TY  - JOUR
AU  - Li, Xiaohui
AU  - Zhou, Lei
AU  - Hong, Junyu
AU  - He, Shiman
AU  - Jing, Xiping
AU  - Dramićanin, Miroslav
AU  - Shi, Jianxin
AU  - Wu, Mingmei
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9016
AB  - Modulation of structural order-disorder transition and structural oxygen defects can provide fundamental insights in the optimization of luminescence performances of phosphors. In this study, the luminescence of Ba3ZnTa2O9(BZT) was systematically elucidated, including the emission arising from the charge transfer (Nb5+/Ta5+ O2-) and anti-site oxygen defect emission due to the B-site disordering (defect type: [2ZnNb3-+ 3Vo2+]), as corroborated by the electronic structural calculations and detailed experiments. We present a two-step design for the optimization of luminescence properties of Ba3ZnTa2O9phosphor. In the first step, the B-site equivalent doping (Ta5+substituted by Nb5+) was used to modulate the B-site atomic arrangement, which induced the formation of the cubic phase with B-site full disordering. In the second step, the A-site nonequivalent doping (Ba2+substituted by Eu3+) was used to decrease the oxygen defect concentration. After the two-step optimization, the photoluminescence excitation spectrum of Ba3-yEuyZnNb2O9(y= 0.1) shows a broad band excitation (300-400 nm), which is a good match with the near-UV LED chip emission. Even more importantly, the emission spectrum covers the entire visible spectral region and exhibits a remarkably enhanced emission intensity (a 40 times enhancement when compared to that of the intrinsic BZT). The fabricated LED device comprising an n-UV chip (= 370 nm) and a single-component Ba3-yEuyZnNb2O9(y= 0.1) phosphor coating emits a warm white light with a low correlated color temperature (CCT = 4813 K) and a good color rendering index (Ra= 82.36).
T2  - Journal of Materials Chemistry C
T1  - Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors
VL  - 8
IS  - 20
SP  - 6715
EP  - 6723
DO  - 10.1039/D0TC01201G
ER  - 

@article{
author = "Li, Xiaohui and Zhou, Lei and Hong, Junyu and He, Shiman and Jing, Xiping and Dramićanin, Miroslav and Shi, Jianxin and Wu, Mingmei",
year = "2020",
abstract = "Modulation of structural order-disorder transition and structural oxygen defects can provide fundamental insights in the optimization of luminescence performances of phosphors. In this study, the luminescence of Ba3ZnTa2O9(BZT) was systematically elucidated, including the emission arising from the charge transfer (Nb5+/Ta5+ O2-) and anti-site oxygen defect emission due to the B-site disordering (defect type: [2ZnNb3-+ 3Vo2+]), as corroborated by the electronic structural calculations and detailed experiments. We present a two-step design for the optimization of luminescence properties of Ba3ZnTa2O9phosphor. In the first step, the B-site equivalent doping (Ta5+substituted by Nb5+) was used to modulate the B-site atomic arrangement, which induced the formation of the cubic phase with B-site full disordering. In the second step, the A-site nonequivalent doping (Ba2+substituted by Eu3+) was used to decrease the oxygen defect concentration. After the two-step optimization, the photoluminescence excitation spectrum of Ba3-yEuyZnNb2O9(y= 0.1) shows a broad band excitation (300-400 nm), which is a good match with the near-UV LED chip emission. Even more importantly, the emission spectrum covers the entire visible spectral region and exhibits a remarkably enhanced emission intensity (a 40 times enhancement when compared to that of the intrinsic BZT). The fabricated LED device comprising an n-UV chip (= 370 nm) and a single-component Ba3-yEuyZnNb2O9(y= 0.1) phosphor coating emits a warm white light with a low correlated color temperature (CCT = 4813 K) and a good color rendering index (Ra= 82.36).",
journal = "Journal of Materials Chemistry C",
title = "Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors",
volume = "8",
number = "20",
pages = "6715-6723",
doi = "10.1039/D0TC01201G"
}

Li, X., Zhou, L., Hong, J., He, S., Jing, X., Dramićanin, M., Shi, J.,& Wu, M.. (2020). Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors. in Journal of Materials Chemistry C, 8(20), 6715-6723.
https://doi.org/10.1039/D0TC01201G

Li X, Zhou L, Hong J, He S, Jing X, Dramićanin M, Shi J, Wu M. Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors. in Journal of Materials Chemistry C. 2020;8(20):6715-6723.
doi:10.1039/D0TC01201G .

Li, Xiaohui, Zhou, Lei, Hong, Junyu, He, Shiman, Jing, Xiping, Dramićanin, Miroslav, Shi, Jianxin, Wu, Mingmei, "Structural modulation induced intensity enhancement of full color spectra: A case of Ba3ZnTa2-xNbxO9:Eu3+phosphors" in Journal of Materials Chemistry C, 8, no. 20 (2020):6715-6723,
https://doi.org/10.1039/D0TC01201G . .

TY  - JOUR
AU  - Li, Xiaohui
AU  - Milićević, Bojana R.
AU  - Dramićanin, Miroslav
AU  - Jing, Xiping
AU  - Tang, Qiang
AU  - Shi, Jianxin
AU  - Wu, Mingmei
PY  - 2019
UR  - http://xlink.rsc.org/?DOI=C9TC00159J
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8087
AB  - Single-component white light phosphors with a broad and full color spectrum are urgently required to overcome residual problems with commercial phosphors. In this paper, we describe how Eu3+, as the dopant of Sr3ZnTa2O9 (SZT), plays an important role in structural modulation (including structural order-disorder and intrinsic oxygen defects), as demonstrated by electronic structural calculations and systematic experiments. Furthermore, D-5(0) F-7(2) emission of Eu3+ provides the red component of the emission spectrum and increases the color rendering index of SZT:Eu3+ phosphors. Consequently, the resulting phosphor SZT:10%Eu3+ shows significantly enhanced emission intensity, and its broadband emission covers the entire visible region from 400 nm to 720 nm. A fabricated LED device using a near-ultraviolet 370 nm chip coated with a single-component, the SZT:10%Eu3+ phosphor, shows warm white emission with a high color rendering index (R-a = 82).
T2  - Journal of Materials Chemistry C
T1  - Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement
VL  - 7
IS  - 9
SP  - 2596
EP  - 2603
DO  - 10.1039/C9TC00159J
ER  - 

@article{
author = "Li, Xiaohui and Milićević, Bojana R. and Dramićanin, Miroslav and Jing, Xiping and Tang, Qiang and Shi, Jianxin and Wu, Mingmei",
year = "2019",
abstract = "Single-component white light phosphors with a broad and full color spectrum are urgently required to overcome residual problems with commercial phosphors. In this paper, we describe how Eu3+, as the dopant of Sr3ZnTa2O9 (SZT), plays an important role in structural modulation (including structural order-disorder and intrinsic oxygen defects), as demonstrated by electronic structural calculations and systematic experiments. Furthermore, D-5(0) F-7(2) emission of Eu3+ provides the red component of the emission spectrum and increases the color rendering index of SZT:Eu3+ phosphors. Consequently, the resulting phosphor SZT:10%Eu3+ shows significantly enhanced emission intensity, and its broadband emission covers the entire visible region from 400 nm to 720 nm. A fabricated LED device using a near-ultraviolet 370 nm chip coated with a single-component, the SZT:10%Eu3+ phosphor, shows warm white emission with a high color rendering index (R-a = 82).",
journal = "Journal of Materials Chemistry C",
title = "Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement",
volume = "7",
number = "9",
pages = "2596-2603",
doi = "10.1039/C9TC00159J"
}

Li, X., Milićević, B. R., Dramićanin, M., Jing, X., Tang, Q., Shi, J.,& Wu, M.. (2019). Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement. in Journal of Materials Chemistry C, 7(9), 2596-2603.
https://doi.org/10.1039/C9TC00159J

Li X, Milićević BR, Dramićanin M, Jing X, Tang Q, Shi J, Wu M. Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement. in Journal of Materials Chemistry C. 2019;7(9):2596-2603.
doi:10.1039/C9TC00159J .

Li, Xiaohui, Milićević, Bojana R., Dramićanin, Miroslav, Jing, Xiping, Tang, Qiang, Shi, Jianxin, Wu, Mingmei, "Eu3+-Activated Sr3ZnTa2O9 single-component white light phosphors: emission intensity enhancement and color rendering improvement" in Journal of Materials Chemistry C, 7, no. 9 (2019):2596-2603,
https://doi.org/10.1039/C9TC00159J . .

TY  - JOUR
AU  - Dolgov, Leonid
AU  - Hong, Junyu
AU  - Zhou, Lei
AU  - Li, Xiaohui
AU  - Li, Junhao
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
AU  - Shi, Jianxin
AU  - Wu, Mingmei
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8349
AB  - One of prospective ways for boosting efficiency of luminescent materials is their combination with noble metal nanoparticles. Collective, so-called plasmon, oscillations of surface electrons in a nanoparticle can resonantly interact with incident or fluorescent light and cause an increase in the light absorption cross section or radiative rate for an adjacent emitter. Plasmonic inorganic phosphors require gentle host crystallization at which added noble nanoparticles will not suffer from aggregation or oxidation. The prospective plasmonic Mg2TiO4:Mn4+ phosphor containing core@shell Ag@SiO2 nanoparticles is prepared here by spare low-temperature annealing of a sol-gel host precursor. It is revealed that Mn4+ luminescence nonmonotonously depends on the size and concentration of 40 and 70 nm silver nanoparticles. It is demonstrated that luminescence of the Mg2TiO4:Mn4+ phosphor can be up to a 1.5 times increase when Mn4+ excitation is supported by localized surface plasmon resonance in Ag@SiO2 nanoparticles. © 2019 American Chemical Society.
T2  - ACS Applied Materials and Interfaces
T1  - Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles
VL  - 11
IS  - 23
SP  - 21004
EP  - 21009
DO  - 10.1021/acsami.9b05781
ER  - 

@article{
author = "Dolgov, Leonid and Hong, Junyu and Zhou, Lei and Li, Xiaohui and Li, Junhao and Đorđević, Vesna R. and Dramićanin, Miroslav and Shi, Jianxin and Wu, Mingmei",
year = "2019",
abstract = "One of prospective ways for boosting efficiency of luminescent materials is their combination with noble metal nanoparticles. Collective, so-called plasmon, oscillations of surface electrons in a nanoparticle can resonantly interact with incident or fluorescent light and cause an increase in the light absorption cross section or radiative rate for an adjacent emitter. Plasmonic inorganic phosphors require gentle host crystallization at which added noble nanoparticles will not suffer from aggregation or oxidation. The prospective plasmonic Mg2TiO4:Mn4+ phosphor containing core@shell Ag@SiO2 nanoparticles is prepared here by spare low-temperature annealing of a sol-gel host precursor. It is revealed that Mn4+ luminescence nonmonotonously depends on the size and concentration of 40 and 70 nm silver nanoparticles. It is demonstrated that luminescence of the Mg2TiO4:Mn4+ phosphor can be up to a 1.5 times increase when Mn4+ excitation is supported by localized surface plasmon resonance in Ag@SiO2 nanoparticles. © 2019 American Chemical Society.",
journal = "ACS Applied Materials and Interfaces",
title = "Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles",
volume = "11",
number = "23",
pages = "21004-21009",
doi = "10.1021/acsami.9b05781"
}

Dolgov, L., Hong, J., Zhou, L., Li, X., Li, J., Đorđević, V. R., Dramićanin, M., Shi, J.,& Wu, M.. (2019). Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles. in ACS Applied Materials and Interfaces, 11(23), 21004-21009.
https://doi.org/10.1021/acsami.9b05781

Dolgov L, Hong J, Zhou L, Li X, Li J, Đorđević VR, Dramićanin M, Shi J, Wu M. Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles. in ACS Applied Materials and Interfaces. 2019;11(23):21004-21009.
doi:10.1021/acsami.9b05781 .

Dolgov, Leonid, Hong, Junyu, Zhou, Lei, Li, Xiaohui, Li, Junhao, Đorđević, Vesna R., Dramićanin, Miroslav, Shi, Jianxin, Wu, Mingmei, "Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles" in ACS Applied Materials and Interfaces, 11, no. 23 (2019):21004-21009,
https://doi.org/10.1021/acsami.9b05781 . .

TY  - JOUR
AU  - Li, Xiaohui
AU  - Zhou, Lei
AU  - Dramićanin, Miroslav
AU  - Tang, Qiang
AU  - Jing, Xiping
AU  - Shi, Jianxin
AU  - Xu, Yiqin
AU  - Wu, Mingmei
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7987
AB  - Broad emission with a full and continuous color spectrum realized by crystal engineering is extensively desired to simulate natural sunlight and improve the white color quality. Herein, new insight into the modulation of B site order-disorder and intrinsic oxygen defects for complex perovskite (A(3)BB(2)O(9)) Sr3-xScxZnNb2O9 (0 x 0.1) phosphors is demonstrated for broad-band emission via crystal engineering. We elucidate that the spectrum of Sr3ZnNb2O9 synthesized at an optimal temperature exhibits two emission bands under near-ultraviolet excitation ((ex) = 374 nm) which is readily available from near ultraviolet chips. The two broad emission bands can be ascribed to charge transfer from the empty 4d (t(2g))-orbitals of Nb5+ ions to the filled 2p-orbitals of O2- ions and the intrinsic oxygen defects. Further, as a proposed strategy to optimize the luminescence property of Sr3ZnNb2O9 (SZN), we realized A-site nonequivalent doping to induce B-site disordering and cancel the luminescence quenching which results from B site ordering. The A-site nonequivalent doping efficiently offsets intrinsic oxygen defects, as validated by systematic analyses of experiments and DFT calculations. Consequently, the novel phosphor Sr3-xScxZnNb2O9 (x = 0.1) shows a high color rendering index (R-a = 82.2) and negligible color shift. In addition, its emission intensity is enhanced by approximate to 70 times as compared to the pristine Sr3ZnNb2O9.
T2  - Journal of Materials Chemistry C
T1  - Broad-band emission of A3B′B′′2O9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder
VL  - 6
IS  - 46
SP  - 12566
EP  - 12574
DO  - 10.1039/C8TC04874F
ER  - 

@article{
author = "Li, Xiaohui and Zhou, Lei and Dramićanin, Miroslav and Tang, Qiang and Jing, Xiping and Shi, Jianxin and Xu, Yiqin and Wu, Mingmei",
year = "2018",
abstract = "Broad emission with a full and continuous color spectrum realized by crystal engineering is extensively desired to simulate natural sunlight and improve the white color quality. Herein, new insight into the modulation of B site order-disorder and intrinsic oxygen defects for complex perovskite (A(3)BB(2)O(9)) Sr3-xScxZnNb2O9 (0 x 0.1) phosphors is demonstrated for broad-band emission via crystal engineering. We elucidate that the spectrum of Sr3ZnNb2O9 synthesized at an optimal temperature exhibits two emission bands under near-ultraviolet excitation ((ex) = 374 nm) which is readily available from near ultraviolet chips. The two broad emission bands can be ascribed to charge transfer from the empty 4d (t(2g))-orbitals of Nb5+ ions to the filled 2p-orbitals of O2- ions and the intrinsic oxygen defects. Further, as a proposed strategy to optimize the luminescence property of Sr3ZnNb2O9 (SZN), we realized A-site nonequivalent doping to induce B-site disordering and cancel the luminescence quenching which results from B site ordering. The A-site nonequivalent doping efficiently offsets intrinsic oxygen defects, as validated by systematic analyses of experiments and DFT calculations. Consequently, the novel phosphor Sr3-xScxZnNb2O9 (x = 0.1) shows a high color rendering index (R-a = 82.2) and negligible color shift. In addition, its emission intensity is enhanced by approximate to 70 times as compared to the pristine Sr3ZnNb2O9.",
journal = "Journal of Materials Chemistry C",
title = "Broad-band emission of A3B′B′′2O9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder",
volume = "6",
number = "46",
pages = "12566-12574",
doi = "10.1039/C8TC04874F"
}

Li, X., Zhou, L., Dramićanin, M., Tang, Q., Jing, X., Shi, J., Xu, Y.,& Wu, M.. (2018). Broad-band emission of A3B′B′′2O9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder. in Journal of Materials Chemistry C, 6(46), 12566-12574.
https://doi.org/10.1039/C8TC04874F

Li X, Zhou L, Dramićanin M, Tang Q, Jing X, Shi J, Xu Y, Wu M. Broad-band emission of A3B′B′′2O9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder. in Journal of Materials Chemistry C. 2018;6(46):12566-12574.
doi:10.1039/C8TC04874F .

Li, Xiaohui, Zhou, Lei, Dramićanin, Miroslav, Tang, Qiang, Jing, Xiping, Shi, Jianxin, Xu, Yiqin, Wu, Mingmei, "Broad-band emission of A3B′B′′2O9 complex perovskites (A = Ba, Sr; B′ = Zn; B′′ = Ta, Nb) realized by structural variations of the B site order–disorder" in Journal of Materials Chemistry C, 6, no. 46 (2018):12566-12574,
https://doi.org/10.1039/C8TC04874F . .