TY  - JOUR
AU  - Jovanović, Vojislav
AU  - Jovanović, Slaviša
AU  - Marković, Gordana
AU  - Samaržija-Jovanović, Suzana
AU  - Porobić, Slavica
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marinović-Cincović, Milena
PY  - 2019
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/pc.24854
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8138
AB  - The powder recycled rubber (PRR) can be used as a filler and a modifier for elastomeric materials and asphalt. Composites based on elastomers and recycled rubber powders are a serious challenge for the environment. The main goal of this paper was to study the effect of rubber powder on the mechanical properties of elastomeric composites based on three precursors of the network. Triple blends were prepared using non-polar natural rubber (NR), polyisoprene rubber (BR), and styrene-butadiene rubber (SBR) (mass ratio 40/40/20). In all rubber compounds, the carbon black (CB)/PRR mass ratio is constant (60). Samples were prepared using two roll mill. The characteristics of hardening (optimum cure time, scorch time, minimum and maximum torque) of rubber mixtures were tested. Tensile strength, modulus at 100% elongation and elongation at break are decreasing with PRR ratio is increasing. It is due to poor adhesion of PRR into NR/BR/SBR/CB matrix. The thermal degradation temperature shifts to a higher temperature up to 5 phr of PRR in NR/BR/SBR/CB rubber blends. Fourier-transform infrared spectra of NR/BR/SBR/CB/PRR samples show that the absorption bands shifted 7–15 cm−1 to higher wavenumbers and confirmed rubber–filler interaction. Morphology was assessed by scanning electron microscopy. POLYM. COMPOS., 40:1307–1314, 2019. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers
T2  - Polymer Composites
T1  - The properties of elastomeric composites based on three network precursors
VL  - 40
IS  - 4
SP  - 1307
EP  - 1314
DO  - 10.1002/pc.24854
ER  - 

@article{
author = "Jovanović, Vojislav and Jovanović, Slaviša and Marković, Gordana and Samaržija-Jovanović, Suzana and Porobić, Slavica and Budinski-Simendić, Jaroslava K. and Marinović-Cincović, Milena",
year = "2019",
abstract = "The powder recycled rubber (PRR) can be used as a filler and a modifier for elastomeric materials and asphalt. Composites based on elastomers and recycled rubber powders are a serious challenge for the environment. The main goal of this paper was to study the effect of rubber powder on the mechanical properties of elastomeric composites based on three precursors of the network. Triple blends were prepared using non-polar natural rubber (NR), polyisoprene rubber (BR), and styrene-butadiene rubber (SBR) (mass ratio 40/40/20). In all rubber compounds, the carbon black (CB)/PRR mass ratio is constant (60). Samples were prepared using two roll mill. The characteristics of hardening (optimum cure time, scorch time, minimum and maximum torque) of rubber mixtures were tested. Tensile strength, modulus at 100% elongation and elongation at break are decreasing with PRR ratio is increasing. It is due to poor adhesion of PRR into NR/BR/SBR/CB matrix. The thermal degradation temperature shifts to a higher temperature up to 5 phr of PRR in NR/BR/SBR/CB rubber blends. Fourier-transform infrared spectra of NR/BR/SBR/CB/PRR samples show that the absorption bands shifted 7–15 cm−1 to higher wavenumbers and confirmed rubber–filler interaction. Morphology was assessed by scanning electron microscopy. POLYM. COMPOS., 40:1307–1314, 2019. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers",
journal = "Polymer Composites",
title = "The properties of elastomeric composites based on three network precursors",
volume = "40",
number = "4",
pages = "1307-1314",
doi = "10.1002/pc.24854"
}

Jovanović, V., Jovanović, S., Marković, G., Samaržija-Jovanović, S., Porobić, S., Budinski-Simendić, J. K.,& Marinović-Cincović, M.. (2019). The properties of elastomeric composites based on three network precursors. in Polymer Composites, 40(4), 1307-1314.
https://doi.org/10.1002/pc.24854

Jovanović V, Jovanović S, Marković G, Samaržija-Jovanović S, Porobić S, Budinski-Simendić JK, Marinović-Cincović M. The properties of elastomeric composites based on three network precursors. in Polymer Composites. 2019;40(4):1307-1314.
doi:10.1002/pc.24854 .

Jovanović, Vojislav, Jovanović, Slaviša, Marković, Gordana, Samaržija-Jovanović, Suzana, Porobić, Slavica, Budinski-Simendić, Jaroslava K., Marinović-Cincović, Milena, "The properties of elastomeric composites based on three network precursors" in Polymer Composites, 40, no. 4 (2019):1307-1314,
https://doi.org/10.1002/pc.24854 . .

TY  - JOUR
AU  - Porobić, Slavica
AU  - Marković, Gordana
AU  - Ristić, Ivan
AU  - Samaržija-Jovanović, Suzana
AU  - Jovanović, Vojislav
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marinović-Cincović, Milena
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8466
AB  - In this applicative work, two types of silica filler were used to increase the adhesion strength between steel and elastomeric hybrid materials based on chlorosulfonated polyethylene rubber (CSM) and polychloroprene rubber (CR) as network precursors. Precipitated silica (PS) with the average size of primary particles 15 nm and diatomaceous earth (DE) with the average size of primary particles 28 μm were used to ascertain differences in metal-elastomer compounds adhesion strength caused by different particle size. The ratio of network precursors in CSM/CR rubber blends was 50:50 (w/w). The filler loading was in the range of 0–35 phr. Characteristics of the obtained composites were examined by combining the cure kinetics, adhesion strength and the dynamic mechanical properties. The viscoelasticity of obtained hybrid materials was assessed by the mechanical spectrometer (in a single cantilever bending mode) in the temperature range from −50 °C to 150 °C using multifrequency mode. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers
T2  - Polymer Composites
T1  - Hybrid materials based on rubber blend nanocomposites
VL  - 40
IS  - 8
SP  - 3056
EP  - 3064
DO  - 10.1002/pc.25150
ER  - 

@article{
author = "Porobić, Slavica and Marković, Gordana and Ristić, Ivan and Samaržija-Jovanović, Suzana and Jovanović, Vojislav and Budinski-Simendić, Jaroslava K. and Marinović-Cincović, Milena",
year = "2019",
abstract = "In this applicative work, two types of silica filler were used to increase the adhesion strength between steel and elastomeric hybrid materials based on chlorosulfonated polyethylene rubber (CSM) and polychloroprene rubber (CR) as network precursors. Precipitated silica (PS) with the average size of primary particles 15 nm and diatomaceous earth (DE) with the average size of primary particles 28 μm were used to ascertain differences in metal-elastomer compounds adhesion strength caused by different particle size. The ratio of network precursors in CSM/CR rubber blends was 50:50 (w/w). The filler loading was in the range of 0–35 phr. Characteristics of the obtained composites were examined by combining the cure kinetics, adhesion strength and the dynamic mechanical properties. The viscoelasticity of obtained hybrid materials was assessed by the mechanical spectrometer (in a single cantilever bending mode) in the temperature range from −50 °C to 150 °C using multifrequency mode. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers",
journal = "Polymer Composites",
title = "Hybrid materials based on rubber blend nanocomposites",
volume = "40",
number = "8",
pages = "3056-3064",
doi = "10.1002/pc.25150"
}

Porobić, S., Marković, G., Ristić, I., Samaržija-Jovanović, S., Jovanović, V., Budinski-Simendić, J. K.,& Marinović-Cincović, M.. (2019). Hybrid materials based on rubber blend nanocomposites. in Polymer Composites, 40(8), 3056-3064.
https://doi.org/10.1002/pc.25150

Porobić S, Marković G, Ristić I, Samaržija-Jovanović S, Jovanović V, Budinski-Simendić JK, Marinović-Cincović M. Hybrid materials based on rubber blend nanocomposites. in Polymer Composites. 2019;40(8):3056-3064.
doi:10.1002/pc.25150 .

Porobić, Slavica, Marković, Gordana, Ristić, Ivan, Samaržija-Jovanović, Suzana, Jovanović, Vojislav, Budinski-Simendić, Jaroslava K., Marinović-Cincović, Milena, "Hybrid materials based on rubber blend nanocomposites" in Polymer Composites, 40, no. 8 (2019):3056-3064,
https://doi.org/10.1002/pc.25150 . .

TY  - JOUR
AU  - Vukić, Nevena
AU  - Ristić, Ivan
AU  - Marinović-Cincović, Milena
AU  - Radičević, Radmila
AU  - Pilić, Branka
AU  - Cakić, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10335
AB  - This paper presents influence of the type of carbon nanotube functionalization on properties of poly(L-lactide) (PLLA) based nanocomposite materials. For this purpose surface modifications of multi-walled carbon nanotubes (MWCNTs) were performed by chemical and irradiation techniques, while thermo gravimetric analysis, UV-Visible and Fourier-transform infrared (FT-IR) spectroscopies confirmed successful covalent functionalization. Series of PLLA bionanocom-posites with different contents of functionalized MWCNTs (0.7; 1.6; 2.1 wt%), were synthesized via ring-opening solution polymerisation of L-lactide. FT-IR analysis confirmed that grafting of L-lactide, under controlled condition, is possible to perform starting from the surface of functionalized MWCNTs. From differential scanning calorimetry results it was concluded that even low contents of chemically and irradiation functionalized MWCNTs had a significant effect on thermal properties of the prepared nanocomposites, raising the values of melting and glass transition temperatures. Thermogravimetric analysis (TGA) has shown that the degradation onset temperature for composites with chemically functionalized MWCNTs, was much higher than that for the neat poly(L-lactide) sample and composites with irradiation functionalized MWCNTs. Morphology studies by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that poly(L-lactide) covered surfaces and separated functionalized MWCNTs. Good dispersion of carbon nanotubes in polymer matrix enabled conductivity of synthesized materials, as determined by conductivity tests.
T2  - Hemijska industrija
T1  - Influence of different functionalization methods of multi-walled carbon nanotubes on the properties of poly(L-lactide) based nanocomposites
VL  - 73
IS  - 3
SP  - 183
EP  - 196
DO  - 10.2298/HEMIND190402016V
ER  - 

@article{
author = "Vukić, Nevena and Ristić, Ivan and Marinović-Cincović, Milena and Radičević, Radmila and Pilić, Branka and Cakić, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2019",
abstract = "This paper presents influence of the type of carbon nanotube functionalization on properties of poly(L-lactide) (PLLA) based nanocomposite materials. For this purpose surface modifications of multi-walled carbon nanotubes (MWCNTs) were performed by chemical and irradiation techniques, while thermo gravimetric analysis, UV-Visible and Fourier-transform infrared (FT-IR) spectroscopies confirmed successful covalent functionalization. Series of PLLA bionanocom-posites with different contents of functionalized MWCNTs (0.7; 1.6; 2.1 wt%), were synthesized via ring-opening solution polymerisation of L-lactide. FT-IR analysis confirmed that grafting of L-lactide, under controlled condition, is possible to perform starting from the surface of functionalized MWCNTs. From differential scanning calorimetry results it was concluded that even low contents of chemically and irradiation functionalized MWCNTs had a significant effect on thermal properties of the prepared nanocomposites, raising the values of melting and glass transition temperatures. Thermogravimetric analysis (TGA) has shown that the degradation onset temperature for composites with chemically functionalized MWCNTs, was much higher than that for the neat poly(L-lactide) sample and composites with irradiation functionalized MWCNTs. Morphology studies by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that poly(L-lactide) covered surfaces and separated functionalized MWCNTs. Good dispersion of carbon nanotubes in polymer matrix enabled conductivity of synthesized materials, as determined by conductivity tests.",
journal = "Hemijska industrija",
title = "Influence of different functionalization methods of multi-walled carbon nanotubes on the properties of poly(L-lactide) based nanocomposites",
volume = "73",
number = "3",
pages = "183-196",
doi = "10.2298/HEMIND190402016V"
}

Vukić, N., Ristić, I., Marinović-Cincović, M., Radičević, R., Pilić, B., Cakić, S.,& Budinski-Simendić, J. K.. (2019). Influence of different functionalization methods of multi-walled carbon nanotubes on the properties of poly(L-lactide) based nanocomposites. in Hemijska industrija, 73(3), 183-196.
https://doi.org/10.2298/HEMIND190402016V

Vukić N, Ristić I, Marinović-Cincović M, Radičević R, Pilić B, Cakić S, Budinski-Simendić JK. Influence of different functionalization methods of multi-walled carbon nanotubes on the properties of poly(L-lactide) based nanocomposites. in Hemijska industrija. 2019;73(3):183-196.
doi:10.2298/HEMIND190402016V .

Vukić, Nevena, Ristić, Ivan, Marinović-Cincović, Milena, Radičević, Radmila, Pilić, Branka, Cakić, Suzana, Budinski-Simendić, Jaroslava K., "Influence of different functionalization methods of multi-walled carbon nanotubes on the properties of poly(L-lactide) based nanocomposites" in Hemijska industrija, 73, no. 3 (2019):183-196,
https://doi.org/10.2298/HEMIND190402016V . .

TY  - CONF
AU  - Samaržija-Jovanović, Suzana
AU  - Jovanović, Vojislav
AU  - Petković, Branka
AU  - Jovanović, Slaviša
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11150
PB  - RAD Centre, Niš, Serbia
C3  - RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro
T1  - The effect of UV irradiation on hydrolytic stability of urea-formaldehyde resins filled with thermally modified montmorillonite
SP  - 209
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11150
ER  - 

@conference{
author = "Samaržija-Jovanović, Suzana and Jovanović, Vojislav and Petković, Branka and Jovanović, Slaviša and Marković, Gordana and Marinović-Cincović, Milena and Budinski-Simendić, Jaroslava K.",
year = "2019",
publisher = "RAD Centre, Niš, Serbia",
journal = "RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro",
title = "The effect of UV irradiation on hydrolytic stability of urea-formaldehyde resins filled with thermally modified montmorillonite",
pages = "209",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11150"
}

Samaržija-Jovanović, S., Jovanović, V., Petković, B., Jovanović, S., Marković, G., Marinović-Cincović, M.,& Budinski-Simendić, J. K.. (2019). The effect of UV irradiation on hydrolytic stability of urea-formaldehyde resins filled with thermally modified montmorillonite. in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro
RAD Centre, Niš, Serbia., 209.
https://hdl.handle.net/21.15107/rcub_vinar_11150

Samaržija-Jovanović S, Jovanović V, Petković B, Jovanović S, Marković G, Marinović-Cincović M, Budinski-Simendić JK. The effect of UV irradiation on hydrolytic stability of urea-formaldehyde resins filled with thermally modified montmorillonite. in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro. 2019;:209.
https://hdl.handle.net/21.15107/rcub_vinar_11150 .

Samaržija-Jovanović, Suzana, Jovanović, Vojislav, Petković, Branka, Jovanović, Slaviša, Marković, Gordana, Marinović-Cincović, Milena, Budinski-Simendić, Jaroslava K., "The effect of UV irradiation on hydrolytic stability of urea-formaldehyde resins filled with thermally modified montmorillonite" in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro (2019):209,
https://hdl.handle.net/21.15107/rcub_vinar_11150 .

TY  - CONF
AU  - Jovanović, Slaviša
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marinović-Cincović, Milena
AU  - Marković, Gordana
AU  - Teofilović, Vesna
AU  - Kojić, Dejan
AU  - Vukić, Nevena
AU  - Jovanović, Vojislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11151
PB  - RAD Centre, Niš, Serbia
C3  - RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro
T1  - The influence of network precursor ratio on the crosslinking and radiation resistance of hybrid elastomeric materials
SP  - 216
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11151
ER  - 

@conference{
author = "Jovanović, Slaviša and Budinski-Simendić, Jaroslava K. and Marinović-Cincović, Milena and Marković, Gordana and Teofilović, Vesna and Kojić, Dejan and Vukić, Nevena and Jovanović, Vojislav",
year = "2019",
publisher = "RAD Centre, Niš, Serbia",
journal = "RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro",
title = "The influence of network precursor ratio on the crosslinking and radiation resistance of hybrid elastomeric materials",
pages = "216",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11151"
}

Jovanović, S., Budinski-Simendić, J. K., Marinović-Cincović, M., Marković, G., Teofilović, V., Kojić, D., Vukić, N.,& Jovanović, V.. (2019). The influence of network precursor ratio on the crosslinking and radiation resistance of hybrid elastomeric materials. in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro
RAD Centre, Niš, Serbia., 216.
https://hdl.handle.net/21.15107/rcub_vinar_11151

Jovanović S, Budinski-Simendić JK, Marinović-Cincović M, Marković G, Teofilović V, Kojić D, Vukić N, Jovanović V. The influence of network precursor ratio on the crosslinking and radiation resistance of hybrid elastomeric materials. in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro. 2019;:216.
https://hdl.handle.net/21.15107/rcub_vinar_11151 .

Jovanović, Slaviša, Budinski-Simendić, Jaroslava K., Marinović-Cincović, Milena, Marković, Gordana, Teofilović, Vesna, Kojić, Dejan, Vukić, Nevena, Jovanović, Vojislav, "The influence of network precursor ratio on the crosslinking and radiation resistance of hybrid elastomeric materials" in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro (2019):216,
https://hdl.handle.net/21.15107/rcub_vinar_11151 .

TY  - CONF
AU  - Budinski-Simendić, Jaroslava
AU  - Marinović-Cincović, Milena
AU  - Kojić, Dejan
AU  - Marković, Gordana
AU  - Pavličević, Jelena
AU  - Aroguz, Ayse
AU  - Samaržija-Jovanović, Suzana
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11191
PB  - RAD Centre, Niš, Serbia
C3  - RAD 2018 : 6th International Conference on Radiation in Various Fields of Research : book of abstracts; June 18-22, 2018; Ohrid, Macedonia
T1  - Determination of glass transition temperature and irradiation resistance of elastomeric materials based on chlorinated natural rubber
SP  - 255
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11191
ER  - 

@conference{
author = "Budinski-Simendić, Jaroslava and Marinović-Cincović, Milena and Kojić, Dejan and Marković, Gordana and Pavličević, Jelena and Aroguz, Ayse and Samaržija-Jovanović, Suzana",
year = "2018",
publisher = "RAD Centre, Niš, Serbia",
journal = "RAD 2018 : 6th International Conference on Radiation in Various Fields of Research : book of abstracts; June 18-22, 2018; Ohrid, Macedonia",
title = "Determination of glass transition temperature and irradiation resistance of elastomeric materials based on chlorinated natural rubber",
pages = "255",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11191"
}

Budinski-Simendić, J., Marinović-Cincović, M., Kojić, D., Marković, G., Pavličević, J., Aroguz, A.,& Samaržija-Jovanović, S.. (2018). Determination of glass transition temperature and irradiation resistance of elastomeric materials based on chlorinated natural rubber. in RAD 2018 : 6th International Conference on Radiation in Various Fields of Research : book of abstracts; June 18-22, 2018; Ohrid, Macedonia
RAD Centre, Niš, Serbia., 255.
https://hdl.handle.net/21.15107/rcub_vinar_11191

Budinski-Simendić J, Marinović-Cincović M, Kojić D, Marković G, Pavličević J, Aroguz A, Samaržija-Jovanović S. Determination of glass transition temperature and irradiation resistance of elastomeric materials based on chlorinated natural rubber. in RAD 2018 : 6th International Conference on Radiation in Various Fields of Research : book of abstracts; June 18-22, 2018; Ohrid, Macedonia. 2018;:255.
https://hdl.handle.net/21.15107/rcub_vinar_11191 .

Budinski-Simendić, Jaroslava, Marinović-Cincović, Milena, Kojić, Dejan, Marković, Gordana, Pavličević, Jelena, Aroguz, Ayse, Samaržija-Jovanović, Suzana, "Determination of glass transition temperature and irradiation resistance of elastomeric materials based on chlorinated natural rubber" in RAD 2018 : 6th International Conference on Radiation in Various Fields of Research : book of abstracts; June 18-22, 2018; Ohrid, Macedonia (2018):255,
https://hdl.handle.net/21.15107/rcub_vinar_11191 .

TY  - JOUR
AU  - Jovanović, Slaviša
AU  - Jovanović, Vojislav
AU  - Marković, Gordana
AU  - Samaržija-Jovanović, Suzana
AU  - Milićević, Zoran
AU  - Marinović-Cincović, Milena
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8362
AB  - The elastomeric materials based on NR/BR/SBR ternary rubber blend were investigated. The polyisoprene (NR), butadiene (BR) and styrene butadiene (SBR) rubbers were used as network precursors and carbon black (CB) as an active filler (60 phr) for elastomeric materials preparation. For sample preparation, the mass ratio of NR to BR was constant, 1:1, but the SBR content was varied from 0 to 80 phr. The morphological, mechanical and thermal properties of prepared elastomeric materials were determined using scanning electron microscopy (SEM), mechanical tensile measurements and thermogravimetric analysis (TGA). Mechanical properties were assessed before and after thermooxidative aging during 168 h at 100 °C. The values of tensile strength, elongation at break, and hardness decrease up to 40 phr of SBR content and after that are increasing, but abrasion resistance of ternary rubber blends increases. The thermal decomposition temperature obviously shifted to a higher temperature for the sample with 40 phr of SBR. © 2019, CI and CEQ. All rights reserved.
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Elastomers based on NR/BR/SBR ternary rubber blend: Morphological, mechanical and thermal properties
VL  - 25
IS  - 1
SP  - 31
EP  - 38
DO  - 10.2298/CICEQ171106016J
ER  - 

@article{
author = "Jovanović, Slaviša and Jovanović, Vojislav and Marković, Gordana and Samaržija-Jovanović, Suzana and Milićević, Zoran and Marinović-Cincović, Milena and Budinski-Simendić, Jaroslava K.",
year = "2018",
abstract = "The elastomeric materials based on NR/BR/SBR ternary rubber blend were investigated. The polyisoprene (NR), butadiene (BR) and styrene butadiene (SBR) rubbers were used as network precursors and carbon black (CB) as an active filler (60 phr) for elastomeric materials preparation. For sample preparation, the mass ratio of NR to BR was constant, 1:1, but the SBR content was varied from 0 to 80 phr. The morphological, mechanical and thermal properties of prepared elastomeric materials were determined using scanning electron microscopy (SEM), mechanical tensile measurements and thermogravimetric analysis (TGA). Mechanical properties were assessed before and after thermooxidative aging during 168 h at 100 °C. The values of tensile strength, elongation at break, and hardness decrease up to 40 phr of SBR content and after that are increasing, but abrasion resistance of ternary rubber blends increases. The thermal decomposition temperature obviously shifted to a higher temperature for the sample with 40 phr of SBR. © 2019, CI and CEQ. All rights reserved.",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Elastomers based on NR/BR/SBR ternary rubber blend: Morphological, mechanical and thermal properties",
volume = "25",
number = "1",
pages = "31-38",
doi = "10.2298/CICEQ171106016J"
}

Jovanović, S., Jovanović, V., Marković, G., Samaržija-Jovanović, S., Milićević, Z., Marinović-Cincović, M.,& Budinski-Simendić, J. K.. (2018). Elastomers based on NR/BR/SBR ternary rubber blend: Morphological, mechanical and thermal properties. in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 25(1), 31-38.
https://doi.org/10.2298/CICEQ171106016J

Jovanović S, Jovanović V, Marković G, Samaržija-Jovanović S, Milićević Z, Marinović-Cincović M, Budinski-Simendić JK. Elastomers based on NR/BR/SBR ternary rubber blend: Morphological, mechanical and thermal properties. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2018;25(1):31-38.
doi:10.2298/CICEQ171106016J .

Jovanović, Slaviša, Jovanović, Vojislav, Marković, Gordana, Samaržija-Jovanović, Suzana, Milićević, Zoran, Marinović-Cincović, Milena, Budinski-Simendić, Jaroslava K., "Elastomers based on NR/BR/SBR ternary rubber blend: Morphological, mechanical and thermal properties" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 25, no. 1 (2018):31-38,
https://doi.org/10.2298/CICEQ171106016J . .

TY  - CONF
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Tanasic, Ljiljana
AU  - Radičević, Radmila
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7170
AB  - Elastomers are very often used in severe environments, for instance, in nuclear power plants, where they may be degraded by high-energy radiation and heat. The ageing behaviour of materials used in different equipments is very important. Elastomers based on chlorosulfonated polyethylene (CSM) are used for cable jacketing materials and have excellent radiation resistance needed in nuclear power stations. In the current work, the influence of gamma-irradiation dose (100, 200 and 400 kGy) on the ageing of reinforced blends based on CSM, styrene butadiene rubber (SBR) and natural rubber (NR) has been evaluated. The content of silica in CSM/SBR and CSM/NR rubber blends was varied. The curing behavior of compounds was estimated using the oscillating disk reometer. The irradiation of nano composites has been performed in air in the Co 60 radiation sterilization unit with the dose rate of 10 kGy h(-1). The thermal properties were studied by thermogravimetric test. The mechanical properties (hardness, modulus at 100% elongation, tensile strength and elongation at break) were determined before and after irradiation. A decrease in the elastic modulus and in the strain at break has been observed with increasing irradiation. At higher doses, the network chain scissions become the main degradation process, the cross-linked topology becomes irregular, and material contains more and more weak zones, which deteriorate the ultimate properties.
C3  - RAD Conference Proceedings
T1  - The High-Energy Irradiation Ageing of Reinforced Elastomers Based on Rubber Blends
SP  - 99
EP  - 102
DO  - 10.21175/RadProc.2016.23
ER  - 

@conference{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Tanasic, Ljiljana and Radičević, Radmila and Budinski-Simendić, Jaroslava K.",
year = "2016",
abstract = "Elastomers are very often used in severe environments, for instance, in nuclear power plants, where they may be degraded by high-energy radiation and heat. The ageing behaviour of materials used in different equipments is very important. Elastomers based on chlorosulfonated polyethylene (CSM) are used for cable jacketing materials and have excellent radiation resistance needed in nuclear power stations. In the current work, the influence of gamma-irradiation dose (100, 200 and 400 kGy) on the ageing of reinforced blends based on CSM, styrene butadiene rubber (SBR) and natural rubber (NR) has been evaluated. The content of silica in CSM/SBR and CSM/NR rubber blends was varied. The curing behavior of compounds was estimated using the oscillating disk reometer. The irradiation of nano composites has been performed in air in the Co 60 radiation sterilization unit with the dose rate of 10 kGy h(-1). The thermal properties were studied by thermogravimetric test. The mechanical properties (hardness, modulus at 100% elongation, tensile strength and elongation at break) were determined before and after irradiation. A decrease in the elastic modulus and in the strain at break has been observed with increasing irradiation. At higher doses, the network chain scissions become the main degradation process, the cross-linked topology becomes irregular, and material contains more and more weak zones, which deteriorate the ultimate properties.",
journal = "RAD Conference Proceedings",
title = "The High-Energy Irradiation Ageing of Reinforced Elastomers Based on Rubber Blends",
pages = "99-102",
doi = "10.21175/RadProc.2016.23"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S., Tanasic, L., Radičević, R.,& Budinski-Simendić, J. K.. (2016). The High-Energy Irradiation Ageing of Reinforced Elastomers Based on Rubber Blends. in RAD Conference Proceedings, 99-102.
https://doi.org/10.21175/RadProc.2016.23

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Tanasic L, Radičević R, Budinski-Simendić JK. The High-Energy Irradiation Ageing of Reinforced Elastomers Based on Rubber Blends. in RAD Conference Proceedings. 2016;:99-102.
doi:10.21175/RadProc.2016.23 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Tanasic, Ljiljana, Radičević, Radmila, Budinski-Simendić, Jaroslava K., "The High-Energy Irradiation Ageing of Reinforced Elastomers Based on Rubber Blends" in RAD Conference Proceedings (2016):99-102,
https://doi.org/10.21175/RadProc.2016.23 . .

TY  - JOUR
AU  - Cakić, Suzana M.
AU  - Ristić, Ivan S.
AU  - Marinović-Cincović, Milena
AU  - Stojiljković, Dragan T.
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1242
AB  - Castor oil polyols (COLs) have been synthesized from glycolyzed oligoester polyol in order to produce waterborne polyurethane (WPU)/silica hybrid dispersions. Soft drinks poly(ethylene terephthalate) (PET) bottles were depolymerized by glycolysis with different molar ratio of poly(ethylene glycol) ( PEG 400), in the presence of zinc acetate as catalyst. The obtained glycolyzed products were reacted with castor oil (CO) to attain castor oil polyols by the process of transesterification. Five castor oil polyols were used with hydroxyl values of 255, 275, 326, 366 and 426 mg KOH g(-1). Several castor oil-based, polyurethane/ silica hybrid dispersions having soft segment content of 39.6% to 28.2% and two concentrations of SiO2 nanoparticles (0.5 and 1.0) have been prepared. The incorporation effect of SiO2 nanoparticles into the PU matrix and the hydroxyl functionality of the COLs on the thermal and mechanical properties of resulting polyurethane films has been examined by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TG) and measurement of the mechanical properties. The degree of phase separation (DPS) between oxide nanoparticles and hard segment, and particle size in the polyurethane, depends to some extent on nanosilica content and the hydroxyl functionality of the polyols employed in the polyurethane preparation process. Thermal stability of obtained hybrid materials depends on the hydroxyl functionality of the COLs and nanosilica content. The T-10 and T-50% (the temperature where 10 and 50% weight loss occurred) of WPU films decreased with the rise of OH functionality of castor oil polyols, caused by the increase of hard segment content. Glass transition temperature increased with increasing OH functionality and SiO2 content. The hardness, adhesion and gloss quality of the polyurethane films were also determined with a view to assessing the effect of mole ratios of PET to glycol in glycolyzed products, the hydroxyl functionality and the SiO2 content. (C) 2016 Elsevier Ltd. All rights reserved.
T2  - International Journal of Adhesion and Adhesives
T1  - Preparation and characterization of waterborne polyurethane/silica hybrid dispersions from castor oil polyols obtained by glycolysis poly (ethylene terephthalate) waste
VL  - 70
SP  - 329
EP  - 341
DO  - 10.1016/j.ijadhadh.2016.07.010
ER  - 

@article{
author = "Cakić, Suzana M. and Ristić, Ivan S. and Marinović-Cincović, Milena and Stojiljković, Dragan T. and Budinski-Simendić, Jaroslava K.",
year = "2016",
abstract = "Castor oil polyols (COLs) have been synthesized from glycolyzed oligoester polyol in order to produce waterborne polyurethane (WPU)/silica hybrid dispersions. Soft drinks poly(ethylene terephthalate) (PET) bottles were depolymerized by glycolysis with different molar ratio of poly(ethylene glycol) ( PEG 400), in the presence of zinc acetate as catalyst. The obtained glycolyzed products were reacted with castor oil (CO) to attain castor oil polyols by the process of transesterification. Five castor oil polyols were used with hydroxyl values of 255, 275, 326, 366 and 426 mg KOH g(-1). Several castor oil-based, polyurethane/ silica hybrid dispersions having soft segment content of 39.6% to 28.2% and two concentrations of SiO2 nanoparticles (0.5 and 1.0) have been prepared. The incorporation effect of SiO2 nanoparticles into the PU matrix and the hydroxyl functionality of the COLs on the thermal and mechanical properties of resulting polyurethane films has been examined by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TG) and measurement of the mechanical properties. The degree of phase separation (DPS) between oxide nanoparticles and hard segment, and particle size in the polyurethane, depends to some extent on nanosilica content and the hydroxyl functionality of the polyols employed in the polyurethane preparation process. Thermal stability of obtained hybrid materials depends on the hydroxyl functionality of the COLs and nanosilica content. The T-10 and T-50% (the temperature where 10 and 50% weight loss occurred) of WPU films decreased with the rise of OH functionality of castor oil polyols, caused by the increase of hard segment content. Glass transition temperature increased with increasing OH functionality and SiO2 content. The hardness, adhesion and gloss quality of the polyurethane films were also determined with a view to assessing the effect of mole ratios of PET to glycol in glycolyzed products, the hydroxyl functionality and the SiO2 content. (C) 2016 Elsevier Ltd. All rights reserved.",
journal = "International Journal of Adhesion and Adhesives",
title = "Preparation and characterization of waterborne polyurethane/silica hybrid dispersions from castor oil polyols obtained by glycolysis poly (ethylene terephthalate) waste",
volume = "70",
pages = "329-341",
doi = "10.1016/j.ijadhadh.2016.07.010"
}

Cakić, S. M., Ristić, I. S., Marinović-Cincović, M., Stojiljković, D. T.,& Budinski-Simendić, J. K.. (2016). Preparation and characterization of waterborne polyurethane/silica hybrid dispersions from castor oil polyols obtained by glycolysis poly (ethylene terephthalate) waste. in International Journal of Adhesion and Adhesives, 70, 329-341.
https://doi.org/10.1016/j.ijadhadh.2016.07.010

Cakić SM, Ristić IS, Marinović-Cincović M, Stojiljković DT, Budinski-Simendić JK. Preparation and characterization of waterborne polyurethane/silica hybrid dispersions from castor oil polyols obtained by glycolysis poly (ethylene terephthalate) waste. in International Journal of Adhesion and Adhesives. 2016;70:329-341.
doi:10.1016/j.ijadhadh.2016.07.010 .

Cakić, Suzana M., Ristić, Ivan S., Marinović-Cincović, Milena, Stojiljković, Dragan T., Budinski-Simendić, Jaroslava K., "Preparation and characterization of waterborne polyurethane/silica hybrid dispersions from castor oil polyols obtained by glycolysis poly (ethylene terephthalate) waste" in International Journal of Adhesion and Adhesives, 70 (2016):329-341,
https://doi.org/10.1016/j.ijadhadh.2016.07.010 . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/393
AB  - Chlorosulfonated polyethylene rubber (CSM) was blended with chlorinated natural rubber (CNR) with various formulations and blend ratios (CSM/CNR: 100/0; 75/25; 50/50; 25/75; 0/100) keeping the total waste rubber powder (WRP) content constant at 50 phr (parts per 100 rubber). Rheological, mechanical, dynamic mechanical and thermal aging properties as well as irradiation resistance were used as characterization of the blends. The amount of CNR in blends significantly affected the properties of the blends. The CSM/CNR/WRP rubber blend (50/50/50) possessed higher tensile strength compared with pure CSM and CNR rubber even after irradiation or thermal aging. Modulus, tensile strength and hardness of the blends appeared to increase, but elongation at break decreased progressively with increasing CNR content. These properties decreased in rubber blends after thermal aging. After irradiation, hardness, modulus and tensile strength increased up to 200 kGy and then decreased significantly for the blends with high CNR content, whereas no change in modulus was observed. CNR and CSM showed damping peaks at about 65 and -45 degrees C, respectively, and these values correlate with the glass transition temperatures (T(g)s) of CNR and CSM, respectively. The shift in the T-g values was observed after blending, suggesting an interfacial interaction between the two phases probably caused by the covulcanization in CSM/CNR blends.
T2  - Journal of Thermoplastic Composite Materials
T1  - Characterization of composites based on chlorosulfonated polyethylene rubber/chlorinated natural rubber/waste rubber powder rubber blends
VL  - 28
IS  - 2
SP  - 241
EP  - 256
DO  - 10.1177/0892705713481373
ER  - 

@article{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2015",
abstract = "Chlorosulfonated polyethylene rubber (CSM) was blended with chlorinated natural rubber (CNR) with various formulations and blend ratios (CSM/CNR: 100/0; 75/25; 50/50; 25/75; 0/100) keeping the total waste rubber powder (WRP) content constant at 50 phr (parts per 100 rubber). Rheological, mechanical, dynamic mechanical and thermal aging properties as well as irradiation resistance were used as characterization of the blends. The amount of CNR in blends significantly affected the properties of the blends. The CSM/CNR/WRP rubber blend (50/50/50) possessed higher tensile strength compared with pure CSM and CNR rubber even after irradiation or thermal aging. Modulus, tensile strength and hardness of the blends appeared to increase, but elongation at break decreased progressively with increasing CNR content. These properties decreased in rubber blends after thermal aging. After irradiation, hardness, modulus and tensile strength increased up to 200 kGy and then decreased significantly for the blends with high CNR content, whereas no change in modulus was observed. CNR and CSM showed damping peaks at about 65 and -45 degrees C, respectively, and these values correlate with the glass transition temperatures (T(g)s) of CNR and CSM, respectively. The shift in the T-g values was observed after blending, suggesting an interfacial interaction between the two phases probably caused by the covulcanization in CSM/CNR blends.",
journal = "Journal of Thermoplastic Composite Materials",
title = "Characterization of composites based on chlorosulfonated polyethylene rubber/chlorinated natural rubber/waste rubber powder rubber blends",
volume = "28",
number = "2",
pages = "241-256",
doi = "10.1177/0892705713481373"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2015). Characterization of composites based on chlorosulfonated polyethylene rubber/chlorinated natural rubber/waste rubber powder rubber blends. in Journal of Thermoplastic Composite Materials, 28(2), 241-256.
https://doi.org/10.1177/0892705713481373

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. Characterization of composites based on chlorosulfonated polyethylene rubber/chlorinated natural rubber/waste rubber powder rubber blends. in Journal of Thermoplastic Composite Materials. 2015;28(2):241-256.
doi:10.1177/0892705713481373 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "Characterization of composites based on chlorosulfonated polyethylene rubber/chlorinated natural rubber/waste rubber powder rubber blends" in Journal of Thermoplastic Composite Materials, 28, no. 2 (2015):241-256,
https://doi.org/10.1177/0892705713481373 . .

TY  - JOUR
AU  - Marinović-Cincović, Milena
AU  - Marković, Gordana
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
AU  - Jovanović, Vojislav
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/911
AB  - This work aimed to study the effects of gamma radiation on the properties of ethylene propylene diene terpolymer/chlorosulfonated polyethylene rubber blend reinforced with 50 phr of carbon black and cross-linked either with sulfur/tetramethylthiuram disulfide or dicumyl peroxide. Irradiation doses were 100, 200, and 400 kGy. It was observed that doses higher than 200 kGy practically destroy the assessed properties of all obtained elastomeric materials, irrespective of used curing system. However, samples cured with sulfur showed a pronounced decrease in mechanical properties.
T2  - Journal of Thermoplastic Composite Materials
T1  - The influence of gamma radiation on the properties of elastomers based on ethylene propylene diene terpolymer and chlorosulfonated polyethylene rubber
VL  - 28
IS  - 10
SP  - 1361
EP  - 1372
DO  - 10.1177/0892705713511481
ER  - 

@article{
author = "Marinović-Cincović, Milena and Marković, Gordana and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K. and Jovanović, Vojislav",
year = "2015",
abstract = "This work aimed to study the effects of gamma radiation on the properties of ethylene propylene diene terpolymer/chlorosulfonated polyethylene rubber blend reinforced with 50 phr of carbon black and cross-linked either with sulfur/tetramethylthiuram disulfide or dicumyl peroxide. Irradiation doses were 100, 200, and 400 kGy. It was observed that doses higher than 200 kGy practically destroy the assessed properties of all obtained elastomeric materials, irrespective of used curing system. However, samples cured with sulfur showed a pronounced decrease in mechanical properties.",
journal = "Journal of Thermoplastic Composite Materials",
title = "The influence of gamma radiation on the properties of elastomers based on ethylene propylene diene terpolymer and chlorosulfonated polyethylene rubber",
volume = "28",
number = "10",
pages = "1361-1372",
doi = "10.1177/0892705713511481"
}

Marinović-Cincović, M., Marković, G., Samaržija-Jovanović, S., Budinski-Simendić, J. K.,& Jovanović, V.. (2015). The influence of gamma radiation on the properties of elastomers based on ethylene propylene diene terpolymer and chlorosulfonated polyethylene rubber. in Journal of Thermoplastic Composite Materials, 28(10), 1361-1372.
https://doi.org/10.1177/0892705713511481

Marinović-Cincović M, Marković G, Samaržija-Jovanović S, Budinski-Simendić JK, Jovanović V. The influence of gamma radiation on the properties of elastomers based on ethylene propylene diene terpolymer and chlorosulfonated polyethylene rubber. in Journal of Thermoplastic Composite Materials. 2015;28(10):1361-1372.
doi:10.1177/0892705713511481 .

Marinović-Cincović, Milena, Marković, Gordana, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., Jovanović, Vojislav, "The influence of gamma radiation on the properties of elastomers based on ethylene propylene diene terpolymer and chlorosulfonated polyethylene rubber" in Journal of Thermoplastic Composite Materials, 28, no. 10 (2015):1361-1372,
https://doi.org/10.1177/0892705713511481 . .

TY  - JOUR
AU  - Samaržija-Jovanović, Suzana
AU  - Jovanović, Vojislav
AU  - Marinović-Cincović, Milena
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marković, Gordana
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6008
AB  - Acrylonitrile butadiene rubber (NBR) and ethylene-propylene diene monomer (EPDM) rubber compounds have been prepared without and with 50 phr contents of high abrasion furnace carbon black (HAF). Cure characteristics, namely, minimum (M-1) and maximum torque (M-h), scorch time (t(s2)), the optimum cure time (t(c90)) and the cure rate index (CRI) have been investigated. Prepared compounds have been subjected to gamma radiation doses up to 200 kGy to induce radiation crosslinking and degradation process under atmospheric conditions. Mechanical and physical properties, namely, tensile strength (TS), elongation at break (Eb), hardness (Sh-A), Flory-Huggins parameter (chi), the crosslink density (nu) and the molecular weight of the rubber between two crosslinks ((M) over bar (c)) have been followed up as a function of irradiation dose. The morphology investigations of prepared compounds were carried out using SEM micrograph. The results obtained indicate that improvement to irradiation has been attained in different properties of carbon black reinforced NBR and EPDM rubber compounds with respect to unloaded ones. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Composites: Part B: Engineering
T1  - Comparative study of radiation effect on rubber-carbon black compounds
VL  - 62
SP  - 183
EP  - 190
DO  - 10.1016/j.compositesb.2014.02.029
ER  - 

@article{
author = "Samaržija-Jovanović, Suzana and Jovanović, Vojislav and Marinović-Cincović, Milena and Budinski-Simendić, Jaroslava K. and Marković, Gordana",
year = "2014",
abstract = "Acrylonitrile butadiene rubber (NBR) and ethylene-propylene diene monomer (EPDM) rubber compounds have been prepared without and with 50 phr contents of high abrasion furnace carbon black (HAF). Cure characteristics, namely, minimum (M-1) and maximum torque (M-h), scorch time (t(s2)), the optimum cure time (t(c90)) and the cure rate index (CRI) have been investigated. Prepared compounds have been subjected to gamma radiation doses up to 200 kGy to induce radiation crosslinking and degradation process under atmospheric conditions. Mechanical and physical properties, namely, tensile strength (TS), elongation at break (Eb), hardness (Sh-A), Flory-Huggins parameter (chi), the crosslink density (nu) and the molecular weight of the rubber between two crosslinks ((M) over bar (c)) have been followed up as a function of irradiation dose. The morphology investigations of prepared compounds were carried out using SEM micrograph. The results obtained indicate that improvement to irradiation has been attained in different properties of carbon black reinforced NBR and EPDM rubber compounds with respect to unloaded ones. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Composites: Part B: Engineering",
title = "Comparative study of radiation effect on rubber-carbon black compounds",
volume = "62",
pages = "183-190",
doi = "10.1016/j.compositesb.2014.02.029"
}

Samaržija-Jovanović, S., Jovanović, V., Marinović-Cincović, M., Budinski-Simendić, J. K.,& Marković, G.. (2014). Comparative study of radiation effect on rubber-carbon black compounds. in Composites: Part B: Engineering, 62, 183-190.
https://doi.org/10.1016/j.compositesb.2014.02.029

Samaržija-Jovanović S, Jovanović V, Marinović-Cincović M, Budinski-Simendić JK, Marković G. Comparative study of radiation effect on rubber-carbon black compounds. in Composites: Part B: Engineering. 2014;62:183-190.
doi:10.1016/j.compositesb.2014.02.029 .

Samaržija-Jovanović, Suzana, Jovanović, Vojislav, Marinović-Cincović, Milena, Budinski-Simendić, Jaroslava K., Marković, Gordana, "Comparative study of radiation effect on rubber-carbon black compounds" in Composites: Part B: Engineering, 62 (2014):183-190,
https://doi.org/10.1016/j.compositesb.2014.02.029 . .

TY  - CHAP
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7053
AB  - The nonlinear viscoelastic behavior of the composites of rubber filled with carbon black, silica, carbon nanotube (CNT), clay and surface-modified nanosilica were studied. The behavior of carbon black-filled rubber is thoroughly analyzed with the intention of developing a constitutive model able to reproduce both static and dynamic material responses. Several nonlinear viscoelastic models have been examined thoroughly and for each of them advantages and disadvantages are highlighted. A series of experiments concerning both static and dynamic tests were performed aimed at measuring all the relevant nonlinear effects. Temperature and strain rate dependencies were investigated and discussed. The standard methodology was applied to perform both tensile and compressive quasi-static tests. Some shortcomings of this procedure, resulting in a unreliable stress-strain constitutive curve around the undeformed configuration, were identified. This lead to the design a non-standard cylindrical specimen able to bear both tensile and compressive loading. Consequently, the influence of the shape factor was removed and the same boundary conditions, in tension and compression, were applied. This allowed the stiffness around the undeformed configuration to be evaluated in detail. The quasi-static experimental results also allowed the influence of the Mullins effect on the quasi-static response to be investigated: during the loading cycles, there is a significant reduction in the stress at a given level of strain, which is a consequence of the internal material rearrangement, i.e., the Mullins effect. This damage phenomenon is sometimes reported to induce transverse isotropy in the material, which is usually assumed to be isotropic. The Payne effect becomes more pronounced at higher silica loading. The filler characteristics such as particle size, specific surface area, and the surface structural features were found to be the key parameters influencing the Payne effect. A nonlinear decrease in storage modulus with increasing strain was observed for unfilled compounds also. The results reveal that the mechanism includes the breakdown of different networks namely the filler-filler network, the weak polymer-filler network, the chemical network, and the entanglement network. The model of variable network density proposed by Maier and Goritz has been applied to explain the nonlinear behavior. The model fits well with the experimental results. The interaction between epoxidized elastomeric matrix and silica as filler was extremely improved, even in the presence of very low content of epoxy groups into the polymer chain.
T2  - Advances in Polymer Science
T1  - Modeling of Non-Linear Viscoelastic Behavior of Filled Rubbers
VL  - 264
SP  - 193
EP  - 271
DO  - 10.1007/978-3-319-08702-3_8
ER  - 

@inbook{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2014",
abstract = "The nonlinear viscoelastic behavior of the composites of rubber filled with carbon black, silica, carbon nanotube (CNT), clay and surface-modified nanosilica were studied. The behavior of carbon black-filled rubber is thoroughly analyzed with the intention of developing a constitutive model able to reproduce both static and dynamic material responses. Several nonlinear viscoelastic models have been examined thoroughly and for each of them advantages and disadvantages are highlighted. A series of experiments concerning both static and dynamic tests were performed aimed at measuring all the relevant nonlinear effects. Temperature and strain rate dependencies were investigated and discussed. The standard methodology was applied to perform both tensile and compressive quasi-static tests. Some shortcomings of this procedure, resulting in a unreliable stress-strain constitutive curve around the undeformed configuration, were identified. This lead to the design a non-standard cylindrical specimen able to bear both tensile and compressive loading. Consequently, the influence of the shape factor was removed and the same boundary conditions, in tension and compression, were applied. This allowed the stiffness around the undeformed configuration to be evaluated in detail. The quasi-static experimental results also allowed the influence of the Mullins effect on the quasi-static response to be investigated: during the loading cycles, there is a significant reduction in the stress at a given level of strain, which is a consequence of the internal material rearrangement, i.e., the Mullins effect. This damage phenomenon is sometimes reported to induce transverse isotropy in the material, which is usually assumed to be isotropic. The Payne effect becomes more pronounced at higher silica loading. The filler characteristics such as particle size, specific surface area, and the surface structural features were found to be the key parameters influencing the Payne effect. A nonlinear decrease in storage modulus with increasing strain was observed for unfilled compounds also. The results reveal that the mechanism includes the breakdown of different networks namely the filler-filler network, the weak polymer-filler network, the chemical network, and the entanglement network. The model of variable network density proposed by Maier and Goritz has been applied to explain the nonlinear behavior. The model fits well with the experimental results. The interaction between epoxidized elastomeric matrix and silica as filler was extremely improved, even in the presence of very low content of epoxy groups into the polymer chain.",
journal = "Advances in Polymer Science",
booktitle = "Modeling of Non-Linear Viscoelastic Behavior of Filled Rubbers",
volume = "264",
pages = "193-271",
doi = "10.1007/978-3-319-08702-3_8"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2014). Modeling of Non-Linear Viscoelastic Behavior of Filled Rubbers. in Advances in Polymer Science, 264, 193-271.
https://doi.org/10.1007/978-3-319-08702-3_8

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. Modeling of Non-Linear Viscoelastic Behavior of Filled Rubbers. in Advances in Polymer Science. 2014;264:193-271.
doi:10.1007/978-3-319-08702-3_8 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "Modeling of Non-Linear Viscoelastic Behavior of Filled Rubbers" in Advances in Polymer Science, 264 (2014):193-271,
https://doi.org/10.1007/978-3-319-08702-3_8 . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Marinović-Cincović, Milena
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5634
AB  - In this study, the effect of gamma-rays on the mechanical and thermal properties of polymer composites based on chlorinated isobutylene-isoprene rubber/chlorosulphonated polyethylene rubber blend with varying contents of carbon black (CB) filler was investigated. The samples were irradiated at ambient conditions with 100, 200 and 400kGy radiation doses. Tensile strength and hardness are increasing with CB content and radiation dose is increasing, while elongation at break is decreasing. Loss of mass of 0.5, 10 and 30% was calculated for the samples from their respective thermogravimetric curves. The thermal stability of the nanocomposites was improved by both the degree of loading with filler and the cross-linking induced by gamma-irradiation.
T2  - Journal of Thermoplastic Composite Materials
T1  - Thermal stability of gamma-irradiated chlorinated isobutylene-isoprene copolymer/chlorosulphonated polyethylene rubber blend/carbon black nanocomposites
VL  - 26
IS  - 8
SP  - 1071
EP  - 1081
DO  - 10.1177/0892705711433438
ER  - 

@article{
author = "Marković, Gordana and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Marinović-Cincović, Milena and Budinski-Simendić, Jaroslava K.",
year = "2013",
abstract = "In this study, the effect of gamma-rays on the mechanical and thermal properties of polymer composites based on chlorinated isobutylene-isoprene rubber/chlorosulphonated polyethylene rubber blend with varying contents of carbon black (CB) filler was investigated. The samples were irradiated at ambient conditions with 100, 200 and 400kGy radiation doses. Tensile strength and hardness are increasing with CB content and radiation dose is increasing, while elongation at break is decreasing. Loss of mass of 0.5, 10 and 30% was calculated for the samples from their respective thermogravimetric curves. The thermal stability of the nanocomposites was improved by both the degree of loading with filler and the cross-linking induced by gamma-irradiation.",
journal = "Journal of Thermoplastic Composite Materials",
title = "Thermal stability of gamma-irradiated chlorinated isobutylene-isoprene copolymer/chlorosulphonated polyethylene rubber blend/carbon black nanocomposites",
volume = "26",
number = "8",
pages = "1071-1081",
doi = "10.1177/0892705711433438"
}

Marković, G., Jovanović, V., Samaržija-Jovanović, S., Marinović-Cincović, M.,& Budinski-Simendić, J. K.. (2013). Thermal stability of gamma-irradiated chlorinated isobutylene-isoprene copolymer/chlorosulphonated polyethylene rubber blend/carbon black nanocomposites. in Journal of Thermoplastic Composite Materials, 26(8), 1071-1081.
https://doi.org/10.1177/0892705711433438

Marković G, Jovanović V, Samaržija-Jovanović S, Marinović-Cincović M, Budinski-Simendić JK. Thermal stability of gamma-irradiated chlorinated isobutylene-isoprene copolymer/chlorosulphonated polyethylene rubber blend/carbon black nanocomposites. in Journal of Thermoplastic Composite Materials. 2013;26(8):1071-1081.
doi:10.1177/0892705711433438 .

Marković, Gordana, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Marinović-Cincović, Milena, Budinski-Simendić, Jaroslava K., "Thermal stability of gamma-irradiated chlorinated isobutylene-isoprene copolymer/chlorosulphonated polyethylene rubber blend/carbon black nanocomposites" in Journal of Thermoplastic Composite Materials, 26, no. 8 (2013):1071-1081,
https://doi.org/10.1177/0892705711433438 . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5712
AB  - Biogenic silica (BSi) was added at different ratios to some polymer blends of polyisoprene rubber (NR) and chlorosulphonated polyethylene rubber (CSM) cured by conventional sulfur system. The reinforcing performance of the filler was investigated using rheometric, mechanical and swelling measurements, differential scanning calorimetry (DSC), thermogravimetric (TGA) and scanning electron microscopy (SEM) analysis. There was a remarkable decrease in the optimum cure time (t(c90)) and the scorch time (t(s2)), which was associated with an increase in the cure rate index (CRI), with filler loading up to 30 phr in the different blend ratios. The tensile strength and hardness was 4-5 Sh-A higher in the case for the different blend compositions, while the resistance to swelling in toluene became higher. SEM photographs show that the filler is located at the interface between the different polymers which induces compatibilization in the immiscible blends. DSC scans of the filled blends showed shifts in the glass transition temperatures Tg which can be attributed to the improve interfacial bonding between filler and NR/CSM matrix. A higher thermal stability of NR/CSM/BSi composites was detected. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Composites: Part B: Engineering
T1  - NR/CSM/biogenic silica rubber blend composites
VL  - 55
SP  - 368
EP  - 373
DO  - 10.1016/j.compositesb.2013.06.045
ER  - 

@article{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2013",
abstract = "Biogenic silica (BSi) was added at different ratios to some polymer blends of polyisoprene rubber (NR) and chlorosulphonated polyethylene rubber (CSM) cured by conventional sulfur system. The reinforcing performance of the filler was investigated using rheometric, mechanical and swelling measurements, differential scanning calorimetry (DSC), thermogravimetric (TGA) and scanning electron microscopy (SEM) analysis. There was a remarkable decrease in the optimum cure time (t(c90)) and the scorch time (t(s2)), which was associated with an increase in the cure rate index (CRI), with filler loading up to 30 phr in the different blend ratios. The tensile strength and hardness was 4-5 Sh-A higher in the case for the different blend compositions, while the resistance to swelling in toluene became higher. SEM photographs show that the filler is located at the interface between the different polymers which induces compatibilization in the immiscible blends. DSC scans of the filled blends showed shifts in the glass transition temperatures Tg which can be attributed to the improve interfacial bonding between filler and NR/CSM matrix. A higher thermal stability of NR/CSM/BSi composites was detected. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Composites: Part B: Engineering",
title = "NR/CSM/biogenic silica rubber blend composites",
volume = "55",
pages = "368-373",
doi = "10.1016/j.compositesb.2013.06.045"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2013). NR/CSM/biogenic silica rubber blend composites. in Composites: Part B: Engineering, 55, 368-373.
https://doi.org/10.1016/j.compositesb.2013.06.045

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. NR/CSM/biogenic silica rubber blend composites. in Composites: Part B: Engineering. 2013;55:368-373.
doi:10.1016/j.compositesb.2013.06.045 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "NR/CSM/biogenic silica rubber blend composites" in Composites: Part B: Engineering, 55 (2013):368-373,
https://doi.org/10.1016/j.compositesb.2013.06.045 . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Veljkovic, Olivera
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5283
AB  - Blend of polybutadiene (BR) rubber with varying ratios of chlorosulphonated polyethylene rubber (CSM), BR/CSM, keeping the total waste rubber powder (WRP) content constant at 50 phr (parts per 100 rubber) have been prepared on a laboratory-size (300 x 600 mm) two-roll mixing mill maintained at 40 +/- 5 degrees C. The mechanical properties, namely tensile strength (TS), tensile modulus at 100% elongation (M100), elongation at break (Eb%) and hardness have been followed up as a function of irradiation dose (dose rate of 10 kGy h(-1) and total absorbed dose of 100, 200, 300 and 400 kGy) as well as blend composition. The results indicated that the addition of CSM has improved the properties of BR/CSM rubber blends waste rubber powder filled composites. The improvement in mechanical properties of the BR/CSM/WRP (50/50/50) rubber blends is in correlation with homogenous WRP distribution which has been assigned by scanning electron microscopy. Also BR/CSM rubber blends waste rubber powder filled composites are thermally and irradiation more stable than BR and CSM rubbers alone. (c) 2012 Elsevier Ltd. All rights reserved.
T2  - Composites: Part B: Engineering
T1  - Composites based on waste rubber powder and rubber blends: BR/CSM
VL  - 45
IS  - 1
SP  - 178
EP  - 184
DO  - 10.1016/j.compositesb.2012.08.013
ER  - 

@article{
author = "Marković, Gordana and Veljkovic, Olivera and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2013",
abstract = "Blend of polybutadiene (BR) rubber with varying ratios of chlorosulphonated polyethylene rubber (CSM), BR/CSM, keeping the total waste rubber powder (WRP) content constant at 50 phr (parts per 100 rubber) have been prepared on a laboratory-size (300 x 600 mm) two-roll mixing mill maintained at 40 +/- 5 degrees C. The mechanical properties, namely tensile strength (TS), tensile modulus at 100% elongation (M100), elongation at break (Eb%) and hardness have been followed up as a function of irradiation dose (dose rate of 10 kGy h(-1) and total absorbed dose of 100, 200, 300 and 400 kGy) as well as blend composition. The results indicated that the addition of CSM has improved the properties of BR/CSM rubber blends waste rubber powder filled composites. The improvement in mechanical properties of the BR/CSM/WRP (50/50/50) rubber blends is in correlation with homogenous WRP distribution which has been assigned by scanning electron microscopy. Also BR/CSM rubber blends waste rubber powder filled composites are thermally and irradiation more stable than BR and CSM rubbers alone. (c) 2012 Elsevier Ltd. All rights reserved.",
journal = "Composites: Part B: Engineering",
title = "Composites based on waste rubber powder and rubber blends: BR/CSM",
volume = "45",
number = "1",
pages = "178-184",
doi = "10.1016/j.compositesb.2012.08.013"
}

Marković, G., Veljkovic, O., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2013). Composites based on waste rubber powder and rubber blends: BR/CSM. in Composites: Part B: Engineering, 45(1), 178-184.
https://doi.org/10.1016/j.compositesb.2012.08.013

Marković G, Veljkovic O, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. Composites based on waste rubber powder and rubber blends: BR/CSM. in Composites: Part B: Engineering. 2013;45(1):178-184.
doi:10.1016/j.compositesb.2012.08.013 .

Marković, Gordana, Veljkovic, Olivera, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "Composites based on waste rubber powder and rubber blends: BR/CSM" in Composites: Part B: Engineering, 45, no. 1 (2013):178-184,
https://doi.org/10.1016/j.compositesb.2012.08.013 . .

TY  - JOUR
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5285
AB  - This paper investigates the effect of carbon black filler (CB) (loading 60-100 phr) on the cure kinetics, mechanical properties, morphology and thermal stability of acrylonitrile-butadiene/ethylene-propylene-diene (NBR/EPDM) rubber blends. The determination of cure characteristics was estimated by Monsanto Oscillating Disc Rheometer R-100. Mechanical properties such as tensile strength, elongation at break, modulus at 200% and 300% elongation, hardness, have been measured at room temperature on an electric tensile testing machine (Zwick 1425) according to ASTM D 412. Morphology of the cross linked system was carried out by scanning electron microscope (SEM). The cure kinetics were determined from three temperature rheokinetic curves (T-1 = 160 degrees C, T-2 = 180 degrees C and T-3 = 190 degrees C). From obtained results of NBR/EPDM/CB (80/20/70) composite, a correlation between mechanical properties and calculated activation energy of cross link (E-ac) and reversion (E-ar) process can be concluded. Maximum tensile strength values and synergism for this blend has been observed. The apparent activation energy values (E-a) of degradation were determined by the Kissinger method for NBR, EPDM and NBR/EPDM/CB rubber blend. E-a for the NBR/EPDM/CB rubber blend composite is lower (45.1 kJ/mol) compared to E-a for the rubber based on NBR (156 kJ/mol) and EPDM (75 kJ/mol), which indicates easier formation of rubber blend. (c) 2012 Elsevier Ltd. All rights reserved.
T2  - Composites: Part B: Engineering
T1  - Composites based on carbon black reinforced NBR/EPDM rubber blends
VL  - 45
IS  - 1
SP  - 333
EP  - 340
DO  - 10.1016/j.compositesb.2012.05.020
ER  - 

@article{
author = "Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K. and Marković, Gordana and Marinović-Cincović, Milena",
year = "2013",
abstract = "This paper investigates the effect of carbon black filler (CB) (loading 60-100 phr) on the cure kinetics, mechanical properties, morphology and thermal stability of acrylonitrile-butadiene/ethylene-propylene-diene (NBR/EPDM) rubber blends. The determination of cure characteristics was estimated by Monsanto Oscillating Disc Rheometer R-100. Mechanical properties such as tensile strength, elongation at break, modulus at 200% and 300% elongation, hardness, have been measured at room temperature on an electric tensile testing machine (Zwick 1425) according to ASTM D 412. Morphology of the cross linked system was carried out by scanning electron microscope (SEM). The cure kinetics were determined from three temperature rheokinetic curves (T-1 = 160 degrees C, T-2 = 180 degrees C and T-3 = 190 degrees C). From obtained results of NBR/EPDM/CB (80/20/70) composite, a correlation between mechanical properties and calculated activation energy of cross link (E-ac) and reversion (E-ar) process can be concluded. Maximum tensile strength values and synergism for this blend has been observed. The apparent activation energy values (E-a) of degradation were determined by the Kissinger method for NBR, EPDM and NBR/EPDM/CB rubber blend. E-a for the NBR/EPDM/CB rubber blend composite is lower (45.1 kJ/mol) compared to E-a for the rubber based on NBR (156 kJ/mol) and EPDM (75 kJ/mol), which indicates easier formation of rubber blend. (c) 2012 Elsevier Ltd. All rights reserved.",
journal = "Composites: Part B: Engineering",
title = "Composites based on carbon black reinforced NBR/EPDM rubber blends",
volume = "45",
number = "1",
pages = "333-340",
doi = "10.1016/j.compositesb.2012.05.020"
}

Jovanović, V., Samaržija-Jovanović, S., Budinski-Simendić, J. K., Marković, G.,& Marinović-Cincović, M.. (2013). Composites based on carbon black reinforced NBR/EPDM rubber blends. in Composites: Part B: Engineering, 45(1), 333-340.
https://doi.org/10.1016/j.compositesb.2012.05.020

Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK, Marković G, Marinović-Cincović M. Composites based on carbon black reinforced NBR/EPDM rubber blends. in Composites: Part B: Engineering. 2013;45(1):333-340.
doi:10.1016/j.compositesb.2012.05.020 .

Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., Marković, Gordana, Marinović-Cincović, Milena, "Composites based on carbon black reinforced NBR/EPDM rubber blends" in Composites: Part B: Engineering, 45, no. 1 (2013):333-340,
https://doi.org/10.1016/j.compositesb.2012.05.020 . .

TY  - JOUR
AU  - Cakić, Suzana M.
AU  - Spirkova, Milena
AU  - Ristić, Ivan S.
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marinović-Cincović, Milena
AU  - Poreba, Rafal
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5364
AB  - Three water-based polyurethane dispersions (PUD) were synthesized by modified dispersing procedure using polycarbonate diol (PCD), isophorone diisocyanate (IPDI), dimethylolpropionic acid (DMPA), triethylamine (TEA) and ethylenediamine (EDA). The ionic group content in the polyurethane-ionomer structure was varied by changing the amount of the internal emulsifier, DMPA (4.5, 7.5 and 10 wt.% to the prepolymer weight). The expected structures of obtained materials were confirmed by FTIR spectroscopy. The effect of the DMPA content on the thermal properties of polyurethane films was measured by TGA, DTA, DSC and DMTA methods. Increased DMPA amounts result in the higher hard segment contents and in the increase of the weight loss corresponding to the degradation of the hard segments. The reduction of hard segment content led to the elevated temperature of decomposition and to the decrease of the glass transition temperature and thermoplasticity. The atomic force microscopy (AFM), results indicated that phase separation between hard and soft segment of PUD with higher DMPA content is more significant than of PUD with lower DMPA content. The physico-mechanical properties, such as hardness, adhesion test and gloss of the dried films were also determined considering the effect of DMPA content on coating properties. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - The waterborne polyurethane dispersions based on polycarbonate diol: Effect of ionic content
VL  - 138
IS  - 1
SP  - 277
EP  - 285
DO  - 10.1016/j.matchemphys.2012.11.057
ER  - 

@article{
author = "Cakić, Suzana M. and Spirkova, Milena and Ristić, Ivan S. and Budinski-Simendić, Jaroslava K. and Marinović-Cincović, Milena and Poreba, Rafal",
year = "2013",
abstract = "Three water-based polyurethane dispersions (PUD) were synthesized by modified dispersing procedure using polycarbonate diol (PCD), isophorone diisocyanate (IPDI), dimethylolpropionic acid (DMPA), triethylamine (TEA) and ethylenediamine (EDA). The ionic group content in the polyurethane-ionomer structure was varied by changing the amount of the internal emulsifier, DMPA (4.5, 7.5 and 10 wt.% to the prepolymer weight). The expected structures of obtained materials were confirmed by FTIR spectroscopy. The effect of the DMPA content on the thermal properties of polyurethane films was measured by TGA, DTA, DSC and DMTA methods. Increased DMPA amounts result in the higher hard segment contents and in the increase of the weight loss corresponding to the degradation of the hard segments. The reduction of hard segment content led to the elevated temperature of decomposition and to the decrease of the glass transition temperature and thermoplasticity. The atomic force microscopy (AFM), results indicated that phase separation between hard and soft segment of PUD with higher DMPA content is more significant than of PUD with lower DMPA content. The physico-mechanical properties, such as hardness, adhesion test and gloss of the dried films were also determined considering the effect of DMPA content on coating properties. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "The waterborne polyurethane dispersions based on polycarbonate diol: Effect of ionic content",
volume = "138",
number = "1",
pages = "277-285",
doi = "10.1016/j.matchemphys.2012.11.057"
}

Cakić, S. M., Spirkova, M., Ristić, I. S., Budinski-Simendić, J. K., Marinović-Cincović, M.,& Poreba, R.. (2013). The waterborne polyurethane dispersions based on polycarbonate diol: Effect of ionic content. in Materials Chemistry and Physics, 138(1), 277-285.
https://doi.org/10.1016/j.matchemphys.2012.11.057

Cakić SM, Spirkova M, Ristić IS, Budinski-Simendić JK, Marinović-Cincović M, Poreba R. The waterborne polyurethane dispersions based on polycarbonate diol: Effect of ionic content. in Materials Chemistry and Physics. 2013;138(1):277-285.
doi:10.1016/j.matchemphys.2012.11.057 .

Cakić, Suzana M., Spirkova, Milena, Ristić, Ivan S., Budinski-Simendić, Jaroslava K., Marinović-Cincović, Milena, Poreba, Rafal, "The waterborne polyurethane dispersions based on polycarbonate diol: Effect of ionic content" in Materials Chemistry and Physics, 138, no. 1 (2013):277-285,
https://doi.org/10.1016/j.matchemphys.2012.11.057 . .

TY  - JOUR
AU  - Ristić, Ivan S.
AU  - Marinović-Cincović, Milena
AU  - Cakić, Suzana M.
AU  - Tanasic, Ljiljana M.
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5503
AB  - The topology of biodegradable polyesters can be adjusted by incorporating multifunctional polyols into the polyester backbone to obtain branched polymers. The aim of this study was to prepare the biodegradable-branched polyester polyols based on l-lactide and castor oil using the trifluoromethanesulfonic acid as a catalyst. FTIR and H-1 NMR spectroscopy measurements were used to estimate the molecular structure of the novel materials. The polyester polyol was synthesized by core-first method which involves a polymerization of l-lactide by using a castor oil as multifunctional initiator. Molar masses estimated by gel permeation chromatography and vapor pressure osmometry were in good correlation with calculated values based on hydroxyl number of obtained polymers. DSC measurements confirmed high crystallinity degree of the synthesized material. It was assessed that the molar masses of obtained polymers-influenced glass transition temperature significantly. The thermal stability was investigated by TG analysis, and the results have shown the dependence of weight loss on the arm length of the star-shaped polyesters. The thermal stability of star-shaped polyesters significantly decreased with degradation of polyester polyol obtained in acid solution.
T2  - Polymer Bulletin
T1  - Synthesis and properties of novel star-shaped polyesters based on l-lactide and castor oil
VL  - 70
IS  - 6
SP  - 1723
EP  - 1738
DO  - 10.1007/s00289-013-0917-0
ER  - 

@article{
author = "Ristić, Ivan S. and Marinović-Cincović, Milena and Cakić, Suzana M. and Tanasic, Ljiljana M. and Budinski-Simendić, Jaroslava K.",
year = "2013",
abstract = "The topology of biodegradable polyesters can be adjusted by incorporating multifunctional polyols into the polyester backbone to obtain branched polymers. The aim of this study was to prepare the biodegradable-branched polyester polyols based on l-lactide and castor oil using the trifluoromethanesulfonic acid as a catalyst. FTIR and H-1 NMR spectroscopy measurements were used to estimate the molecular structure of the novel materials. The polyester polyol was synthesized by core-first method which involves a polymerization of l-lactide by using a castor oil as multifunctional initiator. Molar masses estimated by gel permeation chromatography and vapor pressure osmometry were in good correlation with calculated values based on hydroxyl number of obtained polymers. DSC measurements confirmed high crystallinity degree of the synthesized material. It was assessed that the molar masses of obtained polymers-influenced glass transition temperature significantly. The thermal stability was investigated by TG analysis, and the results have shown the dependence of weight loss on the arm length of the star-shaped polyesters. The thermal stability of star-shaped polyesters significantly decreased with degradation of polyester polyol obtained in acid solution.",
journal = "Polymer Bulletin",
title = "Synthesis and properties of novel star-shaped polyesters based on l-lactide and castor oil",
volume = "70",
number = "6",
pages = "1723-1738",
doi = "10.1007/s00289-013-0917-0"
}

Ristić, I. S., Marinović-Cincović, M., Cakić, S. M., Tanasic, L. M.,& Budinski-Simendić, J. K.. (2013). Synthesis and properties of novel star-shaped polyesters based on l-lactide and castor oil. in Polymer Bulletin, 70(6), 1723-1738.
https://doi.org/10.1007/s00289-013-0917-0

Ristić IS, Marinović-Cincović M, Cakić SM, Tanasic LM, Budinski-Simendić JK. Synthesis and properties of novel star-shaped polyesters based on l-lactide and castor oil. in Polymer Bulletin. 2013;70(6):1723-1738.
doi:10.1007/s00289-013-0917-0 .

Ristić, Ivan S., Marinović-Cincović, Milena, Cakić, Suzana M., Tanasic, Ljiljana M., Budinski-Simendić, Jaroslava K., "Synthesis and properties of novel star-shaped polyesters based on l-lactide and castor oil" in Polymer Bulletin, 70, no. 6 (2013):1723-1738,
https://doi.org/10.1007/s00289-013-0917-0 . .

TY  - CONF
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9304
AB  - This work aimed to study the effects of gamma irradiation on the properties of
ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend
(EPDM/CSM) 50/50 reinforced with 50 phr (parts per hundred rubber) of carbon
black and crosslinked either with sulphur/tetramethyl thiuram disulphide or
dicumyl peroxide. Irradiation dose rate were 100, 200 and 400 kGy h-1. It was
observed that doses higher than 200 kGy practically destroy the assessed properties
for all obtained elastomeric materials, irrespective of used curing system. However
samples cured with sulphur showed a pronounced decrease in mechanical
properties.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
T1  - The effect of gamma irradiation on ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend cured with different systems
VL  - 1
SP  - 406
EP  - 408
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9304
ER  - 

@conference{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2012",
abstract = "This work aimed to study the effects of gamma irradiation on the properties of
ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend
(EPDM/CSM) 50/50 reinforced with 50 phr (parts per hundred rubber) of carbon
black and crosslinked either with sulphur/tetramethyl thiuram disulphide or
dicumyl peroxide. Irradiation dose rate were 100, 200 and 400 kGy h-1. It was
observed that doses higher than 200 kGy practically destroy the assessed properties
for all obtained elastomeric materials, irrespective of used curing system. However
samples cured with sulphur showed a pronounced decrease in mechanical
properties.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry",
title = "The effect of gamma irradiation on ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend cured with different systems",
volume = "1",
pages = "406-408",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9304"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2012). The effect of gamma irradiation on ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend cured with different systems. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia., 1, 406-408.
https://hdl.handle.net/21.15107/rcub_vinar_9304

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. The effect of gamma irradiation on ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend cured with different systems. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry. 2012;1:406-408.
https://hdl.handle.net/21.15107/rcub_vinar_9304 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "The effect of gamma irradiation on ethylene propylene diene terpolymer/chlorosulphonated polyethylene rubber blend cured with different systems" in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry, 1 (2012):406-408,
https://hdl.handle.net/21.15107/rcub_vinar_9304 .

TY  - JOUR
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4728
AB  - The effect of gamma-irradiation on the acrylonitrile butadiene/chlorosulphonated polyethylene rubber blends (NBR/CSM) based nanocomposites containing carbon black (CB) and silica filler (Si) were investigated by TG-DTG and ATR-FTIR techniques. The silica (with primary particle size of 22 nm) was added in content of 0, 10, 20 and 30 phr and carbon black (with primary particle size 40-48 nm) was added in content of 30 phr and rubber blend compounds were prepared. The obtained elastomeric materials were aging to different gamma-irradiation doses (100, 200 and 400 kGy). The cure and mechanical properties of obtained nanocomposites were determined. Incorporating 20 phr of silica to the control NBR/CSM rubber blends containing 30 phr CB resulted 152% increase in tensile strength, 116%, in elongation at break and 142% modulus at 100% elongation, according to synergistic effect between the fillers. FUR measurements of aged samples estimated the formation of alcohols, ethers and small amounts of lactones, anhydrides, esters and carboxylic acids after exposure to lower doses of gamma-radiation (100 kGy). On the basis of the obtained spectra the formation of shorter polyene sequences and aromatic rings in aged elastomeric samples are assumed. The results show that 30 phr of carbon black (CB) and 20 phr of silica are needed for the best gamma aging resistance of NBR/CSM rubber nanocomposites. The result of radiation exposure is decrease in mechanical properties. The dose at which ultimate mechanical properties decreased was at 200 kGy. TG-DTG measurements estimated decrease in thermal stability of gamma-irradiated NBR/CSM rubber blend based nanocomposites. Silica reinforced NBR/CSM rubber blend had better radiation resistant than carbon black. Rough and heterogeneity of fracture surfaces has been observed for NBR/CSM rubber blends filled with silica. More uniform morphology of fracture surfaces according to high polymer-filler interaction and low filler-filler interaction has been observed for CB/Si filled NBR/CSM rubber blend. CO 2011 Elsevier Ltd. All rights reserved.
T2  - Composites: Part B: Engineering
T1  - Gamma irradiation aging of NBR/CSM rubber nanocomposites
VL  - 43
IS  - 2
SP  - 609
EP  - 615
DO  - 10.1016/j.compositesb.2011.11.056
ER  - 

@article{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2012",
abstract = "The effect of gamma-irradiation on the acrylonitrile butadiene/chlorosulphonated polyethylene rubber blends (NBR/CSM) based nanocomposites containing carbon black (CB) and silica filler (Si) were investigated by TG-DTG and ATR-FTIR techniques. The silica (with primary particle size of 22 nm) was added in content of 0, 10, 20 and 30 phr and carbon black (with primary particle size 40-48 nm) was added in content of 30 phr and rubber blend compounds were prepared. The obtained elastomeric materials were aging to different gamma-irradiation doses (100, 200 and 400 kGy). The cure and mechanical properties of obtained nanocomposites were determined. Incorporating 20 phr of silica to the control NBR/CSM rubber blends containing 30 phr CB resulted 152% increase in tensile strength, 116%, in elongation at break and 142% modulus at 100% elongation, according to synergistic effect between the fillers. FUR measurements of aged samples estimated the formation of alcohols, ethers and small amounts of lactones, anhydrides, esters and carboxylic acids after exposure to lower doses of gamma-radiation (100 kGy). On the basis of the obtained spectra the formation of shorter polyene sequences and aromatic rings in aged elastomeric samples are assumed. The results show that 30 phr of carbon black (CB) and 20 phr of silica are needed for the best gamma aging resistance of NBR/CSM rubber nanocomposites. The result of radiation exposure is decrease in mechanical properties. The dose at which ultimate mechanical properties decreased was at 200 kGy. TG-DTG measurements estimated decrease in thermal stability of gamma-irradiated NBR/CSM rubber blend based nanocomposites. Silica reinforced NBR/CSM rubber blend had better radiation resistant than carbon black. Rough and heterogeneity of fracture surfaces has been observed for NBR/CSM rubber blends filled with silica. More uniform morphology of fracture surfaces according to high polymer-filler interaction and low filler-filler interaction has been observed for CB/Si filled NBR/CSM rubber blend. CO 2011 Elsevier Ltd. All rights reserved.",
journal = "Composites: Part B: Engineering",
title = "Gamma irradiation aging of NBR/CSM rubber nanocomposites",
volume = "43",
number = "2",
pages = "609-615",
doi = "10.1016/j.compositesb.2011.11.056"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2012). Gamma irradiation aging of NBR/CSM rubber nanocomposites. in Composites: Part B: Engineering, 43(2), 609-615.
https://doi.org/10.1016/j.compositesb.2011.11.056

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. Gamma irradiation aging of NBR/CSM rubber nanocomposites. in Composites: Part B: Engineering. 2012;43(2):609-615.
doi:10.1016/j.compositesb.2011.11.056 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "Gamma irradiation aging of NBR/CSM rubber nanocomposites" in Composites: Part B: Engineering, 43, no. 2 (2012):609-615,
https://doi.org/10.1016/j.compositesb.2011.11.056 . .

TY  - JOUR
AU  - Cakić, Suzana M.
AU  - Ristić, Ivan S.
AU  - Marinović-Cincović, Milena
AU  - Nikolić, Nada Č.
AU  - Ilic, Olivera Z.
AU  - Stojiljković, Dragan T.
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4786
AB  - Soft drinks poly(ethylene terephthalate) (PET) bottles were depolymerized by glycolysis with different molar ratio of glycol, such as propylene glycol (PG), triethylene glycol (TEG) and poly(ethylene glycol) (PEG 400), in the presence of a zinc acetate catalyst. These glycolyzed products were characterized by hydroxyl value (HV) determinations. The obtained glycolyzed products were reacted with isophorone diisocyanate (IPDI), dimethylol propionic acid (DMPA), as potential ionic center for water dispersibility, and mixed with ethylene diamine (EDA) as extender chain to prepare polyurethane dispersions. The PET glycolyzed products and polyurethane formation were characterized using Fourier transform infrared spectroscopy (FTIR). The molecular masses distribution of oligoester polyol and polyurethane dispersions were determined by using gel permeation chromatography (G PC). The effect of different PET/glycol molar ratio, on the physico-mechanical properties, such as hardness, adhesion test and gloss of polyurethane films were investigated. Thermal properties were investigated by thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). It was observed that initial degradation temperatures were at about 200 degrees C, with two-or three degradation steps. The influence of different molar ratio PET/glycol on DTG curves showed stages that were not noticeable in the appropriate weight loss curves. Polyurethane dispersions which lower molar ratio of PET/glycol in glycolyzed products showed lower thermal stability due to the presence of a greater amount of aromaticity in polyester backbone led to materials with higher film hardness. The values for the film adherence and gloss were confirmed their excellent properties for potential application for coatings in civil engineering, metal or polymer industry. (C) 2011 Elsevier B.V. All rights reserved.
T2  - Progress in Organic Coatings
T1  - Glycolyzed products from PET waste and their application in synthesis of polyurethane dispersions
VL  - 74
IS  - 1
SP  - 115
EP  - 124
DO  - 10.1016/j.porgcoat.2011.11.024
ER  - 

@article{
author = "Cakić, Suzana M. and Ristić, Ivan S. and Marinović-Cincović, Milena and Nikolić, Nada Č. and Ilic, Olivera Z. and Stojiljković, Dragan T. and Budinski-Simendić, Jaroslava K.",
year = "2012",
abstract = "Soft drinks poly(ethylene terephthalate) (PET) bottles were depolymerized by glycolysis with different molar ratio of glycol, such as propylene glycol (PG), triethylene glycol (TEG) and poly(ethylene glycol) (PEG 400), in the presence of a zinc acetate catalyst. These glycolyzed products were characterized by hydroxyl value (HV) determinations. The obtained glycolyzed products were reacted with isophorone diisocyanate (IPDI), dimethylol propionic acid (DMPA), as potential ionic center for water dispersibility, and mixed with ethylene diamine (EDA) as extender chain to prepare polyurethane dispersions. The PET glycolyzed products and polyurethane formation were characterized using Fourier transform infrared spectroscopy (FTIR). The molecular masses distribution of oligoester polyol and polyurethane dispersions were determined by using gel permeation chromatography (G PC). The effect of different PET/glycol molar ratio, on the physico-mechanical properties, such as hardness, adhesion test and gloss of polyurethane films were investigated. Thermal properties were investigated by thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). It was observed that initial degradation temperatures were at about 200 degrees C, with two-or three degradation steps. The influence of different molar ratio PET/glycol on DTG curves showed stages that were not noticeable in the appropriate weight loss curves. Polyurethane dispersions which lower molar ratio of PET/glycol in glycolyzed products showed lower thermal stability due to the presence of a greater amount of aromaticity in polyester backbone led to materials with higher film hardness. The values for the film adherence and gloss were confirmed their excellent properties for potential application for coatings in civil engineering, metal or polymer industry. (C) 2011 Elsevier B.V. All rights reserved.",
journal = "Progress in Organic Coatings",
title = "Glycolyzed products from PET waste and their application in synthesis of polyurethane dispersions",
volume = "74",
number = "1",
pages = "115-124",
doi = "10.1016/j.porgcoat.2011.11.024"
}

Cakić, S. M., Ristić, I. S., Marinović-Cincović, M., Nikolić, N. Č., Ilic, O. Z., Stojiljković, D. T.,& Budinski-Simendić, J. K.. (2012). Glycolyzed products from PET waste and their application in synthesis of polyurethane dispersions. in Progress in Organic Coatings, 74(1), 115-124.
https://doi.org/10.1016/j.porgcoat.2011.11.024

Cakić SM, Ristić IS, Marinović-Cincović M, Nikolić NČ, Ilic OZ, Stojiljković DT, Budinski-Simendić JK. Glycolyzed products from PET waste and their application in synthesis of polyurethane dispersions. in Progress in Organic Coatings. 2012;74(1):115-124.
doi:10.1016/j.porgcoat.2011.11.024 .

Cakić, Suzana M., Ristić, Ivan S., Marinović-Cincović, Milena, Nikolić, Nada Č., Ilic, Olivera Z., Stojiljković, Dragan T., Budinski-Simendić, Jaroslava K., "Glycolyzed products from PET waste and their application in synthesis of polyurethane dispersions" in Progress in Organic Coatings, 74, no. 1 (2012):115-124,
https://doi.org/10.1016/j.porgcoat.2011.11.024 . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4905
AB  - The effects of different particle size of silica (nano-primary particle size 15 nm and micro-primary particle size 28 mu m) on the cure, mechanical, and swelling properties of hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blend were studied. The enhancement in mechanical properties was supported by the data on the increased content of cross-link density obtained from swelling and stress-strain analyses. The interactions between rubber matrix and filler were investigated by Fourier transform infrared spectroscopy with attenuated total reflectance extension and scanning electron microscope. T-g of reinforced blend shifted to 26 degrees C and 30 degrees C for nano and micro silica compounds, respectively.
T2  - Journal of Elastomers and Plastics
T1  - Hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blends reinforced by nano and micro silica
VL  - 44
IS  - 4
SP  - 335
EP  - 351
DO  - 10.1177/0095244311428895
ER  - 

@article{
author = "Marković, Gordana and Marinović-Cincović, Milena and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava K.",
year = "2012",
abstract = "The effects of different particle size of silica (nano-primary particle size 15 nm and micro-primary particle size 28 mu m) on the cure, mechanical, and swelling properties of hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blend were studied. The enhancement in mechanical properties was supported by the data on the increased content of cross-link density obtained from swelling and stress-strain analyses. The interactions between rubber matrix and filler were investigated by Fourier transform infrared spectroscopy with attenuated total reflectance extension and scanning electron microscope. T-g of reinforced blend shifted to 26 degrees C and 30 degrees C for nano and micro silica compounds, respectively.",
journal = "Journal of Elastomers and Plastics",
title = "Hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blends reinforced by nano and micro silica",
volume = "44",
number = "4",
pages = "335-351",
doi = "10.1177/0095244311428895"
}

Marković, G., Marinović-Cincović, M., Jovanović, V., Samaržija-Jovanović, S.,& Budinski-Simendić, J. K.. (2012). Hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blends reinforced by nano and micro silica. in Journal of Elastomers and Plastics, 44(4), 335-351.
https://doi.org/10.1177/0095244311428895

Marković G, Marinović-Cincović M, Jovanović V, Samaržija-Jovanović S, Budinski-Simendić JK. Hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blends reinforced by nano and micro silica. in Journal of Elastomers and Plastics. 2012;44(4):335-351.
doi:10.1177/0095244311428895 .

Marković, Gordana, Marinović-Cincović, Milena, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava K., "Hybrid materials based on brominated copolymer isobutylene isoprene/chlorosulfonated polyethylene rubber blends reinforced by nano and micro silica" in Journal of Elastomers and Plastics, 44, no. 4 (2012):335-351,
https://doi.org/10.1177/0095244311428895 . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Marinović-Cincović, Milena
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4570
AB  - In this paper, the curing and mechanical properties of two series of prepared blends, i.e., chlorosulphonated polyethylene (CSM)/isobutylene-co-isoprene (IIR) rubber blends and chlorosulphonated polyethylene (CSM)/chlorinated isobutylene-co-isoprene (CIIR) rubber blends were carried out. Blends were prepared using a two-roll mill at a temperature of 40-50 degrees C. The curing was assessed using a Monsanto oscillating disc rheometer R-100. The process of vulcanization accelerated sulfur of pure rubbers and their blends was carried out in an electrically heated laboratory hydraulic press under a pressure of about 4 MPa and 160 degrees C. The stress-strain experiments were performed using a tensile tester machine (Zwick 1425). Results indicate that the scorch time, t(s2), and optimum cure time, t(c90), increase with increasing CSM content in both blends. The value of modulus at 100 and 300% elongation and tensile strength increases with increasing CSM content, whereas elongation at break shows a decreasing trend The enhancement in mechanical properties was supported by data of crosslink density in these samples obtained from swelling measurement and scanning electron microscopy studies of the rubber blends fractured surfaces.
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Curing and Mechanical Properties of Chlorosulphonated Polyethylene Rubber Blends
VL  - 17
IS  - 3
SP  - 315
EP  - 321
DO  - 10.2298/CICEQ110315017M
ER  - 

@article{
author = "Marković, Gordana and Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Marinović-Cincović, Milena and Budinski-Simendić, Jaroslava K.",
year = "2011",
abstract = "In this paper, the curing and mechanical properties of two series of prepared blends, i.e., chlorosulphonated polyethylene (CSM)/isobutylene-co-isoprene (IIR) rubber blends and chlorosulphonated polyethylene (CSM)/chlorinated isobutylene-co-isoprene (CIIR) rubber blends were carried out. Blends were prepared using a two-roll mill at a temperature of 40-50 degrees C. The curing was assessed using a Monsanto oscillating disc rheometer R-100. The process of vulcanization accelerated sulfur of pure rubbers and their blends was carried out in an electrically heated laboratory hydraulic press under a pressure of about 4 MPa and 160 degrees C. The stress-strain experiments were performed using a tensile tester machine (Zwick 1425). Results indicate that the scorch time, t(s2), and optimum cure time, t(c90), increase with increasing CSM content in both blends. The value of modulus at 100 and 300% elongation and tensile strength increases with increasing CSM content, whereas elongation at break shows a decreasing trend The enhancement in mechanical properties was supported by data of crosslink density in these samples obtained from swelling measurement and scanning electron microscopy studies of the rubber blends fractured surfaces.",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Curing and Mechanical Properties of Chlorosulphonated Polyethylene Rubber Blends",
volume = "17",
number = "3",
pages = "315-321",
doi = "10.2298/CICEQ110315017M"
}

Marković, G., Jovanović, V., Samaržija-Jovanović, S., Marinović-Cincović, M.,& Budinski-Simendić, J. K.. (2011). Curing and Mechanical Properties of Chlorosulphonated Polyethylene Rubber Blends. in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 17(3), 315-321.
https://doi.org/10.2298/CICEQ110315017M

Marković G, Jovanović V, Samaržija-Jovanović S, Marinović-Cincović M, Budinski-Simendić JK. Curing and Mechanical Properties of Chlorosulphonated Polyethylene Rubber Blends. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2011;17(3):315-321.
doi:10.2298/CICEQ110315017M .

Marković, Gordana, Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Marinović-Cincović, Milena, Budinski-Simendić, Jaroslava K., "Curing and Mechanical Properties of Chlorosulphonated Polyethylene Rubber Blends" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 17, no. 3 (2011):315-321,
https://doi.org/10.2298/CICEQ110315017M . .

TY  - JOUR
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
AU  - Tanasic, Lj.
AU  - Jovanovic, V.
AU  - Samaržija-Jovanović, Suzana
AU  - Vukic, N.
AU  - Budinski-Simendić, Jaroslava K.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4602
AB  - The goal of this work was to study gamma irradiation ageing of rubber blends based on acrylonitrile butadiene rubber (NBR) and chlorosulphonated polyethylene rubber (CSM) reinforced by silica nano particles. The NBR/CSM compounds (50: 50, w/w) filled with different content of filler (0-100 phr) were crosslinked by sulfur. The vulcanization characteristics were assessed using the rheometer with an oscillating disk. The vulcanizates were prepared in a hydraulic press. The obtained materials were exposed to the different irradiation doses (100, 200, 300 and 400 kGy). The mechanical properties (hardness, modulus at 100% elongation, tensile strength and elongation at break) and swelling numbers were assessed before and after gamma irradiation ageing.
T2  - Russian Journal of Physical Chemistry A
T1  - The influence of nano silica particles on gamma-irradiation ageing of elastomers based on chlorosulphonated polyethylene and acrylonitrile butadiene rubber
VL  - 85
IS  - 13
SP  - 2410
EP  - 2415
DO  - 10.1134/S0036024411130139
ER  - 

@article{
author = "Marković, Gordana and Marinović-Cincović, Milena and Tanasic, Lj. and Jovanovic, V. and Samaržija-Jovanović, Suzana and Vukic, N. and Budinski-Simendić, Jaroslava K.",
year = "2011",
abstract = "The goal of this work was to study gamma irradiation ageing of rubber blends based on acrylonitrile butadiene rubber (NBR) and chlorosulphonated polyethylene rubber (CSM) reinforced by silica nano particles. The NBR/CSM compounds (50: 50, w/w) filled with different content of filler (0-100 phr) were crosslinked by sulfur. The vulcanization characteristics were assessed using the rheometer with an oscillating disk. The vulcanizates were prepared in a hydraulic press. The obtained materials were exposed to the different irradiation doses (100, 200, 300 and 400 kGy). The mechanical properties (hardness, modulus at 100% elongation, tensile strength and elongation at break) and swelling numbers were assessed before and after gamma irradiation ageing.",
journal = "Russian Journal of Physical Chemistry A",
title = "The influence of nano silica particles on gamma-irradiation ageing of elastomers based on chlorosulphonated polyethylene and acrylonitrile butadiene rubber",
volume = "85",
number = "13",
pages = "2410-2415",
doi = "10.1134/S0036024411130139"
}

Marković, G., Marinović-Cincović, M., Tanasic, Lj., Jovanovic, V., Samaržija-Jovanović, S., Vukic, N.,& Budinski-Simendić, J. K.. (2011). The influence of nano silica particles on gamma-irradiation ageing of elastomers based on chlorosulphonated polyethylene and acrylonitrile butadiene rubber. in Russian Journal of Physical Chemistry A, 85(13), 2410-2415.
https://doi.org/10.1134/S0036024411130139

Marković G, Marinović-Cincović M, Tanasic L, Jovanovic V, Samaržija-Jovanović S, Vukic N, Budinski-Simendić JK. The influence of nano silica particles on gamma-irradiation ageing of elastomers based on chlorosulphonated polyethylene and acrylonitrile butadiene rubber. in Russian Journal of Physical Chemistry A. 2011;85(13):2410-2415.
doi:10.1134/S0036024411130139 .

Marković, Gordana, Marinović-Cincović, Milena, Tanasic, Lj., Jovanovic, V., Samaržija-Jovanović, Suzana, Vukic, N., Budinski-Simendić, Jaroslava K., "The influence of nano silica particles on gamma-irradiation ageing of elastomers based on chlorosulphonated polyethylene and acrylonitrile butadiene rubber" in Russian Journal of Physical Chemistry A, 85, no. 13 (2011):2410-2415,
https://doi.org/10.1134/S0036024411130139 . .