TY  - JOUR
AU  - Kuzmanović, Bojana
AU  - Vujković, Milica
AU  - Tomić, Nataša M.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Lazović, Vladimir M.
AU  - Šljukić, Biljana
AU  - Ivanović, Nenad
AU  - Mentus, Slavko V.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0013468619305584
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8135
AB  - Cerium oxide (CeO 2-δ ) ultrafine nanoparticles, with the lower (CeO 2-δ -HT) and higher (CeO 2-δ -SS) fraction of oxygen vacancies, were used as anchoring sites for the polymerization of aniline in acidic medium. As a result, polyaniline-emeraldine salt (PANI-ES)-based composites (PANI-ES@CeO 2-δ -HT and PANI-ES@CeO 2-δ -SS) were obtained. The interaction between CeO 2-δ and PANI was examined by FTIR and Raman spectroscopy. The PANI polymerization is initiated via electrostatic interaction of anilinium cation and Cl − ions (adsorbed at the protonated hydroxyl groups of CeO 2-δ ), and proceeds with hydrogen and nitrogen interaction with oxide nanoparticles. Tailoring the oxygen vacancy population of oxide offers the possibility to control the type of PANI-cerium oxide interaction, and consequently structural, electrical, thermal, electronic and charge storage properties of composite. A high capacitance of synthesized materials, reaching ∼294 F g −1 (PANI-ES), ∼299 F g −1 (PANI-ES@CeO 2-δ -HT) and ∼314 F g −1 (PANI-ES@CeO 2-δ -SS), was measured in 1 M HCl, at a common scan rate of 20 mV s −1 . The high adhesion of PANI with cerium oxide prevents the oxide from its slow dissolution in 1MHCl thus providing the stability of this composite in an acidic solution. The rate of electrochemical oxidation of emeraldine salt into pernigraniline was also found to depend on CeO 2-δ characteristics. © 2019 Elsevier Ltd
T2  - Electrochimica Acta
T1  - The influence of oxygen vacancy concentration in nanodispersed non-stoichiometric CeO2-δ oxides on the physico-chemical properties of conducting polyaniline/CeO2 composites
VL  - 306
SP  - 506
EP  - 515
DO  - 10.1016/j.electacta.2019.03.135
ER  - 

@article{
author = "Kuzmanović, Bojana and Vujković, Milica and Tomić, Nataša M. and Bajuk-Bogdanović, Danica V. and Lazović, Vladimir M. and Šljukić, Biljana and Ivanović, Nenad and Mentus, Slavko V.",
year = "2019",
abstract = "Cerium oxide (CeO 2-δ ) ultrafine nanoparticles, with the lower (CeO 2-δ -HT) and higher (CeO 2-δ -SS) fraction of oxygen vacancies, were used as anchoring sites for the polymerization of aniline in acidic medium. As a result, polyaniline-emeraldine salt (PANI-ES)-based composites (PANI-ES@CeO 2-δ -HT and PANI-ES@CeO 2-δ -SS) were obtained. The interaction between CeO 2-δ and PANI was examined by FTIR and Raman spectroscopy. The PANI polymerization is initiated via electrostatic interaction of anilinium cation and Cl − ions (adsorbed at the protonated hydroxyl groups of CeO 2-δ ), and proceeds with hydrogen and nitrogen interaction with oxide nanoparticles. Tailoring the oxygen vacancy population of oxide offers the possibility to control the type of PANI-cerium oxide interaction, and consequently structural, electrical, thermal, electronic and charge storage properties of composite. A high capacitance of synthesized materials, reaching ∼294 F g −1 (PANI-ES), ∼299 F g −1 (PANI-ES@CeO 2-δ -HT) and ∼314 F g −1 (PANI-ES@CeO 2-δ -SS), was measured in 1 M HCl, at a common scan rate of 20 mV s −1 . The high adhesion of PANI with cerium oxide prevents the oxide from its slow dissolution in 1MHCl thus providing the stability of this composite in an acidic solution. The rate of electrochemical oxidation of emeraldine salt into pernigraniline was also found to depend on CeO 2-δ characteristics. © 2019 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "The influence of oxygen vacancy concentration in nanodispersed non-stoichiometric CeO2-δ oxides on the physico-chemical properties of conducting polyaniline/CeO2 composites",
volume = "306",
pages = "506-515",
doi = "10.1016/j.electacta.2019.03.135"
}

Kuzmanović, B., Vujković, M., Tomić, N. M., Bajuk-Bogdanović, D. V., Lazović, V. M., Šljukić, B., Ivanović, N.,& Mentus, S. V.. (2019). The influence of oxygen vacancy concentration in nanodispersed non-stoichiometric CeO2-δ oxides on the physico-chemical properties of conducting polyaniline/CeO2 composites. in Electrochimica Acta, 306, 506-515.
https://doi.org/10.1016/j.electacta.2019.03.135

Kuzmanović B, Vujković M, Tomić NM, Bajuk-Bogdanović DV, Lazović VM, Šljukić B, Ivanović N, Mentus SV. The influence of oxygen vacancy concentration in nanodispersed non-stoichiometric CeO2-δ oxides on the physico-chemical properties of conducting polyaniline/CeO2 composites. in Electrochimica Acta. 2019;306:506-515.
doi:10.1016/j.electacta.2019.03.135 .

Kuzmanović, Bojana, Vujković, Milica, Tomić, Nataša M., Bajuk-Bogdanović, Danica V., Lazović, Vladimir M., Šljukić, Biljana, Ivanović, Nenad, Mentus, Slavko V., "The influence of oxygen vacancy concentration in nanodispersed non-stoichiometric CeO2-δ oxides on the physico-chemical properties of conducting polyaniline/CeO2 composites" in Electrochimica Acta, 306 (2019):506-515,
https://doi.org/10.1016/j.electacta.2019.03.135 . .