Nikolić, Nebojša D.

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f0f51786-47f8-48b6-a206-05850558d035
  • Nikolić, Nebojša D. (8)
  • Nikolić, Nebojša (2)
Projects

Author's Bibliography

Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells

Stevanović, Sanja; Milošević, Dragana; Tripković, Dušan; Ćosović, Vladan; Nikolić, Nebojša; Maksimović, Vesna

(Society of Chemists and Technologists of Macedonia, 2023)

TY  - CONF
AU  - Stevanović, Sanja
AU  - Milošević, Dragana
AU  - Tripković, Dušan
AU  - Ćosović, Vladan
AU  - Nikolić, Nebojša
AU  - Maksimović, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11758
AB  - In order to achieve widespread application of fuel cell technology, the development of an efficient and economical catalyst is a crucial step. Reducing the diameter of catalyst particles, producing particles with a specific orientation surface, and alloying noble metals with less expensive metals are possible approaches to improve catalyst performance. This study will be focused on novel ways for creating PtSnZn catalysts that are more effective for the anodic reactions in fuel cell such are methanol, ethanol and formic acid oxidation reactions. PtZn and PtSnZn nanoparticles were produced using the microwave assisted polyol method and were supported on high surface area carbon Vulcan XC-72R material. The electrochemical behavior of synthesized catalysts was investigated utilizing the cyclic voltammetry, chronoamperometric technique, and electro-oxidation of adsorbed CO. To determine the catalyst's physicochemical characteristics, X-ray diffraction (XRD), transmission electron microscopy analysis (TEM), and thermogravimetric analysis (TGA) were used. High catalytic activity of the PtSnZn/C catalysts was achieved thanks to the benefits of microwave synthesis and carefully adjusted metal alloying.
PB  - Society of Chemists and Technologists of Macedonia
C3  - 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia
T1  - Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells
SP  - 132
EP  - 132
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11758
ER  - 
@conference{
author = "Stevanović, Sanja and Milošević, Dragana and Tripković, Dušan and Ćosović, Vladan and Nikolić, Nebojša and Maksimović, Vesna",
year = "2023",
abstract = "In order to achieve widespread application of fuel cell technology, the development of an efficient and economical catalyst is a crucial step. Reducing the diameter of catalyst particles, producing particles with a specific orientation surface, and alloying noble metals with less expensive metals are possible approaches to improve catalyst performance. This study will be focused on novel ways for creating PtSnZn catalysts that are more effective for the anodic reactions in fuel cell such are methanol, ethanol and formic acid oxidation reactions. PtZn and PtSnZn nanoparticles were produced using the microwave assisted polyol method and were supported on high surface area carbon Vulcan XC-72R material. The electrochemical behavior of synthesized catalysts was investigated utilizing the cyclic voltammetry, chronoamperometric technique, and electro-oxidation of adsorbed CO. To determine the catalyst's physicochemical characteristics, X-ray diffraction (XRD), transmission electron microscopy analysis (TEM), and thermogravimetric analysis (TGA) were used. High catalytic activity of the PtSnZn/C catalysts was achieved thanks to the benefits of microwave synthesis and carefully adjusted metal alloying.",
publisher = "Society of Chemists and Technologists of Macedonia",
journal = "26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia",
title = "Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells",
pages = "132-132",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11758"
}
Stevanović, S., Milošević, D., Tripković, D., Ćosović, V., Nikolić, N.,& Maksimović, V.. (2023). Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells. in 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia
Society of Chemists and Technologists of Macedonia., 132-132.
https://hdl.handle.net/21.15107/rcub_vinar_11758
Stevanović S, Milošević D, Tripković D, Ćosović V, Nikolić N, Maksimović V. Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells. in 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia. 2023;:132-132.
https://hdl.handle.net/21.15107/rcub_vinar_11758 .
Stevanović, Sanja, Milošević, Dragana, Tripković, Dušan, Ćosović, Vladan, Nikolić, Nebojša, Maksimović, Vesna, "Design of PtSnZn Nanocatalysts for Anodic Reactions in Fuel Cells" in 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia (2023):132-132,
https://hdl.handle.net/21.15107/rcub_vinar_11758 .

Monte Carlo dozimetrija u brahiterapiji kancera cerviksa

Krstić, Dragana Ž.; Ilić, Radovan; Jovanović, Aleksandra; Nikezić, Dragoslav; Jeremić, Marija; Nikolić, Nebojša; Mihajlović, Jasmina

(Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе, 2019)

TY  - CONF
AU  - Krstić, Dragana Ž.
AU  - Ilić, Radovan
AU  - Jovanović, Aleksandra
AU  - Nikezić, Dragoslav
AU  - Jeremić, Marija
AU  - Nikolić, Nebojša
AU  - Mihajlović, Jasmina
PY  - 2019
UR  - https://plus.sr.cobiss.net/opac7/bib/279687436
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8719
AB  - U radu je prikazano poređenje apsorbovanih doza u brahiterapijskim planovima i Monte Karlo simulacijama u brahiterapiji pacijentkinja sa karcinomom grlića materice. U Odeljenju za brahiterapiju u Kliničkom centru Kragujevac primenjuje se mikroSelektron za intrakavitarnu brahiterapiju u HDR režimu. Ovaj uređaj koristi minijaturni radioaktivni izvor 192Ir u obliku cilindra, aktivnih dimenzija 0,6 mm × 3,5 mm, i visoke početne aktivnosti od 370 GBq.Pre terapije, vrši se kompjutersko planiranje, koje predstavlja kompjutersku rekonstruk-ciju položaja vodiča izvora u pacijentu na osnovu dva radiografska snimka, i izodozno planiranje u odnosu na željene dozimetrijske tačke. Osnovni podaci planiranja su dnevna doza, koja iznosi 700 cGy i broj frakcija; dnevna doza se isporučuje se u tri frakcije jednom nedeljno. Monte Karlo simulacije su obavljene korišćenjem MCNP6 softvera verzije 2.0 kako bi se procenila raspodela doze u materici i kritičnim organima od rizika (bešika i debelo crevo). MCNP F6 tally (MeV/g) je izabran zbog lakog konvertovanja deponovane energije u apsorbovanu dozu. Za pripremu ulaznih datoteka koje simuliraju brahi-terapiju korišćeni su matematički ORNL i voksel fantomi. Upoređivanjem izmerenih i izračunatih vrednosti može se videti da su Monte Carlo tehnike moćno sredstvo za primenu u planiranju brahiterapije.
AB  - This paper presents the comparison of absorbed doses in brachytherapy plans and Monte Carlo simulation for brachytherapy treatment of a female patient with cervix carcinoma. At the Department of Brachytherapy at the Clinical Center Kragujevac, the microSelectron after loading deviceis used for intracavitary brachytherapy in the HDR regime. This device uses a miniature radioactive source 192Ir in the form of a cylinder, active dimensions of 0.6 mm × 3.5 mm, and a high initial activity of about 370 GBq. Before therapy, computer planning is performed, which represents a computer reconstruction of the position of the source guide in the patient based on two radiographic images, and isodose planning in relation to the desired dosimetry points. Essential planning data are the daily dose and number of fractions. In this case, the daily dose is 700 cGy and is delivered in three fractions once a week. This means that the duration of this brachytherapy treatment will be a total of three weeks. Monte Carlo simulations by using MCNP6 code version 2.0 were applied for brachytherapy treatment to estimate the dose distribution in uterus and several critical organs at risk (bladder and colon). The MCNP tally f6 (MeV/g) was chosen due to easy convert energy deposition toabsorbed dose. The computational ORNL and voxel phantoms were used to prepare input files which simulate brachytherapy.By comparing measured and calculated values, it can be seen that Monte Carlo techniques are a powerful tool for application in brachytherapy planning.
PB  - Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе
C3  - 30. симпозијум ДЗЗСЦГ : зборник радова
T1  - Monte Carlo dozimetrija u brahiterapiji kancera cerviksa
T1  - Monte Carlo dosimetry for brachytherapy of cervical cancer
SP  - 483
EP  - 488
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8719
ER  - 
@conference{
author = "Krstić, Dragana Ž. and Ilić, Radovan and Jovanović, Aleksandra and Nikezić, Dragoslav and Jeremić, Marija and Nikolić, Nebojša and Mihajlović, Jasmina",
year = "2019",
abstract = "U radu je prikazano poređenje apsorbovanih doza u brahiterapijskim planovima i Monte Karlo simulacijama u brahiterapiji pacijentkinja sa karcinomom grlića materice. U Odeljenju za brahiterapiju u Kliničkom centru Kragujevac primenjuje se mikroSelektron za intrakavitarnu brahiterapiju u HDR režimu. Ovaj uređaj koristi minijaturni radioaktivni izvor 192Ir u obliku cilindra, aktivnih dimenzija 0,6 mm × 3,5 mm, i visoke početne aktivnosti od 370 GBq.Pre terapije, vrši se kompjutersko planiranje, koje predstavlja kompjutersku rekonstruk-ciju položaja vodiča izvora u pacijentu na osnovu dva radiografska snimka, i izodozno planiranje u odnosu na željene dozimetrijske tačke. Osnovni podaci planiranja su dnevna doza, koja iznosi 700 cGy i broj frakcija; dnevna doza se isporučuje se u tri frakcije jednom nedeljno. Monte Karlo simulacije su obavljene korišćenjem MCNP6 softvera verzije 2.0 kako bi se procenila raspodela doze u materici i kritičnim organima od rizika (bešika i debelo crevo). MCNP F6 tally (MeV/g) je izabran zbog lakog konvertovanja deponovane energije u apsorbovanu dozu. Za pripremu ulaznih datoteka koje simuliraju brahi-terapiju korišćeni su matematički ORNL i voksel fantomi. Upoređivanjem izmerenih i izračunatih vrednosti može se videti da su Monte Carlo tehnike moćno sredstvo za primenu u planiranju brahiterapije., This paper presents the comparison of absorbed doses in brachytherapy plans and Monte Carlo simulation for brachytherapy treatment of a female patient with cervix carcinoma. At the Department of Brachytherapy at the Clinical Center Kragujevac, the microSelectron after loading deviceis used for intracavitary brachytherapy in the HDR regime. This device uses a miniature radioactive source 192Ir in the form of a cylinder, active dimensions of 0.6 mm × 3.5 mm, and a high initial activity of about 370 GBq. Before therapy, computer planning is performed, which represents a computer reconstruction of the position of the source guide in the patient based on two radiographic images, and isodose planning in relation to the desired dosimetry points. Essential planning data are the daily dose and number of fractions. In this case, the daily dose is 700 cGy and is delivered in three fractions once a week. This means that the duration of this brachytherapy treatment will be a total of three weeks. Monte Carlo simulations by using MCNP6 code version 2.0 were applied for brachytherapy treatment to estimate the dose distribution in uterus and several critical organs at risk (bladder and colon). The MCNP tally f6 (MeV/g) was chosen due to easy convert energy deposition toabsorbed dose. The computational ORNL and voxel phantoms were used to prepare input files which simulate brachytherapy.By comparing measured and calculated values, it can be seen that Monte Carlo techniques are a powerful tool for application in brachytherapy planning.",
publisher = "Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе",
journal = "30. симпозијум ДЗЗСЦГ : зборник радова",
title = "Monte Carlo dozimetrija u brahiterapiji kancera cerviksa, Monte Carlo dosimetry for brachytherapy of cervical cancer",
pages = "483-488",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8719"
}
Krstić, D. Ž., Ilić, R., Jovanović, A., Nikezić, D., Jeremić, M., Nikolić, N.,& Mihajlović, J.. (2019). Monte Carlo dozimetrija u brahiterapiji kancera cerviksa. in 30. симпозијум ДЗЗСЦГ : зборник радова
Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе., 483-488.
https://hdl.handle.net/21.15107/rcub_vinar_8719
Krstić DŽ, Ilić R, Jovanović A, Nikezić D, Jeremić M, Nikolić N, Mihajlović J. Monte Carlo dozimetrija u brahiterapiji kancera cerviksa. in 30. симпозијум ДЗЗСЦГ : зборник радова. 2019;:483-488.
https://hdl.handle.net/21.15107/rcub_vinar_8719 .
Krstić, Dragana Ž., Ilić, Radovan, Jovanović, Aleksandra, Nikezić, Dragoslav, Jeremić, Marija, Nikolić, Nebojša, Mihajlović, Jasmina, "Monte Carlo dozimetrija u brahiterapiji kancera cerviksa" in 30. симпозијум ДЗЗСЦГ : зборник радова (2019):483-488,
https://hdl.handle.net/21.15107/rcub_vinar_8719 .

Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles

Avramović, Ljiljana; Pavlović, Miroslav M.; Maksimović, Vesna; Vuković, Marina; Stevanović, Jasmina S.; Bugarin, Mile; Nikolić, Nebojša D.

(2017)

TY  - JOUR
AU  - Avramović, Ljiljana
AU  - Pavlović, Miroslav M.
AU  - Maksimović, Vesna
AU  - Vuković, Marina
AU  - Stevanović, Jasmina S.
AU  - Bugarin, Mile
AU  - Nikolić, Nebojša D.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1612
AB  - Silver powders chemically synthesized by reduction with hydrazine and those produced by electrolysis from the basic ( nitrate) and complex ( ammonium) electrolytes were examined by X-ray diffraction (XRD) and scanning electron microscopic (SEM) analysis of the produced particles. Morphologies of the obtained particles were very different at the macro level. The needle-like dendrites, as well as the mixture of irregular and regular crystals, were formed from the nitrate electrolyte, while the highly-branched pine-like dendrites with clearly noticeable spherical grains were formed from the ammonium electrolyte. The agglomerates of spherical grains were formed by reduction with hydrazine. In the particles obtained from the nitrate electrolyte, Ag crystallites were strongly oriented in the (111) plane. Although morphologies of Ag particles were very different at the macro level, the similarity at the micro level was observed between chemically-synthesized particles and those obtained by electrolysis from the ammonium electrolyte. Both types of particles were constructed from the spherical grains. This similarity at the micro level was accompanied by the similar XRD patterns, which were very close to the Ag standard with a random orientation of Ag crystallites. For the first time, morphologies of powder particles were correlated with their crystal structure.
T2  - Metals
T1  - Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles
VL  - 7
IS  - 5
DO  - 10.3390/met7050160
ER  - 
@article{
author = "Avramović, Ljiljana and Pavlović, Miroslav M. and Maksimović, Vesna and Vuković, Marina and Stevanović, Jasmina S. and Bugarin, Mile and Nikolić, Nebojša D.",
year = "2017",
abstract = "Silver powders chemically synthesized by reduction with hydrazine and those produced by electrolysis from the basic ( nitrate) and complex ( ammonium) electrolytes were examined by X-ray diffraction (XRD) and scanning electron microscopic (SEM) analysis of the produced particles. Morphologies of the obtained particles were very different at the macro level. The needle-like dendrites, as well as the mixture of irregular and regular crystals, were formed from the nitrate electrolyte, while the highly-branched pine-like dendrites with clearly noticeable spherical grains were formed from the ammonium electrolyte. The agglomerates of spherical grains were formed by reduction with hydrazine. In the particles obtained from the nitrate electrolyte, Ag crystallites were strongly oriented in the (111) plane. Although morphologies of Ag particles were very different at the macro level, the similarity at the micro level was observed between chemically-synthesized particles and those obtained by electrolysis from the ammonium electrolyte. Both types of particles were constructed from the spherical grains. This similarity at the micro level was accompanied by the similar XRD patterns, which were very close to the Ag standard with a random orientation of Ag crystallites. For the first time, morphologies of powder particles were correlated with their crystal structure.",
journal = "Metals",
title = "Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles",
volume = "7",
number = "5",
doi = "10.3390/met7050160"
}
Avramović, L., Pavlović, M. M., Maksimović, V., Vuković, M., Stevanović, J. S., Bugarin, M.,& Nikolić, N. D.. (2017). Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles. in Metals, 7(5).
https://doi.org/10.3390/met7050160
Avramović L, Pavlović MM, Maksimović V, Vuković M, Stevanović JS, Bugarin M, Nikolić ND. Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles. in Metals. 2017;7(5).
doi:10.3390/met7050160 .
Avramović, Ljiljana, Pavlović, Miroslav M., Maksimović, Vesna, Vuković, Marina, Stevanović, Jasmina S., Bugarin, Mile, Nikolić, Nebojša D., "Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles" in Metals, 7, no. 5 (2017),
https://doi.org/10.3390/met7050160 . .
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Correlation between morphology and magnetic properties of electrochemically produced cobalt powder particles

Maksimović, Vesna; Nikolić, Nebojša D.; Kusigerski, Vladan; Blanuša, Jovan

(2015)

TY  - JOUR
AU  - Maksimović, Vesna
AU  - Nikolić, Nebojša D.
AU  - Kusigerski, Vladan
AU  - Blanuša, Jovan
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/453
AB  - Cobalt 3D powder particles were successfully prepared by galvanostatic electrodeposition. The electrodeposited cobalt powders were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and SQUID magnetometry. It was shown that the morphology, structure and magnetic properties of cobalt particles were closely associated and could be easily controlled by adjusting the electrodeposition process parameters. The morphology of cobalt powder particles was strongly affected by the hydrogen evolution reaction as a parallel reaction to cobalt electrodeposition. Depending on the applied current density, two types of powder particles were formed: dendrites at lower and spongy-like particles at higher current densities. Morphologies and structures of powder particles were correlated with their magnetic properties, and compared with those of the bulk cobalt. In comparison with the properties of bulk cobalt, the obtained 3D structutes exhibited a decreased saturation magnetization (M-S), but an enhanced coercivity (H-C), which was explained by their peculiar morphology.
T2  - Journal of the Serbian Chemical Society
T1  - Correlation between morphology and magnetic properties of electrochemically produced cobalt powder particles
VL  - 80
IS  - 2
SP  - 197
EP  - 207
DO  - 10.2298/JSC200814104M
ER  - 
@article{
author = "Maksimović, Vesna and Nikolić, Nebojša D. and Kusigerski, Vladan and Blanuša, Jovan",
year = "2015",
abstract = "Cobalt 3D powder particles were successfully prepared by galvanostatic electrodeposition. The electrodeposited cobalt powders were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and SQUID magnetometry. It was shown that the morphology, structure and magnetic properties of cobalt particles were closely associated and could be easily controlled by adjusting the electrodeposition process parameters. The morphology of cobalt powder particles was strongly affected by the hydrogen evolution reaction as a parallel reaction to cobalt electrodeposition. Depending on the applied current density, two types of powder particles were formed: dendrites at lower and spongy-like particles at higher current densities. Morphologies and structures of powder particles were correlated with their magnetic properties, and compared with those of the bulk cobalt. In comparison with the properties of bulk cobalt, the obtained 3D structutes exhibited a decreased saturation magnetization (M-S), but an enhanced coercivity (H-C), which was explained by their peculiar morphology.",
journal = "Journal of the Serbian Chemical Society",
title = "Correlation between morphology and magnetic properties of electrochemically produced cobalt powder particles",
volume = "80",
number = "2",
pages = "197-207",
doi = "10.2298/JSC200814104M"
}
Maksimović, V., Nikolić, N. D., Kusigerski, V.,& Blanuša, J.. (2015). Correlation between morphology and magnetic properties of electrochemically produced cobalt powder particles. in Journal of the Serbian Chemical Society, 80(2), 197-207.
https://doi.org/10.2298/JSC200814104M
Maksimović V, Nikolić ND, Kusigerski V, Blanuša J. Correlation between morphology and magnetic properties of electrochemically produced cobalt powder particles. in Journal of the Serbian Chemical Society. 2015;80(2):197-207.
doi:10.2298/JSC200814104M .
Maksimović, Vesna, Nikolić, Nebojša D., Kusigerski, Vladan, Blanuša, Jovan, "Correlation between morphology and magnetic properties of electrochemically produced cobalt powder particles" in Journal of the Serbian Chemical Society, 80, no. 2 (2015):197-207,
https://doi.org/10.2298/JSC200814104M . .
1
14
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Morphological and crystallographic characteristics of lead powder obtained by electrodeposition from an environmentally friendly electrolyte

Nikolić, Nebojša D.; Vastag, Djendji Dj.; Maksimović, Vesna; Branković, Goran O.

(2014)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Vastag, Djendji Dj.
AU  - Maksimović, Vesna
AU  - Branković, Goran O.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6093
AB  - Lead powder obtained by potentiostatic electrodeposition from alkaline electrolyte, based on hydroxide ions, was investigated. The shape of lead crystals strongly depends on overpotentials of electrodeposition. The regular crystals are formed in the ohmic control. The shape of dendrites formed in the control of diffusion has a function of overpotentials of the electrodeposition. Increasing overpotential leads to branching of dendrites from primary type to those with developed tertiary branches. Formation of the very branchy dendrites of the strong (111) preferred orientation is explained on the basis of the affiliation of this electrolyte to the group of the complex Pb electrolytes.
T2  - Transactions of Nonferrous Metals Society of China
T1  - Morphological and crystallographic characteristics of lead powder obtained by electrodeposition from an environmentally friendly electrolyte
VL  - 24
IS  - 3
SP  - 884
EP  - 892
DO  - 10.1016/S1003-6326(14)63139-3
ER  - 
@article{
author = "Nikolić, Nebojša D. and Vastag, Djendji Dj. and Maksimović, Vesna and Branković, Goran O.",
year = "2014",
abstract = "Lead powder obtained by potentiostatic electrodeposition from alkaline electrolyte, based on hydroxide ions, was investigated. The shape of lead crystals strongly depends on overpotentials of electrodeposition. The regular crystals are formed in the ohmic control. The shape of dendrites formed in the control of diffusion has a function of overpotentials of the electrodeposition. Increasing overpotential leads to branching of dendrites from primary type to those with developed tertiary branches. Formation of the very branchy dendrites of the strong (111) preferred orientation is explained on the basis of the affiliation of this electrolyte to the group of the complex Pb electrolytes.",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Morphological and crystallographic characteristics of lead powder obtained by electrodeposition from an environmentally friendly electrolyte",
volume = "24",
number = "3",
pages = "884-892",
doi = "10.1016/S1003-6326(14)63139-3"
}
Nikolić, N. D., Vastag, D. Dj., Maksimović, V.,& Branković, G. O.. (2014). Morphological and crystallographic characteristics of lead powder obtained by electrodeposition from an environmentally friendly electrolyte. in Transactions of Nonferrous Metals Society of China, 24(3), 884-892.
https://doi.org/10.1016/S1003-6326(14)63139-3
Nikolić ND, Vastag DD, Maksimović V, Branković GO. Morphological and crystallographic characteristics of lead powder obtained by electrodeposition from an environmentally friendly electrolyte. in Transactions of Nonferrous Metals Society of China. 2014;24(3):884-892.
doi:10.1016/S1003-6326(14)63139-3 .
Nikolić, Nebojša D., Vastag, Djendji Dj., Maksimović, Vesna, Branković, Goran O., "Morphological and crystallographic characteristics of lead powder obtained by electrodeposition from an environmentally friendly electrolyte" in Transactions of Nonferrous Metals Society of China, 24, no. 3 (2014):884-892,
https://doi.org/10.1016/S1003-6326(14)63139-3 . .
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Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles

Nikolić, Nebojša D.; Maksimović, Vesna; Branković, Goran O.; Živković, Predrag M.; Pavlović, Miomir G.

(2013)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna
AU  - Branković, Goran O.
AU  - Živković, Predrag M.
AU  - Pavlović, Miomir G.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5732
AB  - Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.
T2  - Journal of the Serbian Chemical Society
T1  - Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles
VL  - 78
IS  - 9
SP  - 1387
EP  - 1395
DO  - 10.2298/JSC130211034N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Maksimović, Vesna and Branković, Goran O. and Živković, Predrag M. and Pavlović, Miomir G.",
year = "2013",
abstract = "Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.",
journal = "Journal of the Serbian Chemical Society",
title = "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles",
volume = "78",
number = "9",
pages = "1387-1395",
doi = "10.2298/JSC130211034N"
}
Nikolić, N. D., Maksimović, V., Branković, G. O., Živković, P. M.,& Pavlović, M. G.. (2013). Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society, 78(9), 1387-1395.
https://doi.org/10.2298/JSC130211034N
Nikolić ND, Maksimović V, Branković GO, Živković PM, Pavlović MG. Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society. 2013;78(9):1387-1395.
doi:10.2298/JSC130211034N .
Nikolić, Nebojša D., Maksimović, Vesna, Branković, Goran O., Živković, Predrag M., Pavlović, Miomir G., "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles" in Journal of the Serbian Chemical Society, 78, no. 9 (2013):1387-1395,
https://doi.org/10.2298/JSC130211034N . .
14
15
19

Morphology and internal structure of copper deposits electrodeposited by the pulsating current regime in the hydrogen co-deposition range

Nikolić, Nebojša D.; Branković, Goran O.; Maksimović, Vesna

(2012)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Branković, Goran O.
AU  - Maksimović, Vesna
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4629
AB  - The effect of the regime of pulsating current (PC) on copper electrodeposition in the hydrogen co-deposition range was examined by the techniques of scanning electron and optical microscopes. The quantities of evolved hydrogen and morphologies of electrodeposited copper strongly depended on the applied parameters of square waves PC, such as the current density amplitude (or the amplitude of the cathodic current density), deposition pulse, and pause duration. The increase of the current density amplitude led to intensification of hydrogen evolution reaction, and the change of morphology of electrodeposited copper from dendrites and shallow holes to dish-like holes was observed. For the constant pause duration, the prolonging deposition pulses intensify hydrogen evolution reaction leading to the formation of the honeycomb-like structures. The set of modified equations considering the effect of hydrogen generated during metal electrodeposition processes by the pulsating current regime is also presented. The concept of effective overpotential amplitude was proposed to explain the change of copper surface morphology with the intensification of hydrogen evolution reaction.
T2  - Journal of Solid State Electrochemistry
T1  - Morphology and internal structure of copper deposits electrodeposited by the pulsating current regime in the hydrogen co-deposition range
VL  - 16
IS  - 1
SP  - 321
EP  - 328
DO  - 10.1007/s10008-011-1331-x
ER  - 
@article{
author = "Nikolić, Nebojša D. and Branković, Goran O. and Maksimović, Vesna",
year = "2012",
abstract = "The effect of the regime of pulsating current (PC) on copper electrodeposition in the hydrogen co-deposition range was examined by the techniques of scanning electron and optical microscopes. The quantities of evolved hydrogen and morphologies of electrodeposited copper strongly depended on the applied parameters of square waves PC, such as the current density amplitude (or the amplitude of the cathodic current density), deposition pulse, and pause duration. The increase of the current density amplitude led to intensification of hydrogen evolution reaction, and the change of morphology of electrodeposited copper from dendrites and shallow holes to dish-like holes was observed. For the constant pause duration, the prolonging deposition pulses intensify hydrogen evolution reaction leading to the formation of the honeycomb-like structures. The set of modified equations considering the effect of hydrogen generated during metal electrodeposition processes by the pulsating current regime is also presented. The concept of effective overpotential amplitude was proposed to explain the change of copper surface morphology with the intensification of hydrogen evolution reaction.",
journal = "Journal of Solid State Electrochemistry",
title = "Morphology and internal structure of copper deposits electrodeposited by the pulsating current regime in the hydrogen co-deposition range",
volume = "16",
number = "1",
pages = "321-328",
doi = "10.1007/s10008-011-1331-x"
}
Nikolić, N. D., Branković, G. O.,& Maksimović, V.. (2012). Morphology and internal structure of copper deposits electrodeposited by the pulsating current regime in the hydrogen co-deposition range. in Journal of Solid State Electrochemistry, 16(1), 321-328.
https://doi.org/10.1007/s10008-011-1331-x
Nikolić ND, Branković GO, Maksimović V. Morphology and internal structure of copper deposits electrodeposited by the pulsating current regime in the hydrogen co-deposition range. in Journal of Solid State Electrochemistry. 2012;16(1):321-328.
doi:10.1007/s10008-011-1331-x .
Nikolić, Nebojša D., Branković, Goran O., Maksimović, Vesna, "Morphology and internal structure of copper deposits electrodeposited by the pulsating current regime in the hydrogen co-deposition range" in Journal of Solid State Electrochemistry, 16, no. 1 (2012):321-328,
https://doi.org/10.1007/s10008-011-1331-x . .
19
15
19

Effect of the anodic current density on copper electrodeposition in the hydrogen co-deposition range by the reversing current (RC) regime

Nikolić, Nebojša D.; Branković, Goran O.; Maksimović, Vesna

(2011)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Branković, Goran O.
AU  - Maksimović, Vesna
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4584
AB  - In this study, the effect of the anodic current density in the regime of reversing current (RC) on the quantity of evolved hydrogen and morphology of copper deposits was considered. The quantity of evolved hydrogen was quantified by the determination of the average current efficiency for hydrogen evolution reaction, while morphology and internal structures of electrodeposited copper were analyzed using scanning electron (SEM) and optical microscopy techniques, respectively. In all RC experiments, the cathodic current density of 440 mA/cm(2), cathodic pulse of 10 ms and anodic pulse of 5 ms were applied, while the analyzed anodic current densities were: 40, 240, 440 and 640 mA/cm(2). The number, size and shape of holes formed of detached hydrogen bubbles strongly depended on the selected parameters of square waves RC. Due to the decrease of the quantity of evolved hydrogen with the increasing anodic current density, the change of morphology of copper deposits formed around holes from cauliflower-like agglomerates of copper grains to dendrites was observed. Honeycomb-like structures were formed with the anodic current density values up to 440 mA/cm(2). The compactness of the honeycomb-like structures increased with the increase of the anodic current density. The improvement of structural characteristics of the honeycomb-like electrodes was achieved by the application of the RC regime in comparison with both the pulsating current (PC) and constant galvanostatic regimes. It was found that the regime of reversing current is superior in the production of the honeycomb-like electrodes in relation to other current regimes of electrolysis. (C) 2011 Elsevier B.V. All rights reserved.
T2  - Journal of Electroanalytical Chemistry
T1  - Effect of the anodic current density on copper electrodeposition in the hydrogen co-deposition range by the reversing current (RC) regime
VL  - 661
IS  - 2
SP  - 309
EP  - 316
DO  - 10.1016/j.jelechem.2011.08.006
ER  - 
@article{
author = "Nikolić, Nebojša D. and Branković, Goran O. and Maksimović, Vesna",
year = "2011",
abstract = "In this study, the effect of the anodic current density in the regime of reversing current (RC) on the quantity of evolved hydrogen and morphology of copper deposits was considered. The quantity of evolved hydrogen was quantified by the determination of the average current efficiency for hydrogen evolution reaction, while morphology and internal structures of electrodeposited copper were analyzed using scanning electron (SEM) and optical microscopy techniques, respectively. In all RC experiments, the cathodic current density of 440 mA/cm(2), cathodic pulse of 10 ms and anodic pulse of 5 ms were applied, while the analyzed anodic current densities were: 40, 240, 440 and 640 mA/cm(2). The number, size and shape of holes formed of detached hydrogen bubbles strongly depended on the selected parameters of square waves RC. Due to the decrease of the quantity of evolved hydrogen with the increasing anodic current density, the change of morphology of copper deposits formed around holes from cauliflower-like agglomerates of copper grains to dendrites was observed. Honeycomb-like structures were formed with the anodic current density values up to 440 mA/cm(2). The compactness of the honeycomb-like structures increased with the increase of the anodic current density. The improvement of structural characteristics of the honeycomb-like electrodes was achieved by the application of the RC regime in comparison with both the pulsating current (PC) and constant galvanostatic regimes. It was found that the regime of reversing current is superior in the production of the honeycomb-like electrodes in relation to other current regimes of electrolysis. (C) 2011 Elsevier B.V. All rights reserved.",
journal = "Journal of Electroanalytical Chemistry",
title = "Effect of the anodic current density on copper electrodeposition in the hydrogen co-deposition range by the reversing current (RC) regime",
volume = "661",
number = "2",
pages = "309-316",
doi = "10.1016/j.jelechem.2011.08.006"
}
Nikolić, N. D., Branković, G. O.,& Maksimović, V.. (2011). Effect of the anodic current density on copper electrodeposition in the hydrogen co-deposition range by the reversing current (RC) regime. in Journal of Electroanalytical Chemistry, 661(2), 309-316.
https://doi.org/10.1016/j.jelechem.2011.08.006
Nikolić ND, Branković GO, Maksimović V. Effect of the anodic current density on copper electrodeposition in the hydrogen co-deposition range by the reversing current (RC) regime. in Journal of Electroanalytical Chemistry. 2011;661(2):309-316.
doi:10.1016/j.jelechem.2011.08.006 .
Nikolić, Nebojša D., Branković, Goran O., Maksimović, Vesna, "Effect of the anodic current density on copper electrodeposition in the hydrogen co-deposition range by the reversing current (RC) regime" in Journal of Electroanalytical Chemistry, 661, no. 2 (2011):309-316,
https://doi.org/10.1016/j.jelechem.2011.08.006 . .
15
15
16

Cross-section analysis of the morphology of electrodeposited copper obtained in the hydrogen co-deposition range

Nikolić, Nebojša D.; Maksimović, Vesna; Pavlović, Miomir G.; Popov, Konstantin I.

(2009)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Maksimović, Vesna
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3765
AB  - Cross-section analysis of copper deposits electrodeposited in the hydrogen co-deposition range at a constant overpotential and in a pulsating overpotential (PO) regime was performed. It was shown that a complete structural analysis of these technologically very important electrodes is impossible without an analysis of their internal structure. An insight into the compactness (or porosity) of the deposits, as well as into the depth of the holes, can only be obtained by this type of analysis.
T2  - Journal of the Serbian Chemical Society
T1  - Cross-section analysis of the morphology of electrodeposited copper obtained in the hydrogen co-deposition range
VL  - 74
IS  - 6
SP  - 689
EP  - 696
DO  - 10.2298/JSC0906689N
ER  - 
@article{
author = "Nikolić, Nebojša D. and Maksimović, Vesna and Pavlović, Miomir G. and Popov, Konstantin I.",
year = "2009",
abstract = "Cross-section analysis of copper deposits electrodeposited in the hydrogen co-deposition range at a constant overpotential and in a pulsating overpotential (PO) regime was performed. It was shown that a complete structural analysis of these technologically very important electrodes is impossible without an analysis of their internal structure. An insight into the compactness (or porosity) of the deposits, as well as into the depth of the holes, can only be obtained by this type of analysis.",
journal = "Journal of the Serbian Chemical Society",
title = "Cross-section analysis of the morphology of electrodeposited copper obtained in the hydrogen co-deposition range",
volume = "74",
number = "6",
pages = "689-696",
doi = "10.2298/JSC0906689N"
}
Nikolić, N. D., Maksimović, V., Pavlović, M. G.,& Popov, K. I.. (2009). Cross-section analysis of the morphology of electrodeposited copper obtained in the hydrogen co-deposition range. in Journal of the Serbian Chemical Society, 74(6), 689-696.
https://doi.org/10.2298/JSC0906689N
Nikolić ND, Maksimović V, Pavlović MG, Popov KI. Cross-section analysis of the morphology of electrodeposited copper obtained in the hydrogen co-deposition range. in Journal of the Serbian Chemical Society. 2009;74(6):689-696.
doi:10.2298/JSC0906689N .
Nikolić, Nebojša D., Maksimović, Vesna, Pavlović, Miomir G., Popov, Konstantin I., "Cross-section analysis of the morphology of electrodeposited copper obtained in the hydrogen co-deposition range" in Journal of the Serbian Chemical Society, 74, no. 6 (2009):689-696,
https://doi.org/10.2298/JSC0906689N . .
8
9
11

Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes

Nikolić, Nebojša D.; Branković, Goran O.; Maksimović, Vesna; Pavlović, Miomir G.; Popov, Konstantin I.

(2009)

TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Branković, Goran O.
AU  - Maksimović, Vesna
AU  - Pavlović, Miomir G.
AU  - Popov, Konstantin I.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3819
AB  - Electrodeposition of copper by pulsating overpotential (PO) regime in the hydrogen co-deposition range was examined by the determination of the average current efficiency of hydrogen evolution and by microscopic analysis of the morphology of the formed deposits. The techniques of scanning electron microscopy (SEM) and optical microscopy were used for the structural analysis of the copper deposits. Honeycomb-like electrodes were formed with an amplitude overpotential of 1000 mV, a pause of 10 ms, and deposition pulses of 3, 5, 10 and 20 ms. Holes formed by attached hydrogen bubbles were surrounded by dendrites (for deposition pulses of 3 and 5 ms) or agglomerates of copper grains (for 10 and 20 ms). In an interval of deposition pulses between 3 and 10 ms, the length of deposition pulse did not affect the size, number and depth of holes. The change of morphology of copper formed around holes was discussed by the effect of quantity of evolved hydrogen on effectiveness of stirring of solution in the near-electrode layer. The application of square-wave PO with the shorter deposition pulses enabled energy savings in the production of such copper electrodes. For example, the applied deposition pulse of 3 ms enabled energy saving of about 15% in relation to the copper electrode obtained with a deposition pulse of 10 ms (for the unchanged number, size and depth of holes). (C) 2009 Elsevier B.V. All rights reserved.
T2  - Journal of Electroanalytical Chemistry
T1  - Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes
VL  - 635
IS  - 2
SP  - 111
EP  - 119
DO  - 10.1016/j.jelechem.2009.08.005
ER  - 
@article{
author = "Nikolić, Nebojša D. and Branković, Goran O. and Maksimović, Vesna and Pavlović, Miomir G. and Popov, Konstantin I.",
year = "2009",
abstract = "Electrodeposition of copper by pulsating overpotential (PO) regime in the hydrogen co-deposition range was examined by the determination of the average current efficiency of hydrogen evolution and by microscopic analysis of the morphology of the formed deposits. The techniques of scanning electron microscopy (SEM) and optical microscopy were used for the structural analysis of the copper deposits. Honeycomb-like electrodes were formed with an amplitude overpotential of 1000 mV, a pause of 10 ms, and deposition pulses of 3, 5, 10 and 20 ms. Holes formed by attached hydrogen bubbles were surrounded by dendrites (for deposition pulses of 3 and 5 ms) or agglomerates of copper grains (for 10 and 20 ms). In an interval of deposition pulses between 3 and 10 ms, the length of deposition pulse did not affect the size, number and depth of holes. The change of morphology of copper formed around holes was discussed by the effect of quantity of evolved hydrogen on effectiveness of stirring of solution in the near-electrode layer. The application of square-wave PO with the shorter deposition pulses enabled energy savings in the production of such copper electrodes. For example, the applied deposition pulse of 3 ms enabled energy saving of about 15% in relation to the copper electrode obtained with a deposition pulse of 10 ms (for the unchanged number, size and depth of holes). (C) 2009 Elsevier B.V. All rights reserved.",
journal = "Journal of Electroanalytical Chemistry",
title = "Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes",
volume = "635",
number = "2",
pages = "111-119",
doi = "10.1016/j.jelechem.2009.08.005"
}
Nikolić, N. D., Branković, G. O., Maksimović, V., Pavlović, M. G.,& Popov, K. I.. (2009). Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes. in Journal of Electroanalytical Chemistry, 635(2), 111-119.
https://doi.org/10.1016/j.jelechem.2009.08.005
Nikolić ND, Branković GO, Maksimović V, Pavlović MG, Popov KI. Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes. in Journal of Electroanalytical Chemistry. 2009;635(2):111-119.
doi:10.1016/j.jelechem.2009.08.005 .
Nikolić, Nebojša D., Branković, Goran O., Maksimović, Vesna, Pavlović, Miomir G., Popov, Konstantin I., "Influence of potential pulse conditions on the formation of honeycomb-like copper electrodes" in Journal of Electroanalytical Chemistry, 635, no. 2 (2009):111-119,
https://doi.org/10.1016/j.jelechem.2009.08.005 . .
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