Suljovrujić, Denis

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  • Suljovrujić, Denis (2)
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The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Mićić, Maja M.; Suljovrujić, Denis; Miličević, Dejan S.

(2019)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Rogić Miladinović, Zorana
AU  - Mićić, Maja M.
AU  - Suljovrujić, Denis
AU  - Miličević, Dejan S.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8048
AB  - The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd
T2  - Radiation Physics and Chemistry
T1  - The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT
VL  - 158
SP  - 37
EP  - 45
DO  - 10.1016/j.radphyschem.2018.12.034
ER  - 
@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Mićić, Maja M. and Suljovrujić, Denis and Miličević, Dejan S.",
year = "2019",
abstract = "The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT",
volume = "158",
pages = "37-45",
doi = "10.1016/j.radphyschem.2018.12.034"
}
Suljovrujić, E. H., Rogić Miladinović, Z., Mićić, M. M., Suljovrujić, D.,& Miličević, D. S.. (2019). The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry, 158, 37-45.
https://doi.org/10.1016/j.radphyschem.2018.12.034
Suljovrujić EH, Rogić Miladinović Z, Mićić MM, Suljovrujić D, Miličević DS. The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry. 2019;158:37-45.
doi:10.1016/j.radphyschem.2018.12.034 .
Suljovrujić, Edin H., Rogić Miladinović, Zorana, Mićić, Maja M., Suljovrujić, Denis, Miličević, Dejan S., "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT" in Radiation Physics and Chemistry, 158 (2019):37-45,
https://doi.org/10.1016/j.radphyschem.2018.12.034 . .
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8
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The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Mićić, Maja M.; Suljovrujić, Denis; Miličević, Dejan S.

(2019)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Rogić Miladinović, Zorana
AU  - Mićić, Maja M.
AU  - Suljovrujić, Denis
AU  - Miličević, Dejan S.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8051
AB  - The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd
T2  - Radiation Physics and Chemistry
T1  - The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT
VL  - 158
SP  - 37
EP  - 45
DO  - 10.1016/j.radphyschem.2018.12.034
ER  - 
@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Mićić, Maja M. and Suljovrujić, Denis and Miličević, Dejan S.",
year = "2019",
abstract = "The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT",
volume = "158",
pages = "37-45",
doi = "10.1016/j.radphyschem.2018.12.034"
}
Suljovrujić, E. H., Rogić Miladinović, Z., Mićić, M. M., Suljovrujić, D.,& Miličević, D. S.. (2019). The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry, 158, 37-45.
https://doi.org/10.1016/j.radphyschem.2018.12.034
Suljovrujić EH, Rogić Miladinović Z, Mićić MM, Suljovrujić D, Miličević DS. The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry. 2019;158:37-45.
doi:10.1016/j.radphyschem.2018.12.034 .
Suljovrujić, Edin H., Rogić Miladinović, Zorana, Mićić, Maja M., Suljovrujić, Denis, Miličević, Dejan S., "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT" in Radiation Physics and Chemistry, 158 (2019):37-45,
https://doi.org/10.1016/j.radphyschem.2018.12.034 . .
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8
12