Đustebek, Jasmina B.

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  • Đustebek, Jasmina B. (18)
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Author's Bibliography

Study of the vaporization of LiI, LiI/C-70, LiI/LiF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer

Đustebek, Jasmina B.; Veljković, Miomir V.; Veličković, Suzana

(2014)

TY  - JOUR
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Veličković, Suzana
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5937
AB  - The vaporization of LiI, LiI/C-70 and LiI/LIF/C-70 was studied using a Knudsen cell located in the ionization chamber of a magnetic sector mass spectrometer in the temperature range from 350 degrees C to 850 degrees C. The ion species, LinI+ (n = 2, 3, 4 or 6) were identified from the mixture LiI/C-70, while the clusters LinI+ and LinF+ (n = 2, 3, 4, 5 or 6) were detected from a mixture LiI/LiF/C-70. The intensities of LinI+ were higher than the emission of LinF+ cluster when the ratio of LiI to LiF was 2:1. By contrast, the emission of LinF+ is favored when the ratio of LiI to LiF was 1:2. These results show that the vaporization of a mixture LiI/LIF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer represents an efficient and simple way to obtain and investigate clusters of the type LinX, X = F or I. In this work, it was also shown that the trends of the In (Intensity, arb. units) versus temperature for all LinI+ clusters below and above the melting point of LiI were not same. This suggested that the manner of formation of these clusters could be different due to changes in temperature.
T2  - Journal of the Serbian Chemical Society
T1  - Study of the vaporization of LiI, LiI/C-70, LiI/LiF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer
VL  - 79
IS  - 3
SP  - 313
EP  - 324
DO  - 10.2298/JSC130627083D
ER  - 
@article{
author = "Đustebek, Jasmina B. and Veljković, Miomir V. and Veličković, Suzana",
year = "2014",
abstract = "The vaporization of LiI, LiI/C-70 and LiI/LIF/C-70 was studied using a Knudsen cell located in the ionization chamber of a magnetic sector mass spectrometer in the temperature range from 350 degrees C to 850 degrees C. The ion species, LinI+ (n = 2, 3, 4 or 6) were identified from the mixture LiI/C-70, while the clusters LinI+ and LinF+ (n = 2, 3, 4, 5 or 6) were detected from a mixture LiI/LiF/C-70. The intensities of LinI+ were higher than the emission of LinF+ cluster when the ratio of LiI to LiF was 2:1. By contrast, the emission of LinF+ is favored when the ratio of LiI to LiF was 1:2. These results show that the vaporization of a mixture LiI/LIF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer represents an efficient and simple way to obtain and investigate clusters of the type LinX, X = F or I. In this work, it was also shown that the trends of the In (Intensity, arb. units) versus temperature for all LinI+ clusters below and above the melting point of LiI were not same. This suggested that the manner of formation of these clusters could be different due to changes in temperature.",
journal = "Journal of the Serbian Chemical Society",
title = "Study of the vaporization of LiI, LiI/C-70, LiI/LiF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer",
volume = "79",
number = "3",
pages = "313-324",
doi = "10.2298/JSC130627083D"
}
Đustebek, J. B., Veljković, M. V.,& Veličković, S.. (2014). Study of the vaporization of LiI, LiI/C-70, LiI/LiF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer. in Journal of the Serbian Chemical Society, 79(3), 313-324.
https://doi.org/10.2298/JSC130627083D
Đustebek JB, Veljković MV, Veličković S. Study of the vaporization of LiI, LiI/C-70, LiI/LiF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer. in Journal of the Serbian Chemical Society. 2014;79(3):313-324.
doi:10.2298/JSC130627083D .
Đustebek, Jasmina B., Veljković, Miomir V., Veličković, Suzana, "Study of the vaporization of LiI, LiI/C-70, LiI/LiF/C-70 from a Knudsen cell located in the ionization chamber of a mass spectrometer" in Journal of the Serbian Chemical Society, 79, no. 3 (2014):313-324,
https://doi.org/10.2298/JSC130627083D . .
1
1

Theoretical and experimental study of the non-stoichiometric LinI (n=3 and 5) clusters

Đustebek, Jasmina B.; Milovanović, Milan; Jerosimic, Stanka; Veljković, Miomir V.; Veličković, Suzana

(2013)

TY  - JOUR
AU  - Đustebek, Jasmina B.
AU  - Milovanović, Milan
AU  - Jerosimic, Stanka
AU  - Veljković, Miomir V.
AU  - Veličković, Suzana
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5269
AB  - The neutrals of the LinI (n = 2-6) clusters were detected using Knudsen-cell which was placed into ionization chamber of the magnetic sector mass spectrometer. The first theoretical and experimental data on the Li3I and Li5I clusters were presented in this Letter. The ionization energies of the neutral of Li3I and Li5I clusters, obtained by the electron impact ionization mass spectrometry, were (5.14 +/- 0.25) and (4.62 +/- 0.25) eV, respectively. We report the geometry, ionization energies and thermodynamical stability of these clusters, calculated at the restricted coupled cluster RHF-RCCSD/cc-pVTZ(Li), cc-pVTZ-PP(I) level of theory. (C) 2012 Elsevier B. V. All rights reserved.
T2  - Chemical Physics Letters
T1  - Theoretical and experimental study of the non-stoichiometric LinI (n=3 and 5) clusters
VL  - 556
SP  - 380
EP  - 385
DO  - 10.1016/j.cplett.2012.11.086
ER  - 
@article{
author = "Đustebek, Jasmina B. and Milovanović, Milan and Jerosimic, Stanka and Veljković, Miomir V. and Veličković, Suzana",
year = "2013",
abstract = "The neutrals of the LinI (n = 2-6) clusters were detected using Knudsen-cell which was placed into ionization chamber of the magnetic sector mass spectrometer. The first theoretical and experimental data on the Li3I and Li5I clusters were presented in this Letter. The ionization energies of the neutral of Li3I and Li5I clusters, obtained by the electron impact ionization mass spectrometry, were (5.14 +/- 0.25) and (4.62 +/- 0.25) eV, respectively. We report the geometry, ionization energies and thermodynamical stability of these clusters, calculated at the restricted coupled cluster RHF-RCCSD/cc-pVTZ(Li), cc-pVTZ-PP(I) level of theory. (C) 2012 Elsevier B. V. All rights reserved.",
journal = "Chemical Physics Letters",
title = "Theoretical and experimental study of the non-stoichiometric LinI (n=3 and 5) clusters",
volume = "556",
pages = "380-385",
doi = "10.1016/j.cplett.2012.11.086"
}
Đustebek, J. B., Milovanović, M., Jerosimic, S., Veljković, M. V.,& Veličković, S.. (2013). Theoretical and experimental study of the non-stoichiometric LinI (n=3 and 5) clusters. in Chemical Physics Letters, 556, 380-385.
https://doi.org/10.1016/j.cplett.2012.11.086
Đustebek JB, Milovanović M, Jerosimic S, Veljković MV, Veličković S. Theoretical and experimental study of the non-stoichiometric LinI (n=3 and 5) clusters. in Chemical Physics Letters. 2013;556:380-385.
doi:10.1016/j.cplett.2012.11.086 .
Đustebek, Jasmina B., Milovanović, Milan, Jerosimic, Stanka, Veljković, Miomir V., Veličković, Suzana, "Theoretical and experimental study of the non-stoichiometric LinI (n=3 and 5) clusters" in Chemical Physics Letters, 556 (2013):380-385,
https://doi.org/10.1016/j.cplett.2012.11.086 . .
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Major Factors Affecting the Emission of Dilithium-Fluoride Cluster Ion in Thermal Ionization Mass Spectrometry

Đustebek, Jasmina B.; Veljković, Miomir V.; Veličković, Suzana

(2013)

TY  - JOUR
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Veličković, Suzana
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5370
AB  - The process of generating dilithium fluoride ion from the samples of LiF, LiF/C-60, LIF/LiI, and LIF/LiI/C-60 using a double and a triple filament thermal ionization source for a mass spectrometer was studied. This cluster belong to the superalkali class that can form the building block for new nanoscale cluster assembled materials. The results show that in the case of the double filament thermal source when the solution of LiF/C60 was used the Li2F+ ion was detected in the longest temperature range of the evaporation filament. On the other hand, the best abundances of Li2F+ ion was obtained when the solution of LiF/C-60 were loaded on the evaporation filaments of the triple filament thermal ionization source. It has also been found that several different processes are involved in the generation of Li2F+ by the triple filament thermal source: (1) Li2F2 - GT Li2F+ + F; (2) Li+ + LiF - GT Li2F+; and (3) Li+(from LiI) + LiF - GT Li2F+. Reaction (1) is dominant at the low temperatures of evaporation filament (Te), reaction (2) it appears at Te GT 1000 degrees K, for all four above mentioned samples. Reaction (3) appears when the samples were the solution of LiF/LiI and LiF/LiI/C-60 at the high temperature of the evaporation filament.
T2  - Digest Journal of Nanomaterials and Biostructures
T1  - Major Factors Affecting the Emission of Dilithium-Fluoride Cluster Ion in Thermal Ionization Mass Spectrometry
VL  - 8
IS  - 1
SP  - 359
EP  - 366
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5370
ER  - 
@article{
author = "Đustebek, Jasmina B. and Veljković, Miomir V. and Veličković, Suzana",
year = "2013",
abstract = "The process of generating dilithium fluoride ion from the samples of LiF, LiF/C-60, LIF/LiI, and LIF/LiI/C-60 using a double and a triple filament thermal ionization source for a mass spectrometer was studied. This cluster belong to the superalkali class that can form the building block for new nanoscale cluster assembled materials. The results show that in the case of the double filament thermal source when the solution of LiF/C60 was used the Li2F+ ion was detected in the longest temperature range of the evaporation filament. On the other hand, the best abundances of Li2F+ ion was obtained when the solution of LiF/C-60 were loaded on the evaporation filaments of the triple filament thermal ionization source. It has also been found that several different processes are involved in the generation of Li2F+ by the triple filament thermal source: (1) Li2F2 - GT Li2F+ + F; (2) Li+ + LiF - GT Li2F+; and (3) Li+(from LiI) + LiF - GT Li2F+. Reaction (1) is dominant at the low temperatures of evaporation filament (Te), reaction (2) it appears at Te GT 1000 degrees K, for all four above mentioned samples. Reaction (3) appears when the samples were the solution of LiF/LiI and LiF/LiI/C-60 at the high temperature of the evaporation filament.",
journal = "Digest Journal of Nanomaterials and Biostructures",
title = "Major Factors Affecting the Emission of Dilithium-Fluoride Cluster Ion in Thermal Ionization Mass Spectrometry",
volume = "8",
number = "1",
pages = "359-366",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5370"
}
Đustebek, J. B., Veljković, M. V.,& Veličković, S.. (2013). Major Factors Affecting the Emission of Dilithium-Fluoride Cluster Ion in Thermal Ionization Mass Spectrometry. in Digest Journal of Nanomaterials and Biostructures, 8(1), 359-366.
https://hdl.handle.net/21.15107/rcub_vinar_5370
Đustebek JB, Veljković MV, Veličković S. Major Factors Affecting the Emission of Dilithium-Fluoride Cluster Ion in Thermal Ionization Mass Spectrometry. in Digest Journal of Nanomaterials and Biostructures. 2013;8(1):359-366.
https://hdl.handle.net/21.15107/rcub_vinar_5370 .
Đustebek, Jasmina B., Veljković, Miomir V., Veličković, Suzana, "Major Factors Affecting the Emission of Dilithium-Fluoride Cluster Ion in Thermal Ionization Mass Spectrometry" in Digest Journal of Nanomaterials and Biostructures, 8, no. 1 (2013):359-366,
https://hdl.handle.net/21.15107/rcub_vinar_5370 .

Formation and ionization energies of small chlorine-doped lithium clusters by thermal ionization mass spectrometry

Veličković, Suzana; Đustebek, Jasmina B.; Veljković, Filip M.; Radak, Bojan; Veljković, Miomir V.

(2012)

TY  - JOUR
AU  - Veličković, Suzana
AU  - Đustebek, Jasmina B.
AU  - Veljković, Filip M.
AU  - Radak, Bojan
AU  - Veljković, Miomir V.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4666
AB  - RATIONALE: Theoretical calculations have shown that the first ionization energy of clusters of the type LinCl (n GT = 2), with more than eight valent electrons, is lower than that of alkali metal atoms; hence they are named superalkali. Superalkali clusters can mimic the chemical behavior of alkali metals and may be used as building blocks of new cluster-assembled materials. There is currently no reliable experimental proof of this kind of clusters and such proof is required. METHODS: The LinCl (n = 2-6) clusters were produced by a thermal ionization source of modified design, and mass selected by a magnetic-sector mass spectrometer. The modification pertains to the replacement of the side filaments by a cylinder in the triple-filament thermal ionization source. The sample, which is LiCl salt, was pressed into a ring and placed on the inner wall of the cylinder. RESULTS: It was observed that the ions of clusters with an even number of lithium atoms (Li2Cl+, Li4Cl+, Li6Cl+) are more stable than the odd-numbered ones (Li5Cl+, Li3Cl+). The ionization energies were determined to be 3.98 +/- 0.25 eV for Li2Cl, 4.10 +/- 0.25 eV for Li3Cl, 3.90 +/- 0.25 eV for Li4Cl, 4.01 +/- 0.25 eV for Li5Cl, and 4.09 +/- 0.25 eV for Li6Cl. The presence of a halogen atom reduces the ionization energy of the metal clusters. CONCLUSIONS: The thermal ionization source of modified design presents a suitable simple way to obtaining and measuring the ionization energies of very small lithium monochloride clusters. Clusters LinCl, n = 4 to 6, were detected for the first time. Copyright (C) 2012 John Wiley and Sons, Ltd.
T2  - Rapid Communications in Mass Spectrometry
T1  - Formation and ionization energies of small chlorine-doped lithium clusters by thermal ionization mass spectrometry
VL  - 26
IS  - 4
SP  - 443
EP  - 448
DO  - 10.1002/rcm.6122
ER  - 
@article{
author = "Veličković, Suzana and Đustebek, Jasmina B. and Veljković, Filip M. and Radak, Bojan and Veljković, Miomir V.",
year = "2012",
abstract = "RATIONALE: Theoretical calculations have shown that the first ionization energy of clusters of the type LinCl (n GT = 2), with more than eight valent electrons, is lower than that of alkali metal atoms; hence they are named superalkali. Superalkali clusters can mimic the chemical behavior of alkali metals and may be used as building blocks of new cluster-assembled materials. There is currently no reliable experimental proof of this kind of clusters and such proof is required. METHODS: The LinCl (n = 2-6) clusters were produced by a thermal ionization source of modified design, and mass selected by a magnetic-sector mass spectrometer. The modification pertains to the replacement of the side filaments by a cylinder in the triple-filament thermal ionization source. The sample, which is LiCl salt, was pressed into a ring and placed on the inner wall of the cylinder. RESULTS: It was observed that the ions of clusters with an even number of lithium atoms (Li2Cl+, Li4Cl+, Li6Cl+) are more stable than the odd-numbered ones (Li5Cl+, Li3Cl+). The ionization energies were determined to be 3.98 +/- 0.25 eV for Li2Cl, 4.10 +/- 0.25 eV for Li3Cl, 3.90 +/- 0.25 eV for Li4Cl, 4.01 +/- 0.25 eV for Li5Cl, and 4.09 +/- 0.25 eV for Li6Cl. The presence of a halogen atom reduces the ionization energy of the metal clusters. CONCLUSIONS: The thermal ionization source of modified design presents a suitable simple way to obtaining and measuring the ionization energies of very small lithium monochloride clusters. Clusters LinCl, n = 4 to 6, were detected for the first time. Copyright (C) 2012 John Wiley and Sons, Ltd.",
journal = "Rapid Communications in Mass Spectrometry",
title = "Formation and ionization energies of small chlorine-doped lithium clusters by thermal ionization mass spectrometry",
volume = "26",
number = "4",
pages = "443-448",
doi = "10.1002/rcm.6122"
}
Veličković, S., Đustebek, J. B., Veljković, F. M., Radak, B.,& Veljković, M. V.. (2012). Formation and ionization energies of small chlorine-doped lithium clusters by thermal ionization mass spectrometry. in Rapid Communications in Mass Spectrometry, 26(4), 443-448.
https://doi.org/10.1002/rcm.6122
Veličković S, Đustebek JB, Veljković FM, Radak B, Veljković MV. Formation and ionization energies of small chlorine-doped lithium clusters by thermal ionization mass spectrometry. in Rapid Communications in Mass Spectrometry. 2012;26(4):443-448.
doi:10.1002/rcm.6122 .
Veličković, Suzana, Đustebek, Jasmina B., Veljković, Filip M., Radak, Bojan, Veljković, Miomir V., "Formation and ionization energies of small chlorine-doped lithium clusters by thermal ionization mass spectrometry" in Rapid Communications in Mass Spectrometry, 26, no. 4 (2012):443-448,
https://doi.org/10.1002/rcm.6122 . .
1
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20

Formation of positive cluster ions LinBr (n=2-7) and ionization energies studied by thermal ionization mass spectrometry

Veličković, Suzana; Đustebek, Jasmina B.; Veljković, Filip M.; Veljković, Miomir V.

(2012)

TY  - JOUR
AU  - Veličković, Suzana
AU  - Đustebek, Jasmina B.
AU  - Veljković, Filip M.
AU  - Veljković, Miomir V.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4898
AB  - Clusters of the type LinX (X = halides) can be considered as potential building blocks of cluster-assembly materials. In this work, LinBr (n = 2-7) clusters were obtained by a thermal ionization source of modified design and selected by a magnetic sector mass spectrometer. Positive ions of the LinBr (n = 4-7) cluster were detected for the first time. The order of ion intensities was Li2Br+ Li4Br+ GT Li5Br+ GT Li6Br+ GT Li3Br+. The ionization energies (IEs) were measured and found to be 3.95 +/- 0.20 eV for Li2Br, 3.92 +/- 0.20 eV for Li3Br, 3.93 +/- 0.20 eV for Li4Br, 4.08 +/- 0.20 eV for Li5Br, 4.14 +/- 0.20 eV for Li6Br and 4.19 +/- 0.20 eV for Li7Br. All of these clusters have a much lower ionization potential than that of the lithium atom, so they belong to the superalkali class. The IEs of LinBr (n = 2-4) are slightly lower than those in the corresponding small Li-n or LinH clusters, whereas the IEs of LinBr are very similar to those of Li-n or LinH for n = 5 and 6. The thermal ionization source of modified design is an important means for simultaneously obtaining and measuring the IEs of LinBr (n = 2-7) clusters (because their ions are thermodynamically stable with respect to the loss of lithium atoms in the gas phase) and increasingly contributes toward the development of clusters for practical applications. Copyright (C) 2012 John Wiley and Sons, Ltd.
T2  - Journal of Mass Spectrometry
T1  - Formation of positive cluster ions LinBr (n=2-7) and ionization energies studied by thermal ionization mass spectrometry
VL  - 47
IS  - 5
SP  - 627
EP  - 631
DO  - 10.1002/jms.3001
ER  - 
@article{
author = "Veličković, Suzana and Đustebek, Jasmina B. and Veljković, Filip M. and Veljković, Miomir V.",
year = "2012",
abstract = "Clusters of the type LinX (X = halides) can be considered as potential building blocks of cluster-assembly materials. In this work, LinBr (n = 2-7) clusters were obtained by a thermal ionization source of modified design and selected by a magnetic sector mass spectrometer. Positive ions of the LinBr (n = 4-7) cluster were detected for the first time. The order of ion intensities was Li2Br+ Li4Br+ GT Li5Br+ GT Li6Br+ GT Li3Br+. The ionization energies (IEs) were measured and found to be 3.95 +/- 0.20 eV for Li2Br, 3.92 +/- 0.20 eV for Li3Br, 3.93 +/- 0.20 eV for Li4Br, 4.08 +/- 0.20 eV for Li5Br, 4.14 +/- 0.20 eV for Li6Br and 4.19 +/- 0.20 eV for Li7Br. All of these clusters have a much lower ionization potential than that of the lithium atom, so they belong to the superalkali class. The IEs of LinBr (n = 2-4) are slightly lower than those in the corresponding small Li-n or LinH clusters, whereas the IEs of LinBr are very similar to those of Li-n or LinH for n = 5 and 6. The thermal ionization source of modified design is an important means for simultaneously obtaining and measuring the IEs of LinBr (n = 2-7) clusters (because their ions are thermodynamically stable with respect to the loss of lithium atoms in the gas phase) and increasingly contributes toward the development of clusters for practical applications. Copyright (C) 2012 John Wiley and Sons, Ltd.",
journal = "Journal of Mass Spectrometry",
title = "Formation of positive cluster ions LinBr (n=2-7) and ionization energies studied by thermal ionization mass spectrometry",
volume = "47",
number = "5",
pages = "627-631",
doi = "10.1002/jms.3001"
}
Veličković, S., Đustebek, J. B., Veljković, F. M.,& Veljković, M. V.. (2012). Formation of positive cluster ions LinBr (n=2-7) and ionization energies studied by thermal ionization mass spectrometry. in Journal of Mass Spectrometry, 47(5), 627-631.
https://doi.org/10.1002/jms.3001
Veličković S, Đustebek JB, Veljković FM, Veljković MV. Formation of positive cluster ions LinBr (n=2-7) and ionization energies studied by thermal ionization mass spectrometry. in Journal of Mass Spectrometry. 2012;47(5):627-631.
doi:10.1002/jms.3001 .
Veličković, Suzana, Đustebek, Jasmina B., Veljković, Filip M., Veljković, Miomir V., "Formation of positive cluster ions LinBr (n=2-7) and ionization energies studied by thermal ionization mass spectrometry" in Journal of Mass Spectrometry, 47, no. 5 (2012):627-631,
https://doi.org/10.1002/jms.3001 . .
18
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Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry

Veljković, Filip M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Veličković, Suzana; Perić-Grujić, Aleksandra A.

(2012)

TY  - JOUR
AU  - Veljković, Filip M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Veličković, Suzana
AU  - Perić-Grujić, Aleksandra A.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4942
AB  - RATIONALE The very small clusters of the type KnF are of particular importance since their first ionization energies (IEs) are lower than those of the alkali metal atoms. Theoretical calculation has demonstrated that this kind of cluster represents a potential building block for cluster-assembly materials with unique structural, electronic, optical, magnetic, and thermodynamic properties. To date, however, there have been no experimental results on the IEs of KnF (n GT 2) clusters. METHOD KnF (n?=?26) clusters were produced by the evaporation of a solid potassium fluoride salt using a modified thermal ionization source of modified design, and mass selected by a magnetic sector mass spectrometer where their IEs were determined. RESULTS Clusters KnF (n?=?36) were detected for the first time. The order of the ion intensities was K2F+ GT ? GT ?K4F+ GT ? GT ?K3F+K6F+? GT ?K5F+. The determined IEs were 3.99 +/- 0.20?eV for K2F, 4.16 +/- 0.20?eV for K3F, 4.27 +/- 0.20?eV for K4F, 4.22 +/- 0.20?eV for K5F, and 4.31 +/- 0.20?eV for K6F. The IEs of KnF increase slightly with the increase in potassium atom number from 2 to 6. We also observed that the presence of a fluorine atom leads to increasing ionization energy of bare metal potassium clusters. CONCLUSIONS The modified thermal ionization source provides an efficient way of obtaining the fluorine-doped potassium clusters. These results also present experimental proof that KnF (n?=?26) clusters belong to the group of superalkali species. Copyright (C)2012 John Wiley and Sons, Ltd.
T2  - Rapid Communications in Mass Spectrometry
T1  - Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry
VL  - 26
IS  - 16
SP  - 1761
EP  - 1766
DO  - 10.1002/rcm.6284
ER  - 
@article{
author = "Veljković, Filip M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Veličković, Suzana and Perić-Grujić, Aleksandra A.",
year = "2012",
abstract = "RATIONALE The very small clusters of the type KnF are of particular importance since their first ionization energies (IEs) are lower than those of the alkali metal atoms. Theoretical calculation has demonstrated that this kind of cluster represents a potential building block for cluster-assembly materials with unique structural, electronic, optical, magnetic, and thermodynamic properties. To date, however, there have been no experimental results on the IEs of KnF (n GT 2) clusters. METHOD KnF (n?=?26) clusters were produced by the evaporation of a solid potassium fluoride salt using a modified thermal ionization source of modified design, and mass selected by a magnetic sector mass spectrometer where their IEs were determined. RESULTS Clusters KnF (n?=?36) were detected for the first time. The order of the ion intensities was K2F+ GT ? GT ?K4F+ GT ? GT ?K3F+K6F+? GT ?K5F+. The determined IEs were 3.99 +/- 0.20?eV for K2F, 4.16 +/- 0.20?eV for K3F, 4.27 +/- 0.20?eV for K4F, 4.22 +/- 0.20?eV for K5F, and 4.31 +/- 0.20?eV for K6F. The IEs of KnF increase slightly with the increase in potassium atom number from 2 to 6. We also observed that the presence of a fluorine atom leads to increasing ionization energy of bare metal potassium clusters. CONCLUSIONS The modified thermal ionization source provides an efficient way of obtaining the fluorine-doped potassium clusters. These results also present experimental proof that KnF (n?=?26) clusters belong to the group of superalkali species. Copyright (C)2012 John Wiley and Sons, Ltd.",
journal = "Rapid Communications in Mass Spectrometry",
title = "Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry",
volume = "26",
number = "16",
pages = "1761-1766",
doi = "10.1002/rcm.6284"
}
Veljković, F. M., Đustebek, J. B., Veljković, M. V., Veličković, S.,& Perić-Grujić, A. A.. (2012). Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry. in Rapid Communications in Mass Spectrometry, 26(16), 1761-1766.
https://doi.org/10.1002/rcm.6284
Veljković FM, Đustebek JB, Veljković MV, Veličković S, Perić-Grujić AA. Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry. in Rapid Communications in Mass Spectrometry. 2012;26(16):1761-1766.
doi:10.1002/rcm.6284 .
Veljković, Filip M., Đustebek, Jasmina B., Veljković, Miomir V., Veličković, Suzana, Perić-Grujić, Aleksandra A., "Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry" in Rapid Communications in Mass Spectrometry, 26, no. 16 (2012):1761-1766,
https://doi.org/10.1002/rcm.6284 . .
1
4
3
4

Study of small chlorine-doped potassium clusters by thermal ionization mass spectrometry

Veljković, Filip M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Perić-Grujić, Aleksandra A.; Veličković, Suzana

(2012)

TY  - JOUR
AU  - Veljković, Filip M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Perić-Grujić, Aleksandra A.
AU  - Veličković, Suzana
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5164
AB  - The theoretical calculations have predicted that nonmetal-doped potassium clusters can be used in the synthesis of a new class of charge-transfer salts which can be considered as potential building blocks for the assembly of novel nanostructured material. In this work, KnCl (n?=?26) and KnCln-1 (n?=?3 and 4) clusters were produced by vaporization of a solid potassium chloride salt in a thermal ionization mass spectrometry. The ionization energies (IEs) were measured, and found to be 3.64?+/-?0.20?eV for K2Cl, 3.67?+/-?0.20?eV for K3Cl, 3.62?+/-?0.20?eV for K4Cl, 3.57?+/-?0.20?eV for K5Cl, 3.69?+/-?0.20?eV for K6Cl, 3.71?+/-?0.20?eV for K3Cl2 and 3.72?+/-?0.20?eV for K4Cl3. The KnCl+ (n?=?36) clusters were detected for the first time in a cluster beam generated by the thermal ionization source of modified design. Also, this work is the first to report experimentally obtained values of IEs for KnCl+ (n?=?36) and KnCln-1+ (n?=?3 and 4) clusters. The ionization energies for KnCl+ and KnCln-1+ clusters are much lower than the 4.34?eV of the potassium atom; hence, these clusters should be classified as superalkali species. Copyright (c) 2012 John Wiley and Sons, Ltd.
T2  - Journal of Mass Spectrometry
T1  - Study of small chlorine-doped potassium clusters by thermal ionization mass spectrometry
VL  - 47
IS  - 11
SP  - 1495
EP  - 1499
DO  - 10.1002/jms.3076
ER  - 
@article{
author = "Veljković, Filip M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Perić-Grujić, Aleksandra A. and Veličković, Suzana",
year = "2012",
abstract = "The theoretical calculations have predicted that nonmetal-doped potassium clusters can be used in the synthesis of a new class of charge-transfer salts which can be considered as potential building blocks for the assembly of novel nanostructured material. In this work, KnCl (n?=?26) and KnCln-1 (n?=?3 and 4) clusters were produced by vaporization of a solid potassium chloride salt in a thermal ionization mass spectrometry. The ionization energies (IEs) were measured, and found to be 3.64?+/-?0.20?eV for K2Cl, 3.67?+/-?0.20?eV for K3Cl, 3.62?+/-?0.20?eV for K4Cl, 3.57?+/-?0.20?eV for K5Cl, 3.69?+/-?0.20?eV for K6Cl, 3.71?+/-?0.20?eV for K3Cl2 and 3.72?+/-?0.20?eV for K4Cl3. The KnCl+ (n?=?36) clusters were detected for the first time in a cluster beam generated by the thermal ionization source of modified design. Also, this work is the first to report experimentally obtained values of IEs for KnCl+ (n?=?36) and KnCln-1+ (n?=?3 and 4) clusters. The ionization energies for KnCl+ and KnCln-1+ clusters are much lower than the 4.34?eV of the potassium atom; hence, these clusters should be classified as superalkali species. Copyright (c) 2012 John Wiley and Sons, Ltd.",
journal = "Journal of Mass Spectrometry",
title = "Study of small chlorine-doped potassium clusters by thermal ionization mass spectrometry",
volume = "47",
number = "11",
pages = "1495-1499",
doi = "10.1002/jms.3076"
}
Veljković, F. M., Đustebek, J. B., Veljković, M. V., Perić-Grujić, A. A.,& Veličković, S.. (2012). Study of small chlorine-doped potassium clusters by thermal ionization mass spectrometry. in Journal of Mass Spectrometry, 47(11), 1495-1499.
https://doi.org/10.1002/jms.3076
Veljković FM, Đustebek JB, Veljković MV, Perić-Grujić AA, Veličković S. Study of small chlorine-doped potassium clusters by thermal ionization mass spectrometry. in Journal of Mass Spectrometry. 2012;47(11):1495-1499.
doi:10.1002/jms.3076 .
Veljković, Filip M., Đustebek, Jasmina B., Veljković, Miomir V., Perić-Grujić, Aleksandra A., Veličković, Suzana, "Study of small chlorine-doped potassium clusters by thermal ionization mass spectrometry" in Journal of Mass Spectrometry, 47, no. 11 (2012):1495-1499,
https://doi.org/10.1002/jms.3076 . .
1
7
7
8

Production of Heterogeneous Superalkali Clusters Linf (N=2-6) By Knudsen - Cell Mass Spectrometry

Đustebek, Jasmina B.; Veličković, Suzana; Veljković, Filip M.; Veljković, Miomir V.

(2012)

TY  - JOUR
AU  - Đustebek, Jasmina B.
AU  - Veličković, Suzana
AU  - Veljković, Filip M.
AU  - Veljković, Miomir V.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5228
AB  - The superalkali clusters are important because they can be considered as potential building block for the assembly of novel nanostructured materials with unique structural, electronic, optical, magnetic, and thermodynamic properties. We have modified and used the Knudsen cell mass spectrometer in order to obtain and measurement of the ionization potentials of the superalkali clusters. In this work the clusters LinF (n = 2 - 6) have produces in the vapor over a mixture of lithium fluoride and lithium iodide by means of Knudsen cell which is placed into ionization chamber of the magnetic sector mass spectrometer. The simultaneous production and mass spectrometric detection of the ionic of clusters provide information on the conditions of formation and the distribution of these ion species. It is observed that the ions of clusters with an even numbered of lithium atoms are more stable than the ions of clusters with an odd numbered of lithium atoms. The clusters Li5F and Li6F were detected experimentally for the first time with their ionization energies of (4.29 +/- 0.25) eV, and (4.24 +/- 0.25) eV, respectively.
T2  - Digest Journal of Nanomaterials and Biostructures
T1  - Production of Heterogeneous Superalkali Clusters Linf (N=2-6) By Knudsen - Cell Mass Spectrometry
VL  - 7
IS  - 4
SP  - 1365
EP  - 1372
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5228
ER  - 
@article{
author = "Đustebek, Jasmina B. and Veličković, Suzana and Veljković, Filip M. and Veljković, Miomir V.",
year = "2012",
abstract = "The superalkali clusters are important because they can be considered as potential building block for the assembly of novel nanostructured materials with unique structural, electronic, optical, magnetic, and thermodynamic properties. We have modified and used the Knudsen cell mass spectrometer in order to obtain and measurement of the ionization potentials of the superalkali clusters. In this work the clusters LinF (n = 2 - 6) have produces in the vapor over a mixture of lithium fluoride and lithium iodide by means of Knudsen cell which is placed into ionization chamber of the magnetic sector mass spectrometer. The simultaneous production and mass spectrometric detection of the ionic of clusters provide information on the conditions of formation and the distribution of these ion species. It is observed that the ions of clusters with an even numbered of lithium atoms are more stable than the ions of clusters with an odd numbered of lithium atoms. The clusters Li5F and Li6F were detected experimentally for the first time with their ionization energies of (4.29 +/- 0.25) eV, and (4.24 +/- 0.25) eV, respectively.",
journal = "Digest Journal of Nanomaterials and Biostructures",
title = "Production of Heterogeneous Superalkali Clusters Linf (N=2-6) By Knudsen - Cell Mass Spectrometry",
volume = "7",
number = "4",
pages = "1365-1372",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5228"
}
Đustebek, J. B., Veličković, S., Veljković, F. M.,& Veljković, M. V.. (2012). Production of Heterogeneous Superalkali Clusters Linf (N=2-6) By Knudsen - Cell Mass Spectrometry. in Digest Journal of Nanomaterials and Biostructures, 7(4), 1365-1372.
https://hdl.handle.net/21.15107/rcub_vinar_5228
Đustebek JB, Veličković S, Veljković FM, Veljković MV. Production of Heterogeneous Superalkali Clusters Linf (N=2-6) By Knudsen - Cell Mass Spectrometry. in Digest Journal of Nanomaterials and Biostructures. 2012;7(4):1365-1372.
https://hdl.handle.net/21.15107/rcub_vinar_5228 .
Đustebek, Jasmina B., Veličković, Suzana, Veljković, Filip M., Veljković, Miomir V., "Production of Heterogeneous Superalkali Clusters Linf (N=2-6) By Knudsen - Cell Mass Spectrometry" in Digest Journal of Nanomaterials and Biostructures, 7, no. 4 (2012):1365-1372,
https://hdl.handle.net/21.15107/rcub_vinar_5228 .
12
19

Mass spectrometric study of the structures and ionization potential of LinI (n=2, 4, 6) clusters

Đustebek, Jasmina B.; Veličković, Suzana; Jerosimic, Stanka; Veljković, Miomir V.

(2011)

TY  - JOUR
AU  - Đustebek, Jasmina B.
AU  - Veličković, Suzana
AU  - Jerosimic, Stanka
AU  - Veljković, Miomir V.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4424
AB  - We report a combined experimental and theoretical investigation of small heterogeneous clusters of lithium iodide. Apparatus based on magnetic sector instrument, where Knudsen cell is placed into the ionization chamber, provides suitable conditions for the detection of both the ionic and neutral components of LinI (n = 2, 4, 6) clusters. The clusters Li4I and Li6I were detected experimentally for the first time. Ionization potentials determined by the electron impact ionization mass spectrometry were (4.69 +/- 0.25) eV for Li2I, (4.86 +/- 0.25) eV for Li4I and (4.96 +/- 0.25) eV for Li6I. The ionization potential of Li2I corresponds to previous experimental data obtained by thermal ionization mass spectrometry. The first theoretical data of the ionization potential and structure of the above mentioned clusters are presented in this work. A comparison with the experimental ionization potentials provides evidence for the theoretically calculated geometrical structures of the small heterogeneous clusters of lithium iodide.
T2  - Journal of Analytical Atomic Spectrometry
T1  - Mass spectrometric study of the structures and ionization potential of LinI (n=2, 4, 6) clusters
VL  - 26
IS  - 8
SP  - 1641
EP  - 1647
DO  - 10.1039/c1ja10078e
ER  - 
@article{
author = "Đustebek, Jasmina B. and Veličković, Suzana and Jerosimic, Stanka and Veljković, Miomir V.",
year = "2011",
abstract = "We report a combined experimental and theoretical investigation of small heterogeneous clusters of lithium iodide. Apparatus based on magnetic sector instrument, where Knudsen cell is placed into the ionization chamber, provides suitable conditions for the detection of both the ionic and neutral components of LinI (n = 2, 4, 6) clusters. The clusters Li4I and Li6I were detected experimentally for the first time. Ionization potentials determined by the electron impact ionization mass spectrometry were (4.69 +/- 0.25) eV for Li2I, (4.86 +/- 0.25) eV for Li4I and (4.96 +/- 0.25) eV for Li6I. The ionization potential of Li2I corresponds to previous experimental data obtained by thermal ionization mass spectrometry. The first theoretical data of the ionization potential and structure of the above mentioned clusters are presented in this work. A comparison with the experimental ionization potentials provides evidence for the theoretically calculated geometrical structures of the small heterogeneous clusters of lithium iodide.",
journal = "Journal of Analytical Atomic Spectrometry",
title = "Mass spectrometric study of the structures and ionization potential of LinI (n=2, 4, 6) clusters",
volume = "26",
number = "8",
pages = "1641-1647",
doi = "10.1039/c1ja10078e"
}
Đustebek, J. B., Veličković, S., Jerosimic, S.,& Veljković, M. V.. (2011). Mass spectrometric study of the structures and ionization potential of LinI (n=2, 4, 6) clusters. in Journal of Analytical Atomic Spectrometry, 26(8), 1641-1647.
https://doi.org/10.1039/c1ja10078e
Đustebek JB, Veličković S, Jerosimic S, Veljković MV. Mass spectrometric study of the structures and ionization potential of LinI (n=2, 4, 6) clusters. in Journal of Analytical Atomic Spectrometry. 2011;26(8):1641-1647.
doi:10.1039/c1ja10078e .
Đustebek, Jasmina B., Veličković, Suzana, Jerosimic, Stanka, Veljković, Miomir V., "Mass spectrometric study of the structures and ionization potential of LinI (n=2, 4, 6) clusters" in Journal of Analytical Atomic Spectrometry, 26, no. 8 (2011):1641-1647,
https://doi.org/10.1039/c1ja10078e . .
11
13
13

Electron impact ionisation of encapsulated Tc-99m"C-60 and Tc-99m"C-70

Đustebek, Jasmina B.; Đorđević, Vesna R.; Cvetićanin, Jelena M.; Veličković, Suzana; Veljković, Miomir V.; Nešković, Olivera M.; Rakočević, Zlatko Lj.; Bibić, Nataša M.

(2010)

TY  - JOUR
AU  - Đustebek, Jasmina B.
AU  - Đorđević, Vesna R.
AU  - Cvetićanin, Jelena M.
AU  - Veličković, Suzana
AU  - Veljković, Miomir V.
AU  - Nešković, Olivera M.
AU  - Rakočević, Zlatko Lj.
AU  - Bibić, Nataša M.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3970
AB  - The present study shows simultaneous surface ionisation and electron impact ionisation during the formation and investigation of endohedral fullerenes Tc-99m"C-60 and Tc-99m"C-70. The endohedral fullerenes were generated using a mass spectrometer with a triple rhenium filament as an ion source. The ionisation energies (IE) determined were: 8.52 +/- 0.25 eV for Tc-99m"C-60 and 9.57 +/- 0.25 eV for Tc-99m"C-70.
T2  - Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms
T1  - Electron impact ionisation of encapsulated Tc-99m"C-60 and Tc-99m"C-70
VL  - 268
IS  - 5
SP  - 466
EP  - 469
DO  - 10.1016/j.nimb.2009.11.002
ER  - 
@article{
author = "Đustebek, Jasmina B. and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Veličković, Suzana and Veljković, Miomir V. and Nešković, Olivera M. and Rakočević, Zlatko Lj. and Bibić, Nataša M.",
year = "2010",
abstract = "The present study shows simultaneous surface ionisation and electron impact ionisation during the formation and investigation of endohedral fullerenes Tc-99m"C-60 and Tc-99m"C-70. The endohedral fullerenes were generated using a mass spectrometer with a triple rhenium filament as an ion source. The ionisation energies (IE) determined were: 8.52 +/- 0.25 eV for Tc-99m"C-60 and 9.57 +/- 0.25 eV for Tc-99m"C-70.",
journal = "Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms",
title = "Electron impact ionisation of encapsulated Tc-99m"C-60 and Tc-99m"C-70",
volume = "268",
number = "5",
pages = "466-469",
doi = "10.1016/j.nimb.2009.11.002"
}
Đustebek, J. B., Đorđević, V. R., Cvetićanin, J. M., Veličković, S., Veljković, M. V., Nešković, O. M., Rakočević, Z. Lj.,& Bibić, N. M.. (2010). Electron impact ionisation of encapsulated Tc-99m"C-60 and Tc-99m"C-70. in Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms, 268(5), 466-469.
https://doi.org/10.1016/j.nimb.2009.11.002
Đustebek JB, Đorđević VR, Cvetićanin JM, Veličković S, Veljković MV, Nešković OM, Rakočević ZL, Bibić NM. Electron impact ionisation of encapsulated Tc-99m"C-60 and Tc-99m"C-70. in Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms. 2010;268(5):466-469.
doi:10.1016/j.nimb.2009.11.002 .
Đustebek, Jasmina B., Đorđević, Vesna R., Cvetićanin, Jelena M., Veličković, Suzana, Veljković, Miomir V., Nešković, Olivera M., Rakočević, Zlatko Lj., Bibić, Nataša M., "Electron impact ionisation of encapsulated Tc-99m"C-60 and Tc-99m"C-70" in Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms, 268, no. 5 (2010):466-469,
https://doi.org/10.1016/j.nimb.2009.11.002 . .
1
1
1

TIMS and MALDI TOF of endohedral Li-n"C-70 (n=1-3) metallofullerenes

Cvetićanin, Jelena M.; Veličković, Suzana; Đorđević, Vesna R.; Đustebek, Jasmina B.; Veljković, Miomir V.; Perić-Grujić, Aleksandra A.; Nešković, Olivera M.

(2008)

TY  - JOUR
AU  - Cvetićanin, Jelena M.
AU  - Veličković, Suzana
AU  - Đorđević, Vesna R.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Perić-Grujić, Aleksandra A.
AU  - Nešković, Olivera M.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3472
AB  - Using the ion implantation technique (introducing negatively charged fullerene into a low temperature lithium plasma column by a strong axial magnetic field) endohedral fullerenes Li"C-70, Li-2"C-70 and Li-3"C-70 were produced. Mass spectral studies (both TIMS-thermal ionization mass spectrometry and MALDI TOF MS - matrix assisted laser desorption ionization time-of-flight mass spectrometry) of these endohedral fullerenes provided detailed structural and reactivity information about these unusual species. The fragmentation of the obtained ions is shown to be by a multiple C-2 loss (shrink-wrap mechanism). According to the fact that more atoms in the fullerene make the produced endohedral less stable, Li-3"C-70 shows a big degree of instability. The presence of Li-3"C-70 was observed on MALDI TOF MS.
T2  - Journal of Optoelectronics and Advanced Materials
T1  - TIMS and MALDI TOF of endohedral Li-n"C-70 (n=1-3) metallofullerenes
VL  - 10
IS  - 6
SP  - 1505
EP  - 1507
UR  - https://hdl.handle.net/21.15107/rcub_vinar_3472
ER  - 
@article{
author = "Cvetićanin, Jelena M. and Veličković, Suzana and Đorđević, Vesna R. and Đustebek, Jasmina B. and Veljković, Miomir V. and Perić-Grujić, Aleksandra A. and Nešković, Olivera M.",
year = "2008",
abstract = "Using the ion implantation technique (introducing negatively charged fullerene into a low temperature lithium plasma column by a strong axial magnetic field) endohedral fullerenes Li"C-70, Li-2"C-70 and Li-3"C-70 were produced. Mass spectral studies (both TIMS-thermal ionization mass spectrometry and MALDI TOF MS - matrix assisted laser desorption ionization time-of-flight mass spectrometry) of these endohedral fullerenes provided detailed structural and reactivity information about these unusual species. The fragmentation of the obtained ions is shown to be by a multiple C-2 loss (shrink-wrap mechanism). According to the fact that more atoms in the fullerene make the produced endohedral less stable, Li-3"C-70 shows a big degree of instability. The presence of Li-3"C-70 was observed on MALDI TOF MS.",
journal = "Journal of Optoelectronics and Advanced Materials",
title = "TIMS and MALDI TOF of endohedral Li-n"C-70 (n=1-3) metallofullerenes",
volume = "10",
number = "6",
pages = "1505-1507",
url = "https://hdl.handle.net/21.15107/rcub_vinar_3472"
}
Cvetićanin, J. M., Veličković, S., Đorđević, V. R., Đustebek, J. B., Veljković, M. V., Perić-Grujić, A. A.,& Nešković, O. M.. (2008). TIMS and MALDI TOF of endohedral Li-n"C-70 (n=1-3) metallofullerenes. in Journal of Optoelectronics and Advanced Materials, 10(6), 1505-1507.
https://hdl.handle.net/21.15107/rcub_vinar_3472
Cvetićanin JM, Veličković S, Đorđević VR, Đustebek JB, Veljković MV, Perić-Grujić AA, Nešković OM. TIMS and MALDI TOF of endohedral Li-n"C-70 (n=1-3) metallofullerenes. in Journal of Optoelectronics and Advanced Materials. 2008;10(6):1505-1507.
https://hdl.handle.net/21.15107/rcub_vinar_3472 .
Cvetićanin, Jelena M., Veličković, Suzana, Đorđević, Vesna R., Đustebek, Jasmina B., Veljković, Miomir V., Perić-Grujić, Aleksandra A., Nešković, Olivera M., "TIMS and MALDI TOF of endohedral Li-n"C-70 (n=1-3) metallofullerenes" in Journal of Optoelectronics and Advanced Materials, 10, no. 6 (2008):1505-1507,
https://hdl.handle.net/21.15107/rcub_vinar_3472 .
1

Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters

Veličković, Suzana; Đorđević, Vesna R.; Cvetićanin, Jelena M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Nešković, Olivera M.

(2008)

TY  - JOUR
AU  - Veličković, Suzana
AU  - Đorđević, Vesna R.
AU  - Cvetićanin, Jelena M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Nešković, Olivera M.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3547
AB  - Ionization energies of non-stoichiometric LinFn-1 (n =3,4, 6) clusters determined by a thermal ionization mass spectrometry (TIMS) were 4.2 +/- 0.2 eV for Li3F2, 4.3 +/- 0.2 eV for Li4F3 and 4.1 +/- 0.2 eV for Li6F5. The ionization energy of Li6F5 cluster was obtained experimentally for the first time. The ionization energies of Li3F2 and Li4F3 are in correlation with the results obtained by photoionization time-of-flight mass spectrometry. The determined ionization energies are comparable with theoretical ionization energies calculated by ab initio method. The theoretical predictions supported that the most stable isomers of a non-stoichiometric cluster LinFn-1 (n = 3 and n = 4) in which the excess electron localizes on a specific site have a segregated electronic structure composed of the metallic part and ionic part. (C) 2008 Elsevier Ltd. All rights reserved.
T2  - Vacuum
T1  - Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters
VL  - 83
IS  - 2
SP  - 378
EP  - 380
DO  - 10.1016/j.vacuum.2008.05.026
ER  - 
@article{
author = "Veličković, Suzana and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Nešković, Olivera M.",
year = "2008",
abstract = "Ionization energies of non-stoichiometric LinFn-1 (n =3,4, 6) clusters determined by a thermal ionization mass spectrometry (TIMS) were 4.2 +/- 0.2 eV for Li3F2, 4.3 +/- 0.2 eV for Li4F3 and 4.1 +/- 0.2 eV for Li6F5. The ionization energy of Li6F5 cluster was obtained experimentally for the first time. The ionization energies of Li3F2 and Li4F3 are in correlation with the results obtained by photoionization time-of-flight mass spectrometry. The determined ionization energies are comparable with theoretical ionization energies calculated by ab initio method. The theoretical predictions supported that the most stable isomers of a non-stoichiometric cluster LinFn-1 (n = 3 and n = 4) in which the excess electron localizes on a specific site have a segregated electronic structure composed of the metallic part and ionic part. (C) 2008 Elsevier Ltd. All rights reserved.",
journal = "Vacuum",
title = "Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters",
volume = "83",
number = "2",
pages = "378-380",
doi = "10.1016/j.vacuum.2008.05.026"
}
Veličković, S., Đorđević, V. R., Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V.,& Nešković, O. M.. (2008). Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters. in Vacuum, 83(2), 378-380.
https://doi.org/10.1016/j.vacuum.2008.05.026
Veličković S, Đorđević VR, Cvetićanin JM, Đustebek JB, Veljković MV, Nešković OM. Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters. in Vacuum. 2008;83(2):378-380.
doi:10.1016/j.vacuum.2008.05.026 .
Veličković, Suzana, Đorđević, Vesna R., Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Nešković, Olivera M., "Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters" in Vacuum, 83, no. 2 (2008):378-380,
https://doi.org/10.1016/j.vacuum.2008.05.026 . .
8
10
11

Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)

Veličković, Suzana; Koteski, Vasil J.; Belošević-Čavor, Jelena; Đorđević, Vesna R.; Cvetićanin, Jelena M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Nešković, Olivera M.

(2007)

TY  - JOUR
AU  - Veličković, Suzana
AU  - Koteski, Vasil J.
AU  - Belošević-Čavor, Jelena
AU  - Đorđević, Vesna R.
AU  - Cvetićanin, Jelena M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Nešković, Olivera M.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3323
AB  - Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 +/- 0.2 eV for Li2F, 4.0 +/- 0.2 eV for Li3F and 3.9 +/- 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2-4) molecules and their cations were also predicted. (C) 2007 Elsevier B.V. All rights reserved.
T2  - Chemical Physics Letters
T1  - Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)
VL  - 448
IS  - 4-6
SP  - 151
EP  - 155
DO  - 10.1016/j.cplett.2007.09.082
ER  - 
@article{
author = "Veličković, Suzana and Koteski, Vasil J. and Belošević-Čavor, Jelena and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Nešković, Olivera M.",
year = "2007",
abstract = "Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 +/- 0.2 eV for Li2F, 4.0 +/- 0.2 eV for Li3F and 3.9 +/- 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2-4) molecules and their cations were also predicted. (C) 2007 Elsevier B.V. All rights reserved.",
journal = "Chemical Physics Letters",
title = "Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)",
volume = "448",
number = "4-6",
pages = "151-155",
doi = "10.1016/j.cplett.2007.09.082"
}
Veličković, S., Koteski, V. J., Belošević-Čavor, J., Đorđević, V. R., Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V.,& Nešković, O. M.. (2007). Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4). in Chemical Physics Letters, 448(4-6), 151-155.
https://doi.org/10.1016/j.cplett.2007.09.082
Veličković S, Koteski VJ, Belošević-Čavor J, Đorđević VR, Cvetićanin JM, Đustebek JB, Veljković MV, Nešković OM. Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4). in Chemical Physics Letters. 2007;448(4-6):151-155.
doi:10.1016/j.cplett.2007.09.082 .
Veličković, Suzana, Koteski, Vasil J., Belošević-Čavor, Jelena, Đorđević, Vesna R., Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Nešković, Olivera M., "Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)" in Chemical Physics Letters, 448, no. 4-6 (2007):151-155,
https://doi.org/10.1016/j.cplett.2007.09.082 . .
58
51
64

Methods of purification and characterization of carbon nanotubes

Đorđević, Vesna R.; Đustebek, Jasmina B.; Cvetićanin, Jelena M.; Veličković, Suzana; Veljković, Miomir V.; Bokorov, M.; Babić-Stojić, Branka S.; Nešković, Olivera M.

(2006)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Đustebek, Jasmina B.
AU  - Cvetićanin, Jelena M.
AU  - Veličković, Suzana
AU  - Veljković, Miomir V.
AU  - Bokorov, M.
AU  - Babić-Stojić, Branka S.
AU  - Nešković, Olivera M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3065
AB  - In an attempt to purify MWNT in mild conditions, we have applied two different methods of purification. The first method of purifying the material was a combination of relatively often used methods, such as etching and acid treatment, and the second method was a relatively new one, using an organic polymer PmPV. Sample purity was obtained with SEM and ESR techniques.
T2  - Journal of Optoelectronics and Advanced Materials
T1  - Methods of purification and characterization of carbon nanotubes
VL  - 8
IS  - 4
SP  - 1631
EP  - 1634
UR  - https://hdl.handle.net/21.15107/rcub_vinar_3065
ER  - 
@article{
author = "Đorđević, Vesna R. and Đustebek, Jasmina B. and Cvetićanin, Jelena M. and Veličković, Suzana and Veljković, Miomir V. and Bokorov, M. and Babić-Stojić, Branka S. and Nešković, Olivera M.",
year = "2006",
abstract = "In an attempt to purify MWNT in mild conditions, we have applied two different methods of purification. The first method of purifying the material was a combination of relatively often used methods, such as etching and acid treatment, and the second method was a relatively new one, using an organic polymer PmPV. Sample purity was obtained with SEM and ESR techniques.",
journal = "Journal of Optoelectronics and Advanced Materials",
title = "Methods of purification and characterization of carbon nanotubes",
volume = "8",
number = "4",
pages = "1631-1634",
url = "https://hdl.handle.net/21.15107/rcub_vinar_3065"
}
Đorđević, V. R., Đustebek, J. B., Cvetićanin, J. M., Veličković, S., Veljković, M. V., Bokorov, M., Babić-Stojić, B. S.,& Nešković, O. M.. (2006). Methods of purification and characterization of carbon nanotubes. in Journal of Optoelectronics and Advanced Materials, 8(4), 1631-1634.
https://hdl.handle.net/21.15107/rcub_vinar_3065
Đorđević VR, Đustebek JB, Cvetićanin JM, Veličković S, Veljković MV, Bokorov M, Babić-Stojić BS, Nešković OM. Methods of purification and characterization of carbon nanotubes. in Journal of Optoelectronics and Advanced Materials. 2006;8(4):1631-1634.
https://hdl.handle.net/21.15107/rcub_vinar_3065 .
Đorđević, Vesna R., Đustebek, Jasmina B., Cvetićanin, Jelena M., Veličković, Suzana, Veljković, Miomir V., Bokorov, M., Babić-Stojić, Branka S., Nešković, Olivera M., "Methods of purification and characterization of carbon nanotubes" in Journal of Optoelectronics and Advanced Materials, 8, no. 4 (2006):1631-1634,
https://hdl.handle.net/21.15107/rcub_vinar_3065 .
30

Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules

Veličković, Suzana; Đorđević, Vesna R.; Cvetićanin, Jelena M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Nešković, Olivera M.

(2006)

TY  - JOUR
AU  - Veličković, Suzana
AU  - Đorđević, Vesna R.
AU  - Cvetićanin, Jelena M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Nešković, Olivera M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3102
AB  - Molecules of LinX (n = 2,3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C-60). The ionization energies obtained for Li2Cl, Li2Br and Li2I Molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV. respectively. The first ionization energy of Li2Cl is documented, while there are no literature data for the ionization energies of Li2Br and Li2I. The molecules of Li3Cl, Li3Br and Li3I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of LinX (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. Copyright (c) 2006 John Wiley and Sons, Ltd.
T2  - Rapid Communications in Mass Spectrometry
T1  - Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules
VL  - 20
IS  - 20
SP  - 3151
EP  - 3153
DO  - 10.1002/rcm.2712
ER  - 
@article{
author = "Veličković, Suzana and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Nešković, Olivera M.",
year = "2006",
abstract = "Molecules of LinX (n = 2,3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C-60). The ionization energies obtained for Li2Cl, Li2Br and Li2I Molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV. respectively. The first ionization energy of Li2Cl is documented, while there are no literature data for the ionization energies of Li2Br and Li2I. The molecules of Li3Cl, Li3Br and Li3I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of LinX (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. Copyright (c) 2006 John Wiley and Sons, Ltd.",
journal = "Rapid Communications in Mass Spectrometry",
title = "Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules",
volume = "20",
number = "20",
pages = "3151-3153",
doi = "10.1002/rcm.2712"
}
Veličković, S., Đorđević, V. R., Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V.,& Nešković, O. M.. (2006). Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules. in Rapid Communications in Mass Spectrometry, 20(20), 3151-3153.
https://doi.org/10.1002/rcm.2712
Veličković S, Đorđević VR, Cvetićanin JM, Đustebek JB, Veljković MV, Nešković OM. Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules. in Rapid Communications in Mass Spectrometry. 2006;20(20):3151-3153.
doi:10.1002/rcm.2712 .
Veličković, Suzana, Đorđević, Vesna R., Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Nešković, Olivera M., "Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules" in Rapid Communications in Mass Spectrometry, 20, no. 20 (2006):3151-3153,
https://doi.org/10.1002/rcm.2712 . .
32
32
35

Endohedral fullerenes of different elements

Cvetićanin, Jelena M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Veličković, Suzana; Đorđević, Vesna R.; Nešković, Olivera M.

(2006)

TY  - JOUR
AU  - Cvetićanin, Jelena M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Veličković, Suzana
AU  - Đorđević, Vesna R.
AU  - Nešković, Olivera M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3106
AB  - In this work we have studied the Li/C-60, Li/C-70, (99)mTc/C-60, (TC)-T-99/C-70, Gd/C-60, Gd/C-70, Nd/C-60, Nd/C-70, Y/C-60 and Y/C-70 systems by surface ionization mass spectrometry and investigated a possibility of the formation of endohedral fullerenes. Using the ion implantation technique (introducing negatively charged fullerene into a low temperature lithium, technetium, gadolinium, neodymium or yttrium plasma column by a strong axial magnetic field), the endohedral fullerenes Li congruent to C-60, Li congruent to C-70, Li-2 congruent to C-70, Tc-99m congruent to C-60, Tc-99m congruent to C-70, Gd congruent to C-60, Nd congruent to C-60, Y congruent to C-60, Gd congruent to C-70, Nd congruent to C-70 and Y congruent to C-70 have been produced and ionization energies were measured. Their existence was demonstrated through the high sensitivity, magnetic mass spectrometer (TIMS- thermal ionization mass spectrometer). These metallofullerenes were identified as stable molecules. The reaction of the obtained endohedral fullerenes with oxygen compounds (H2O, O-2 and N2O) has also been investigated. The result showed that these metallofullerenes are very inert to all of these gas phase oxygen-rich molecules, leading support to the endohedral structure of the metallofullerenes. Observed ionization energies for Li congruent to C-60, Li congruent to C-70, Li-2 congruent to C-70, Tc-99m congruent to C-60, Tc-99m congruent to C-70, Gd congruent to C-60, Nd congruent to C-60, Y congruent to C-60, Gd congruent to C-70, Nd congruent to C-70 and Y congruent to C-70 were 5.9eV, 5.1eV, 5.3eV, 5.1eV, 5.3ev, 6.2eV, 6.5eV, 6.6eV, 6.4eV, 6.5eV and 6.7eV, respectively.
T2  - Journal of Optoelectronics and Advanced Materials
T1  - Endohedral fullerenes of different elements
VL  - 8
IS  - 5
SP  - 1892
EP  - 1894
UR  - https://hdl.handle.net/21.15107/rcub_vinar_3106
ER  - 
@article{
author = "Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Veličković, Suzana and Đorđević, Vesna R. and Nešković, Olivera M.",
year = "2006",
abstract = "In this work we have studied the Li/C-60, Li/C-70, (99)mTc/C-60, (TC)-T-99/C-70, Gd/C-60, Gd/C-70, Nd/C-60, Nd/C-70, Y/C-60 and Y/C-70 systems by surface ionization mass spectrometry and investigated a possibility of the formation of endohedral fullerenes. Using the ion implantation technique (introducing negatively charged fullerene into a low temperature lithium, technetium, gadolinium, neodymium or yttrium plasma column by a strong axial magnetic field), the endohedral fullerenes Li congruent to C-60, Li congruent to C-70, Li-2 congruent to C-70, Tc-99m congruent to C-60, Tc-99m congruent to C-70, Gd congruent to C-60, Nd congruent to C-60, Y congruent to C-60, Gd congruent to C-70, Nd congruent to C-70 and Y congruent to C-70 have been produced and ionization energies were measured. Their existence was demonstrated through the high sensitivity, magnetic mass spectrometer (TIMS- thermal ionization mass spectrometer). These metallofullerenes were identified as stable molecules. The reaction of the obtained endohedral fullerenes with oxygen compounds (H2O, O-2 and N2O) has also been investigated. The result showed that these metallofullerenes are very inert to all of these gas phase oxygen-rich molecules, leading support to the endohedral structure of the metallofullerenes. Observed ionization energies for Li congruent to C-60, Li congruent to C-70, Li-2 congruent to C-70, Tc-99m congruent to C-60, Tc-99m congruent to C-70, Gd congruent to C-60, Nd congruent to C-60, Y congruent to C-60, Gd congruent to C-70, Nd congruent to C-70 and Y congruent to C-70 were 5.9eV, 5.1eV, 5.3eV, 5.1eV, 5.3ev, 6.2eV, 6.5eV, 6.6eV, 6.4eV, 6.5eV and 6.7eV, respectively.",
journal = "Journal of Optoelectronics and Advanced Materials",
title = "Endohedral fullerenes of different elements",
volume = "8",
number = "5",
pages = "1892-1894",
url = "https://hdl.handle.net/21.15107/rcub_vinar_3106"
}
Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V., Veličković, S., Đorđević, V. R.,& Nešković, O. M.. (2006). Endohedral fullerenes of different elements. in Journal of Optoelectronics and Advanced Materials, 8(5), 1892-1894.
https://hdl.handle.net/21.15107/rcub_vinar_3106
Cvetićanin JM, Đustebek JB, Veljković MV, Veličković S, Đorđević VR, Nešković OM. Endohedral fullerenes of different elements. in Journal of Optoelectronics and Advanced Materials. 2006;8(5):1892-1894.
https://hdl.handle.net/21.15107/rcub_vinar_3106 .
Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Veličković, Suzana, Đorđević, Vesna R., Nešković, Olivera M., "Endohedral fullerenes of different elements" in Journal of Optoelectronics and Advanced Materials, 8, no. 5 (2006):1892-1894,
https://hdl.handle.net/21.15107/rcub_vinar_3106 .
4
4

Surface ionization study of the non- stoichiometric LnFn-1 (n = 4 – 6) clusters

Veličković, Suzana; Veljković, M.; Đorđević, V.; Cvetičanin, Jelena; Đustebek, Jasmina B.; Nešković, Olivera M.

(Society of Physical Chemists of Serbia, 2006)

TY  - CONF
AU  - Veličković, Suzana
AU  - Veljković, M.
AU  - Đorđević, V.
AU  - Cvetičanin, Jelena
AU  - Đustebek, Jasmina B.
AU  - Nešković, Olivera M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9415
AB  - In this study we are presenting the results of the surface ionization of LinFn-1 (n=4- 6) clusters on rhenium surface impregnated with fullerenes using the magnetic mass spectrometer. The Li5F4 nanocubic cluster was detected for the first time. We determined values of ionization energies for Li4F3 and Li6F5, they are 4,3±0,2 eV, 4,0±0,2eV, respectively. The ionization energies agreed with theoretical ionization energies obtained by ab initio method, which indicates the excess electron localized in a specific site for non-stoichiometric clusters. The first ionization energy value for the Li4F3 was in accordance with earlier results obtained experimentally using photoionization time-of-flight mass spectrometer. There are currently no reliable experimental data for the ionization energy of Li6F5 cluster.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry
T1  - Surface ionization study of the non- stoichiometric LnFn-1 (n = 4 – 6) clusters
SP  - 117
EP  - 119
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9415
ER  - 
@conference{
author = "Veličković, Suzana and Veljković, M. and Đorđević, V. and Cvetičanin, Jelena and Đustebek, Jasmina B. and Nešković, Olivera M.",
year = "2006",
abstract = "In this study we are presenting the results of the surface ionization of LinFn-1 (n=4- 6) clusters on rhenium surface impregnated with fullerenes using the magnetic mass spectrometer. The Li5F4 nanocubic cluster was detected for the first time. We determined values of ionization energies for Li4F3 and Li6F5, they are 4,3±0,2 eV, 4,0±0,2eV, respectively. The ionization energies agreed with theoretical ionization energies obtained by ab initio method, which indicates the excess electron localized in a specific site for non-stoichiometric clusters. The first ionization energy value for the Li4F3 was in accordance with earlier results obtained experimentally using photoionization time-of-flight mass spectrometer. There are currently no reliable experimental data for the ionization energy of Li6F5 cluster.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry",
title = "Surface ionization study of the non- stoichiometric LnFn-1 (n = 4 – 6) clusters",
pages = "117-119",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9415"
}
Veličković, S., Veljković, M., Đorđević, V., Cvetičanin, J., Đustebek, J. B.,& Nešković, O. M.. (2006). Surface ionization study of the non- stoichiometric LnFn-1 (n = 4 – 6) clusters. in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry
Society of Physical Chemists of Serbia., 117-119.
https://hdl.handle.net/21.15107/rcub_vinar_9415
Veličković S, Veljković M, Đorđević V, Cvetičanin J, Đustebek JB, Nešković OM. Surface ionization study of the non- stoichiometric LnFn-1 (n = 4 – 6) clusters. in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry. 2006;:117-119.
https://hdl.handle.net/21.15107/rcub_vinar_9415 .
Veličković, Suzana, Veljković, M., Đorđević, V., Cvetičanin, Jelena, Đustebek, Jasmina B., Nešković, Olivera M., "Surface ionization study of the non- stoichiometric LnFn-1 (n = 4 – 6) clusters" in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry (2006):117-119,
https://hdl.handle.net/21.15107/rcub_vinar_9415 .

Tims and maldi tof of endohedral 99mTc@C60 metallofullerene

Đustebek, Jasmina B.; Cvetićanin, Jelena M.; Đorđević, Vesna R.; Veličković, Sava J.; Veljković, Miomir V.; Nešković, Olivera M.

(Society of Physical Chemists of Serbia, 2006)

TY  - CONF
AU  - Đustebek, Jasmina B.
AU  - Cvetićanin, Jelena M.
AU  - Đorđević, Vesna R.
AU  - Veličković, Sava J.
AU  - Veljković, Miomir V.
AU  - Nešković, Olivera M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9449
AB  - Mass spectral studies (both TIMS – thermal ionization and MALDI TOF – matrixassisted laser desorption time-of-flight mass spectrometry) of the endohedral metallofullerenes, 99mTc@C60 and 99mTc@C70, provided detailed structural and reactivity information about these unusual species. MS experiment revealed that both fullerenes and endohedral metallofullerenes fragment by multiple C2 loss. However, a difference in the terminal fragmentation products was observed for metallofullerene relative to C60, suggesting that the encapsulation metal strongly impacts the fragmentation product. Singly charged cations of the metallofullerenes (M@Cn + ) were completely unreactive in the gas phase with oxygenated compounds such as ethylene oxide: however, the corresponding neutral species appear to react readily with oxygenated species. Collisional dissociation of the ionized endohedral fullerenes listed above revealed multiple C2 loss (either as sequential C2 loss or larger C2n eliminations) to generate similar terminal fragmentation products, which might be predicted due to the similar ionic radii of the encapsulated metals. The observed ionization energies of endohedral molecules were, 5.1 ± 0.1 eV and 5.3 ± 0.1 eV, respectively.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry
T1  - Tims and maldi tof of endohedral 99mTc@C60 metallofullerene
SP  - 504
EP  - 506
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9449
ER  - 
@conference{
author = "Đustebek, Jasmina B. and Cvetićanin, Jelena M. and Đorđević, Vesna R. and Veličković, Sava J. and Veljković, Miomir V. and Nešković, Olivera M.",
year = "2006",
abstract = "Mass spectral studies (both TIMS – thermal ionization and MALDI TOF – matrixassisted laser desorption time-of-flight mass spectrometry) of the endohedral metallofullerenes, 99mTc@C60 and 99mTc@C70, provided detailed structural and reactivity information about these unusual species. MS experiment revealed that both fullerenes and endohedral metallofullerenes fragment by multiple C2 loss. However, a difference in the terminal fragmentation products was observed for metallofullerene relative to C60, suggesting that the encapsulation metal strongly impacts the fragmentation product. Singly charged cations of the metallofullerenes (M@Cn + ) were completely unreactive in the gas phase with oxygenated compounds such as ethylene oxide: however, the corresponding neutral species appear to react readily with oxygenated species. Collisional dissociation of the ionized endohedral fullerenes listed above revealed multiple C2 loss (either as sequential C2 loss or larger C2n eliminations) to generate similar terminal fragmentation products, which might be predicted due to the similar ionic radii of the encapsulated metals. The observed ionization energies of endohedral molecules were, 5.1 ± 0.1 eV and 5.3 ± 0.1 eV, respectively.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry",
title = "Tims and maldi tof of endohedral 99mTc@C60 metallofullerene",
pages = "504-506",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9449"
}
Đustebek, J. B., Cvetićanin, J. M., Đorđević, V. R., Veličković, S. J., Veljković, M. V.,& Nešković, O. M.. (2006). Tims and maldi tof of endohedral 99mTc@C60 metallofullerene. in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry
Society of Physical Chemists of Serbia., 504-506.
https://hdl.handle.net/21.15107/rcub_vinar_9449
Đustebek JB, Cvetićanin JM, Đorđević VR, Veličković SJ, Veljković MV, Nešković OM. Tims and maldi tof of endohedral 99mTc@C60 metallofullerene. in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry. 2006;:504-506.
https://hdl.handle.net/21.15107/rcub_vinar_9449 .
Đustebek, Jasmina B., Cvetićanin, Jelena M., Đorđević, Vesna R., Veličković, Sava J., Veljković, Miomir V., Nešković, Olivera M., "Tims and maldi tof of endohedral 99mTc@C60 metallofullerene" in Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry (2006):504-506,
https://hdl.handle.net/21.15107/rcub_vinar_9449 .