TY  - JOUR
AU  - Pergal, Marija V.
AU  - Kodranov, Igor D.
AU  - Pergal, Miodrag M.
AU  - Gašić, Uroš M.
AU  - Stanković, Dalibor M.
AU  - Petković, Branka B.
AU  - Manojlović, Dragan D.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9112
AB  - The aim of this study was to investigate, analyze, and compare applied techniques suitable for achieving efficient removal of organophosphorus pesticides (OPPs) (malathion and fenitrothion) from aqueous solutions and analyze the degradation products and processes. Pesticide degradation efficiency (%) was monitored by high-performance liquid chromatography (HPLC) equipped with a photodiode array detector (DAD), while mineralization degree was determined by total organic carbon analysis (TOC). Daphnia magna was used for screening the environmental safety aspects of the degradation methods, i.e., for assessing the toxicity of solutions obtained after degradation. Additionally, a surface river water was utilized to examine the likely influence of organic matter on the pesticides’ degradation. Pesticide degradation products were identified using gas chromatography with a triple quadrupole mass detector (GC-MS/MS) as well as ultrahigh-performance liquid chromatography coupled with a linear ion trap, Orbitrap mass spectrometer (UHPLC-LTQ Orbitrap MS), and a simple pesticide degradation mechanism is proposed. Removal of pesticides from water using chlorine dioxide was successful, resulting in high degradation efficiency (98% for malathion and 81% for fenitrothion). Partial mineralization was achieved, and Daphnia magna mortality decreased in the waters containing degradation products (compared with the parent pesticides), indicating that the solutions formed were less toxic than the parent pesticides. Lower degradation rates (80% for malathion and 72% for fenitrothion) in Sava River water were measured, indicating the influence of the organic matter contained in this naturally occurring surface water. The results prove that chlorine dioxide could be used as an agent for successful removal of these OPPs from water.
T2  - Water, Air, and Soil Pollution
T1  - Degradation Products, Mineralization, and Toxicity Assessment of Pesticides Malathion and Fenitrothion
VL  - 231
IS  - 8
DO  - 10.1007/s11270-020-04800-x
ER  - 

@article{
author = "Pergal, Marija V. and Kodranov, Igor D. and Pergal, Miodrag M. and Gašić, Uroš M. and Stanković, Dalibor M. and Petković, Branka B. and Manojlović, Dragan D.",
year = "2020",
abstract = "The aim of this study was to investigate, analyze, and compare applied techniques suitable for achieving efficient removal of organophosphorus pesticides (OPPs) (malathion and fenitrothion) from aqueous solutions and analyze the degradation products and processes. Pesticide degradation efficiency (%) was monitored by high-performance liquid chromatography (HPLC) equipped with a photodiode array detector (DAD), while mineralization degree was determined by total organic carbon analysis (TOC). Daphnia magna was used for screening the environmental safety aspects of the degradation methods, i.e., for assessing the toxicity of solutions obtained after degradation. Additionally, a surface river water was utilized to examine the likely influence of organic matter on the pesticides’ degradation. Pesticide degradation products were identified using gas chromatography with a triple quadrupole mass detector (GC-MS/MS) as well as ultrahigh-performance liquid chromatography coupled with a linear ion trap, Orbitrap mass spectrometer (UHPLC-LTQ Orbitrap MS), and a simple pesticide degradation mechanism is proposed. Removal of pesticides from water using chlorine dioxide was successful, resulting in high degradation efficiency (98% for malathion and 81% for fenitrothion). Partial mineralization was achieved, and Daphnia magna mortality decreased in the waters containing degradation products (compared with the parent pesticides), indicating that the solutions formed were less toxic than the parent pesticides. Lower degradation rates (80% for malathion and 72% for fenitrothion) in Sava River water were measured, indicating the influence of the organic matter contained in this naturally occurring surface water. The results prove that chlorine dioxide could be used as an agent for successful removal of these OPPs from water.",
journal = "Water, Air, and Soil Pollution",
title = "Degradation Products, Mineralization, and Toxicity Assessment of Pesticides Malathion and Fenitrothion",
volume = "231",
number = "8",
doi = "10.1007/s11270-020-04800-x"
}

Pergal, M. V., Kodranov, I. D., Pergal, M. M., Gašić, U. M., Stanković, D. M., Petković, B. B.,& Manojlović, D. D.. (2020). Degradation Products, Mineralization, and Toxicity Assessment of Pesticides Malathion and Fenitrothion. in Water, Air, and Soil Pollution, 231(8).
https://doi.org/10.1007/s11270-020-04800-x

Pergal MV, Kodranov ID, Pergal MM, Gašić UM, Stanković DM, Petković BB, Manojlović DD. Degradation Products, Mineralization, and Toxicity Assessment of Pesticides Malathion and Fenitrothion. in Water, Air, and Soil Pollution. 2020;231(8).
doi:10.1007/s11270-020-04800-x .

Pergal, Marija V., Kodranov, Igor D., Pergal, Miodrag M., Gašić, Uroš M., Stanković, Dalibor M., Petković, Branka B., Manojlović, Dragan D., "Degradation Products, Mineralization, and Toxicity Assessment of Pesticides Malathion and Fenitrothion" in Water, Air, and Soil Pollution, 231, no. 8 (2020),
https://doi.org/10.1007/s11270-020-04800-x . .

TY  - JOUR
AU  - Vasić, Vesna M.
AU  - Gašić, Uroš M.
AU  - Stanković, Dalibor M.
AU  - Lušić, Dražen
AU  - Vukić-Lušić, Darija
AU  - Milojković-Opsenica, Dušanka M.
AU  - Tešić, Živoslav
AU  - Trifković, Jelena Đ.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0308814618316169
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7868
AB  - Concerning the particular nutritive value of honeydew honey compared to blossom honey, and small number of studies defining botanical origin of honeydew honey, comprehensive analysis of phenolic profile of 64 honeydew honey samples of specific botanical origin was performed. Two advanced techniques of liquid chromatography hyphenated with mass spectrometry were used for identification of a total of 52 compounds and quantification of 25 of them. Pattern recognition analysis applied on data on phenolic compounds content confirmed that quercetin, naringenin, caffeoylquinic acid, hydroxyphenylacetic acid, apigenin and genistein, could be considered as potential markers of botanical origin of honeydew honey. Spectroscopic and electrochemical approaches were applied for the evaluation of the antioxidant capacity. Quercus sps. samples, Quercus frainetto and Quercus ilex, showed high biological activity and specific chemical composition. Additionally, cyclic voltammetry profiles were used for characterization and natural clustering of honeydew honey for the first time. © 2018 Elsevier Ltd
T2  - Food Chemistry
T1  - Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity
VL  - 274
SP  - 629
EP  - 641
DO  - 10.1016/j.foodchem.2018.09.045
ER  - 

@article{
author = "Vasić, Vesna M. and Gašić, Uroš M. and Stanković, Dalibor M. and Lušić, Dražen and Vukić-Lušić, Darija and Milojković-Opsenica, Dušanka M. and Tešić, Živoslav and Trifković, Jelena Đ.",
year = "2019",
abstract = "Concerning the particular nutritive value of honeydew honey compared to blossom honey, and small number of studies defining botanical origin of honeydew honey, comprehensive analysis of phenolic profile of 64 honeydew honey samples of specific botanical origin was performed. Two advanced techniques of liquid chromatography hyphenated with mass spectrometry were used for identification of a total of 52 compounds and quantification of 25 of them. Pattern recognition analysis applied on data on phenolic compounds content confirmed that quercetin, naringenin, caffeoylquinic acid, hydroxyphenylacetic acid, apigenin and genistein, could be considered as potential markers of botanical origin of honeydew honey. Spectroscopic and electrochemical approaches were applied for the evaluation of the antioxidant capacity. Quercus sps. samples, Quercus frainetto and Quercus ilex, showed high biological activity and specific chemical composition. Additionally, cyclic voltammetry profiles were used for characterization and natural clustering of honeydew honey for the first time. © 2018 Elsevier Ltd",
journal = "Food Chemistry",
title = "Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity",
volume = "274",
pages = "629-641",
doi = "10.1016/j.foodchem.2018.09.045"
}

Vasić, V. M., Gašić, U. M., Stanković, D. M., Lušić, D., Vukić-Lušić, D., Milojković-Opsenica, D. M., Tešić, Ž.,& Trifković, J. Đ.. (2019). Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity. in Food Chemistry, 274, 629-641.
https://doi.org/10.1016/j.foodchem.2018.09.045

Vasić VM, Gašić UM, Stanković DM, Lušić D, Vukić-Lušić D, Milojković-Opsenica DM, Tešić Ž, Trifković JĐ. Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity. in Food Chemistry. 2019;274:629-641.
doi:10.1016/j.foodchem.2018.09.045 .

Vasić, Vesna M., Gašić, Uroš M., Stanković, Dalibor M., Lušić, Dražen, Vukić-Lušić, Darija, Milojković-Opsenica, Dušanka M., Tešić, Živoslav, Trifković, Jelena Đ., "Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity" in Food Chemistry, 274 (2019):629-641,
https://doi.org/10.1016/j.foodchem.2018.09.045 . .