Schumann, Dorothea

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  • Schumann, Dorothea (1)
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Optimizing a radiochemical separation of 26Al from an acidic V-rich matrix

Cvjetinović, Đorđe; Pan, Xiaohan; Petrović, Jelena; Schumann, Dorothea

(2024)

TY  - JOUR
AU  - Cvjetinović, Đorđe
AU  - Pan, Xiaohan
AU  - Petrović, Jelena
AU  - Schumann, Dorothea
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13179
AB  - Sorption and desorption of Al(III) on a series of different extraction resins (LN, LN2, LN3, TK100, TK101, TK201) in acidic HNO3 media containing high concentrations of V(IV,V) was investigated. Static batch studies were conducted as a way of obtaining preliminary distribution coefficient (Kd) values that were further used to develop dynamic tests on real samples. It was shown that a complete separation and recovery of Al(III) from V(V) under acidic conditions (pH = 2) is possible by utilizing LN resin. Active “hot” dynamic studies with 26Al (≈10 Bq) as a radiotracer and real waste samples were conducted to further investigate and confirm the results of the inactive “cold” experiments. Utilizing this separation procedure, we have successfully removed all traces of 26Al (∼10−9 g) radiotracer from the bulk vanadium matrix.
T2  - Microchemical Journal
T1  - Optimizing a radiochemical separation of 26Al from an acidic V-rich matrix
VL  - 200
SP  - 110477
DO  - 10.1016/j.microc.2024.110477
ER  - 
@article{
author = "Cvjetinović, Đorđe and Pan, Xiaohan and Petrović, Jelena and Schumann, Dorothea",
year = "2024",
abstract = "Sorption and desorption of Al(III) on a series of different extraction resins (LN, LN2, LN3, TK100, TK101, TK201) in acidic HNO3 media containing high concentrations of V(IV,V) was investigated. Static batch studies were conducted as a way of obtaining preliminary distribution coefficient (Kd) values that were further used to develop dynamic tests on real samples. It was shown that a complete separation and recovery of Al(III) from V(V) under acidic conditions (pH = 2) is possible by utilizing LN resin. Active “hot” dynamic studies with 26Al (≈10 Bq) as a radiotracer and real waste samples were conducted to further investigate and confirm the results of the inactive “cold” experiments. Utilizing this separation procedure, we have successfully removed all traces of 26Al (∼10−9 g) radiotracer from the bulk vanadium matrix.",
journal = "Microchemical Journal",
title = "Optimizing a radiochemical separation of 26Al from an acidic V-rich matrix",
volume = "200",
pages = "110477",
doi = "10.1016/j.microc.2024.110477"
}
Cvjetinović, Đ., Pan, X., Petrović, J.,& Schumann, D.. (2024). Optimizing a radiochemical separation of 26Al from an acidic V-rich matrix. in Microchemical Journal, 200, 110477.
https://doi.org/10.1016/j.microc.2024.110477
Cvjetinović Đ, Pan X, Petrović J, Schumann D. Optimizing a radiochemical separation of 26Al from an acidic V-rich matrix. in Microchemical Journal. 2024;200:110477.
doi:10.1016/j.microc.2024.110477 .
Cvjetinović, Đorđe, Pan, Xiaohan, Petrović, Jelena, Schumann, Dorothea, "Optimizing a radiochemical separation of 26Al from an acidic V-rich matrix" in Microchemical Journal, 200 (2024):110477,
https://doi.org/10.1016/j.microc.2024.110477 . .