TY  - JOUR
AU  - Košević, Milica G.
AU  - Krstić, Sanja S.
AU  - Panić, Vladimir V.
AU  - Nikolić, Branislav Ž.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10466
AB  - The influence of different hydroxides, applied to activate carbon black, on the electrochemical properties of activated carbon was investigated. The carbon material was prepared by hydrothermal treatment of sucrose and afterwards thermally activated using KOH, NaOH and LiOH. The electrochemical properties of the obtained samples were examined by cyclic voltammetry and electrochemical impedance spectroscopy and correlated to their physicochemical properties. All samples showed characteristic capacitor-like behaviour. The highest specific capacitance was obtained for the KOH-treated sample, while the increase in capacitance follows the sequence of the growth of ionic radius of a metal from an alkali which is used for activation. It was found that the dependence on the type of hydroxide is due to differences in the radii of a metal. The alkalies of larger radii of metal generated make pores wider and consequently the structure of a porous layer become more accessible to the charge transfer of capacitive response.
T2  - Journal of the Serbian Chemical Society
T1  - Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose
VL  - 87
IS  - 7-8
SP  - 867
EP  - 877
DO  - 10.2298/JSC220730059K
ER  - 

@article{
author = "Košević, Milica G. and Krstić, Sanja S. and Panić, Vladimir V. and Nikolić, Branislav Ž.",
year = "2022",
abstract = "The influence of different hydroxides, applied to activate carbon black, on the electrochemical properties of activated carbon was investigated. The carbon material was prepared by hydrothermal treatment of sucrose and afterwards thermally activated using KOH, NaOH and LiOH. The electrochemical properties of the obtained samples were examined by cyclic voltammetry and electrochemical impedance spectroscopy and correlated to their physicochemical properties. All samples showed characteristic capacitor-like behaviour. The highest specific capacitance was obtained for the KOH-treated sample, while the increase in capacitance follows the sequence of the growth of ionic radius of a metal from an alkali which is used for activation. It was found that the dependence on the type of hydroxide is due to differences in the radii of a metal. The alkalies of larger radii of metal generated make pores wider and consequently the structure of a porous layer become more accessible to the charge transfer of capacitive response.",
journal = "Journal of the Serbian Chemical Society",
title = "Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose",
volume = "87",
number = "7-8",
pages = "867-877",
doi = "10.2298/JSC220730059K"
}

Košević, M. G., Krstić, S. S., Panić, V. V.,& Nikolić, B. Ž.. (2022). Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose. in Journal of the Serbian Chemical Society, 87(7-8), 867-877.
https://doi.org/10.2298/JSC220730059K

Košević MG, Krstić SS, Panić VV, Nikolić BŽ. Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose. in Journal of the Serbian Chemical Society. 2022;87(7-8):867-877.
doi:10.2298/JSC220730059K .

Košević, Milica G., Krstić, Sanja S., Panić, Vladimir V., Nikolić, Branislav Ž., "Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose" in Journal of the Serbian Chemical Society, 87, no. 7-8 (2022):867-877,
https://doi.org/10.2298/JSC220730059K . .

TY  - JOUR
AU  - Pantović Pavlović, Marijana R.
AU  - Pavlović, Miroslav M.
AU  - Eraković, Sanja
AU  - Barudžija, Tanja
AU  - Stevanović, Jasmina S.
AU  - Ignjatović, Nenad L.
AU  - Panić, Vladimir V.
PY  - 2019
UR  - https://www.shd-pub.org.rs/index.php/JSCS/article/view/8524
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8671
AB  - The optimization of the anodization process of Ti substrate for in situ synthesis of hydroxyapatite/titanium oxide composite coatings on titanium substrate was accomplished. The anodization was performed under 30, 60 and 90 V cell voltage, and the morphology of treated surface, as well as linear and surface roughness, were analysed by field emission-scanning electron micro­scopy, atomic force microscopy and roughness tester. It was shown by linear and surface roughness analyses that titanium anodized under 60 V has the high­est roughness, whereas at 90 V the flattening of the surface occurs. As the highest surface roughness results emerged at 60 V, the novel process of com­po­site anHAp/TiO2 coating synthesis, which comprises simultaneous processes of TiO2 formation and HAp deposition, as well as HAp impregnation within TiO2 surface layer, was performed at this voltage. Ti substrate surface was completely covered by composite coating, with no visible cracks. The adhesion quantified according to ASTM D3359-02 standard is considerably improved with respect to the coatings obtained by cathaphoretic processes, with no need of subsequent sintering.
T2  - Journal of the Serbian Chemical Society
T1  - Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite
VL  - 84
IS  - 11
SP  - 1305
EP  - 1318
DO  - 10.2298/JSC190730105P
ER  - 

@article{
author = "Pantović Pavlović, Marijana R. and Pavlović, Miroslav M. and Eraković, Sanja and Barudžija, Tanja and Stevanović, Jasmina S. and Ignjatović, Nenad L. and Panić, Vladimir V.",
year = "2019",
abstract = "The optimization of the anodization process of Ti substrate for in situ synthesis of hydroxyapatite/titanium oxide composite coatings on titanium substrate was accomplished. The anodization was performed under 30, 60 and 90 V cell voltage, and the morphology of treated surface, as well as linear and surface roughness, were analysed by field emission-scanning electron micro­scopy, atomic force microscopy and roughness tester. It was shown by linear and surface roughness analyses that titanium anodized under 60 V has the high­est roughness, whereas at 90 V the flattening of the surface occurs. As the highest surface roughness results emerged at 60 V, the novel process of com­po­site anHAp/TiO2 coating synthesis, which comprises simultaneous processes of TiO2 formation and HAp deposition, as well as HAp impregnation within TiO2 surface layer, was performed at this voltage. Ti substrate surface was completely covered by composite coating, with no visible cracks. The adhesion quantified according to ASTM D3359-02 standard is considerably improved with respect to the coatings obtained by cathaphoretic processes, with no need of subsequent sintering.",
journal = "Journal of the Serbian Chemical Society",
title = "Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite",
volume = "84",
number = "11",
pages = "1305-1318",
doi = "10.2298/JSC190730105P"
}

Pantović Pavlović, M. R., Pavlović, M. M., Eraković, S., Barudžija, T., Stevanović, J. S., Ignjatović, N. L.,& Panić, V. V.. (2019). Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite. in Journal of the Serbian Chemical Society, 84(11), 1305-1318.
https://doi.org/10.2298/JSC190730105P

Pantović Pavlović MR, Pavlović MM, Eraković S, Barudžija T, Stevanović JS, Ignjatović NL, Panić VV. Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite. in Journal of the Serbian Chemical Society. 2019;84(11):1305-1318.
doi:10.2298/JSC190730105P .

Pantović Pavlović, Marijana R., Pavlović, Miroslav M., Eraković, Sanja, Barudžija, Tanja, Stevanović, Jasmina S., Ignjatović, Nenad L., Panić, Vladimir V., "Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite" in Journal of the Serbian Chemical Society, 84, no. 11 (2019):1305-1318,
https://doi.org/10.2298/JSC190730105P . .

TY  - JOUR
AU  - Eraković, Sanja
AU  - Pavlović, Miroslav M.
AU  - Stopić, Srećko
AU  - Stevanović, Jasmina
AU  - Mitrić, Miodrag
AU  - Friedrich, Bernd
AU  - Panić, Vladimir
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8470
AB  - Considerable promotion of RuO2 hosted by perovskite-like structure of rare earth–CoO3 composite and vice versa supercapacitive performances is reported. Spherical, sub-μm-sized, regular spheres of La0.6Sr0.4CoO3 (LSCO), were synthesized by ultrasonic spray pyrolysis. The sphere surface was subsequently hydrothermally doped by RuO2. LSCO and LSCO/RuO2 composites were investigated for their supercapacitive performances in alkaline solution. Microstructure and surface morphology were studied by SEM and XRD. It was found that amorphous Ru species decorate LSCO surface, and possibly incorporate partially into B-site of the LSCO lattice. Electrochemical characterization by cyclic voltammetry (CV), galvanostatic charge-discharge (G-C/DC) and electrochemical impedance spectroscopy (EIS) clearly revealed that capacitive performances of LSCO are considerably improved by addition of 20 mass. % of RuO2. The registered capacitance for LSCO/RuO2 reaches the values of pure RuO2, which reveals the promoting influence of LSCO on RuO2 pseudocapacitance. The EIS analysis showed that RuO2 catalyzes the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive RuO2 abilities while being hosted by LSCO. This intrinsic interactive promotion introduces LSCO/RuO2 composite as unique supercapacitive material. G-C/DC curves showed that LSCO/RuO2 is of modest cyclability with respect to pure LSCO and RuO2, although the capacitance losses with cycling are acceptably low. © 2019 Elsevier Ltd
T2  - Electrochimica Acta
T1  - Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide
VL  - 321
SP  - 134721
DO  - 10.1016/j.electacta.2019.134721
ER  - 

@article{
author = "Eraković, Sanja and Pavlović, Miroslav M. and Stopić, Srećko and Stevanović, Jasmina and Mitrić, Miodrag and Friedrich, Bernd and Panić, Vladimir",
year = "2019",
abstract = "Considerable promotion of RuO2 hosted by perovskite-like structure of rare earth–CoO3 composite and vice versa supercapacitive performances is reported. Spherical, sub-μm-sized, regular spheres of La0.6Sr0.4CoO3 (LSCO), were synthesized by ultrasonic spray pyrolysis. The sphere surface was subsequently hydrothermally doped by RuO2. LSCO and LSCO/RuO2 composites were investigated for their supercapacitive performances in alkaline solution. Microstructure and surface morphology were studied by SEM and XRD. It was found that amorphous Ru species decorate LSCO surface, and possibly incorporate partially into B-site of the LSCO lattice. Electrochemical characterization by cyclic voltammetry (CV), galvanostatic charge-discharge (G-C/DC) and electrochemical impedance spectroscopy (EIS) clearly revealed that capacitive performances of LSCO are considerably improved by addition of 20 mass. % of RuO2. The registered capacitance for LSCO/RuO2 reaches the values of pure RuO2, which reveals the promoting influence of LSCO on RuO2 pseudocapacitance. The EIS analysis showed that RuO2 catalyzes the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive RuO2 abilities while being hosted by LSCO. This intrinsic interactive promotion introduces LSCO/RuO2 composite as unique supercapacitive material. G-C/DC curves showed that LSCO/RuO2 is of modest cyclability with respect to pure LSCO and RuO2, although the capacitance losses with cycling are acceptably low. © 2019 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide",
volume = "321",
pages = "134721",
doi = "10.1016/j.electacta.2019.134721"
}

Eraković, S., Pavlović, M. M., Stopić, S., Stevanović, J., Mitrić, M., Friedrich, B.,& Panić, V.. (2019). Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide. in Electrochimica Acta, 321, 134721.
https://doi.org/10.1016/j.electacta.2019.134721

Eraković S, Pavlović MM, Stopić S, Stevanović J, Mitrić M, Friedrich B, Panić V. Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide. in Electrochimica Acta. 2019;321:134721.
doi:10.1016/j.electacta.2019.134721 .

Eraković, Sanja, Pavlović, Miroslav M., Stopić, Srećko, Stevanović, Jasmina, Mitrić, Miodrag, Friedrich, Bernd, Panić, Vladimir, "Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide" in Electrochimica Acta, 321 (2019):134721,
https://doi.org/10.1016/j.electacta.2019.134721 . .

TY  - JOUR
AU  - Mijailović, Daniel M.
AU  - Vukčević, Marija M.
AU  - Stević, Zoran M.
AU  - Kalijadis, Ana
AU  - Stojanović, Dušica B.
AU  - Panić, Vladimir V.
AU  - Uskoković, Petar S.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1583
AB  - Activated carbons with high specific surface area (even above 2000 m(2) g(-1)) and pronounced microporosity are prepared in two-stage process involving conventional carbonization of waste hemp fibers and subsequent activation by potassium hydroxide. Samples with considerably different surface and intrinsic micro-and mesoporous properties are obtained at different carbonization and activation conditions. The improvements of the capacitive properties are found upon increase in carbonization temperature, since it considerably influenced the specific surface area and the content of surface oxygen groups. Cyclic voltammetry experiments reveal the dependence of specific capacitance on the sweep rate due to the characteristic porous structure of the samples. The highest measured value in 1 M H2SO4 solution is 122 F g(-1). The electrochemical impedance data indicates eight-branch transmission line equivalent electric behavior of activated carbons. (C) 2017 The Electrochemical Society. All rights reserved.
T2  - Journal of the Electrochemical Society
T1  - Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers
VL  - 164
IS  - 6
SP  - A1061
EP  - A1068
DO  - 10.1149/2.0581706jes
ER  - 

@article{
author = "Mijailović, Daniel M. and Vukčević, Marija M. and Stević, Zoran M. and Kalijadis, Ana and Stojanović, Dušica B. and Panić, Vladimir V. and Uskoković, Petar S.",
year = "2017",
abstract = "Activated carbons with high specific surface area (even above 2000 m(2) g(-1)) and pronounced microporosity are prepared in two-stage process involving conventional carbonization of waste hemp fibers and subsequent activation by potassium hydroxide. Samples with considerably different surface and intrinsic micro-and mesoporous properties are obtained at different carbonization and activation conditions. The improvements of the capacitive properties are found upon increase in carbonization temperature, since it considerably influenced the specific surface area and the content of surface oxygen groups. Cyclic voltammetry experiments reveal the dependence of specific capacitance on the sweep rate due to the characteristic porous structure of the samples. The highest measured value in 1 M H2SO4 solution is 122 F g(-1). The electrochemical impedance data indicates eight-branch transmission line equivalent electric behavior of activated carbons. (C) 2017 The Electrochemical Society. All rights reserved.",
journal = "Journal of the Electrochemical Society",
title = "Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers",
volume = "164",
number = "6",
pages = "A1061-A1068",
doi = "10.1149/2.0581706jes"
}

Mijailović, D. M., Vukčević, M. M., Stević, Z. M., Kalijadis, A., Stojanović, D. B., Panić, V. V.,& Uskoković, P. S.. (2017). Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers. in Journal of the Electrochemical Society, 164(6), A1061-A1068.
https://doi.org/10.1149/2.0581706jes

Mijailović DM, Vukčević MM, Stević ZM, Kalijadis A, Stojanović DB, Panić VV, Uskoković PS. Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers. in Journal of the Electrochemical Society. 2017;164(6):A1061-A1068.
doi:10.1149/2.0581706jes .

Mijailović, Daniel M., Vukčević, Marija M., Stević, Zoran M., Kalijadis, Ana, Stojanović, Dušica B., Panić, Vladimir V., Uskoković, Petar S., "Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers" in Journal of the Electrochemical Society, 164, no. 6 (2017):A1061-A1068,
https://doi.org/10.1149/2.0581706jes . .

TY  - JOUR
AU  - Košević, Milica
AU  - Šekularac, Gavrilo
AU  - Živković, Ljiljana
AU  - Panić, Vladimir
AU  - Nikolić, Branislav Ž.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1836
AB  - TiO2 powder was synthesized by a forced hydrolysis process and used for the synthesis of Pt/TiO2 composite that is to be foreseen as an advanced electrode material. Pt was incorporated into the synthesized TiO2 from a Pt colloidal dispersion as a precursor prepared by a microwave- assisted polyol process. Physicochemical properties of TiO2 and TiO2- supported Pt were investigated by scanning electron microscopy, dynamic light scattering and X- ray spectroscopy and diffraction techniques. The properties of Pt/TiO2 composite are correlated to the basic voltammetric response of its thin-layer form. It was found that subsequent thermal treatment of synthesized TiO2, which caused crystallization into mainly rutile phase, is required for appropriate Pt incorporation. Although being appropriately loaded by Pt, and the voltammetric response is typical for Pt-based material, the voltammetry of Pt/TiO2 corresponded to much lower loadings.The possibility for Pt particles to be trapped inside TiO2 agglomerates is indicated. The catalyst usage from the synthesized Pt/TiO2 was found quite moderate due to this trapping.
T2  - Croatica Chemica Acta
T1  - TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications
VL  - 90
IS  - 2
SP  - 251
EP  - 258
DO  - 10.5562/cca3175
ER  - 

@article{
author = "Košević, Milica and Šekularac, Gavrilo and Živković, Ljiljana and Panić, Vladimir and Nikolić, Branislav Ž.",
year = "2017",
abstract = "TiO2 powder was synthesized by a forced hydrolysis process and used for the synthesis of Pt/TiO2 composite that is to be foreseen as an advanced electrode material. Pt was incorporated into the synthesized TiO2 from a Pt colloidal dispersion as a precursor prepared by a microwave- assisted polyol process. Physicochemical properties of TiO2 and TiO2- supported Pt were investigated by scanning electron microscopy, dynamic light scattering and X- ray spectroscopy and diffraction techniques. The properties of Pt/TiO2 composite are correlated to the basic voltammetric response of its thin-layer form. It was found that subsequent thermal treatment of synthesized TiO2, which caused crystallization into mainly rutile phase, is required for appropriate Pt incorporation. Although being appropriately loaded by Pt, and the voltammetric response is typical for Pt-based material, the voltammetry of Pt/TiO2 corresponded to much lower loadings.The possibility for Pt particles to be trapped inside TiO2 agglomerates is indicated. The catalyst usage from the synthesized Pt/TiO2 was found quite moderate due to this trapping.",
journal = "Croatica Chemica Acta",
title = "TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications",
volume = "90",
number = "2",
pages = "251-258",
doi = "10.5562/cca3175"
}

Košević, M., Šekularac, G., Živković, L., Panić, V.,& Nikolić, B. Ž.. (2017). TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications. in Croatica Chemica Acta, 90(2), 251-258.
https://doi.org/10.5562/cca3175

Košević M, Šekularac G, Živković L, Panić V, Nikolić BŽ. TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications. in Croatica Chemica Acta. 2017;90(2):251-258.
doi:10.5562/cca3175 .

Košević, Milica, Šekularac, Gavrilo, Živković, Ljiljana, Panić, Vladimir, Nikolić, Branislav Ž., "TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications" in Croatica Chemica Acta, 90, no. 2 (2017):251-258,
https://doi.org/10.5562/cca3175 . .

TY  - JOUR
AU  - Gulicovski, Jelena J.
AU  - Bajat, Jelena B.
AU  - Jokić, Bojan M.
AU  - Panić, Vladimir
AU  - Mišković-Stanković, Vesna B.
AU  - Milonjić, Slobodan K.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/894
AB  - Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.
PB  - Springer
T2  - Journal of Solid State Electrochemistry
T1  - Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium
VL  - 20
IS  - 1
SP  - 293
EP  - 303
DO  - 10.1007/s10008-015-3040-3
ER  - 

@article{
author = "Gulicovski, Jelena J. and Bajat, Jelena B. and Jokić, Bojan M. and Panić, Vladimir and Mišković-Stanković, Vesna B. and Milonjić, Slobodan K.",
year = "2016",
abstract = "Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.",
publisher = "Springer",
journal = "Journal of Solid State Electrochemistry",
title = "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium",
volume = "20",
number = "1",
pages = "293-303",
doi = "10.1007/s10008-015-3040-3"
}

Gulicovski, J. J., Bajat, J. B., Jokić, B. M., Panić, V., Mišković-Stanković, V. B.,& Milonjić, S. K.. (2016). Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry
Springer., 20(1), 293-303.
https://doi.org/10.1007/s10008-015-3040-3

Gulicovski JJ, Bajat JB, Jokić BM, Panić V, Mišković-Stanković VB, Milonjić SK. Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry. 2016;20(1):293-303.
doi:10.1007/s10008-015-3040-3 .

Gulicovski, Jelena J., Bajat, Jelena B., Jokić, Bojan M., Panić, Vladimir, Mišković-Stanković, Vesna B., Milonjić, Slobodan K., "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium" in Journal of Solid State Electrochemistry, 20, no. 1 (2016):293-303,
https://doi.org/10.1007/s10008-015-3040-3 . .

TY  - CONF
AU  - Gulicovski, Jelena J.
AU  - Bajat, Jelena B.
AU  - Mišković-Stanković, Vesna B.
AU  - Jokić, Bojan M.
AU  - Panić, Vladimir
AU  - Milonjić, Slobodan K.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7011
AB  - CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, previously prepared by forced hydrolysis of Ce(NO3)(4). The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coatings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are subjected to more pronounced diffusion limitations in comparison to the processes below passive aluminum oxide film, as the consequence of the formation of highly compact protective coating. The results show that the deposition of ceria coatings is an effective way to improve corrosion resistance for aluminum.
T1  - Cerium Oxide as Conversion Coating for the Corrosion Protection of Aluminum
SP  - 429
EP  - 432
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7011
ER  - 

@conference{
author = "Gulicovski, Jelena J. and Bajat, Jelena B. and Mišković-Stanković, Vesna B. and Jokić, Bojan M. and Panić, Vladimir and Milonjić, Slobodan K.",
year = "2012",
abstract = "CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, previously prepared by forced hydrolysis of Ce(NO3)(4). The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coatings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are subjected to more pronounced diffusion limitations in comparison to the processes below passive aluminum oxide film, as the consequence of the formation of highly compact protective coating. The results show that the deposition of ceria coatings is an effective way to improve corrosion resistance for aluminum.",
title = "Cerium Oxide as Conversion Coating for the Corrosion Protection of Aluminum",
pages = "429-432",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7011"
}

Gulicovski, J. J., Bajat, J. B., Mišković-Stanković, V. B., Jokić, B. M., Panić, V.,& Milonjić, S. K.. (2012). Cerium Oxide as Conversion Coating for the Corrosion Protection of Aluminum. , 429-432.
https://hdl.handle.net/21.15107/rcub_vinar_7011

Gulicovski JJ, Bajat JB, Mišković-Stanković VB, Jokić BM, Panić V, Milonjić SK. Cerium Oxide as Conversion Coating for the Corrosion Protection of Aluminum. 2012;:429-432.
https://hdl.handle.net/21.15107/rcub_vinar_7011 .

Gulicovski, Jelena J., Bajat, Jelena B., Mišković-Stanković, Vesna B., Jokić, Bojan M., Panić, Vladimir, Milonjić, Slobodan K., "Cerium Oxide as Conversion Coating for the Corrosion Protection of Aluminum" (2012):429-432,
https://hdl.handle.net/21.15107/rcub_vinar_7011 .

TY  - JOUR
AU  - Djosic, M. S.
AU  - Panić, Vladimir
AU  - Stojanovic, J.
AU  - Mitrić, Miodrag
AU  - Mišković-Stanković, Vesna B.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4840
AB  - Electrochemical deposition of calcium phosphate coatings on titanium was performed galvanostatically from the aqueous solution of Ca(NO3)(2) and NH4H2PO4 with the current densities between 5.0 and 10 mA cm(-2), for different deposition times, at room temperature. The coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results showed that dicalcium phosphate dihydrate (DCPD), brushite (CaHPO4 center dot 2H(2)O) coatings were deposited. The influence of applied current density and the deposition time on the phase composition, crystallite domain size and the morphology of brushite coatings were investigated. It was shown that brushite coating of the greatest mass was obtained for the longest deposition time, while the increase in current density over 7 mA cm(-2) does not affect significantly the mass of brushite coatings. The finest crystallites, with the smallest crystallite domain size of 15.6nm, were deposited at the current density of 9.0 mA cm(-2). Brushite coatings were fully converted to hydroxyapatite in simulated body fluid (SBF) which was confirmed by XRD and SEM. The crystallite domain size of HA coatings is controlled by applied current density for brushite coatings deposition: crystallization of HA at more porous brushite coatings, deposited at higher current density, caused the formation of smaller crystallites of hydroxyapatite. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Colloids and Surfaces. A: Physicochemical and Engineering Aspects
T1  - The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium
VL  - 400
SP  - 36
EP  - 43
DO  - 10.1016/j.colsurfa.2012.02.040
ER  - 

@article{
author = "Djosic, M. S. and Panić, Vladimir and Stojanovic, J. and Mitrić, Miodrag and Mišković-Stanković, Vesna B.",
year = "2012",
abstract = "Electrochemical deposition of calcium phosphate coatings on titanium was performed galvanostatically from the aqueous solution of Ca(NO3)(2) and NH4H2PO4 with the current densities between 5.0 and 10 mA cm(-2), for different deposition times, at room temperature. The coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results showed that dicalcium phosphate dihydrate (DCPD), brushite (CaHPO4 center dot 2H(2)O) coatings were deposited. The influence of applied current density and the deposition time on the phase composition, crystallite domain size and the morphology of brushite coatings were investigated. It was shown that brushite coating of the greatest mass was obtained for the longest deposition time, while the increase in current density over 7 mA cm(-2) does not affect significantly the mass of brushite coatings. The finest crystallites, with the smallest crystallite domain size of 15.6nm, were deposited at the current density of 9.0 mA cm(-2). Brushite coatings were fully converted to hydroxyapatite in simulated body fluid (SBF) which was confirmed by XRD and SEM. The crystallite domain size of HA coatings is controlled by applied current density for brushite coatings deposition: crystallization of HA at more porous brushite coatings, deposited at higher current density, caused the formation of smaller crystallites of hydroxyapatite. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Colloids and Surfaces. A: Physicochemical and Engineering Aspects",
title = "The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium",
volume = "400",
pages = "36-43",
doi = "10.1016/j.colsurfa.2012.02.040"
}

Djosic, M. S., Panić, V., Stojanovic, J., Mitrić, M.,& Mišković-Stanković, V. B.. (2012). The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 400, 36-43.
https://doi.org/10.1016/j.colsurfa.2012.02.040

Djosic MS, Panić V, Stojanovic J, Mitrić M, Mišković-Stanković VB. The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects. 2012;400:36-43.
doi:10.1016/j.colsurfa.2012.02.040 .

Djosic, M. S., Panić, Vladimir, Stojanovic, J., Mitrić, Miodrag, Mišković-Stanković, Vesna B., "The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium" in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 400 (2012):36-43,
https://doi.org/10.1016/j.colsurfa.2012.02.040 . .

TY  - JOUR
AU  - Cvijović-Alagić, Ivana
AU  - Cvijović, Zorica M.
AU  - Mitrovic, S.
AU  - Panić, Vladimir
AU  - Rakin, Marko P.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4216
AB  - Wear and corrosion behaviour of cold-rolled Ti-13Nb-13Zr alloy, with martensitic microstructure, and Ti-6Al-4V ELI alloy, in martensitic and two-phase (alpha + beta) microstructural conditions, was studied in a Ringers solution. The wear experiments were performed at room temperature with a normal load of 40 N and sliding speeds 0.26. 0.5 and 1.0 m/s. The corrosion behaviour was studied at 37 degrees C using open circuit potential-time measurements and potentiodynamic polarization. It was found that Ti-13Nb-13Zr alloy has a substantially lower wear resistance than Ti-6Al-4V ELI alloy in both microstructural conditions. Surface damage extent increases with sliding speed increase and is always smallest for martensitic Ti-6Al-4V ELI alloy with highest hardness. Both alloys exhibit spontaneous passivity in Ringers solution. Corrosion potential values are similar for all three materials. However, Ti-13Nb-13Zr and martensitic Ti-6Al-4V ELI alloys show improved corrosion resistance comparatively to Ti-6Al-4V ELI alloy with (alpha + beta) microstructure. Martensitic Ti-6Al-4V ELI alloy possesses the best combination of both corrosion and wear resistance, although its corrosion resistance is found to be slightly higher than that of the Ti-13Nb-13Zr alloy. (C) 2010 Elsevier Ltd. All rights reserved.
T2  - Corrosion Science
T1  - Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution
VL  - 53
IS  - 2
SP  - 796
EP  - 808
DO  - 10.1016/j.corsci.2010.11.014
ER  - 

@article{
author = "Cvijović-Alagić, Ivana and Cvijović, Zorica M. and Mitrovic, S. and Panić, Vladimir and Rakin, Marko P.",
year = "2011",
abstract = "Wear and corrosion behaviour of cold-rolled Ti-13Nb-13Zr alloy, with martensitic microstructure, and Ti-6Al-4V ELI alloy, in martensitic and two-phase (alpha + beta) microstructural conditions, was studied in a Ringers solution. The wear experiments were performed at room temperature with a normal load of 40 N and sliding speeds 0.26. 0.5 and 1.0 m/s. The corrosion behaviour was studied at 37 degrees C using open circuit potential-time measurements and potentiodynamic polarization. It was found that Ti-13Nb-13Zr alloy has a substantially lower wear resistance than Ti-6Al-4V ELI alloy in both microstructural conditions. Surface damage extent increases with sliding speed increase and is always smallest for martensitic Ti-6Al-4V ELI alloy with highest hardness. Both alloys exhibit spontaneous passivity in Ringers solution. Corrosion potential values are similar for all three materials. However, Ti-13Nb-13Zr and martensitic Ti-6Al-4V ELI alloys show improved corrosion resistance comparatively to Ti-6Al-4V ELI alloy with (alpha + beta) microstructure. Martensitic Ti-6Al-4V ELI alloy possesses the best combination of both corrosion and wear resistance, although its corrosion resistance is found to be slightly higher than that of the Ti-13Nb-13Zr alloy. (C) 2010 Elsevier Ltd. All rights reserved.",
journal = "Corrosion Science",
title = "Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution",
volume = "53",
number = "2",
pages = "796-808",
doi = "10.1016/j.corsci.2010.11.014"
}

Cvijović-Alagić, I., Cvijović, Z. M., Mitrovic, S., Panić, V.,& Rakin, M. P.. (2011). Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution. in Corrosion Science, 53(2), 796-808.
https://doi.org/10.1016/j.corsci.2010.11.014

Cvijović-Alagić I, Cvijović ZM, Mitrovic S, Panić V, Rakin MP. Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution. in Corrosion Science. 2011;53(2):796-808.
doi:10.1016/j.corsci.2010.11.014 .

Cvijović-Alagić, Ivana, Cvijović, Zorica M., Mitrovic, S., Panić, Vladimir, Rakin, Marko P., "Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution" in Corrosion Science, 53, no. 2 (2011):796-808,
https://doi.org/10.1016/j.corsci.2010.11.014 . .

TY  - JOUR
AU  - Panić, Vladimir V.
AU  - Dekanski, Aleksandar B.
AU  - Mitrić, Miodrag
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna B.
AU  - Nikolić, Branislav Ž.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4030
AB  - Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.
T2  - Physical Chemistry Chemical Physics
T1  - The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties
VL  - 12
IS  - 27
SP  - 7521
EP  - 7528
DO  - 10.1039/b921582d
ER  - 

@article{
author = "Panić, Vladimir V. and Dekanski, Aleksandar B. and Mitrić, Miodrag and Milonjić, Slobodan K. and Mišković-Stanković, Vesna B. and Nikolić, Branislav Ž.",
year = "2010",
abstract = "Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.",
journal = "Physical Chemistry Chemical Physics",
title = "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties",
volume = "12",
number = "27",
pages = "7521-7528",
doi = "10.1039/b921582d"
}

Panić, V. V., Dekanski, A. B., Mitrić, M., Milonjić, S. K., Mišković-Stanković, V. B.,& Nikolić, B. Ž.. (2010). The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics, 12(27), 7521-7528.
https://doi.org/10.1039/b921582d

Panić VV, Dekanski AB, Mitrić M, Milonjić SK, Mišković-Stanković VB, Nikolić BŽ. The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics. 2010;12(27):7521-7528.
doi:10.1039/b921582d .

Panić, Vladimir V., Dekanski, Aleksandar B., Mitrić, Miodrag, Milonjić, Slobodan K., Mišković-Stanković, Vesna B., Nikolić, Branislav Ž., "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties" in Physical Chemistry Chemical Physics, 12, no. 27 (2010):7521-7528,
https://doi.org/10.1039/b921582d . .

TY  - JOUR
AU  - Panić, Vladimir V.
AU  - Dekanski, Aleksandar B.
AU  - Mišković-Stanković, Vesna B.
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4138
AB  - The electrochemical characteristics of Ti(0.6)Ir(0.4)O(2)/Ti and Ti(0.6)Ru(0.4)O(2)/Ti anodes prepared by the sol gel procedure from the corresponding oxide sols, obtained by force hydrolysis of the corresponding metal chlorides, were compared. The voltammetric properties in H(2)SO(4) solution indicate that Ti(0.6)Ir(0.4)O(2)/Ti has more pronounced pseudocapacitive characteristics, caused by proton-assisted, solid state surface redox transitions of the oxide. At potentials negative to 0.0 V(SCE), this electrode is of poor conductivity and activity, while the voltammetric behavior of the Ti(0.6)Ru(0.4)O(2)/Ti electrode is governed by proton injection/ejection into the oxide structure. The Ti(0.6)Ir(0.4)O(2)/Ti electrode had a higher electrocatalytical activity for oxygen evolution, while the investigated anodes were of similar activity for chlorine evolution. The potential dependence of the impedance characteristics showed that the Ti(0.6)Ru(0.4)O(2)/Ti electrode behaved like a capacitor over a wider potential range than the Ti(0.6)Ir(0.4)O(2)/Ti electrode, with fully-developed pseudocapacitive properties at. potentials positive to 0.60 V(SCE). However, the impedance characteristics of the Ti(0.6)Ir(0.4)O(2)/Ti electrode changed with increasing potential from resistor-like to capacitor-like behavior.
T2  - Journal of the Serbian Chemical Society
T1  - Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure
VL  - 75
IS  - 10
SP  - 1413
EP  - 1420
DO  - 10.2298/JSC100310078P
ER  - 

@article{
author = "Panić, Vladimir V. and Dekanski, Aleksandar B. and Mišković-Stanković, Vesna B. and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2010",
abstract = "The electrochemical characteristics of Ti(0.6)Ir(0.4)O(2)/Ti and Ti(0.6)Ru(0.4)O(2)/Ti anodes prepared by the sol gel procedure from the corresponding oxide sols, obtained by force hydrolysis of the corresponding metal chlorides, were compared. The voltammetric properties in H(2)SO(4) solution indicate that Ti(0.6)Ir(0.4)O(2)/Ti has more pronounced pseudocapacitive characteristics, caused by proton-assisted, solid state surface redox transitions of the oxide. At potentials negative to 0.0 V(SCE), this electrode is of poor conductivity and activity, while the voltammetric behavior of the Ti(0.6)Ru(0.4)O(2)/Ti electrode is governed by proton injection/ejection into the oxide structure. The Ti(0.6)Ir(0.4)O(2)/Ti electrode had a higher electrocatalytical activity for oxygen evolution, while the investigated anodes were of similar activity for chlorine evolution. The potential dependence of the impedance characteristics showed that the Ti(0.6)Ru(0.4)O(2)/Ti electrode behaved like a capacitor over a wider potential range than the Ti(0.6)Ir(0.4)O(2)/Ti electrode, with fully-developed pseudocapacitive properties at. potentials positive to 0.60 V(SCE). However, the impedance characteristics of the Ti(0.6)Ir(0.4)O(2)/Ti electrode changed with increasing potential from resistor-like to capacitor-like behavior.",
journal = "Journal of the Serbian Chemical Society",
title = "Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure",
volume = "75",
number = "10",
pages = "1413-1420",
doi = "10.2298/JSC100310078P"
}

Panić, V. V., Dekanski, A. B., Mišković-Stanković, V. B., Milonjić, S. K.,& Nikolić, B. Ž.. (2010). Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure. in Journal of the Serbian Chemical Society, 75(10), 1413-1420.
https://doi.org/10.2298/JSC100310078P

Panić VV, Dekanski AB, Mišković-Stanković VB, Milonjić SK, Nikolić BŽ. Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2010;75(10):1413-1420.
doi:10.2298/JSC100310078P .

Panić, Vladimir V., Dekanski, Aleksandar B., Mišković-Stanković, Vesna B., Milonjić, Slobodan K., Nikolić, Branislav Ž., "Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure" in Journal of the Serbian Chemical Society, 75, no. 10 (2010):1413-1420,
https://doi.org/10.2298/JSC100310078P . .

TY  - JOUR
AU  - Obradović, Maja D.
AU  - Babić, Biljana M.
AU  - Kowal, Andrzej
AU  - Panić, Vladimir V.
AU  - Gojković, Snežana Lj.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3601
AB  - The electrochemical characteristics of a mixture of Pt-black and WC powders and its catalytic activity for methanol and formic acid oxidation were investigated in acid solution. XRD and AFM measurements revealed that the WC powder employed for the investigation was a single-phase material consisting of crystallites/spherical particles of average size of about 50 nm, which were agglomerated into much larger particles. Cyclic voltammetry showed that the WC underwent electrochemical oxidation, producing tungstate species. In the case of the mixed Pt + WC powders, the tungstate species were deposited on the Pt as a thin film of hydrous tungsten oxide. Enhanced hydrogen intercalation in the hydrous tungsten oxide was observed and it was proposed to be promoted in mixed powders by the presence of hydrogen adatoms on bare Pt sites. The determination of Pt surface area in the Pt + WC layer by stripping of underpotentially deposited Cu revealed that the entire Pt surface was accessible for underpotential deposition of Cu. Investigation of the electrochemical oxidation of methanol and formic acid on Pt + WC and pure Pt layers did not indicate electrocatalytic promotion due to the presence of WC.
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemical properties of mixed WC and Pt-black powders
VL  - 73
IS  - 12
SP  - 1197
EP  - 1209
DO  - 10.2298/JSC0812197O
ER  - 

@article{
author = "Obradović, Maja D. and Babić, Biljana M. and Kowal, Andrzej and Panić, Vladimir V. and Gojković, Snežana Lj.",
year = "2008",
abstract = "The electrochemical characteristics of a mixture of Pt-black and WC powders and its catalytic activity for methanol and formic acid oxidation were investigated in acid solution. XRD and AFM measurements revealed that the WC powder employed for the investigation was a single-phase material consisting of crystallites/spherical particles of average size of about 50 nm, which were agglomerated into much larger particles. Cyclic voltammetry showed that the WC underwent electrochemical oxidation, producing tungstate species. In the case of the mixed Pt + WC powders, the tungstate species were deposited on the Pt as a thin film of hydrous tungsten oxide. Enhanced hydrogen intercalation in the hydrous tungsten oxide was observed and it was proposed to be promoted in mixed powders by the presence of hydrogen adatoms on bare Pt sites. The determination of Pt surface area in the Pt + WC layer by stripping of underpotentially deposited Cu revealed that the entire Pt surface was accessible for underpotential deposition of Cu. Investigation of the electrochemical oxidation of methanol and formic acid on Pt + WC and pure Pt layers did not indicate electrocatalytic promotion due to the presence of WC.",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical properties of mixed WC and Pt-black powders",
volume = "73",
number = "12",
pages = "1197-1209",
doi = "10.2298/JSC0812197O"
}

Obradović, M. D., Babić, B. M., Kowal, A., Panić, V. V.,& Gojković, S. Lj.. (2008). Electrochemical properties of mixed WC and Pt-black powders. in Journal of the Serbian Chemical Society, 73(12), 1197-1209.
https://doi.org/10.2298/JSC0812197O

Obradović MD, Babić BM, Kowal A, Panić VV, Gojković SL. Electrochemical properties of mixed WC and Pt-black powders. in Journal of the Serbian Chemical Society. 2008;73(12):1197-1209.
doi:10.2298/JSC0812197O .

Obradović, Maja D., Babić, Biljana M., Kowal, Andrzej, Panić, Vladimir V., Gojković, Snežana Lj., "Electrochemical properties of mixed WC and Pt-black powders" in Journal of the Serbian Chemical Society, 73, no. 12 (2008):1197-1209,
https://doi.org/10.2298/JSC0812197O . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna B.
AU  - Nikolić, Branislav Ž.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3143
AB  - Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol (ink method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in ail ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical propel-ties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.
T2  - Journal of the Serbian Chemical Society
T1  - Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route
VL  - 71
IS  - 11
SP  - 1173
EP  - 1186
DO  - 10.2298/JSC0611173P
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Mišković-Stanković, Vesna B. and Nikolić, Branislav Ž.",
year = "2006",
abstract = "Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol (ink method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in ail ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical propel-ties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.",
journal = "Journal of the Serbian Chemical Society",
title = "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route",
volume = "71",
number = "11",
pages = "1173-1186",
doi = "10.2298/JSC0611173P"
}

Panić, V., Dekanski, A. B., Milonjić, S. K., Mišković-Stanković, V. B.,& Nikolić, B. Ž.. (2006). Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society, 71(11), 1173-1186.
https://doi.org/10.2298/JSC0611173P

Panić V, Dekanski AB, Milonjić SK, Mišković-Stanković VB, Nikolić BŽ. Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society. 2006;71(11):1173-1186.
doi:10.2298/JSC0611173P .

Panić, Vladimir, Dekanski, Aleksandar B., Milonjić, Slobodan K., Mišković-Stanković, Vesna B., Nikolić, Branislav Ž., "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1173-1186,
https://doi.org/10.2298/JSC0611173P . .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Gojković, S
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna B.
AU  - Nikolić, Branislav Ž.
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6529
AB  - The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.
T2  - Materials Science Forum
T1  - Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure
VL  - 494
SP  - 235
EP  - 240
DO  - 10.4028/www.scientific.net/MSF.494.235
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Gojković, S and Milonjić, Slobodan K. and Mišković-Stanković, Vesna B. and Nikolić, Branislav Ž.",
year = "2005",
abstract = "The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.",
journal = "Materials Science Forum",
title = "Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure",
volume = "494",
pages = "235-240",
doi = "10.4028/www.scientific.net/MSF.494.235"
}

Panic, V., Dekanski, A. B., Gojković, S., Milonjić, S. K., Mišković-Stanković, V. B.,& Nikolić, B. Ž.. (2005). Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Materials Science Forum, 494, 235-240.
https://doi.org/10.4028/www.scientific.net/MSF.494.235

Panic V, Dekanski AB, Gojković S, Milonjić SK, Mišković-Stanković VB, Nikolić BŽ. Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Materials Science Forum. 2005;494:235-240.
doi:10.4028/www.scientific.net/MSF.494.235 .

Panic, V, Dekanski, Aleksandar B., Gojković, S, Milonjić, Slobodan K., Mišković-Stanković, Vesna B., Nikolić, Branislav Ž., "Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure" in Materials Science Forum, 494 (2005):235-240,
https://doi.org/10.4028/www.scientific.net/MSF.494.235 . .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Mišković-Stanković, Vesna B.
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2883
AB  - The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was investigated. The loss of electrocatalytic activity was registered by an accelerated stability test in 0.50 mol dm(-3) NaCl electrolyte, while the changes in the electrochemical properties were monitored during the stability test by cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy in 1.0 mol dm(-3) HClO4 and in 0.50 mol dm(-3) NaCl. The changes in anode behavior suggest that the essential cause for the deactivation of the anode prepared by the sol-gel procedure is the formation of an insulating TiO2-rich layer at the coating surface due to the continuous dissolution of the Ru active species. However, the growth of the insulating TiO2 layer in the coating/Ti substrate interphase mainly causes deactivation of the thermally prepared anode. The deactivation mechanism appeared to be the consequence of the different morphology of the coatings prepared by two different procedures. (c) 2005 Elsevier B.V. All rights reserved.
T2  - Journal of Electroanalytical Chemistry
T1  - On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure
VL  - 579
IS  - 1
SP  - 67
EP  - 76
DO  - 10.1016/j.jelechem.2005.01.026
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Mišković-Stanković, Vesna B. and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2005",
abstract = "The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was investigated. The loss of electrocatalytic activity was registered by an accelerated stability test in 0.50 mol dm(-3) NaCl electrolyte, while the changes in the electrochemical properties were monitored during the stability test by cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy in 1.0 mol dm(-3) HClO4 and in 0.50 mol dm(-3) NaCl. The changes in anode behavior suggest that the essential cause for the deactivation of the anode prepared by the sol-gel procedure is the formation of an insulating TiO2-rich layer at the coating surface due to the continuous dissolution of the Ru active species. However, the growth of the insulating TiO2 layer in the coating/Ti substrate interphase mainly causes deactivation of the thermally prepared anode. The deactivation mechanism appeared to be the consequence of the different morphology of the coatings prepared by two different procedures. (c) 2005 Elsevier B.V. All rights reserved.",
journal = "Journal of Electroanalytical Chemistry",
title = "On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure",
volume = "579",
number = "1",
pages = "67-76",
doi = "10.1016/j.jelechem.2005.01.026"
}

Panic, V., Dekanski, A. B., Mišković-Stanković, V. B., Milonjić, S. K.,& Nikolić, B. Ž.. (2005). On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure. in Journal of Electroanalytical Chemistry, 579(1), 67-76.
https://doi.org/10.1016/j.jelechem.2005.01.026

Panic V, Dekanski AB, Mišković-Stanković VB, Milonjić SK, Nikolić BŽ. On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure. in Journal of Electroanalytical Chemistry. 2005;579(1):67-76.
doi:10.1016/j.jelechem.2005.01.026 .

Panic, V, Dekanski, Aleksandar B., Mišković-Stanković, Vesna B., Milonjić, Slobodan K., Nikolić, Branislav Ž., "On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure" in Journal of Electroanalytical Chemistry, 579, no. 1 (2005):67-76,
https://doi.org/10.1016/j.jelechem.2005.01.026 . .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Mišković-Stanković, Vesna B.
AU  - Nikolić, Branislav Ž.
AU  - Milonjić, Slobodan K.
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2853
AB  - Using a sol-gel procedure, RuO2-TiO2 active coatings were formed on a titanium support. The conditions of preparation of the RuO2 and TiO2 sols were investigated and the sols were characterized by transmission electron microscopy (TEM) and X-ray diffraction technique. Prepared anodes were investigated from the standpoint of morphology (scanning tunneling and electron microscopy) and electrochemical behavior (cyclic voltammetry, polarization measurements, and electrochemical impedance spectroscopy). The service life of the RuO2-TiO2 active coatings was examined by an accelerated corrosion stability test in 0.5 mol dm(-3) NaCl solution. In order to resolve the role of TiO2 in the deactivation mechanism of the active coating, additional TiO2 layers were introduced in the support/coating interface or on the surface of the coating. The behavior of these anodes with the TiO2-enriched coating layer was compared with the behavior of anodes with regular RuO2-TiO2 coatings. The results show that the loss of coating electrocatalytic activity is caused by dissolution of active Ru species and TiO2 enrichment in the coating. It is also observed that the sol-gel preparation procedure favors the formation of the TiO2 layer at the surface of the RuO2-TiO2 coating.
T2  - Materials and Manufacturing Processes
T1  - The role of sol-gel procedure conditions in electrochemical behavior and corrosion stability of Ti/[RuO2-TiO2] anodes
VL  - 20
IS  - 1
SP  - 89
EP  - 103
DO  - 10.1081/AMP-200041645
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Mišković-Stanković, Vesna B. and Nikolić, Branislav Ž. and Milonjić, Slobodan K.",
year = "2005",
abstract = "Using a sol-gel procedure, RuO2-TiO2 active coatings were formed on a titanium support. The conditions of preparation of the RuO2 and TiO2 sols were investigated and the sols were characterized by transmission electron microscopy (TEM) and X-ray diffraction technique. Prepared anodes were investigated from the standpoint of morphology (scanning tunneling and electron microscopy) and electrochemical behavior (cyclic voltammetry, polarization measurements, and electrochemical impedance spectroscopy). The service life of the RuO2-TiO2 active coatings was examined by an accelerated corrosion stability test in 0.5 mol dm(-3) NaCl solution. In order to resolve the role of TiO2 in the deactivation mechanism of the active coating, additional TiO2 layers were introduced in the support/coating interface or on the surface of the coating. The behavior of these anodes with the TiO2-enriched coating layer was compared with the behavior of anodes with regular RuO2-TiO2 coatings. The results show that the loss of coating electrocatalytic activity is caused by dissolution of active Ru species and TiO2 enrichment in the coating. It is also observed that the sol-gel preparation procedure favors the formation of the TiO2 layer at the surface of the RuO2-TiO2 coating.",
journal = "Materials and Manufacturing Processes",
title = "The role of sol-gel procedure conditions in electrochemical behavior and corrosion stability of Ti/[RuO2-TiO2] anodes",
volume = "20",
number = "1",
pages = "89-103",
doi = "10.1081/AMP-200041645"
}

Panic, V., Dekanski, A. B., Mišković-Stanković, V. B., Nikolić, B. Ž.,& Milonjić, S. K.. (2005). The role of sol-gel procedure conditions in electrochemical behavior and corrosion stability of Ti/[RuO2-TiO2] anodes. in Materials and Manufacturing Processes, 20(1), 89-103.
https://doi.org/10.1081/AMP-200041645

Panic V, Dekanski AB, Mišković-Stanković VB, Nikolić BŽ, Milonjić SK. The role of sol-gel procedure conditions in electrochemical behavior and corrosion stability of Ti/[RuO2-TiO2] anodes. in Materials and Manufacturing Processes. 2005;20(1):89-103.
doi:10.1081/AMP-200041645 .

Panic, V, Dekanski, Aleksandar B., Mišković-Stanković, Vesna B., Nikolić, Branislav Ž., Milonjić, Slobodan K., "The role of sol-gel procedure conditions in electrochemical behavior and corrosion stability of Ti/[RuO2-TiO2] anodes" in Materials and Manufacturing Processes, 20, no. 1 (2005):89-103,
https://doi.org/10.1081/AMP-200041645 . .

TY  - JOUR
AU  - Panic, V
AU  - Vidakovic, T
AU  - Gojković, S
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2003
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6385
AB  - Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000(R) (BP) and Vulcan(R) XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 degreesC. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 degreesC, while the lowintensity peak at 2theta position that corresponds to the most intensive peak of the rutile structure was registered at 450 degreesC. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g(-1) of composite was registered for RuOxHy supported on BP and calcined at 300 degreesC while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOXHy composite is highly porous while BP-supported one is more compact. (C) 2003 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol
VL  - 48
IS  - 25-26
SP  - 3805
EP  - 3813
DO  - 10.1016/S0013-4686(03)00514-0
ER  - 

@article{
author = "Panic, V and Vidakovic, T and Gojković, S and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2003",
abstract = "Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000(R) (BP) and Vulcan(R) XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 degreesC. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 degreesC, while the lowintensity peak at 2theta position that corresponds to the most intensive peak of the rutile structure was registered at 450 degreesC. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g(-1) of composite was registered for RuOxHy supported on BP and calcined at 300 degreesC while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOXHy composite is highly porous while BP-supported one is more compact. (C) 2003 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol",
volume = "48",
number = "25-26",
pages = "3805-3813",
doi = "10.1016/S0013-4686(03)00514-0"
}

Panic, V., Vidakovic, T., Gojković, S., Dekanski, A. B., Milonjić, S. K.,& Nikolić, B. Ž.. (2003). The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta, 48(25-26), 3805-3813.
https://doi.org/10.1016/S0013-4686(03)00514-0

Panic V, Vidakovic T, Gojković S, Dekanski AB, Milonjić SK, Nikolić BŽ. The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta. 2003;48(25-26):3805-3813.
doi:10.1016/S0013-4686(03)00514-0 .

Panic, V, Vidakovic, T, Gojković, S, Dekanski, Aleksandar B., Milonjić, Slobodan K., Nikolić, Branislav Ž., "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol" in Electrochimica Acta, 48, no. 25-26 (2003):3805-3813,
https://doi.org/10.1016/S0013-4686(03)00514-0 . .

TY  - JOUR
AU  - Panic, VV
AU  - Dekanski, Aleksandar B.
AU  - Mišković-Stanković, Vesna B.
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2003
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2700
AB  - In order to understand the rule of TiO2 in the deactivation mechanism of an active RuO2-TiO2 coating, an additional TiO2 laver was introduced in the support\coating interphase of regular Ti//[RuO2-TiO2] anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2-TiO2 coatings. which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot, obtained by electrochemical impedance spectroscopy, for a regular RuO2-TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TO, layer at different position within RuO2-TiO2 coating.
T2  - Journal of the Serbian Chemical Society
T1  - The role of titanium oxide concentration profile of titanium oxide of RuO2-TiO2 coatings obtained by the sol-gel procedure on its electrochemical behavior
VL  - 68
IS  - 12
SP  - 979
EP  - 988
DO  - 10.2298/0352-51390312979P
ER  - 

@article{
author = "Panic, VV and Dekanski, Aleksandar B. and Mišković-Stanković, Vesna B. and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2003",
abstract = "In order to understand the rule of TiO2 in the deactivation mechanism of an active RuO2-TiO2 coating, an additional TiO2 laver was introduced in the support\coating interphase of regular Ti//[RuO2-TiO2] anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2-TiO2 coatings. which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot, obtained by electrochemical impedance spectroscopy, for a regular RuO2-TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TO, layer at different position within RuO2-TiO2 coating.",
journal = "Journal of the Serbian Chemical Society",
title = "The role of titanium oxide concentration profile of titanium oxide of RuO2-TiO2 coatings obtained by the sol-gel procedure on its electrochemical behavior",
volume = "68",
number = "12",
pages = "979-988",
doi = "10.2298/0352-51390312979P"
}

Panic, V., Dekanski, A. B., Mišković-Stanković, V. B., Milonjić, S. K.,& Nikolić, B. Ž.. (2003). The role of titanium oxide concentration profile of titanium oxide of RuO2-TiO2 coatings obtained by the sol-gel procedure on its electrochemical behavior. in Journal of the Serbian Chemical Society, 68(12), 979-988.
https://doi.org/10.2298/0352-51390312979P

Panic V, Dekanski AB, Mišković-Stanković VB, Milonjić SK, Nikolić BŽ. The role of titanium oxide concentration profile of titanium oxide of RuO2-TiO2 coatings obtained by the sol-gel procedure on its electrochemical behavior. in Journal of the Serbian Chemical Society. 2003;68(12):979-988.
doi:10.2298/0352-51390312979P .

Panic, VV, Dekanski, Aleksandar B., Mišković-Stanković, Vesna B., Milonjić, Slobodan K., Nikolić, Branislav Ž., "The role of titanium oxide concentration profile of titanium oxide of RuO2-TiO2 coatings obtained by the sol-gel procedure on its electrochemical behavior" in Journal of the Serbian Chemical Society, 68, no. 12 (2003):979-988,
https://doi.org/10.2298/0352-51390312979P . .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Wang, G
AU  - Fedoroff, M
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2003
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2641
AB  - Characterization of RuO2 and TiO2 sols of different aging times, obtained by forced hydrolysis of appropriate chloride salts, was performed by transmission electron microscopy (TEM). The aging time of TiO2 sols was observed to affect the size of particles as well as the crystallinity of the solid phase of the sols. The surface morphology of RuO2-TiO2 coatings on titanium, obtained by the sol-gel procedure using TiO2 sols of different aging times and RuO2 sol of fixed aging time, was investigated by scanning tunneling microscopy (STM) at three different scan sizes. The STM data indicated uniform microdistribution of the coating material (small microroughness) and an increase in nanoroughness with the aging time of the TiO2 sol. The observed increase in real coating surface area with increasing TiO2 particle size confirms the earlier cyclic voltammetry results. (C) 2003 Elsevier Science (USA). All rights reserved.
T2  - Journal of Colloid and Interface Science
T1  - Morphology of RuO2-TiO2 coatings and TEM characterization of oxide sols used for their preparation
VL  - 263
IS  - 1
SP  - 68
EP  - 73
DO  - 10.1016/S0021-9797(03)00261-3
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Wang, G and Fedoroff, M and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2003",
abstract = "Characterization of RuO2 and TiO2 sols of different aging times, obtained by forced hydrolysis of appropriate chloride salts, was performed by transmission electron microscopy (TEM). The aging time of TiO2 sols was observed to affect the size of particles as well as the crystallinity of the solid phase of the sols. The surface morphology of RuO2-TiO2 coatings on titanium, obtained by the sol-gel procedure using TiO2 sols of different aging times and RuO2 sol of fixed aging time, was investigated by scanning tunneling microscopy (STM) at three different scan sizes. The STM data indicated uniform microdistribution of the coating material (small microroughness) and an increase in nanoroughness with the aging time of the TiO2 sol. The observed increase in real coating surface area with increasing TiO2 particle size confirms the earlier cyclic voltammetry results. (C) 2003 Elsevier Science (USA). All rights reserved.",
journal = "Journal of Colloid and Interface Science",
title = "Morphology of RuO2-TiO2 coatings and TEM characterization of oxide sols used for their preparation",
volume = "263",
number = "1",
pages = "68-73",
doi = "10.1016/S0021-9797(03)00261-3"
}

Panic, V., Dekanski, A. B., Wang, G., Fedoroff, M., Milonjić, S. K.,& Nikolić, B. Ž.. (2003). Morphology of RuO2-TiO2 coatings and TEM characterization of oxide sols used for their preparation. in Journal of Colloid and Interface Science, 263(1), 68-73.
https://doi.org/10.1016/S0021-9797(03)00261-3

Panic V, Dekanski AB, Wang G, Fedoroff M, Milonjić SK, Nikolić BŽ. Morphology of RuO2-TiO2 coatings and TEM characterization of oxide sols used for their preparation. in Journal of Colloid and Interface Science. 2003;263(1):68-73.
doi:10.1016/S0021-9797(03)00261-3 .

Panic, V, Dekanski, Aleksandar B., Wang, G, Fedoroff, M, Milonjić, Slobodan K., Nikolić, Branislav Ž., "Morphology of RuO2-TiO2 coatings and TEM characterization of oxide sols used for their preparation" in Journal of Colloid and Interface Science, 263, no. 1 (2003):68-73,
https://doi.org/10.1016/S0021-9797(03)00261-3 . .

TY  - JOUR
AU  - Mitrovic, D
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, R
AU  - Nikolić, Branislav Ž.
PY  - 2001
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2485
AB  - The influence of the addition of methanol, ethanol, 1-propanol and 2-propanol to the dispersing medium of a mixture of RuO2 and TiO2 sols on the electrochemically active surface area for proton exchange, as well as on the electrocatalytic activity for the chlorine evolution reaction (CER) of RuO2-TiO2/Ti electrode obtained by sol-gel procedure was investigated. The electrochemically active surface area was examined by cyclic voltammetry, while the analysis of the activity for the CER was performed by polarization measurements. The stability of the obtained anode coatings was also checked by an accelerated stability test. The anode properties depend on the number of C atoms in the alcohol molecule, as well as on the elapsed time between the preparation of the sols/alcohol mixture and its application onto the titanium support. The addition of alcohol increased the activity of the anodes for the CER, compared to those prepared without the addition, but their stability was smaller.
T2  - Journal of the Serbian Chemical Society
T1  - The effect of the composition of the dispersing medium of oxide sols on the electro catalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes
VL  - 66
IS  - 11-12
SP  - 847
EP  - 857
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2485
ER  - 

@article{
author = "Mitrovic, D and Panic, V and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Atanasoski, R and Nikolić, Branislav Ž.",
year = "2001",
abstract = "The influence of the addition of methanol, ethanol, 1-propanol and 2-propanol to the dispersing medium of a mixture of RuO2 and TiO2 sols on the electrochemically active surface area for proton exchange, as well as on the electrocatalytic activity for the chlorine evolution reaction (CER) of RuO2-TiO2/Ti electrode obtained by sol-gel procedure was investigated. The electrochemically active surface area was examined by cyclic voltammetry, while the analysis of the activity for the CER was performed by polarization measurements. The stability of the obtained anode coatings was also checked by an accelerated stability test. The anode properties depend on the number of C atoms in the alcohol molecule, as well as on the elapsed time between the preparation of the sols/alcohol mixture and its application onto the titanium support. The addition of alcohol increased the activity of the anodes for the CER, compared to those prepared without the addition, but their stability was smaller.",
journal = "Journal of the Serbian Chemical Society",
title = "The effect of the composition of the dispersing medium of oxide sols on the electro catalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes",
volume = "66",
number = "11-12",
pages = "847-857",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2485"
}

Mitrovic, D., Panic, V., Dekanski, A. B., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (2001). The effect of the composition of the dispersing medium of oxide sols on the electro catalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes. in Journal of the Serbian Chemical Society, 66(11-12), 847-857.
https://hdl.handle.net/21.15107/rcub_vinar_2485

Mitrovic D, Panic V, Dekanski AB, Milonjić SK, Atanasoski R, Nikolić BŽ. The effect of the composition of the dispersing medium of oxide sols on the electro catalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes. in Journal of the Serbian Chemical Society. 2001;66(11-12):847-857.
https://hdl.handle.net/21.15107/rcub_vinar_2485 .

Mitrovic, D, Panic, V, Dekanski, Aleksandar B., Milonjić, Slobodan K., Atanasoski, R, Nikolić, Branislav Ž., "The effect of the composition of the dispersing medium of oxide sols on the electro catalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes" in Journal of the Serbian Chemical Society, 66, no. 11-12 (2001):847-857,
https://hdl.handle.net/21.15107/rcub_vinar_2485 .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, R
AU  - Nikolić, Branislav Ž.
PY  - 2000
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6305
AB  - The influence of the aging time of RuO2 sol on the electrochemical properties and behaviour in chlorine evolution reaction of RuO2/Ti and (40%RuO2 + 60%TiO2)/Ti anodes obtained by sol-gel procedure was studied. The electrochemically active surface area of the anode coatings was examined by cyclic voltammetry. The electrocatalytic activity and anode stability in chlorine evolution reaction were investigated by polarization measurements and accelerated stability test. The dependence of electrochemical properties of obtained activated titanium anodes on RuO2 particle size was established.
T2  - Materials Science Forum
T1  - The influence of the aging time of RuO2 sol on the electrochemical properties of the activated titanium anodes obtained by sol-gel procedure
VL  - 352
SP  - 117
EP  - 122
DO  - 10.4028/www.scientific.net/MSF.352.117
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Atanasoski, R and Nikolić, Branislav Ž.",
year = "2000",
abstract = "The influence of the aging time of RuO2 sol on the electrochemical properties and behaviour in chlorine evolution reaction of RuO2/Ti and (40%RuO2 + 60%TiO2)/Ti anodes obtained by sol-gel procedure was studied. The electrochemically active surface area of the anode coatings was examined by cyclic voltammetry. The electrocatalytic activity and anode stability in chlorine evolution reaction were investigated by polarization measurements and accelerated stability test. The dependence of electrochemical properties of obtained activated titanium anodes on RuO2 particle size was established.",
journal = "Materials Science Forum",
title = "The influence of the aging time of RuO2 sol on the electrochemical properties of the activated titanium anodes obtained by sol-gel procedure",
volume = "352",
pages = "117-122",
doi = "10.4028/www.scientific.net/MSF.352.117"
}

Panic, V., Dekanski, A. B., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (2000). The influence of the aging time of RuO2 sol on the electrochemical properties of the activated titanium anodes obtained by sol-gel procedure. in Materials Science Forum, 352, 117-122.
https://doi.org/10.4028/www.scientific.net/MSF.352.117

Panic V, Dekanski AB, Milonjić SK, Atanasoski R, Nikolić BŽ. The influence of the aging time of RuO2 sol on the electrochemical properties of the activated titanium anodes obtained by sol-gel procedure. in Materials Science Forum. 2000;352:117-122.
doi:10.4028/www.scientific.net/MSF.352.117 .

Panic, V, Dekanski, Aleksandar B., Milonjić, Slobodan K., Atanasoski, R, Nikolić, Branislav Ž., "The influence of the aging time of RuO2 sol on the electrochemical properties of the activated titanium anodes obtained by sol-gel procedure" in Materials Science Forum, 352 (2000):117-122,
https://doi.org/10.4028/www.scientific.net/MSF.352.117 . .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, R
AU  - Nikolić, Branislav Ž.
PY  - 2000
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2375
AB  - The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated.
T2  - Journal of the Serbian Chemical Society
T1  - The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure
VL  - 65
IS  - 9
SP  - 649
EP  - 660
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2375
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Atanasoski, R and Nikolić, Branislav Ž.",
year = "2000",
abstract = "The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated.",
journal = "Journal of the Serbian Chemical Society",
title = "The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure",
volume = "65",
number = "9",
pages = "649-660",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2375"
}

Panic, V., Dekanski, A. B., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (2000). The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society, 65(9), 649-660.
https://hdl.handle.net/21.15107/rcub_vinar_2375

Panic V, Dekanski AB, Milonjić SK, Atanasoski R, Nikolić BŽ. The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2000;65(9):649-660.
https://hdl.handle.net/21.15107/rcub_vinar_2375 .

Panic, V, Dekanski, Aleksandar B., Milonjić, Slobodan K., Atanasoski, R, Nikolić, Branislav Ž., "The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure" in Journal of the Serbian Chemical Society, 65, no. 9 (2000):649-660,
https://hdl.handle.net/21.15107/rcub_vinar_2375 .

TY  - JOUR
AU  - Panic, V
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, R
AU  - Nikolić, Branislav Ž.
PY  - 2000
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6298
AB  - The influence of the aging time of RuO2 and TiO2 sols used for the preparation of (40% RuO2 + 60% TiO2)/Ti anodes by the sol-gel procedure on the electrochemical properties and behavior for the chlorine evolution reaction of obtained anodes was studied. The electrochemical (active) surface area of the anode coatings was examined by cyclic voltammetry. The electrocatalytic activity and stability of obtained anodes for the chlorine evolution reaction were investigated by polarization measurements and accelerated stability test. The dependence of electrochemical properties of obtained activated titanium anodes on RuO2 and TiO2 sol particle size was established. (C) 2000 Elsevier Science Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure
VL  - 46
IS  - 2-3
SP  - 415
EP  - 421
DO  - 10.1016/S0013-4686(00)00600-9
ER  - 

@article{
author = "Panic, V and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Atanasoski, R and Nikolić, Branislav Ž.",
year = "2000",
abstract = "The influence of the aging time of RuO2 and TiO2 sols used for the preparation of (40% RuO2 + 60% TiO2)/Ti anodes by the sol-gel procedure on the electrochemical properties and behavior for the chlorine evolution reaction of obtained anodes was studied. The electrochemical (active) surface area of the anode coatings was examined by cyclic voltammetry. The electrocatalytic activity and stability of obtained anodes for the chlorine evolution reaction were investigated by polarization measurements and accelerated stability test. The dependence of electrochemical properties of obtained activated titanium anodes on RuO2 and TiO2 sol particle size was established. (C) 2000 Elsevier Science Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure",
volume = "46",
number = "2-3",
pages = "415-421",
doi = "10.1016/S0013-4686(00)00600-9"
}

Panic, V., Dekanski, A. B., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (2000). The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure. in Electrochimica Acta, 46(2-3), 415-421.
https://doi.org/10.1016/S0013-4686(00)00600-9

Panic V, Dekanski AB, Milonjić SK, Atanasoski R, Nikolić BŽ. The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure. in Electrochimica Acta. 2000;46(2-3):415-421.
doi:10.1016/S0013-4686(00)00600-9 .

Panic, V, Dekanski, Aleksandar B., Milonjić, Slobodan K., Atanasoski, R, Nikolić, Branislav Ž., "The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure" in Electrochimica Acta, 46, no. 2-3 (2000):415-421,
https://doi.org/10.1016/S0013-4686(00)00600-9 . .

TY  - JOUR
AU  - Panic, VV
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, RT
AU  - Nikolić, Branislav Ž.
PY  - 1999
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6285
AB  - TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis at elevated temperature. The Ti supported coatings were obtained by the sol-gel method using a sol mixture in which the metal content was Ru(40%)-Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was examined by S-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows a considerably higher lifetime for sol-gel coated anodes than for those obtained by the usual thermal decomposition method. (C) 1999 Elsevier Science B.V. All rights reserved.
T2  - Colloids and Surfaces. A: Physicochemical and Engineering Aspects
T1  - RuO2-TiO2 coated titanium anodes obtained by the sol-gel procedure and their electrochemical behaviour in the chlorine evolution reaction
VL  - 157
IS  - 1-3
SP  - 269
EP  - 274
DO  - 10.1016/S0927-7757(99)00094-1
ER  - 

@article{
author = "Panic, VV and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Atanasoski, RT and Nikolić, Branislav Ž.",
year = "1999",
abstract = "TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis at elevated temperature. The Ti supported coatings were obtained by the sol-gel method using a sol mixture in which the metal content was Ru(40%)-Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was examined by S-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows a considerably higher lifetime for sol-gel coated anodes than for those obtained by the usual thermal decomposition method. (C) 1999 Elsevier Science B.V. All rights reserved.",
journal = "Colloids and Surfaces. A: Physicochemical and Engineering Aspects",
title = "RuO2-TiO2 coated titanium anodes obtained by the sol-gel procedure and their electrochemical behaviour in the chlorine evolution reaction",
volume = "157",
number = "1-3",
pages = "269-274",
doi = "10.1016/S0927-7757(99)00094-1"
}

Panic, V., Dekanski, A. B., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (1999). RuO2-TiO2 coated titanium anodes obtained by the sol-gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 157(1-3), 269-274.
https://doi.org/10.1016/S0927-7757(99)00094-1

Panic V, Dekanski AB, Milonjić SK, Atanasoski R, Nikolić BŽ. RuO2-TiO2 coated titanium anodes obtained by the sol-gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects. 1999;157(1-3):269-274.
doi:10.1016/S0927-7757(99)00094-1 .

Panic, VV, Dekanski, Aleksandar B., Milonjić, Slobodan K., Atanasoski, RT, Nikolić, Branislav Ž., "RuO2-TiO2 coated titanium anodes obtained by the sol-gel procedure and their electrochemical behaviour in the chlorine evolution reaction" in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 157, no. 1-3 (1999):269-274,
https://doi.org/10.1016/S0927-7757(99)00094-1 . .