Rogić Miladinović, Zorana

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orcid::0000-0002-0019-8091
  • Rogić Miladinović, Zorana (19)
  • Rogić, Zorana (2)

Author's Bibliography

Optimization of thermoresponsive hydrogels based on oligomers with lower critical solution temperature (LCST) far below/above physiological temperatures for biomedical applications

Suljovrujić, Edin H.; Krstić, Maja; Rogić Miladinović, Zorana; Petrović, Sandra; Leskovac, Andreja; Stamboliev, Georgi

(2023)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Krstić, Maja
AU  - Rogić Miladinović, Zorana
AU  - Petrović, Sandra
AU  - Leskovac, Andreja
AU  - Stamboliev, Georgi
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11063
AB  - Hydrogels with oligo(ethylene glycol) (OEG), oligo(propylene glycol) (OPG), and for the first time with combined OEG/OPG pendant chains within the methacrylate (MA) network, were synthesized and the swelling behavior, thermal properties, microstructure, and genotoxicity were investigated. Prior to hydrogel fabrication, an optimized method was developed for oligo(propylene glycol) methacrylate (OPGMA), i.e., oligomer with an LCST below a temperature at which synthesis occurs, indicating that proper preparation and tuning of reaction conditions were required. PEG6MA and PPG5MA homopolymers, as well as P(EG6/PG5)MA copolymer hydrogel, were produced by gamma radiation-induced polymerization and crosslinking of OEG and OPG monomers from the monomer-solvent mixture by using different water/ethanol composition as a solvent and by exposing the reaction mixture to various radiation doses. The combination of OEG and OPG pendant chains within the same network was advantageous in that it allowed an easy tuning of the phase transition temperature. Thus, the volume phase transition (VPT) at temperatures above 70 °C observed in the case of PEG6MA, and in the case of PPG5MA at temperatures below 15 °C, could easily be tuned close to physiological temperatures for P(EG6/PG5)MA hydrogel. Finally, all obtained thermoresponsive hydrogels showed non-genotoxic and non-cytotoxic properties, which indicate promising potential for biomedical applications.
T2  - Reactive and Functional Polymers
T1  - Optimization of thermoresponsive hydrogels based on oligomers with lower critical solution temperature (LCST) far below/above physiological temperatures for biomedical applications
VL  - 189
SP  - 105612
DO  - 10.1016/j.reactfunctpolym.2023.105612
ER  - 
@article{
author = "Suljovrujić, Edin H. and Krstić, Maja and Rogić Miladinović, Zorana and Petrović, Sandra and Leskovac, Andreja and Stamboliev, Georgi",
year = "2023",
abstract = "Hydrogels with oligo(ethylene glycol) (OEG), oligo(propylene glycol) (OPG), and for the first time with combined OEG/OPG pendant chains within the methacrylate (MA) network, were synthesized and the swelling behavior, thermal properties, microstructure, and genotoxicity were investigated. Prior to hydrogel fabrication, an optimized method was developed for oligo(propylene glycol) methacrylate (OPGMA), i.e., oligomer with an LCST below a temperature at which synthesis occurs, indicating that proper preparation and tuning of reaction conditions were required. PEG6MA and PPG5MA homopolymers, as well as P(EG6/PG5)MA copolymer hydrogel, were produced by gamma radiation-induced polymerization and crosslinking of OEG and OPG monomers from the monomer-solvent mixture by using different water/ethanol composition as a solvent and by exposing the reaction mixture to various radiation doses. The combination of OEG and OPG pendant chains within the same network was advantageous in that it allowed an easy tuning of the phase transition temperature. Thus, the volume phase transition (VPT) at temperatures above 70 °C observed in the case of PEG6MA, and in the case of PPG5MA at temperatures below 15 °C, could easily be tuned close to physiological temperatures for P(EG6/PG5)MA hydrogel. Finally, all obtained thermoresponsive hydrogels showed non-genotoxic and non-cytotoxic properties, which indicate promising potential for biomedical applications.",
journal = "Reactive and Functional Polymers",
title = "Optimization of thermoresponsive hydrogels based on oligomers with lower critical solution temperature (LCST) far below/above physiological temperatures for biomedical applications",
volume = "189",
pages = "105612",
doi = "10.1016/j.reactfunctpolym.2023.105612"
}
Suljovrujić, E. H., Krstić, M., Rogić Miladinović, Z., Petrović, S., Leskovac, A.,& Stamboliev, G.. (2023). Optimization of thermoresponsive hydrogels based on oligomers with lower critical solution temperature (LCST) far below/above physiological temperatures for biomedical applications. in Reactive and Functional Polymers, 189, 105612.
https://doi.org/10.1016/j.reactfunctpolym.2023.105612
Suljovrujić EH, Krstić M, Rogić Miladinović Z, Petrović S, Leskovac A, Stamboliev G. Optimization of thermoresponsive hydrogels based on oligomers with lower critical solution temperature (LCST) far below/above physiological temperatures for biomedical applications. in Reactive and Functional Polymers. 2023;189:105612.
doi:10.1016/j.reactfunctpolym.2023.105612 .
Suljovrujić, Edin H., Krstić, Maja, Rogić Miladinović, Zorana, Petrović, Sandra, Leskovac, Andreja, Stamboliev, Georgi, "Optimization of thermoresponsive hydrogels based on oligomers with lower critical solution temperature (LCST) far below/above physiological temperatures for biomedical applications" in Reactive and Functional Polymers, 189 (2023):105612,
https://doi.org/10.1016/j.reactfunctpolym.2023.105612 . .

Methacrylate-based hydrogels as sorbents for the removal of Mn+2 from aqueous solutions

Mladenović, Anita; Rogić Miladinović, Zorana; Stolić, Anđelka; Suljovrujić, Edin

(Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club, 2023)

TY  - CONF
AU  - Mladenović, Anita
AU  - Rogić Miladinović, Zorana
AU  - Stolić, Anđelka
AU  - Suljovrujić, Edin
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12408
AB  - One of today's imperatives is the effective removal of pollutants from the biosphere, particularly from natural and wastewater sources. The removal of metal ions from solutions has long been a goal of numerous investigations, and hydrogels have been utilized as sorbent materials for this purpose. [1,2] This research was performed in order to create a new class of poly(oligo(propylene glycol methacrylate)/oligo(ethylene glycol methacrylate))/acid), abbreviated as p(OPGMA/OEGMA/acid), temperature-responsive copolymeric hydrogels and to analyze the influence of different acids on the volume phase transition temperature (VPTT) of the obtained hydrogels and on the efficiency of Mn+2 removal from the water. In this work, three acids were used: itaconic (IA), acrylic (AA), and methacrylate (MA), which were incorporated into the composition of the hydrogel in the monomer feed ratio OPGMA/OEGMA/acid of 95:2:3. Henceforth, the obtained hydrogels p(OPGMA/OEGMA/acid) were synthesized for the first time by γ-irradiation polymerization and crosslinking of monomers from a water/ethanol solution. The hydrogels were put through swelling analysis and testing as potential sorbents once the high level of gel content was confirmed. Taking into account the size of the metal ions, their concentration in the solution, and the porosity of the gel, the results show that hydrogels can be employed to remove manganese ions from solutions.
PB  - Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club
C3  - 9th Conference of Young Chemists of Serbia : Book of abstracts
T1  - Methacrylate-based hydrogels as sorbents for the removal of Mn+2 from aqueous solutions
SP  - 154
EP  - 154
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12408
ER  - 
@conference{
author = "Mladenović, Anita and Rogić Miladinović, Zorana and Stolić, Anđelka and Suljovrujić, Edin",
year = "2023",
abstract = "One of today's imperatives is the effective removal of pollutants from the biosphere, particularly from natural and wastewater sources. The removal of metal ions from solutions has long been a goal of numerous investigations, and hydrogels have been utilized as sorbent materials for this purpose. [1,2] This research was performed in order to create a new class of poly(oligo(propylene glycol methacrylate)/oligo(ethylene glycol methacrylate))/acid), abbreviated as p(OPGMA/OEGMA/acid), temperature-responsive copolymeric hydrogels and to analyze the influence of different acids on the volume phase transition temperature (VPTT) of the obtained hydrogels and on the efficiency of Mn+2 removal from the water. In this work, three acids were used: itaconic (IA), acrylic (AA), and methacrylate (MA), which were incorporated into the composition of the hydrogel in the monomer feed ratio OPGMA/OEGMA/acid of 95:2:3. Henceforth, the obtained hydrogels p(OPGMA/OEGMA/acid) were synthesized for the first time by γ-irradiation polymerization and crosslinking of monomers from a water/ethanol solution. The hydrogels were put through swelling analysis and testing as potential sorbents once the high level of gel content was confirmed. Taking into account the size of the metal ions, their concentration in the solution, and the porosity of the gel, the results show that hydrogels can be employed to remove manganese ions from solutions.",
publisher = "Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club",
journal = "9th Conference of Young Chemists of Serbia : Book of abstracts",
title = "Methacrylate-based hydrogels as sorbents for the removal of Mn+2 from aqueous solutions",
pages = "154-154",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12408"
}
Mladenović, A., Rogić Miladinović, Z., Stolić, A.,& Suljovrujić, E.. (2023). Methacrylate-based hydrogels as sorbents for the removal of Mn+2 from aqueous solutions. in 9th Conference of Young Chemists of Serbia : Book of abstracts
Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club., 154-154.
https://hdl.handle.net/21.15107/rcub_vinar_12408
Mladenović A, Rogić Miladinović Z, Stolić A, Suljovrujić E. Methacrylate-based hydrogels as sorbents for the removal of Mn+2 from aqueous solutions. in 9th Conference of Young Chemists of Serbia : Book of abstracts. 2023;:154-154.
https://hdl.handle.net/21.15107/rcub_vinar_12408 .
Mladenović, Anita, Rogić Miladinović, Zorana, Stolić, Anđelka, Suljovrujić, Edin, "Methacrylate-based hydrogels as sorbents for the removal of Mn+2 from aqueous solutions" in 9th Conference of Young Chemists of Serbia : Book of abstracts (2023):154-154,
https://hdl.handle.net/21.15107/rcub_vinar_12408 .

A comparative study of two different methods of sample preparation for polyolefins commonly used in medical devices

Jolić, Anđelka; Miličević, Dejan; Rogić Miladinović, Zorana; Suljovrujić, Edin

(Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club, 2022)

TY  - CONF
AU  - Jolić, Anđelka
AU  - Miličević, Dejan
AU  - Rogić Miladinović, Zorana
AU  - Suljovrujić, Edin
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12407
AB  - Polyolefins (POs) are currently the most widely used engineering plastics due to their
relatively low cost, durability, and ease of processing. A feature such as inertness makes
polyolefins suitable for applications such as food packaging and medical devices. For
the purpose of this study, polyethylene (PE) with good rigidity, hardness, impact
strength, environmental stress cracking resistance, and excellent processability, and
polypropylene (PP), with high fluidity and very good transparency, were selected
polyolefins [1,2]. Knowing that most of the polymer applications are strongly dependent
on the initial state of the products, i.e., their morphology, thermal properties, and
crystallinity, it is possible to obtain a great variety of morphologies and supermolecular
formations by varying different conditions in the preparation process, e.g. cooling
conditions during the crystallization process from the melt.
One of the aims of this work was to compare the results obtained for two different
methods of sample preparation, quenching, and slow cooling. Initial preparation was
performed for selected POs by rapid quenching in ice water and slow air cooling after
compression molding. Further, the prepared samples were characterized by SEM,
WAXD, FTIR, and mechanical measurements.
The obtained results indicated that PP is much more sensitive to the method of sample
preparation than PE, as well as that the initial preparation of samples plays a decisive
role in the final properties of materials for polymeric medical devices.
PB  - Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club
C3  - 8th Conference of Young Chemists of Serbia : Book of abstracts
T1  - A comparative study of two different methods of sample preparation for polyolefins commonly used in medical devices
SP  - 91
EP  - 91
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12407
ER  - 
@conference{
author = "Jolić, Anđelka and Miličević, Dejan and Rogić Miladinović, Zorana and Suljovrujić, Edin",
year = "2022",
abstract = "Polyolefins (POs) are currently the most widely used engineering plastics due to their
relatively low cost, durability, and ease of processing. A feature such as inertness makes
polyolefins suitable for applications such as food packaging and medical devices. For
the purpose of this study, polyethylene (PE) with good rigidity, hardness, impact
strength, environmental stress cracking resistance, and excellent processability, and
polypropylene (PP), with high fluidity and very good transparency, were selected
polyolefins [1,2]. Knowing that most of the polymer applications are strongly dependent
on the initial state of the products, i.e., their morphology, thermal properties, and
crystallinity, it is possible to obtain a great variety of morphologies and supermolecular
formations by varying different conditions in the preparation process, e.g. cooling
conditions during the crystallization process from the melt.
One of the aims of this work was to compare the results obtained for two different
methods of sample preparation, quenching, and slow cooling. Initial preparation was
performed for selected POs by rapid quenching in ice water and slow air cooling after
compression molding. Further, the prepared samples were characterized by SEM,
WAXD, FTIR, and mechanical measurements.
The obtained results indicated that PP is much more sensitive to the method of sample
preparation than PE, as well as that the initial preparation of samples plays a decisive
role in the final properties of materials for polymeric medical devices.",
publisher = "Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club",
journal = "8th Conference of Young Chemists of Serbia : Book of abstracts",
title = "A comparative study of two different methods of sample preparation for polyolefins commonly used in medical devices",
pages = "91-91",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12407"
}
Jolić, A., Miličević, D., Rogić Miladinović, Z.,& Suljovrujić, E.. (2022). A comparative study of two different methods of sample preparation for polyolefins commonly used in medical devices. in 8th Conference of Young Chemists of Serbia : Book of abstracts
Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club., 91-91.
https://hdl.handle.net/21.15107/rcub_vinar_12407
Jolić A, Miličević D, Rogić Miladinović Z, Suljovrujić E. A comparative study of two different methods of sample preparation for polyolefins commonly used in medical devices. in 8th Conference of Young Chemists of Serbia : Book of abstracts. 2022;:91-91.
https://hdl.handle.net/21.15107/rcub_vinar_12407 .
Jolić, Anđelka, Miličević, Dejan, Rogić Miladinović, Zorana, Suljovrujić, Edin, "A comparative study of two different methods of sample preparation for polyolefins commonly used in medical devices" in 8th Conference of Young Chemists of Serbia : Book of abstracts (2022):91-91,
https://hdl.handle.net/21.15107/rcub_vinar_12407 .

Preparation and swelling characterization of P(NiPAM/OPGMA) hydrogels

Mladenović, Anita S.; Rogić Miladinović, Zorana; Krstić, Maja; Suljovrujić, Edin

(Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club, 2022)

TY  - CONF
AU  - Mladenović, Anita S.
AU  - Rogić Miladinović, Zorana
AU  - Krstić, Maja
AU  - Suljovrujić, Edin
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11477
AB  - For many years now, thermally actuated hydrogels have been the ones most studied and employed in the field of polymeric biomaterials. The monomers, N-isopropyl acrylamide (NiPAM), and oligo(propylene glycol) methacrylate (OPGMA) were selected based on the sharp temperature response of their corresponding hydrogels in a known range of temperatures.1,2 This research was performed in order to create a new class of P(NiPAM/OPGMA) temperature-responsive hydrogels, and to analyze the influence of different content of monomers on the volume phase transition temperature (VPTT) of the obtained hydrogels. One of the objectives of this study was to provide insight into the effects of applied radiation dose on the swelling and mechanical properties of the hydrogels.  In further work, P(NiPAM/OPGMA) hydrogels were synthesized for the first time by γradiation crosslinking of monomers from water/ethanol solution. After the high sol-gel conversion was established, xerogels were subjected to swelling analysis and tested for the mechanism of water diffusion within the hydrogels. The obtained results indicated that new hydrogels based on NiPAM and OPGMA show promising potential for water treatment application due to the relatively high swelling degree of hydrogels and the ability to combine their VPTT close to annual river water temperatures in Serbia.
PB  - Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club
C3  - 8th Conference of Young Chemists of Serbia : Book of abstracts
T1  - Preparation and swelling characterization of P(NiPAM/OPGMA) hydrogels
SP  - 89
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11477
ER  - 
@conference{
author = "Mladenović, Anita S. and Rogić Miladinović, Zorana and Krstić, Maja and Suljovrujić, Edin",
year = "2022",
abstract = "For many years now, thermally actuated hydrogels have been the ones most studied and employed in the field of polymeric biomaterials. The monomers, N-isopropyl acrylamide (NiPAM), and oligo(propylene glycol) methacrylate (OPGMA) were selected based on the sharp temperature response of their corresponding hydrogels in a known range of temperatures.1,2 This research was performed in order to create a new class of P(NiPAM/OPGMA) temperature-responsive hydrogels, and to analyze the influence of different content of monomers on the volume phase transition temperature (VPTT) of the obtained hydrogels. One of the objectives of this study was to provide insight into the effects of applied radiation dose on the swelling and mechanical properties of the hydrogels.  In further work, P(NiPAM/OPGMA) hydrogels were synthesized for the first time by γradiation crosslinking of monomers from water/ethanol solution. After the high sol-gel conversion was established, xerogels were subjected to swelling analysis and tested for the mechanism of water diffusion within the hydrogels. The obtained results indicated that new hydrogels based on NiPAM and OPGMA show promising potential for water treatment application due to the relatively high swelling degree of hydrogels and the ability to combine their VPTT close to annual river water temperatures in Serbia.",
publisher = "Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club",
journal = "8th Conference of Young Chemists of Serbia : Book of abstracts",
title = "Preparation and swelling characterization of P(NiPAM/OPGMA) hydrogels",
pages = "89",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11477"
}
Mladenović, A. S., Rogić Miladinović, Z., Krstić, M.,& Suljovrujić, E.. (2022). Preparation and swelling characterization of P(NiPAM/OPGMA) hydrogels. in 8th Conference of Young Chemists of Serbia : Book of abstracts
Belgrade : Serbian Chemical Society and Serbian Young Chemists’ Club., 89.
https://hdl.handle.net/21.15107/rcub_vinar_11477
Mladenović AS, Rogić Miladinović Z, Krstić M, Suljovrujić E. Preparation and swelling characterization of P(NiPAM/OPGMA) hydrogels. in 8th Conference of Young Chemists of Serbia : Book of abstracts. 2022;:89.
https://hdl.handle.net/21.15107/rcub_vinar_11477 .
Mladenović, Anita S., Rogić Miladinović, Zorana, Krstić, Maja, Suljovrujić, Edin, "Preparation and swelling characterization of P(NiPAM/OPGMA) hydrogels" in 8th Conference of Young Chemists of Serbia : Book of abstracts (2022):89,
https://hdl.handle.net/21.15107/rcub_vinar_11477 .

Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Krstić, Maja

(2021)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Rogić Miladinović, Zorana
AU  - Krstić, Maja
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11469
AB  - Oligo (ethylene glycol) oligo (propylene glycol) methacrylates (OEGOPGMA) with diferent numbers of ethylene glycol (EG) and propylene glycol (PG) units in backbone were used for the preparation of new thermoresponsive POEGOPGMA hydrogels; EG6PG3MA and EG3PG6MA monomers were used; and three diferent POEGOPGMA hydrogels (PEG6PG3MA, PEG3PG6MA and P(EG6PG3/EG3PG6) MA copolymer with equal mol% of previous two) were fabricated from mono‑ mer–solvent (OEGOPGMA–water/ethanol) mixture by gamma radiation. Charac‑ terisation of the hydrogels was conducted by swelling, UV–Vis, scanning electron microscope, diferential scanning calorimetry and in  vitro biocompatibility (cyto‑ compatibility and haemolytic activity) investigations. The modelling of drug release and difusion characteristics was tested using cephalexin drug. For the frst time, it was shown how to efectively tune the volume phase transition temperature (VPTT) values of the hydrogels by changing the ratio of more hydrophilic (EG) and more hydrophobic (PG) units in (EGPG) “block” pendant chains. The obtained hydrogels revealed the great potential for diferent biomedical applications not only due to the possibility to tune VPTT in the desired way but also due to the good biocompatibil‑ ity and controlled drug delivery within the target temperature range.
T2  - Polymer Bulletin
T1  - Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature
VL  - 78
SP  - 2405
EP  - 2425
DO  - 10.1007/s00289-020-03217-0
ER  - 
@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Krstić, Maja",
year = "2021",
abstract = "Oligo (ethylene glycol) oligo (propylene glycol) methacrylates (OEGOPGMA) with diferent numbers of ethylene glycol (EG) and propylene glycol (PG) units in backbone were used for the preparation of new thermoresponsive POEGOPGMA hydrogels; EG6PG3MA and EG3PG6MA monomers were used; and three diferent POEGOPGMA hydrogels (PEG6PG3MA, PEG3PG6MA and P(EG6PG3/EG3PG6) MA copolymer with equal mol% of previous two) were fabricated from mono‑ mer–solvent (OEGOPGMA–water/ethanol) mixture by gamma radiation. Charac‑ terisation of the hydrogels was conducted by swelling, UV–Vis, scanning electron microscope, diferential scanning calorimetry and in  vitro biocompatibility (cyto‑ compatibility and haemolytic activity) investigations. The modelling of drug release and difusion characteristics was tested using cephalexin drug. For the frst time, it was shown how to efectively tune the volume phase transition temperature (VPTT) values of the hydrogels by changing the ratio of more hydrophilic (EG) and more hydrophobic (PG) units in (EGPG) “block” pendant chains. The obtained hydrogels revealed the great potential for diferent biomedical applications not only due to the possibility to tune VPTT in the desired way but also due to the good biocompatibil‑ ity and controlled drug delivery within the target temperature range.",
journal = "Polymer Bulletin",
title = "Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature",
volume = "78",
pages = "2405-2425",
doi = "10.1007/s00289-020-03217-0"
}
Suljovrujić, E. H., Rogić Miladinović, Z.,& Krstić, M.. (2021). Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature. in Polymer Bulletin, 78, 2405-2425.
https://doi.org/10.1007/s00289-020-03217-0
Suljovrujić EH, Rogić Miladinović Z, Krstić M. Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature. in Polymer Bulletin. 2021;78:2405-2425.
doi:10.1007/s00289-020-03217-0 .
Suljovrujić, Edin H., Rogić Miladinović, Zorana, Krstić, Maja, "Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature" in Polymer Bulletin, 78 (2021):2405-2425,
https://doi.org/10.1007/s00289-020-03217-0 . .
7
2
6

The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Mićić, Maja M.; Suljovrujić, Denis; Miličević, Dejan S.

(2019)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Rogić Miladinović, Zorana
AU  - Mićić, Maja M.
AU  - Suljovrujić, Denis
AU  - Miličević, Dejan S.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8048
AB  - The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd
T2  - Radiation Physics and Chemistry
T1  - The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT
VL  - 158
SP  - 37
EP  - 45
DO  - 10.1016/j.radphyschem.2018.12.034
ER  - 
@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Mićić, Maja M. and Suljovrujić, Denis and Miličević, Dejan S.",
year = "2019",
abstract = "The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT",
volume = "158",
pages = "37-45",
doi = "10.1016/j.radphyschem.2018.12.034"
}
Suljovrujić, E. H., Rogić Miladinović, Z., Mićić, M. M., Suljovrujić, D.,& Miličević, D. S.. (2019). The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry, 158, 37-45.
https://doi.org/10.1016/j.radphyschem.2018.12.034
Suljovrujić EH, Rogić Miladinović Z, Mićić MM, Suljovrujić D, Miličević DS. The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry. 2019;158:37-45.
doi:10.1016/j.radphyschem.2018.12.034 .
Suljovrujić, Edin H., Rogić Miladinović, Zorana, Mićić, Maja M., Suljovrujić, Denis, Miličević, Dejan S., "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT" in Radiation Physics and Chemistry, 158 (2019):37-45,
https://doi.org/10.1016/j.radphyschem.2018.12.034 . .
14
8
11

The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Mićić, Maja M.; Suljovrujić, Denis; Miličević, Dejan S.

(2019)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Rogić Miladinović, Zorana
AU  - Mićić, Maja M.
AU  - Suljovrujić, Denis
AU  - Miličević, Dejan S.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8051
AB  - The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd
T2  - Radiation Physics and Chemistry
T1  - The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT
VL  - 158
SP  - 37
EP  - 45
DO  - 10.1016/j.radphyschem.2018.12.034
ER  - 
@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Mićić, Maja M. and Suljovrujić, Denis and Miličević, Dejan S.",
year = "2019",
abstract = "The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT",
volume = "158",
pages = "37-45",
doi = "10.1016/j.radphyschem.2018.12.034"
}
Suljovrujić, E. H., Rogić Miladinović, Z., Mićić, M. M., Suljovrujić, D.,& Miličević, D. S.. (2019). The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry, 158, 37-45.
https://doi.org/10.1016/j.radphyschem.2018.12.034
Suljovrujić EH, Rogić Miladinović Z, Mićić MM, Suljovrujić D, Miličević DS. The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry. 2019;158:37-45.
doi:10.1016/j.radphyschem.2018.12.034 .
Suljovrujić, Edin H., Rogić Miladinović, Zorana, Mićić, Maja M., Suljovrujić, Denis, Miličević, Dejan S., "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT" in Radiation Physics and Chemistry, 158 (2019):37-45,
https://doi.org/10.1016/j.radphyschem.2018.12.034 . .
14
8
12

Smart hydrogels with ethylene glycol propylene glycol pendant chains

Rogić Miladinović, Zorana; Mićić, Maja M.; Mraković, Ana Đ.; Suljovrujić, Edin H.

(2018)

TY  - JOUR
AU  - Rogić Miladinović, Zorana
AU  - Mićić, Maja M.
AU  - Mraković, Ana Đ.
AU  - Suljovrujić, Edin H.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1884
AB  - New hydrogels based on different oligo(alkylene glycol) methacrylate (OAGMA) with inverse thermoresponse and volume phase transition temperature (VPTT) were obtained and characterised in this paper. Synthesis was performed from monomer-solvent (OAGMA-water/ethanol) mixture by simultaneous radiation-induced polymerisation and crosslinking; three different OAGMA (EG(6)MA, EG(6)PG(3)MA, and PG(5)MA) were used. The main focus was made on PEG(6)PG(3)MA hydrogel based on ethylene glycol (EG) propylene glycol (PG) pendant chains with EG (6) and PG (3) block units, since in the case of POPGMA and POEGMA homopolymers (i.e. hydrogels with pure PG and EG pendant chains) the VPTTs were observed far below and far above the human body temperature, respectively. Characterisation of the hydrogels was performed by swelling, UV-Vis, FTIR, SEM, DSC and in vitro biocompatibility (cytocompatibility and haemolytic activity) investigations. Due to the possibility to combine VPTT close to human body temperature with good biocompatibility, new hydrogel based on EGPG block pendant chains showed promising potential for different biomedical applications.
T2  - Journal of Polymer Research
T1  - Smart hydrogels with ethylene glycol propylene glycol pendant chains
VL  - 25
IS  - 1
DO  - 10.1007/s10965-017-1408-z
ER  - 
@article{
author = "Rogić Miladinović, Zorana and Mićić, Maja M. and Mraković, Ana Đ. and Suljovrujić, Edin H.",
year = "2018",
abstract = "New hydrogels based on different oligo(alkylene glycol) methacrylate (OAGMA) with inverse thermoresponse and volume phase transition temperature (VPTT) were obtained and characterised in this paper. Synthesis was performed from monomer-solvent (OAGMA-water/ethanol) mixture by simultaneous radiation-induced polymerisation and crosslinking; three different OAGMA (EG(6)MA, EG(6)PG(3)MA, and PG(5)MA) were used. The main focus was made on PEG(6)PG(3)MA hydrogel based on ethylene glycol (EG) propylene glycol (PG) pendant chains with EG (6) and PG (3) block units, since in the case of POPGMA and POEGMA homopolymers (i.e. hydrogels with pure PG and EG pendant chains) the VPTTs were observed far below and far above the human body temperature, respectively. Characterisation of the hydrogels was performed by swelling, UV-Vis, FTIR, SEM, DSC and in vitro biocompatibility (cytocompatibility and haemolytic activity) investigations. Due to the possibility to combine VPTT close to human body temperature with good biocompatibility, new hydrogel based on EGPG block pendant chains showed promising potential for different biomedical applications.",
journal = "Journal of Polymer Research",
title = "Smart hydrogels with ethylene glycol propylene glycol pendant chains",
volume = "25",
number = "1",
doi = "10.1007/s10965-017-1408-z"
}
Rogić Miladinović, Z., Mićić, M. M., Mraković, A. Đ.,& Suljovrujić, E. H.. (2018). Smart hydrogels with ethylene glycol propylene glycol pendant chains. in Journal of Polymer Research, 25(1).
https://doi.org/10.1007/s10965-017-1408-z
Rogić Miladinović Z, Mićić MM, Mraković AĐ, Suljovrujić EH. Smart hydrogels with ethylene glycol propylene glycol pendant chains. in Journal of Polymer Research. 2018;25(1).
doi:10.1007/s10965-017-1408-z .
Rogić Miladinović, Zorana, Mićić, Maja M., Mraković, Ana Đ., Suljovrujić, Edin H., "Smart hydrogels with ethylene glycol propylene glycol pendant chains" in Journal of Polymer Research, 25, no. 1 (2018),
https://doi.org/10.1007/s10965-017-1408-z . .
44
8
17

Temperature responsive hydrogels based on ethylene glycol propylene glycol "block" units with VPTT close to human body temperature

Suljovrujić, Edin; Mićić, Maja M.; Rogić Miladinović, Zorana; Miličević, Dejan

(Belgrade : Materials Research Society of Serbia, 2017)

TY  - CONF
AU  - Suljovrujić, Edin
AU  - Mićić, Maja M.
AU  - Rogić Miladinović, Zorana
AU  - Miličević, Dejan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11470
AB  - New hydrogels based on different oligo(alkylene glycol) methacrylate (OAGMA) with inverse thermo-response and volume phase transition temperature (VPTT) close to human body temperature were investigated in this work. Synthesis was performed from monomer-solvent mixture by gamma radiation; four different OAGMA (EG6MA, EG6PG3MA, EG3PG6MA and PG5MA) were used. The main focus was made on hydrogels based on EGxPGy pendant chains with different number of ethylene glycol and propylene glycol units in “block” backbone since in the case of POPGMA and POEGMA homopolimers (e.g. hydrogels with pure PG and EG pedant chains) the VPTTs were observed far below and far above the human body temperature, respectively. Characterisation of the hydrogels was performed by swelling, UV-Vis, FTIR, SEM, DSC and in vitro biocompatibility investigations. Due to the possibility to combined VPTT close to human body temperature with good biocompatibility, new hydrogels based on EGPG “block” pedant chains show great potential for biomedical applications.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
T1  - Temperature responsive hydrogels based on ethylene glycol propylene glycol "block" units with VPTT close to human body temperature
SP  - 71
EP  - 71
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11470
ER  - 
@conference{
author = "Suljovrujić, Edin and Mićić, Maja M. and Rogić Miladinović, Zorana and Miličević, Dejan",
year = "2017",
abstract = "New hydrogels based on different oligo(alkylene glycol) methacrylate (OAGMA) with inverse thermo-response and volume phase transition temperature (VPTT) close to human body temperature were investigated in this work. Synthesis was performed from monomer-solvent mixture by gamma radiation; four different OAGMA (EG6MA, EG6PG3MA, EG3PG6MA and PG5MA) were used. The main focus was made on hydrogels based on EGxPGy pendant chains with different number of ethylene glycol and propylene glycol units in “block” backbone since in the case of POPGMA and POEGMA homopolimers (e.g. hydrogels with pure PG and EG pedant chains) the VPTTs were observed far below and far above the human body temperature, respectively. Characterisation of the hydrogels was performed by swelling, UV-Vis, FTIR, SEM, DSC and in vitro biocompatibility investigations. Due to the possibility to combined VPTT close to human body temperature with good biocompatibility, new hydrogels based on EGPG “block” pedant chains show great potential for biomedical applications.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017",
title = "Temperature responsive hydrogels based on ethylene glycol propylene glycol "block" units with VPTT close to human body temperature",
pages = "71-71",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11470"
}
Suljovrujić, E., Mićić, M. M., Rogić Miladinović, Z.,& Miličević, D.. (2017). Temperature responsive hydrogels based on ethylene glycol propylene glycol "block" units with VPTT close to human body temperature. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
Belgrade : Materials Research Society of Serbia., 71-71.
https://hdl.handle.net/21.15107/rcub_vinar_11470
Suljovrujić E, Mićić MM, Rogić Miladinović Z, Miličević D. Temperature responsive hydrogels based on ethylene glycol propylene glycol "block" units with VPTT close to human body temperature. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017. 2017;:71-71.
https://hdl.handle.net/21.15107/rcub_vinar_11470 .
Suljovrujić, Edin, Mićić, Maja M., Rogić Miladinović, Zorana, Miličević, Dejan, "Temperature responsive hydrogels based on ethylene glycol propylene glycol "block" units with VPTT close to human body temperature" in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017 (2017):71-71,
https://hdl.handle.net/21.15107/rcub_vinar_11470 .

Temperature responsive hydrogels with ethylene glycol propylene glycol pendant chains

Suljovrujić, Edin; Rogić Miladinović, Zorana; Miličević, Dejan; Mićić, Maja

(Belgrade : Materials Research Society of Serbia, 2016)

TY  - CONF
AU  - Suljovrujić, Edin
AU  - Rogić Miladinović, Zorana
AU  - Miličević, Dejan
AU  - Mićić, Maja
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12406
AB  - New hydrogels based on different oligo(alkylene glycol) methacrylate (OAGMA) with inverse thermoresponse and volume phase transition temperature (VPTT) were obtained and characterised. Synthesis was performed from monomer-solvent (OAGMA-water/ethanol) mixture using gamma radiation. Characterisation of the hydrogels was performed by swelling, UV-Vis, FTIR, SEM, DSC and in vitro biocompatibility (cytocompatibility and haemolytic activity) investigations. Due to the possibility to combine VPTT close to human body temperature with good biocompatibility, new homopolymeric hydrogel based on EGPG “block” pendant chains showed promising potential for different biomedical applications.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : Programme and the book of abstracts
T1  - Temperature responsive hydrogels with ethylene glycol propylene glycol pendant chains
SP  - 74
EP  - 74
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12406
ER  - 
@conference{
author = "Suljovrujić, Edin and Rogić Miladinović, Zorana and Miličević, Dejan and Mićić, Maja",
year = "2016",
abstract = "New hydrogels based on different oligo(alkylene glycol) methacrylate (OAGMA) with inverse thermoresponse and volume phase transition temperature (VPTT) were obtained and characterised. Synthesis was performed from monomer-solvent (OAGMA-water/ethanol) mixture using gamma radiation. Characterisation of the hydrogels was performed by swelling, UV-Vis, FTIR, SEM, DSC and in vitro biocompatibility (cytocompatibility and haemolytic activity) investigations. Due to the possibility to combine VPTT close to human body temperature with good biocompatibility, new homopolymeric hydrogel based on EGPG “block” pendant chains showed promising potential for different biomedical applications.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : Programme and the book of abstracts",
title = "Temperature responsive hydrogels with ethylene glycol propylene glycol pendant chains",
pages = "74-74",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12406"
}
Suljovrujić, E., Rogić Miladinović, Z., Miličević, D.,& Mićić, M.. (2016). Temperature responsive hydrogels with ethylene glycol propylene glycol pendant chains. in YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : Programme and the book of abstracts
Belgrade : Materials Research Society of Serbia., 74-74.
https://hdl.handle.net/21.15107/rcub_vinar_12406
Suljovrujić E, Rogić Miladinović Z, Miličević D, Mićić M. Temperature responsive hydrogels with ethylene glycol propylene glycol pendant chains. in YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : Programme and the book of abstracts. 2016;:74-74.
https://hdl.handle.net/21.15107/rcub_vinar_12406 .
Suljovrujić, Edin, Rogić Miladinović, Zorana, Miličević, Dejan, Mićić, Maja, "Temperature responsive hydrogels with ethylene glycol propylene glycol pendant chains" in YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : Programme and the book of abstracts (2016):74-74,
https://hdl.handle.net/21.15107/rcub_vinar_12406 .

Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate

Mićić, Maja M.; Rogić Miladinović, Zorana; Suljovrujić, Edin H.

(2016)

TY  - JOUR
AU  - Mićić, Maja M.
AU  - Rogić Miladinović, Zorana
AU  - Suljovrujić, Edin H.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/765
AB  - Gamma radiation was used to prepare copolymer hydrogel libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0% to 100% of OPGMA. Determination of gel fraction was performed as the first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study. Additional characterization of structure and properties was conducted by FTIR, DSC, and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition. [GRAPHICS] .
T2  - International Journal of Polymeric Materials and Polymeric Biomaterials
T1  - Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate
VL  - 65
IS  - 1
SP  - 18
EP  - 27
DO  - 10.1080/00914037.2015.1055627
ER  - 
@article{
author = "Mićić, Maja M. and Rogić Miladinović, Zorana and Suljovrujić, Edin H.",
year = "2016",
abstract = "Gamma radiation was used to prepare copolymer hydrogel libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0% to 100% of OPGMA. Determination of gel fraction was performed as the first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study. Additional characterization of structure and properties was conducted by FTIR, DSC, and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition. [GRAPHICS] .",
journal = "International Journal of Polymeric Materials and Polymeric Biomaterials",
title = "Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate",
volume = "65",
number = "1",
pages = "18-27",
doi = "10.1080/00914037.2015.1055627"
}
Mićić, M. M., Rogić Miladinović, Z.,& Suljovrujić, E. H.. (2016). Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate. in International Journal of Polymeric Materials and Polymeric Biomaterials, 65(1), 18-27.
https://doi.org/10.1080/00914037.2015.1055627
Mićić MM, Rogić Miladinović Z, Suljovrujić EH. Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate. in International Journal of Polymeric Materials and Polymeric Biomaterials. 2016;65(1):18-27.
doi:10.1080/00914037.2015.1055627 .
Mićić, Maja M., Rogić Miladinović, Zorana, Suljovrujić, Edin H., "Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate" in International Journal of Polymeric Materials and Polymeric Biomaterials, 65, no. 1 (2016):18-27,
https://doi.org/10.1080/00914037.2015.1055627 . .
11
9
11

Temperature/pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study

Rogić Miladinović, Zorana; Mićić, Maja M.; Suljovrujić, Edin H.

(Springer, 2016)

TY  - JOUR
AU  - Rogić Miladinović, Zorana
AU  - Mićić, Maja M.
AU  - Suljovrujić, Edin H.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/989
AB  - The purpose of this study was to attain oligo(propylene glycol) methacrylate (OPGMA) based hydrogels for different biomedical applications. Since the volume phase transition temperature (VPTT) of poly(oligo(propylene glycol) methacrylate) (POPGMA) homopolymer was below room temperature, it was necessary to tune the thermoresponsiveness and the VPTT to higher temperatures; radical copolymerisation of OPGMA with more hydrophilic and/or pH responsive monomers was used to adjust these values. A series of copolymeric hydrogels with different ratios of OPGMA, 2-hydroxyethyl methacrylate (HEMA) and itaconic acid (IA) was synthesised by gamma radiation. The swelling properties were preliminarily investigated over a wide pH (2.2-9.0) and temperature (4-80 degrees C) ranges. Additional characterization of their structure and properties was conducted by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The presented results revealed temperature/pH dual responsive P(OPGMA/IA) and P(OPGMA/HEMA/IA) copolymers with large diversity in swelling properties, as a result of the addition of OPGMA thermoresponsive units with a lower critical solution temperature (LCST) and IA pH responsive units. It was demonstrated that VPTT can be significantly shifted to higher (e. g. body) temperatures at higher pH values (pH = 4) by increasing the IA content in the hydrogel composition. Due to the possibility of making dual responsive copolymers in the manner explained in this paper, OPGMA based hydrogels show potential for different biomedical applications.
PB  - Springer
T2  - Journal of Polymer Research
T1  - Temperature/pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study
VL  - 23
IS  - 4
DO  - 10.1007/s10965-016-0975-8
ER  - 
@article{
author = "Rogić Miladinović, Zorana and Mićić, Maja M. and Suljovrujić, Edin H.",
year = "2016",
abstract = "The purpose of this study was to attain oligo(propylene glycol) methacrylate (OPGMA) based hydrogels for different biomedical applications. Since the volume phase transition temperature (VPTT) of poly(oligo(propylene glycol) methacrylate) (POPGMA) homopolymer was below room temperature, it was necessary to tune the thermoresponsiveness and the VPTT to higher temperatures; radical copolymerisation of OPGMA with more hydrophilic and/or pH responsive monomers was used to adjust these values. A series of copolymeric hydrogels with different ratios of OPGMA, 2-hydroxyethyl methacrylate (HEMA) and itaconic acid (IA) was synthesised by gamma radiation. The swelling properties were preliminarily investigated over a wide pH (2.2-9.0) and temperature (4-80 degrees C) ranges. Additional characterization of their structure and properties was conducted by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The presented results revealed temperature/pH dual responsive P(OPGMA/IA) and P(OPGMA/HEMA/IA) copolymers with large diversity in swelling properties, as a result of the addition of OPGMA thermoresponsive units with a lower critical solution temperature (LCST) and IA pH responsive units. It was demonstrated that VPTT can be significantly shifted to higher (e. g. body) temperatures at higher pH values (pH = 4) by increasing the IA content in the hydrogel composition. Due to the possibility of making dual responsive copolymers in the manner explained in this paper, OPGMA based hydrogels show potential for different biomedical applications.",
publisher = "Springer",
journal = "Journal of Polymer Research",
title = "Temperature/pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study",
volume = "23",
number = "4",
doi = "10.1007/s10965-016-0975-8"
}
Rogić Miladinović, Z., Mićić, M. M.,& Suljovrujić, E. H.. (2016). Temperature/pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study. in Journal of Polymer Research
Springer., 23(4).
https://doi.org/10.1007/s10965-016-0975-8
Rogić Miladinović Z, Mićić MM, Suljovrujić EH. Temperature/pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study. in Journal of Polymer Research. 2016;23(4).
doi:10.1007/s10965-016-0975-8 .
Rogić Miladinović, Zorana, Mićić, Maja M., Suljovrujić, Edin H., "Temperature/pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study" in Journal of Polymer Research, 23, no. 4 (2016),
https://doi.org/10.1007/s10965-016-0975-8 . .
16
11
15

The influence of gradient copolymerisation poly(oligo(propylene glycol) methacrylate) hydrogels with 2-hydroxyethyl methacrylate on thermoresponsive properties

Mićić, Maja; Rogić Miladinović, Zorana; Miličević, Dejan; Suljovrujić, Edin

(Belgrade : Materials Research Society of Serbia, 2015)

TY  - CONF
AU  - Mićić, Maja
AU  - Rogić Miladinović, Zorana
AU  - Miličević, Dejan
AU  - Suljovrujić, Edin
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12405
AB  - Gamma radiation was used to prepare copolymer libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0 to 100% of OPGMA. Determination of gel fraction was performed as a first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study; the swelling properties were preliminary investigated over the wide pH (2.2-9.0) and temperature (4-80°C) ranges. It has been observed that P(OPGMA/HEMA) hydrogels followed a simple rule in their thermoresponsive behaviour showing a linear increase in VPTT with a decreasing wt% of OPGMA in the copolymer composition. Additional characterisation of the structure and properties was conducted by FTIR, DSC and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts
T1  - The influence of gradient copolymerisation poly(oligo(propylene glycol) methacrylate) hydrogels with 2-hydroxyethyl methacrylate on thermoresponsive properties
SP  - 87
EP  - 87
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12405
ER  - 
@conference{
author = "Mićić, Maja and Rogić Miladinović, Zorana and Miličević, Dejan and Suljovrujić, Edin",
year = "2015",
abstract = "Gamma radiation was used to prepare copolymer libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0 to 100% of OPGMA. Determination of gel fraction was performed as a first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study; the swelling properties were preliminary investigated over the wide pH (2.2-9.0) and temperature (4-80°C) ranges. It has been observed that P(OPGMA/HEMA) hydrogels followed a simple rule in their thermoresponsive behaviour showing a linear increase in VPTT with a decreasing wt% of OPGMA in the copolymer composition. Additional characterisation of the structure and properties was conducted by FTIR, DSC and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts",
title = "The influence of gradient copolymerisation poly(oligo(propylene glycol) methacrylate) hydrogels with 2-hydroxyethyl methacrylate on thermoresponsive properties",
pages = "87-87",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12405"
}
Mićić, M., Rogić Miladinović, Z., Miličević, D.,& Suljovrujić, E.. (2015). The influence of gradient copolymerisation poly(oligo(propylene glycol) methacrylate) hydrogels with 2-hydroxyethyl methacrylate on thermoresponsive properties. in Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts
Belgrade : Materials Research Society of Serbia., 87-87.
https://hdl.handle.net/21.15107/rcub_vinar_12405
Mićić M, Rogić Miladinović Z, Miličević D, Suljovrujić E. The influence of gradient copolymerisation poly(oligo(propylene glycol) methacrylate) hydrogels with 2-hydroxyethyl methacrylate on thermoresponsive properties. in Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts. 2015;:87-87.
https://hdl.handle.net/21.15107/rcub_vinar_12405 .
Mićić, Maja, Rogić Miladinović, Zorana, Miličević, Dejan, Suljovrujić, Edin, "The influence of gradient copolymerisation poly(oligo(propylene glycol) methacrylate) hydrogels with 2-hydroxyethyl methacrylate on thermoresponsive properties" in Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts (2015):87-87,
https://hdl.handle.net/21.15107/rcub_vinar_12405 .

Femtosecond laser surface patterning of steel and titanium alloy

Milovanović, Dubravka S.; Gaković, Biljana M.; Radu, C.; Zamfirescu, M.; Radak, Bojan; Petrović, Suzana; Rogić Miladinović, Zorana; Mihailescu, Ion N.

(2014)

TY  - JOUR
AU  - Milovanović, Dubravka S.
AU  - Gaković, Biljana M.
AU  - Radu, C.
AU  - Zamfirescu, M.
AU  - Radak, Bojan
AU  - Petrović, Suzana
AU  - Rogić Miladinović, Zorana
AU  - Mihailescu, Ion N.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7058
AB  - In this work, we present the results obtained by femtosecond laser processing of AISI D2 steel and the widely applicable titanium-based alloy, Ti6Al4V. Patterning the materials surfaces was done by a Ti: sapphire system at 775 nm wavelength and 200 fs pulse duration, while varying the output pulse energies and the scanning speed. The formation of laser-induced periodical surface structures were found for both materials.
T2  - Physica Scripta
T1  - Femtosecond laser surface patterning of steel and titanium alloy
VL  - T162
DO  - 10.1088/0031-8949/2014/T162/014017
ER  - 
@article{
author = "Milovanović, Dubravka S. and Gaković, Biljana M. and Radu, C. and Zamfirescu, M. and Radak, Bojan and Petrović, Suzana and Rogić Miladinović, Zorana and Mihailescu, Ion N.",
year = "2014",
abstract = "In this work, we present the results obtained by femtosecond laser processing of AISI D2 steel and the widely applicable titanium-based alloy, Ti6Al4V. Patterning the materials surfaces was done by a Ti: sapphire system at 775 nm wavelength and 200 fs pulse duration, while varying the output pulse energies and the scanning speed. The formation of laser-induced periodical surface structures were found for both materials.",
journal = "Physica Scripta",
title = "Femtosecond laser surface patterning of steel and titanium alloy",
volume = "T162",
doi = "10.1088/0031-8949/2014/T162/014017"
}
Milovanović, D. S., Gaković, B. M., Radu, C., Zamfirescu, M., Radak, B., Petrović, S., Rogić Miladinović, Z.,& Mihailescu, I. N.. (2014). Femtosecond laser surface patterning of steel and titanium alloy. in Physica Scripta, T162.
https://doi.org/10.1088/0031-8949/2014/T162/014017
Milovanović DS, Gaković BM, Radu C, Zamfirescu M, Radak B, Petrović S, Rogić Miladinović Z, Mihailescu IN. Femtosecond laser surface patterning of steel and titanium alloy. in Physica Scripta. 2014;T162.
doi:10.1088/0031-8949/2014/T162/014017 .
Milovanović, Dubravka S., Gaković, Biljana M., Radu, C., Zamfirescu, M., Radak, Bojan, Petrović, Suzana, Rogić Miladinović, Zorana, Mihailescu, Ion N., "Femtosecond laser surface patterning of steel and titanium alloy" in Physica Scripta, T162 (2014),
https://doi.org/10.1088/0031-8949/2014/T162/014017 . .
10
7
11

MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation

Cvetićanin, Jelena M.; Koteski, Vasil J.; Belošević-Čavor, Jelena; Radosavljević, Aleksandra; Kačarević-Popović, Zorica M.; Trpkov, Đorđe; Aćimović, Danka D.; Rogić Miladinović, Zorana; Cindrić, Mario; Nešković, Olivera M.

(2013)

TY  - JOUR
AU  - Cvetićanin, Jelena M.
AU  - Koteski, Vasil J.
AU  - Belošević-Čavor, Jelena
AU  - Radosavljević, Aleksandra
AU  - Kačarević-Popović, Zorica M.
AU  - Trpkov, Đorđe
AU  - Aćimović, Danka D.
AU  - Rogić Miladinović, Zorana
AU  - Cindrić, Mario
AU  - Nešković, Olivera M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5207
AB  - The aim of this study is to evaluate the size and stability of radiolytically produced silver clusters. The clusters obtained by the gamma irradiation of a mixture of a silver salt and polyvinyl alcohol (PVA) were studied both theoretically and by mass spectrometry. MALDI TOF mass spectrometry of the Ag-n clusters showed the presence of clusters containing between 5 and 29 atoms. Both the theoretical and experimental results of this paper show that the most stable clusters are small clusters with an odd number of atoms. The stability of these clusters is correlated with the clusters electronic configuration. (C) 2012 Elsevier Ltd. All rights reserved.
T2  - Vacuum
T1  - MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation
VL  - 89
IS  - SI
SP  - 47
EP  - 52
DO  - 10.1016/j.vacuum.2012.08.016
ER  - 
@article{
author = "Cvetićanin, Jelena M. and Koteski, Vasil J. and Belošević-Čavor, Jelena and Radosavljević, Aleksandra and Kačarević-Popović, Zorica M. and Trpkov, Đorđe and Aćimović, Danka D. and Rogić Miladinović, Zorana and Cindrić, Mario and Nešković, Olivera M.",
year = "2013",
abstract = "The aim of this study is to evaluate the size and stability of radiolytically produced silver clusters. The clusters obtained by the gamma irradiation of a mixture of a silver salt and polyvinyl alcohol (PVA) were studied both theoretically and by mass spectrometry. MALDI TOF mass spectrometry of the Ag-n clusters showed the presence of clusters containing between 5 and 29 atoms. Both the theoretical and experimental results of this paper show that the most stable clusters are small clusters with an odd number of atoms. The stability of these clusters is correlated with the clusters electronic configuration. (C) 2012 Elsevier Ltd. All rights reserved.",
journal = "Vacuum",
title = "MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation",
volume = "89",
number = "SI",
pages = "47-52",
doi = "10.1016/j.vacuum.2012.08.016"
}
Cvetićanin, J. M., Koteski, V. J., Belošević-Čavor, J., Radosavljević, A., Kačarević-Popović, Z. M., Trpkov, Đ., Aćimović, D. D., Rogić Miladinović, Z., Cindrić, M.,& Nešković, O. M.. (2013). MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation. in Vacuum, 89(SI), 47-52.
https://doi.org/10.1016/j.vacuum.2012.08.016
Cvetićanin JM, Koteski VJ, Belošević-Čavor J, Radosavljević A, Kačarević-Popović ZM, Trpkov Đ, Aćimović DD, Rogić Miladinović Z, Cindrić M, Nešković OM. MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation. in Vacuum. 2013;89(SI):47-52.
doi:10.1016/j.vacuum.2012.08.016 .
Cvetićanin, Jelena M., Koteski, Vasil J., Belošević-Čavor, Jelena, Radosavljević, Aleksandra, Kačarević-Popović, Zorica M., Trpkov, Đorđe, Aćimović, Danka D., Rogić Miladinović, Zorana, Cindrić, Mario, Nešković, Olivera M., "MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation" in Vacuum, 89, no. SI (2013):47-52,
https://doi.org/10.1016/j.vacuum.2012.08.016 . .
7
7
7

MALDI TOF and AFM studies of DNA/SWNT hybrids

Trpkov, Đorđe; Rogić Miladinović, Zorana; Aćimović, Danka D.; Cvetićanin, Jelena M.; Rakočević, Zlatko Lj.; Nešković, Olivera M.

(Society of Physical Chemists of Serbia, 2012)

TY  - CONF
AU  - Trpkov, Đorđe
AU  - Rogić Miladinović, Zorana
AU  - Aćimović, Danka D.
AU  - Cvetićanin, Jelena M.
AU  - Rakočević, Zlatko Lj.
AU  - Nešković, Olivera M.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9270
AB  - A primer is a strand of nucleic acid that serves as a starting point for DNA
synthesis. DNA, as a large molecule, is very difficult for analysis by means of mass
spectrometry. However, primer, as a short sequence of nucleic acid, is much more
convinient for e.g. MALDI TOF MS analysis. Mass spectrometric experiment
resulted in quality MALDI TOF spectra of 3 primers. Compound 3-HPA (3-
hydroxypicolinic acid) showed the best results as matrix. AFM studies were also
conducted, for both pure primer samples and hybrids of primer molecule with
single wall carbon nanotubes (SWNT). Thus, obtained functionalisation of SWNT
with DNA primers was confirmed by AFM imaging. AFM images clearly showed
wrapping of DNA structures around nanotube „template“. Functionalisation of
SWNT is very important for potential applications of nanotubes in biomedical
field. MALDI TOF mass spectrometry, in combination with AFM imaging, proved
its great potential in analysis of short DNA sequences, and indicated the possibility
of investigating more complex DNA structures.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
T1  - MALDI TOF and AFM studies of DNA/SWNT hybrids
VL  - 1
SP  - 125
EP  - 127
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9270
ER  - 
@conference{
author = "Trpkov, Đorđe and Rogić Miladinović, Zorana and Aćimović, Danka D. and Cvetićanin, Jelena M. and Rakočević, Zlatko Lj. and Nešković, Olivera M.",
year = "2012",
abstract = "A primer is a strand of nucleic acid that serves as a starting point for DNA
synthesis. DNA, as a large molecule, is very difficult for analysis by means of mass
spectrometry. However, primer, as a short sequence of nucleic acid, is much more
convinient for e.g. MALDI TOF MS analysis. Mass spectrometric experiment
resulted in quality MALDI TOF spectra of 3 primers. Compound 3-HPA (3-
hydroxypicolinic acid) showed the best results as matrix. AFM studies were also
conducted, for both pure primer samples and hybrids of primer molecule with
single wall carbon nanotubes (SWNT). Thus, obtained functionalisation of SWNT
with DNA primers was confirmed by AFM imaging. AFM images clearly showed
wrapping of DNA structures around nanotube „template“. Functionalisation of
SWNT is very important for potential applications of nanotubes in biomedical
field. MALDI TOF mass spectrometry, in combination with AFM imaging, proved
its great potential in analysis of short DNA sequences, and indicated the possibility
of investigating more complex DNA structures.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry",
title = "MALDI TOF and AFM studies of DNA/SWNT hybrids",
volume = "1",
pages = "125-127",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9270"
}
Trpkov, Đ., Rogić Miladinović, Z., Aćimović, D. D., Cvetićanin, J. M., Rakočević, Z. Lj.,& Nešković, O. M.. (2012). MALDI TOF and AFM studies of DNA/SWNT hybrids. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia., 1, 125-127.
https://hdl.handle.net/21.15107/rcub_vinar_9270
Trpkov Đ, Rogić Miladinović Z, Aćimović DD, Cvetićanin JM, Rakočević ZL, Nešković OM. MALDI TOF and AFM studies of DNA/SWNT hybrids. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry. 2012;1:125-127.
https://hdl.handle.net/21.15107/rcub_vinar_9270 .
Trpkov, Đorđe, Rogić Miladinović, Zorana, Aćimović, Danka D., Cvetićanin, Jelena M., Rakočević, Zlatko Lj., Nešković, Olivera M., "MALDI TOF and AFM studies of DNA/SWNT hybrids" in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry, 1 (2012):125-127,
https://hdl.handle.net/21.15107/rcub_vinar_9270 .

Collagen Structure and Morphology Analysis by TEM and AFM

Rogić Miladinović, Zorana; Aćimović, D.; Trpkov, Đorđe; Cvetićanin, Jelena; Bibić, Nataša; Rakočević, Zlatko; Nešković, Olivera M.

(Belgrade : Materials Research Society of Serbia, 2012)

TY  - CONF
AU  - Rogić Miladinović, Zorana
AU  - Aćimović, D.
AU  - Trpkov, Đorđe
AU  - Cvetićanin, Jelena
AU  - Bibić, Nataša
AU  - Rakočević, Zlatko
AU  - Nešković, Olivera M.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12404
AB  - Collagens, one of the most abundant on the Earth, are family of proteins which constitute the basis of connective tissue (extracellular matrix) in multicellular organisms. We used collagen type II from bovine Achilles tendon. In further work, collagen has been studied by transmission electron microscopy (TEM) and atomic force microscopy (AFM). Using TEM we successfully obtained images of collagen and whole collagen fibrils. Using AFM we captured images of whole collagen as well as images of fragments from collagenase-treated collagen (it was digested with collagenase from Clostridium histolycium). AFM images of collagenase-treated collagen showed many fibrils grouping into large bundles – collagen fiber. Based on obtained images we studied surface morphology, shape and length of fragments from collagenase-treated collagen.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts
T1  - Collagen Structure and Morphology Analysis by TEM and AFM
SP  - 112
EP  - 112
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12404
ER  - 
@conference{
author = "Rogić Miladinović, Zorana and Aćimović, D. and Trpkov, Đorđe and Cvetićanin, Jelena and Bibić, Nataša and Rakočević, Zlatko and Nešković, Olivera M.",
year = "2012",
abstract = "Collagens, one of the most abundant on the Earth, are family of proteins which constitute the basis of connective tissue (extracellular matrix) in multicellular organisms. We used collagen type II from bovine Achilles tendon. In further work, collagen has been studied by transmission electron microscopy (TEM) and atomic force microscopy (AFM). Using TEM we successfully obtained images of collagen and whole collagen fibrils. Using AFM we captured images of whole collagen as well as images of fragments from collagenase-treated collagen (it was digested with collagenase from Clostridium histolycium). AFM images of collagenase-treated collagen showed many fibrils grouping into large bundles – collagen fiber. Based on obtained images we studied surface morphology, shape and length of fragments from collagenase-treated collagen.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts",
title = "Collagen Structure and Morphology Analysis by TEM and AFM",
pages = "112-112",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12404"
}
Rogić Miladinović, Z., Aćimović, D., Trpkov, Đ., Cvetićanin, J., Bibić, N., Rakočević, Z.,& Nešković, O. M.. (2012). Collagen Structure and Morphology Analysis by TEM and AFM. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 112-112.
https://hdl.handle.net/21.15107/rcub_vinar_12404
Rogić Miladinović Z, Aćimović D, Trpkov Đ, Cvetićanin J, Bibić N, Rakočević Z, Nešković OM. Collagen Structure and Morphology Analysis by TEM and AFM. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts. 2012;:112-112.
https://hdl.handle.net/21.15107/rcub_vinar_12404 .
Rogić Miladinović, Zorana, Aćimović, D., Trpkov, Đorđe, Cvetićanin, Jelena, Bibić, Nataša, Rakočević, Zlatko, Nešković, Olivera M., "Collagen Structure and Morphology Analysis by TEM and AFM" in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts (2012):112-112,
https://hdl.handle.net/21.15107/rcub_vinar_12404 .

MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite

Đorđević, Aleksandar; Seke, Mariana; Trpkov, Đorđe; Cvetićanin, Jelena; Rogić Miladinović, Zorana; Aćimović, Danka; Demajo, Miroslav; Nešković, Olivera; Rakočević, Zlatko

(Belgrade : Vinča Institute of Nuclear Sciences, 2012)

TY  - CONF
AU  - Đorđević, Aleksandar
AU  - Seke, Mariana
AU  - Trpkov, Đorđe
AU  - Cvetićanin, Jelena
AU  - Rogić Miladinović, Zorana
AU  - Aćimović, Danka
AU  - Demajo, Miroslav
AU  - Nešković, Olivera
AU  - Rakočević, Zlatko
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12409
PB  - Belgrade : Vinča Institute of Nuclear Sciences
C3  - 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings
T1  - MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite
SP  - 34
EP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12409
ER  - 
@conference{
author = "Đorđević, Aleksandar and Seke, Mariana and Trpkov, Đorđe and Cvetićanin, Jelena and Rogić Miladinović, Zorana and Aćimović, Danka and Demajo, Miroslav and Nešković, Olivera and Rakočević, Zlatko",
year = "2012",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences",
journal = "3rd Workshop Specific Methods for Food Safety and Quality : Proceedings",
title = "MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite",
pages = "34-38",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12409"
}
Đorđević, A., Seke, M., Trpkov, Đ., Cvetićanin, J., Rogić Miladinović, Z., Aćimović, D., Demajo, M., Nešković, O.,& Rakočević, Z.. (2012). MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite. in 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings
Belgrade : Vinča Institute of Nuclear Sciences., 34-38.
https://hdl.handle.net/21.15107/rcub_vinar_12409
Đorđević A, Seke M, Trpkov Đ, Cvetićanin J, Rogić Miladinović Z, Aćimović D, Demajo M, Nešković O, Rakočević Z. MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite. in 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings. 2012;:34-38.
https://hdl.handle.net/21.15107/rcub_vinar_12409 .
Đorđević, Aleksandar, Seke, Mariana, Trpkov, Đorđe, Cvetićanin, Jelena, Rogić Miladinović, Zorana, Aćimović, Danka, Demajo, Miroslav, Nešković, Olivera, Rakočević, Zlatko, "MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite" in 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings (2012):34-38,
https://hdl.handle.net/21.15107/rcub_vinar_12409 .

MALDI TOF Mass Spectrometry Characterization of Collagen

Aćimović, D.; Rogić Miladinović, Zorana; Cvetićanin, Jelena; Trpkov, Đorđe; Nešković, Olivera M.

(Belgrade : Materials Research Society of Serbia, 2012)

TY  - CONF
AU  - Aćimović, D.
AU  - Rogić Miladinović, Zorana
AU  - Cvetićanin, Jelena
AU  - Trpkov, Đorđe
AU  - Nešković, Olivera M.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12403
AB  - Collagen is the most frequently occuring fibrillar protein in mammals, which can be found in cartilage, tendon, bone, ligament, skin, etc. The structure of collagen is based on a complicated helix structure of single chains of amino acids (most abundant is glicine-Gly, proline-Pro and hydroxyproline-Hyp) which are connected by hydrogen bonds. We tried to establish MALDI method to get better resolution of collagen’s mass spectra. Digested collagen (type II from bovine Achilles tendon which was digested with collagenase from Clostridium histolycium) has been analysed on MALDI-TOF MS in order to find peptide’s fragments that are characteristic for collagen. In mass spetra we found peaks of peptides, which is highly indicative for collagen (GlyPro-Hyp, Gly-Pro-Asp, Gly-Pro-Glu ect.) We hope that it should be possible to obtain MS analysis and structure characterization of collagen by MALDI-TOF/TOF in future.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts
T1  - MALDI TOF Mass Spectrometry Characterization of Collagen
SP  - 112
EP  - 112
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12403
ER  - 
@conference{
author = "Aćimović, D. and Rogić Miladinović, Zorana and Cvetićanin, Jelena and Trpkov, Đorđe and Nešković, Olivera M.",
year = "2012",
abstract = "Collagen is the most frequently occuring fibrillar protein in mammals, which can be found in cartilage, tendon, bone, ligament, skin, etc. The structure of collagen is based on a complicated helix structure of single chains of amino acids (most abundant is glicine-Gly, proline-Pro and hydroxyproline-Hyp) which are connected by hydrogen bonds. We tried to establish MALDI method to get better resolution of collagen’s mass spectra. Digested collagen (type II from bovine Achilles tendon which was digested with collagenase from Clostridium histolycium) has been analysed on MALDI-TOF MS in order to find peptide’s fragments that are characteristic for collagen. In mass spetra we found peaks of peptides, which is highly indicative for collagen (GlyPro-Hyp, Gly-Pro-Asp, Gly-Pro-Glu ect.) We hope that it should be possible to obtain MS analysis and structure characterization of collagen by MALDI-TOF/TOF in future.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts",
title = "MALDI TOF Mass Spectrometry Characterization of Collagen",
pages = "112-112",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12403"
}
Aćimović, D., Rogić Miladinović, Z., Cvetićanin, J., Trpkov, Đ.,& Nešković, O. M.. (2012). MALDI TOF Mass Spectrometry Characterization of Collagen. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 112-112.
https://hdl.handle.net/21.15107/rcub_vinar_12403
Aćimović D, Rogić Miladinović Z, Cvetićanin J, Trpkov Đ, Nešković OM. MALDI TOF Mass Spectrometry Characterization of Collagen. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts. 2012;:112-112.
https://hdl.handle.net/21.15107/rcub_vinar_12403 .
Aćimović, D., Rogić Miladinović, Zorana, Cvetićanin, Jelena, Trpkov, Đorđe, Nešković, Olivera M., "MALDI TOF Mass Spectrometry Characterization of Collagen" in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts (2012):112-112,
https://hdl.handle.net/21.15107/rcub_vinar_12403 .

The calcification of collagen by HAP functionalized carbon materials

Nešković, Olivera M.; Rakočević, Zlatko; Bibić, Nataša; Cvetićanin, Jelena; Trpkov, Đorđe; Rogić, Zorana; Vlatković, Danka

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2011)

TY  - CONF
AU  - Nešković, Olivera M.
AU  - Rakočević, Zlatko
AU  - Bibić, Nataša
AU  - Cvetićanin, Jelena
AU  - Trpkov, Đorđe
AU  - Rogić, Zorana
AU  - Vlatković, Danka
PY  - 2011
UR  - http://www.ceramic-society.rs/wp-content/uploads/2018/11/Book-of-Abstracts-2011.pdf
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12402
AB  - Bone is composed of two phases. The organic phase is made of collagen fibrils assembled in broad fibers acting as a template for mineralization. The mineral phase comprises hydroxyapatite (HAP) crystals grown between and inside the collagen fibers. We have developed a material using functionalized carbon nanotubes, carbon fibers and glasy carbon as scaffold to initiate in vitro mineralization. Mentioned carbon materials are functionalized with carboxylic groups prior to decorating. All samples were dispersed in ultra-pure water and incubated for 2 weeks in a synthetic body fluid with dispersed HAP, in order to induce the calcification of the functionalized carbon materials. Atomic force microscopy (AFM) and transmision electron microscopy (TEM) showed that Ca2+ and PO4 3- ions were deposited as round-shaped nodules. Raman spectroscopic studies confirmed the HAP formation, and image analysis made on TEM pictures showed that HAP were packed around and inside the carbon materials together. All three types of investigated carbon materials leading to successful calcification of collagen. This suggests that it takes the presence of carbon materials to prevent it from calcification of collagen, independent of the structures of the material.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 1CSCS-2011 : 1st Conference of the Serbian Ceramic Materials : program and the book of abstracts; March 17-18, Belgrade
T1  - The calcification of collagen by HAP functionalized carbon materials
SP  - 50
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12402
ER  - 
@conference{
author = "Nešković, Olivera M. and Rakočević, Zlatko and Bibić, Nataša and Cvetićanin, Jelena and Trpkov, Đorđe and Rogić, Zorana and Vlatković, Danka",
year = "2011",
abstract = "Bone is composed of two phases. The organic phase is made of collagen fibrils assembled in broad fibers acting as a template for mineralization. The mineral phase comprises hydroxyapatite (HAP) crystals grown between and inside the collagen fibers. We have developed a material using functionalized carbon nanotubes, carbon fibers and glasy carbon as scaffold to initiate in vitro mineralization. Mentioned carbon materials are functionalized with carboxylic groups prior to decorating. All samples were dispersed in ultra-pure water and incubated for 2 weeks in a synthetic body fluid with dispersed HAP, in order to induce the calcification of the functionalized carbon materials. Atomic force microscopy (AFM) and transmision electron microscopy (TEM) showed that Ca2+ and PO4 3- ions were deposited as round-shaped nodules. Raman spectroscopic studies confirmed the HAP formation, and image analysis made on TEM pictures showed that HAP were packed around and inside the carbon materials together. All three types of investigated carbon materials leading to successful calcification of collagen. This suggests that it takes the presence of carbon materials to prevent it from calcification of collagen, independent of the structures of the material.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "1CSCS-2011 : 1st Conference of the Serbian Ceramic Materials : program and the book of abstracts; March 17-18, Belgrade",
title = "The calcification of collagen by HAP functionalized carbon materials",
pages = "50-50",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12402"
}
Nešković, O. M., Rakočević, Z., Bibić, N., Cvetićanin, J., Trpkov, Đ., Rogić, Z.,& Vlatković, D.. (2011). The calcification of collagen by HAP functionalized carbon materials. in 1CSCS-2011 : 1st Conference of the Serbian Ceramic Materials : program and the book of abstracts; March 17-18, Belgrade
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 50-50.
https://hdl.handle.net/21.15107/rcub_vinar_12402
Nešković OM, Rakočević Z, Bibić N, Cvetićanin J, Trpkov Đ, Rogić Z, Vlatković D. The calcification of collagen by HAP functionalized carbon materials. in 1CSCS-2011 : 1st Conference of the Serbian Ceramic Materials : program and the book of abstracts; March 17-18, Belgrade. 2011;:50-50.
https://hdl.handle.net/21.15107/rcub_vinar_12402 .
Nešković, Olivera M., Rakočević, Zlatko, Bibić, Nataša, Cvetićanin, Jelena, Trpkov, Đorđe, Rogić, Zorana, Vlatković, Danka, "The calcification of collagen by HAP functionalized carbon materials" in 1CSCS-2011 : 1st Conference of the Serbian Ceramic Materials : program and the book of abstracts; March 17-18, Belgrade (2011):50-50,
https://hdl.handle.net/21.15107/rcub_vinar_12402 .

The application of physicochemical methods for the analysis of radiation processed food products

Rogić, Zorana; Spasojević, I.; Ignjatović, A,; Mojović, M.

(Belgrade : Society of Physical Chemists of Serbia, 2010)

TY  - CONF
AU  - Rogić, Zorana
AU  - Spasojević, I.
AU  - Ignjatović, A,
AU  - Mojović, M.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12410
AB  - The aim of this study was to investigate the occurrence and stability of free radicals in freeze-dried samples of cow milk, pineapple and banana after irradiation (10 kGy dose), using the ESR spectroscopy, as well as to assess possible changes in their protein structure by means of electrophoresis.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry : Proceedings
T1  - The application of physicochemical methods for the analysis of radiation processed food products
SP  - 361
EP  - 363
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12410
ER  - 
@conference{
author = "Rogić, Zorana and Spasojević, I. and Ignjatović, A, and Mojović, M.",
year = "2010",
abstract = "The aim of this study was to investigate the occurrence and stability of free radicals in freeze-dried samples of cow milk, pineapple and banana after irradiation (10 kGy dose), using the ESR spectroscopy, as well as to assess possible changes in their protein structure by means of electrophoresis.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry : Proceedings",
title = "The application of physicochemical methods for the analysis of radiation processed food products",
pages = "361-363",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12410"
}
Rogić, Z., Spasojević, I., Ignjatović, A.,& Mojović, M.. (2010). The application of physicochemical methods for the analysis of radiation processed food products. in Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry : Proceedings
Belgrade : Society of Physical Chemists of Serbia., 361-363.
https://hdl.handle.net/21.15107/rcub_vinar_12410
Rogić Z, Spasojević I, Ignjatović A, Mojović M. The application of physicochemical methods for the analysis of radiation processed food products. in Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry : Proceedings. 2010;:361-363.
https://hdl.handle.net/21.15107/rcub_vinar_12410 .
Rogić, Zorana, Spasojević, I., Ignjatović, A,, Mojović, M., "The application of physicochemical methods for the analysis of radiation processed food products" in Physical chemistry 2010 : 10th international conference on fundamental and applied aspects of physical chemistry : Proceedings (2010):361-363,
https://hdl.handle.net/21.15107/rcub_vinar_12410 .