživanja u ovom radu su BTEX jedinjenja u uzorcima građevinskog materijala sa mineralnim uljima kao glavnom komponentom. S obzirom da su ona sastavni deo mineralnih ulja, važno je odrediti njihovo prisustvo, koncentraciju i dalju distribuciju u životnu sredinu. Tokom eksperimentalnog istraživanja, ispitivan je sadržaj BTEX jedinjenja: benzen, toluen, ksilen (o, p, m) i etilbenzen u uzorcima mineralnih ulja iz građevinskih materijala i otpada. Metoda za određivanje ovih jedinjenja, kao i za njihovu kvantifikaciju u uzorcima mineralnih ulja, razvijena je u Laboratoriji za fizičku hemiju, Instituta za nuklearne nauke „Vinča“, Univerziteta u Beogradu, modifikacijom i unapređenjem standardnih metoda[1, 2]. Za potrebe ovog istraživanja,u eksperimentalnom delu, primenom Headspace ekstrakcije sa GC-FID tehnikom, određen je kvalitativni i kvantitativni sadržaj BTEX jedinjenja, što istovremeno predstavlja i validaciju ispitivane metode, kao i određivanje njene merne nesigurnosti (Tabela 1.).Parametri za validaciju ove metode su bili: specifičnost, linearnost, granica detekcije (LOD), granica kvantifikacije (LOQ), ponovljivost i tačnost svakog jedinjenja. Primenom opisane metode postignuta je pouzdana identifikacija ispitivanih jedinjenja. Identifikacija se ostvaruje poređenjem retencionih vremena ispitivanih jedinjenja sa retencionim vremenima analitičkih standarda. FID detektor pokazuje linearan odgovor u opsegu 0,1 do 10 µg , odnosno R ≥ 0,99. Vrednosti standarda na kalibracionoj krivi su potvrdili preciznost metode. Relativna standardna devijacija RSD je ispod 5%, što dokazuje da je metoda tačna i reproduktivna [3-8]. Predstavljena metoda je validirana kao pouzdana, precizna i tačna za potrebe kontrole kvaliteta mineralnih ulja koja su korišćena ili će se koristiti u toku izgradnje građevinskih objekata, kao i za otpadni materijal.
PB  - Belgrade : Serbian Chemical Society
C3  - ENVIROCHEM 2018 : 8th Symposium Chemistry and Environmental Protection : program and the book of abstracts
T1  - Određivanja sadržaja BTEX jedinjenja u uzorcima građevinskog materijala i otpada sa mineralnim uljima kao glavnom komponentom, metodom GC/FID Headspace
T1  - Determination of the BTEX compounds in building materials and waste samples containing mineral oils as the main component using Headspace GC/FID
SP  - 203
EP  - 204
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12695
ER  - 
@conference{
author = "Tošić, Miloš and Nikolić, Željka and Georgijević, Jelena M. and Brdarić, Tanja and Tasić, Gvozden and Nikolić, Vladimir and Milovanović, Dubravka and Marčeta Kaninski, Milica",
year = "2018",
abstract = "BTEX jedinjenja su lako isparlјiva aromatična jedinjenja, klasifikovana kao toksična jedinjenja i kao takva su opasna po zdravlje ljudii životnu sredinu. Predmet istraživanja u ovom radu su BTEX jedinjenja u uzorcima građevinskog materijala sa mineralnim uljima kao glavnom komponentom. S obzirom da su ona sastavni deo mineralnih ulja, važno je odrediti njihovo prisustvo, koncentraciju i dalju distribuciju u životnu sredinu. Tokom eksperimentalnog istraživanja, ispitivan je sadržaj BTEX jedinjenja: benzen, toluen, ksilen (o, p, m) i etilbenzen u uzorcima mineralnih ulja iz građevinskih materijala i otpada. Metoda za određivanje ovih jedinjenja, kao i za njihovu kvantifikaciju u uzorcima mineralnih ulja, razvijena je u Laboratoriji za fizičku hemiju, Instituta za nuklearne nauke „Vinča“, Univerziteta u Beogradu, modifikacijom i unapređenjem standardnih metoda[1, 2]. Za potrebe ovog istraživanja,u eksperimentalnom delu, primenom Headspace ekstrakcije sa GC-FID tehnikom, određen je kvalitativni i kvantitativni sadržaj BTEX jedinjenja, što istovremeno predstavlja i validaciju ispitivane metode, kao i određivanje njene merne nesigurnosti (Tabela 1.).Parametri za validaciju ove metode su bili: specifičnost, linearnost, granica detekcije (LOD), granica kvantifikacije (LOQ), ponovljivost i tačnost svakog jedinjenja. Primenom opisane metode postignuta je pouzdana identifikacija ispitivanih jedinjenja. Identifikacija se ostvaruje poređenjem retencionih vremena ispitivanih jedinjenja sa retencionim vremenima analitičkih standarda. FID detektor pokazuje linearan odgovor u opsegu 0,1 do 10 µg , odnosno R ≥ 0,99. Vrednosti standarda na kalibracionoj krivi su potvrdili preciznost metode. Relativna standardna devijacija RSD je ispod 5%, što dokazuje da je metoda tačna i reproduktivna [3-8]. Predstavljena metoda je validirana kao pouzdana, precizna i tačna za potrebe kontrole kvaliteta mineralnih ulja koja su korišćena ili će se koristiti u toku izgradnje građevinskih objekata, kao i za otpadni materijal.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "ENVIROCHEM 2018 : 8th Symposium Chemistry and Environmental Protection : program and the book of abstracts",
title = "Određivanja sadržaja BTEX jedinjenja u uzorcima građevinskog materijala i otpada sa mineralnim uljima kao glavnom komponentom, metodom GC/FID Headspace, Determination of the BTEX compounds in building materials and waste samples containing mineral oils as the main component using Headspace GC/FID",
pages = "203-204",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12695"
}
Tošić, M., Nikolić, Ž., Georgijević, J. M., Brdarić, T., Tasić, G., Nikolić, V., Milovanović, D.,& Marčeta Kaninski, M.. (2018). Određivanja sadržaja BTEX jedinjenja u uzorcima građevinskog materijala i otpada sa mineralnim uljima kao glavnom komponentom, metodom GC/FID Headspace. in ENVIROCHEM 2018 : 8th Symposium Chemistry and Environmental Protection : program and the book of abstracts
Belgrade : Serbian Chemical Society., 203-204.
https://hdl.handle.net/21.15107/rcub_vinar_12695
Tošić M, Nikolić Ž, Georgijević JM, Brdarić T, Tasić G, Nikolić V, Milovanović D, Marčeta Kaninski M. Određivanja sadržaja BTEX jedinjenja u uzorcima građevinskog materijala i otpada sa mineralnim uljima kao glavnom komponentom, metodom GC/FID Headspace. in ENVIROCHEM 2018 : 8th Symposium Chemistry and Environmental Protection : program and the book of abstracts. 2018;:203-204.
https://hdl.handle.net/21.15107/rcub_vinar_12695 .
Tošić, Miloš, Nikolić, Željka, Georgijević, Jelena M., Brdarić, Tanja, Tasić, Gvozden, Nikolić, Vladimir, Milovanović, Dubravka, Marčeta Kaninski, Milica, "Određivanja sadržaja BTEX jedinjenja u uzorcima građevinskog materijala i otpada sa mineralnim uljima kao glavnom komponentom, metodom GC/FID Headspace" in ENVIROCHEM 2018 : 8th Symposium Chemistry and Environmental Protection : program and the book of abstracts (2018):203-204,
https://hdl.handle.net/21.15107/rcub_vinar_12695 .

Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete

Aćimović, Danka D.; Nikolić, Željka; Tošić, Miloš S.; Milovanović, Dubravka S.; Nikolić, Vladimir M.; Brdarić, Tanja; Marčeta Kaninski, Milica

(2017)

TY  - JOUR
AU  - Aćimović, Danka D.
AU  - Nikolić, Željka
AU  - Tošić, Miloš S.
AU  - Milovanović, Dubravka S.
AU  - Nikolić, Vladimir M.
AU  - Brdarić, Tanja
AU  - Marčeta Kaninski, Milica
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1390
AB  - Human exposure to persistent organic contaminants, from building materials, negatively affects peoples health and overall quality of life. This paper presents the validation and uncertainty assessment of the analytical method, developed for the simultaneous determination of 16 EPA polycyclic aromatic hydrocarbons (PAHs) in solid-solid concrete by ultra-performance liquid chromatography with photo diode-array detector. Linearity of calibration curves was good over the whole range of calibration. Limits of detection varied between 0.2 and 2.9 mu gkg(-1). The accuracy in terms of recovery of the validated method is within the range from 54 to 106%. The developed method proved to be appropriate for analysis of PAHs and can be used for the quality control testing of concrete during the construction of new buildings, the old residences and related buildings associated with sick-building syndrome. In addition, this is the first reported method described for the evaluation of PAHs in solid-solid concrete. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Journal of Hazardous Materials
T1  - Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete
VL  - 325
SP  - 271
EP  - 278
DO  - 10.1016/j.jhazmat.2016.12.008
ER  - 
@article{
author = "Aćimović, Danka D. and Nikolić, Željka and Tošić, Miloš S. and Milovanović, Dubravka S. and Nikolić, Vladimir M. and Brdarić, Tanja and Marčeta Kaninski, Milica",
year = "2017",
abstract = "Human exposure to persistent organic contaminants, from building materials, negatively affects peoples health and overall quality of life. This paper presents the validation and uncertainty assessment of the analytical method, developed for the simultaneous determination of 16 EPA polycyclic aromatic hydrocarbons (PAHs) in solid-solid concrete by ultra-performance liquid chromatography with photo diode-array detector. Linearity of calibration curves was good over the whole range of calibration. Limits of detection varied between 0.2 and 2.9 mu gkg(-1). The accuracy in terms of recovery of the validated method is within the range from 54 to 106%. The developed method proved to be appropriate for analysis of PAHs and can be used for the quality control testing of concrete during the construction of new buildings, the old residences and related buildings associated with sick-building syndrome. In addition, this is the first reported method described for the evaluation of PAHs in solid-solid concrete. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Journal of Hazardous Materials",
title = "Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete",
volume = "325",
pages = "271-278",
doi = "10.1016/j.jhazmat.2016.12.008"
}
Aćimović, D. D., Nikolić, Ž., Tošić, M. S., Milovanović, D. S., Nikolić, V. M., Brdarić, T.,& Marčeta Kaninski, M.. (2017). Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete. in Journal of Hazardous Materials, 325, 271-278.
https://doi.org/10.1016/j.jhazmat.2016.12.008
Aćimović DD, Nikolić Ž, Tošić MS, Milovanović DS, Nikolić VM, Brdarić T, Marčeta Kaninski M. Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete. in Journal of Hazardous Materials. 2017;325:271-278.
doi:10.1016/j.jhazmat.2016.12.008 .
Aćimović, Danka D., Nikolić, Željka, Tošić, Miloš S., Milovanović, Dubravka S., Nikolić, Vladimir M., Brdarić, Tanja, Marčeta Kaninski, Milica, "Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete" in Journal of Hazardous Materials, 325 (2017):271-278,
https://doi.org/10.1016/j.jhazmat.2016.12.008 . .
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Novel photochemical advanced oxidation process for the removal of polycyclic aromatic hydrocarbons from polluted concrete

Nikolić, Vladimir M.; Karić, Slavko D.; Nikolić, Željka; Tošić, Miloš S.; Tasić, Gvozden S.; Milovanović, Dubravka S.; Marčeta Kaninski, Milica

(2017)

TY  - JOUR
AU  - Nikolić, Vladimir M.
AU  - Karić, Slavko D.
AU  - Nikolić, Željka
AU  - Tošić, Miloš S.
AU  - Tasić, Gvozden S.
AU  - Milovanović, Dubravka S.
AU  - Marčeta Kaninski, Milica
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1399
AB  - Polycyclic aromatic hydrocarbons (PAHs) are denoted by International Agency for Research on Cancer as mutagens, teratogens and carcinogenic to humans. In 2013, Vinca Institute of Nuclear Sciences was hired to determine whether PAHs are present in significant quantities in the concrete walls of newly built residential buildings (about 15,000 m(2) of apartments), and to propose appropriate technical solution for PAH removal in this case. As PAH occurrence, determination and remediation in concrete is, to our knowledge, a completely new field, it was necessary to face a number of challenges, including lack of regulations considering contents of PAHs in concrete, investigation of the origin of PAH contamination in concrete (if established), as Well as finding feasible and non-expensive remediation method, which would be appropriate for residential space. In first part of this study, a Markedly high concentrations of 5 PAHs were detected by UPLC/PDA analysis in samples of both concrete walls and mineral oil used for coating of planks during formwork, while control concrete and mineral oil, taken from independent construction site, were taken as a reference. Such coincidence, as well as the fact that mineral oil has penetrated into the concrete which is proven by ASAP/MS analysis, pointed to the mineral oil as the most probable source of PAH contamination of the concrete. In the second part, an efficient and easy-applicable method for PAH oxidation in concrete (called FHO3AOP), using UV light, H2O2 and ozone, was presented and discussed in terms of previous literature data. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Chemical Engineering Journal
T1  - Novel photochemical advanced oxidation process for the removal of polycyclic aromatic hydrocarbons from polluted concrete
VL  - 312
SP  - 99
EP  - 105
DO  - 10.1016/j.cej.2016.11.117
ER  - 
@article{
author = "Nikolić, Vladimir M. and Karić, Slavko D. and Nikolić, Željka and Tošić, Miloš S. and Tasić, Gvozden S. and Milovanović, Dubravka S. and Marčeta Kaninski, Milica",
year = "2017",
abstract = "Polycyclic aromatic hydrocarbons (PAHs) are denoted by International Agency for Research on Cancer as mutagens, teratogens and carcinogenic to humans. In 2013, Vinca Institute of Nuclear Sciences was hired to determine whether PAHs are present in significant quantities in the concrete walls of newly built residential buildings (about 15,000 m(2) of apartments), and to propose appropriate technical solution for PAH removal in this case. As PAH occurrence, determination and remediation in concrete is, to our knowledge, a completely new field, it was necessary to face a number of challenges, including lack of regulations considering contents of PAHs in concrete, investigation of the origin of PAH contamination in concrete (if established), as Well as finding feasible and non-expensive remediation method, which would be appropriate for residential space. In first part of this study, a Markedly high concentrations of 5 PAHs were detected by UPLC/PDA analysis in samples of both concrete walls and mineral oil used for coating of planks during formwork, while control concrete and mineral oil, taken from independent construction site, were taken as a reference. Such coincidence, as well as the fact that mineral oil has penetrated into the concrete which is proven by ASAP/MS analysis, pointed to the mineral oil as the most probable source of PAH contamination of the concrete. In the second part, an efficient and easy-applicable method for PAH oxidation in concrete (called FHO3AOP), using UV light, H2O2 and ozone, was presented and discussed in terms of previous literature data. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Chemical Engineering Journal",
title = "Novel photochemical advanced oxidation process for the removal of polycyclic aromatic hydrocarbons from polluted concrete",
volume = "312",
pages = "99-105",
doi = "10.1016/j.cej.2016.11.117"
}
Nikolić, V. M., Karić, S. D., Nikolić, Ž., Tošić, M. S., Tasić, G. S., Milovanović, D. S.,& Marčeta Kaninski, M.. (2017). Novel photochemical advanced oxidation process for the removal of polycyclic aromatic hydrocarbons from polluted concrete. in Chemical Engineering Journal, 312, 99-105.
https://doi.org/10.1016/j.cej.2016.11.117
Nikolić VM, Karić SD, Nikolić Ž, Tošić MS, Tasić GS, Milovanović DS, Marčeta Kaninski M. Novel photochemical advanced oxidation process for the removal of polycyclic aromatic hydrocarbons from polluted concrete. in Chemical Engineering Journal. 2017;312:99-105.
doi:10.1016/j.cej.2016.11.117 .
Nikolić, Vladimir M., Karić, Slavko D., Nikolić, Željka, Tošić, Miloš S., Tasić, Gvozden S., Milovanović, Dubravka S., Marčeta Kaninski, Milica, "Novel photochemical advanced oxidation process for the removal of polycyclic aromatic hydrocarbons from polluted concrete" in Chemical Engineering Journal, 312 (2017):99-105,
https://doi.org/10.1016/j.cej.2016.11.117 . .
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