Ćirić, Aleksandar

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Authority KeyName Variants
orcid::0000-0003-2492-9036
  • Ćirić, Aleksandar (72)
Projects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development of the Republic of Serbia
Graphitic and Inorganic Low-dimensional Nanostructures Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
NATO Science for Peace and Security Programme [G5751] Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200162 (University of Belgrade, Faculty of Physics)
Ministry of Education, Science and Technological development of the Republic of Serbia Ministry of Education, Science, and Technological Development of the Republic of Serbia
NanoTBTech - Nanoparticles-based 2D thermal bioimaging technologies National Recruitment Program of High-end Foreign Experts [GDT20185200479]
Chongqing University of Posts and Telecommunications and the National Foreign Experts Program for “Belt and Road Initiative” Innovative Talent Exchange [Grant No. DL2021035001L]
Chongqing University of Posts and Telecommunications (CQUPT) CONACyT [607462, 447874]
Erasmus+ [project Nr. 66345] Estonian Research Council [Grant PUT PRG111]
Estonian Research Council [PUT PRG111] European Regional Development Fund [TK141]
European Union (EU) [TK141] Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites
REMTES - Technology for Remote Temperature Measurements in Microfluidic Devices King Saud University, Riyadh, Saudi Arabia, Researchers Supporting Project [RSP2023R304]
Ministry of Culture and Information of the Republic of Serbia Ministry of Education, Science and Technological Development of the Republic of Serbia.
Ministry of Education, Science, andTechnological Development of the Republic of Serbia Ministry of Education, Science and Technological Development, Serbia
Ministry of Education, Youth and Sports of the Czech Republic [project 8X20001] Ministry of Science, Technological Development and Innovation of the Republic of Serbia
NATO [grant No. SPS.MYP G5751] NATO [Grant No. SPS.MYP G5751]

Author's Bibliography

Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing

Gavrilović, Tamara; Ćirić, Aleksandar; Medić, Mina M.; Ristić, Zoran; Periša, Jovana; Antić, Željka; Dramićanin, Miroslav

(2024)

TY  - JOUR
AU  - Gavrilović, Tamara
AU  - Ćirić, Aleksandar
AU  - Medić, Mina M.
AU  - Ristić, Zoran
AU  - Periša, Jovana
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13710
AB  - first_pagesettingsOrder Article Reprints Open AccessArticle Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing by Tamara Gavrilović *,Aleksandar Ćirić *,Mina Medić,Zoran RistićORCID,Jovana Periša,Željka AntićORCID andMiroslav D. Dramićanin Center of Excellence for Photoconversion, Vinča Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, 11001 Belgrade, Serbia * Authors to whom correspondence should be addressed. Materials 2024, 17(17), 4267; https://doi.org/10.3390/ma17174267 Submission received: 23 July 2024 / Revised: 12 August 2024 / Accepted: 20 August 2024 / Published: 28 August 2024 (This article belongs to the Special Issue Exploring the Versatility of Piezoelectric and Dielectric Electroceramics: Synthesis, Characterization, and Applications) Downloadkeyboard_arrow_down Browse Figures Versions Notes Abstract A set of Eu3+-doped molybdates, Y2−xEuxMo3O12 (x = 0.04; 0.16; 0.2; 0.4; 0.8; 1; 1.6; 2), was synthesized using a solid-state technique and their properties studied as a function of Eu3+ concentration. X-ray diffraction showed that the replacement of Y3+ with larger Eu3+ resulted in a transformation from orthorhombic (low doping concentrations) through tetragonal (high doping concentrations), reaching monoclinic structure for full replacement in Eu2Mo3O12. The intensity of typical Eu3+ red emission slightly increases in the orthorhombic structure then rises significantly with dopant concentration and has the highest value for the tetragonal Y2Mo3O12:80mol% Eu3+. Further, the complete substitution of Y3+ with Eu3+ in the case of monoclinic Eu2Mo3O12 leads to decreased emission intensity. Lifetime follows a similar trend; it is lower in the orthorhombic structure, reaching slightly higher values for the tetragonal structure and showing a strong decrease for monoclinic Eu2Mo3O12. Temperature-sensing properties of the sample with the highest red Eu3+ emission, Y2Mo3O12:80mol% Eu3+, were analyzed by the luminescence intensity ratio method. For the first time, the peak-sharpening algorithm was employed to separate overlapping peaks in luminescence thermometry, in contrast to the peak deconvolution method. The Sr (relative sensitivity) value of 2.8 % K−1 was obtained at room temperature.
T2  - Materials
T1  - Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing
VL  - 17
IS  - 17
SP  - 4267
DO  - 10.3390/ma17174267
ER  - 
@article{
author = "Gavrilović, Tamara and Ćirić, Aleksandar and Medić, Mina M. and Ristić, Zoran and Periša, Jovana and Antić, Željka and Dramićanin, Miroslav",
year = "2024",
abstract = "first_pagesettingsOrder Article Reprints Open AccessArticle Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing by Tamara Gavrilović *,Aleksandar Ćirić *,Mina Medić,Zoran RistićORCID,Jovana Periša,Željka AntićORCID andMiroslav D. Dramićanin Center of Excellence for Photoconversion, Vinča Institute of Nuclear Sciences-National Institute of the Republic of Serbia, University of Belgrade, 11001 Belgrade, Serbia * Authors to whom correspondence should be addressed. Materials 2024, 17(17), 4267; https://doi.org/10.3390/ma17174267 Submission received: 23 July 2024 / Revised: 12 August 2024 / Accepted: 20 August 2024 / Published: 28 August 2024 (This article belongs to the Special Issue Exploring the Versatility of Piezoelectric and Dielectric Electroceramics: Synthesis, Characterization, and Applications) Downloadkeyboard_arrow_down Browse Figures Versions Notes Abstract A set of Eu3+-doped molybdates, Y2−xEuxMo3O12 (x = 0.04; 0.16; 0.2; 0.4; 0.8; 1; 1.6; 2), was synthesized using a solid-state technique and their properties studied as a function of Eu3+ concentration. X-ray diffraction showed that the replacement of Y3+ with larger Eu3+ resulted in a transformation from orthorhombic (low doping concentrations) through tetragonal (high doping concentrations), reaching monoclinic structure for full replacement in Eu2Mo3O12. The intensity of typical Eu3+ red emission slightly increases in the orthorhombic structure then rises significantly with dopant concentration and has the highest value for the tetragonal Y2Mo3O12:80mol% Eu3+. Further, the complete substitution of Y3+ with Eu3+ in the case of monoclinic Eu2Mo3O12 leads to decreased emission intensity. Lifetime follows a similar trend; it is lower in the orthorhombic structure, reaching slightly higher values for the tetragonal structure and showing a strong decrease for monoclinic Eu2Mo3O12. Temperature-sensing properties of the sample with the highest red Eu3+ emission, Y2Mo3O12:80mol% Eu3+, were analyzed by the luminescence intensity ratio method. For the first time, the peak-sharpening algorithm was employed to separate overlapping peaks in luminescence thermometry, in contrast to the peak deconvolution method. The Sr (relative sensitivity) value of 2.8 % K−1 was obtained at room temperature.",
journal = "Materials",
title = "Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing",
volume = "17",
number = "17",
pages = "4267",
doi = "10.3390/ma17174267"
}
Gavrilović, T., Ćirić, A., Medić, M. M., Ristić, Z., Periša, J., Antić, Ž.,& Dramićanin, M.. (2024). Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing. in Materials, 17(17), 4267.
https://doi.org/10.3390/ma17174267
Gavrilović T, Ćirić A, Medić MM, Ristić Z, Periša J, Antić Ž, Dramićanin M. Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing. in Materials. 2024;17(17):4267.
doi:10.3390/ma17174267 .
Gavrilović, Tamara, Ćirić, Aleksandar, Medić, Mina M., Ristić, Zoran, Periša, Jovana, Antić, Željka, Dramićanin, Miroslav, "Structure–Dopant Concentration Relations in Europium-Doped Yttrium Molybdate and Peak-Sharpening for Luminescence Temperature Sensing" in Materials, 17, no. 17 (2024):4267,
https://doi.org/10.3390/ma17174267 . .
1

Tunable emission color of novel Y3NbO7:xDy3+ phosphor

Đačanin Far, Ljubica; Ćirić, Aleksandar; Periša, Jovana; Đorđević, Vesna R.; Ristić, Zoran; Milićević, Bojana R.; Dramićanin, Miroslav

(2024)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Periša, Jovana
AU  - Đorđević, Vesna R.
AU  - Ristić, Zoran
AU  - Milićević, Bojana R.
AU  - Dramićanin, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13412
AB  - Powders of Y3NbO7:xDy3+ (x = 0.5, 1, 1.5, 3 and 5 mol%) were produced through a solid-state process. X-ray diffraction investigations confirm the fluorite-type structure (space group ??3̅?) of powders with crystallite size in the range of 19–60 nm. Both the photoluminescence excitation and emission spectra revealed the presence of defects within the material. With different excitation wavelengths, the emission spectra exhibited distinct emission patterns. At each excitation wavelength, the emission was quenched at Dy3+ concentration higher than 1 mol%. The decay time measurements of the highest intensity emission revealed a progressive decrease from 0.472 milliseconds for x = 0.5 mol% to 0.246 milliseconds for x = 5 mol%. The CIE chromaticity coordinates investigation revealed that the emission color may be altered by varying the excitation wavelength, ranging from blue (excitation at 333 nm) and near-white (excitation at 353 nm and 390 nm) to orange (excitation at 457 nm). The chromaticity of emission under 353 nm and 390 nm excitation validated the material's suitability as an almost-white phosphor.
T2  - Romanian Reports in Physics
T1  - Tunable emission color of novel Y3NbO7:xDy3+ phosphor
VL  - 76
IS  - 2
SP  - 505
DO  - 10.59277/RomRepPhys.2024.76.505
ER  - 
@article{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Periša, Jovana and Đorđević, Vesna R. and Ristić, Zoran and Milićević, Bojana R. and Dramićanin, Miroslav",
year = "2024",
abstract = "Powders of Y3NbO7:xDy3+ (x = 0.5, 1, 1.5, 3 and 5 mol%) were produced through a solid-state process. X-ray diffraction investigations confirm the fluorite-type structure (space group ??3̅?) of powders with crystallite size in the range of 19–60 nm. Both the photoluminescence excitation and emission spectra revealed the presence of defects within the material. With different excitation wavelengths, the emission spectra exhibited distinct emission patterns. At each excitation wavelength, the emission was quenched at Dy3+ concentration higher than 1 mol%. The decay time measurements of the highest intensity emission revealed a progressive decrease from 0.472 milliseconds for x = 0.5 mol% to 0.246 milliseconds for x = 5 mol%. The CIE chromaticity coordinates investigation revealed that the emission color may be altered by varying the excitation wavelength, ranging from blue (excitation at 333 nm) and near-white (excitation at 353 nm and 390 nm) to orange (excitation at 457 nm). The chromaticity of emission under 353 nm and 390 nm excitation validated the material's suitability as an almost-white phosphor.",
journal = "Romanian Reports in Physics",
title = "Tunable emission color of novel Y3NbO7:xDy3+ phosphor",
volume = "76",
number = "2",
pages = "505",
doi = "10.59277/RomRepPhys.2024.76.505"
}
Đačanin Far, L., Ćirić, A., Periša, J., Đorđević, V. R., Ristić, Z., Milićević, B. R.,& Dramićanin, M.. (2024). Tunable emission color of novel Y3NbO7:xDy3+ phosphor. in Romanian Reports in Physics, 76(2), 505.
https://doi.org/10.59277/RomRepPhys.2024.76.505
Đačanin Far L, Ćirić A, Periša J, Đorđević VR, Ristić Z, Milićević BR, Dramićanin M. Tunable emission color of novel Y3NbO7:xDy3+ phosphor. in Romanian Reports in Physics. 2024;76(2):505.
doi:10.59277/RomRepPhys.2024.76.505 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Periša, Jovana, Đorđević, Vesna R., Ristić, Zoran, Milićević, Bojana R., Dramićanin, Miroslav, "Tunable emission color of novel Y3NbO7:xDy3+ phosphor" in Romanian Reports in Physics, 76, no. 2 (2024):505,
https://doi.org/10.59277/RomRepPhys.2024.76.505 . .

Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe

Ćirić, Aleksandar; Maričić, Milica; Ristić, Zoran; Gavrilović, Tamara; Medić, Mina M.; Dramićanin, Miroslav

(2024)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Maričić, Milica
AU  - Ristić, Zoran
AU  - Gavrilović, Tamara
AU  - Medić, Mina M.
AU  - Dramićanin, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13260
AB  - Pure-phase LiAl5O8:Cr3+ leaf-like particles were synthesized by combustion synthetic route at various concentrations. Both sharp peaks and broad emission photoluminescence are apparent even at room temperature. The most optimum doping concentration of 0.75 % based on lifetime and emission intensity was chosen. Peaks of different configurations were separated by deconvolution from 120 K to 680 K, where 4T2 peak increases in temperature to the expense of the sharp 2E emissions, giving luminescence intensity ratio (LIR) relative sensitivity of 2.8 % K−1 at room temperature. Large separation between Cr3+ R lines marks their LIR as perspective at low temperatures. At high temperatures luminescence lifetime provided for 0.8 % K−1 sensitivity, while line-shift and bandwidth methods are not sensitive enough for thermometric applications. Deconvolution of peaks enabled for 10 % more precise estimation of Debye temperature (679 K).
T2  - Current Applied Physics
T1  - Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe
VL  - 64
SP  - 48
EP  - 56
DO  - 10.1016/j.cap.2024.05.013
ER  - 
@article{
author = "Ćirić, Aleksandar and Maričić, Milica and Ristić, Zoran and Gavrilović, Tamara and Medić, Mina M. and Dramićanin, Miroslav",
year = "2024",
abstract = "Pure-phase LiAl5O8:Cr3+ leaf-like particles were synthesized by combustion synthetic route at various concentrations. Both sharp peaks and broad emission photoluminescence are apparent even at room temperature. The most optimum doping concentration of 0.75 % based on lifetime and emission intensity was chosen. Peaks of different configurations were separated by deconvolution from 120 K to 680 K, where 4T2 peak increases in temperature to the expense of the sharp 2E emissions, giving luminescence intensity ratio (LIR) relative sensitivity of 2.8 % K−1 at room temperature. Large separation between Cr3+ R lines marks their LIR as perspective at low temperatures. At high temperatures luminescence lifetime provided for 0.8 % K−1 sensitivity, while line-shift and bandwidth methods are not sensitive enough for thermometric applications. Deconvolution of peaks enabled for 10 % more precise estimation of Debye temperature (679 K).",
journal = "Current Applied Physics",
title = "Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe",
volume = "64",
pages = "48-56",
doi = "10.1016/j.cap.2024.05.013"
}
Ćirić, A., Maričić, M., Ristić, Z., Gavrilović, T., Medić, M. M.,& Dramićanin, M.. (2024). Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe. in Current Applied Physics, 64, 48-56.
https://doi.org/10.1016/j.cap.2024.05.013
Ćirić A, Maričić M, Ristić Z, Gavrilović T, Medić MM, Dramićanin M. Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe. in Current Applied Physics. 2024;64:48-56.
doi:10.1016/j.cap.2024.05.013 .
Ćirić, Aleksandar, Maričić, Milica, Ristić, Zoran, Gavrilović, Tamara, Medić, Mina M., Dramićanin, Miroslav, "Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe" in Current Applied Physics, 64 (2024):48-56,
https://doi.org/10.1016/j.cap.2024.05.013 . .

Overwhelming effects of COVID-19 on public library services and recovery perspectives

Ćirić, Jelena; Ćirić, Aleksandar

(2024)

TY  - JOUR
AU  - Ćirić, Jelena
AU  - Ćirić, Aleksandar
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13654
AB  - Purpose– The COVID-19 pandemic led to a significant decline in library lending, but the response from libraries was insufficient. While researchershave providedguidelines,quantitative analysisofthe extentof the impact is lacking. Design/methodology/approach– Here, we examine library lending trends from 2019 to 2022, comparing the pre-pandemic and pandemic periods, analyzing lending changes among adults and children and different types of literature, using a public library as a case study. Findings– This study shows a significant decrease in lending practice, especially among adults, and later recovery. Digital, fine and scientific literature gained popularity compared to other types. Originality/value– The research results can serve as library management guidelines in case of a new pandemic.
T2  - Library Management
T1  - Overwhelming effects of COVID-19 on public library services and recovery perspectives
VL  - 45
IS  - 6/7
SP  - 477
EP  - 487
DO  - 10.1108/LM-11-2023-0114
ER  - 
@article{
author = "Ćirić, Jelena and Ćirić, Aleksandar",
year = "2024",
abstract = "Purpose– The COVID-19 pandemic led to a significant decline in library lending, but the response from libraries was insufficient. While researchershave providedguidelines,quantitative analysisofthe extentof the impact is lacking. Design/methodology/approach– Here, we examine library lending trends from 2019 to 2022, comparing the pre-pandemic and pandemic periods, analyzing lending changes among adults and children and different types of literature, using a public library as a case study. Findings– This study shows a significant decrease in lending practice, especially among adults, and later recovery. Digital, fine and scientific literature gained popularity compared to other types. Originality/value– The research results can serve as library management guidelines in case of a new pandemic.",
journal = "Library Management",
title = "Overwhelming effects of COVID-19 on public library services and recovery perspectives",
volume = "45",
number = "6/7",
pages = "477-487",
doi = "10.1108/LM-11-2023-0114"
}
Ćirić, J.,& Ćirić, A.. (2024). Overwhelming effects of COVID-19 on public library services and recovery perspectives. in Library Management, 45(6/7), 477-487.
https://doi.org/10.1108/LM-11-2023-0114
Ćirić J, Ćirić A. Overwhelming effects of COVID-19 on public library services and recovery perspectives. in Library Management. 2024;45(6/7):477-487.
doi:10.1108/LM-11-2023-0114 .
Ćirić, Jelena, Ćirić, Aleksandar, "Overwhelming effects of COVID-19 on public library services and recovery perspectives" in Library Management, 45, no. 6/7 (2024):477-487,
https://doi.org/10.1108/LM-11-2023-0114 . .

Perspektive primena inovativnih metoda fotonike, spektroskopije i luminiscencije na razvoj opštine Knjaževac

Ćirić, Aleksandar

(Knjaževac : Narodna biblioteka "Njegoš", 2024)

TY  - CONF
AU  - Ćirić, Aleksandar
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13236
AB  - Abstract: The municipality of Knjaževac represents an area with rich historical and cultural content favorable geographical location, tourist attractions, unique microclimate, and agricultural products. However, it is accompanied by numerous economic and environmental problems. This paper demonstrates
how certain problems can be solved or existing institutions and the commercial sector can be improved by applying new findings in photonics. It is shown how luminescence spectroscopy in librarianship can provide a precise analysis of the age of library materials and how lasers can successfully remove mold from old books. In agriculture, luminescence spectroscopy is demonstrated to determine the origin and quality of honey and wine, which are characteristic features of this region. Luminescent particles can achieve significantly higher yields of fruits, vegetables, and ornamental plants in greenhouses. Finally, hyperspectral cameras monitoring the luminescence of harmful gases show how industrial and landfill pollution levels can be tracked. This enables the implementation of specific measures aimed at improving human and animal health and preserving the environment.
AB  - Апстракт: Општина Књажевац представља средину са богатим историјским и културним садржајем, повољним географским положајем, туристичким садржајем, јединственом микроклимом и прехрамбеним производима, али је праћена мноштвом економских и еколошких проблема. Овај рад показује како је могуће решити одређене проблеме или унапредити рад постојећих институција или комерцијалног сектора применом нових сазнања у фотоници. Показано је како се у библиотекарству луминисцентном спектроскопијом може дати прецизна анализа старости библиотечке грађе уи како се ласерима може успешно уклонити буђ са старих књига. У пољопривреди показано је како се луминисцентном спектроскопијом може утврдити порекло и исправност меда и вина, који су обележја овог краја. Луминисцентним честицама могуће је остварити значајно веће приносе воћа, поврћа и украсног биља у стакленицима. На крају, хиперспектралним камерама које прате луминисценцију штетних гасова показано је како се може пратити ниво индустријског и депонијског загађења, те се може приступити одређеним мерама које за циљ имају побољшање здравља људи и животиња и очувања животне средине.
PB  - Knjaževac : Narodna biblioteka "Njegoš"
PB  - Beograd : Srpsko geografsko društvo
C3  - Knjaževački kraj - potencijali, stanje i perspektive razvoja 2 : zbornik radova Druge Naučne konferencije
T1  - Perspektive primena inovativnih metoda fotonike, spektroskopije i luminiscencije na razvoj opštine Knjaževac
T1  - Perspectives for applications of innovative methods in photonics, spectroscopy and luminescence for the development of Knjaževac municipality
SP  - 133
EP  - 144
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13236
ER  - 
@conference{
author = "Ćirić, Aleksandar",
year = "2024",
abstract = "Abstract: The municipality of Knjaževac represents an area with rich historical and cultural content favorable geographical location, tourist attractions, unique microclimate, and agricultural products. However, it is accompanied by numerous economic and environmental problems. This paper demonstrates
how certain problems can be solved or existing institutions and the commercial sector can be improved by applying new findings in photonics. It is shown how luminescence spectroscopy in librarianship can provide a precise analysis of the age of library materials and how lasers can successfully remove mold from old books. In agriculture, luminescence spectroscopy is demonstrated to determine the origin and quality of honey and wine, which are characteristic features of this region. Luminescent particles can achieve significantly higher yields of fruits, vegetables, and ornamental plants in greenhouses. Finally, hyperspectral cameras monitoring the luminescence of harmful gases show how industrial and landfill pollution levels can be tracked. This enables the implementation of specific measures aimed at improving human and animal health and preserving the environment., Апстракт: Општина Књажевац представља средину са богатим историјским и културним садржајем, повољним географским положајем, туристичким садржајем, јединственом микроклимом и прехрамбеним производима, али је праћена мноштвом економских и еколошких проблема. Овај рад показује како је могуће решити одређене проблеме или унапредити рад постојећих институција или комерцијалног сектора применом нових сазнања у фотоници. Показано је како се у библиотекарству луминисцентном спектроскопијом може дати прецизна анализа старости библиотечке грађе уи како се ласерима може успешно уклонити буђ са старих књига. У пољопривреди показано је како се луминисцентном спектроскопијом може утврдити порекло и исправност меда и вина, који су обележја овог краја. Луминисцентним честицама могуће је остварити значајно веће приносе воћа, поврћа и украсног биља у стакленицима. На крају, хиперспектралним камерама које прате луминисценцију штетних гасова показано је како се може пратити ниво индустријског и депонијског загађења, те се може приступити одређеним мерама које за циљ имају побољшање здравља људи и животиња и очувања животне средине.",
publisher = "Knjaževac : Narodna biblioteka "Njegoš", Beograd : Srpsko geografsko društvo",
journal = "Knjaževački kraj - potencijali, stanje i perspektive razvoja 2 : zbornik radova Druge Naučne konferencije",
title = "Perspektive primena inovativnih metoda fotonike, spektroskopije i luminiscencije na razvoj opštine Knjaževac, Perspectives for applications of innovative methods in photonics, spectroscopy and luminescence for the development of Knjaževac municipality",
pages = "133-144",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13236"
}
Ćirić, A.. (2024). Perspektive primena inovativnih metoda fotonike, spektroskopije i luminiscencije na razvoj opštine Knjaževac. in Knjaževački kraj - potencijali, stanje i perspektive razvoja 2 : zbornik radova Druge Naučne konferencije
Knjaževac : Narodna biblioteka "Njegoš"., 133-144.
https://hdl.handle.net/21.15107/rcub_vinar_13236
Ćirić A. Perspektive primena inovativnih metoda fotonike, spektroskopije i luminiscencije na razvoj opštine Knjaževac. in Knjaževački kraj - potencijali, stanje i perspektive razvoja 2 : zbornik radova Druge Naučne konferencije. 2024;:133-144.
https://hdl.handle.net/21.15107/rcub_vinar_13236 .
Ćirić, Aleksandar, "Perspektive primena inovativnih metoda fotonike, spektroskopije i luminiscencije na razvoj opštine Knjaževac" in Knjaževački kraj - potencijali, stanje i perspektive razvoja 2 : zbornik radova Druge Naučne konferencije (2024):133-144,
https://hdl.handle.net/21.15107/rcub_vinar_13236 .

The photocatalytic ability of visible-light-responsive interfacial charge transfer complex between TiO2 and Tiron

Lazić, Vesna; Sredojević, Dušan; Ćirić, Aleksandar; Nedeljković, Jovan; Zelenková, Gabriela; Férová, Marta; Zelenka, Tomáš; Chavhan, Madhav Prabhakar; Slovák, Václav

(2024)

TY  - JOUR
AU  - Lazić, Vesna
AU  - Sredojević, Dušan
AU  - Ćirić, Aleksandar
AU  - Nedeljković, Jovan
AU  - Zelenková, Gabriela
AU  - Férová, Marta
AU  - Zelenka, Tomáš
AU  - Chavhan, Madhav Prabhakar
AU  - Slovák, Václav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12392
AB  - The surface modification of commercial TiO2 powder with catecholate-type ligand Tiron (TIR) leads to the formation of the interfacial charge transfer complex (ICT) absorbing in the visible spectral range. The estimated band gap energy of the ICT complex (Eg = 2.2 eV) by density functional theory (DFT) calculations agrees with experimental measurements. The surface-modified TiO2 with TIR has enhanced sorption capacity towards Pb2+ ions compared to the pristine one due to the presence of free sulfonate groups. Our attempt to reduce Pb2+ ions to metallic form failed. The TiO2-based ICT complex with TIR can serve as an efficient sorbent to remove Pb2+ ions from the solution without the ability to recover them in metallic form in a photo-driven catalytic process. The photocatalytic ability of the ICT complex to induce oxidation reactions is significantly improved since the complete degradation of organic dye methyl orange occurs under exclusive excitations with visible light photons.
T2  - Journal of Photochemistry and Photobiology A: Chemistry
T1  - The photocatalytic ability of visible-light-responsive interfacial charge transfer complex between TiO2 and Tiron
VL  - 449
SP  - 115394
DO  - 10.1016/j.jphotochem.2023.115394
ER  - 
@article{
author = "Lazić, Vesna and Sredojević, Dušan and Ćirić, Aleksandar and Nedeljković, Jovan and Zelenková, Gabriela and Férová, Marta and Zelenka, Tomáš and Chavhan, Madhav Prabhakar and Slovák, Václav",
year = "2024",
abstract = "The surface modification of commercial TiO2 powder with catecholate-type ligand Tiron (TIR) leads to the formation of the interfacial charge transfer complex (ICT) absorbing in the visible spectral range. The estimated band gap energy of the ICT complex (Eg = 2.2 eV) by density functional theory (DFT) calculations agrees with experimental measurements. The surface-modified TiO2 with TIR has enhanced sorption capacity towards Pb2+ ions compared to the pristine one due to the presence of free sulfonate groups. Our attempt to reduce Pb2+ ions to metallic form failed. The TiO2-based ICT complex with TIR can serve as an efficient sorbent to remove Pb2+ ions from the solution without the ability to recover them in metallic form in a photo-driven catalytic process. The photocatalytic ability of the ICT complex to induce oxidation reactions is significantly improved since the complete degradation of organic dye methyl orange occurs under exclusive excitations with visible light photons.",
journal = "Journal of Photochemistry and Photobiology A: Chemistry",
title = "The photocatalytic ability of visible-light-responsive interfacial charge transfer complex between TiO2 and Tiron",
volume = "449",
pages = "115394",
doi = "10.1016/j.jphotochem.2023.115394"
}
Lazić, V., Sredojević, D., Ćirić, A., Nedeljković, J., Zelenková, G., Férová, M., Zelenka, T., Chavhan, M. P.,& Slovák, V.. (2024). The photocatalytic ability of visible-light-responsive interfacial charge transfer complex between TiO2 and Tiron. in Journal of Photochemistry and Photobiology A: Chemistry, 449, 115394.
https://doi.org/10.1016/j.jphotochem.2023.115394
Lazić V, Sredojević D, Ćirić A, Nedeljković J, Zelenková G, Férová M, Zelenka T, Chavhan MP, Slovák V. The photocatalytic ability of visible-light-responsive interfacial charge transfer complex between TiO2 and Tiron. in Journal of Photochemistry and Photobiology A: Chemistry. 2024;449:115394.
doi:10.1016/j.jphotochem.2023.115394 .
Lazić, Vesna, Sredojević, Dušan, Ćirić, Aleksandar, Nedeljković, Jovan, Zelenková, Gabriela, Férová, Marta, Zelenka, Tomáš, Chavhan, Madhav Prabhakar, Slovák, Václav, "The photocatalytic ability of visible-light-responsive interfacial charge transfer complex between TiO2 and Tiron" in Journal of Photochemistry and Photobiology A: Chemistry, 449 (2024):115394,
https://doi.org/10.1016/j.jphotochem.2023.115394 . .
1
1

Tuning phase and photoluminescent properties of ZrO2:Eu3+ coatings formed by plasma electrolytic oxidation and Judd-Ofelt analysis of composite materials

Ćirić, Aleksandar; Stojadinović, Stevan

(2024)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11828
AB  - Eu3+ doped Zirconia coatings were synthesized by the electrochemical plasma electrolytic oxidation method in only 8 min from the pure zirconium substrate. The phase constitution from pure monoclinic to pure tetragonal and exactly in between was achieved by using different concentrations of Na3PO4 and NaAlO2 electrolytes. The complex emission spectra composed of Eu2+, Eu3+, and ZrO2 defect emission greatly depend on the excitation wavelength and phase constitution. Eu3+ photoluminescence properties depend on the phase, which is reflected by the different Stark splitting and different intensities of transitions. Thus, both phase and photoluminescent properties of ZrO2 coatings are fine-tuneable. Judd-Ofelt analysis was performed from the emission and excitation spectra, showing that all 3 intensity parameters depend linearly on the phase constitution, being largest in the pure monoclinic phase. The mixed phase has Judd-Ofelt parameters between those in pure phases. Eu3+ has 2.45 times more preference to get incorporated into the tetragonal than in the monoclinic phase in the mixed phase samples. The general equation for Judd-Ofelt parameters in a compound with mixed constituents and probability of incorporation is introduced, allowing also for a prediction of the spectrum shape based on the Judd-Ofelt parameters of pure-phase compounds. Python software code for estimating the percent of incorporation by multiple linear regression model is also provided.
T2  - Journal of Luminescence
T1  - Tuning phase and photoluminescent properties of ZrO2:Eu3+ coatings formed by plasma electrolytic oxidation and Judd-Ofelt analysis of composite materials
VL  - 266
SP  - 120268
DO  - 10.1016/j.jlumin.2023.120268
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan",
year = "2024",
abstract = "Eu3+ doped Zirconia coatings were synthesized by the electrochemical plasma electrolytic oxidation method in only 8 min from the pure zirconium substrate. The phase constitution from pure monoclinic to pure tetragonal and exactly in between was achieved by using different concentrations of Na3PO4 and NaAlO2 electrolytes. The complex emission spectra composed of Eu2+, Eu3+, and ZrO2 defect emission greatly depend on the excitation wavelength and phase constitution. Eu3+ photoluminescence properties depend on the phase, which is reflected by the different Stark splitting and different intensities of transitions. Thus, both phase and photoluminescent properties of ZrO2 coatings are fine-tuneable. Judd-Ofelt analysis was performed from the emission and excitation spectra, showing that all 3 intensity parameters depend linearly on the phase constitution, being largest in the pure monoclinic phase. The mixed phase has Judd-Ofelt parameters between those in pure phases. Eu3+ has 2.45 times more preference to get incorporated into the tetragonal than in the monoclinic phase in the mixed phase samples. The general equation for Judd-Ofelt parameters in a compound with mixed constituents and probability of incorporation is introduced, allowing also for a prediction of the spectrum shape based on the Judd-Ofelt parameters of pure-phase compounds. Python software code for estimating the percent of incorporation by multiple linear regression model is also provided.",
journal = "Journal of Luminescence",
title = "Tuning phase and photoluminescent properties of ZrO2:Eu3+ coatings formed by plasma electrolytic oxidation and Judd-Ofelt analysis of composite materials",
volume = "266",
pages = "120268",
doi = "10.1016/j.jlumin.2023.120268"
}
Ćirić, A.,& Stojadinović, S.. (2024). Tuning phase and photoluminescent properties of ZrO2:Eu3+ coatings formed by plasma electrolytic oxidation and Judd-Ofelt analysis of composite materials. in Journal of Luminescence, 266, 120268.
https://doi.org/10.1016/j.jlumin.2023.120268
Ćirić A, Stojadinović S. Tuning phase and photoluminescent properties of ZrO2:Eu3+ coatings formed by plasma electrolytic oxidation and Judd-Ofelt analysis of composite materials. in Journal of Luminescence. 2024;266:120268.
doi:10.1016/j.jlumin.2023.120268 .
Ćirić, Aleksandar, Stojadinović, Stevan, "Tuning phase and photoluminescent properties of ZrO2:Eu3+ coatings formed by plasma electrolytic oxidation and Judd-Ofelt analysis of composite materials" in Journal of Luminescence, 266 (2024):120268,
https://doi.org/10.1016/j.jlumin.2023.120268 . .
2
2

Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations

Đačanin Far, Ljubica; Ćirić, Aleksandar; Sekulić, Milica; Periša, Jovana; Ristić, Zoran; Antić, Željka; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Sekulić, Milica
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10551
AB  - YNbO4:xEu3+ powders (0.1, 0.25, 0.5, 0.75, 1, 3, 5, 7.5, 10, 15, 20 mol %) were synthesized by a solid-state reaction, after homogenization in a vibrational mill. All the samples crystallize in a monoclinic Fergusonite-beta-(Y) structure (C2/c space group), with 45–65 nm crystallite sizes and show a strong orange/red luminescence with 5D0 excited state lifetimes of around 0.6 ms. Photoluminescence emission spectra showed no concentration quenching within the examined concentration range. Judd–Ofelt intensity parameters show a slight increase with rising concentration, up to Ω2 = 8.13∙10−20 cm2, Ω4 = 2.67∙10−20 cm2, and Ω6 is concentration invariant with the 0.35∙10−20 cm2 value. Emission lifetimes of the 5D0 state are almost constant with ∼0.6 ms, and a slight decrease is observed with the highest concentrations. The intrinsic quantum yield of all the samples is about 0.5.
T2  - Optik
T1  - Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations
VL  - 272
SP  - 170398
DO  - 10.1016/j.ijleo.2022.170398
ER  - 
@article{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Sekulić, Milica and Periša, Jovana and Ristić, Zoran and Antić, Željka and Dramićanin, Miroslav",
year = "2023",
abstract = "YNbO4:xEu3+ powders (0.1, 0.25, 0.5, 0.75, 1, 3, 5, 7.5, 10, 15, 20 mol %) were synthesized by a solid-state reaction, after homogenization in a vibrational mill. All the samples crystallize in a monoclinic Fergusonite-beta-(Y) structure (C2/c space group), with 45–65 nm crystallite sizes and show a strong orange/red luminescence with 5D0 excited state lifetimes of around 0.6 ms. Photoluminescence emission spectra showed no concentration quenching within the examined concentration range. Judd–Ofelt intensity parameters show a slight increase with rising concentration, up to Ω2 = 8.13∙10−20 cm2, Ω4 = 2.67∙10−20 cm2, and Ω6 is concentration invariant with the 0.35∙10−20 cm2 value. Emission lifetimes of the 5D0 state are almost constant with ∼0.6 ms, and a slight decrease is observed with the highest concentrations. The intrinsic quantum yield of all the samples is about 0.5.",
journal = "Optik",
title = "Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations",
volume = "272",
pages = "170398",
doi = "10.1016/j.ijleo.2022.170398"
}
Đačanin Far, L., Ćirić, A., Sekulić, M., Periša, J., Ristić, Z., Antić, Ž.,& Dramićanin, M.. (2023). Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations. in Optik, 272, 170398.
https://doi.org/10.1016/j.ijleo.2022.170398
Đačanin Far L, Ćirić A, Sekulić M, Periša J, Ristić Z, Antić Ž, Dramićanin M. Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations. in Optik. 2023;272:170398.
doi:10.1016/j.ijleo.2022.170398 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Sekulić, Milica, Periša, Jovana, Ristić, Zoran, Antić, Željka, Dramićanin, Miroslav, "Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations" in Optik, 272 (2023):170398,
https://doi.org/10.1016/j.ijleo.2022.170398 . .
2
2

Twofold increase in the sensitivity of Er3+/Yb3+ Boltzmann thermometer

Ćirić, Aleksandar; van Swieten, Thomas; Periša, Jovana; Meijerink, Andries; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - van Swieten, Thomas
AU  - Periša, Jovana
AU  - Meijerink, Andries
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11066
AB  - Luminescence thermometry is the most versatile remote temperature sensing technique and can be employed from living cells to large surfaces and from cryogenic temperatures to the melting points of metals. Ongoing research aims to optimize the sensitivity of the ratio between the emission intensity from two coupled excited states. However, this approach is inherently limited to temperature-dependent processes involving only the excited states. Here, we develop a novel measurement technique, called luminescence intensity ratio squared (LIR2) for the Yb3+/Er3+ pair, that combines the temperature sensitivity of ground- and excited-state populations. We use Y3Al5O12:Er3+,Yb3+ nanoparticles as a promising model system with both visible and infrared emissions. To apply our method, we record two luminescence spectra at different excitation wavelengths and determine the LIR2 using one emission in each of the two spectra. The LIR2 testing with Y3Al5O12 nanoparticles showed a sensitivity increase of 70% in the visible region and an impressive 230% increase in the NIR region compared to the conventional LIR method. This enhances the measurement precision by a factor of 1.5–2.5. The LIR2 based on the visible upconversion emission is particularly useful for measurements of high temperatures, while the LIR2 based on the downshifted ∼1.5 μm emission may revolutionize temperature measurements of biological samples in the range of physiological temperatures.
T2  - Journal of Applied Physics
T1  - Twofold increase in the sensitivity of Er3+/Yb3+ Boltzmann thermometer
VL  - 133
IS  - 19
SP  - 194501
DO  - 10.1063/5.0149757
ER  - 
@article{
author = "Ćirić, Aleksandar and van Swieten, Thomas and Periša, Jovana and Meijerink, Andries and Dramićanin, Miroslav",
year = "2023",
abstract = "Luminescence thermometry is the most versatile remote temperature sensing technique and can be employed from living cells to large surfaces and from cryogenic temperatures to the melting points of metals. Ongoing research aims to optimize the sensitivity of the ratio between the emission intensity from two coupled excited states. However, this approach is inherently limited to temperature-dependent processes involving only the excited states. Here, we develop a novel measurement technique, called luminescence intensity ratio squared (LIR2) for the Yb3+/Er3+ pair, that combines the temperature sensitivity of ground- and excited-state populations. We use Y3Al5O12:Er3+,Yb3+ nanoparticles as a promising model system with both visible and infrared emissions. To apply our method, we record two luminescence spectra at different excitation wavelengths and determine the LIR2 using one emission in each of the two spectra. The LIR2 testing with Y3Al5O12 nanoparticles showed a sensitivity increase of 70% in the visible region and an impressive 230% increase in the NIR region compared to the conventional LIR method. This enhances the measurement precision by a factor of 1.5–2.5. The LIR2 based on the visible upconversion emission is particularly useful for measurements of high temperatures, while the LIR2 based on the downshifted ∼1.5 μm emission may revolutionize temperature measurements of biological samples in the range of physiological temperatures.",
journal = "Journal of Applied Physics",
title = "Twofold increase in the sensitivity of Er3+/Yb3+ Boltzmann thermometer",
volume = "133",
number = "19",
pages = "194501",
doi = "10.1063/5.0149757"
}
Ćirić, A., van Swieten, T., Periša, J., Meijerink, A.,& Dramićanin, M.. (2023). Twofold increase in the sensitivity of Er3+/Yb3+ Boltzmann thermometer. in Journal of Applied Physics, 133(19), 194501.
https://doi.org/10.1063/5.0149757
Ćirić A, van Swieten T, Periša J, Meijerink A, Dramićanin M. Twofold increase in the sensitivity of Er3+/Yb3+ Boltzmann thermometer. in Journal of Applied Physics. 2023;133(19):194501.
doi:10.1063/5.0149757 .
Ćirić, Aleksandar, van Swieten, Thomas, Periša, Jovana, Meijerink, Andries, Dramićanin, Miroslav, "Twofold increase in the sensitivity of Er3+/Yb3+ Boltzmann thermometer" in Journal of Applied Physics, 133, no. 19 (2023):194501,
https://doi.org/10.1063/5.0149757 . .
2
4
4

Thirty-Fold Increase in Relative Sensitivity of Dy3+ Luminescent Boltzmann Thermometers Using Multiparameter and Multilevel Cascade Temperature Readings

Antić, Željka; Ćirić, Aleksandar; Sekulić, Milica; Periša, Jovana; Milićević, Bojana; Alodhayb, Abdullah N.; Alrebdi, Tahani A.; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Antić, Željka
AU  - Ćirić, Aleksandar
AU  - Sekulić, Milica
AU  - Periša, Jovana
AU  - Milićević, Bojana
AU  - Alodhayb, Abdullah N.
AU  - Alrebdi, Tahani A.
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11216
AB  - The sensitivity of luminescent Boltzmann thermometers is restricted by the energy difference between the thermally coupled excitement levels of trivalent lanthanides, and their values further decrease with increases in temperature, rendering their use at high temperatures difficult. Here, we demonstrate how to overcome this sensitivity limitation by employing multiparameter and multilevel cascade temperature readings. For this purpose, we synthesized Dy3+:Y2SiO5, a phosphor whose emission is known to begin quenching at very high temperatures. Its photoluminescence-emission features, later used for thermometry, consisted of two blue emission bands centered around 486 nm and 458 nm, and two bands centered around 430 nm and 398 nm, which were only visible at elevated temperatures. Next, we performed thermometry using the standard luminescence-intensity ratio (LIR) method, which employs the 4F9/2 and 4I15/2 Dy3+ levels’ emissions and the multilevel cascade method, which additionally uses the 4G11/2 level and overlapping intensities of 4I13/2, 4M21/2, 4K17/2, and 4F7/2 levels to create two LIRs with a larger energy difference than the standard LIR. This approach yielded a sensitivity that was 3.14 times greater than the standard method. Finally, we simultaneously exploited all the LIRs in the multiparameter temperature readings and found a relative sensitivity that was 30 times greater than that of the standard approach.
T2  - Crystals
T1  - Thirty-Fold Increase in Relative Sensitivity of Dy3+ Luminescent Boltzmann Thermometers Using Multiparameter and Multilevel Cascade Temperature Readings
VL  - 13
IS  - 6
SP  - 884
DO  - 10.3390/cryst13060884
ER  - 
@article{
author = "Antić, Željka and Ćirić, Aleksandar and Sekulić, Milica and Periša, Jovana and Milićević, Bojana and Alodhayb, Abdullah N. and Alrebdi, Tahani A. and Dramićanin, Miroslav",
year = "2023",
abstract = "The sensitivity of luminescent Boltzmann thermometers is restricted by the energy difference between the thermally coupled excitement levels of trivalent lanthanides, and their values further decrease with increases in temperature, rendering their use at high temperatures difficult. Here, we demonstrate how to overcome this sensitivity limitation by employing multiparameter and multilevel cascade temperature readings. For this purpose, we synthesized Dy3+:Y2SiO5, a phosphor whose emission is known to begin quenching at very high temperatures. Its photoluminescence-emission features, later used for thermometry, consisted of two blue emission bands centered around 486 nm and 458 nm, and two bands centered around 430 nm and 398 nm, which were only visible at elevated temperatures. Next, we performed thermometry using the standard luminescence-intensity ratio (LIR) method, which employs the 4F9/2 and 4I15/2 Dy3+ levels’ emissions and the multilevel cascade method, which additionally uses the 4G11/2 level and overlapping intensities of 4I13/2, 4M21/2, 4K17/2, and 4F7/2 levels to create two LIRs with a larger energy difference than the standard LIR. This approach yielded a sensitivity that was 3.14 times greater than the standard method. Finally, we simultaneously exploited all the LIRs in the multiparameter temperature readings and found a relative sensitivity that was 30 times greater than that of the standard approach.",
journal = "Crystals",
title = "Thirty-Fold Increase in Relative Sensitivity of Dy3+ Luminescent Boltzmann Thermometers Using Multiparameter and Multilevel Cascade Temperature Readings",
volume = "13",
number = "6",
pages = "884",
doi = "10.3390/cryst13060884"
}
Antić, Ž., Ćirić, A., Sekulić, M., Periša, J., Milićević, B., Alodhayb, A. N., Alrebdi, T. A.,& Dramićanin, M.. (2023). Thirty-Fold Increase in Relative Sensitivity of Dy3+ Luminescent Boltzmann Thermometers Using Multiparameter and Multilevel Cascade Temperature Readings. in Crystals, 13(6), 884.
https://doi.org/10.3390/cryst13060884
Antić Ž, Ćirić A, Sekulić M, Periša J, Milićević B, Alodhayb AN, Alrebdi TA, Dramićanin M. Thirty-Fold Increase in Relative Sensitivity of Dy3+ Luminescent Boltzmann Thermometers Using Multiparameter and Multilevel Cascade Temperature Readings. in Crystals. 2023;13(6):884.
doi:10.3390/cryst13060884 .
Antić, Željka, Ćirić, Aleksandar, Sekulić, Milica, Periša, Jovana, Milićević, Bojana, Alodhayb, Abdullah N., Alrebdi, Tahani A., Dramićanin, Miroslav, "Thirty-Fold Increase in Relative Sensitivity of Dy3+ Luminescent Boltzmann Thermometers Using Multiparameter and Multilevel Cascade Temperature Readings" in Crystals, 13, no. 6 (2023):884,
https://doi.org/10.3390/cryst13060884 . .
1
2

Thermometric Judd-Ofelt model for Dy3+ ion tested in CaYAlO4 host and evaluation of its sensing performances for luminescence thermometry

Martinović, Ana; Milićević, Bojana; Periša, Jovana; Ristić, Zoran; Stojadinović, Stevan; Dramićanin, Miroslav; Ćirić, Aleksandar

(2023)

TY  - JOUR
AU  - Martinović, Ana
AU  - Milićević, Bojana
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Stojadinović, Stevan
AU  - Dramićanin, Miroslav
AU  - Ćirić, Aleksandar
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11361
AB  - Luminescence thermometry uses temperature-dependent emission of light for remote sensing. Dy3+ is established as a perspective ion for high-temperature probes, but given that there is an infinite number of potential hosts it is impossible to find conventionally the one with the best performance. Judd-Ofelt thermometric model can predict sensitivities but it was not yet experimentally validated on Dy3+ ion. Pure phase CaYAlO4:Dy3+ powder was synthesized via the modified Pechini method. Photoluminescence spectra were taken from 300 to 600 K. Luminescence intensity ratio was estimated using 4 I15/2 and 4 F9/2 levels. Experimentally obtained thermometric parameters and sensitivities showed an excellent matching with those obtained from the Judd-Ofelt, indicating the potential application of the Judd-Ofelt model for fast assessment of Dy3+-doped luminescent sensor thermometric perspective. The maximum absolute and relative sensitivities are ~0.001 K− 1 at 600 K and ~1.4% K− 1 at 300 K, respectively. The optimum temperature range for the CaYAlO4:Dy3+ probe is from 370 to 616 K.
T2  - Physica B: Condensed Matter
T1  - Thermometric Judd-Ofelt model for Dy3+ ion tested in CaYAlO4 host and evaluation of its sensing performances for luminescence thermometry
VL  - 666
SP  - 415096
DO  - 10.1016/j.physb.2023.415096
ER  - 
@article{
author = "Martinović, Ana and Milićević, Bojana and Periša, Jovana and Ristić, Zoran and Stojadinović, Stevan and Dramićanin, Miroslav and Ćirić, Aleksandar",
year = "2023",
abstract = "Luminescence thermometry uses temperature-dependent emission of light for remote sensing. Dy3+ is established as a perspective ion for high-temperature probes, but given that there is an infinite number of potential hosts it is impossible to find conventionally the one with the best performance. Judd-Ofelt thermometric model can predict sensitivities but it was not yet experimentally validated on Dy3+ ion. Pure phase CaYAlO4:Dy3+ powder was synthesized via the modified Pechini method. Photoluminescence spectra were taken from 300 to 600 K. Luminescence intensity ratio was estimated using 4 I15/2 and 4 F9/2 levels. Experimentally obtained thermometric parameters and sensitivities showed an excellent matching with those obtained from the Judd-Ofelt, indicating the potential application of the Judd-Ofelt model for fast assessment of Dy3+-doped luminescent sensor thermometric perspective. The maximum absolute and relative sensitivities are ~0.001 K− 1 at 600 K and ~1.4% K− 1 at 300 K, respectively. The optimum temperature range for the CaYAlO4:Dy3+ probe is from 370 to 616 K.",
journal = "Physica B: Condensed Matter",
title = "Thermometric Judd-Ofelt model for Dy3+ ion tested in CaYAlO4 host and evaluation of its sensing performances for luminescence thermometry",
volume = "666",
pages = "415096",
doi = "10.1016/j.physb.2023.415096"
}
Martinović, A., Milićević, B., Periša, J., Ristić, Z., Stojadinović, S., Dramićanin, M.,& Ćirić, A.. (2023). Thermometric Judd-Ofelt model for Dy3+ ion tested in CaYAlO4 host and evaluation of its sensing performances for luminescence thermometry. in Physica B: Condensed Matter, 666, 415096.
https://doi.org/10.1016/j.physb.2023.415096
Martinović A, Milićević B, Periša J, Ristić Z, Stojadinović S, Dramićanin M, Ćirić A. Thermometric Judd-Ofelt model for Dy3+ ion tested in CaYAlO4 host and evaluation of its sensing performances for luminescence thermometry. in Physica B: Condensed Matter. 2023;666:415096.
doi:10.1016/j.physb.2023.415096 .
Martinović, Ana, Milićević, Bojana, Periša, Jovana, Ristić, Zoran, Stojadinović, Stevan, Dramićanin, Miroslav, Ćirić, Aleksandar, "Thermometric Judd-Ofelt model for Dy3+ ion tested in CaYAlO4 host and evaluation of its sensing performances for luminescence thermometry" in Physica B: Condensed Matter, 666 (2023):415096,
https://doi.org/10.1016/j.physb.2023.415096 . .
1
1

Novel Y3NbO7:xDy3+ phosphor and its tunable emission

Đačanin Far, Ljubica; Ćirić, Aleksandar; Periša, Jovana; Đorđević, Vesna; Ristić, Zoran; Milićević, Bojana; Dramićanin, Miroslav

(Belgrade : Society for science development of Serbia, 2023)

TY  - CONF
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Periša, Jovana
AU  - Đorđević, Vesna
AU  - Ristić, Zoran
AU  - Milićević, Bojana
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13229
AB  - As yttrium niobates, the Y2O3–Nb2O5 combination exists in two forms: YNbO4 and Y3NbO7, and the latter has been studied as a host for photoluminescent ions to a limited extent [1-3]. In this research, the powders of Y3NbO7:xDy3+ (x = 0.5, 1, 1.5, 3 and 5 mol%) were produced through a solid-state process. X-ray diffraction investigations confirmed the fluorite-type structure (space group ) of powders with crystallite size in the range of 19–60 nm. Both the photoluminescence excitation and emission spectra revealed the presence of defects within the material. With different excitation wavelengths, the emission spectra exhibited distinct emission patterns. At each excitation wavelength, the emission was quenched at Dy3+ concentration higher than 1mol%. The decay time measurements of the highest intensity emission revealed a progressive decrease from 0.472 milliseconds for x = 0.5 mol% to 0.246 milliseconds for x = 5 mol%. The CIE chromaticity coordinates investigation revealed that the emission color may be altered by varying the excitation wavelength, ranging from blue (excitation at 333 nm) and nearwhite (excitation at 353 nm and 390 nm) to orange (excitation at 457 nm). The chromaticity of emission under 353 nm and 390 nm excitation validated the material's suitability as an almostwhite phosphor.
PB  - Belgrade : Society for science development of Serbia
C3  - SCOM 2023 : The 2nd Serbian Conference on Materials Application and Technology : Book of abstracts
T1  - Novel Y3NbO7:xDy3+ phosphor and its tunable emission
SP  - O-8
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13229
ER  - 
@conference{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Periša, Jovana and Đorđević, Vesna and Ristić, Zoran and Milićević, Bojana and Dramićanin, Miroslav",
year = "2023",
abstract = "As yttrium niobates, the Y2O3–Nb2O5 combination exists in two forms: YNbO4 and Y3NbO7, and the latter has been studied as a host for photoluminescent ions to a limited extent [1-3]. In this research, the powders of Y3NbO7:xDy3+ (x = 0.5, 1, 1.5, 3 and 5 mol%) were produced through a solid-state process. X-ray diffraction investigations confirmed the fluorite-type structure (space group ) of powders with crystallite size in the range of 19–60 nm. Both the photoluminescence excitation and emission spectra revealed the presence of defects within the material. With different excitation wavelengths, the emission spectra exhibited distinct emission patterns. At each excitation wavelength, the emission was quenched at Dy3+ concentration higher than 1mol%. The decay time measurements of the highest intensity emission revealed a progressive decrease from 0.472 milliseconds for x = 0.5 mol% to 0.246 milliseconds for x = 5 mol%. The CIE chromaticity coordinates investigation revealed that the emission color may be altered by varying the excitation wavelength, ranging from blue (excitation at 333 nm) and nearwhite (excitation at 353 nm and 390 nm) to orange (excitation at 457 nm). The chromaticity of emission under 353 nm and 390 nm excitation validated the material's suitability as an almostwhite phosphor.",
publisher = "Belgrade : Society for science development of Serbia",
journal = "SCOM 2023 : The 2nd Serbian Conference on Materials Application and Technology : Book of abstracts",
title = "Novel Y3NbO7:xDy3+ phosphor and its tunable emission",
pages = "O-8",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13229"
}
Đačanin Far, L., Ćirić, A., Periša, J., Đorđević, V., Ristić, Z., Milićević, B.,& Dramićanin, M.. (2023). Novel Y3NbO7:xDy3+ phosphor and its tunable emission. in SCOM 2023 : The 2nd Serbian Conference on Materials Application and Technology : Book of abstracts
Belgrade : Society for science development of Serbia., O-8.
https://hdl.handle.net/21.15107/rcub_vinar_13229
Đačanin Far L, Ćirić A, Periša J, Đorđević V, Ristić Z, Milićević B, Dramićanin M. Novel Y3NbO7:xDy3+ phosphor and its tunable emission. in SCOM 2023 : The 2nd Serbian Conference on Materials Application and Technology : Book of abstracts. 2023;:O-8.
https://hdl.handle.net/21.15107/rcub_vinar_13229 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Periša, Jovana, Đorđević, Vesna, Ristić, Zoran, Milićević, Bojana, Dramićanin, Miroslav, "Novel Y3NbO7:xDy3+ phosphor and its tunable emission" in SCOM 2023 : The 2nd Serbian Conference on Materials Application and Technology : Book of abstracts (2023):O-8,
https://hdl.handle.net/21.15107/rcub_vinar_13229 .

30-Fold increase in relative sensitivity of Dy3+ luminescent boltzmann thermometers using multiparameter and multilevel cascade temperature readings

Antić, Željka; Ćirić, Aleksandar; Sekulić, Milica; Periša, Jovana; Milićević, Bojana; Dramićanin, Miroslav

(Wroclaw, Poland : W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 2023)

TY  - CONF
AU  - Antić, Željka
AU  - Ćirić, Aleksandar
AU  - Sekulić, Milica
AU  - Periša, Jovana
AU  - Milićević, Bojana
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13278
PB  - Wroclaw, Poland : W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences
PB  - Wroclaw, Poland : University of Wroclaw, Faculty of Chemistry
PB  - Wroclaw, Poland : INTech Transfer Technology Centre
C3  - ESTE 2023 : 8th International Conference on Excited States of Transition Elements : Abstracts book
T1  - 30-Fold increase in relative sensitivity of Dy3+ luminescent boltzmann thermometers using multiparameter and multilevel cascade temperature readings
SP  - O-5
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13278
ER  - 
@conference{
author = "Antić, Željka and Ćirić, Aleksandar and Sekulić, Milica and Periša, Jovana and Milićević, Bojana and Dramićanin, Miroslav",
year = "2023",
publisher = "Wroclaw, Poland : W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Wroclaw, Poland : University of Wroclaw, Faculty of Chemistry, Wroclaw, Poland : INTech Transfer Technology Centre",
journal = "ESTE 2023 : 8th International Conference on Excited States of Transition Elements : Abstracts book",
title = "30-Fold increase in relative sensitivity of Dy3+ luminescent boltzmann thermometers using multiparameter and multilevel cascade temperature readings",
pages = "O-5",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13278"
}
Antić, Ž., Ćirić, A., Sekulić, M., Periša, J., Milićević, B.,& Dramićanin, M.. (2023). 30-Fold increase in relative sensitivity of Dy3+ luminescent boltzmann thermometers using multiparameter and multilevel cascade temperature readings. in ESTE 2023 : 8th International Conference on Excited States of Transition Elements : Abstracts book
Wroclaw, Poland : W. Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences., O-5.
https://hdl.handle.net/21.15107/rcub_vinar_13278
Antić Ž, Ćirić A, Sekulić M, Periša J, Milićević B, Dramićanin M. 30-Fold increase in relative sensitivity of Dy3+ luminescent boltzmann thermometers using multiparameter and multilevel cascade temperature readings. in ESTE 2023 : 8th International Conference on Excited States of Transition Elements : Abstracts book. 2023;:O-5.
https://hdl.handle.net/21.15107/rcub_vinar_13278 .
Antić, Željka, Ćirić, Aleksandar, Sekulić, Milica, Periša, Jovana, Milićević, Bojana, Dramićanin, Miroslav, "30-Fold increase in relative sensitivity of Dy3+ luminescent boltzmann thermometers using multiparameter and multilevel cascade temperature readings" in ESTE 2023 : 8th International Conference on Excited States of Transition Elements : Abstracts book (2023):O-5,
https://hdl.handle.net/21.15107/rcub_vinar_13278 .

Multifunctional Al2O3:Eu2+/Sm2+,3+ + Y2O3:Eu3+ Coatings Created by the Plasma Electrolytic Oxidation

Ćirić, Aleksandar; Stojadinović, Stevan; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11372
AB  - The industrial applications of luminescent coatings for temperature sensing and high-security QR codes have multiple inherent problems in their application (speed, cost, industrial feasibility) or properties (poor adhesion, chemical, thermal stability, or thermal contact). Luminescent coatings created by the electrochemical Plasma Electrolytic Oxidation (PEO) process have superior properties and can be grown directly within minutes, but are limited to the number of possible luminescent dopants. Having the unlimited possibility for doping on the PEO coatings would provide for superior coatings in all industrially appealing features. Herein, it is shown that adding any luminescent powder results in its partial dissociation and incorporation of its constituents, while it also gets incorporated as a whole. In this manner, alumina coatings are grown with various combinations and concentrations of divalent samarium and europium, and yttrium oxide with trivalent europium ions. These polycrystalline coatings whose microhardness is next to that of the diamond produce intense luminescence in the blue and red regions. Al2O3:Eu2+/Sm2+/3+ + Y2O3:Eu3+ coatings show an excellent temperature sensing performance from the cryogenic up to the high temperatures. Ultimately, the proof-of-concept of the luminescent QR code by the electrochemical process is realized creating a highly secure code with unprecedented environmental stability. © 2023 Wiley-VCH GmbH.
T2  - Advanced Materials Technologies
T1  - Multifunctional Al2O3:Eu2+/Sm2+,3+ + Y2O3:Eu3+ Coatings Created by the Plasma Electrolytic Oxidation
DO  - 10.1002/admt.202300607
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Dramićanin, Miroslav",
year = "2023",
abstract = "The industrial applications of luminescent coatings for temperature sensing and high-security QR codes have multiple inherent problems in their application (speed, cost, industrial feasibility) or properties (poor adhesion, chemical, thermal stability, or thermal contact). Luminescent coatings created by the electrochemical Plasma Electrolytic Oxidation (PEO) process have superior properties and can be grown directly within minutes, but are limited to the number of possible luminescent dopants. Having the unlimited possibility for doping on the PEO coatings would provide for superior coatings in all industrially appealing features. Herein, it is shown that adding any luminescent powder results in its partial dissociation and incorporation of its constituents, while it also gets incorporated as a whole. In this manner, alumina coatings are grown with various combinations and concentrations of divalent samarium and europium, and yttrium oxide with trivalent europium ions. These polycrystalline coatings whose microhardness is next to that of the diamond produce intense luminescence in the blue and red regions. Al2O3:Eu2+/Sm2+/3+ + Y2O3:Eu3+ coatings show an excellent temperature sensing performance from the cryogenic up to the high temperatures. Ultimately, the proof-of-concept of the luminescent QR code by the electrochemical process is realized creating a highly secure code with unprecedented environmental stability. © 2023 Wiley-VCH GmbH.",
journal = "Advanced Materials Technologies",
title = "Multifunctional Al2O3:Eu2+/Sm2+,3+ + Y2O3:Eu3+ Coatings Created by the Plasma Electrolytic Oxidation",
doi = "10.1002/admt.202300607"
}
Ćirić, A., Stojadinović, S.,& Dramićanin, M.. (2023). Multifunctional Al2O3:Eu2+/Sm2+,3+ + Y2O3:Eu3+ Coatings Created by the Plasma Electrolytic Oxidation. in Advanced Materials Technologies.
https://doi.org/10.1002/admt.202300607
Ćirić A, Stojadinović S, Dramićanin M. Multifunctional Al2O3:Eu2+/Sm2+,3+ + Y2O3:Eu3+ Coatings Created by the Plasma Electrolytic Oxidation. in Advanced Materials Technologies. 2023;.
doi:10.1002/admt.202300607 .
Ćirić, Aleksandar, Stojadinović, Stevan, Dramićanin, Miroslav, "Multifunctional Al2O3:Eu2+/Sm2+,3+ + Y2O3:Eu3+ Coatings Created by the Plasma Electrolytic Oxidation" in Advanced Materials Technologies (2023),
https://doi.org/10.1002/admt.202300607 . .
4
4

Scientific software for luminescence modelling

Ćirić, Aleksandar; Ristić, Zoran; Dramićanin, Miroslav

(2023)

TY  - CONF
AU  - Ćirić, Aleksandar
AU  - Ristić, Zoran
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13277
C3  - Silk-Road Conference on Luminescent Materials and Devices: Sino-Poland : Book of abstracts
T1  - Scientific software for luminescence modelling
SP  - 65
EP  - 65
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13277
ER  - 
@conference{
author = "Ćirić, Aleksandar and Ristić, Zoran and Dramićanin, Miroslav",
year = "2023",
journal = "Silk-Road Conference on Luminescent Materials and Devices: Sino-Poland : Book of abstracts",
title = "Scientific software for luminescence modelling",
pages = "65-65",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13277"
}
Ćirić, A., Ristić, Z.,& Dramićanin, M.. (2023). Scientific software for luminescence modelling. in Silk-Road Conference on Luminescent Materials and Devices: Sino-Poland : Book of abstracts, 65-65.
https://hdl.handle.net/21.15107/rcub_vinar_13277
Ćirić A, Ristić Z, Dramićanin M. Scientific software for luminescence modelling. in Silk-Road Conference on Luminescent Materials and Devices: Sino-Poland : Book of abstracts. 2023;:65-65.
https://hdl.handle.net/21.15107/rcub_vinar_13277 .
Ćirić, Aleksandar, Ristić, Zoran, Dramićanin, Miroslav, "Scientific software for luminescence modelling" in Silk-Road Conference on Luminescent Materials and Devices: Sino-Poland : Book of abstracts (2023):65-65,
https://hdl.handle.net/21.15107/rcub_vinar_13277 .

Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy

Racu, Andrei V.; Ristić, Zoran; Ćirić, Aleksandar; Ðorđević, Vesna; Buse, Gabriel; Poienar, Maria; Gutmann, Michael J.; Ivashko, Oleh; Stef, Marius; Vizman, Daniel; Dramićanin, Miroslav; Piasecki, Michal; Brik, Mikhail G.

(2023)

TY  - JOUR
AU  - Racu, Andrei V.
AU  - Ristić, Zoran
AU  - Ćirić, Aleksandar
AU  - Ðorđević, Vesna
AU  - Buse, Gabriel
AU  - Poienar, Maria
AU  - Gutmann, Michael J.
AU  - Ivashko, Oleh
AU  - Stef, Marius
AU  - Vizman, Daniel
AU  - Dramićanin, Miroslav
AU  - Piasecki, Michal
AU  - Brik, Mikhail G.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10561
AB  - The understanding of complex relationships between luminescent properties, local symmetry of an emitting center, and the host crystal structure provides a better insight into optical properties of materials. In this work, the alkaline earths CaF2 and BaF2 fluoride crystals doped with 0.1 mol% ErF3 were investigated. The crystals structure has been studied using a synchrotron and laboratory X-ray diffraction. The C3v and C4v sites symmetry were determined using erbium probed high resolution emission spectroscopy (HRPL) at low temperature (LT) of 10 K. The considerable difference in room temperature (RT) optical properties for CaF2 compared to BaF2 crystals was observed. Such difference in absorption intensity of 4.7 times of erbium 4G11/2 manifold in UV, and 7.5 times in green emission from 4S3/2 manifold, could be due to the distinction in the host crystals cationic radius (ΔrCa,Ba) and the dopant-host ionic radius (ΔrCa-Er, ΔrBa-Er). Those Δr differences influence the structure and lead to the following symmetry formation: In CaF2, the C4v and C3v isolated centers were identified, with the determined Er3+- F−i bond lengths of 2.734 Å and 4.735 Å respectively; In BaF2, only C3v isolated centers were identified with the determined Er3+- F−i bond lengths of 5.380 Å. The present work is the first study that takes into account correlations of optical properties, the local symmetry and the structure in mentioned fluorides crystals, and it could be a step forward in the lanthanide doped optical materials systematics.
T2  - Optical Materials
T1  - Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy
VL  - 136
SP  - 113337
DO  - 10.1016/j.optmat.2022.113337
ER  - 
@article{
author = "Racu, Andrei V. and Ristić, Zoran and Ćirić, Aleksandar and Ðorđević, Vesna and Buse, Gabriel and Poienar, Maria and Gutmann, Michael J. and Ivashko, Oleh and Stef, Marius and Vizman, Daniel and Dramićanin, Miroslav and Piasecki, Michal and Brik, Mikhail G.",
year = "2023",
abstract = "The understanding of complex relationships between luminescent properties, local symmetry of an emitting center, and the host crystal structure provides a better insight into optical properties of materials. In this work, the alkaline earths CaF2 and BaF2 fluoride crystals doped with 0.1 mol% ErF3 were investigated. The crystals structure has been studied using a synchrotron and laboratory X-ray diffraction. The C3v and C4v sites symmetry were determined using erbium probed high resolution emission spectroscopy (HRPL) at low temperature (LT) of 10 K. The considerable difference in room temperature (RT) optical properties for CaF2 compared to BaF2 crystals was observed. Such difference in absorption intensity of 4.7 times of erbium 4G11/2 manifold in UV, and 7.5 times in green emission from 4S3/2 manifold, could be due to the distinction in the host crystals cationic radius (ΔrCa,Ba) and the dopant-host ionic radius (ΔrCa-Er, ΔrBa-Er). Those Δr differences influence the structure and lead to the following symmetry formation: In CaF2, the C4v and C3v isolated centers were identified, with the determined Er3+- F−i bond lengths of 2.734 Å and 4.735 Å respectively; In BaF2, only C3v isolated centers were identified with the determined Er3+- F−i bond lengths of 5.380 Å. The present work is the first study that takes into account correlations of optical properties, the local symmetry and the structure in mentioned fluorides crystals, and it could be a step forward in the lanthanide doped optical materials systematics.",
journal = "Optical Materials",
title = "Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy",
volume = "136",
pages = "113337",
doi = "10.1016/j.optmat.2022.113337"
}
Racu, A. V., Ristić, Z., Ćirić, A., Ðorđević, V., Buse, G., Poienar, M., Gutmann, M. J., Ivashko, O., Stef, M., Vizman, D., Dramićanin, M., Piasecki, M.,& Brik, M. G.. (2023). Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy. in Optical Materials, 136, 113337.
https://doi.org/10.1016/j.optmat.2022.113337
Racu AV, Ristić Z, Ćirić A, Ðorđević V, Buse G, Poienar M, Gutmann MJ, Ivashko O, Stef M, Vizman D, Dramićanin M, Piasecki M, Brik MG. Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy. in Optical Materials. 2023;136:113337.
doi:10.1016/j.optmat.2022.113337 .
Racu, Andrei V., Ristić, Zoran, Ćirić, Aleksandar, Ðorđević, Vesna, Buse, Gabriel, Poienar, Maria, Gutmann, Michael J., Ivashko, Oleh, Stef, Marius, Vizman, Daniel, Dramićanin, Miroslav, Piasecki, Michal, Brik, Mikhail G., "Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy" in Optical Materials, 136 (2023):113337,
https://doi.org/10.1016/j.optmat.2022.113337 . .
3
3

The spectroscopic quality factor, phase, morphological, structural, and photoluminescent analysis of ZrO2:Nd3+ coatings created by Plasma electrolytic oxidation

Ćirić, Aleksandar; Stojadinović, Stevan

(2023)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10587
AB  - 15 μm thick ZrO2:Nd3+ coatings were synthesized by the plasma electrolytic oxidation process from the pure zirconium substrate in an alkaline electrolyte with the addition of five different concentrations of Nd2O3 powders. SEM/EDS images show morphologies characterized by numerous pores and cracks, and uniform distribution of coating constituents. XRD revealed that the monoclinic phase is dominant and that Nd impurity stabilizes the tetragonal phase. The average crystalline size is 27.5 nm. XRF revealed a linear increase in incorporated Nd with increasing Nd2O3 concentration. Photoluminescence spectra are characterized by the NIR emissions at typical energies for Nd3+ ion. The highest emission intensity is obtained with 2.0 g/L Nd2O3. The explicit equation for branching ratios in relation to the emission intensities and Judd-Ofelt parameters is recalculated. A novel, more precise equation for the calculation of the spectroscopic quality factor from the most intense emissions is presented. The spectroscopic quality factor is the lowest in the sample with the highest photoluminescent intensity, and is one of the lowest values, in comparison with the 203 spectroscopic quality factors calculated from the Judd-Ofelt parameters in the literature. The luminescence intensity decreases with temperature by the phonon-assisted cross-relaxation mechanism. The luminescence thermometry by the lifetime of 4F3/2 level shows ∼2% K−1 relative sensitivity in the 300–380 K temperature range.
T2  - Journal of Luminescence
T1  - The spectroscopic quality factor, phase, morphological, structural, and photoluminescent analysis of ZrO2:Nd3+ coatings created by Plasma electrolytic oxidation
VL  - 257
SP  - 119665
DO  - 10.1016/j.jlumin.2022.119665
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan",
year = "2023",
abstract = "15 μm thick ZrO2:Nd3+ coatings were synthesized by the plasma electrolytic oxidation process from the pure zirconium substrate in an alkaline electrolyte with the addition of five different concentrations of Nd2O3 powders. SEM/EDS images show morphologies characterized by numerous pores and cracks, and uniform distribution of coating constituents. XRD revealed that the monoclinic phase is dominant and that Nd impurity stabilizes the tetragonal phase. The average crystalline size is 27.5 nm. XRF revealed a linear increase in incorporated Nd with increasing Nd2O3 concentration. Photoluminescence spectra are characterized by the NIR emissions at typical energies for Nd3+ ion. The highest emission intensity is obtained with 2.0 g/L Nd2O3. The explicit equation for branching ratios in relation to the emission intensities and Judd-Ofelt parameters is recalculated. A novel, more precise equation for the calculation of the spectroscopic quality factor from the most intense emissions is presented. The spectroscopic quality factor is the lowest in the sample with the highest photoluminescent intensity, and is one of the lowest values, in comparison with the 203 spectroscopic quality factors calculated from the Judd-Ofelt parameters in the literature. The luminescence intensity decreases with temperature by the phonon-assisted cross-relaxation mechanism. The luminescence thermometry by the lifetime of 4F3/2 level shows ∼2% K−1 relative sensitivity in the 300–380 K temperature range.",
journal = "Journal of Luminescence",
title = "The spectroscopic quality factor, phase, morphological, structural, and photoluminescent analysis of ZrO2:Nd3+ coatings created by Plasma electrolytic oxidation",
volume = "257",
pages = "119665",
doi = "10.1016/j.jlumin.2022.119665"
}
Ćirić, A.,& Stojadinović, S.. (2023). The spectroscopic quality factor, phase, morphological, structural, and photoluminescent analysis of ZrO2:Nd3+ coatings created by Plasma electrolytic oxidation. in Journal of Luminescence, 257, 119665.
https://doi.org/10.1016/j.jlumin.2022.119665
Ćirić A, Stojadinović S. The spectroscopic quality factor, phase, morphological, structural, and photoluminescent analysis of ZrO2:Nd3+ coatings created by Plasma electrolytic oxidation. in Journal of Luminescence. 2023;257:119665.
doi:10.1016/j.jlumin.2022.119665 .
Ćirić, Aleksandar, Stojadinović, Stevan, "The spectroscopic quality factor, phase, morphological, structural, and photoluminescent analysis of ZrO2:Nd3+ coatings created by Plasma electrolytic oxidation" in Journal of Luminescence, 257 (2023):119665,
https://doi.org/10.1016/j.jlumin.2022.119665 . .
6
6

Down-conversion photoluminescence of Ta2O5:Ho3+ and up-conversion photoluminescence of Ta2O5:Ho3+/Yb3+ coatings formed by plasma electrolytic oxidation of tantalum

Stojadinović, Stevan; Perković, Mladen; Ćirić, Aleksandar

(2023)

TY  - JOUR
AU  - Stojadinović, Stevan
AU  - Perković, Mladen
AU  - Ćirić, Aleksandar
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11434
AB  - This study demonstrated that Ta2O5 coatings formed by plasma electrolytic oxidation of tantalum substrate in an alkaline electrolyte containing Ho2O3 nanoparticles have the potential to be used as a host for Ho3+ ions. Down-conversion photoluminescence (PL) intensity of Ta2O5:Ho3+ is strongly dependent on the concentration of Ho3+ incorporated into Ta2O5 coatings, which depends on the duration of the PEO process and the concentration of Ho2O3 nanoparticles in the electrolyte. In the PL emission spectra, dominant green PL emission bands of Ho3+ centered at around 544 nm are assigned to 5S2,5F4 → 5I8 transitions. Also observed are red and near-infrared emission bands centered at around 658 nm and 758 nm, corresponding to the 5F5 → 5I8 and 5S2,5F4 → 5I7 transitions of Ho3+, respectively. The PL excitation spectra of Ho3+ doped Ta2O5 coatings show a broad band from 250 to 325 nm caused by electron transfer between completely filled 2p orbitals of O2− ions and 4f orbitals of Ho3+ ions and a series of sharp peaks between 325 and 500 nm attributed to direct excitation of Ho3+ ions from the 5I8 ground state to higher levels of the 4f-manifold. Ta2O5:Ho3+ coatings do not exhibit detectable up-conversion PL under 980 nm excitation, but Ta2O5:Ho3+/Yb3+ coatings formed in an alkaline electrolyte containing both Ho2O3 and Yb2O3 nanoparticles do. Also discernible are three groups of up-conversion PL emission bands linked to the 4f–4f transition of Ho3+ ions. With increasing Yb3+ ion concentration in coatings, there is a progressive increase in the PL intensity of all up-conversion emission bands, indicating an efficient energy transfer from excited Yb3+ ions to Ho3+ ions. The potential mechanisms for up-conversion that could result in the population of different excited levels are discussed.
T2  - Journal of Materials Science: Materials in Electronics
T1  - Down-conversion photoluminescence of Ta2O5:Ho3+ and up-conversion photoluminescence of Ta2O5:Ho3+/Yb3+ coatings formed by plasma electrolytic oxidation of tantalum
VL  - 34
IS  - 23
SP  - 1658
DO  - 10.1007/s10854-023-11084-4
ER  - 
@article{
author = "Stojadinović, Stevan and Perković, Mladen and Ćirić, Aleksandar",
year = "2023",
abstract = "This study demonstrated that Ta2O5 coatings formed by plasma electrolytic oxidation of tantalum substrate in an alkaline electrolyte containing Ho2O3 nanoparticles have the potential to be used as a host for Ho3+ ions. Down-conversion photoluminescence (PL) intensity of Ta2O5:Ho3+ is strongly dependent on the concentration of Ho3+ incorporated into Ta2O5 coatings, which depends on the duration of the PEO process and the concentration of Ho2O3 nanoparticles in the electrolyte. In the PL emission spectra, dominant green PL emission bands of Ho3+ centered at around 544 nm are assigned to 5S2,5F4 → 5I8 transitions. Also observed are red and near-infrared emission bands centered at around 658 nm and 758 nm, corresponding to the 5F5 → 5I8 and 5S2,5F4 → 5I7 transitions of Ho3+, respectively. The PL excitation spectra of Ho3+ doped Ta2O5 coatings show a broad band from 250 to 325 nm caused by electron transfer between completely filled 2p orbitals of O2− ions and 4f orbitals of Ho3+ ions and a series of sharp peaks between 325 and 500 nm attributed to direct excitation of Ho3+ ions from the 5I8 ground state to higher levels of the 4f-manifold. Ta2O5:Ho3+ coatings do not exhibit detectable up-conversion PL under 980 nm excitation, but Ta2O5:Ho3+/Yb3+ coatings formed in an alkaline electrolyte containing both Ho2O3 and Yb2O3 nanoparticles do. Also discernible are three groups of up-conversion PL emission bands linked to the 4f–4f transition of Ho3+ ions. With increasing Yb3+ ion concentration in coatings, there is a progressive increase in the PL intensity of all up-conversion emission bands, indicating an efficient energy transfer from excited Yb3+ ions to Ho3+ ions. The potential mechanisms for up-conversion that could result in the population of different excited levels are discussed.",
journal = "Journal of Materials Science: Materials in Electronics",
title = "Down-conversion photoluminescence of Ta2O5:Ho3+ and up-conversion photoluminescence of Ta2O5:Ho3+/Yb3+ coatings formed by plasma electrolytic oxidation of tantalum",
volume = "34",
number = "23",
pages = "1658",
doi = "10.1007/s10854-023-11084-4"
}
Stojadinović, S., Perković, M.,& Ćirić, A.. (2023). Down-conversion photoluminescence of Ta2O5:Ho3+ and up-conversion photoluminescence of Ta2O5:Ho3+/Yb3+ coatings formed by plasma electrolytic oxidation of tantalum. in Journal of Materials Science: Materials in Electronics, 34(23), 1658.
https://doi.org/10.1007/s10854-023-11084-4
Stojadinović S, Perković M, Ćirić A. Down-conversion photoluminescence of Ta2O5:Ho3+ and up-conversion photoluminescence of Ta2O5:Ho3+/Yb3+ coatings formed by plasma electrolytic oxidation of tantalum. in Journal of Materials Science: Materials in Electronics. 2023;34(23):1658.
doi:10.1007/s10854-023-11084-4 .
Stojadinović, Stevan, Perković, Mladen, Ćirić, Aleksandar, "Down-conversion photoluminescence of Ta2O5:Ho3+ and up-conversion photoluminescence of Ta2O5:Ho3+/Yb3+ coatings formed by plasma electrolytic oxidation of tantalum" in Journal of Materials Science: Materials in Electronics, 34, no. 23 (2023):1658,
https://doi.org/10.1007/s10854-023-11084-4 . .
1
1

Dual-Mode Photoluminescence of Er3+ -Doped Ta2O5 Coatings Formed by Plasma Electrolytic Oxidation of Tantalum

Stojadinović, Stevan; Ćirić, Aleksandar

(2023)

TY  - JOUR
AU  - Stojadinović, Stevan
AU  - Ćirić, Aleksandar
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11479
AB  - Orthorhombic Ta2O5:Er3+ coatings were obtained by plasma electrolytic oxidation (PEO) of tantalum in an alkaline electrolyte with the addition of Er2O3 particles in various concentrations. Down-conversion photoluminescence (PL) emission spectra is featured by sharp bands attributed to 4f–4f transitions of Er3+. The most intense green PL emission band centered at 544 nm is attributed to the 4S3/2 → 4I15/2 emission of Er3+. Population paths of the Er3+ down-conversion PL happen under resonant excitation conditions of the Er3+ from ground state 4I15/2 to higher levels, and via a broad violet charge transfer excitation band. Both excitation energy and Er content have an impact on the PL emission response in Ta2O5:Er3+ coatings. The 4I15/2 → 4G11/2 transition is the dominant excitation pathway for the PL emission of Er3+. Up-conversion PL spectra created after 980 nm irradiation of Ta2O5:Er3+ coatings have characteristic 4f–4f transitions of Er3+. The intensity of the green 4S3/2 → 4I15/2 is much higher compared to the red 4F9/2 → 4I15/2 emission of Er3+. Co-doping Ta2O5:Er3+ coatings with sensitizer Yb3+ ions increased the up-conversion emission PL intensity of Er3+ thanks to the efficient energy transfer from Yb3+ to Er3+. The red up-conversion PL intensity of 4F9/2 → 4I15/2 transition increases more rapidly with respect to green emission 4S3/2 → 4I15/2. A phonon-assisted energy back transfer process from Er3+ ions (4S3/2 → 4I13/2) to the neighboring Yb3+ ions (2F7/2 → 2F5/2) leads to enhanced red emission 4F9/2 → 4I15 and decreased green emission 4S3/2 → 4I15/2. © 2023, The Minerals, Metals & Materials Society.
T2  - Journal of Electronic Materials
T1  - Dual-Mode Photoluminescence of Er3+ -Doped Ta2O5 Coatings Formed by Plasma Electrolytic Oxidation of Tantalum
DO  - 10.1007/s11664-023-10658-6
ER  - 
@article{
author = "Stojadinović, Stevan and Ćirić, Aleksandar",
year = "2023",
abstract = "Orthorhombic Ta2O5:Er3+ coatings were obtained by plasma electrolytic oxidation (PEO) of tantalum in an alkaline electrolyte with the addition of Er2O3 particles in various concentrations. Down-conversion photoluminescence (PL) emission spectra is featured by sharp bands attributed to 4f–4f transitions of Er3+. The most intense green PL emission band centered at 544 nm is attributed to the 4S3/2 → 4I15/2 emission of Er3+. Population paths of the Er3+ down-conversion PL happen under resonant excitation conditions of the Er3+ from ground state 4I15/2 to higher levels, and via a broad violet charge transfer excitation band. Both excitation energy and Er content have an impact on the PL emission response in Ta2O5:Er3+ coatings. The 4I15/2 → 4G11/2 transition is the dominant excitation pathway for the PL emission of Er3+. Up-conversion PL spectra created after 980 nm irradiation of Ta2O5:Er3+ coatings have characteristic 4f–4f transitions of Er3+. The intensity of the green 4S3/2 → 4I15/2 is much higher compared to the red 4F9/2 → 4I15/2 emission of Er3+. Co-doping Ta2O5:Er3+ coatings with sensitizer Yb3+ ions increased the up-conversion emission PL intensity of Er3+ thanks to the efficient energy transfer from Yb3+ to Er3+. The red up-conversion PL intensity of 4F9/2 → 4I15/2 transition increases more rapidly with respect to green emission 4S3/2 → 4I15/2. A phonon-assisted energy back transfer process from Er3+ ions (4S3/2 → 4I13/2) to the neighboring Yb3+ ions (2F7/2 → 2F5/2) leads to enhanced red emission 4F9/2 → 4I15 and decreased green emission 4S3/2 → 4I15/2. © 2023, The Minerals, Metals & Materials Society.",
journal = "Journal of Electronic Materials",
title = "Dual-Mode Photoluminescence of Er3+ -Doped Ta2O5 Coatings Formed by Plasma Electrolytic Oxidation of Tantalum",
doi = "10.1007/s11664-023-10658-6"
}
Stojadinović, S.,& Ćirić, A.. (2023). Dual-Mode Photoluminescence of Er3+ -Doped Ta2O5 Coatings Formed by Plasma Electrolytic Oxidation of Tantalum. in Journal of Electronic Materials.
https://doi.org/10.1007/s11664-023-10658-6
Stojadinović S, Ćirić A. Dual-Mode Photoluminescence of Er3+ -Doped Ta2O5 Coatings Formed by Plasma Electrolytic Oxidation of Tantalum. in Journal of Electronic Materials. 2023;.
doi:10.1007/s11664-023-10658-6 .
Stojadinović, Stevan, Ćirić, Aleksandar, "Dual-Mode Photoluminescence of Er3+ -Doped Ta2O5 Coatings Formed by Plasma Electrolytic Oxidation of Tantalum" in Journal of Electronic Materials (2023),
https://doi.org/10.1007/s11664-023-10658-6 . .
2
3

Mechanisms of Luminescence in Upconversion Nanoparticles

Ćirić, Aleksandar

(Singapore : Springer Nature Singapore, 2023)

TY  - CHAP
AU  - Ćirić, Aleksandar
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11480
AB  - Upconversion nanoparticles show an increasing interest that is not bound to stop for many years to come. The upconversion is observed in various materials, from transition metals, semiconductor quantum dots, lanthanide ions, organic nanoparticles, and their combinations. The advancement in the field and increase in luminescence efficiency is closely bound to the understanding of the underlying mechanisms behind the upconversion in each of the material types, being that excited state absorption, energy transfer upconversion, cooperative luminescence, triplet–triplet annihilation, etc. Currently, their research state ranges from purely scientific to highly applicative and industry ready, and they all possess their limitations and characteristic spectral appeal. This chapter is concerned with the introduction to these various upconversion nanoparticle types and a description of the most efficient upconversion mechanisms that drive their luminescence, providing a guide—a brief handbook in the world of modern upconverting nanoparticles and systems. © 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
PB  - Singapore : Springer Nature Singapore
T2  - Upconversion Nanoparticles (UCNPs) for Functional Applications
T1  - Mechanisms of Luminescence in Upconversion Nanoparticles
VL  - 24
SP  - 1
EP  - 18
DO  - 10.1007/978-981-99-3913-8_1
ER  - 
@inbook{
author = "Ćirić, Aleksandar",
year = "2023",
abstract = "Upconversion nanoparticles show an increasing interest that is not bound to stop for many years to come. The upconversion is observed in various materials, from transition metals, semiconductor quantum dots, lanthanide ions, organic nanoparticles, and their combinations. The advancement in the field and increase in luminescence efficiency is closely bound to the understanding of the underlying mechanisms behind the upconversion in each of the material types, being that excited state absorption, energy transfer upconversion, cooperative luminescence, triplet–triplet annihilation, etc. Currently, their research state ranges from purely scientific to highly applicative and industry ready, and they all possess their limitations and characteristic spectral appeal. This chapter is concerned with the introduction to these various upconversion nanoparticle types and a description of the most efficient upconversion mechanisms that drive their luminescence, providing a guide—a brief handbook in the world of modern upconverting nanoparticles and systems. © 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.",
publisher = "Singapore : Springer Nature Singapore",
journal = "Upconversion Nanoparticles (UCNPs) for Functional Applications",
booktitle = "Mechanisms of Luminescence in Upconversion Nanoparticles",
volume = "24",
pages = "1-18",
doi = "10.1007/978-981-99-3913-8_1"
}
Ćirić, A.. (2023). Mechanisms of Luminescence in Upconversion Nanoparticles. in Upconversion Nanoparticles (UCNPs) for Functional Applications
Singapore : Springer Nature Singapore., 24, 1-18.
https://doi.org/10.1007/978-981-99-3913-8_1
Ćirić A. Mechanisms of Luminescence in Upconversion Nanoparticles. in Upconversion Nanoparticles (UCNPs) for Functional Applications. 2023;24:1-18.
doi:10.1007/978-981-99-3913-8_1 .
Ćirić, Aleksandar, "Mechanisms of Luminescence in Upconversion Nanoparticles" in Upconversion Nanoparticles (UCNPs) for Functional Applications, 24 (2023):1-18,
https://doi.org/10.1007/978-981-99-3913-8_1 . .

Down-conversion Photoluminescence Properties of ZrO 2 : Ln 3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) Films Formed by Plasma Electrolytic Oxidation

Ćirić, Aleksandar; Stojadinović, Stevan

(Wiley, 2023)

TY  - CHAP
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11640
AB  - Down-conversion photoluminescent ZrO2: Ln3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) films were prepared by the plasma electrolytic oxidation (PEO) method from a pure zirconium foil, by adding Ln2 O3 particles to a basic electrolyte. Photoluminescence (PL) emission spectra of ZrO2: Ln3+ films are characterized by a broad band of ZrO2 host with a maximum positioned at about 490 nm and sharp emission bands ascribed to 4f–4f transitions of Ln3+ ions. The most intense 4f–4f transitions of Ln3+ are 5 D 0  →  7 F2 at 613 nm for Eu3+,4 G5/2  → 6 H7/2 at 617 nm for Sm3+,4 S3/2  → 4 I15/2 at 548 nm for Er3+,5 D4  → 7 F5 at 543 nm for Tb3+,5 F4  → 5 I8 at 540 nm for Ho3+,1 D2  → 3 F4 at 456 nm for Tm3+,3 P0  → 3 H6 at 608 nm for Pr3+,6 P7/2  → 8 S7/2at 313 nm for Gd3+, and4 F9/2 → 6 H13/2at 578 nm for Dy3+. Ln3+ ions in ZrO2 host can be directly excited into 4f levels. For Eu3+ more efficient excitation is through charge transfer band caused by electron transfer between the completely filled 2p orbital of O2− ions and the partially filled 4f orbital of Eu3+, while for Tb3+ through the inter-configurational 4f8  → 4f7 5d1 transition.
PB  - Wiley
T2  - Nanotechnology in Electronics: Materials, Properties, Devices
T1  - Down-conversion Photoluminescence Properties of ZrO 2  : Ln 3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) Films Formed by Plasma Electrolytic Oxidation
SP  - 279
EP  - 300
DO  - 10.1002/9783527824229.ch9
ER  - 
@inbook{
author = "Ćirić, Aleksandar and Stojadinović, Stevan",
year = "2023",
abstract = "Down-conversion photoluminescent ZrO2: Ln3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) films were prepared by the plasma electrolytic oxidation (PEO) method from a pure zirconium foil, by adding Ln2 O3 particles to a basic electrolyte. Photoluminescence (PL) emission spectra of ZrO2: Ln3+ films are characterized by a broad band of ZrO2 host with a maximum positioned at about 490 nm and sharp emission bands ascribed to 4f–4f transitions of Ln3+ ions. The most intense 4f–4f transitions of Ln3+ are 5 D 0  →  7 F2 at 613 nm for Eu3+,4 G5/2  → 6 H7/2 at 617 nm for Sm3+,4 S3/2  → 4 I15/2 at 548 nm for Er3+,5 D4  → 7 F5 at 543 nm for Tb3+,5 F4  → 5 I8 at 540 nm for Ho3+,1 D2  → 3 F4 at 456 nm for Tm3+,3 P0  → 3 H6 at 608 nm for Pr3+,6 P7/2  → 8 S7/2at 313 nm for Gd3+, and4 F9/2 → 6 H13/2at 578 nm for Dy3+. Ln3+ ions in ZrO2 host can be directly excited into 4f levels. For Eu3+ more efficient excitation is through charge transfer band caused by electron transfer between the completely filled 2p orbital of O2− ions and the partially filled 4f orbital of Eu3+, while for Tb3+ through the inter-configurational 4f8  → 4f7 5d1 transition.",
publisher = "Wiley",
journal = "Nanotechnology in Electronics: Materials, Properties, Devices",
booktitle = "Down-conversion Photoluminescence Properties of ZrO 2  : Ln 3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) Films Formed by Plasma Electrolytic Oxidation",
pages = "279-300",
doi = "10.1002/9783527824229.ch9"
}
Ćirić, A.,& Stojadinović, S.. (2023). Down-conversion Photoluminescence Properties of ZrO 2  : Ln 3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) Films Formed by Plasma Electrolytic Oxidation. in Nanotechnology in Electronics: Materials, Properties, Devices
Wiley., 279-300.
https://doi.org/10.1002/9783527824229.ch9
Ćirić A, Stojadinović S. Down-conversion Photoluminescence Properties of ZrO 2  : Ln 3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) Films Formed by Plasma Electrolytic Oxidation. in Nanotechnology in Electronics: Materials, Properties, Devices. 2023;:279-300.
doi:10.1002/9783527824229.ch9 .
Ćirić, Aleksandar, Stojadinović, Stevan, "Down-conversion Photoluminescence Properties of ZrO 2  : Ln 3+ (Ln = Eu, Sm, Er, Tb, Ho, Tm, Pr, Gd, Dy) Films Formed by Plasma Electrolytic Oxidation" in Nanotechnology in Electronics: Materials, Properties, Devices (2023):279-300,
https://doi.org/10.1002/9783527824229.ch9 . .
2
1

Multilevel-cascade intensity ratio temperature read-out of Dy3+ luminescence thermometers

Ćirić, Aleksandar; Periša, Jovana; Zeković, Ivana Lj.; Antić, Željka; Dramićanin, Miroslav

(2022)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Periša, Jovana
AU  - Zeković, Ivana Lj.
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10172
AB  - We report on overcoming the sensitivity limit of Boltzmann's thermometers by utilization of seven thermalized Dy3+ excited states in the Lu1.5Y1·5Al5O12 host. Emission spectra recorded from room temperature to 938 K show transitions originating from seven 4F9/2, 4I15/2, 4G11/2, 4I13/2, 4M21/2, 4K17/2, and 4F7/2 excited levels to the 6H15/2 ground state. We introduce the multi-cascade LIR (McLIR) by extending the conventional, two-thermalized level Boltzmann-type LIR to seven thermalized levels. This approach provides higher energy differences between thermalized levels which results in five times larger sensitivity than in the conventional LIR. Considering energy differences between Dy3+ excited states of 1043, 2464, 4331, and 5089 cm−1, the luminescence thermometry with McLIR provided 0.35, 0.84, 1.47, 1.73% K−1 relative sensitivities at 650 K, respectively, in four different LIR combinations. The validity of the McLIR method and the effectiveness of thermalizations between levels is confirmed with the good theoretical fit of experimental data.
T2  - Journal of Luminescence
T1  - Multilevel-cascade intensity ratio temperature read-out of Dy3+ luminescence thermometers
VL  - 245
SP  - 118795
DO  - 10.1016/j.jlumin.2022.118795
ER  - 
@article{
author = "Ćirić, Aleksandar and Periša, Jovana and Zeković, Ivana Lj. and Antić, Željka and Dramićanin, Miroslav",
year = "2022",
abstract = "We report on overcoming the sensitivity limit of Boltzmann's thermometers by utilization of seven thermalized Dy3+ excited states in the Lu1.5Y1·5Al5O12 host. Emission spectra recorded from room temperature to 938 K show transitions originating from seven 4F9/2, 4I15/2, 4G11/2, 4I13/2, 4M21/2, 4K17/2, and 4F7/2 excited levels to the 6H15/2 ground state. We introduce the multi-cascade LIR (McLIR) by extending the conventional, two-thermalized level Boltzmann-type LIR to seven thermalized levels. This approach provides higher energy differences between thermalized levels which results in five times larger sensitivity than in the conventional LIR. Considering energy differences between Dy3+ excited states of 1043, 2464, 4331, and 5089 cm−1, the luminescence thermometry with McLIR provided 0.35, 0.84, 1.47, 1.73% K−1 relative sensitivities at 650 K, respectively, in four different LIR combinations. The validity of the McLIR method and the effectiveness of thermalizations between levels is confirmed with the good theoretical fit of experimental data.",
journal = "Journal of Luminescence",
title = "Multilevel-cascade intensity ratio temperature read-out of Dy3+ luminescence thermometers",
volume = "245",
pages = "118795",
doi = "10.1016/j.jlumin.2022.118795"
}
Ćirić, A., Periša, J., Zeković, I. Lj., Antić, Ž.,& Dramićanin, M.. (2022). Multilevel-cascade intensity ratio temperature read-out of Dy3+ luminescence thermometers. in Journal of Luminescence, 245, 118795.
https://doi.org/10.1016/j.jlumin.2022.118795
Ćirić A, Periša J, Zeković IL, Antić Ž, Dramićanin M. Multilevel-cascade intensity ratio temperature read-out of Dy3+ luminescence thermometers. in Journal of Luminescence. 2022;245:118795.
doi:10.1016/j.jlumin.2022.118795 .
Ćirić, Aleksandar, Periša, Jovana, Zeković, Ivana Lj., Antić, Željka, Dramićanin, Miroslav, "Multilevel-cascade intensity ratio temperature read-out of Dy3+ luminescence thermometers" in Journal of Luminescence, 245 (2022):118795,
https://doi.org/10.1016/j.jlumin.2022.118795 . .
2
14
12
14

Photoluminescence of Y3NbO7:Eu3+ powders

Đačanin Far, Ljubica; Ćirić, Aleksandar; Ristić, Zoran; Periša, Jovana; Dramićanin, Tatjana; Lukić-Petrović, Svetlana R.; Dramićanin, Miroslav

(2022)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Ristić, Zoran
AU  - Periša, Jovana
AU  - Dramićanin, Tatjana
AU  - Lukić-Petrović, Svetlana R.
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10342
AB  - Y3NbO7:xEu3+ powders (x = 0.25, 0.5, 0.75, 2, 3, 5, 10 at%) were synthesized by a two-step vibrational milling, alternating with annealing. All the samples crystallize as fluorite-type structure (space group Fm3‾m), with crystallite size 50–60 nm and show a strong orange/red luminescence with an excited state lifetime around 1.2 ms. Photoluminescence excitation and emission spectra show rapid intensity decline after 3 at% of Eu3+ content, indicating this concentration as critical for the concentration quenching, and we predicted multipolar interaction as the dominant mechanism behind it. Judd–Ofelt intensity parameters (Ω2 = 0.941∙10−20 cm2, Ω4 = 0.277∙10−20 cm2, Ω6 = 0.277∙10−20 cm2) were obtained from the excitation spectrum of Y3NbO7:3 at%Eu3+. The emission of this luminescent powder is characterized by radiative and nonradiative lifetimes of 2.3 ms and 2.4 ms, respectively, and an intrinsic quantum yield of 51.5%.
T2  - Ceramics International
T1  - Photoluminescence of Y3NbO7:Eu3+ powders
DO  - 10.1016/j.ceramint.2022.06.130
ER  - 
@article{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Ristić, Zoran and Periša, Jovana and Dramićanin, Tatjana and Lukić-Petrović, Svetlana R. and Dramićanin, Miroslav",
year = "2022",
abstract = "Y3NbO7:xEu3+ powders (x = 0.25, 0.5, 0.75, 2, 3, 5, 10 at%) were synthesized by a two-step vibrational milling, alternating with annealing. All the samples crystallize as fluorite-type structure (space group Fm3‾m), with crystallite size 50–60 nm and show a strong orange/red luminescence with an excited state lifetime around 1.2 ms. Photoluminescence excitation and emission spectra show rapid intensity decline after 3 at% of Eu3+ content, indicating this concentration as critical for the concentration quenching, and we predicted multipolar interaction as the dominant mechanism behind it. Judd–Ofelt intensity parameters (Ω2 = 0.941∙10−20 cm2, Ω4 = 0.277∙10−20 cm2, Ω6 = 0.277∙10−20 cm2) were obtained from the excitation spectrum of Y3NbO7:3 at%Eu3+. The emission of this luminescent powder is characterized by radiative and nonradiative lifetimes of 2.3 ms and 2.4 ms, respectively, and an intrinsic quantum yield of 51.5%.",
journal = "Ceramics International",
title = "Photoluminescence of Y3NbO7:Eu3+ powders",
doi = "10.1016/j.ceramint.2022.06.130"
}
Đačanin Far, L., Ćirić, A., Ristić, Z., Periša, J., Dramićanin, T., Lukić-Petrović, S. R.,& Dramićanin, M.. (2022). Photoluminescence of Y3NbO7:Eu3+ powders. in Ceramics International.
https://doi.org/10.1016/j.ceramint.2022.06.130
Đačanin Far L, Ćirić A, Ristić Z, Periša J, Dramićanin T, Lukić-Petrović SR, Dramićanin M. Photoluminescence of Y3NbO7:Eu3+ powders. in Ceramics International. 2022;.
doi:10.1016/j.ceramint.2022.06.130 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Ristić, Zoran, Periša, Jovana, Dramićanin, Tatjana, Lukić-Petrović, Svetlana R., Dramićanin, Miroslav, "Photoluminescence of Y3NbO7:Eu3+ powders" in Ceramics International (2022),
https://doi.org/10.1016/j.ceramint.2022.06.130 . .
10
9

Exploiting High-Energy Emissions of YAlO3:Dy3+ for Sensitivity Improvement of Ratiometric Luminescence Thermometry

Periša, Jovana; Ćirić, Aleksandar; Zeković, Ivana Lj.; Đorđević, Vesna; Sekulić, Milica; Antić, Željka; Dramićanin, Miroslav

(2022)

TY  - JOUR
AU  - Periša, Jovana
AU  - Ćirić, Aleksandar
AU  - Zeković, Ivana Lj.
AU  - Đorđević, Vesna
AU  - Sekulić, Milica
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10481
AB  - The sensitivity of luminescence thermometry is enhanced at high temperatures when using a three-level luminescence intensity ratio approach with Dy3+- activated yttrium aluminum perovskite. This material was synthesized via the Pechini method, and the structure was verified using X-ray diffraction analysis. The average crystallite size was calculated to be around 46 nm. The morphology was examined using scanning electron microscopy, which showed agglomerates composed of densely packed, elongated spherical particles, the majority of which were 80–100 nm in size. The temperature-dependent photoluminescence emission spectra (ex = 353 nm, 300–850 K) included Dy3+ emissions in blue (458 nm), blue (483 nm), and violet (430 nm, T 600 K). Luminescence intensity ratio, the most utilized temperature readout method in luminescent thermometry, was used as the testing method: a) using the intensity ratio of Dy3+ ions and 4I15/2→6H15/2/4F9/2→6H15/2 transitions; and b) employing the third, higher energy 4G11/2 thermalized level, i.e., using the intensity ratio of 4G11/2→6H15/2/4F9/2→6H15/2 transitions, thereby showing the relative sensitivities of 0.41% K−1 and 0.86% K−1 at 600 K, respectively. This more than doubles the increase in sensitivity and therefore demonstrates the method’s usability at high temperatures, although the major limitation of the method is the chemical stability of the host material and the temperature at which the temperature quenching commences. Lastly, it must be noted that at 850 K, the emission intensities from the energetically higher levels were still increasing in YAP: Dy3+.
T2  - Sensors
T1  - Exploiting High-Energy Emissions of YAlO3:Dy3+ for Sensitivity Improvement of Ratiometric Luminescence Thermometry
VL  - 22
IS  - 20
SP  - 7997
DO  - 10.3390/s22207997
ER  - 
@article{
author = "Periša, Jovana and Ćirić, Aleksandar and Zeković, Ivana Lj. and Đorđević, Vesna and Sekulić, Milica and Antić, Željka and Dramićanin, Miroslav",
year = "2022",
abstract = "The sensitivity of luminescence thermometry is enhanced at high temperatures when using a three-level luminescence intensity ratio approach with Dy3+- activated yttrium aluminum perovskite. This material was synthesized via the Pechini method, and the structure was verified using X-ray diffraction analysis. The average crystallite size was calculated to be around 46 nm. The morphology was examined using scanning electron microscopy, which showed agglomerates composed of densely packed, elongated spherical particles, the majority of which were 80–100 nm in size. The temperature-dependent photoluminescence emission spectra (ex = 353 nm, 300–850 K) included Dy3+ emissions in blue (458 nm), blue (483 nm), and violet (430 nm, T 600 K). Luminescence intensity ratio, the most utilized temperature readout method in luminescent thermometry, was used as the testing method: a) using the intensity ratio of Dy3+ ions and 4I15/2→6H15/2/4F9/2→6H15/2 transitions; and b) employing the third, higher energy 4G11/2 thermalized level, i.e., using the intensity ratio of 4G11/2→6H15/2/4F9/2→6H15/2 transitions, thereby showing the relative sensitivities of 0.41% K−1 and 0.86% K−1 at 600 K, respectively. This more than doubles the increase in sensitivity and therefore demonstrates the method’s usability at high temperatures, although the major limitation of the method is the chemical stability of the host material and the temperature at which the temperature quenching commences. Lastly, it must be noted that at 850 K, the emission intensities from the energetically higher levels were still increasing in YAP: Dy3+.",
journal = "Sensors",
title = "Exploiting High-Energy Emissions of YAlO3:Dy3+ for Sensitivity Improvement of Ratiometric Luminescence Thermometry",
volume = "22",
number = "20",
pages = "7997",
doi = "10.3390/s22207997"
}
Periša, J., Ćirić, A., Zeković, I. Lj., Đorđević, V., Sekulić, M., Antić, Ž.,& Dramićanin, M.. (2022). Exploiting High-Energy Emissions of YAlO3:Dy3+ for Sensitivity Improvement of Ratiometric Luminescence Thermometry. in Sensors, 22(20), 7997.
https://doi.org/10.3390/s22207997
Periša J, Ćirić A, Zeković IL, Đorđević V, Sekulić M, Antić Ž, Dramićanin M. Exploiting High-Energy Emissions of YAlO3:Dy3+ for Sensitivity Improvement of Ratiometric Luminescence Thermometry. in Sensors. 2022;22(20):7997.
doi:10.3390/s22207997 .
Periša, Jovana, Ćirić, Aleksandar, Zeković, Ivana Lj., Đorđević, Vesna, Sekulić, Milica, Antić, Željka, Dramićanin, Miroslav, "Exploiting High-Energy Emissions of YAlO3:Dy3+ for Sensitivity Improvement of Ratiometric Luminescence Thermometry" in Sensors, 22, no. 20 (2022):7997,
https://doi.org/10.3390/s22207997 . .
1
4
4

MgAl2O4:Cr3+ probe for luminescence thermometry in the physiological temperatures range

Periša, Jovana; Ćirić, Aleksandar; Ristić, Zoran; Antić, Željka; Dramićanin, Miroslav

(Belgrade : Society for science development of Serbia, 2022)

TY  - CONF
AU  - Periša, Jovana
AU  - Ćirić, Aleksandar
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13233
AB  - Temperature sensing from the photoluminescence of MgAl2O4:Cr3+ powder is systematically examined and presented. The material was prepared by the self-propagating high-temperature synthesis method and its structure was confirmed by X-ray diffraction analysis. In this host, Cr3+ ions are in a strong crystal field, so the overlapping emissions from 2E and 4T2 energy levels are observed. Emission and excitation spectra were recorded in the 300 - 540 K temperature range. The broad photoluminescence attributed to 4T2→4A2 transition increases in intensity with an increase in temperature on account of 2E→4A2 emission intensity until 460 K when both emissions start quenching. The emissions were separated by deconvolution at each temperature and used for the luminescence intensity ratio temperature readout method. The obtained relative sensitivity displayed high values in the physiological range, from 3.5 %K-1 at 300 K to 2.9 %K-1 at 330 K, above 2 %K-1 below 400 K, and above 1 %K-1 between 400 K and 540 K.
PB  - Belgrade : Society for science development of Serbia
C3  - ICOM&IWPPP 2022 : The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors : Book of abstracts
T1  - MgAl2O4:Cr3+ probe for luminescence thermometry in the physiological temperatures range
SP  - P-31
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13233
ER  - 
@conference{
author = "Periša, Jovana and Ćirić, Aleksandar and Ristić, Zoran and Antić, Željka and Dramićanin, Miroslav",
year = "2022",
abstract = "Temperature sensing from the photoluminescence of MgAl2O4:Cr3+ powder is systematically examined and presented. The material was prepared by the self-propagating high-temperature synthesis method and its structure was confirmed by X-ray diffraction analysis. In this host, Cr3+ ions are in a strong crystal field, so the overlapping emissions from 2E and 4T2 energy levels are observed. Emission and excitation spectra were recorded in the 300 - 540 K temperature range. The broad photoluminescence attributed to 4T2→4A2 transition increases in intensity with an increase in temperature on account of 2E→4A2 emission intensity until 460 K when both emissions start quenching. The emissions were separated by deconvolution at each temperature and used for the luminescence intensity ratio temperature readout method. The obtained relative sensitivity displayed high values in the physiological range, from 3.5 %K-1 at 300 K to 2.9 %K-1 at 330 K, above 2 %K-1 below 400 K, and above 1 %K-1 between 400 K and 540 K.",
publisher = "Belgrade : Society for science development of Serbia",
journal = "ICOM&IWPPP 2022 : The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors : Book of abstracts",
title = "MgAl2O4:Cr3+ probe for luminescence thermometry in the physiological temperatures range",
pages = "P-31",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13233"
}
Periša, J., Ćirić, A., Ristić, Z., Antić, Ž.,& Dramićanin, M.. (2022). MgAl2O4:Cr3+ probe for luminescence thermometry in the physiological temperatures range. in ICOM&IWPPP 2022 : The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors : Book of abstracts
Belgrade : Society for science development of Serbia., P-31.
https://hdl.handle.net/21.15107/rcub_vinar_13233
Periša J, Ćirić A, Ristić Z, Antić Ž, Dramićanin M. MgAl2O4:Cr3+ probe for luminescence thermometry in the physiological temperatures range. in ICOM&IWPPP 2022 : The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors : Book of abstracts. 2022;:P-31.
https://hdl.handle.net/21.15107/rcub_vinar_13233 .
Periša, Jovana, Ćirić, Aleksandar, Ristić, Zoran, Antić, Željka, Dramićanin, Miroslav, "MgAl2O4:Cr3+ probe for luminescence thermometry in the physiological temperatures range" in ICOM&IWPPP 2022 : The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors : Book of abstracts (2022):P-31,
https://hdl.handle.net/21.15107/rcub_vinar_13233 .