@article{
author = "Leovac, Vukadin M. and Bogdanović, Goran A. and Češljević, Valerija I. and Jovanović, Ljiljana S. and Novaković, Slađana B. and Vojinović-Ješić, Ljiljana S.",
year = "2007",
abstract = "The ligand, salicylaldehyde Girard-T hydrazonium chloride, [H(2)SalGT]Cl (1), and two complexes [Cu(HSalGT)X-2]center dot H2O (X = Br(2); Cl(3)) were synthesized and their crystal structures were determined by single-crystal X-ray analysis. In the two isostructural complexes, the Cu(II) is located in a square-pyramidal environment, with the chelating ligand and one halogen atom in the basal plane and the second halogen in the apical position. The most apparent structural difference between the 1 and its complexes 2 and 3 is the orientation of the N(CH3)(3) group: in 1, it is practically coplanar to the rest of the molecule, while in 2 and 3 it is oriented to the side of the axially bonded halogen, which can be explained by the C-H center dot center dot center dot X intramolecular interactions. The compounds were characterized by elemental analysis, molar conductivity, magnetic susceptibility and electronic absorption spectra.",
publisher = "Springer",
journal = "Structural Chemistry",
title = "Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes",
volume = "18",
number = "1",
pages = "113-119",
doi = "10.1007/s11224-006-9136-8"
}