TY  - JOUR
AU  - Jelić, Aleksandra
AU  - Marinković, Aleksandar D.
AU  - Sekulić, Milica
AU  - Dikić, Stefan
AU  - Ugrinović, Vukašin
AU  - Pavlović, Vladimir B.
AU  - Putić, Slaviša
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9562
AB  - In this study, halloysite nanotubes (HNT) were modified by: 3-glycidyloxypropyltrimethoxysilane (GLYMO), 3-aminopropyltrimethoxysilane (APTES), and 2,2-Bis[4-(glycidyloxy) phenyl] propane (DGEBA), and incorporated in the epoxy resin matrix to enhance its mechanical properties. The HNT/epoxy nanocomposite materials were prepared by mixing different ratios of untreated/treated HNT with neat epoxy resin. Characterization of untreated/treated HNT was performed by Fourier-transformation infrared (FTIR) spectroscopy, and X-ray diffraction (XRD). The quantity of grafted molecules and thermal stability of newly synthesized materials were determined by thermogravimetric (TG) and derivative thermogravimetric (DTG) analysis. Tensile properties of newly synthesized materials were compared, and scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analysis of the fracture surfaces were performed. Incorporation of APTES modified HNT (HNTAPT) and two-step modification APTES followed by DGEBA (HNTAPTDG) has increased the tensile strength of the nanocomposite materials up to 72% and 61%, and strain at break up to 1082% and 1216%, respectively, compared to neat epoxy. It was concluded that the modification of HNT contributed to the enhancement of the dispersion and the cross-linking in the epoxy resin matrix. © 2021 Society of Plastics Engineers
T2  - Polymer Composites
T1  - Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites
VL  - 42
IS  - 5
SP  - 2180
EP  - 2192
DO  - 10.1002/pc.25967
ER  - 

@article{
author = "Jelić, Aleksandra and Marinković, Aleksandar D. and Sekulić, Milica and Dikić, Stefan and Ugrinović, Vukašin and Pavlović, Vladimir B. and Putić, Slaviša",
year = "2021",
abstract = "In this study, halloysite nanotubes (HNT) were modified by: 3-glycidyloxypropyltrimethoxysilane (GLYMO), 3-aminopropyltrimethoxysilane (APTES), and 2,2-Bis[4-(glycidyloxy) phenyl] propane (DGEBA), and incorporated in the epoxy resin matrix to enhance its mechanical properties. The HNT/epoxy nanocomposite materials were prepared by mixing different ratios of untreated/treated HNT with neat epoxy resin. Characterization of untreated/treated HNT was performed by Fourier-transformation infrared (FTIR) spectroscopy, and X-ray diffraction (XRD). The quantity of grafted molecules and thermal stability of newly synthesized materials were determined by thermogravimetric (TG) and derivative thermogravimetric (DTG) analysis. Tensile properties of newly synthesized materials were compared, and scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analysis of the fracture surfaces were performed. Incorporation of APTES modified HNT (HNTAPT) and two-step modification APTES followed by DGEBA (HNTAPTDG) has increased the tensile strength of the nanocomposite materials up to 72% and 61%, and strain at break up to 1082% and 1216%, respectively, compared to neat epoxy. It was concluded that the modification of HNT contributed to the enhancement of the dispersion and the cross-linking in the epoxy resin matrix. © 2021 Society of Plastics Engineers",
journal = "Polymer Composites",
title = "Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites",
volume = "42",
number = "5",
pages = "2180-2192",
doi = "10.1002/pc.25967"
}

Jelić, A., Marinković, A. D., Sekulić, M., Dikić, S., Ugrinović, V., Pavlović, V. B.,& Putić, S.. (2021). Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites. in Polymer Composites, 42(5), 2180-2192.
https://doi.org/10.1002/pc.25967

Jelić A, Marinković AD, Sekulić M, Dikić S, Ugrinović V, Pavlović VB, Putić S. Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites. in Polymer Composites. 2021;42(5):2180-2192.
doi:10.1002/pc.25967 .

Jelić, Aleksandra, Marinković, Aleksandar D., Sekulić, Milica, Dikić, Stefan, Ugrinović, Vukašin, Pavlović, Vladimir B., Putić, Slaviša, "Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites" in Polymer Composites, 42, no. 5 (2021):2180-2192,
https://doi.org/10.1002/pc.25967 . .

TY  - CHAP
AU  - Jelić, Aleksandra
AU  - Božić, Aleksandra
AU  - Stamenović, Marina
AU  - Sekulić, Milica
AU  - Porobić, Slavica
AU  - Dikić, Stefan
AU  - Putić, Slaviša
AU  - Mitrović, Nenad
AU  - Mladenović, Goran
AU  - Mitrović, Aleksandra
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9636
AB  - Halloysite nanotubes (HNTs), naturally occurring as aluminosilicate nanoclay mineral, have recently emerged as a possible nanomaterial for countless applications due to their specific chemical structure, tubular shape, high aspect ratio, biocompatibility and low toxicity. In this study, HNTs were incorporated into the epoxy resin matrix to improve its mechanical properties and thermal stability. However, heterogeneous size, surface charge and surface hydrogen bond formation, result in aggregation of HNTs in epoxies to a certain extent. Three specific techniques were used to integrate HNTs into neat epoxy resin (NE). The structure and morphology of the embedded nanotubes were confirmed by Fourier-transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Tensile testing was carried out and the fractured surface of the tested specimen was analysed using scanning electron microscopy (SEM). The thermal stability of the prepared nanocomposite materials was investigated by thermogravimetric (TG) and derivative thermogravimetry (DTG) studies. The obtained results indicated that improved properties of HNTs/epoxy nanocomposite materials were related to the unique properties of well-dispersed HNTs, agglomerate scale, and reduced void presence, and could be controlled by the manufacturing processes.
PB  - Springer International Publishing
T2  - Experimental and Computational Investigations in Engineering
T1  - Effects of dispersion and particle-matrix interactions on mechanical and thermal properties of hnt/epoxy nanocomposite materials
SP  - 310
EP  - 325
DO  - 10.1007/978-3-030-58362-0_18
ER  - 

@inbook{
author = "Jelić, Aleksandra and Božić, Aleksandra and Stamenović, Marina and Sekulić, Milica and Porobić, Slavica and Dikić, Stefan and Putić, Slaviša and Mitrović, Nenad and Mladenović, Goran and Mitrović, Aleksandra",
year = "2021",
abstract = "Halloysite nanotubes (HNTs), naturally occurring as aluminosilicate nanoclay mineral, have recently emerged as a possible nanomaterial for countless applications due to their specific chemical structure, tubular shape, high aspect ratio, biocompatibility and low toxicity. In this study, HNTs were incorporated into the epoxy resin matrix to improve its mechanical properties and thermal stability. However, heterogeneous size, surface charge and surface hydrogen bond formation, result in aggregation of HNTs in epoxies to a certain extent. Three specific techniques were used to integrate HNTs into neat epoxy resin (NE). The structure and morphology of the embedded nanotubes were confirmed by Fourier-transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Tensile testing was carried out and the fractured surface of the tested specimen was analysed using scanning electron microscopy (SEM). The thermal stability of the prepared nanocomposite materials was investigated by thermogravimetric (TG) and derivative thermogravimetry (DTG) studies. The obtained results indicated that improved properties of HNTs/epoxy nanocomposite materials were related to the unique properties of well-dispersed HNTs, agglomerate scale, and reduced void presence, and could be controlled by the manufacturing processes.",
publisher = "Springer International Publishing",
journal = "Experimental and Computational Investigations in Engineering",
booktitle = "Effects of dispersion and particle-matrix interactions on mechanical and thermal properties of hnt/epoxy nanocomposite materials",
pages = "310-325",
doi = "10.1007/978-3-030-58362-0_18"
}

Jelić, A., Božić, A., Stamenović, M., Sekulić, M., Porobić, S., Dikić, S., Putić, S., Mitrović, N., Mladenović, G.,& Mitrović, A.. (2021). Effects of dispersion and particle-matrix interactions on mechanical and thermal properties of hnt/epoxy nanocomposite materials. in Experimental and Computational Investigations in Engineering
Springer International Publishing., 310-325.
https://doi.org/10.1007/978-3-030-58362-0_18

Jelić A, Božić A, Stamenović M, Sekulić M, Porobić S, Dikić S, Putić S, Mitrović N, Mladenović G, Mitrović A. Effects of dispersion and particle-matrix interactions on mechanical and thermal properties of hnt/epoxy nanocomposite materials. in Experimental and Computational Investigations in Engineering. 2021;:310-325.
doi:10.1007/978-3-030-58362-0_18 .

Jelić, Aleksandra, Božić, Aleksandra, Stamenović, Marina, Sekulić, Milica, Porobić, Slavica, Dikić, Stefan, Putić, Slaviša, Mitrović, Nenad, Mladenović, Goran, Mitrović, Aleksandra, "Effects of dispersion and particle-matrix interactions on mechanical and thermal properties of hnt/epoxy nanocomposite materials" in Experimental and Computational Investigations in Engineering (2021):310-325,
https://doi.org/10.1007/978-3-030-58362-0_18 . .