Askrabic, Sonja

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  • Askrabic, Sonja (4)

Author's Bibliography

Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders

Matović, Branko; Luković, Jelena M.; Stojadinović, Bojan; Askrabic, Sonja; Zarubica, Aleksandra R.; Babić, Biljana M.; Dohčević-Mitrović, Zorana

(2017)

TY  - JOUR
AU  - Matović, Branko
AU  - Luković, Jelena M.
AU  - Stojadinović, Bojan
AU  - Askrabic, Sonja
AU  - Zarubica, Aleksandra R.
AU  - Babić, Biljana M.
AU  - Dohčević-Mitrović, Zorana 
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1905
AB  - Nanosized Mg-doped ceria powders were obtained by self-propagating room temperature reaction without using surfactants or templates. X-ray diffraction analysis and field emission scanning microscopy results showed that the doped samples are solid solutions with fluorite-type structure and spherical morphology. Raman spectra revealed an increase in the amount of oxygen vacancies with the increase of Mg concentration. This increasing results in a narrowing of the bandgap of CeO2. The photocatalytic performances of the Mg-doped ceria solid solutions were evaluated by decomposing an organic dye, crystal violet under UV irradiation. The Mg-doped ceria solid solutions exhibit significantly better photocatalytic activity than the pure CeO2 and commercial TiO2. The higher first rate constant of the Mg-doped samples demonstrated that they are much more efficient than TiO2 and CeO2 under UV light. Mg2+ dopant ions and oxygen vacancies play a significant role in the enhancement of photocatalytic performances of the Mg-doped ceria.
T2  - Processing and Application of Ceramics
T1  - Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders
VL  - 11
IS  - 4
SP  - 304
EP  - 310
DO  - 10.2298/PAC1704304M
ER  - 
@article{
author = "Matović, Branko and Luković, Jelena M. and Stojadinović, Bojan and Askrabic, Sonja and Zarubica, Aleksandra R. and Babić, Biljana M. and Dohčević-Mitrović, Zorana ",
year = "2017",
abstract = "Nanosized Mg-doped ceria powders were obtained by self-propagating room temperature reaction without using surfactants or templates. X-ray diffraction analysis and field emission scanning microscopy results showed that the doped samples are solid solutions with fluorite-type structure and spherical morphology. Raman spectra revealed an increase in the amount of oxygen vacancies with the increase of Mg concentration. This increasing results in a narrowing of the bandgap of CeO2. The photocatalytic performances of the Mg-doped ceria solid solutions were evaluated by decomposing an organic dye, crystal violet under UV irradiation. The Mg-doped ceria solid solutions exhibit significantly better photocatalytic activity than the pure CeO2 and commercial TiO2. The higher first rate constant of the Mg-doped samples demonstrated that they are much more efficient than TiO2 and CeO2 under UV light. Mg2+ dopant ions and oxygen vacancies play a significant role in the enhancement of photocatalytic performances of the Mg-doped ceria.",
journal = "Processing and Application of Ceramics",
title = "Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders",
volume = "11",
number = "4",
pages = "304-310",
doi = "10.2298/PAC1704304M"
}
Matović, B., Luković, J. M., Stojadinović, B., Askrabic, S., Zarubica, A. R., Babić, B. M.,& Dohčević-Mitrović, Z.. (2017). Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders. in Processing and Application of Ceramics, 11(4), 304-310.
https://doi.org/10.2298/PAC1704304M
Matović B, Luković JM, Stojadinović B, Askrabic S, Zarubica AR, Babić BM, Dohčević-Mitrović Z. Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders. in Processing and Application of Ceramics. 2017;11(4):304-310.
doi:10.2298/PAC1704304M .
Matović, Branko, Luković, Jelena M., Stojadinović, Bojan, Askrabic, Sonja, Zarubica, Aleksandra R., Babić, Biljana M., Dohčević-Mitrović, Zorana , "Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders" in Processing and Application of Ceramics, 11, no. 4 (2017):304-310,
https://doi.org/10.2298/PAC1704304M . .
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WO3/TiO2 composite coatings: Structural, optical and photocatalytic properties

Dohčević-Mitrović, Zorana ; Stojadinovic, Stevan; Lozzi, Luca; Askrabic, Sonja; Rosić, Milena; Tomic, Natasa; Paunović, Novica M.; Lazovic, Sasa; Nikolić, Marko G.; Santucci, Sandro

(2016)

TY  - JOUR
AU  - Dohčević-Mitrović, Zorana 
AU  - Stojadinovic, Stevan
AU  - Lozzi, Luca
AU  - Askrabic, Sonja
AU  - Rosić, Milena
AU  - Tomic, Natasa
AU  - Paunović, Novica M.
AU  - Lazovic, Sasa
AU  - Nikolić, Marko G.
AU  - Santucci, Sandro
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1234
AB  - WO3/TiO2 and TiO2 coatings were prepared on titania substrates using facile and cost-effective plasma electrolytic oxidation process. The coatings were characterized by X-ray diffraction, scanning electron microscopy, Raman, UV vis diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. With increasing duration of PEO process, the monoclinic WO3 phase became dominant and new monoclinic WO2.95 phase appeared. The optical absorption edge in the WO3/TiO2 samples, enriched with WO3/WO2.96 phase, was shifted to the visible region. The photocatalytic efficiency of WO3/TiO2 and pure TiO2 samples was evaluated by performing the photodegradation experiments in an aqueous solution of Rhodamine 6G and Mordant Blue 9 under the visible and UV light. The WO3/TiO2 catalysts are much more efficient than pure TiO2 under visible light and slightly better under UV light. The improvement of photocatalytic activity in the visible region is attributed to better light absorption, higher adsorption affinity and increased charge separation efficiency. (C) 2016 Elsevier Ltd. All rights reserved.
T2  - Materials Research Bulletin
T1  - WO3/TiO2 composite coatings: Structural, optical and photocatalytic properties
VL  - 83
SP  - 217
EP  - 224
DO  - 10.1016/j.materresbull.2016.06.011
ER  - 
@article{
author = "Dohčević-Mitrović, Zorana  and Stojadinovic, Stevan and Lozzi, Luca and Askrabic, Sonja and Rosić, Milena and Tomic, Natasa and Paunović, Novica M. and Lazovic, Sasa and Nikolić, Marko G. and Santucci, Sandro",
year = "2016",
abstract = "WO3/TiO2 and TiO2 coatings were prepared on titania substrates using facile and cost-effective plasma electrolytic oxidation process. The coatings were characterized by X-ray diffraction, scanning electron microscopy, Raman, UV vis diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. With increasing duration of PEO process, the monoclinic WO3 phase became dominant and new monoclinic WO2.95 phase appeared. The optical absorption edge in the WO3/TiO2 samples, enriched with WO3/WO2.96 phase, was shifted to the visible region. The photocatalytic efficiency of WO3/TiO2 and pure TiO2 samples was evaluated by performing the photodegradation experiments in an aqueous solution of Rhodamine 6G and Mordant Blue 9 under the visible and UV light. The WO3/TiO2 catalysts are much more efficient than pure TiO2 under visible light and slightly better under UV light. The improvement of photocatalytic activity in the visible region is attributed to better light absorption, higher adsorption affinity and increased charge separation efficiency. (C) 2016 Elsevier Ltd. All rights reserved.",
journal = "Materials Research Bulletin",
title = "WO3/TiO2 composite coatings: Structural, optical and photocatalytic properties",
volume = "83",
pages = "217-224",
doi = "10.1016/j.materresbull.2016.06.011"
}
Dohčević-Mitrović, Z., Stojadinovic, S., Lozzi, L., Askrabic, S., Rosić, M., Tomic, N., Paunović, N. M., Lazovic, S., Nikolić, M. G.,& Santucci, S.. (2016). WO3/TiO2 composite coatings: Structural, optical and photocatalytic properties. in Materials Research Bulletin, 83, 217-224.
https://doi.org/10.1016/j.materresbull.2016.06.011
Dohčević-Mitrović Z, Stojadinovic S, Lozzi L, Askrabic S, Rosić M, Tomic N, Paunović NM, Lazovic S, Nikolić MG, Santucci S. WO3/TiO2 composite coatings: Structural, optical and photocatalytic properties. in Materials Research Bulletin. 2016;83:217-224.
doi:10.1016/j.materresbull.2016.06.011 .
Dohčević-Mitrović, Zorana , Stojadinovic, Stevan, Lozzi, Luca, Askrabic, Sonja, Rosić, Milena, Tomic, Natasa, Paunović, Novica M., Lazovic, Sasa, Nikolić, Marko G., Santucci, Sandro, "WO3/TiO2 composite coatings: Structural, optical and photocatalytic properties" in Materials Research Bulletin, 83 (2016):217-224,
https://doi.org/10.1016/j.materresbull.2016.06.011 . .
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Nano-structural and compositional basis of devitalized tooth fragility

Zelic, Ksenija; Milovanović, Petar; Rakočević, Zlatko Lj.; Askrabic, Sonja; Potočnik, Jelena; Popovic, Miroslav; Đurić, Marija

(2014)

TY  - JOUR
AU  - Zelic, Ksenija
AU  - Milovanović, Petar
AU  - Rakočević, Zlatko Lj.
AU  - Askrabic, Sonja
AU  - Potočnik, Jelena
AU  - Popovic, Miroslav
AU  - Đurić, Marija
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5962
AB  - Objective. Increased tooth fragility after devitalization is commonly observed but there is no definite mechanistic explanation for such phenomenon. Therefore, it is important to analyze more profoundly structural and compositional properties of this altered form of dentin. The present study investigates the differences between normal and devitalized dentin using advanced techniques. Methods. Atomic force microscopic imaging (AFM), energy dispersive X-ray analysis (EDX) and micro-Raman spectroscopy were performed on 16 dentin specimens, eight vital and eight that underwent root-canal treatment at least two years before extraction and had no infection in root canals before or after devitalization. Results. The mean size of mineral crystals showed by AFM was larger in devitalized than in healthy dentin in the same age category. AFM phase shifts in devitalized cases revealed altered mechanical characteristics and suggested differences in composition of material between devitalized teeth and healthy controls. No significant difference in Ca/P ratio between vital and devitalized teeth was found using EDX. However, micro-Raman analyses showed that in devitalized teeth, apart from hydroxyapatite, dentin contained significant amounts of apatite phases with lower calcium content: octacalcium phosphate, dicalcium phosphate dihydrate and tricalcium phosphate. Significance. Differences between vital and devitalized dentin bring new insights into the basis of devitalized tooth fragility. Larger mineral crystals could account for decreased mechanical strength in devitalized teeth. Moreover, calcium-phosphate phases with lower Ca content have lower material strength, and the presence of these phases in devitalized teeth may explain their increased fragility. (C) 2014 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.
T2  - Dental Materials
T1  - Nano-structural and compositional basis of devitalized tooth fragility
VL  - 30
IS  - 5
SP  - 476
EP  - 486
DO  - 10.1016/j.dental.2014.01.014
ER  - 
@article{
author = "Zelic, Ksenija and Milovanović, Petar and Rakočević, Zlatko Lj. and Askrabic, Sonja and Potočnik, Jelena and Popovic, Miroslav and Đurić, Marija",
year = "2014",
abstract = "Objective. Increased tooth fragility after devitalization is commonly observed but there is no definite mechanistic explanation for such phenomenon. Therefore, it is important to analyze more profoundly structural and compositional properties of this altered form of dentin. The present study investigates the differences between normal and devitalized dentin using advanced techniques. Methods. Atomic force microscopic imaging (AFM), energy dispersive X-ray analysis (EDX) and micro-Raman spectroscopy were performed on 16 dentin specimens, eight vital and eight that underwent root-canal treatment at least two years before extraction and had no infection in root canals before or after devitalization. Results. The mean size of mineral crystals showed by AFM was larger in devitalized than in healthy dentin in the same age category. AFM phase shifts in devitalized cases revealed altered mechanical characteristics and suggested differences in composition of material between devitalized teeth and healthy controls. No significant difference in Ca/P ratio between vital and devitalized teeth was found using EDX. However, micro-Raman analyses showed that in devitalized teeth, apart from hydroxyapatite, dentin contained significant amounts of apatite phases with lower calcium content: octacalcium phosphate, dicalcium phosphate dihydrate and tricalcium phosphate. Significance. Differences between vital and devitalized dentin bring new insights into the basis of devitalized tooth fragility. Larger mineral crystals could account for decreased mechanical strength in devitalized teeth. Moreover, calcium-phosphate phases with lower Ca content have lower material strength, and the presence of these phases in devitalized teeth may explain their increased fragility. (C) 2014 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.",
journal = "Dental Materials",
title = "Nano-structural and compositional basis of devitalized tooth fragility",
volume = "30",
number = "5",
pages = "476-486",
doi = "10.1016/j.dental.2014.01.014"
}
Zelic, K., Milovanović, P., Rakočević, Z. Lj., Askrabic, S., Potočnik, J., Popovic, M.,& Đurić, M.. (2014). Nano-structural and compositional basis of devitalized tooth fragility. in Dental Materials, 30(5), 476-486.
https://doi.org/10.1016/j.dental.2014.01.014
Zelic K, Milovanović P, Rakočević ZL, Askrabic S, Potočnik J, Popovic M, Đurić M. Nano-structural and compositional basis of devitalized tooth fragility. in Dental Materials. 2014;30(5):476-486.
doi:10.1016/j.dental.2014.01.014 .
Zelic, Ksenija, Milovanović, Petar, Rakočević, Zlatko Lj., Askrabic, Sonja, Potočnik, Jelena, Popovic, Miroslav, Đurić, Marija, "Nano-structural and compositional basis of devitalized tooth fragility" in Dental Materials, 30, no. 5 (2014):476-486,
https://doi.org/10.1016/j.dental.2014.01.014 . .
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Suppression of inherent ferromagnetism in Pr-doped CeO2 nanocrystals

Paunović, Novica M.; Dohčević-Mitrović, Zorana ; Scurtu, Rares; Askrabic, Sonja; Prekajski, Marija D.; Matović, Branko; Popović, Zoran V.

(2012)

TY  - JOUR
AU  - Paunović, Novica M.
AU  - Dohčević-Mitrović, Zorana 
AU  - Scurtu, Rares
AU  - Askrabic, Sonja
AU  - Prekajski, Marija D.
AU  - Matović, Branko
AU  - Popović, Zoran V.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4992
AB  - Ce1-xPrxO2-delta (0 LT = x LT = 0.4) nanocrystals were synthesized by self-propagating method and thoroughly characterized using X-ray diffraction, Raman and X-ray photoelectron spectroscopy and magnetic measurements. Undoped CeO2 nanocrystals exhibited intrinsic ferromagnetism at room temperature. Despite the increased concentration of oxygen vacancies in doped samples, our results showed that ferromagnetic ordering rapidly degrades with Pr doping. The suppression of ferromagnetism can be explained in terms of the different dopant valence state, the different nature of the vacancies formed in Pr-doped samples and their ability/disability to establish the ferromagnetic ordering.
T2  - Nanoscale
T1  - Suppression of inherent ferromagnetism in Pr-doped CeO2 nanocrystals
VL  - 4
IS  - 17
SP  - 5469
EP  - 5476
DO  - 10.1039/c2nr30799e
ER  - 
@article{
author = "Paunović, Novica M. and Dohčević-Mitrović, Zorana  and Scurtu, Rares and Askrabic, Sonja and Prekajski, Marija D. and Matović, Branko and Popović, Zoran V.",
year = "2012",
abstract = "Ce1-xPrxO2-delta (0 LT = x LT = 0.4) nanocrystals were synthesized by self-propagating method and thoroughly characterized using X-ray diffraction, Raman and X-ray photoelectron spectroscopy and magnetic measurements. Undoped CeO2 nanocrystals exhibited intrinsic ferromagnetism at room temperature. Despite the increased concentration of oxygen vacancies in doped samples, our results showed that ferromagnetic ordering rapidly degrades with Pr doping. The suppression of ferromagnetism can be explained in terms of the different dopant valence state, the different nature of the vacancies formed in Pr-doped samples and their ability/disability to establish the ferromagnetic ordering.",
journal = "Nanoscale",
title = "Suppression of inherent ferromagnetism in Pr-doped CeO2 nanocrystals",
volume = "4",
number = "17",
pages = "5469-5476",
doi = "10.1039/c2nr30799e"
}
Paunović, N. M., Dohčević-Mitrović, Z., Scurtu, R., Askrabic, S., Prekajski, M. D., Matović, B.,& Popović, Z. V.. (2012). Suppression of inherent ferromagnetism in Pr-doped CeO2 nanocrystals. in Nanoscale, 4(17), 5469-5476.
https://doi.org/10.1039/c2nr30799e
Paunović NM, Dohčević-Mitrović Z, Scurtu R, Askrabic S, Prekajski MD, Matović B, Popović ZV. Suppression of inherent ferromagnetism in Pr-doped CeO2 nanocrystals. in Nanoscale. 2012;4(17):5469-5476.
doi:10.1039/c2nr30799e .
Paunović, Novica M., Dohčević-Mitrović, Zorana , Scurtu, Rares, Askrabic, Sonja, Prekajski, Marija D., Matović, Branko, Popović, Zoran V., "Suppression of inherent ferromagnetism in Pr-doped CeO2 nanocrystals" in Nanoscale, 4, no. 17 (2012):5469-5476,
https://doi.org/10.1039/c2nr30799e . .
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