Maletić, Slavica

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  • Maletić, Slavica (1)
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Dielectric properties of epoxy/graphite flakes composites: Influence of loading and surface treatment

Maletić, Slavica; Jović Orsini, Nataša; Milić, Mirjana; Dojčilović, Jablan; Montone, Amelia

(2023)

TY  - JOUR
AU  - Maletić, Slavica
AU  - Jović Orsini, Nataša
AU  - Milić, Mirjana
AU  - Dojčilović, Jablan
AU  - Montone, Amelia
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11994
AB  - Epoxy-rich carbon-based composites are well recognized materials in industries owing to their good mechanical properties and thermal stability. Here, dielectric properties of composites based on bisphenol-A-epoxy resin loaded with 5, 6, 10, and 15 wt% of graphite flakes (GF) have been studied. The frequency and temperature dependence of the dielectric permittivity, dielectric loss, and ac conductivity have been examined in temperature (−103 to 97°C) and frequency (20 Hz–200 kHz) range. Influence of the filler surface chemistry have been studied for composites loaded with 5 wt% GF obtained: (i) under wet milling, without or with adding Triton-100x as a surfactant, or (ii) under dry milling in the presence of KOH. The composite made of epoxy loaded with 5 wt% exfoliated expanded graphite flakes (EEG), was also prepared. The surface treatment with KOH notably increased dielectric constant of the composite, keeping low dielectric loss, while treatment with Triton-100x significantly increased tanδ. The composite loaded with exfoliated expanded graphite shows higher ac conductivity than those obtained with flaky graphite, GF. Possibility to change dielectric properties of the composites without changing the loading content can be used as an approach in tailoring one with desired dielectric properties.
T2  - Journal of Applied Polymer Science
T1  - Dielectric properties of epoxy/graphite flakes composites: Influence of loading and surface treatment
VL  - 141
IS  - 5
SP  - e54881
DO  - 10.1002/app.54881
ER  - 
@article{
author = "Maletić, Slavica and Jović Orsini, Nataša and Milić, Mirjana and Dojčilović, Jablan and Montone, Amelia",
year = "2023",
abstract = "Epoxy-rich carbon-based composites are well recognized materials in industries owing to their good mechanical properties and thermal stability. Here, dielectric properties of composites based on bisphenol-A-epoxy resin loaded with 5, 6, 10, and 15 wt% of graphite flakes (GF) have been studied. The frequency and temperature dependence of the dielectric permittivity, dielectric loss, and ac conductivity have been examined in temperature (−103 to 97°C) and frequency (20 Hz–200 kHz) range. Influence of the filler surface chemistry have been studied for composites loaded with 5 wt% GF obtained: (i) under wet milling, without or with adding Triton-100x as a surfactant, or (ii) under dry milling in the presence of KOH. The composite made of epoxy loaded with 5 wt% exfoliated expanded graphite flakes (EEG), was also prepared. The surface treatment with KOH notably increased dielectric constant of the composite, keeping low dielectric loss, while treatment with Triton-100x significantly increased tanδ. The composite loaded with exfoliated expanded graphite shows higher ac conductivity than those obtained with flaky graphite, GF. Possibility to change dielectric properties of the composites without changing the loading content can be used as an approach in tailoring one with desired dielectric properties.",
journal = "Journal of Applied Polymer Science",
title = "Dielectric properties of epoxy/graphite flakes composites: Influence of loading and surface treatment",
volume = "141",
number = "5",
pages = "e54881",
doi = "10.1002/app.54881"
}
Maletić, S., Jović Orsini, N., Milić, M., Dojčilović, J.,& Montone, A.. (2023). Dielectric properties of epoxy/graphite flakes composites: Influence of loading and surface treatment. in Journal of Applied Polymer Science, 141(5), e54881.
https://doi.org/10.1002/app.54881
Maletić S, Jović Orsini N, Milić M, Dojčilović J, Montone A. Dielectric properties of epoxy/graphite flakes composites: Influence of loading and surface treatment. in Journal of Applied Polymer Science. 2023;141(5):e54881.
doi:10.1002/app.54881 .
Maletić, Slavica, Jović Orsini, Nataša, Milić, Mirjana, Dojčilović, Jablan, Montone, Amelia, "Dielectric properties of epoxy/graphite flakes composites: Influence of loading and surface treatment" in Journal of Applied Polymer Science, 141, no. 5 (2023):e54881,
https://doi.org/10.1002/app.54881 . .
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