TY  - CONF
AU  - Grujičić, Marija
AU  - Jelić, Marko
AU  - Stojković Simatović, Ivana
AU  - Bajuk Bogdanović, Danica
AU  - Petković, Darija
AU  - Jovanović, Zoran
AU  - Jovanović, Sonja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12317
AB  - In this study, solvothermally synthesized nanoparticles of cobalt ferrite (CoFe2O4, CFO) and Zn/Ga-dopped cobalt ferrite (Co0.5Zn0.5Fe2O4, CFO_Zn and CoFe1.5Ga0.5O4, CFO_Ga, respectively) with dihydrocaffeic acid (DHCA) as a surfactant were examined for electrochemical detection of gallic acid. Based on X-ray diffraction analysis, diffraction maxima of all samples correspond to the cubic spinel phase, while transmission electron microscopy showed that the nanoparticles are non-agglomerated, sphere-like with an average size of 5±1 nm. The presence of DHCA on the surface of nanoparticles was confirmed by Fourier Transform Infrared Spectroscopy (FTIR). For the purpose of electrochemical detection of gallic acid the modified glassy carbon electrode (m-GCE) was prepared from CFO, CFO_Zn and CFO_Ga nanoparticles. Initial tests have shown instability/disintegration of m-GCE in aqueous solutions, because of which samples were annealed at 450 °C in air. Cyclic voltammograms of all annealed samples showed good reversibility in the system [Fe(CN)6] 3-/4- . The most efficient electron transfer was achieved when the mass ratio between sample and Nafion® was 85:15, respectively. The best sensitivity to gallic acid (10-4 M, in Britton-Robinson buffer) was observed for CFO_Zn sample. Results are showing that by selective functionalization and surface modification of nanoparticles, it is possible to optimize the electrochemical properties suitable for sensing, which is the basis of this method and the goal of further research.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Enhanced electrochemical detection of gallic acid using modified glassy carbon electrodes with Zn/Ga-dopped cobalt ferrite
SP  - 44
EP  - 44
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12317
ER  - 

@conference{
author = "Grujičić, Marija and Jelić, Marko and Stojković Simatović, Ivana and Bajuk Bogdanović, Danica and Petković, Darija and Jovanović, Zoran and Jovanović, Sonja",
year = "2023",
abstract = "In this study, solvothermally synthesized nanoparticles of cobalt ferrite (CoFe2O4, CFO) and Zn/Ga-dopped cobalt ferrite (Co0.5Zn0.5Fe2O4, CFO_Zn and CoFe1.5Ga0.5O4, CFO_Ga, respectively) with dihydrocaffeic acid (DHCA) as a surfactant were examined for electrochemical detection of gallic acid. Based on X-ray diffraction analysis, diffraction maxima of all samples correspond to the cubic spinel phase, while transmission electron microscopy showed that the nanoparticles are non-agglomerated, sphere-like with an average size of 5±1 nm. The presence of DHCA on the surface of nanoparticles was confirmed by Fourier Transform Infrared Spectroscopy (FTIR). For the purpose of electrochemical detection of gallic acid the modified glassy carbon electrode (m-GCE) was prepared from CFO, CFO_Zn and CFO_Ga nanoparticles. Initial tests have shown instability/disintegration of m-GCE in aqueous solutions, because of which samples were annealed at 450 °C in air. Cyclic voltammograms of all annealed samples showed good reversibility in the system [Fe(CN)6] 3-/4- . The most efficient electron transfer was achieved when the mass ratio between sample and Nafion® was 85:15, respectively. The best sensitivity to gallic acid (10-4 M, in Britton-Robinson buffer) was observed for CFO_Zn sample. Results are showing that by selective functionalization and surface modification of nanoparticles, it is possible to optimize the electrochemical properties suitable for sensing, which is the basis of this method and the goal of further research.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Enhanced electrochemical detection of gallic acid using modified glassy carbon electrodes with Zn/Ga-dopped cobalt ferrite",
pages = "44-44",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12317"
}

Grujičić, M., Jelić, M., Stojković Simatović, I., Bajuk Bogdanović, D., Petković, D., Jovanović, Z.,& Jovanović, S.. (2023). Enhanced electrochemical detection of gallic acid using modified glassy carbon electrodes with Zn/Ga-dopped cobalt ferrite. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 44-44.
https://hdl.handle.net/21.15107/rcub_vinar_12317

Grujičić M, Jelić M, Stojković Simatović I, Bajuk Bogdanović D, Petković D, Jovanović Z, Jovanović S. Enhanced electrochemical detection of gallic acid using modified glassy carbon electrodes with Zn/Ga-dopped cobalt ferrite. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:44-44.
https://hdl.handle.net/21.15107/rcub_vinar_12317 .

Grujičić, Marija, Jelić, Marko, Stojković Simatović, Ivana, Bajuk Bogdanović, Danica, Petković, Darija, Jovanović, Zoran, Jovanović, Sonja, "Enhanced electrochemical detection of gallic acid using modified glassy carbon electrodes with Zn/Ga-dopped cobalt ferrite" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):44-44,
https://hdl.handle.net/21.15107/rcub_vinar_12317 .

TY  - JOUR
AU  - Rmuš Mravik, Jelena
AU  - Milanović, Igor
AU  - Milošević Govedarović, Sanja
AU  - Mraković, Ana
AU  - Korneeva, Ekaterina
AU  - Stojković Simatović, Ivana
AU  - Kurko, Sandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11187
AB  - Molybdenum disulfide (MoS2) is considered promising noble metal-free catalysts for the hydrogen evolution reaction (HER). Whereas the bulk MoS2 does not exhibit significant activity, the catalytic properties of various nanostructures are noticeable. Therefore we synthesized flower-like molybdenum disulfide with the simple, one-step hydrothermal method. To enhance the catalytic activity of the material, low-energy ion irradiation is employed. As-prepared MoS2 is irradiated with hydrogen and carbon ions of various energies (20–40 keV) and fluences (1014-1017 ion/cm2). Our results show that irradiation has beneficial influence on MoS2 catalytic activity toward hydrogen evolution reaction. By producing morphological changes and defects in the structure, ion irradiation also impacts the conductivity of the material, which shows predominant effect on hydrogen evolution. The increase of current density at an overpotential of 300 mV with hydrogen ion irradiation is even 6 times higher than for as-synthesized catalyst.
T2  - International Journal of Hydrogen Energy
T1  - Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation
VL  - 48
IS  - 98
SP  - 38676
EP  - 38685
DO  - 10.1016/j.ijhydene.2023.06.178
ER  - 

@article{
author = "Rmuš Mravik, Jelena and Milanović, Igor and Milošević Govedarović, Sanja and Mraković, Ana and Korneeva, Ekaterina and Stojković Simatović, Ivana and Kurko, Sandra",
year = "2023",
abstract = "Molybdenum disulfide (MoS2) is considered promising noble metal-free catalysts for the hydrogen evolution reaction (HER). Whereas the bulk MoS2 does not exhibit significant activity, the catalytic properties of various nanostructures are noticeable. Therefore we synthesized flower-like molybdenum disulfide with the simple, one-step hydrothermal method. To enhance the catalytic activity of the material, low-energy ion irradiation is employed. As-prepared MoS2 is irradiated with hydrogen and carbon ions of various energies (20–40 keV) and fluences (1014-1017 ion/cm2). Our results show that irradiation has beneficial influence on MoS2 catalytic activity toward hydrogen evolution reaction. By producing morphological changes and defects in the structure, ion irradiation also impacts the conductivity of the material, which shows predominant effect on hydrogen evolution. The increase of current density at an overpotential of 300 mV with hydrogen ion irradiation is even 6 times higher than for as-synthesized catalyst.",
journal = "International Journal of Hydrogen Energy",
title = "Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation",
volume = "48",
number = "98",
pages = "38676-38685",
doi = "10.1016/j.ijhydene.2023.06.178"
}

Rmuš Mravik, J., Milanović, I., Milošević Govedarović, S., Mraković, A., Korneeva, E., Stojković Simatović, I.,& Kurko, S.. (2023). Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation. in International Journal of Hydrogen Energy, 48(98), 38676-38685.
https://doi.org/10.1016/j.ijhydene.2023.06.178

Rmuš Mravik J, Milanović I, Milošević Govedarović S, Mraković A, Korneeva E, Stojković Simatović I, Kurko S. Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation. in International Journal of Hydrogen Energy. 2023;48(98):38676-38685.
doi:10.1016/j.ijhydene.2023.06.178 .

Rmuš Mravik, Jelena, Milanović, Igor, Milošević Govedarović, Sanja, Mraković, Ana, Korneeva, Ekaterina, Stojković Simatović, Ivana, Kurko, Sandra, "Improvement of MoS2 electrocatalytic activity for hydrogen evolution reaction by ion irradiation" in International Journal of Hydrogen Energy, 48, no. 98 (2023):38676-38685,
https://doi.org/10.1016/j.ijhydene.2023.06.178 . .

TY  - JOUR
AU  - Aleksić, Katarina
AU  - Stojković Simatović, Ivana
AU  - Stanković, Ana
AU  - Veselinović, Ljiljana
AU  - Stojadinović, Stevan
AU  - Rac, Vladislav
AU  - Radmilović, Nadežda
AU  - Rajić, Vladimir
AU  - Škapin, Srečo Davor
AU  - Mančić, Lidija
AU  - Marković, Smilja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11080
AB  - Catalytic materials are the greatest challenge for the commercial application of water electrolysis (WEs) and fuel cells (FCs) as clean energy technologies. There is a need to find an alternative to expensive and unavailable platinum group metal (PGM) catalysts. This study aimed to reduce the cost of PGM materials by replacing Ru with RuO2 and lowering the amount of RuO2 by adding abundant and multifunctional ZnO. A ZnO@RuO2 composite in a 10:1 molar ratio was synthesized by microwave processing of a precipitate as a green, low-cost, and fast method, and then annealed at 300°C and 600°C to improve the catalytic properties. The physicochemical properties of the ZnO@RuO2 composites were investigated by X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The electrochemical activity of the samples was investigated by linear sweep voltammetry in acidic and alkaline electrolytes. We observed good bifunctional catalytic activity of the ZnO@RuO2 composites toward HER and OER in both electrolytes. The improved bifunctional catalytic activity of the ZnO@RuO2 composite by annealing was discussed and attributed to the reduced number of bulk oxygen vacancies and the increased number of established heterojunctions.
T2  - Frontiers in Chemistry
T1  - Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting
VL  - 11
DO  - 10.3389/fchem.2023.1173910
ER  - 

@article{
author = "Aleksić, Katarina and Stojković Simatović, Ivana and Stanković, Ana and Veselinović, Ljiljana and Stojadinović, Stevan and Rac, Vladislav and Radmilović, Nadežda and Rajić, Vladimir and Škapin, Srečo Davor and Mančić, Lidija and Marković, Smilja",
year = "2023",
abstract = "Catalytic materials are the greatest challenge for the commercial application of water electrolysis (WEs) and fuel cells (FCs) as clean energy technologies. There is a need to find an alternative to expensive and unavailable platinum group metal (PGM) catalysts. This study aimed to reduce the cost of PGM materials by replacing Ru with RuO2 and lowering the amount of RuO2 by adding abundant and multifunctional ZnO. A ZnO@RuO2 composite in a 10:1 molar ratio was synthesized by microwave processing of a precipitate as a green, low-cost, and fast method, and then annealed at 300°C and 600°C to improve the catalytic properties. The physicochemical properties of the ZnO@RuO2 composites were investigated by X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The electrochemical activity of the samples was investigated by linear sweep voltammetry in acidic and alkaline electrolytes. We observed good bifunctional catalytic activity of the ZnO@RuO2 composites toward HER and OER in both electrolytes. The improved bifunctional catalytic activity of the ZnO@RuO2 composite by annealing was discussed and attributed to the reduced number of bulk oxygen vacancies and the increased number of established heterojunctions.",
journal = "Frontiers in Chemistry",
title = "Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting",
volume = "11",
doi = "10.3389/fchem.2023.1173910"
}

Aleksić, K., Stojković Simatović, I., Stanković, A., Veselinović, L., Stojadinović, S., Rac, V., Radmilović, N., Rajić, V., Škapin, S. D., Mančić, L.,& Marković, S.. (2023). Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting. in Frontiers in Chemistry, 11.
https://doi.org/10.3389/fchem.2023.1173910

Aleksić K, Stojković Simatović I, Stanković A, Veselinović L, Stojadinović S, Rac V, Radmilović N, Rajić V, Škapin SD, Mančić L, Marković S. Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting. in Frontiers in Chemistry. 2023;11.
doi:10.3389/fchem.2023.1173910 .

Aleksić, Katarina, Stojković Simatović, Ivana, Stanković, Ana, Veselinović, Ljiljana, Stojadinović, Stevan, Rac, Vladislav, Radmilović, Nadežda, Rajić, Vladimir, Škapin, Srečo Davor, Mančić, Lidija, Marković, Smilja, "Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting" in Frontiers in Chemistry, 11 (2023),
https://doi.org/10.3389/fchem.2023.1173910 . .

TY  - CONF
AU  - Rajić, Vladimir
AU  - Marković, Smilja
AU  - Popović, M.
AU  - Novaković, M.
AU  - Veselinović, Ljiljana
AU  - Stojković Simatović, Ivana
AU  - Škapin, Srečo Davor
AU  - Stojanović, S.
AU  - Rac, Vladislav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11554
AB  - Zink oxide-based materials have a great potential to be applied in photo and electro catalysts, opto-electronic (indoor illumination, LED), etc. Attractiveness of ZnO is attributed to wide bandgap energy at room temperature (3.37 eV), high electron mobility and transfer efficiency (115-155 cm2·V-1·s-1), large exciton binding energy (60 meV), intrinsic stability, nontoxicity, environmental compatibility and also, simple and not expensive synthesis procedure. A lot of different approaches can be used to modify the bandgap (i.e. optical absorption) of ZnO materials: metal and nonmetal ion doping, hydrogenation, the incorporation of crystalline defects in the form of V and I, modification of particles morphology and surface topology, etc. In this study, eco-friendly and rapid microwave processing of a precipitate was used to produce Fe-doped ZnO nanoparticles with 5, 10, 15 and 20 at.% of Fe (Zn1-xFeyO(1-x+1.5y)). The influence of different amount of Fe substituted Zn in ZnO on the crystal structure, morphological, textural, and optical properties as well as on functionality of ZnO particles was investigated. The crystal structure and phase purity of the Zn1-xFeyO(1-x+1.5y) particles were determined by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Effects of the Fe3+ amount on particles morphology and texture properties were observed with field emission scanning electron microscopy (FE–SEM), transmission electron microscopy (TEM) and nitrogen adsorption–desorption isotherm, respectively. Optical properties were studied using UV-Vis diffuse reflectance and photoluminescence spectroscopy. Functionality of ZnO particles was studied due to their photocatalytic and electrochemical activities. Photocatalytic activity was examined via decolorization of methylene blue under direct sunlight irradiation. Electrochemical behavior of the ZnO samples as anode material was evaluated by linear sweep voltammetry in 0.5 M Na2SO4 electrolyte.
PB  - Belgrade : Vinča Institute of Nuclear Sciences
C3  - PHOTONICA2023 : 9th International School and Conference on Photonics : book of abstracts; August 28 - September 1, 2023; Belgrade
T1  - Crystal structure, optical properties and photo/electrocatalytic activity of nanostructured Zn1-xFeyO(1-x+1.5y)
SP  - 34
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11554
ER  - 

@conference{
author = "Rajić, Vladimir and Marković, Smilja and Popović, M. and Novaković, M. and Veselinović, Ljiljana and Stojković Simatović, Ivana and Škapin, Srečo Davor and Stojanović, S. and Rac, Vladislav",
year = "2023",
abstract = "Zink oxide-based materials have a great potential to be applied in photo and electro catalysts, opto-electronic (indoor illumination, LED), etc. Attractiveness of ZnO is attributed to wide bandgap energy at room temperature (3.37 eV), high electron mobility and transfer efficiency (115-155 cm2·V-1·s-1), large exciton binding energy (60 meV), intrinsic stability, nontoxicity, environmental compatibility and also, simple and not expensive synthesis procedure. A lot of different approaches can be used to modify the bandgap (i.e. optical absorption) of ZnO materials: metal and nonmetal ion doping, hydrogenation, the incorporation of crystalline defects in the form of V and I, modification of particles morphology and surface topology, etc. In this study, eco-friendly and rapid microwave processing of a precipitate was used to produce Fe-doped ZnO nanoparticles with 5, 10, 15 and 20 at.% of Fe (Zn1-xFeyO(1-x+1.5y)). The influence of different amount of Fe substituted Zn in ZnO on the crystal structure, morphological, textural, and optical properties as well as on functionality of ZnO particles was investigated. The crystal structure and phase purity of the Zn1-xFeyO(1-x+1.5y) particles were determined by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Effects of the Fe3+ amount on particles morphology and texture properties were observed with field emission scanning electron microscopy (FE–SEM), transmission electron microscopy (TEM) and nitrogen adsorption–desorption isotherm, respectively. Optical properties were studied using UV-Vis diffuse reflectance and photoluminescence spectroscopy. Functionality of ZnO particles was studied due to their photocatalytic and electrochemical activities. Photocatalytic activity was examined via decolorization of methylene blue under direct sunlight irradiation. Electrochemical behavior of the ZnO samples as anode material was evaluated by linear sweep voltammetry in 0.5 M Na2SO4 electrolyte.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences",
journal = "PHOTONICA2023 : 9th International School and Conference on Photonics : book of abstracts; August 28 - September 1, 2023; Belgrade",
title = "Crystal structure, optical properties and photo/electrocatalytic activity of nanostructured Zn1-xFeyO(1-x+1.5y)",
pages = "34",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11554"
}

Rajić, V., Marković, S., Popović, M., Novaković, M., Veselinović, L., Stojković Simatović, I., Škapin, S. D., Stojanović, S.,& Rac, V.. (2023). Crystal structure, optical properties and photo/electrocatalytic activity of nanostructured Zn1-xFeyO(1-x+1.5y). in PHOTONICA2023 : 9th International School and Conference on Photonics : book of abstracts; August 28 - September 1, 2023; Belgrade
Belgrade : Vinča Institute of Nuclear Sciences., 34.
https://hdl.handle.net/21.15107/rcub_vinar_11554

Rajić V, Marković S, Popović M, Novaković M, Veselinović L, Stojković Simatović I, Škapin SD, Stojanović S, Rac V. Crystal structure, optical properties and photo/electrocatalytic activity of nanostructured Zn1-xFeyO(1-x+1.5y). in PHOTONICA2023 : 9th International School and Conference on Photonics : book of abstracts; August 28 - September 1, 2023; Belgrade. 2023;:34.
https://hdl.handle.net/21.15107/rcub_vinar_11554 .

Rajić, Vladimir, Marković, Smilja, Popović, M., Novaković, M., Veselinović, Ljiljana, Stojković Simatović, Ivana, Škapin, Srečo Davor, Stojanović, S., Rac, Vladislav, "Crystal structure, optical properties and photo/electrocatalytic activity of nanostructured Zn1-xFeyO(1-x+1.5y)" in PHOTONICA2023 : 9th International School and Conference on Photonics : book of abstracts; August 28 - September 1, 2023; Belgrade (2023):34,
https://hdl.handle.net/21.15107/rcub_vinar_11554 .

TY  - CONF
AU  - Rmuš Mravik, Jelena
AU  - Rajić, Vladimir
AU  - Belec, Blaž
AU  - Mravik, Željko
AU  - Jovanović, Zoran
AU  - Stojković Simatović, Ivana
AU  - Kurko, Sandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11657
AB  - Hydrogen production can be outlined as an important aspect of the modern economy. In order to be more clean and renewable, green hydrogen is most desirable, where expensive catalysts for water electrolysis are usually used. As alternative, transition metal dichalcogenides represent potentially good material, with room for further improvement. Molybdenum disulfide is a stable material with a reasonable amount of it available. The properties of the material can be easily tuned in order to increase its charge transport and create more active sites. The incorporation of defects and additives can be beneficial for the catalytic activity of MoS2. Graphene oxide (GO) is carbon nanomaterial, with a large surface area and when reduced, it could be used as a conductive additive. Furthermore, ball milling is a known low-cost, simple and scalable method to introduce defects in the structure. Therefore, combining these two approaches should result in a material with enhanced catalytic activity for hydrogen evolution reaction. The molybdenum disulfide was prepared by easy one-step hydrothermal synthesis. The graphene oxide was first obtained by modified Hummers’ method and after that reduced by thermal treatment at 200 °C. Thus prepared constituents are combined in different mass ratios and composites were obtained by milling with a high-energy ball mill. The various milling parameters were optimized. The prepared composites were analyzed as catalysts for hydrogen evolution reaction in an acidic solution.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
T1  - Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application
SP  - 156
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11657
ER  - 

@conference{
author = "Rmuš Mravik, Jelena and Rajić, Vladimir and Belec, Blaž and Mravik, Željko and Jovanović, Zoran and Stojković Simatović, Ivana and Kurko, Sandra",
year = "2023",
abstract = "Hydrogen production can be outlined as an important aspect of the modern economy. In order to be more clean and renewable, green hydrogen is most desirable, where expensive catalysts for water electrolysis are usually used. As alternative, transition metal dichalcogenides represent potentially good material, with room for further improvement. Molybdenum disulfide is a stable material with a reasonable amount of it available. The properties of the material can be easily tuned in order to increase its charge transport and create more active sites. The incorporation of defects and additives can be beneficial for the catalytic activity of MoS2. Graphene oxide (GO) is carbon nanomaterial, with a large surface area and when reduced, it could be used as a conductive additive. Furthermore, ball milling is a known low-cost, simple and scalable method to introduce defects in the structure. Therefore, combining these two approaches should result in a material with enhanced catalytic activity for hydrogen evolution reaction. The molybdenum disulfide was prepared by easy one-step hydrothermal synthesis. The graphene oxide was first obtained by modified Hummers’ method and after that reduced by thermal treatment at 200 °C. Thus prepared constituents are combined in different mass ratios and composites were obtained by milling with a high-energy ball mill. The various milling parameters were optimized. The prepared composites were analyzed as catalysts for hydrogen evolution reaction in an acidic solution.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro",
title = "Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application",
pages = "156",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11657"
}

Rmuš Mravik, J., Rajić, V., Belec, B., Mravik, Ž., Jovanović, Z., Stojković Simatović, I.,& Kurko, S.. (2023). Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
Belgrade : Materials Research Society of Serbia., 156.
https://hdl.handle.net/21.15107/rcub_vinar_11657

Rmuš Mravik J, Rajić V, Belec B, Mravik Ž, Jovanović Z, Stojković Simatović I, Kurko S. Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro. 2023;:156.
https://hdl.handle.net/21.15107/rcub_vinar_11657 .

Rmuš Mravik, Jelena, Rajić, Vladimir, Belec, Blaž, Mravik, Željko, Jovanović, Zoran, Stojković Simatović, Ivana, Kurko, Sandra, "Modification of MoS2/GO composites with ball milling and thermal treatment for catalytic application" in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro (2023):156,
https://hdl.handle.net/21.15107/rcub_vinar_11657 .

TY  - JOUR
AU  - Grujičić, Marija
AU  - Mravik, Željko
AU  - Bajuk-Bogdanović, Danica
AU  - Vengust, Damjan
AU  - Jovanović, Zoran M.
AU  - Stojković Simatović, Ivana
AU  - Jovanović, Sonja
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12756
AB  - U ovom radu prikazana su elektrohemijska svojstva kompozita grafen-oksida i nanočestica kobalt-ferita, kao i kobalt-ferita dopiranog sa cinkom i galijumom. Grafen-oksid (GO) sintetisan je modifikovanom Hamerovom metodom. Magnetne nanočestice sintetisane su solvotermalnom metodom, nakon čega je izvršena izmena oleinske kiseline dihidrokofeinskom kiselinom sa ciljem dobijanja hidrofilnog materijala. Kompoziti grafen-oksida i magnetnih nanočestica sintetisani su hidrotermalnom metodom, prilikom čega je udeo magnetnih čestica bio 5 i 15 težinskih % u odnosu na grafen-oksid. Rezultati rendgeno-strukturne i FTIR analize potvrdili su potpunu oksidaciju grafenskih slojeva. SEM i TEM analize pokazale su depoziciju magnetnih nanočestica na sloju grafen-oksida, bez promene veličine ili oblika nanočestica. FTIR analiza hidrotemalno tretiranog grafen-oksida i kompozita pokazala je da dolazi do delimične redukcije epoksi grupa, kao i da se uspostavlja vodonična veza između komponenti kompozita. Ciklovoltamogrami pokazuju da su kompoziti stabilni pri brzinama polarizacije od 5 do 400 mV s-1, kao i da je njihov kapacitet pretežno pseudokapacitivne prirode. Pseudokapacitivnost potiče od oksidoredukcionih reakcija H+ jona iz elektrolita i površinskih funkcionalnih grupa grafen oksida. Na osnovu ciklovoltamograma izračunati su specifični kapaciteti svih kompozita, pri čemu je najveću vrednost pokazao kompozit CFO_GO_15% koja iznosi 36,86 F g-1 pri brzini polarizacije od 5 mV s-1.
AB  - This paper presents the electrochemical properties of graphene-oxide composites and nanoparticles of cobalt-ferrite, as well as cobalt-ferrite doped with zinc and gallium. Graphene-oxide (GO) was synthesized by a modified Hummer's method. The magnetic nanoparticles were synthesized by the solvothermal method, after which the oleic acid was exchanged with dihydrocaffeic acid to obtain the hydrophilic material. Composites of graphene-oxide and magnetic nanoparticles were synthesized by the hydrothermal method, where the share of magnetic particles was 5 and 15 wt.% on graphene-oxide. The results of X-ray structural and FTIR analysis confirmed the complete oxidation of graphene layers. SEM and TEM analyzes showed deposition of magnetic nanoparticles on the graphene-oxide layer, without changing the size or shape of the nanoparticles. FTIR analysis of hydrothermally treated graphene oxide and composites showed that there is a partial reduction of epoxy groups, also a hydrogen bond is established between the components of the composite. Cyclic voltammograms show that the composites are stable at polarization rates of 5-400 mV s-1, and that their capacity is predominantly pseudocapacitive in nature. Pseudocapacitance originates from the oxidoreduction reactions of H+ ions from electrolytes and surface functional groups of graphene-oxide. Based on the cyclic voltammograms, the specific capacities of all composites were calculated and the highest value being shown by the CFO_GO_15% composite, which is 36.86 F g-1 at a polarization rate of 5 mV s-1.
T2  - Tehnika
T1  - Elektrohemijska svojstva kompozita grafen-oksida i kobalt-ferita dopiranog cinkom i galijumom
T1  - Electrochemical properties of composites of graphene-oxide and cobalt-ferrite doped with zink and gallium
VL  - 77
IS  - 2
SP  - 155
EP  - 162
DO  - 10.5937/tehnika2202155G
ER  - 

@article{
author = "Grujičić, Marija and Mravik, Željko and Bajuk-Bogdanović, Danica and Vengust, Damjan and Jovanović, Zoran M. and Stojković Simatović, Ivana and Jovanović, Sonja",
year = "2022",
abstract = "U ovom radu prikazana su elektrohemijska svojstva kompozita grafen-oksida i nanočestica kobalt-ferita, kao i kobalt-ferita dopiranog sa cinkom i galijumom. Grafen-oksid (GO) sintetisan je modifikovanom Hamerovom metodom. Magnetne nanočestice sintetisane su solvotermalnom metodom, nakon čega je izvršena izmena oleinske kiseline dihidrokofeinskom kiselinom sa ciljem dobijanja hidrofilnog materijala. Kompoziti grafen-oksida i magnetnih nanočestica sintetisani su hidrotermalnom metodom, prilikom čega je udeo magnetnih čestica bio 5 i 15 težinskih % u odnosu na grafen-oksid. Rezultati rendgeno-strukturne i FTIR analize potvrdili su potpunu oksidaciju grafenskih slojeva. SEM i TEM analize pokazale su depoziciju magnetnih nanočestica na sloju grafen-oksida, bez promene veličine ili oblika nanočestica. FTIR analiza hidrotemalno tretiranog grafen-oksida i kompozita pokazala je da dolazi do delimične redukcije epoksi grupa, kao i da se uspostavlja vodonična veza između komponenti kompozita. Ciklovoltamogrami pokazuju da su kompoziti stabilni pri brzinama polarizacije od 5 do 400 mV s-1, kao i da je njihov kapacitet pretežno pseudokapacitivne prirode. Pseudokapacitivnost potiče od oksidoredukcionih reakcija H+ jona iz elektrolita i površinskih funkcionalnih grupa grafen oksida. Na osnovu ciklovoltamograma izračunati su specifični kapaciteti svih kompozita, pri čemu je najveću vrednost pokazao kompozit CFO_GO_15% koja iznosi 36,86 F g-1 pri brzini polarizacije od 5 mV s-1., This paper presents the electrochemical properties of graphene-oxide composites and nanoparticles of cobalt-ferrite, as well as cobalt-ferrite doped with zinc and gallium. Graphene-oxide (GO) was synthesized by a modified Hummer's method. The magnetic nanoparticles were synthesized by the solvothermal method, after which the oleic acid was exchanged with dihydrocaffeic acid to obtain the hydrophilic material. Composites of graphene-oxide and magnetic nanoparticles were synthesized by the hydrothermal method, where the share of magnetic particles was 5 and 15 wt.% on graphene-oxide. The results of X-ray structural and FTIR analysis confirmed the complete oxidation of graphene layers. SEM and TEM analyzes showed deposition of magnetic nanoparticles on the graphene-oxide layer, without changing the size or shape of the nanoparticles. FTIR analysis of hydrothermally treated graphene oxide and composites showed that there is a partial reduction of epoxy groups, also a hydrogen bond is established between the components of the composite. Cyclic voltammograms show that the composites are stable at polarization rates of 5-400 mV s-1, and that their capacity is predominantly pseudocapacitive in nature. Pseudocapacitance originates from the oxidoreduction reactions of H+ ions from electrolytes and surface functional groups of graphene-oxide. Based on the cyclic voltammograms, the specific capacities of all composites were calculated and the highest value being shown by the CFO_GO_15% composite, which is 36.86 F g-1 at a polarization rate of 5 mV s-1.",
journal = "Tehnika",
title = "Elektrohemijska svojstva kompozita grafen-oksida i kobalt-ferita dopiranog cinkom i galijumom, Electrochemical properties of composites of graphene-oxide and cobalt-ferrite doped with zink and gallium",
volume = "77",
number = "2",
pages = "155-162",
doi = "10.5937/tehnika2202155G"
}

Grujičić, M., Mravik, Ž., Bajuk-Bogdanović, D., Vengust, D., Jovanović, Z. M., Stojković Simatović, I.,& Jovanović, S.. (2022). Elektrohemijska svojstva kompozita grafen-oksida i kobalt-ferita dopiranog cinkom i galijumom. in Tehnika, 77(2), 155-162.
https://doi.org/10.5937/tehnika2202155G

Grujičić M, Mravik Ž, Bajuk-Bogdanović D, Vengust D, Jovanović ZM, Stojković Simatović I, Jovanović S. Elektrohemijska svojstva kompozita grafen-oksida i kobalt-ferita dopiranog cinkom i galijumom. in Tehnika. 2022;77(2):155-162.
doi:10.5937/tehnika2202155G .

Grujičić, Marija, Mravik, Željko, Bajuk-Bogdanović, Danica, Vengust, Damjan, Jovanović, Zoran M., Stojković Simatović, Ivana, Jovanović, Sonja, "Elektrohemijska svojstva kompozita grafen-oksida i kobalt-ferita dopiranog cinkom i galijumom" in Tehnika, 77, no. 2 (2022):155-162,
https://doi.org/10.5937/tehnika2202155G . .

TY  - CONF
AU  - Grujičić, Marija
AU  - Mravik, Željko
AU  - Bajuk-Bogdanović, Danica
AU  - Vengust, Damjan
AU  - Jovanović, Zoran
AU  - Stojković Simatović, Ivana
AU  - Jovanović, Sonja
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12757
AB  - The possibility of surface functionalization and formation of stable aqueous suspensions make graphene oxide (GO) suitable as base for composite materials, especially with nanoparticles. Cobalt ferrite (CFO) has attracted attention due to its unique properties such as large magnetic anisotropy, high coercivity, moderate saturation magnetization, excellent chemical stability, mechanical hardness, etc. This study presents the electrochemical properties of GO and CFO composites, as well as CFO doped with zinc (CFO_Zn) and gallium (CFO_Ga). Magnetic nanoparticles were synthesized using the solvothermal method, after which the oleic acid was exchanged with dihydrocaffeic acid to obtain the hydrophilic material. GO was synthesized using a modified Hummer's method. Composites of GO and magnetic nanoparticles were synthesized by the hydrothermal method (T = 120 °C, t = 3 h), with nominal fractions of 5 and 15 wt.% of magnetic nanoparticles. X-ray structural diffraction, as well as FTIR analysis, confirmed the complete oxidation of graphene layers. SEM and TEM images showed deposition of magnetic nanoparticles on GO layer with the different distribution density between 5 wt.% and 15 wt.% composites. Also, shape and size of magnetic nanoparticles remained unchanged. Based on FTIR analysis of hydrothermally treated GO and composites a partial reduction of epoxy groups was found along with hydrogen bond established between the components of the composite. The electrochemical charge storage of composites is mainly of pseudocapacitive nature, which originates from the oxidoreduction reactions of H+ ions from electrolytes and surface functional groups of GO. The best electrochemical properties, in terms of the highest specific capacity, were shown by the composite which contains 15 wt.% CFO, which value is 36.86 F g-1 at a polarization rate of 5 mV s-1
PB  - Belgrade : Materials Research Society of Serbia – MRS-Serbia
C3  - 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts
T1  - Electrochemical properties of composites of graphene oxide and cobalt ferrite doped with zink and gallium
VL  - XLV
SP  - 135
EP  - 135
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12757
ER  - 

@conference{
author = "Grujičić, Marija and Mravik, Željko and Bajuk-Bogdanović, Danica and Vengust, Damjan and Jovanović, Zoran and Stojković Simatović, Ivana and Jovanović, Sonja",
year = "2022",
abstract = "The possibility of surface functionalization and formation of stable aqueous suspensions make graphene oxide (GO) suitable as base for composite materials, especially with nanoparticles. Cobalt ferrite (CFO) has attracted attention due to its unique properties such as large magnetic anisotropy, high coercivity, moderate saturation magnetization, excellent chemical stability, mechanical hardness, etc. This study presents the electrochemical properties of GO and CFO composites, as well as CFO doped with zinc (CFO_Zn) and gallium (CFO_Ga). Magnetic nanoparticles were synthesized using the solvothermal method, after which the oleic acid was exchanged with dihydrocaffeic acid to obtain the hydrophilic material. GO was synthesized using a modified Hummer's method. Composites of GO and magnetic nanoparticles were synthesized by the hydrothermal method (T = 120 °C, t = 3 h), with nominal fractions of 5 and 15 wt.% of magnetic nanoparticles. X-ray structural diffraction, as well as FTIR analysis, confirmed the complete oxidation of graphene layers. SEM and TEM images showed deposition of magnetic nanoparticles on GO layer with the different distribution density between 5 wt.% and 15 wt.% composites. Also, shape and size of magnetic nanoparticles remained unchanged. Based on FTIR analysis of hydrothermally treated GO and composites a partial reduction of epoxy groups was found along with hydrogen bond established between the components of the composite. The electrochemical charge storage of composites is mainly of pseudocapacitive nature, which originates from the oxidoreduction reactions of H+ ions from electrolytes and surface functional groups of GO. The best electrochemical properties, in terms of the highest specific capacity, were shown by the composite which contains 15 wt.% CFO, which value is 36.86 F g-1 at a polarization rate of 5 mV s-1",
publisher = "Belgrade : Materials Research Society of Serbia – MRS-Serbia",
journal = "23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts",
title = "Electrochemical properties of composites of graphene oxide and cobalt ferrite doped with zink and gallium",
volume = "XLV",
pages = "135-135",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12757"
}

Grujičić, M., Mravik, Ž., Bajuk-Bogdanović, D., Vengust, D., Jovanović, Z., Stojković Simatović, I.,& Jovanović, S.. (2022). Electrochemical properties of composites of graphene oxide and cobalt ferrite doped with zink and gallium. in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts
Belgrade : Materials Research Society of Serbia – MRS-Serbia., XLV, 135-135.
https://hdl.handle.net/21.15107/rcub_vinar_12757

Grujičić M, Mravik Ž, Bajuk-Bogdanović D, Vengust D, Jovanović Z, Stojković Simatović I, Jovanović S. Electrochemical properties of composites of graphene oxide and cobalt ferrite doped with zink and gallium. in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts. 2022;XLV:135-135.
https://hdl.handle.net/21.15107/rcub_vinar_12757 .

Grujičić, Marija, Mravik, Željko, Bajuk-Bogdanović, Danica, Vengust, Damjan, Jovanović, Zoran, Stojković Simatović, Ivana, Jovanović, Sonja, "Electrochemical properties of composites of graphene oxide and cobalt ferrite doped with zink and gallium" in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts, XLV (2022):135-135,
https://hdl.handle.net/21.15107/rcub_vinar_12757 .

TY  - JOUR
AU  - Rakočević, Lazar
AU  - Štrbac, Svetlana
AU  - Potočnik, Jelena
AU  - Popović, Maja
AU  - Jugović, Dragana
AU  - Stojković-Simatović, Ivana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10203
AB  - Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 ◦C, while 3-D tunnel structured Na0⋅4MnO2 and Na0⋅44MnO2, both with rod-like morphology, were obtained at 800 ◦C and 900 ◦C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0⋅44MnO2 obtained at 900 ◦C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.
T2  - Ceramics International
T1  - The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries
VL  - 47
IS  - 4
SP  - 4595
EP  - 4603
DO  - 10.1016/j.ceramint.2020.10.025
UR  - https://hdl.handle.net/21.15107/rcub_dais_11229
ER  - 

@article{
author = "Rakočević, Lazar and Štrbac, Svetlana and Potočnik, Jelena and Popović, Maja and Jugović, Dragana and Stojković-Simatović, Ivana",
year = "2021",
abstract = "Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 ◦C, while 3-D tunnel structured Na0⋅4MnO2 and Na0⋅44MnO2, both with rod-like morphology, were obtained at 800 ◦C and 900 ◦C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0⋅44MnO2 obtained at 900 ◦C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.",
journal = "Ceramics International",
title = "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries",
volume = "47",
number = "4",
pages = "4595-4603",
doi = "10.1016/j.ceramint.2020.10.025",
url = "https://hdl.handle.net/21.15107/rcub_dais_11229"
}

Rakočević, L., Štrbac, S., Potočnik, J., Popović, M., Jugović, D.,& Stojković-Simatović, I.. (2021). The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International, 47(4), 4595-4603.
https://doi.org/10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_11229

Rakočević L, Štrbac S, Potočnik J, Popović M, Jugović D, Stojković-Simatović I. The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International. 2021;47(4):4595-4603.
doi:10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_11229 .

Rakočević, Lazar, Štrbac, Svetlana, Potočnik, Jelena, Popović, Maja, Jugović, Dragana, Stojković-Simatović, Ivana, "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries" in Ceramics International, 47, no. 4 (2021):4595-4603,
https://doi.org/10.1016/j.ceramint.2020.10.025 .,
https://hdl.handle.net/21.15107/rcub_dais_11229 .

TY  - CONF
AU  - Grujičić, Marija
AU  - Stojković Simatović, Ivana
AU  - Bajuk-Bogdanović, Danica
AU  - Jovanović, Zoran
AU  - Mravik, Željko
AU  - Jovanović, Sonja
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12711
AB  - In this paper, the physicochemical properties of nanocomposites of graphene oxide (GO) and cobalt ferrite nanoparticles CFO NPs (pristine and doped with zinc and gallium, CFO_Zn, CFO_Ga) were investigated. CFO, CFO_Zn and CFO_Ga NPs were synthesized using the solvothermal method with oleic acid (OA) as a surfactant. X-ray diffraction (XRD) confirmed the presence of pure ferrite phase while transmission electron microscopy (TEM) revealed spherical and non-agglomerated NPs with average size of 5±1 nm. Fourier transform infrared spectroscopy (FTIR) has confirmed bridging bidentate interaction between the oleic acid and the metal atoms on the surface of the NPs, while Raman spectroscopy results confirmed the incorporation of zinc and gallium in the spinel structure. Prior to preparation of nanocomposite with GO, an OA coating has been exchanged with dihydrocaffeic acid (DHCA). DHCA binds to surface of NPs through both covalent bridging bidentate interaction and catechol groups, as determined by FTIR. Nanocomposite has been obtained by adding CFO(_Zn/Ga) NPs to a GO suspension with nominal fractions of 5 to 15 wt.%, followed by homogenization and hydrothermal treatment (T=120 °C, t=3 h). TEM results revealed that the shape and size of NPs remain unchanged in nanocomposite, while FTIR results have shown that hydrogen bond is established between the functional groups of GO and DHCA. Electrochemical properties of individual components and nanocomposite were examined by cyclic voltammetry. The best electrochemical properties, in terms of the highest specific capacity, were shown by the composite which contains 15 wt.% CFO NPs.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 19th Young Researchers’ Conference - Materials Science and Engineering : Program and the Book of Abstracts
T1  - Surface, structural and electric properties of ion beam irradiated graphene oxide papers
SP  - 39
EP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12711
ER  - 

@conference{
author = "Grujičić, Marija and Stojković Simatović, Ivana and Bajuk-Bogdanović, Danica and Jovanović, Zoran and Mravik, Željko and Jovanović, Sonja",
year = "2021",
abstract = "In this paper, the physicochemical properties of nanocomposites of graphene oxide (GO) and cobalt ferrite nanoparticles CFO NPs (pristine and doped with zinc and gallium, CFO_Zn, CFO_Ga) were investigated. CFO, CFO_Zn and CFO_Ga NPs were synthesized using the solvothermal method with oleic acid (OA) as a surfactant. X-ray diffraction (XRD) confirmed the presence of pure ferrite phase while transmission electron microscopy (TEM) revealed spherical and non-agglomerated NPs with average size of 5±1 nm. Fourier transform infrared spectroscopy (FTIR) has confirmed bridging bidentate interaction between the oleic acid and the metal atoms on the surface of the NPs, while Raman spectroscopy results confirmed the incorporation of zinc and gallium in the spinel structure. Prior to preparation of nanocomposite with GO, an OA coating has been exchanged with dihydrocaffeic acid (DHCA). DHCA binds to surface of NPs through both covalent bridging bidentate interaction and catechol groups, as determined by FTIR. Nanocomposite has been obtained by adding CFO(_Zn/Ga) NPs to a GO suspension with nominal fractions of 5 to 15 wt.%, followed by homogenization and hydrothermal treatment (T=120 °C, t=3 h). TEM results revealed that the shape and size of NPs remain unchanged in nanocomposite, while FTIR results have shown that hydrogen bond is established between the functional groups of GO and DHCA. Electrochemical properties of individual components and nanocomposite were examined by cyclic voltammetry. The best electrochemical properties, in terms of the highest specific capacity, were shown by the composite which contains 15 wt.% CFO NPs.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "19th Young Researchers’ Conference - Materials Science and Engineering : Program and the Book of Abstracts",
title = "Surface, structural and electric properties of ion beam irradiated graphene oxide papers",
pages = "39-39",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12711"
}

Grujičić, M., Stojković Simatović, I., Bajuk-Bogdanović, D., Jovanović, Z., Mravik, Ž.,& Jovanović, S.. (2021). Surface, structural and electric properties of ion beam irradiated graphene oxide papers. in 19th Young Researchers’ Conference - Materials Science and Engineering : Program and the Book of Abstracts
Belgrade : Institute of Technical Sciences of SASA., 39-39.
https://hdl.handle.net/21.15107/rcub_vinar_12711

Grujičić M, Stojković Simatović I, Bajuk-Bogdanović D, Jovanović Z, Mravik Ž, Jovanović S. Surface, structural and electric properties of ion beam irradiated graphene oxide papers. in 19th Young Researchers’ Conference - Materials Science and Engineering : Program and the Book of Abstracts. 2021;:39-39.
https://hdl.handle.net/21.15107/rcub_vinar_12711 .

Grujičić, Marija, Stojković Simatović, Ivana, Bajuk-Bogdanović, Danica, Jovanović, Zoran, Mravik, Željko, Jovanović, Sonja, "Surface, structural and electric properties of ion beam irradiated graphene oxide papers" in 19th Young Researchers’ Conference - Materials Science and Engineering : Program and the Book of Abstracts (2021):39-39,
https://hdl.handle.net/21.15107/rcub_vinar_12711 .

TY  - JOUR
AU  - Rakočević, Lazar
AU  - Štrbac, Svetlana
AU  - Potočnik, Jelena
AU  - Popović, Maja
AU  - Jugović, Dragana
AU  - Stojković-Simatović, Ivana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10202
AB  - Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 ◦C, while 3-D tunnel structured Na0⋅4MnO2 and Na0⋅44MnO2, both with rod-like morphology, were obtained at 800 ◦C and 900 ◦C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0⋅44MnO2 obtained at 900 ◦C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.
T2  - Ceramics International
T1  - The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries
VL  - 47
IS  - 4
SP  - 4595
EP  - 4603
DO  - 10.1016/j.ceramint.2020.10.025
UR  - https://hdl.handle.net/21.15107/rcub_dais_11229
ER  - 

@article{
author = "Rakočević, Lazar and Štrbac, Svetlana and Potočnik, Jelena and Popović, Maja and Jugović, Dragana and Stojković-Simatović, Ivana",
year = "2021",
abstract = "Cathodic material for sodium-ion rechargeable batteries based on NaxMnO2 were synthesized by glycine nitrate method and subsequent annealing at high temperatures. Different crystal structures with different morphologies were obtained depending on the annealing temperature: hexagonal layeredα-Na0.7MnO2.05 nanoplates were obtained at 850 ◦C, while 3-D tunnel structured Na0⋅4MnO2 and Na0⋅44MnO2, both with rod-like morphology, were obtained at 800 ◦C and 900 ◦C, respectively. The investigations of the electrochemical behavior of obtained cathodic materials in aqueous NaNO3 solution have shown that Na0⋅44MnO2 obtained at 900 ◦C has shown the best battery performance. Its initial discharge capacities are 123.5 mA h/g, 113.2 mA h/g, and 102.0 mA h/g at the high current densities of 1000, 2000 and 5000 mA/g, respectively.",
journal = "Ceramics International",
title = "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries",
volume = "47",
number = "4",
pages = "4595-4603",
doi = "10.1016/j.ceramint.2020.10.025",
url = "https://hdl.handle.net/21.15107/rcub_dais_11229"
}

Rakočević, L., Štrbac, S., Potočnik, J., Popović, M., Jugović, D.,& Stojković-Simatović, I.. (2021). The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International, 47(4), 4595-4603.
https://doi.org/10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_11229

Rakočević L, Štrbac S, Potočnik J, Popović M, Jugović D, Stojković-Simatović I. The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries. in Ceramics International. 2021;47(4):4595-4603.
doi:10.1016/j.ceramint.2020.10.025
https://hdl.handle.net/21.15107/rcub_dais_11229 .

Rakočević, Lazar, Štrbac, Svetlana, Potočnik, Jelena, Popović, Maja, Jugović, Dragana, Stojković-Simatović, Ivana, "The NaxMnO2 materials prepared by a glycine-nitrate method as advanced cathode materials for aqueous sodium-ion rechargeable batteries" in Ceramics International, 47, no. 4 (2021):4595-4603,
https://doi.org/10.1016/j.ceramint.2020.10.025 .,
https://hdl.handle.net/21.15107/rcub_dais_11229 .

TY  - CONF
AU  - Marković, Smilja
AU  - Stojanović, Zoran S.
AU  - Veselinović, Ljiljana
AU  - Simić, Danica
AU  - Samolov, Aleksandra
AU  - Stojković Simatović, Ivana
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11785
AB  - Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on glass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.
PB  - Belgrade : Military Technical Institute
C3  - OTEH’20 : 9th International Scientific Conference on Defensive Technologies : the book of abstracts; Oct 15-16, Belgrade
T1  - HAp:Co as tunable VIS-NIR reflective pigment
SP  - 475
EP  - 480
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11785
ER  - 

@conference{
author = "Marković, Smilja and Stojanović, Zoran S. and Veselinović, Ljiljana and Simić, Danica and Samolov, Aleksandra and Stojković Simatović, Ivana",
year = "2020",
abstract = "Radar-absorbent materials, used in stealth technology for defense aircrafts, vehicles, satellites, etc. from radar detection, are commonly based on graphite or semiconductive particles embedded in a polymer matrix. In this study, we employed Co2+ ion-substitution to improve Vis-NIR reflectivity of hydroxyapatite (Ca10(PO4)6(OH)2, HAP) powder. HAP:Co with nominally 5 at.% of Co was prepared with hydrothermal processing of a precipitate. Synthesized powder was characterized by XRD, Raman and ATR-FTIR spectroscopy, FE-SEM and TEM. Thermal stability of HAP:Co powder was examined by simultaneous TG-DTA analyzer. To modify its optical properties and obtain powders with a varietty of color tone, the HAP:Co powder was calcined at 800, 1000, and 1100 °C, in an air atmosphere, for 1 hour. Afterward, the calcined particles were used to prepare composites with poly(vinyl butyral), (PVB); the concentration range was 1 wt.% of the HAP:Co in PVB. The composite coatings, in the form of thin films on glass, were prepared by the solvent-casting technique, using ethanol as a fast evaporating solvent. Firstly, the HAP:Co particles were dispersed in ethanol, then PVB was added (Mowital B30H) and dissolved. To evaporate the solvent before spectrophotometric measurements, the coatings on glass were dried at room temperature for 72 hours. To comprehend optical properties of the coatings, diffuse reflection, transmission, and color coordinates were determined. We found that calcined HAP:Co particles have potential to be used in the formulation of coatings for camouflage protection.",
publisher = "Belgrade : Military Technical Institute",
journal = "OTEH’20 : 9th International Scientific Conference on Defensive Technologies : the book of abstracts; Oct 15-16, Belgrade",
title = "HAp:Co as tunable VIS-NIR reflective pigment",
pages = "475-480",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11785"
}

Marković, S., Stojanović, Z. S., Veselinović, L., Simić, D., Samolov, A.,& Stojković Simatović, I.. (2020). HAp:Co as tunable VIS-NIR reflective pigment. in OTEH’20 : 9th International Scientific Conference on Defensive Technologies : the book of abstracts; Oct 15-16, Belgrade
Belgrade : Military Technical Institute., 475-480.
https://hdl.handle.net/21.15107/rcub_vinar_11785

Marković S, Stojanović ZS, Veselinović L, Simić D, Samolov A, Stojković Simatović I. HAp:Co as tunable VIS-NIR reflective pigment. in OTEH’20 : 9th International Scientific Conference on Defensive Technologies : the book of abstracts; Oct 15-16, Belgrade. 2020;:475-480.
https://hdl.handle.net/21.15107/rcub_vinar_11785 .

Marković, Smilja, Stojanović, Zoran S., Veselinović, Ljiljana, Simić, Danica, Samolov, Aleksandra, Stojković Simatović, Ivana, "HAp:Co as tunable VIS-NIR reflective pigment" in OTEH’20 : 9th International Scientific Conference on Defensive Technologies : the book of abstracts; Oct 15-16, Belgrade (2020):475-480,
https://hdl.handle.net/21.15107/rcub_vinar_11785 .

TY  - CONF
AU  - Rakočević, Lazar
AU  - Novaković, Mirjana M.
AU  - Potočnik, Jelena
AU  - Jugović, Dragana
AU  - Stojković-Simatović, Ivana
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8734
AB  - Due to the increasing use of batteries in everyday life and in industry, there is a need for developing cheaper batteries than the widely used lithium ion batteries. Lower price and higher abundance of sodium compared to lithium mineral resources intensified the development of Na-ion batteries. Aqueous lithium/ sodium rechargeable batteries have attracted considerable attention for energy storage because they do not contain flammable organic electrolytes as commercial batteries do, the ionic conductivity of the aqueous electrolyte is about two orders of magnitude higher than in non-aqueous electrolyte and the electrolyte salt and solvent are cheaper. Various materials such as manganese oxides, vanadium oxide and phosphates have been used as electrode materials (cathodic and anodic) in sodium batteries due to high sodium intercalation ability in both, organic and aqueous electrolytes. The most frequently used type of manganese oxides are Li–Mn–O or Na–Mn–O systems due to their tunnel or layered crystal structures which facilitate the lithium/sodium intercalation-deintercalation. In this work, a glycine-nitrate method (GNM) was applied for the synthesis of cathode material Na0.4MnO2.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
T1  - Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device
SP  - 154
EP  - 156
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8734
ER  - 

@conference{
author = "Rakočević, Lazar and Novaković, Mirjana M. and Potočnik, Jelena and Jugović, Dragana and Stojković-Simatović, Ivana",
year = "2018",
abstract = "Due to the increasing use of batteries in everyday life and in industry, there is a need for developing cheaper batteries than the widely used lithium ion batteries. Lower price and higher abundance of sodium compared to lithium mineral resources intensified the development of Na-ion batteries. Aqueous lithium/ sodium rechargeable batteries have attracted considerable attention for energy storage because they do not contain flammable organic electrolytes as commercial batteries do, the ionic conductivity of the aqueous electrolyte is about two orders of magnitude higher than in non-aqueous electrolyte and the electrolyte salt and solvent are cheaper. Various materials such as manganese oxides, vanadium oxide and phosphates have been used as electrode materials (cathodic and anodic) in sodium batteries due to high sodium intercalation ability in both, organic and aqueous electrolytes. The most frequently used type of manganese oxides are Li–Mn–O or Na–Mn–O systems due to their tunnel or layered crystal structures which facilitate the lithium/sodium intercalation-deintercalation. In this work, a glycine-nitrate method (GNM) was applied for the synthesis of cathode material Na0.4MnO2.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia",
title = "Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device",
pages = "154-156",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8734"
}

Rakočević, L., Novaković, M. M., Potočnik, J., Jugović, D.,& Stojković-Simatović, I.. (2018). Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
Belgrade : Serbian Academy of Sciences and Arts., 154-156.
https://hdl.handle.net/21.15107/rcub_vinar_8734

Rakočević L, Novaković MM, Potočnik J, Jugović D, Stojković-Simatović I. Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia. 2018;:154-156.
https://hdl.handle.net/21.15107/rcub_vinar_8734 .

Rakočević, Lazar, Novaković, Mirjana M., Potočnik, Jelena, Jugović, Dragana, Stojković-Simatović, Ivana, "Synthesis and Characterization of Na0.4MnO2 as a Positive Electrode Material for an Aqueous Electrolyte Sodium-ion Energy Storage Device" in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia (2018):154-156,
https://hdl.handle.net/21.15107/rcub_vinar_8734 .

TY  - JOUR
AU  - Egelja, Adela
AU  - Pašalić, Snežana
AU  - Dodevski, Vladimir
AU  - Kragović, Milan M.
AU  - Stojković-Simatović, Ivana
AU  - Radovanović, Željko
AU  - Stojmenović, Marija
PY  - 2018
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X1803357E
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8070
AB  - Alumina/YAG composites (AYX_t) with high relative density (99.2 %TD) were successfully obtained by mixing commercial alumina powder with different volume fractions of yttrium aluminium garnet (Y3Al5O12-YAG; 7, 14, 21 and 28). YAG was synthetized by nitrate glycine reaction in the form of precursor powder. Polycrystalline YAG powder was obtained by calcination at 950 degrees C for 2 h. Additionally, obtained compositions were characterized by XRD, SEM, EDX and electrochemical impedance spectroscopy. By XRPD analysis was found that the particle size of YAG powders lies in the nanometric range (being lower than 35 nm). By SEM microphotographs of composites were confirmed the formation of a conductive path consisting from mutually interconnected YAG particles. This was confirmed by the electrochemical impedance spectroscopy. The highest electrical conductivity of grain (K-g) and grain boundary (K-gb) at 700 degrees C amounted to 2.22x10(-2) ohm(-1)cm(-1) and 9.44x10(-3) ohm(-1) cm(-1), respectively, was measured in the composite containing 21 vol% of YAG.
T2  - Science of Sintering
T1  - Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC
VL  - 50
IS  - 3
SP  - 357
EP  - 369
DO  - 10.2298/SOS1803357E
ER  - 

@article{
author = "Egelja, Adela and Pašalić, Snežana and Dodevski, Vladimir and Kragović, Milan M. and Stojković-Simatović, Ivana and Radovanović, Željko and Stojmenović, Marija",
year = "2018",
abstract = "Alumina/YAG composites (AYX_t) with high relative density (99.2 %TD) were successfully obtained by mixing commercial alumina powder with different volume fractions of yttrium aluminium garnet (Y3Al5O12-YAG; 7, 14, 21 and 28). YAG was synthetized by nitrate glycine reaction in the form of precursor powder. Polycrystalline YAG powder was obtained by calcination at 950 degrees C for 2 h. Additionally, obtained compositions were characterized by XRD, SEM, EDX and electrochemical impedance spectroscopy. By XRPD analysis was found that the particle size of YAG powders lies in the nanometric range (being lower than 35 nm). By SEM microphotographs of composites were confirmed the formation of a conductive path consisting from mutually interconnected YAG particles. This was confirmed by the electrochemical impedance spectroscopy. The highest electrical conductivity of grain (K-g) and grain boundary (K-gb) at 700 degrees C amounted to 2.22x10(-2) ohm(-1)cm(-1) and 9.44x10(-3) ohm(-1) cm(-1), respectively, was measured in the composite containing 21 vol% of YAG.",
journal = "Science of Sintering",
title = "Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC",
volume = "50",
number = "3",
pages = "357-369",
doi = "10.2298/SOS1803357E"
}

Egelja, A., Pašalić, S., Dodevski, V., Kragović, M. M., Stojković-Simatović, I., Radovanović, Ž.,& Stojmenović, M.. (2018). Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC. in Science of Sintering, 50(3), 357-369.
https://doi.org/10.2298/SOS1803357E

Egelja A, Pašalić S, Dodevski V, Kragović MM, Stojković-Simatović I, Radovanović Ž, Stojmenović M. Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC. in Science of Sintering. 2018;50(3):357-369.
doi:10.2298/SOS1803357E .

Egelja, Adela, Pašalić, Snežana, Dodevski, Vladimir, Kragović, Milan M., Stojković-Simatović, Ivana, Radovanović, Željko, Stojmenović, Marija, "Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC" in Science of Sintering, 50, no. 3 (2018):357-369,
https://doi.org/10.2298/SOS1803357E . .

TY  - CONF
AU  - Barešić, Jadranka
AU  - Nikolov, Jovana
AU  - Todorović, Nataša
AU  - Krajcar Bronić, Ines
AU  - Stojković, Ivana
AU  - Tenjović, Branislava
AU  - Krmpotić, Matea
AU  - Tomić, Milan
AU  - Marić, Dragana
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8325
UR  - https://plus.sr.cobiss.net/opac7/bib/245691404
UR  - http://dzz.org.rs/wp-content/uploads/2013/06/Zbornik_XXIX_Simpozijum_DZZ_SCG_Srebrno_jezero_2.pdf
AB  - A method of direct measurement of 14C activity concentration via liquid scintillation
counting (LSC) is recognized as good and fast method for determination of biogenic
component in liquid fuels. Two laboratories that used this14C technique participated in
this survey: Laboratory from University of Novi Sad (UNS), Serbia and Laboratory
from Ruđer Bošković Institute (RBI), Croatia. Each laboratory used its own calibration
methods on the same set of samples (produced diesel-based bio-fuels and commercially
available domestic oils).
From the obtained results it can be concluded that each method which uses 14C
technique for determination of biogenic component in liquid fuels has its advantages
and disadvantages. RBI data evaluation method is based on two calibration curves, for
purely biogenic and purely fossil liquids, and the calibration does not depend on the
exact chemical composition of the organic liquid. The limits of the method are defined
by the SQP(E) of approximately 690. Below this value the count rates of biogenic and
fossil liquids become close to each other or even indistinguishable from one another
and the obtained results for biogenic fractions are not reliable. In this intercomparison
UNS used two different methods, one for produced bio-diesels and the other one for
domestic oils. UNS data evaluation method is very dependent on the composition of the
examined fuels, so the obtained results with the "two-step" method were relatively good
in the case of diesel mixtures with biogenic component. In the case of biogenic oil
samples (bought on market), UNS "two-step" method did not give realistic results, and
with the "one-step" method the limitation is large quenching in the samples, so for the
samples with SQP(E) less than 700 this method could not give expected results. Samples
prepared with liquid fuels are usually colored and the main challenge for determination
of biogenic component in both laboratories is handling of highly quenched liquids.
AB  - Prema preporukama Evropske Unije sa ciljem da se koriste obnovljivi i održivi izvori,
do 2020. godine zahteva se da se u svim tečnim gorivima koja se koriste nalazi bar 10%
sintetisanog biodizela. Da bi se koncentracija biodizela mogla proveriti, nekoliko
laboratorija u svetu je razvilo metode za tačnu, efikasnu i pouzdanu kvantifikaciju
sadržaja biogene komponente. Direktno merenje koncentracije aktivnosti 14C tečnim
scintilacionim detektorom (LSC), koje podrazumeva određivanje količine 14C u uzorku
kao meru prisutnosti biogene komponente u testiranom gorivu, pokazalo se kao dobra i
brza metoda. U ovoj interkomparaciji učestvovale su dve laboratorije: Laboratorija sa
Univerziteta u Novom Sadu (UNS), Srbija i Laboratorija sa Instituta Ruđer Bošković
(RBI), Hrvatska. Svaka laboratorija je koristila sopstveni kalibracioni metod i isti set
uzoraka za interkomparaciju (proizvedena bio-goriva bazirana na dizelu i komercijalno
dostupna domaća ulja).
Iz dobijenih rezultata može se zaključiti da svaki od prikazanih metoda ima svoje
prednosti i mane, što zavisi od samog sastava uzorka. RBI metod se zasniva na upotrebi
dve kalibracione krive, za čisto biogena i čisto fosilna goriva, i kalibracija nije zavisna
od hemijskog sastava analiziranog uzorka. Ograničenje ove metode je SQP(E) vrednost
niža od 690. Ispod ove vrednosti odbroji biogene i fosilne komponente postaju veoma
bliski jedan drugom i samim tim rezultati koji se dobijaju nisu pouzdani. U ovoj
interkomparaciji, UNS je koristila dve različite metode kalibracije, jednu za
proizvedene bio-dizele, a drugu za domaća ulja. UNS metod evaluacije izmerenih
podataka u mnogome zavisi od sastava ispitivanog goriva, pa su rezultati dobijeni sa
"two-step" metodom relativno dobri za smeše dizela sa biogenom komponentom. U
slučaju biogenih ulja, UNS "two-step" metod nije dao realistične rezultate, zbog toga je
korišćen "one-step" metoda za koji je utvrđeno ograničenje za SQP(E) parametar na
700.
Uzorci koji se pripremaju sa tečnim gorivima su najčešće obojeni i najveći problem koji
se javlja je korekcija na prigušenje u samom uzorku, koja mora biti detaljno sprovedena
kako bi se dobio pouzdan rezultat, pa najveći izazov daljnjeg razvoja ovih metoda
postaje postupak merenja biogene komponente u jako prigušenim uzorcima.
PB  - Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе
C3  - 29. симпозијум ДЗЗСЦГ : зборник радова
T1  - Comparison of methods for determination of biogenic fraction in liquid fuels
T1  - Poređenje metoda za određivanje biogene komponente u tečnim gorivima
SP  - 529
EP  - 536
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8325
ER  - 

@conference{
author = "Barešić, Jadranka and Nikolov, Jovana and Todorović, Nataša and Krajcar Bronić, Ines and Stojković, Ivana and Tenjović, Branislava and Krmpotić, Matea and Tomić, Milan and Marić, Dragana",
year = "2017",
abstract = "A method of direct measurement of 14C activity concentration via liquid scintillation
counting (LSC) is recognized as good and fast method for determination of biogenic
component in liquid fuels. Two laboratories that used this14C technique participated in
this survey: Laboratory from University of Novi Sad (UNS), Serbia and Laboratory
from Ruđer Bošković Institute (RBI), Croatia. Each laboratory used its own calibration
methods on the same set of samples (produced diesel-based bio-fuels and commercially
available domestic oils).
From the obtained results it can be concluded that each method which uses 14C
technique for determination of biogenic component in liquid fuels has its advantages
and disadvantages. RBI data evaluation method is based on two calibration curves, for
purely biogenic and purely fossil liquids, and the calibration does not depend on the
exact chemical composition of the organic liquid. The limits of the method are defined
by the SQP(E) of approximately 690. Below this value the count rates of biogenic and
fossil liquids become close to each other or even indistinguishable from one another
and the obtained results for biogenic fractions are not reliable. In this intercomparison
UNS used two different methods, one for produced bio-diesels and the other one for
domestic oils. UNS data evaluation method is very dependent on the composition of the
examined fuels, so the obtained results with the "two-step" method were relatively good
in the case of diesel mixtures with biogenic component. In the case of biogenic oil
samples (bought on market), UNS "two-step" method did not give realistic results, and
with the "one-step" method the limitation is large quenching in the samples, so for the
samples with SQP(E) less than 700 this method could not give expected results. Samples
prepared with liquid fuels are usually colored and the main challenge for determination
of biogenic component in both laboratories is handling of highly quenched liquids., Prema preporukama Evropske Unije sa ciljem da se koriste obnovljivi i održivi izvori,
do 2020. godine zahteva se da se u svim tečnim gorivima koja se koriste nalazi bar 10%
sintetisanog biodizela. Da bi se koncentracija biodizela mogla proveriti, nekoliko
laboratorija u svetu je razvilo metode za tačnu, efikasnu i pouzdanu kvantifikaciju
sadržaja biogene komponente. Direktno merenje koncentracije aktivnosti 14C tečnim
scintilacionim detektorom (LSC), koje podrazumeva određivanje količine 14C u uzorku
kao meru prisutnosti biogene komponente u testiranom gorivu, pokazalo se kao dobra i
brza metoda. U ovoj interkomparaciji učestvovale su dve laboratorije: Laboratorija sa
Univerziteta u Novom Sadu (UNS), Srbija i Laboratorija sa Instituta Ruđer Bošković
(RBI), Hrvatska. Svaka laboratorija je koristila sopstveni kalibracioni metod i isti set
uzoraka za interkomparaciju (proizvedena bio-goriva bazirana na dizelu i komercijalno
dostupna domaća ulja).
Iz dobijenih rezultata može se zaključiti da svaki od prikazanih metoda ima svoje
prednosti i mane, što zavisi od samog sastava uzorka. RBI metod se zasniva na upotrebi
dve kalibracione krive, za čisto biogena i čisto fosilna goriva, i kalibracija nije zavisna
od hemijskog sastava analiziranog uzorka. Ograničenje ove metode je SQP(E) vrednost
niža od 690. Ispod ove vrednosti odbroji biogene i fosilne komponente postaju veoma
bliski jedan drugom i samim tim rezultati koji se dobijaju nisu pouzdani. U ovoj
interkomparaciji, UNS je koristila dve različite metode kalibracije, jednu za
proizvedene bio-dizele, a drugu za domaća ulja. UNS metod evaluacije izmerenih
podataka u mnogome zavisi od sastava ispitivanog goriva, pa su rezultati dobijeni sa
"two-step" metodom relativno dobri za smeše dizela sa biogenom komponentom. U
slučaju biogenih ulja, UNS "two-step" metod nije dao realistične rezultate, zbog toga je
korišćen "one-step" metoda za koji je utvrđeno ograničenje za SQP(E) parametar na
700.
Uzorci koji se pripremaju sa tečnim gorivima su najčešće obojeni i najveći problem koji
se javlja je korekcija na prigušenje u samom uzorku, koja mora biti detaljno sprovedena
kako bi se dobio pouzdan rezultat, pa najveći izazov daljnjeg razvoja ovih metoda
postaje postupak merenja biogene komponente u jako prigušenim uzorcima.",
publisher = "Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе",
journal = "29. симпозијум ДЗЗСЦГ : зборник радова",
title = "Comparison of methods for determination of biogenic fraction in liquid fuels, Poređenje metoda za određivanje biogene komponente u tečnim gorivima",
pages = "529-536",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8325"
}

Barešić, J., Nikolov, J., Todorović, N., Krajcar Bronić, I., Stojković, I., Tenjović, B., Krmpotić, M., Tomić, M.,& Marić, D.. (2017). Comparison of methods for determination of biogenic fraction in liquid fuels. in 29. симпозијум ДЗЗСЦГ : зборник радова
Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе., 529-536.
https://hdl.handle.net/21.15107/rcub_vinar_8325

Barešić J, Nikolov J, Todorović N, Krajcar Bronić I, Stojković I, Tenjović B, Krmpotić M, Tomić M, Marić D. Comparison of methods for determination of biogenic fraction in liquid fuels. in 29. симпозијум ДЗЗСЦГ : зборник радова. 2017;:529-536.
https://hdl.handle.net/21.15107/rcub_vinar_8325 .

Barešić, Jadranka, Nikolov, Jovana, Todorović, Nataša, Krajcar Bronić, Ines, Stojković, Ivana, Tenjović, Branislava, Krmpotić, Matea, Tomić, Milan, Marić, Dragana, "Comparison of methods for determination of biogenic fraction in liquid fuels" in 29. симпозијум ДЗЗСЦГ : зборник радова (2017):529-536,
https://hdl.handle.net/21.15107/rcub_vinar_8325 .

TY  - CONF
AU  - Vraničar, Andrej
AU  - Todorović, Nataša
AU  - Nikolov, Jovana
AU  - Tenjović, Branislava
AU  - Stojković, Ivana
AU  - Jovančević, Nikola
AU  - Hansman, Jan
AU  - Krmar, Miodrag
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8320
UR  - https://plus.sr.cobiss.net/opac7/bib/245691404
UR  - http://dzz.org.rs/wp-content/uploads/2013/06/Zbornik_XXIX_Simpozijum_DZZ_SCG_Srebrno_jezero_2.pdf
AB  - Zbog svoje visoke efikasnosti, NaI detektor oblika jame je odličan izbor za detekciju
niskih aktivnosti, pogotovo kod uzoraka uzetih iz prirode. No velik prostorni ugao kojeg
aktivna zapremina detektora oblika jame zauzima, neminovno dovodi do efekta
koincidentnog sumiranja. Na osnovu većeg broja gama spektara rastvora radijuma je
ispitan uticaj koincidentnog sumiranja na efikasnost detekcije u cilju razvijanja brzog i
pouzdanog metoda za merenje radijuma u pijaćim vodama. Razvijen je i nov “grafički”
metod za određivanje praga detekcije koji je ispitan na primeru voluminoznih uzoraka
male aktivnosti.
AB  - Due to its high efficiency, a well-type NaI detector is an excellent choice for low-level
activity detection, especially for samples taken from nature. But, the large space angle
that active volume of the detector includes, indispicably leads to coincident summing.
Based on large number of gamma spectra of radium solutions, the effect of coincident
summing was examined for purposes of developing a fast and reliable method for
drinking water radium measurements. Also, a new ”graphical”method for determining
MDA, based on measurements of small activity voluminous samples was developed.
PB  - Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе
C3  - 29. симпозијум ДЗЗСЦГ : зборник радова
T1  - Radijum u vodi: detekcija voluminoznih uzoraka NaI detektorom oblika jame
T1  - Radium in water: detection of bulk samples in well-type NaI detector
SP  - 493
EP  - 499
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8320
ER  - 

@conference{
author = "Vraničar, Andrej and Todorović, Nataša and Nikolov, Jovana and Tenjović, Branislava and Stojković, Ivana and Jovančević, Nikola and Hansman, Jan and Krmar, Miodrag",
year = "2017",
abstract = "Zbog svoje visoke efikasnosti, NaI detektor oblika jame je odličan izbor za detekciju
niskih aktivnosti, pogotovo kod uzoraka uzetih iz prirode. No velik prostorni ugao kojeg
aktivna zapremina detektora oblika jame zauzima, neminovno dovodi do efekta
koincidentnog sumiranja. Na osnovu većeg broja gama spektara rastvora radijuma je
ispitan uticaj koincidentnog sumiranja na efikasnost detekcije u cilju razvijanja brzog i
pouzdanog metoda za merenje radijuma u pijaćim vodama. Razvijen je i nov “grafički”
metod za određivanje praga detekcije koji je ispitan na primeru voluminoznih uzoraka
male aktivnosti., Due to its high efficiency, a well-type NaI detector is an excellent choice for low-level
activity detection, especially for samples taken from nature. But, the large space angle
that active volume of the detector includes, indispicably leads to coincident summing.
Based on large number of gamma spectra of radium solutions, the effect of coincident
summing was examined for purposes of developing a fast and reliable method for
drinking water radium measurements. Also, a new ”graphical”method for determining
MDA, based on measurements of small activity voluminous samples was developed.",
publisher = "Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе",
journal = "29. симпозијум ДЗЗСЦГ : зборник радова",
title = "Radijum u vodi: detekcija voluminoznih uzoraka NaI detektorom oblika jame, Radium in water: detection of bulk samples in well-type NaI detector",
pages = "493-499",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8320"
}

Vraničar, A., Todorović, N., Nikolov, J., Tenjović, B., Stojković, I., Jovančević, N., Hansman, J.,& Krmar, M.. (2017). Radijum u vodi: detekcija voluminoznih uzoraka NaI detektorom oblika jame. in 29. симпозијум ДЗЗСЦГ : зборник радова
Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе., 493-499.
https://hdl.handle.net/21.15107/rcub_vinar_8320

Vraničar A, Todorović N, Nikolov J, Tenjović B, Stojković I, Jovančević N, Hansman J, Krmar M. Radijum u vodi: detekcija voluminoznih uzoraka NaI detektorom oblika jame. in 29. симпозијум ДЗЗСЦГ : зборник радова. 2017;:493-499.
https://hdl.handle.net/21.15107/rcub_vinar_8320 .

Vraničar, Andrej, Todorović, Nataša, Nikolov, Jovana, Tenjović, Branislava, Stojković, Ivana, Jovančević, Nikola, Hansman, Jan, Krmar, Miodrag, "Radijum u vodi: detekcija voluminoznih uzoraka NaI detektorom oblika jame" in 29. симпозијум ДЗЗСЦГ : зборник радова (2017):493-499,
https://hdl.handle.net/21.15107/rcub_vinar_8320 .

TY  - CONF
AU  - Todorović, Nataša
AU  - Nikolov, Jovana
AU  - Stojković, Ivana
AU  - Hansman, Jan
AU  - Kuzmanović, Predrag
AU  - Vraničar, Andrej
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8319
UR  - https://plus.sr.cobiss.net/opac7/bib/245691404
UR  - http://dzz.org.rs/wp-content/uploads/2013/06/Zbornik_XXIX_Simpozijum_DZZ_SCG_Srebrno_jezero_2.pdf
AB  - U radu je prikazano poređenje različitih metoda i tehnika za određivanje 226Ra u vodi:
tečna scinitlaciona spektrometrija (LSC), alfa spektrometrija i gama spektrometrija.
Tehnikom LSC određen je sadržaj 226Ra u vodi korišćenjem sledećih metoda:
standardne test metode ASTM D 7283-06 i EPA metode 913.0. Gama spektrometrijom
je sadržaj 226Ra određen direktnom metodom u Marineli geometriji. Alfa spektrometrom
RAD 7 određena je koncentracija aktivnosti 226Ra u vodi korišćenjem protokola
Wat250. Izvršeno je poređene rezultata dobijenih ovim metodama i dat je pregled
prednosti i nedostataka svake metode i tehnike. Dobijene eksperimentalne vrednosti za
sve metode su date sa odgovarajućim korekcijom.
AB  - The measurement of 226Ra in natural water samples is important because it is one of the
most hazardous elements with respect to internal radiation exposure. Therefore, in the
monitoring studies it is desirable to have a precise and accurate technique for the
determination of the activity concentration of this radionuclide.
This paper presents a comparison of different techniques and methods for 226
Ra in
water samples spiked with different concentrations of 226Ra isotope: LSC (Liquid
Scintillation Counting), alpha and gamma spectrometry. An overview of the advantages
and disadvantages of each techniques are presented. 226Ra in water samples were
determined by gamma spectrometry using direct method (untreated water samples) and
by RAD7 solid state detector. For 226Ra determination by LSC two different methods
were tested: ASTM D 7283-06 Standard test method for alpha and beta activity in water
by liquid scintillation and EPA Method 913.0 for radon determination in drinking
water.
PB  - Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе
C3  - 29. симпозијум ДЗЗСЦГ : зборник радова
T1  - Poređenje metoda za ispitivanje Ra226 u vodi
T1  - Different techniques for Ra226 determination in water samples
SP  - 482
EP  - 492
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8319
ER  - 

@conference{
author = "Todorović, Nataša and Nikolov, Jovana and Stojković, Ivana and Hansman, Jan and Kuzmanović, Predrag and Vraničar, Andrej",
year = "2017",
abstract = "U radu je prikazano poređenje različitih metoda i tehnika za određivanje 226Ra u vodi:
tečna scinitlaciona spektrometrija (LSC), alfa spektrometrija i gama spektrometrija.
Tehnikom LSC određen je sadržaj 226Ra u vodi korišćenjem sledećih metoda:
standardne test metode ASTM D 7283-06 i EPA metode 913.0. Gama spektrometrijom
je sadržaj 226Ra određen direktnom metodom u Marineli geometriji. Alfa spektrometrom
RAD 7 određena je koncentracija aktivnosti 226Ra u vodi korišćenjem protokola
Wat250. Izvršeno je poređene rezultata dobijenih ovim metodama i dat je pregled
prednosti i nedostataka svake metode i tehnike. Dobijene eksperimentalne vrednosti za
sve metode su date sa odgovarajućim korekcijom., The measurement of 226Ra in natural water samples is important because it is one of the
most hazardous elements with respect to internal radiation exposure. Therefore, in the
monitoring studies it is desirable to have a precise and accurate technique for the
determination of the activity concentration of this radionuclide.
This paper presents a comparison of different techniques and methods for 226
Ra in
water samples spiked with different concentrations of 226Ra isotope: LSC (Liquid
Scintillation Counting), alpha and gamma spectrometry. An overview of the advantages
and disadvantages of each techniques are presented. 226Ra in water samples were
determined by gamma spectrometry using direct method (untreated water samples) and
by RAD7 solid state detector. For 226Ra determination by LSC two different methods
were tested: ASTM D 7283-06 Standard test method for alpha and beta activity in water
by liquid scintillation and EPA Method 913.0 for radon determination in drinking
water.",
publisher = "Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе",
journal = "29. симпозијум ДЗЗСЦГ : зборник радова",
title = "Poređenje metoda za ispitivanje Ra226 u vodi, Different techniques for Ra226 determination in water samples",
pages = "482-492",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8319"
}

Todorović, N., Nikolov, J., Stojković, I., Hansman, J., Kuzmanović, P.,& Vraničar, A.. (2017). Poređenje metoda za ispitivanje Ra226 u vodi. in 29. симпозијум ДЗЗСЦГ : зборник радова
Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе., 482-492.
https://hdl.handle.net/21.15107/rcub_vinar_8319

Todorović N, Nikolov J, Stojković I, Hansman J, Kuzmanović P, Vraničar A. Poređenje metoda za ispitivanje Ra226 u vodi. in 29. симпозијум ДЗЗСЦГ : зборник радова. 2017;:482-492.
https://hdl.handle.net/21.15107/rcub_vinar_8319 .

Todorović, Nataša, Nikolov, Jovana, Stojković, Ivana, Hansman, Jan, Kuzmanović, Predrag, Vraničar, Andrej, "Poređenje metoda za ispitivanje Ra226 u vodi" in 29. симпозијум ДЗЗСЦГ : зборник радова (2017):482-492,
https://hdl.handle.net/21.15107/rcub_vinar_8319 .

TY  - CONF
AU  - Stojković, Ivana
AU  - Todorović, Nataša
AU  - Nikolov, Jovana
AU  - Tenjović, Branislava
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8326
UR  - https://plus.sr.cobiss.net/opac7/bib/245691404
UR  - http://dzz.org.rs/wp-content/uploads/2013/06/Zbornik_XXIX_Simpozijum_DZZ_SCG_Srebrno_jezero_2.pdf
AB  - Monitoring of environmental samples, drinking and surface waters, is continuously
carried out, demanding development of methods that are both reliable and accurate on
one side, but as simple and fast as possible, on the other. Screening tests such as gross
alpha/beta activity measurements in water samples are one liquid scintillation counting
(LSC) technique widely used as an efficient tool for radiological assesment and
estimation whether water sample needs further analysis or not. In this paper,
establishment of rapid gross alpha/beta screening technique in waters has been
presented, which assumes modification of conventional ASTM D 7283-06 method, since
samples were directly mixed with liquid scintillation cocktail, without any sample
pretreatment. Method’s optimization involved sample-to-cocktail ratio determination
based on the achieved detection limit and sample’s quench level. Optimal value of Pulse
Shape Analysis (PSA) discriminator that considerably improves performance of LSC
technique through alpha/beta spectra separation during radiological quality
measurements of drinking waters has also been investigated. Results of calibration
experiments and method’s validity measurements on spiked samples with 241Am and
90Sr/90Y aqueous standards are presented. Achieved detection limits for 300 minutes
of counting are MDAα=0.294(11) Bq l-1 and MDAβ=0.405(5) Bq l-1, in alpha and beta
window, respectively. Direct alpha/beta method provides deviations up to 40% from
reference values, but it offers advantages over conventional alpha/beta measurements,
it is ultra fast, simple and inexpensive test for efficient screening of water samples.
AB  - Rutinski monitoring pijaćih i površinskih voda sprovodi se kontinuirano i nameće
potrebu za razvojem metoda koje su, s jedne strane, pouzdane i tačne, ali istovremeno,
jednostavne i brze. Screening testovi radi procene ukupne alfa/beta aktivnosti u
uzorcima voda, jedna su od često primenjenih tehnika tečne scintilacione
spektroskopije, kojima se efikasno može utvrditi da li uzorak zahteva dalju radiološku
analizu ili ne. U radu je predstavljena optimizacija brze direktne metode za ispitivanje
ukupne alfa/beta aktivnosti u vodama, uz prikaz i diskusiju postignutih granica
detekcije. Ova metoda je modifikacija standardne test metode ASTM D 7283-06 za
ispitivanje ukupne alfa i beta aktivnosti i podrazumeva direktno mešanje uzorka vode sa
scintilacionim koktelom. Na taj način, uzorak je spreman za merenje bez prethodne
pripreme koja, prema standardnim metodama, obično podrazumeva duge procedure
poput uparavanja do suvog ostatka. Optimizacija metode sastoji se u određivanju
optimalnog odnosa uzorak: scintilacioni koktel na osnovu granica detekcije (MDA) u
alfa i beta kanalima, kao i nivoa prigušenja u uzorcima, uzimajući u obzir i maksimalni
kapacitet određenog koktela. Podešena je vrednost PSA (Pulse Shape Analysis)
diskriminatora u cilju optimalne separacije alfa i beta spektara i redukcije pozadinskih
efekata. Kalibracija i validacija metode je izvršena standardnim referentnim materijalima, rastvorima 241Am i 90Sr/90Y. Utvrđeno je da za 300 minuta merenja tečnim
scintilacionim brojačem, mogu se izmeriti koncentracije aktivnosti koje premašuju
vrednosti MDAα=0,294(11) Bq l-1 i MDAβ=0,405(5) Bq l-1 u alfa i beta kanalima,
respektivno. Rezultati validacije metode pokazuju da maksimalna relativna odstupanja
mogu iznositi do 40%, što je prihvatljivo, uzimajući u obzir da metod nije predviđen za
precizno merenje koncentracija aktivnosti pojedinih radionuklida, već za celokupnu
procenu radiološke bezbednosti uzoraka voda.
PB  - Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе
C3  - 29. симпозијум ДЗЗСЦГ : зборник радова
T1  - Rapid LSC method for direct alpha/beta measurements in waters
T1  - Direktna metoda za određivanje ukupne alfa/beta aktivnosti u vodama
SP  - 537
EP  - 543
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8326
ER  - 

@conference{
author = "Stojković, Ivana and Todorović, Nataša and Nikolov, Jovana and Tenjović, Branislava",
year = "2017",
abstract = "Monitoring of environmental samples, drinking and surface waters, is continuously
carried out, demanding development of methods that are both reliable and accurate on
one side, but as simple and fast as possible, on the other. Screening tests such as gross
alpha/beta activity measurements in water samples are one liquid scintillation counting
(LSC) technique widely used as an efficient tool for radiological assesment and
estimation whether water sample needs further analysis or not. In this paper,
establishment of rapid gross alpha/beta screening technique in waters has been
presented, which assumes modification of conventional ASTM D 7283-06 method, since
samples were directly mixed with liquid scintillation cocktail, without any sample
pretreatment. Method’s optimization involved sample-to-cocktail ratio determination
based on the achieved detection limit and sample’s quench level. Optimal value of Pulse
Shape Analysis (PSA) discriminator that considerably improves performance of LSC
technique through alpha/beta spectra separation during radiological quality
measurements of drinking waters has also been investigated. Results of calibration
experiments and method’s validity measurements on spiked samples with 241Am and
90Sr/90Y aqueous standards are presented. Achieved detection limits for 300 minutes
of counting are MDAα=0.294(11) Bq l-1 and MDAβ=0.405(5) Bq l-1, in alpha and beta
window, respectively. Direct alpha/beta method provides deviations up to 40% from
reference values, but it offers advantages over conventional alpha/beta measurements,
it is ultra fast, simple and inexpensive test for efficient screening of water samples., Rutinski monitoring pijaćih i površinskih voda sprovodi se kontinuirano i nameće
potrebu za razvojem metoda koje su, s jedne strane, pouzdane i tačne, ali istovremeno,
jednostavne i brze. Screening testovi radi procene ukupne alfa/beta aktivnosti u
uzorcima voda, jedna su od često primenjenih tehnika tečne scintilacione
spektroskopije, kojima se efikasno može utvrditi da li uzorak zahteva dalju radiološku
analizu ili ne. U radu je predstavljena optimizacija brze direktne metode za ispitivanje
ukupne alfa/beta aktivnosti u vodama, uz prikaz i diskusiju postignutih granica
detekcije. Ova metoda je modifikacija standardne test metode ASTM D 7283-06 za
ispitivanje ukupne alfa i beta aktivnosti i podrazumeva direktno mešanje uzorka vode sa
scintilacionim koktelom. Na taj način, uzorak je spreman za merenje bez prethodne
pripreme koja, prema standardnim metodama, obično podrazumeva duge procedure
poput uparavanja do suvog ostatka. Optimizacija metode sastoji se u određivanju
optimalnog odnosa uzorak: scintilacioni koktel na osnovu granica detekcije (MDA) u
alfa i beta kanalima, kao i nivoa prigušenja u uzorcima, uzimajući u obzir i maksimalni
kapacitet određenog koktela. Podešena je vrednost PSA (Pulse Shape Analysis)
diskriminatora u cilju optimalne separacije alfa i beta spektara i redukcije pozadinskih
efekata. Kalibracija i validacija metode je izvršena standardnim referentnim materijalima, rastvorima 241Am i 90Sr/90Y. Utvrđeno je da za 300 minuta merenja tečnim
scintilacionim brojačem, mogu se izmeriti koncentracije aktivnosti koje premašuju
vrednosti MDAα=0,294(11) Bq l-1 i MDAβ=0,405(5) Bq l-1 u alfa i beta kanalima,
respektivno. Rezultati validacije metode pokazuju da maksimalna relativna odstupanja
mogu iznositi do 40%, što je prihvatljivo, uzimajući u obzir da metod nije predviđen za
precizno merenje koncentracija aktivnosti pojedinih radionuklida, već za celokupnu
procenu radiološke bezbednosti uzoraka voda.",
publisher = "Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе",
journal = "29. симпозијум ДЗЗСЦГ : зборник радова",
title = "Rapid LSC method for direct alpha/beta measurements in waters, Direktna metoda za određivanje ukupne alfa/beta aktivnosti u vodama",
pages = "537-543",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8326"
}

Stojković, I., Todorović, N., Nikolov, J.,& Tenjović, B.. (2017). Rapid LSC method for direct alpha/beta measurements in waters. in 29. симпозијум ДЗЗСЦГ : зборник радова
Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе., 537-543.
https://hdl.handle.net/21.15107/rcub_vinar_8326

Stojković I, Todorović N, Nikolov J, Tenjović B. Rapid LSC method for direct alpha/beta measurements in waters. in 29. симпозијум ДЗЗСЦГ : зборник радова. 2017;:537-543.
https://hdl.handle.net/21.15107/rcub_vinar_8326 .

Stojković, Ivana, Todorović, Nataša, Nikolov, Jovana, Tenjović, Branislava, "Rapid LSC method for direct alpha/beta measurements in waters" in 29. симпозијум ДЗЗСЦГ : зборник радова (2017):537-543,
https://hdl.handle.net/21.15107/rcub_vinar_8326 .

TY  - CONF
AU  - Nikolov, Jovana
AU  - Todorović, Nataša
AU  - Stojković, Ivana
AU  - Tenjović, Branislava
AU  - Vraničar, Andrej
AU  - Knežević, Jovana
AU  - Vuković, Srđan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8321
UR  - https://plus.sr.cobiss.net/opac7/bib/245691404
UR  - http://dzz.org.rs/wp-content/uploads/2013/06/Zbornik_XXIX_Simpozijum_DZZ_SCG_Srebrno_jezero_2.pdf
AB  - Radon 222Rn nastaje kao produkt raspada 226Ra, rastvorljiv je u vodi i predstavlja jedan
od najzastupljenijih prirodnih izvora zračenja. Monitoring 222Rn u vodi za piće je važno
kontinuirano sprovoditi kako zbog hidrogeoloških studija tako i zbog procene
radiološkog rizika. Postoje različite metode merenja radona u vodi. Alfa
spektrometrijske metode su najzastupljenije, posebno se izdvaja RAD7 kao portabilni
alfa spektrometar koji omogućava merenja na terenu. Tečna scintilaciona
spektrometrija (LSC) se često preferira kao tehnika merenja 222Rn u uzorcima vode.
Sama metoda se sprovodi mešanjem uzoraka vode sa organskim scintilacionim
koktelom, koktel izaziva difuziju radona iz vodenog rastvora u organsku fazu jer radon
ima veći afinitet ka organskoj fazi, čime se sprečava emanacija radona iz vode. Pored
pomenutih metoda, i gama spektrometrijska metoda koja koristi sekularnu radioaktivnu
ravnotežu radona i njegovih potomaka daje zadovoljavajuće rezutlate. U ovom radu
biće prikazane prednosti i mane četiri različite metode merenja radona u vodi: dve LSC
metode (monofazna i dvofazna), RAD7 i gama spektrometrijska metoda. Pored
razčičitih tehnika merenja, u radu će biti prikazano i poređenje dve metode uzorkovanja
voda za analizu.
AB  - Radon 222Rn is formed as a product of decomposition of 226Ra, it is radioactive isotope
that is soluble in water and represents one of the most common natural sources of
radiation. Monitoring of 222Rn in drinking water is important to continuously implement
due to hydrogeological studies and also radiological risk assessment. There are
different methods of measuring radon in water. Alpha spectrometric methods are the
most commonly used, especially RAD7 as a portable alpha spectrometer that allows on
field measurements. Liquid scintillation spectrometry (LSC) is often preferred as a
technique of measuring 222Rn in water samples. The method itself is carried out by
mixing water samples with an organic scintillation cocktail. The cocktail causes the
radon diffusion from the aqueous solution to the organic phase because radon has a
higher affinity for the organic phase, thus preventing the emission of radon from the
water. In addition to the before mentioned methods, a gamma spectrometric method
that uses the secular radioactive equilibrium of radon and its daughter products gave us
satisfactory results. In this paper, the advantages and disadvantages of four different
methods of measuring radon in water will be shown: two LSC methods (monophase and
two-phase), RAD7 and gamma spectrometric method. All three methods have very low
minimal detectable activity (MDA) values, lower than 1 Bq l-1. In addition to the
different measurement techniques, a comparison of two methods for sampling of water
will be presented also on few examples.
PB  - Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе
C3  - 29. симпозијум ДЗЗСЦГ : зборник радова
T1  - Metode merenja Rn222 u vodi
T1  - Methods of Rn222 in water measurement
SP  - 500
EP  - 506
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8321
ER  - 

@conference{
author = "Nikolov, Jovana and Todorović, Nataša and Stojković, Ivana and Tenjović, Branislava and Vraničar, Andrej and Knežević, Jovana and Vuković, Srđan",
year = "2017",
abstract = "Radon 222Rn nastaje kao produkt raspada 226Ra, rastvorljiv je u vodi i predstavlja jedan
od najzastupljenijih prirodnih izvora zračenja. Monitoring 222Rn u vodi za piće je važno
kontinuirano sprovoditi kako zbog hidrogeoloških studija tako i zbog procene
radiološkog rizika. Postoje različite metode merenja radona u vodi. Alfa
spektrometrijske metode su najzastupljenije, posebno se izdvaja RAD7 kao portabilni
alfa spektrometar koji omogućava merenja na terenu. Tečna scintilaciona
spektrometrija (LSC) se često preferira kao tehnika merenja 222Rn u uzorcima vode.
Sama metoda se sprovodi mešanjem uzoraka vode sa organskim scintilacionim
koktelom, koktel izaziva difuziju radona iz vodenog rastvora u organsku fazu jer radon
ima veći afinitet ka organskoj fazi, čime se sprečava emanacija radona iz vode. Pored
pomenutih metoda, i gama spektrometrijska metoda koja koristi sekularnu radioaktivnu
ravnotežu radona i njegovih potomaka daje zadovoljavajuće rezutlate. U ovom radu
biće prikazane prednosti i mane četiri različite metode merenja radona u vodi: dve LSC
metode (monofazna i dvofazna), RAD7 i gama spektrometrijska metoda. Pored
razčičitih tehnika merenja, u radu će biti prikazano i poređenje dve metode uzorkovanja
voda za analizu., Radon 222Rn is formed as a product of decomposition of 226Ra, it is radioactive isotope
that is soluble in water and represents one of the most common natural sources of
radiation. Monitoring of 222Rn in drinking water is important to continuously implement
due to hydrogeological studies and also radiological risk assessment. There are
different methods of measuring radon in water. Alpha spectrometric methods are the
most commonly used, especially RAD7 as a portable alpha spectrometer that allows on
field measurements. Liquid scintillation spectrometry (LSC) is often preferred as a
technique of measuring 222Rn in water samples. The method itself is carried out by
mixing water samples with an organic scintillation cocktail. The cocktail causes the
radon diffusion from the aqueous solution to the organic phase because radon has a
higher affinity for the organic phase, thus preventing the emission of radon from the
water. In addition to the before mentioned methods, a gamma spectrometric method
that uses the secular radioactive equilibrium of radon and its daughter products gave us
satisfactory results. In this paper, the advantages and disadvantages of four different
methods of measuring radon in water will be shown: two LSC methods (monophase and
two-phase), RAD7 and gamma spectrometric method. All three methods have very low
minimal detectable activity (MDA) values, lower than 1 Bq l-1. In addition to the
different measurement techniques, a comparison of two methods for sampling of water
will be presented also on few examples.",
publisher = "Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе",
journal = "29. симпозијум ДЗЗСЦГ : зборник радова",
title = "Metode merenja Rn222 u vodi, Methods of Rn222 in water measurement",
pages = "500-506",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8321"
}

Nikolov, J., Todorović, N., Stojković, I., Tenjović, B., Vraničar, A., Knežević, J.,& Vuković, S.. (2017). Metode merenja Rn222 u vodi. in 29. симпозијум ДЗЗСЦГ : зборник радова
Београд : Институт за нуклеарне науке "Винча" : Друштво за заштиту од зрачења Србије и Црне Горе., 500-506.
https://hdl.handle.net/21.15107/rcub_vinar_8321

Nikolov J, Todorović N, Stojković I, Tenjović B, Vraničar A, Knežević J, Vuković S. Metode merenja Rn222 u vodi. in 29. симпозијум ДЗЗСЦГ : зборник радова. 2017;:500-506.
https://hdl.handle.net/21.15107/rcub_vinar_8321 .

Nikolov, Jovana, Todorović, Nataša, Stojković, Ivana, Tenjović, Branislava, Vraničar, Andrej, Knežević, Jovana, Vuković, Srđan, "Metode merenja Rn222 u vodi" in 29. симпозијум ДЗЗСЦГ : зборник радова (2017):500-506,
https://hdl.handle.net/21.15107/rcub_vinar_8321 .

TY  - JOUR
AU  - Jovic, Aleksandar
AU  - Đorđević, Aleksandar R.
AU  - Čebela, Maria
AU  - Stojković-Simatović, Ivana
AU  - Hercigonja, Radmila V.
AU  - Šljukić, Biljana
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1263
AB  - Electrodes based on composites of zeolites with carbonized polyaniline prepared in the presence of 5-sulfosalicylic acid are evaluated for both qualitative and quantitative determination of phenols in aqueous solutions. Zeolites used included NaX and NaY, as well as their transition metal (Mn and Cu) cation-exchanged forms, and they were all characterized usingXRPD, FTIR and SEM. Cyclic voltammetry was used to study composites electrochemical response in the presence of p-nitrophenol, phenol and 5-aminophenol in acidic, neutral and al- kaline media. Linear dependence of current on p-nitrophenol concentration in acidic media was obtained in 0.11 mM concentration range. The comparative evaluation of the electrochemical response of NaX/carbonized polyaniline composite and its individual components revealed significantly lower limit of detection obtained using composite electrode (1.27 mu M) compared to that obtained using pure zeolite (135 mu M) or pure carbonized polyaniline (94.5 mu M) electrode. Composite electrode gave response to p-nitrophenol presence in neutral media as well, but it quickly disappeared with continuous scanning, while no clear response could be seen in highly alkaline media. Thus, this work demonstrates benefits of using novel composite based on zeolites and carbonized polyaniline for sensing of phenols in acidic aqueous solutions. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Journal of Electroanalytical Chemistry
T1  - Composite zeolite/carbonized polyaniline electrodes for p-nitrophenol sensing
VL  - 778
SP  - 137
EP  - 147
DO  - 10.1016/j.jelechem.2016.08.025
ER  - 

@article{
author = "Jovic, Aleksandar and Đorđević, Aleksandar R. and Čebela, Maria and Stojković-Simatović, Ivana and Hercigonja, Radmila V. and Šljukić, Biljana",
year = "2016",
abstract = "Electrodes based on composites of zeolites with carbonized polyaniline prepared in the presence of 5-sulfosalicylic acid are evaluated for both qualitative and quantitative determination of phenols in aqueous solutions. Zeolites used included NaX and NaY, as well as their transition metal (Mn and Cu) cation-exchanged forms, and they were all characterized usingXRPD, FTIR and SEM. Cyclic voltammetry was used to study composites electrochemical response in the presence of p-nitrophenol, phenol and 5-aminophenol in acidic, neutral and al- kaline media. Linear dependence of current on p-nitrophenol concentration in acidic media was obtained in 0.11 mM concentration range. The comparative evaluation of the electrochemical response of NaX/carbonized polyaniline composite and its individual components revealed significantly lower limit of detection obtained using composite electrode (1.27 mu M) compared to that obtained using pure zeolite (135 mu M) or pure carbonized polyaniline (94.5 mu M) electrode. Composite electrode gave response to p-nitrophenol presence in neutral media as well, but it quickly disappeared with continuous scanning, while no clear response could be seen in highly alkaline media. Thus, this work demonstrates benefits of using novel composite based on zeolites and carbonized polyaniline for sensing of phenols in acidic aqueous solutions. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Journal of Electroanalytical Chemistry",
title = "Composite zeolite/carbonized polyaniline electrodes for p-nitrophenol sensing",
volume = "778",
pages = "137-147",
doi = "10.1016/j.jelechem.2016.08.025"
}

Jovic, A., Đorđević, A. R., Čebela, M., Stojković-Simatović, I., Hercigonja, R. V.,& Šljukić, B.. (2016). Composite zeolite/carbonized polyaniline electrodes for p-nitrophenol sensing. in Journal of Electroanalytical Chemistry, 778, 137-147.
https://doi.org/10.1016/j.jelechem.2016.08.025

Jovic A, Đorđević AR, Čebela M, Stojković-Simatović I, Hercigonja RV, Šljukić B. Composite zeolite/carbonized polyaniline electrodes for p-nitrophenol sensing. in Journal of Electroanalytical Chemistry. 2016;778:137-147.
doi:10.1016/j.jelechem.2016.08.025 .

Jovic, Aleksandar, Đorđević, Aleksandar R., Čebela, Maria, Stojković-Simatović, Ivana, Hercigonja, Radmila V., Šljukić, Biljana, "Composite zeolite/carbonized polyaniline electrodes for p-nitrophenol sensing" in Journal of Electroanalytical Chemistry, 778 (2016):137-147,
https://doi.org/10.1016/j.jelechem.2016.08.025 . .

TY  - JOUR
AU  - Milović, Miloš
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Dominko, Robert
AU  - Stojković-Simatović, Ivana
AU  - Jokić, Bojan M.
AU  - Uskoković, Dragan
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/909
AB  - The key parameters related to cathode materials for commercial use are a high specific capacity, good cycling stability, capacity retention at high current rates, as well as the simplicity of the synthesis process. This study presents a facile synthesis of a composite cathode material, Li2FeSiO4 with carbon, under extreme conditions: rapid heating, short dwell at 750 A degrees C and subsequent quenching. The water-soluble polymer methylcellulose was used both as an excellent dispersing agent and a carbon source that pyrolytically degrades to carbon, thereby enabling the homogeneous deployment of the precursor compounds and the control of the Li2FeSiO4 particle growth from the earliest stage of processing. X-ray powder diffraction reveals the formation of Li2FeSiO4 nanocrystallites with a monoclinic structure in the P2(1)/n space group (#14). The composites electrochemical performance as a cathode material in Li-ion batteries was examined. The influence of the amount of methylcellulose on the microstructural, morphological, conductive, and electrochemical properties of the obtained powders has been discussed. It has been shown that the overall electrochemical performance is improved with an increase of carbon content, through both the decrease of the mean particle diameter and the increase of electrical conductivity.
PB  - Springer
T2  - Cellulose
T1  - The use of methylcellulose for the synthesis of Li2FeSiO4/C composites
VL  - 23
IS  - 1
SP  - 239
EP  - 246
DO  - 10.1007/s10570-015-0806-9
ER  - 

@article{
author = "Milović, Miloš and Jugović, Dragana and Mitrić, Miodrag and Dominko, Robert and Stojković-Simatović, Ivana and Jokić, Bojan M. and Uskoković, Dragan",
year = "2016",
abstract = "The key parameters related to cathode materials for commercial use are a high specific capacity, good cycling stability, capacity retention at high current rates, as well as the simplicity of the synthesis process. This study presents a facile synthesis of a composite cathode material, Li2FeSiO4 with carbon, under extreme conditions: rapid heating, short dwell at 750 A degrees C and subsequent quenching. The water-soluble polymer methylcellulose was used both as an excellent dispersing agent and a carbon source that pyrolytically degrades to carbon, thereby enabling the homogeneous deployment of the precursor compounds and the control of the Li2FeSiO4 particle growth from the earliest stage of processing. X-ray powder diffraction reveals the formation of Li2FeSiO4 nanocrystallites with a monoclinic structure in the P2(1)/n space group (#14). The composites electrochemical performance as a cathode material in Li-ion batteries was examined. The influence of the amount of methylcellulose on the microstructural, morphological, conductive, and electrochemical properties of the obtained powders has been discussed. It has been shown that the overall electrochemical performance is improved with an increase of carbon content, through both the decrease of the mean particle diameter and the increase of electrical conductivity.",
publisher = "Springer",
journal = "Cellulose",
title = "The use of methylcellulose for the synthesis of Li2FeSiO4/C composites",
volume = "23",
number = "1",
pages = "239-246",
doi = "10.1007/s10570-015-0806-9"
}

Milović, M., Jugović, D., Mitrić, M., Dominko, R., Stojković-Simatović, I., Jokić, B. M.,& Uskoković, D.. (2016). The use of methylcellulose for the synthesis of Li2FeSiO4/C composites. in Cellulose
Springer., 23(1), 239-246.
https://doi.org/10.1007/s10570-015-0806-9

Milović M, Jugović D, Mitrić M, Dominko R, Stojković-Simatović I, Jokić BM, Uskoković D. The use of methylcellulose for the synthesis of Li2FeSiO4/C composites. in Cellulose. 2016;23(1):239-246.
doi:10.1007/s10570-015-0806-9 .

Milović, Miloš, Jugović, Dragana, Mitrić, Miodrag, Dominko, Robert, Stojković-Simatović, Ivana, Jokić, Bojan M., Uskoković, Dragan, "The use of methylcellulose for the synthesis of Li2FeSiO4/C composites" in Cellulose, 23, no. 1 (2016):239-246,
https://doi.org/10.1007/s10570-015-0806-9 . .

TY  - JOUR
AU  - Milošević, Sanja S.
AU  - Stojković, Ivana
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/708
AB  - The VO2(B) was synthesized via a simple solvothermal route at 160 degrees C in ethanol. The initial discharge capacity of the VO2(B) anode, in saturated aqueous solution of LiNO3, was 177 mAh g(-1) at a current rate of 50 mA g(-1). After 50 cycles, the capacity fade was 4 %, but from 20th-50th cycle, no capacity drop was observed. The VO2(B) showed very good cyclability at a current rate of even 1000 mA g(-1) with initial discharge capacity of 92 mAh g(-1). The excellent electrochemical performance of VO2(B) was attributed to the stability of micro-nano structures to a repeated intercalation/deintercalation process, very good electronic conductivity as well as the very low charge transfer resistance in an aqueous electrolyte.
T2  - Journal of the Serbian Chemical Society
T1  - High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries
VL  - 80
IS  - 5
SP  - 685
EP  - 694
DO  - 10.2298/JSC140922128M
ER  - 

@article{
author = "Milošević, Sanja S. and Stojković, Ivana and Mitrić, Miodrag and Cvjetićanin, Nikola",
year = "2015",
abstract = "The VO2(B) was synthesized via a simple solvothermal route at 160 degrees C in ethanol. The initial discharge capacity of the VO2(B) anode, in saturated aqueous solution of LiNO3, was 177 mAh g(-1) at a current rate of 50 mA g(-1). After 50 cycles, the capacity fade was 4 %, but from 20th-50th cycle, no capacity drop was observed. The VO2(B) showed very good cyclability at a current rate of even 1000 mA g(-1) with initial discharge capacity of 92 mAh g(-1). The excellent electrochemical performance of VO2(B) was attributed to the stability of micro-nano structures to a repeated intercalation/deintercalation process, very good electronic conductivity as well as the very low charge transfer resistance in an aqueous electrolyte.",
journal = "Journal of the Serbian Chemical Society",
title = "High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries",
volume = "80",
number = "5",
pages = "685-694",
doi = "10.2298/JSC140922128M"
}

Milošević, S. S., Stojković, I., Mitrić, M.,& Cvjetićanin, N.. (2015). High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries. in Journal of the Serbian Chemical Society, 80(5), 685-694.
https://doi.org/10.2298/JSC140922128M

Milošević SS, Stojković I, Mitrić M, Cvjetićanin N. High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries. in Journal of the Serbian Chemical Society. 2015;80(5):685-694.
doi:10.2298/JSC140922128M .

Milošević, Sanja S., Stojković, Ivana, Mitrić, Miodrag, Cvjetićanin, Nikola, "High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries" in Journal of the Serbian Chemical Society, 80, no. 5 (2015):685-694,
https://doi.org/10.2298/JSC140922128M . .

TY  - JOUR
AU  - Vujković, Milica
AU  - Šljukić-Paunković, Biljana
AU  - Stojković-Simatović, Ivana
AU  - Mitrić, Miodrag
AU  - Sequeira, C. A. C.
AU  - Mentus, Slavko V.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/285
AB  - Single phase nanobelt-like Na1.2V3O8 was synthesized by precipitation from aqueous solution of V2O5, H2O2 and NaOH, and subsequent annealing at 400 degrees C. The product was characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. As measured by both galvanostatic charging/discharging and cyclic voltammetry methods, in air-equilibrated equeous electrolyte solutions containing nitrates of lithium, sodium and magnesium, this compound displayed fast inter- calation/deintercalation reactions. The galvanostatic charging and discharging curves observed at rates ranging 500-7000 mA g(-1), did not display clear plateaus characteristic of phase changes. The discharging capacities were found to range 101-35, 55-17 and 67-22 mAh g(-1) for Li, Na and Mg intercalation, respectively. By cyclic voltammetry, for the sweep rates increasing in the range 5-400 mV s(-1) (roughly 9-700 C), the capacity was found to decrease within the limits 63-35 mAh g(-1) for Li+ intercalation, and 40 -11 mAh g(-1) for Na+ and Mg2+ intercalation, respectively. By analyzing the dependence log (current) versus log (sweep rate), the interval of potentials corresponding to preferably diffusion control of intercalation/deintercalation processes was determined. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Versatile insertion capability of Na1.2V3O8 nanobelts in aqueous electrolyte solutions
VL  - 147
SP  - 167
EP  - 175
DO  - 10.1016/j.electacta.2014.08.137
ER  - 

@article{
author = "Vujković, Milica and Šljukić-Paunković, Biljana and Stojković-Simatović, Ivana and Mitrić, Miodrag and Sequeira, C. A. C. and Mentus, Slavko V.",
year = "2014",
abstract = "Single phase nanobelt-like Na1.2V3O8 was synthesized by precipitation from aqueous solution of V2O5, H2O2 and NaOH, and subsequent annealing at 400 degrees C. The product was characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. As measured by both galvanostatic charging/discharging and cyclic voltammetry methods, in air-equilibrated equeous electrolyte solutions containing nitrates of lithium, sodium and magnesium, this compound displayed fast inter- calation/deintercalation reactions. The galvanostatic charging and discharging curves observed at rates ranging 500-7000 mA g(-1), did not display clear plateaus characteristic of phase changes. The discharging capacities were found to range 101-35, 55-17 and 67-22 mAh g(-1) for Li, Na and Mg intercalation, respectively. By cyclic voltammetry, for the sweep rates increasing in the range 5-400 mV s(-1) (roughly 9-700 C), the capacity was found to decrease within the limits 63-35 mAh g(-1) for Li+ intercalation, and 40 -11 mAh g(-1) for Na+ and Mg2+ intercalation, respectively. By analyzing the dependence log (current) versus log (sweep rate), the interval of potentials corresponding to preferably diffusion control of intercalation/deintercalation processes was determined. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Versatile insertion capability of Na1.2V3O8 nanobelts in aqueous electrolyte solutions",
volume = "147",
pages = "167-175",
doi = "10.1016/j.electacta.2014.08.137"
}

Vujković, M., Šljukić-Paunković, B., Stojković-Simatović, I., Mitrić, M., Sequeira, C. A. C.,& Mentus, S. V.. (2014). Versatile insertion capability of Na1.2V3O8 nanobelts in aqueous electrolyte solutions. in Electrochimica Acta, 147, 167-175.
https://doi.org/10.1016/j.electacta.2014.08.137

Vujković M, Šljukić-Paunković B, Stojković-Simatović I, Mitrić M, Sequeira CAC, Mentus SV. Versatile insertion capability of Na1.2V3O8 nanobelts in aqueous electrolyte solutions. in Electrochimica Acta. 2014;147:167-175.
doi:10.1016/j.electacta.2014.08.137 .

Vujković, Milica, Šljukić-Paunković, Biljana, Stojković-Simatović, Ivana, Mitrić, Miodrag, Sequeira, C. A. C., Mentus, Slavko V., "Versatile insertion capability of Na1.2V3O8 nanobelts in aqueous electrolyte solutions" in Electrochimica Acta, 147 (2014):167-175,
https://doi.org/10.1016/j.electacta.2014.08.137 . .

TY  - CONF
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Stojković-Simatović, Ivana
AU  - Cvjetićanin, Nikola
AU  - Mentus, Slavko V.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/407
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7423
AB  - The simple and fast (malonic acid+glycine)-assisted gel-combustion process, followed by a heat treatment at 750oC under reductive atmosphere, is found to be a very effective way for the synthesis of (V-doped LiFePO4)/C composites. The Rietveld refinement confirms that vanadium incorporation into olivine structure was accompanied by the formation of iron phosphide conducting phase. The coulombic capacity and rate capability of (V-doped LiFePO4)/C composite, in both organic and aqueous electrolyte solutions, were significantly improved relative to an undoped sample, as revealed by both galvanostatic cycling and cyclic voltammetry. The average discharging capacities of ~5mol.%V-doped LiFePO4/C composite in an aqueous LiNO3 solution were 91, 73 and 35 mAh g-1 at 1, 10 and 100 C, respectively, with no perceivable capacity fade upon 100 charging/discharging cycles.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
T1  - The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte
SP  - 101
EP  - 101
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7423
ER  - 

@conference{
author = "Vujković, Milica and Jugović, Dragana and Mitrić, Miodrag and Stojković-Simatović, Ivana and Cvjetićanin, Nikola and Mentus, Slavko V.",
year = "2013",
abstract = "The simple and fast (malonic acid+glycine)-assisted gel-combustion process, followed by a heat treatment at 750oC under reductive atmosphere, is found to be a very effective way for the synthesis of (V-doped LiFePO4)/C composites. The Rietveld refinement confirms that vanadium incorporation into olivine structure was accompanied by the formation of iron phosphide conducting phase. The coulombic capacity and rate capability of (V-doped LiFePO4)/C composite, in both organic and aqueous electrolyte solutions, were significantly improved relative to an undoped sample, as revealed by both galvanostatic cycling and cyclic voltammetry. The average discharging capacities of ~5mol.%V-doped LiFePO4/C composite in an aqueous LiNO3 solution were 91, 73 and 35 mAh g-1 at 1, 10 and 100 C, respectively, with no perceivable capacity fade upon 100 charging/discharging cycles.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts",
title = "The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte",
pages = "101-101",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7423"
}

Vujković, M., Jugović, D., Mitrić, M., Stojković-Simatović, I., Cvjetićanin, N.,& Mentus, S. V.. (2013). The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 101-101.
https://hdl.handle.net/21.15107/rcub_vinar_7423

Vujković M, Jugović D, Mitrić M, Stojković-Simatović I, Cvjetićanin N, Mentus SV. The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts. 2013;:101-101.
https://hdl.handle.net/21.15107/rcub_vinar_7423 .

Vujković, Milica, Jugović, Dragana, Mitrić, Miodrag, Stojković-Simatović, Ivana, Cvjetićanin, Nikola, Mentus, Slavko V., "The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte" in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts (2013):101-101,
https://hdl.handle.net/21.15107/rcub_vinar_7423 .

TY  - JOUR
AU  - Vujković, Milica
AU  - Stojković, Ivana
AU  - Mitrić, Miodrag
AU  - Mentus, Slavko V.
AU  - Cvjetićanin, Nikola
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5356
AB  - Li4Ti5O12/C composites with low (3 wt.%) and high (33 wt.%) carbon black content as well as carbon-free Li4Ti5O12 were prepared in two steps under identical conditions: hydrothermal reaction at 130 degrees C and post-calcination at 400 degrees C. The X-ray diffraction experiments confirmed the spinet structure of Li4Ti5O12 in all samples. The carbon content altered significantly the morphology of obtained micro/nanoparticles. The Li4Ti5O12/C composite with the high carbon content showed the highest electrical conductivity (2.0 S cm(-1)), and displayed also extraordinary electrochemical performance: the cyclovoltammograms consisted of well defined reversible redox peaks at a scan rate as high as 10 mV s(-1), while, by galvanostatic cycling, the coulombic capacity of 150 mAh g(-1) was evidenced at a discharging rate of 10 C. (c) 2012 Elsevier Ltd. All rights reserved.
T2  - Materials Research Bulletin
T1  - Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance
VL  - 48
IS  - 2
SP  - 218
EP  - 223
DO  - 10.1016/j.materresbull.2012.09.071
ER  - 

@article{
author = "Vujković, Milica and Stojković, Ivana and Mitrić, Miodrag and Mentus, Slavko V. and Cvjetićanin, Nikola",
year = "2013",
abstract = "Li4Ti5O12/C composites with low (3 wt.%) and high (33 wt.%) carbon black content as well as carbon-free Li4Ti5O12 were prepared in two steps under identical conditions: hydrothermal reaction at 130 degrees C and post-calcination at 400 degrees C. The X-ray diffraction experiments confirmed the spinet structure of Li4Ti5O12 in all samples. The carbon content altered significantly the morphology of obtained micro/nanoparticles. The Li4Ti5O12/C composite with the high carbon content showed the highest electrical conductivity (2.0 S cm(-1)), and displayed also extraordinary electrochemical performance: the cyclovoltammograms consisted of well defined reversible redox peaks at a scan rate as high as 10 mV s(-1), while, by galvanostatic cycling, the coulombic capacity of 150 mAh g(-1) was evidenced at a discharging rate of 10 C. (c) 2012 Elsevier Ltd. All rights reserved.",
journal = "Materials Research Bulletin",
title = "Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance",
volume = "48",
number = "2",
pages = "218-223",
doi = "10.1016/j.materresbull.2012.09.071"
}

Vujković, M., Stojković, I., Mitrić, M., Mentus, S. V.,& Cvjetićanin, N.. (2013). Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance. in Materials Research Bulletin, 48(2), 218-223.
https://doi.org/10.1016/j.materresbull.2012.09.071

Vujković M, Stojković I, Mitrić M, Mentus SV, Cvjetićanin N. Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance. in Materials Research Bulletin. 2013;48(2):218-223.
doi:10.1016/j.materresbull.2012.09.071 .

Vujković, Milica, Stojković, Ivana, Mitrić, Miodrag, Mentus, Slavko V., Cvjetićanin, Nikola, "Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance" in Materials Research Bulletin, 48, no. 2 (2013):218-223,
https://doi.org/10.1016/j.materresbull.2012.09.071 . .

TY  - JOUR
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Stojković, Ivana
AU  - Cvjetićanin, Nikola
AU  - Mentus, Slavko V.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5784
AB  - The nitrate-(glycine + malonic acid)-assisted gel-combustion process, followed by a heat treatment at 750 degrees C under reductive atmosphere, was used as a fast and effective way to synthesize vanadium doped olivine incorporated in carbon matrix, of general formula LiFe(1-x)VxPO4/C. The two-phased Rietveld refinement confirmed that vanadium incorporation into olivine structure was complete. The heating under reduction atmosphere caused the formation of iron phosphide to some extent, the concentration was determined by Rietveld analysis. The capacity and rate capability of these composites were tested by both cyclic voltammetry and galvanostatic cycling. Specifically, the average discharging capacities of the composite with x=0.055, determined in an saturated aqueous LiNO3 solution equilibrated with air, at the rates of 1, 10 and 100 C, amounted to 91, 73 and 35 mAh g(-1), respectively, with no perceivable capacity fade. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions
VL  - 109
SP  - 835
EP  - 842
DO  - 10.1016/j.electacta.2013.07.219
ER  - 

@article{
author = "Vujković, Milica and Jugović, Dragana and Mitrić, Miodrag and Stojković, Ivana and Cvjetićanin, Nikola and Mentus, Slavko V.",
year = "2013",
abstract = "The nitrate-(glycine + malonic acid)-assisted gel-combustion process, followed by a heat treatment at 750 degrees C under reductive atmosphere, was used as a fast and effective way to synthesize vanadium doped olivine incorporated in carbon matrix, of general formula LiFe(1-x)VxPO4/C. The two-phased Rietveld refinement confirmed that vanadium incorporation into olivine structure was complete. The heating under reduction atmosphere caused the formation of iron phosphide to some extent, the concentration was determined by Rietveld analysis. The capacity and rate capability of these composites were tested by both cyclic voltammetry and galvanostatic cycling. Specifically, the average discharging capacities of the composite with x=0.055, determined in an saturated aqueous LiNO3 solution equilibrated with air, at the rates of 1, 10 and 100 C, amounted to 91, 73 and 35 mAh g(-1), respectively, with no perceivable capacity fade. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions",
volume = "109",
pages = "835-842",
doi = "10.1016/j.electacta.2013.07.219"
}

Vujković, M., Jugović, D., Mitrić, M., Stojković, I., Cvjetićanin, N.,& Mentus, S. V.. (2013). The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions. in Electrochimica Acta, 109, 835-842.
https://doi.org/10.1016/j.electacta.2013.07.219

Vujković M, Jugović D, Mitrić M, Stojković I, Cvjetićanin N, Mentus SV. The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions. in Electrochimica Acta. 2013;109:835-842.
doi:10.1016/j.electacta.2013.07.219 .

Vujković, Milica, Jugović, Dragana, Mitrić, Miodrag, Stojković, Ivana, Cvjetićanin, Nikola, Mentus, Slavko V., "The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions" in Electrochimica Acta, 109 (2013):835-842,
https://doi.org/10.1016/j.electacta.2013.07.219 . .