TY  - JOUR
AU  - Perić, Marko R.
AU  - Kyne, Sara H.
AU  - Gruden, Maja
AU  - Rodić, Marko V.
AU  - Jeremić, Dejan
AU  - Stanković, Dalibor M.
AU  - Brčeski, Ilija
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8381
AB  - In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.
T2  - Monatshefte fur Chemie
T1  - Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand
VL  - 150
IS  - 7
SP  - 1241
EP  - 1248
DO  - 10.1007/s00706-019-02405-7
ER  - 

@article{
author = "Perić, Marko R. and Kyne, Sara H. and Gruden, Maja and Rodić, Marko V. and Jeremić, Dejan and Stanković, Dalibor M. and Brčeski, Ilija",
year = "2019",
abstract = "In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.",
journal = "Monatshefte fur Chemie",
title = "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand",
volume = "150",
number = "7",
pages = "1241-1248",
doi = "10.1007/s00706-019-02405-7"
}

Perić, M. R., Kyne, S. H., Gruden, M., Rodić, M. V., Jeremić, D., Stanković, D. M.,& Brčeski, I.. (2019). Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie, 150(7), 1241-1248.
https://doi.org/10.1007/s00706-019-02405-7

Perić MR, Kyne SH, Gruden M, Rodić MV, Jeremić D, Stanković DM, Brčeski I. Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie. 2019;150(7):1241-1248.
doi:10.1007/s00706-019-02405-7 .

Perić, Marko R., Kyne, Sara H., Gruden, Maja, Rodić, Marko V., Jeremić, Dejan, Stanković, Dalibor M., Brčeski, Ilija, "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand" in Monatshefte fur Chemie, 150, no. 7 (2019):1241-1248,
https://doi.org/10.1007/s00706-019-02405-7 . .

TY  - JOUR
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Brceski, Ilija D.
AU  - Leovac, Vukadin M.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3754
AB  - The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)
VL  - 65
SP  - M263
EP  - M265
DO  - 10.1107/S0108270109021970
ER  - 

@article{
author = "Novaković, Slađana B. and Bogdanović, Goran A. and Brceski, Ilija D. and Leovac, Vukadin M.",
year = "2009",
abstract = "The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)",
volume = "65",
pages = "M263-M265",
doi = "10.1107/S0108270109021970"
}

Novaković, S. B., Bogdanović, G. A., Brceski, I. D.,& Leovac, V. M.. (2009). Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications, 65, M263-M265.
https://doi.org/10.1107/S0108270109021970

Novaković SB, Bogdanović GA, Brceski ID, Leovac VM. Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65:M263-M265.
doi:10.1107/S0108270109021970 .

Novaković, Slađana B., Bogdanović, Goran A., Brceski, Ilija D., Leovac, Vukadin M., "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009):M263-M265,
https://doi.org/10.1107/S0108270109021970 . .

TY  - JOUR
AU  - Drašković, Bojana M.
AU  - Bogdanović, Goran A.
AU  - Leovac, Vukadin M.
AU  - Brceski, Ilija D.
AU  - Poleti, Dejan
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3037
AB  - The title compound, [Ni(C28H30N3O2PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni-II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from a thiosemicarbazide-based tetradentate ligand. The Ni-II atom and the ONN donor atoms are nearly coplanar, while the P atom deviates from their mean planes by 0.278 (4) and 0.202 (4) angstrom for the two independent molecules. The P-containing chelate rings are remarkably non-planar, adopting a boat conformation, which is unusual for chelate rings in transition metal complexes with thiosemicarbazide-based tetradentate ligands. The orientation of the ethoxy group bonded to this chelate ring is caused by an intramolecular C-H center dot center dot center dot pi interaction with the opposing phenyl ring. There are no hydrogen bonds; instead, numerous intermolecular C-H center dot center dot center dot pi interactions dominate in the crystal packing.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)
VL  - 62
SP  - M319
EP  - M322
DO  - 10.1107/S0108271016018932
ER  - 

@article{
author = "Drašković, Bojana M. and Bogdanović, Goran A. and Leovac, Vukadin M. and Brceski, Ilija D. and Poleti, Dejan",
year = "2006",
abstract = "The title compound, [Ni(C28H30N3O2PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni-II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from a thiosemicarbazide-based tetradentate ligand. The Ni-II atom and the ONN donor atoms are nearly coplanar, while the P atom deviates from their mean planes by 0.278 (4) and 0.202 (4) angstrom for the two independent molecules. The P-containing chelate rings are remarkably non-planar, adopting a boat conformation, which is unusual for chelate rings in transition metal complexes with thiosemicarbazide-based tetradentate ligands. The orientation of the ethoxy group bonded to this chelate ring is caused by an intramolecular C-H center dot center dot center dot pi interaction with the opposing phenyl ring. There are no hydrogen bonds; instead, numerous intermolecular C-H center dot center dot center dot pi interactions dominate in the crystal packing.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)",
volume = "62",
pages = "M319-M322",
doi = "10.1107/S0108271016018932"
}

Drašković, B. M., Bogdanović, G. A., Leovac, V. M., Brceski, I. D.,& Poleti, D.. (2006). Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II). in Acta Crystallographica. Section C: Crystal Structure Communications, 62, M319-M322.
https://doi.org/10.1107/S0108271016018932

Drašković BM, Bogdanović GA, Leovac VM, Brceski ID, Poleti D. Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II). in Acta Crystallographica. Section C: Crystal Structure Communications. 2006;62:M319-M322.
doi:10.1107/S0108271016018932 .

Drašković, Bojana M., Bogdanović, Goran A., Leovac, Vukadin M., Brceski, Ilija D., Poleti, Dejan, "Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 62 (2006):M319-M322,
https://doi.org/10.1107/S0108271016018932 . .

TY  - JOUR
AU  - Brceski, ID
AU  - Leovac, Vukadin M.
AU  - Bogdanović, Goran A.
AU  - Sovilj, Sofija P.
AU  - Revenco, M
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2709
AB  - The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V.
T2  - Inorganic Chemistry Communications
T1  - Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)
VL  - 7
IS  - 2
SP  - 253
EP  - 256
DO  - 10.1016/j.inoche.2003.11.013
ER  - 

@article{
author = "Brceski, ID and Leovac, Vukadin M. and Bogdanović, Goran A. and Sovilj, Sofija P. and Revenco, M",
year = "2004",
abstract = "The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V.",
journal = "Inorganic Chemistry Communications",
title = "Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)",
volume = "7",
number = "2",
pages = "253-256",
doi = "10.1016/j.inoche.2003.11.013"
}

Brceski, I., Leovac, V. M., Bogdanović, G. A., Sovilj, S. P.,& Revenco, M.. (2004). Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II). in Inorganic Chemistry Communications, 7(2), 253-256.
https://doi.org/10.1016/j.inoche.2003.11.013

Brceski I, Leovac VM, Bogdanović GA, Sovilj SP, Revenco M. Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II). in Inorganic Chemistry Communications. 2004;7(2):253-256.
doi:10.1016/j.inoche.2003.11.013 .

Brceski, ID, Leovac, Vukadin M., Bogdanović, Goran A., Sovilj, Sofija P., Revenco, M, "Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)" in Inorganic Chemistry Communications, 7, no. 2 (2004):253-256,
https://doi.org/10.1016/j.inoche.2003.11.013 . .