TY  - JOUR
AU  - Petrović, Jelena
AU  - Ranković, Dragan
AU  - Kuzmanović, Miroslav M.
AU  - Savović, Jelena
AU  - Kiris, Vasili
AU  - Nevar, Alena
AU  - Nedelko, Mikhail
AU  - Tarasenko, Nikolai
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10658
AB  - Time-integrated optical emission analysis of laser-induced plasma on Teflon is presented. Plasma was induced under atmospheric pressure air using transversely excited atmospheric CO2 laser pulses. Teflon is a C-based polymer that is, among other things, interesting as a substrate for laser-induced breakdown spectroscopy analysis of liquid samples. This study aimed to determine the optimal experimental conditions for obtaining neutral and ionized C spectral lines and C2 and CN molecular band emission suitable for spectrochemical purposes. Evaluation of plasma parameters was done using several spectroscopic techniques. Stark profiles of appropriate C ionic lines were used to determine electron number density. The ratio of the integral intensity of ionic-to-atomic C spectral lines was used to determine the ionization temperature. A spectral emission of C2 Swan and CN violet bands system was used to determine the temperature of the colder, peripheral parts of plasma. We critically analyzed the use of molecular emission bands as a tool for plasma diagnostics and suggested methods for possible improvements.
T2  - Plasma Science and Technology
T1  - Diagnostics of laser-induced plasma on carbon-based polymer material using atomic and molecular emission spectra
VL  - 25
IS  - 4
SP  - 045507
DO  - 10.1088/2058-6272/aca30f
ER  - 

@article{
author = "Petrović, Jelena and Ranković, Dragan and Kuzmanović, Miroslav M. and Savović, Jelena and Kiris, Vasili and Nevar, Alena and Nedelko, Mikhail and Tarasenko, Nikolai",
year = "2023",
abstract = "Time-integrated optical emission analysis of laser-induced plasma on Teflon is presented. Plasma was induced under atmospheric pressure air using transversely excited atmospheric CO2 laser pulses. Teflon is a C-based polymer that is, among other things, interesting as a substrate for laser-induced breakdown spectroscopy analysis of liquid samples. This study aimed to determine the optimal experimental conditions for obtaining neutral and ionized C spectral lines and C2 and CN molecular band emission suitable for spectrochemical purposes. Evaluation of plasma parameters was done using several spectroscopic techniques. Stark profiles of appropriate C ionic lines were used to determine electron number density. The ratio of the integral intensity of ionic-to-atomic C spectral lines was used to determine the ionization temperature. A spectral emission of C2 Swan and CN violet bands system was used to determine the temperature of the colder, peripheral parts of plasma. We critically analyzed the use of molecular emission bands as a tool for plasma diagnostics and suggested methods for possible improvements.",
journal = "Plasma Science and Technology",
title = "Diagnostics of laser-induced plasma on carbon-based polymer material using atomic and molecular emission spectra",
volume = "25",
number = "4",
pages = "045507",
doi = "10.1088/2058-6272/aca30f"
}

Petrović, J., Ranković, D., Kuzmanović, M. M., Savović, J., Kiris, V., Nevar, A., Nedelko, M.,& Tarasenko, N.. (2023). Diagnostics of laser-induced plasma on carbon-based polymer material using atomic and molecular emission spectra. in Plasma Science and Technology, 25(4), 045507.
https://doi.org/10.1088/2058-6272/aca30f

Petrović J, Ranković D, Kuzmanović MM, Savović J, Kiris V, Nevar A, Nedelko M, Tarasenko N. Diagnostics of laser-induced plasma on carbon-based polymer material using atomic and molecular emission spectra. in Plasma Science and Technology. 2023;25(4):045507.
doi:10.1088/2058-6272/aca30f .

Petrović, Jelena, Ranković, Dragan, Kuzmanović, Miroslav M., Savović, Jelena, Kiris, Vasili, Nevar, Alena, Nedelko, Mikhail, Tarasenko, Nikolai, "Diagnostics of laser-induced plasma on carbon-based polymer material using atomic and molecular emission spectra" in Plasma Science and Technology, 25, no. 4 (2023):045507,
https://doi.org/10.1088/2058-6272/aca30f . .

TY  - JOUR
AU  - Kiris, Vasili
AU  - Savović, Jelena
AU  - Nevar, Alena
AU  - Kuzmanović, Miroslav M.
AU  - Nedelko, Mikhail
AU  - Ranković, Dragan
AU  - Tarasenko, Nikolai
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10059
AB  - The analytical potential of LIBS for the analysis of liquid solutions was evaluated using two experimental setups, one based on a TEA CO2 laser and the other in which Nd:YAG laser was used. Polytetrafluoroethylene (PTFE) was used as a substrate on which a 10 μL drop of analyte solutions with different concentrations of analyte elements, Be, Cr, Ni, Co, Pb, Tl, and V, were deposited and dried. The samples were deposited either directly on the PTFE or over the pre-deposited layer of copper oxide nanoparticles to study the influence of nanoparticles (NPs) on the ablation and plasma excitation. The obtained results imply that the presence of Cu oxide NPs does not significantly affect the analytical performance of LIBS based on TEA CO2 laser for analysis of solutions. At the same time, it was shown that plasma created by TEA CO2 laser radiation efficiently excited ablated material, making metal elements detectable in the sub-ppm concentration range. On the other hand, Cu oxide NPs significantly influence the formation and the analytical properties of plasma induced by Nd:YAG laser. Without the presence of NPs, the intensities of analyte lines were very low, unsuitable for spectrochemical analysis. At the optimal surface concentration of NPs, 0.36 mg/cm2, the intensity of analyte lines was increased more than ten times. Limits of detection of Be and Cr were 5.3 ppb and 33 ppb, with good linearity of curves of growth.
T2  - Spectrochimica Acta. Part B: Atomic Spectroscopy
T1  - Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect
VL  - 187
SP  - 106333
DO  - 10.1016/j.sab.2021.106333
ER  - 

@article{
author = "Kiris, Vasili and Savović, Jelena and Nevar, Alena and Kuzmanović, Miroslav M. and Nedelko, Mikhail and Ranković, Dragan and Tarasenko, Nikolai",
year = "2022",
abstract = "The analytical potential of LIBS for the analysis of liquid solutions was evaluated using two experimental setups, one based on a TEA CO2 laser and the other in which Nd:YAG laser was used. Polytetrafluoroethylene (PTFE) was used as a substrate on which a 10 μL drop of analyte solutions with different concentrations of analyte elements, Be, Cr, Ni, Co, Pb, Tl, and V, were deposited and dried. The samples were deposited either directly on the PTFE or over the pre-deposited layer of copper oxide nanoparticles to study the influence of nanoparticles (NPs) on the ablation and plasma excitation. The obtained results imply that the presence of Cu oxide NPs does not significantly affect the analytical performance of LIBS based on TEA CO2 laser for analysis of solutions. At the same time, it was shown that plasma created by TEA CO2 laser radiation efficiently excited ablated material, making metal elements detectable in the sub-ppm concentration range. On the other hand, Cu oxide NPs significantly influence the formation and the analytical properties of plasma induced by Nd:YAG laser. Without the presence of NPs, the intensities of analyte lines were very low, unsuitable for spectrochemical analysis. At the optimal surface concentration of NPs, 0.36 mg/cm2, the intensity of analyte lines was increased more than ten times. Limits of detection of Be and Cr were 5.3 ppb and 33 ppb, with good linearity of curves of growth.",
journal = "Spectrochimica Acta. Part B: Atomic Spectroscopy",
title = "Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect",
volume = "187",
pages = "106333",
doi = "10.1016/j.sab.2021.106333"
}

Kiris, V., Savović, J., Nevar, A., Kuzmanović, M. M., Nedelko, M., Ranković, D.,& Tarasenko, N.. (2022). Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect. in Spectrochimica Acta. Part B: Atomic Spectroscopy, 187, 106333.
https://doi.org/10.1016/j.sab.2021.106333

Kiris V, Savović J, Nevar A, Kuzmanović MM, Nedelko M, Ranković D, Tarasenko N. Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect. in Spectrochimica Acta. Part B: Atomic Spectroscopy. 2022;187:106333.
doi:10.1016/j.sab.2021.106333 .

Kiris, Vasili, Savović, Jelena, Nevar, Alena, Kuzmanović, Miroslav M., Nedelko, Mikhail, Ranković, Dragan, Tarasenko, Nikolai, "Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect" in Spectrochimica Acta. Part B: Atomic Spectroscopy, 187 (2022):106333,
https://doi.org/10.1016/j.sab.2021.106333 . .