Mitić, Vojislav V.

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  • Mitić, Vojislav V. (14)

Author's Bibliography

Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization

Dodevski, Vladimir; Pagnacco, Maja C.; Radović, Ivana M.; Rosić, Milena; Janković, Bojan Ž.; Stojmenović, Marija; Mitić, Vojislav V.

(2020)

TY  - JOUR
AU  - Dodevski, Vladimir
AU  - Pagnacco, Maja C.
AU  - Radović, Ivana M.
AU  - Rosić, Milena
AU  - Janković, Bojan Ž.
AU  - Stojmenović, Marija
AU  - Mitić, Vojislav V.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8817
AB  - The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.
T2  - Materials Chemistry and Physics
T1  - Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization
VL  - 245
SP  - 122768
DO  - 10.1016/j.matchemphys.2020.122768
ER  - 
@article{
author = "Dodevski, Vladimir and Pagnacco, Maja C. and Radović, Ivana M. and Rosić, Milena and Janković, Bojan Ž. and Stojmenović, Marija and Mitić, Vojislav V.",
year = "2020",
abstract = "The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.",
journal = "Materials Chemistry and Physics",
title = "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization",
volume = "245",
pages = "122768",
doi = "10.1016/j.matchemphys.2020.122768"
}
Dodevski, V., Pagnacco, M. C., Radović, I. M., Rosić, M., Janković, B. Ž., Stojmenović, M.,& Mitić, V. V.. (2020). Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics, 245, 122768.
https://doi.org/10.1016/j.matchemphys.2020.122768
Dodevski V, Pagnacco MC, Radović IM, Rosić M, Janković BŽ, Stojmenović M, Mitić VV. Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics. 2020;245:122768.
doi:10.1016/j.matchemphys.2020.122768 .
Dodevski, Vladimir, Pagnacco, Maja C., Radović, Ivana M., Rosić, Milena, Janković, Bojan Ž., Stojmenović, Marija, Mitić, Vojislav V., "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization" in Materials Chemistry and Physics, 245 (2020):122768,
https://doi.org/10.1016/j.matchemphys.2020.122768 . .
1
10
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9

The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers

Mitić, Vojislav V.; Lazović, Goran; Lu, Chun-An; Paunović, Vesna; Radović, Ivana M.; Stajčić, Aleksandar; Vlahović, Branislav

(2020)

TY  - JOUR
AU  - Mitić, Vojislav V.
AU  - Lazović, Goran
AU  - Lu, Chun-An
AU  - Paunović, Vesna
AU  - Radović, Ivana M.
AU  - Stajčić, Aleksandar
AU  - Vlahović, Branislav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9010
AB  - The BaTiO3 ceramics applications based on electronic properties have very high gradient scientific and industrial-technological interests. Our scientific research has been based on nano BaTiO3 modified with Yttrium based organometallic salt (MOD-Y). The samples have been consolidated at a sintering temperature of 1350 °C. Within the study, the new frontiers for different electronic properties between the layers of BaTiO3 grains have been introduced. The research target was grain boundary investigations and the influence on dielectric properties. After scanning electron microscopy and dielectric measurements, it has been established that modified BaTiO3 samples with larger grains showed a better compact state that led to a higher dielectric constant value. DC bias stability was also investigated and showed a connection between the grain size and capacitance stability. Analyses of functions that could approximate experimental curves were successfully employed. Practical application of fractal corrections was performed, based on surface (αs) and pore size (αp) corrections, which resulted in obtainment of the relation between the capacitance and Curie temperature. Successful introduction of fractal corrections for capacitance-Curie temperature dependence for a set of experimental data is an important step towards further miniaturization of intergranular capacitors. © 2020 by the authors.
T2  - Applied Sciences
T1  - The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers
VL  - 10
IS  - 10
SP  - 3485
DO  - 10.3390/app10103485
ER  - 
@article{
author = "Mitić, Vojislav V. and Lazović, Goran and Lu, Chun-An and Paunović, Vesna and Radović, Ivana M. and Stajčić, Aleksandar and Vlahović, Branislav",
year = "2020",
abstract = "The BaTiO3 ceramics applications based on electronic properties have very high gradient scientific and industrial-technological interests. Our scientific research has been based on nano BaTiO3 modified with Yttrium based organometallic salt (MOD-Y). The samples have been consolidated at a sintering temperature of 1350 °C. Within the study, the new frontiers for different electronic properties between the layers of BaTiO3 grains have been introduced. The research target was grain boundary investigations and the influence on dielectric properties. After scanning electron microscopy and dielectric measurements, it has been established that modified BaTiO3 samples with larger grains showed a better compact state that led to a higher dielectric constant value. DC bias stability was also investigated and showed a connection between the grain size and capacitance stability. Analyses of functions that could approximate experimental curves were successfully employed. Practical application of fractal corrections was performed, based on surface (αs) and pore size (αp) corrections, which resulted in obtainment of the relation between the capacitance and Curie temperature. Successful introduction of fractal corrections for capacitance-Curie temperature dependence for a set of experimental data is an important step towards further miniaturization of intergranular capacitors. © 2020 by the authors.",
journal = "Applied Sciences",
title = "The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers",
volume = "10",
number = "10",
pages = "3485",
doi = "10.3390/app10103485"
}
Mitić, V. V., Lazović, G., Lu, C., Paunović, V., Radović, I. M., Stajčić, A.,& Vlahović, B.. (2020). The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers. in Applied Sciences, 10(10), 3485.
https://doi.org/10.3390/app10103485
Mitić VV, Lazović G, Lu C, Paunović V, Radović IM, Stajčić A, Vlahović B. The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers. in Applied Sciences. 2020;10(10):3485.
doi:10.3390/app10103485 .
Mitić, Vojislav V., Lazović, Goran, Lu, Chun-An, Paunović, Vesna, Radović, Ivana M., Stajčić, Aleksandar, Vlahović, Branislav, "The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers" in Applied Sciences, 10, no. 10 (2020):3485,
https://doi.org/10.3390/app10103485 . .
4
1
4

Solvent effects on structural changes in self-healing epoxy composites

Radović, Ivana M.; Stajčić, Aleksandar; Radisavljević, Anđela; Veljković, Filip M.; Čebela, Maria; Mitić, Vojislav V.; Radojević, Vesna

(2020)

TY  - JOUR
AU  - Radović, Ivana M.
AU  - Stajčić, Aleksandar
AU  - Radisavljević, Anđela
AU  - Veljković, Filip M.
AU  - Čebela, Maria
AU  - Mitić, Vojislav V.
AU  - Radojević, Vesna
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9609
AB  - Nowadays, there is a very high importance of composite research and variety of their applications in the modern world. In that sense, we researched hollow glass capillaries filled with dissolved Grubbs catalyst (GC) and dicyclopentadiene (DCPD) were incorporated into a fiber-reinforced epoxy with the aim of improving the flow of healing agents to the crack site. The morphological investigation of the crack site was performed using field emission scanning electron microscopy (FESEM), showing the difference between the samples depending on the used solvent. The software analysis of sample photographs has been performed by calculating the fractured/healed surface area of the samples, revealing that approximately 20% of the volume was affected by the impact. Fourier transform infrared spectroscopy (FTIR) revealed that poly (dicyclopentadiene) (PDCPD) formed at the healed interface. However, the FTIR investigation of catalyst stability in different solvents showed structural changes in GC and partial deactivation. The mechanical tests of the samples showed that a recovery of 60% after 24 h at room temperature could be achieved through the use of a solvent and very low concentration of GC. The performed research results are a good base to develop the model for predicting the processes and morphology, with the goal to design the final mechanical and in the future, thermal, properties in advance. This opens a new direction for future research in the field of composite healing. © 2020 Elsevier B.V.
T2  - Materials Chemistry and Physics
T1  - Solvent effects on structural changes in self-healing epoxy composites
VL  - 256
DO  - 10.1016/j.matchemphys.2020.123761
ER  - 
@article{
author = "Radović, Ivana M. and Stajčić, Aleksandar and Radisavljević, Anđela and Veljković, Filip M. and Čebela, Maria and Mitić, Vojislav V. and Radojević, Vesna",
year = "2020",
abstract = "Nowadays, there is a very high importance of composite research and variety of their applications in the modern world. In that sense, we researched hollow glass capillaries filled with dissolved Grubbs catalyst (GC) and dicyclopentadiene (DCPD) were incorporated into a fiber-reinforced epoxy with the aim of improving the flow of healing agents to the crack site. The morphological investigation of the crack site was performed using field emission scanning electron microscopy (FESEM), showing the difference between the samples depending on the used solvent. The software analysis of sample photographs has been performed by calculating the fractured/healed surface area of the samples, revealing that approximately 20% of the volume was affected by the impact. Fourier transform infrared spectroscopy (FTIR) revealed that poly (dicyclopentadiene) (PDCPD) formed at the healed interface. However, the FTIR investigation of catalyst stability in different solvents showed structural changes in GC and partial deactivation. The mechanical tests of the samples showed that a recovery of 60% after 24 h at room temperature could be achieved through the use of a solvent and very low concentration of GC. The performed research results are a good base to develop the model for predicting the processes and morphology, with the goal to design the final mechanical and in the future, thermal, properties in advance. This opens a new direction for future research in the field of composite healing. © 2020 Elsevier B.V.",
journal = "Materials Chemistry and Physics",
title = "Solvent effects on structural changes in self-healing epoxy composites",
volume = "256",
doi = "10.1016/j.matchemphys.2020.123761"
}
Radović, I. M., Stajčić, A., Radisavljević, A., Veljković, F. M., Čebela, M., Mitić, V. V.,& Radojević, V.. (2020). Solvent effects on structural changes in self-healing epoxy composites. in Materials Chemistry and Physics, 256.
https://doi.org/10.1016/j.matchemphys.2020.123761
Radović IM, Stajčić A, Radisavljević A, Veljković FM, Čebela M, Mitić VV, Radojević V. Solvent effects on structural changes in self-healing epoxy composites. in Materials Chemistry and Physics. 2020;256.
doi:10.1016/j.matchemphys.2020.123761 .
Radović, Ivana M., Stajčić, Aleksandar, Radisavljević, Anđela, Veljković, Filip M., Čebela, Maria, Mitić, Vojislav V., Radojević, Vesna, "Solvent effects on structural changes in self-healing epoxy composites" in Materials Chemistry and Physics, 256 (2020),
https://doi.org/10.1016/j.matchemphys.2020.123761 . .
15
2
14

The Rare-Earths influences on doped BaTiO3-Ceramics Microstructure and Electric Characteristics

Paunović, Vesna; Mitić, Vojislav V.; Kocić, Ljubiša; Marjanović, Miloš; Đorđević, Miloš

(Belgrade : Serbian Ceramic Society, 2016)

TY  - CONF
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
AU  - Kocić, Ljubiša
AU  - Marjanović, Miloš
AU  - Đorđević, Miloš
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/875
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7549
AB  - The influence of rare-earth additive content on microstructure and electric properties of doped BaTiO3 ceramics is investigated. The concentration of Er2O3 and Yb2O3 in the doped samples range from 0.01 to 1.0at % . The samples are prepared by the conventional solid state reaction, and sintered at 1320° and 1350°C in air atmosphere for 4 hours. SEM analysis shows that all samples are characterized by polygonal grains. The uniform and homogeneous microstructure with grain size ranged from 20 to 45μm is the main low doped samples characteristics. For the samples doped with the higher dopant concentration (0.5 and 1.0 at%) the average grains size is ranged from 5 to 10μm. Dielectric measurements are carried out as a function of temperature up to 180°C at different frequencies. The low doped samples display the high value of dielectric permittivity at room temperature. A nearly flat permittivity-temperature response is obtained in specimens with higher additive content. The Curie temperature of doped samples were ranged from 126 to 130°C. The Curie constant for all series of samples decrease with increment of dopant concentration and the lowest values is mesured from samples doped with 0.01 wt% of aditive. The obtained value of γ pointed out that the specimens have almost sharp phase transition. Also, the specific electrical resistance is measured in function of temperature at the different frequencies from 100Hz to 1MHz. With increasing additives concentration, the electrical resistance decreases to the concentration of 0.5 at% and then increases.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade
T1  - The Rare-Earths influences on doped BaTiO3-Ceramics Microstructure and Electric Characteristics
SP  - 44
EP  - 44
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7549
ER  - 
@conference{
author = "Paunović, Vesna and Mitić, Vojislav V. and Kocić, Ljubiša and Marjanović, Miloš and Đorđević, Miloš",
year = "2016",
abstract = "The influence of rare-earth additive content on microstructure and electric properties of doped BaTiO3 ceramics is investigated. The concentration of Er2O3 and Yb2O3 in the doped samples range from 0.01 to 1.0at % . The samples are prepared by the conventional solid state reaction, and sintered at 1320° and 1350°C in air atmosphere for 4 hours. SEM analysis shows that all samples are characterized by polygonal grains. The uniform and homogeneous microstructure with grain size ranged from 20 to 45μm is the main low doped samples characteristics. For the samples doped with the higher dopant concentration (0.5 and 1.0 at%) the average grains size is ranged from 5 to 10μm. Dielectric measurements are carried out as a function of temperature up to 180°C at different frequencies. The low doped samples display the high value of dielectric permittivity at room temperature. A nearly flat permittivity-temperature response is obtained in specimens with higher additive content. The Curie temperature of doped samples were ranged from 126 to 130°C. The Curie constant for all series of samples decrease with increment of dopant concentration and the lowest values is mesured from samples doped with 0.01 wt% of aditive. The obtained value of γ pointed out that the specimens have almost sharp phase transition. Also, the specific electrical resistance is measured in function of temperature at the different frequencies from 100Hz to 1MHz. With increasing additives concentration, the electrical resistance decreases to the concentration of 0.5 at% and then increases.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade",
title = "The Rare-Earths influences on doped BaTiO3-Ceramics Microstructure and Electric Characteristics",
pages = "44-44",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7549"
}
Paunović, V., Mitić, V. V., Kocić, L., Marjanović, M.,& Đorđević, M.. (2016). The Rare-Earths influences on doped BaTiO3-Ceramics Microstructure and Electric Characteristics. in Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade
Belgrade : Serbian Ceramic Society., 44-44.
https://hdl.handle.net/21.15107/rcub_vinar_7549
Paunović V, Mitić VV, Kocić L, Marjanović M, Đorđević M. The Rare-Earths influences on doped BaTiO3-Ceramics Microstructure and Electric Characteristics. in Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade. 2016;:44-44.
https://hdl.handle.net/21.15107/rcub_vinar_7549 .
Paunović, Vesna, Mitić, Vojislav V., Kocić, Ljubiša, Marjanović, Miloš, Đorđević, Miloš, "The Rare-Earths influences on doped BaTiO3-Ceramics Microstructure and Electric Characteristics" in Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade (2016):44-44,
https://hdl.handle.net/21.15107/rcub_vinar_7549 .

Chemical Analysis of Mortars of Archeological Samples form Mediana

Stanković, Maja; Krstić, Nenad S.; Đorđević, Dragan; Đorđević, Miloš; Topličić Ćurčić, Gordana; Mitić, Vojislav V.

(Belgrade : Serbian Ceramic Society, 2016)

TY  - CONF
AU  - Stanković, Maja
AU  - Krstić, Nenad S.
AU  - Đorđević, Dragan
AU  - Đorđević, Miloš
AU  - Topličić Ćurčić, Gordana
AU  - Mitić, Vojislav V.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/878
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7550
AB  - The aim of this study was mineralogical and chemical analysis of mortar from the floor, ceiling and wall of Stibadium B, from the archaeological site of Mediana. ICP-OES and FTIR-spectroscopy were used to determine chemical composition and some major mineralogical species. The obtained results show that lime mortar is probably used. Large contribution of silicon- and aluminum-oxides, indicate the presence of quartz and clay minerals derived from the aggregate, river sand and crushed bricks. The obtained results also show large amount of iron, manganese and copper. The determinated metals in samples from floor and wall of Stibadium B, are mostly present in oxide fraction, while in sample from ceiling, they are mostly found in silicate fraction.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade
T1  - Chemical Analysis of Mortars of Archeological Samples form Mediana
SP  - 80
EP  - 80
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7550
ER  - 
@conference{
author = "Stanković, Maja and Krstić, Nenad S. and Đorđević, Dragan and Đorđević, Miloš and Topličić Ćurčić, Gordana and Mitić, Vojislav V.",
year = "2016",
abstract = "The aim of this study was mineralogical and chemical analysis of mortar from the floor, ceiling and wall of Stibadium B, from the archaeological site of Mediana. ICP-OES and FTIR-spectroscopy were used to determine chemical composition and some major mineralogical species. The obtained results show that lime mortar is probably used. Large contribution of silicon- and aluminum-oxides, indicate the presence of quartz and clay minerals derived from the aggregate, river sand and crushed bricks. The obtained results also show large amount of iron, manganese and copper. The determinated metals in samples from floor and wall of Stibadium B, are mostly present in oxide fraction, while in sample from ceiling, they are mostly found in silicate fraction.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade",
title = "Chemical Analysis of Mortars of Archeological Samples form Mediana",
pages = "80-80",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7550"
}
Stanković, M., Krstić, N. S., Đorđević, D., Đorđević, M., Topličić Ćurčić, G.,& Mitić, V. V.. (2016). Chemical Analysis of Mortars of Archeological Samples form Mediana. in Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade
Belgrade : Serbian Ceramic Society., 80-80.
https://hdl.handle.net/21.15107/rcub_vinar_7550
Stanković M, Krstić NS, Đorđević D, Đorđević M, Topličić Ćurčić G, Mitić VV. Chemical Analysis of Mortars of Archeological Samples form Mediana. in Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade. 2016;:80-80.
https://hdl.handle.net/21.15107/rcub_vinar_7550 .
Stanković, Maja, Krstić, Nenad S., Đorđević, Dragan, Đorđević, Miloš, Topličić Ćurčić, Gordana, Mitić, Vojislav V., "Chemical Analysis of Mortars of Archeological Samples form Mediana" in Advanced Ceramics and Application : 5th Serbian Ceramic Society Conference : program and the book of abstracts; September 21-23, 2016; Belgrade (2016):80-80,
https://hdl.handle.net/21.15107/rcub_vinar_7550 .

Influence of Sm2O3 on the Microstructure and Dielectric Characteristics of Codoped BaTiO3 Ceramics

Paunović, Vesna; Mitić, Vojislav V.; Živković, Ljiljana; Kocić, Ljubiša

(Belgrade : Serbian Ceramic Society, 2014)

TY  - CONF
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
AU  - Živković, Ljiljana
AU  - Kocić, Ljubiša
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/595
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7488
AB  - The samples of Sm/Mn codoped BaTiO3 ceramics, prepared by conventional solid state procedure with dopant concentrations ranged from 0.1 up to 5.0 at%, were investigated in this paper. The specimens were sintered at 1290°C and 1350°C in an air atmosphere for two hours. The low doped samples demonstrated the mainly uniform and homogeneous microstructure with average grain sizes ranged from 0.3 μm to 5.0 μm. The appearances of secondary abnormal grains in fine grain matrix and core-shell structure were observed in highly doped Sm/BaTiO3 sintered at 1350°C. Dielectric measurements were carried out as a function of temperature up to 200°C. The low doped samples, sintered at 1350°C, display the high value of dielectric permittivity (εr=6800 ) at room temperature. A nearly flat permittivity-response was obtained in specimens with 5.0 at% additive content. Using a modified Curie-Weiss low the Curie-like constant C´ and a critical exponent γ were calculated. The obtained values of γ pointed out the diffuse phase transformation in heavily doped BaTiO3 samples.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade
T1  - Influence of Sm2O3 on the Microstructure and Dielectric Characteristics of Codoped BaTiO3 Ceramics
SP  - 62
EP  - 62
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7488
ER  - 
@conference{
author = "Paunović, Vesna and Mitić, Vojislav V. and Živković, Ljiljana and Kocić, Ljubiša",
year = "2014",
abstract = "The samples of Sm/Mn codoped BaTiO3 ceramics, prepared by conventional solid state procedure with dopant concentrations ranged from 0.1 up to 5.0 at%, were investigated in this paper. The specimens were sintered at 1290°C and 1350°C in an air atmosphere for two hours. The low doped samples demonstrated the mainly uniform and homogeneous microstructure with average grain sizes ranged from 0.3 μm to 5.0 μm. The appearances of secondary abnormal grains in fine grain matrix and core-shell structure were observed in highly doped Sm/BaTiO3 sintered at 1350°C. Dielectric measurements were carried out as a function of temperature up to 200°C. The low doped samples, sintered at 1350°C, display the high value of dielectric permittivity (εr=6800 ) at room temperature. A nearly flat permittivity-response was obtained in specimens with 5.0 at% additive content. Using a modified Curie-Weiss low the Curie-like constant C´ and a critical exponent γ were calculated. The obtained values of γ pointed out the diffuse phase transformation in heavily doped BaTiO3 samples.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade",
title = "Influence of Sm2O3 on the Microstructure and Dielectric Characteristics of Codoped BaTiO3 Ceramics",
pages = "62-62",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7488"
}
Paunović, V., Mitić, V. V., Živković, L.,& Kocić, L.. (2014). Influence of Sm2O3 on the Microstructure and Dielectric Characteristics of Codoped BaTiO3 Ceramics. in Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade
Belgrade : Serbian Ceramic Society., 62-62.
https://hdl.handle.net/21.15107/rcub_vinar_7488
Paunović V, Mitić VV, Živković L, Kocić L. Influence of Sm2O3 on the Microstructure and Dielectric Characteristics of Codoped BaTiO3 Ceramics. in Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade. 2014;:62-62.
https://hdl.handle.net/21.15107/rcub_vinar_7488 .
Paunović, Vesna, Mitić, Vojislav V., Živković, Ljiljana, Kocić, Ljubiša, "Influence of Sm2O3 on the Microstructure and Dielectric Characteristics of Codoped BaTiO3 Ceramics" in Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade (2014):62-62,
https://hdl.handle.net/21.15107/rcub_vinar_7488 .

Microstructure and dielectric properties of Dy/Mn doped BaTiO3 ceramics

Paunović, Vesna; Mitić, Vojislav V.; Prijić, Z.; Živković, Ljiljana

(Elsevier, 2014)

TY  - JOUR
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
AU  - Prijić, Z.
AU  - Živković, Ljiljana
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/563
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7479
AB  - Dy/Mn doped BaTiO3 with different Dy2O3 contents, ranging from 0.1 to 5.0 at% Dy, were investigated regarding their microstructural and dielectric characteristics. The content of 0.05 at% Mn was constant in all the investigated samples. The samples were prepared by the conventional solid state reaction and sintered at 1290°, and 1350 °C in air atmosphere for 2 h. The low doped samples (0.1 and 0.5 at% Dy) exhibit mainly fairly uniform and homogeneous microstructure with average grain sizes ranged from 0.3 μm to 3.0 μm. At 1350 °C, the appearance of secondary, abnormal, grains in the fine grain matrix and core–shell structure were observed in highly doped Dy/BaTiO3. Dielectric measurements were carried out as a function of temperature up to 180 °C. The low doped samples sintered at 1350 °C, display the high value of dielectric permittivity at room temperature, 5600 for 0.1Dy/BaTiO3. A nearly flat permittivity–temperature response was obtained in specimens with 2.0 and 5.0 at% additive content. Using a Curie–Weiss and modified Curie–Weiss low, the Curie constant (C), Curie like constant (C′), Curie temperature (TC) and a critical exponent (γ) were calculated. The obtained values of γ pointed out the diffuse phase transformation in highly doped BaTiO3 samples.
PB  - Elsevier
T2  - Ceramics International
T1  - Microstructure and dielectric properties of Dy/Mn doped BaTiO3 ceramics
SP  - 4277
EP  - 4284
DO  - 10.1016/j.ceramint.2013.08.092
ER  - 
@article{
author = "Paunović, Vesna and Mitić, Vojislav V. and Prijić, Z. and Živković, Ljiljana",
year = "2014",
abstract = "Dy/Mn doped BaTiO3 with different Dy2O3 contents, ranging from 0.1 to 5.0 at% Dy, were investigated regarding their microstructural and dielectric characteristics. The content of 0.05 at% Mn was constant in all the investigated samples. The samples were prepared by the conventional solid state reaction and sintered at 1290°, and 1350 °C in air atmosphere for 2 h. The low doped samples (0.1 and 0.5 at% Dy) exhibit mainly fairly uniform and homogeneous microstructure with average grain sizes ranged from 0.3 μm to 3.0 μm. At 1350 °C, the appearance of secondary, abnormal, grains in the fine grain matrix and core–shell structure were observed in highly doped Dy/BaTiO3. Dielectric measurements were carried out as a function of temperature up to 180 °C. The low doped samples sintered at 1350 °C, display the high value of dielectric permittivity at room temperature, 5600 for 0.1Dy/BaTiO3. A nearly flat permittivity–temperature response was obtained in specimens with 2.0 and 5.0 at% additive content. Using a Curie–Weiss and modified Curie–Weiss low, the Curie constant (C), Curie like constant (C′), Curie temperature (TC) and a critical exponent (γ) were calculated. The obtained values of γ pointed out the diffuse phase transformation in highly doped BaTiO3 samples.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Microstructure and dielectric properties of Dy/Mn doped BaTiO3 ceramics",
pages = "4277-4284",
doi = "10.1016/j.ceramint.2013.08.092"
}
Paunović, V., Mitić, V. V., Prijić, Z.,& Živković, L.. (2014). Microstructure and dielectric properties of Dy/Mn doped BaTiO3 ceramics. in Ceramics International
Elsevier., 4277-4284.
https://doi.org/10.1016/j.ceramint.2013.08.092
Paunović V, Mitić VV, Prijić Z, Živković L. Microstructure and dielectric properties of Dy/Mn doped BaTiO3 ceramics. in Ceramics International. 2014;:4277-4284.
doi:10.1016/j.ceramint.2013.08.092 .
Paunović, Vesna, Mitić, Vojislav V., Prijić, Z., Živković, Ljiljana, "Microstructure and dielectric properties of Dy/Mn doped BaTiO3 ceramics" in Ceramics International (2014):4277-4284,
https://doi.org/10.1016/j.ceramint.2013.08.092 . .
34
29
35

The Electrical Characteristics of Nb doped BaTiO3 Ceramics

Marjanović, Miloš; Đorđević, Miloš; Paunović, Vesna; Mitić, Vojislav V.

(Belgrade : Serbian Ceramic Society, 2014)

TY  - CONF
AU  - Marjanović, Miloš
AU  - Đorđević, Miloš
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/609
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7490
AB  - The Nb doped BaTiO3 ceramics, with different Nb2O5 content, ranging from 0.5 to 2.0 at% Nb, were investigated regarding their electrical characteristics in this paper. Nb/BaTiO3 ceramics using in this investigation were prepared by the conventional solid state reaction and sintered at 1320°C in an air atmosphere for 2 hours. The dielectric characteristic of doped BaTiO3 ceramics like as dielectric constant, dissipation factor, impedance (resistance, reactance) have been done by using LCR-Meter Agilent 4284A in the frequency range 20 Hz-1 MHz and Agilent E4991A RF Impedance/Material Analyzer for high frequency measurements (1 MHz – 3 GHz). Dielectric constant and tangent losses after initial large values remains nearly independent of frequency greater than 3 kHz. Dielectric measurements were carried out as a function of temperature up to 180°C. The low doped samples sintered at 1320°C, display the high value of dielectric permittivity at room temperature, 2600 for 0.5Nb/BaTiO3. A nearly flat permittivity-temperature response was obtained in specimens with 2.0 at% additive content. The Curie-Weiss and modified Curie-Weiss law is used to clarify the influence of dopant on the dielectric properties and BaTiO3 phase transformation. All investigated samples have an electrical resistivity ρ >105 Ωcm at room temperature.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade
T1  - The Electrical Characteristics of Nb doped BaTiO3 Ceramics
SP  - 105
EP  - 105
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7490
ER  - 
@conference{
author = "Marjanović, Miloš and Đorđević, Miloš and Paunović, Vesna and Mitić, Vojislav V.",
year = "2014",
abstract = "The Nb doped BaTiO3 ceramics, with different Nb2O5 content, ranging from 0.5 to 2.0 at% Nb, were investigated regarding their electrical characteristics in this paper. Nb/BaTiO3 ceramics using in this investigation were prepared by the conventional solid state reaction and sintered at 1320°C in an air atmosphere for 2 hours. The dielectric characteristic of doped BaTiO3 ceramics like as dielectric constant, dissipation factor, impedance (resistance, reactance) have been done by using LCR-Meter Agilent 4284A in the frequency range 20 Hz-1 MHz and Agilent E4991A RF Impedance/Material Analyzer for high frequency measurements (1 MHz – 3 GHz). Dielectric constant and tangent losses after initial large values remains nearly independent of frequency greater than 3 kHz. Dielectric measurements were carried out as a function of temperature up to 180°C. The low doped samples sintered at 1320°C, display the high value of dielectric permittivity at room temperature, 2600 for 0.5Nb/BaTiO3. A nearly flat permittivity-temperature response was obtained in specimens with 2.0 at% additive content. The Curie-Weiss and modified Curie-Weiss law is used to clarify the influence of dopant on the dielectric properties and BaTiO3 phase transformation. All investigated samples have an electrical resistivity ρ >105 Ωcm at room temperature.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade",
title = "The Electrical Characteristics of Nb doped BaTiO3 Ceramics",
pages = "105-105",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7490"
}
Marjanović, M., Đorđević, M., Paunović, V.,& Mitić, V. V.. (2014). The Electrical Characteristics of Nb doped BaTiO3 Ceramics. in Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade
Belgrade : Serbian Ceramic Society., 105-105.
https://hdl.handle.net/21.15107/rcub_vinar_7490
Marjanović M, Đorđević M, Paunović V, Mitić VV. The Electrical Characteristics of Nb doped BaTiO3 Ceramics. in Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade. 2014;:105-105.
https://hdl.handle.net/21.15107/rcub_vinar_7490 .
Marjanović, Miloš, Đorđević, Miloš, Paunović, Vesna, Mitić, Vojislav V., "The Electrical Characteristics of Nb doped BaTiO3 Ceramics" in Advanced Ceramics and Application : 3rd Serbian Ceramic Society Conference : program and the book of abstracts; September 29 - October 1, 2014; Belgrade (2014):105-105,
https://hdl.handle.net/21.15107/rcub_vinar_7490 .

Microstructure evolution and phase transition in Er doped BaTiO3 ceramics

Paunović, Vesna; Mitić, Vojislav V.; Miljković, Miroslav; Živković, Ljiljana

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
AU  - Miljković, Miroslav
AU  - Živković, Ljiljana
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/412
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7425
AB  - The Er doped BaTiO3 ceramics, with different Er2O3 content, ranging from 0.01 to 1.0 wt% Er, were investigated regarding their microstructural and dielectric characteristics in this paper. Doped BaTiO3 were prepared by using conventional method of solid state sintering at 1380 °C for four hours. SEM analysis of Er/BaTiO3 doped ceramics showed that in samples doped with a rareearth ions low level, the grain size ranged from 20-40 μm, while with the higher dopant concentration the abnormal grain growth is inhibited and the grain size ranged between 2-10μm. Dielectric measurements were carried out as a function of temperature up to180°C at different frequencies. The low doped samples sintered at 1380 °C, display the high value of dielectric permittivity at room temperature, 2160 for 0.01 Er/BaTiO3. A nearly flat permittivity-response was obtained in specimens with higher additive content. Using a Curie-Weiss low and modified Curie-Weiss low the Curie constant C, Curie temperature Tc and a critical exponent of nonlinearity γ were calculated. The Curie temperature of doped samples were ranged from 126 to 130 °C. The Curie constant for all series of samples decrease with increase of dopant concentration and the lowest values were mesured from samples doped with 0.01 wt% of aditive. The obtained value of γ pointed out that the specimens have almost sharp phase transition.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade
T1  - Microstructure evolution and phase transition in Er doped BaTiO3 ceramics
SP  - 20
EP  - 20
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7425
ER  - 
@conference{
author = "Paunović, Vesna and Mitić, Vojislav V. and Miljković, Miroslav and Živković, Ljiljana",
year = "2013",
abstract = "The Er doped BaTiO3 ceramics, with different Er2O3 content, ranging from 0.01 to 1.0 wt% Er, were investigated regarding their microstructural and dielectric characteristics in this paper. Doped BaTiO3 were prepared by using conventional method of solid state sintering at 1380 °C for four hours. SEM analysis of Er/BaTiO3 doped ceramics showed that in samples doped with a rareearth ions low level, the grain size ranged from 20-40 μm, while with the higher dopant concentration the abnormal grain growth is inhibited and the grain size ranged between 2-10μm. Dielectric measurements were carried out as a function of temperature up to180°C at different frequencies. The low doped samples sintered at 1380 °C, display the high value of dielectric permittivity at room temperature, 2160 for 0.01 Er/BaTiO3. A nearly flat permittivity-response was obtained in specimens with higher additive content. Using a Curie-Weiss low and modified Curie-Weiss low the Curie constant C, Curie temperature Tc and a critical exponent of nonlinearity γ were calculated. The Curie temperature of doped samples were ranged from 126 to 130 °C. The Curie constant for all series of samples decrease with increase of dopant concentration and the lowest values were mesured from samples doped with 0.01 wt% of aditive. The obtained value of γ pointed out that the specimens have almost sharp phase transition.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade",
title = "Microstructure evolution and phase transition in Er doped BaTiO3 ceramics",
pages = "20-20",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7425"
}
Paunović, V., Mitić, V. V., Miljković, M.,& Živković, L.. (2013). Microstructure evolution and phase transition in Er doped BaTiO3 ceramics. in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade
Belgrade : Serbian Ceramic Society., 20-20.
https://hdl.handle.net/21.15107/rcub_vinar_7425
Paunović V, Mitić VV, Miljković M, Živković L. Microstructure evolution and phase transition in Er doped BaTiO3 ceramics. in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade. 2013;:20-20.
https://hdl.handle.net/21.15107/rcub_vinar_7425 .
Paunović, Vesna, Mitić, Vojislav V., Miljković, Miroslav, Živković, Ljiljana, "Microstructure evolution and phase transition in Er doped BaTiO3 ceramics" in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade (2013):20-20,
https://hdl.handle.net/21.15107/rcub_vinar_7425 .

Dielectric characterization of microalloyed alumo-silicate ceramics by using linear regression model

Purenović, Jelena M.; Mitić, Vojislav V.; Ranđelović, Marjan S.; Matović, Branko; Purenović, Milovan M.

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Purenović, Jelena M.
AU  - Mitić, Vojislav V.
AU  - Ranđelović, Marjan S.
AU  - Matović, Branko
AU  - Purenović, Milovan M.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/420
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7430
AB  - In this paper, dielectric characterization of porous alumo-silicate ceramics, modified by alloying with magnesium and microalloying with aluminum, was investigated. Microstructure investigations have revealed non-uniform and highly porous structure with broad distribution of grain size, specifically shaped grains and high degree of agglomeration. Complex multiphase system, as active microalloyed ceramics, has specific behavior under external electrical field influence. Dielectric properties (the changes of permittivity, electrical resistivity, dielectric losses and impedance) were measured in the frequency range 20 Hz – 1 MHz. All characteristics showed nonlinear distribution and complex functional dependences because of significant nonhomogeneity of active microalloyed ceramics. Values for permittivity ranged between 140 – 430. Order of magnitude for electrical resistivity was about 106 Ωm, for impedance 104 – 108 Ω, and loss tangent had values much greater than 0.05. Mathematical model of linear regression was applied on the dielectric characterization results. Consistency with experimental data was approved, since the values for correlation coefficient r and determination coefficient r2 were obtained near value 1.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade
T1  - Dielectric characterization of microalloyed alumo-silicate ceramics by using linear regression model
SP  - 42
EP  - 42
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7430
ER  - 
@conference{
author = "Purenović, Jelena M. and Mitić, Vojislav V. and Ranđelović, Marjan S. and Matović, Branko and Purenović, Milovan M.",
year = "2013",
abstract = "In this paper, dielectric characterization of porous alumo-silicate ceramics, modified by alloying with magnesium and microalloying with aluminum, was investigated. Microstructure investigations have revealed non-uniform and highly porous structure with broad distribution of grain size, specifically shaped grains and high degree of agglomeration. Complex multiphase system, as active microalloyed ceramics, has specific behavior under external electrical field influence. Dielectric properties (the changes of permittivity, electrical resistivity, dielectric losses and impedance) were measured in the frequency range 20 Hz – 1 MHz. All characteristics showed nonlinear distribution and complex functional dependences because of significant nonhomogeneity of active microalloyed ceramics. Values for permittivity ranged between 140 – 430. Order of magnitude for electrical resistivity was about 106 Ωm, for impedance 104 – 108 Ω, and loss tangent had values much greater than 0.05. Mathematical model of linear regression was applied on the dielectric characterization results. Consistency with experimental data was approved, since the values for correlation coefficient r and determination coefficient r2 were obtained near value 1.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade",
title = "Dielectric characterization of microalloyed alumo-silicate ceramics by using linear regression model",
pages = "42-42",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7430"
}
Purenović, J. M., Mitić, V. V., Ranđelović, M. S., Matović, B.,& Purenović, M. M.. (2013). Dielectric characterization of microalloyed alumo-silicate ceramics by using linear regression model. in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade
Belgrade : Serbian Ceramic Society., 42-42.
https://hdl.handle.net/21.15107/rcub_vinar_7430
Purenović JM, Mitić VV, Ranđelović MS, Matović B, Purenović MM. Dielectric characterization of microalloyed alumo-silicate ceramics by using linear regression model. in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade. 2013;:42-42.
https://hdl.handle.net/21.15107/rcub_vinar_7430 .
Purenović, Jelena M., Mitić, Vojislav V., Ranđelović, Marjan S., Matović, Branko, Purenović, Milovan M., "Dielectric characterization of microalloyed alumo-silicate ceramics by using linear regression model" in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade (2013):42-42,
https://hdl.handle.net/21.15107/rcub_vinar_7430 .

Application of Minkowski layer for microalloyed alumo-silicate ceramics grains fractal analysis

Purenović, Jelena M.; Mitić, Vojislav V.; Kocić, Ljubiša; Ranđelović, Marjan S.; Matović, Branko; Purenović, Milovan M.

(Belgrade : Serbian Ceramic Society, 2013)

TY  - CONF
AU  - Purenović, Jelena M.
AU  - Mitić, Vojislav V.
AU  - Kocić, Ljubiša
AU  - Ranđelović, Marjan S.
AU  - Matović, Branko
AU  - Purenović, Milovan M.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/421
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7431
AB  - Porous aluminium-silicate ceramics, modified by alloying with magnesium and microalloying with alluminium belongs to a group of advanced multifunctional ceramics materials. This multiphase solid-solid system has predominantly amorphous microstructure and micro morphology. Intergranular and interphase areas are very complex, because they represent areas, where numbered processes and interactions take place, making new boundaries and regions with fractal nature. Solid contact between grains is actually very complex configuration of microcontacts with fractal nature. Fractal analysis of intergranular microstructure has included application of Minkowski layer. This layer is in correlation with fractal dimension, and defines grains contact probability. It represents convex layer of grains contour roughness and irregularity. Considering the fractal nature of intergranular contacts, it is possible to establish correlation between material electrical properties and fractal analysis, as a tool for future correlation with microstructure characterization.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade
T1  - Application of Minkowski layer for microalloyed alumo-silicate ceramics grains fractal analysis
SP  - 43
EP  - 43
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7431
ER  - 
@conference{
author = "Purenović, Jelena M. and Mitić, Vojislav V. and Kocić, Ljubiša and Ranđelović, Marjan S. and Matović, Branko and Purenović, Milovan M.",
year = "2013",
abstract = "Porous aluminium-silicate ceramics, modified by alloying with magnesium and microalloying with alluminium belongs to a group of advanced multifunctional ceramics materials. This multiphase solid-solid system has predominantly amorphous microstructure and micro morphology. Intergranular and interphase areas are very complex, because they represent areas, where numbered processes and interactions take place, making new boundaries and regions with fractal nature. Solid contact between grains is actually very complex configuration of microcontacts with fractal nature. Fractal analysis of intergranular microstructure has included application of Minkowski layer. This layer is in correlation with fractal dimension, and defines grains contact probability. It represents convex layer of grains contour roughness and irregularity. Considering the fractal nature of intergranular contacts, it is possible to establish correlation between material electrical properties and fractal analysis, as a tool for future correlation with microstructure characterization.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade",
title = "Application of Minkowski layer for microalloyed alumo-silicate ceramics grains fractal analysis",
pages = "43-43",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7431"
}
Purenović, J. M., Mitić, V. V., Kocić, L., Ranđelović, M. S., Matović, B.,& Purenović, M. M.. (2013). Application of Minkowski layer for microalloyed alumo-silicate ceramics grains fractal analysis. in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade
Belgrade : Serbian Ceramic Society., 43-43.
https://hdl.handle.net/21.15107/rcub_vinar_7431
Purenović JM, Mitić VV, Kocić L, Ranđelović MS, Matović B, Purenović MM. Application of Minkowski layer for microalloyed alumo-silicate ceramics grains fractal analysis. in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade. 2013;:43-43.
https://hdl.handle.net/21.15107/rcub_vinar_7431 .
Purenović, Jelena M., Mitić, Vojislav V., Kocić, Ljubiša, Ranđelović, Marjan S., Matović, Branko, Purenović, Milovan M., "Application of Minkowski layer for microalloyed alumo-silicate ceramics grains fractal analysis" in Advanced Ceramics and Application : 2nd Serbian Ceramic Society Conference : program and the book of abstracts; September 30 - October 1, 2013; Belgrade (2013):43-43,
https://hdl.handle.net/21.15107/rcub_vinar_7431 .

Ho2O3 Additive Effects on Microstructure and Dielectrical Properties of BaTiO3 Ceramics

Paunović, Vesna; Mitić, Vojislav V.; Živković, Ljiljana; Miljković, Miroslav

(Belgrade : Serbian Ceramic Society, 2012)

TY  - CONF
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
AU  - Živković, Ljiljana
AU  - Miljković, Miroslav
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/526
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7469
AB  - Doped BaTiO3-ceramics is very interesting for its application as resistors with PTCR, multilayer ceramics capacitors, thermal sensors etc. Ho doped BaTiO3 ceramics, with different Ho2O3 content, ranging from 0.01 to 1.0 wt% Ho, were investigated regarding their microstructural and dielectric characteristics. The samples were prepared by the conventional solid state reaction and sintered at 1320°, 1350 °C and 1380°C in an air atmosphere for 4 hours. The grain size and microstructure characteristics for various samples and their phase composition were carried out using a scanning electron microscope SEM equipped with EDS system. SEM analysis of Ho/BaTiO3 doped ceramics showed that in samples doped with a low level of rare-earth ions, the grain size ranged from 10-40mm, while with the higher dopant concentration the abnormal grain growth is inhibited and the grain size ranged between 2-10μm. Dielectric measurements were carried out as a function of temperature up to180°C. The low doped samples sintered at 1380°C, display the high value of dielectric permittivity at room temperature, 2500 for 0.01Ho/BaTiO3. A nearly flat permittivity-response was obtained in specimens with higher additive content. Using a modified Curie-Weiss low the Curie constant (C/) and a critical exponent γ were calculated. The obtained values of γ pointed out the diffuse phase transformation in heavily doped BaTiO3 samples.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 1st Serbian Ceramic Society Conference : program and the book of abstracts; May 10-11, 2012; Belgrade
T1  - Ho2O3 Additive Effects on Microstructure and Dielectrical Properties of BaTiO3 Ceramics
SP  - 10
EP  - 10
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7469
ER  - 
@conference{
author = "Paunović, Vesna and Mitić, Vojislav V. and Živković, Ljiljana and Miljković, Miroslav",
year = "2012",
abstract = "Doped BaTiO3-ceramics is very interesting for its application as resistors with PTCR, multilayer ceramics capacitors, thermal sensors etc. Ho doped BaTiO3 ceramics, with different Ho2O3 content, ranging from 0.01 to 1.0 wt% Ho, were investigated regarding their microstructural and dielectric characteristics. The samples were prepared by the conventional solid state reaction and sintered at 1320°, 1350 °C and 1380°C in an air atmosphere for 4 hours. The grain size and microstructure characteristics for various samples and their phase composition were carried out using a scanning electron microscope SEM equipped with EDS system. SEM analysis of Ho/BaTiO3 doped ceramics showed that in samples doped with a low level of rare-earth ions, the grain size ranged from 10-40mm, while with the higher dopant concentration the abnormal grain growth is inhibited and the grain size ranged between 2-10μm. Dielectric measurements were carried out as a function of temperature up to180°C. The low doped samples sintered at 1380°C, display the high value of dielectric permittivity at room temperature, 2500 for 0.01Ho/BaTiO3. A nearly flat permittivity-response was obtained in specimens with higher additive content. Using a modified Curie-Weiss low the Curie constant (C/) and a critical exponent γ were calculated. The obtained values of γ pointed out the diffuse phase transformation in heavily doped BaTiO3 samples.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 1st Serbian Ceramic Society Conference : program and the book of abstracts; May 10-11, 2012; Belgrade",
title = "Ho2O3 Additive Effects on Microstructure and Dielectrical Properties of BaTiO3 Ceramics",
pages = "10-10",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7469"
}
Paunović, V., Mitić, V. V., Živković, L.,& Miljković, M.. (2012). Ho2O3 Additive Effects on Microstructure and Dielectrical Properties of BaTiO3 Ceramics. in Advanced Ceramics and Application : 1st Serbian Ceramic Society Conference : program and the book of abstracts; May 10-11, 2012; Belgrade
Belgrade : Serbian Ceramic Society., 10-10.
https://hdl.handle.net/21.15107/rcub_vinar_7469
Paunović V, Mitić VV, Živković L, Miljković M. Ho2O3 Additive Effects on Microstructure and Dielectrical Properties of BaTiO3 Ceramics. in Advanced Ceramics and Application : 1st Serbian Ceramic Society Conference : program and the book of abstracts; May 10-11, 2012; Belgrade. 2012;:10-10.
https://hdl.handle.net/21.15107/rcub_vinar_7469 .
Paunović, Vesna, Mitić, Vojislav V., Živković, Ljiljana, Miljković, Miroslav, "Ho2O3 Additive Effects on Microstructure and Dielectrical Properties of BaTiO3 Ceramics" in Advanced Ceramics and Application : 1st Serbian Ceramic Society Conference : program and the book of abstracts; May 10-11, 2012; Belgrade (2012):10-10,
https://hdl.handle.net/21.15107/rcub_vinar_7469 .

Ho2O3 Additive Effects on BaTiO3 Ceramics Microstructure and Dielectric Properties

Paunović, Vesna; Mitić, Vojislav V.; Miljković, Miroslav; Pavlović, Vera P.; Živković, Ljiljana

(Belgrade : International Institute for the Science of Sintering, 2012)

TY  - JOUR
AU  - Paunović, Vesna
AU  - Mitić, Vojislav V.
AU  - Miljković, Miroslav
AU  - Pavlović, Vera P.
AU  - Živković, Ljiljana
PY  - 2012
UR  - http://dais.sanu.ac.rs/123456789/194
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7364
AB  - Doped BaTiO 3-ceramics is very interesting for their application as PTCR resistors, multilayer ceramic capacitors, thermal sensors etc. Ho doped BaTiO 3 ceramics, with different Ho 2O 3 content, ranging from 0.01 to 1.0 wt% Ho, were investigated regarding their microstructural and dielectric characteristics. The samples were prepared by the conventional solid state reaction and sintered at 1320° and 1380°C in an air atmosphere for 4 hours. The grain size and microstructure characteristics for various samples and their phase composition was carried out using a scanning electron microscope (SEM) equipped with EDS system. SEM analysis of Ho/BaTiO 3 doped ceramics showed that in samples doped with a rare-earth ions low level, the grain size ranged from 20-30μμm, while with the higher dopant concentration the abnormal grain growth is inhibited and the grain size ranged between 2-10μμm. Dielectric measurements were carried out as a function of temperature up to180 °C. The low doped samples sintered at 1380 °C, display the high value of dielectric permittivity at room temperature, 2400 for 0.01 Ho/BaTiO 3. A nearly flat permittivity-response was obtained in specimens with higher additive content. Using a Curie-Weiss low and modified CurieWeiss low the Curie constant (C), Curie temperature (Tc) and a critical exponent of nonlinearity (γ) were calculated. The obtained value of γ pointed out that the specimens have almost sharp phase transition.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Ho2O3 Additive Effects on BaTiO3 Ceramics Microstructure and Dielectric Properties
SP  - 223
EP  - 233
DO  - 10.2298/SOS1202223P
ER  - 
@article{
author = "Paunović, Vesna and Mitić, Vojislav V. and Miljković, Miroslav and Pavlović, Vera P. and Živković, Ljiljana",
year = "2012",
abstract = "Doped BaTiO 3-ceramics is very interesting for their application as PTCR resistors, multilayer ceramic capacitors, thermal sensors etc. Ho doped BaTiO 3 ceramics, with different Ho 2O 3 content, ranging from 0.01 to 1.0 wt% Ho, were investigated regarding their microstructural and dielectric characteristics. The samples were prepared by the conventional solid state reaction and sintered at 1320° and 1380°C in an air atmosphere for 4 hours. The grain size and microstructure characteristics for various samples and their phase composition was carried out using a scanning electron microscope (SEM) equipped with EDS system. SEM analysis of Ho/BaTiO 3 doped ceramics showed that in samples doped with a rare-earth ions low level, the grain size ranged from 20-30μμm, while with the higher dopant concentration the abnormal grain growth is inhibited and the grain size ranged between 2-10μμm. Dielectric measurements were carried out as a function of temperature up to180 °C. The low doped samples sintered at 1380 °C, display the high value of dielectric permittivity at room temperature, 2400 for 0.01 Ho/BaTiO 3. A nearly flat permittivity-response was obtained in specimens with higher additive content. Using a Curie-Weiss low and modified CurieWeiss low the Curie constant (C), Curie temperature (Tc) and a critical exponent of nonlinearity (γ) were calculated. The obtained value of γ pointed out that the specimens have almost sharp phase transition.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Ho2O3 Additive Effects on BaTiO3 Ceramics Microstructure and Dielectric Properties",
pages = "223-233",
doi = "10.2298/SOS1202223P"
}
Paunović, V., Mitić, V. V., Miljković, M., Pavlović, V. P.,& Živković, L.. (2012). Ho2O3 Additive Effects on BaTiO3 Ceramics Microstructure and Dielectric Properties. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 223-233.
https://doi.org/10.2298/SOS1202223P
Paunović V, Mitić VV, Miljković M, Pavlović VP, Živković L. Ho2O3 Additive Effects on BaTiO3 Ceramics Microstructure and Dielectric Properties. in Science of Sintering. 2012;:223-233.
doi:10.2298/SOS1202223P .
Paunović, Vesna, Mitić, Vojislav V., Miljković, Miroslav, Pavlović, Vera P., Živković, Ljiljana, "Ho2O3 Additive Effects on BaTiO3 Ceramics Microstructure and Dielectric Properties" in Science of Sintering (2012):223-233,
https://doi.org/10.2298/SOS1202223P . .
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Sintering process influence on microstructure and intergranular impedance of rare-earth modified BaTiO3-ceramics

Mitić, Vojislav V.; Paunović, Vesna; Pavlović, Vera P.; Živković, Ljiljana

(Belgrade : International Institute for the Science of Sintering, 2011)

TY  - JOUR
AU  - Mitić, Vojislav V.
AU  - Paunović, Vesna
AU  - Pavlović, Vera P.
AU  - Živković, Ljiljana
PY  - 2011
UR  - http://dais.sanu.ac.rs/123456789/198
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7365
AB  - Sintering process is a complex of different synergetic effects during the ceramics materials consolidation. The microstructural level properties control is very important as a stage in advanced materials prognosis. SEM analysis of Yb/BaTiO3 doped ceramics showed that in samples doped with a low level of dopant and sintered at higher temperatures the grain size ranged from 10-60μm, while with the higher dopant concentration the grain size ranged between 2-15μm. The morphology of sintered BaTiO3-ceramics grains points out the validity of developing new structure analytical methods based on different geometries of grains' model systems. The idea of electrical properties of BaTiO3-ceramics being influenced by intergrain microcontacts can be successfully followed if we start with the two-sphere Coble’s model and also the correction of the Coble’s model. In this paper, the grains contact models based on spherical, ellipsoidal and polyhedral geometries are presented making a new modeling tool for structure research of BaTiO3-ceramics materials. Intergranular impedance analysis of grains clusters was also introduced. Obtained results enabled establishment of interrelation between structural and electrical parameters.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Sintering process influence on microstructure and intergranular impedance of rare-earth modified BaTiO3-ceramics
SP  - 277
EP  - 287
DO  - 10.2298/SOS1103277M
ER  - 
@article{
author = "Mitić, Vojislav V. and Paunović, Vesna and Pavlović, Vera P. and Živković, Ljiljana",
year = "2011",
abstract = "Sintering process is a complex of different synergetic effects during the ceramics materials consolidation. The microstructural level properties control is very important as a stage in advanced materials prognosis. SEM analysis of Yb/BaTiO3 doped ceramics showed that in samples doped with a low level of dopant and sintered at higher temperatures the grain size ranged from 10-60μm, while with the higher dopant concentration the grain size ranged between 2-15μm. The morphology of sintered BaTiO3-ceramics grains points out the validity of developing new structure analytical methods based on different geometries of grains' model systems. The idea of electrical properties of BaTiO3-ceramics being influenced by intergrain microcontacts can be successfully followed if we start with the two-sphere Coble’s model and also the correction of the Coble’s model. In this paper, the grains contact models based on spherical, ellipsoidal and polyhedral geometries are presented making a new modeling tool for structure research of BaTiO3-ceramics materials. Intergranular impedance analysis of grains clusters was also introduced. Obtained results enabled establishment of interrelation between structural and electrical parameters.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Sintering process influence on microstructure and intergranular impedance of rare-earth modified BaTiO3-ceramics",
pages = "277-287",
doi = "10.2298/SOS1103277M"
}
Mitić, V. V., Paunović, V., Pavlović, V. P.,& Živković, L.. (2011). Sintering process influence on microstructure and intergranular impedance of rare-earth modified BaTiO3-ceramics. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 277-287.
https://doi.org/10.2298/SOS1103277M
Mitić VV, Paunović V, Pavlović VP, Živković L. Sintering process influence on microstructure and intergranular impedance of rare-earth modified BaTiO3-ceramics. in Science of Sintering. 2011;:277-287.
doi:10.2298/SOS1103277M .
Mitić, Vojislav V., Paunović, Vesna, Pavlović, Vera P., Živković, Ljiljana, "Sintering process influence on microstructure and intergranular impedance of rare-earth modified BaTiO3-ceramics" in Science of Sintering (2011):277-287,
https://doi.org/10.2298/SOS1103277M . .
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