Radhakrishnan, T.

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  • Radhakrishnan, T. (9)
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Author's Bibliography

Semiconductor nanoparticles in poly((2-dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymers

Trandafilović, Lidija V.; Bibić, Nataša M.; Georges, M. K.; Blanuša, Jovan; Radhakrishnan, T.; Đoković, Vladimir

(2013)

TY  - JOUR
AU  - Trandafilović, Lidija V.
AU  - Bibić, Nataša M.
AU  - Georges, M. K.
AU  - Blanuša, Jovan
AU  - Radhakrishnan, T.
AU  - Đoković, Vladimir
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7027
AB  - Nanostructured cadmium selenide (CdSe) and lead sulfide (PbS) semiconductors were prepared in a poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) matrix. The obtained nanoparticles were characterized by using optical and structural methods. Co-polymers were synthesized in two different molar ratios of pDMAEMA: acrylic acid monomer units (1 : 2, 1 : 1). Transmission electron microscopy analysis confirmed the presence of nano-sized CdSe and PbS particles. In the case of CdSe, a shift of the onset of the optical absorption toward lower wavelengths was observed. X-ray diffraction analysis revealed that both CdSe and PbS nanoparticles have cubic crystal structure.
T2  - Physica Scripta
T1  - Semiconductor nanoparticles in poly((2-dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymers
VL  - T157
DO  - 10.1088/0031-8949/2013/T157/014063
ER  - 
@article{
author = "Trandafilović, Lidija V. and Bibić, Nataša M. and Georges, M. K. and Blanuša, Jovan and Radhakrishnan, T. and Đoković, Vladimir",
year = "2013",
abstract = "Nanostructured cadmium selenide (CdSe) and lead sulfide (PbS) semiconductors were prepared in a poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) matrix. The obtained nanoparticles were characterized by using optical and structural methods. Co-polymers were synthesized in two different molar ratios of pDMAEMA: acrylic acid monomer units (1 : 2, 1 : 1). Transmission electron microscopy analysis confirmed the presence of nano-sized CdSe and PbS particles. In the case of CdSe, a shift of the onset of the optical absorption toward lower wavelengths was observed. X-ray diffraction analysis revealed that both CdSe and PbS nanoparticles have cubic crystal structure.",
journal = "Physica Scripta",
title = "Semiconductor nanoparticles in poly((2-dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymers",
volume = "T157",
doi = "10.1088/0031-8949/2013/T157/014063"
}
Trandafilović, L. V., Bibić, N. M., Georges, M. K., Blanuša, J., Radhakrishnan, T.,& Đoković, V.. (2013). Semiconductor nanoparticles in poly((2-dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymers. in Physica Scripta, T157.
https://doi.org/10.1088/0031-8949/2013/T157/014063
Trandafilović LV, Bibić NM, Georges MK, Blanuša J, Radhakrishnan T, Đoković V. Semiconductor nanoparticles in poly((2-dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymers. in Physica Scripta. 2013;T157.
doi:10.1088/0031-8949/2013/T157/014063 .
Trandafilović, Lidija V., Bibić, Nataša M., Georges, M. K., Blanuša, Jovan, Radhakrishnan, T., Đoković, Vladimir, "Semiconductor nanoparticles in poly((2-dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymers" in Physica Scripta, T157 (2013),
https://doi.org/10.1088/0031-8949/2013/T157/014063 . .
1
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1

Formation of nano-plate silver particles in the presence of polyampholyte copolymer

Trandafilović, Lidija V.; Luyt, Adriaan S.; Bibić, Nataša M.; Dimitrijević-Branković, Suzana I.; Georges, M. K.; Radhakrishnan, T.; Đoković, Vladimir

(2012)

TY  - JOUR
AU  - Trandafilović, Lidija V.
AU  - Luyt, Adriaan S.
AU  - Bibić, Nataša M.
AU  - Dimitrijević-Branković, Suzana I.
AU  - Georges, M. K.
AU  - Radhakrishnan, T.
AU  - Đoković, Vladimir
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5209
AB  - Poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) polyampholyte copolymers were synthesized by radical polymerization of the co-monomers in different molar ratios (2-1, 1-1 and 1-2). The water solutions of the obtained materials were used as stabilization agents for the synthesis of silver nanoparticles. XRD. FTIR and DMA methods were used to study the physical properties of the pure copolymers. It was found that the copolymer is a completely amorphous and inhomogeneous material. The FTIR spectrum was analysed by using literature data and corresponding numerical simulations. TEM analysis showed that the shape of the nanoparticles prepared by reduction of the silver salt in the presence of co-polymers strongly depends on the ratio of DMAEMA and AA co-monomer units. Besides spherical Ag-nanoparticles, reduction in the presence of the polymer with equal molar content of co-monomers also resulted in the formation of nano-plate particles (circular thin plates and thin triangular nanoprisms). The formation of the nano-plate particles was further promoted by heating the mentioned solution at 60 degrees C in air. UV-vis spectroscopy was used to study the change in the surface plasmon resonance behaviour during the growth of the nanoplates. The Ag-nanocomposite thin films of all three co-polymers showed fast antimicrobial activity against the Staphylococcus aureus, Escherichia coli and Candida albicans pathogens (more than 99% reduction after 2 h of exposure). (C) 201 2 Elsevier B.V. All rights reserved.
T2  - Colloids and Surfaces. A: Physicochemical and Engineering Aspects
T1  - Formation of nano-plate silver particles in the presence of polyampholyte copolymer
VL  - 414
SP  - 17
EP  - 25
DO  - 10.1016/j.colsurfa.2012.08.010
ER  - 
@article{
author = "Trandafilović, Lidija V. and Luyt, Adriaan S. and Bibić, Nataša M. and Dimitrijević-Branković, Suzana I. and Georges, M. K. and Radhakrishnan, T. and Đoković, Vladimir",
year = "2012",
abstract = "Poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) polyampholyte copolymers were synthesized by radical polymerization of the co-monomers in different molar ratios (2-1, 1-1 and 1-2). The water solutions of the obtained materials were used as stabilization agents for the synthesis of silver nanoparticles. XRD. FTIR and DMA methods were used to study the physical properties of the pure copolymers. It was found that the copolymer is a completely amorphous and inhomogeneous material. The FTIR spectrum was analysed by using literature data and corresponding numerical simulations. TEM analysis showed that the shape of the nanoparticles prepared by reduction of the silver salt in the presence of co-polymers strongly depends on the ratio of DMAEMA and AA co-monomer units. Besides spherical Ag-nanoparticles, reduction in the presence of the polymer with equal molar content of co-monomers also resulted in the formation of nano-plate particles (circular thin plates and thin triangular nanoprisms). The formation of the nano-plate particles was further promoted by heating the mentioned solution at 60 degrees C in air. UV-vis spectroscopy was used to study the change in the surface plasmon resonance behaviour during the growth of the nanoplates. The Ag-nanocomposite thin films of all three co-polymers showed fast antimicrobial activity against the Staphylococcus aureus, Escherichia coli and Candida albicans pathogens (more than 99% reduction after 2 h of exposure). (C) 201 2 Elsevier B.V. All rights reserved.",
journal = "Colloids and Surfaces. A: Physicochemical and Engineering Aspects",
title = "Formation of nano-plate silver particles in the presence of polyampholyte copolymer",
volume = "414",
pages = "17-25",
doi = "10.1016/j.colsurfa.2012.08.010"
}
Trandafilović, L. V., Luyt, A. S., Bibić, N. M., Dimitrijević-Branković, S. I., Georges, M. K., Radhakrishnan, T.,& Đoković, V.. (2012). Formation of nano-plate silver particles in the presence of polyampholyte copolymer. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 414, 17-25.
https://doi.org/10.1016/j.colsurfa.2012.08.010
Trandafilović LV, Luyt AS, Bibić NM, Dimitrijević-Branković SI, Georges MK, Radhakrishnan T, Đoković V. Formation of nano-plate silver particles in the presence of polyampholyte copolymer. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects. 2012;414:17-25.
doi:10.1016/j.colsurfa.2012.08.010 .
Trandafilović, Lidija V., Luyt, Adriaan S., Bibić, Nataša M., Dimitrijević-Branković, Suzana I., Georges, M. K., Radhakrishnan, T., Đoković, Vladimir, "Formation of nano-plate silver particles in the presence of polyampholyte copolymer" in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 414 (2012):17-25,
https://doi.org/10.1016/j.colsurfa.2012.08.010 . .
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Confined growth of Ag2S semiconductor nanocrystals in the presence of PDMAEMA-co-AA polyampholyte co-polymer

Trandafilović, Lidija V.; Đoković, Vladimir; Bibić, Nataša M.; Georges, M. K.; Radhakrishnan, T.

(2010)

TY  - JOUR
AU  - Trandafilović, Lidija V.
AU  - Đoković, Vladimir
AU  - Bibić, Nataša M.
AU  - Georges, M. K.
AU  - Radhakrishnan, T.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3982
AB  - Silver sulfide (Ag2S) nanoparticles were synthesized in the presence of poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymer. It was shown that this polyampholyte can stabilize the growth of the Ag2S in solution which resulted in formation of nanoparticles with relatively narrow size distribution. The obtained nanoparticles were characterized with structural and optical methods. The results showed that their average size depended on the number of acrylic acid units along the polymer chains. (C) 2010 Elsevier B.V. All rights reserved.
T2  - Materials Letters
T1  - Confined growth of Ag2S semiconductor nanocrystals in the presence of PDMAEMA-co-AA polyampholyte co-polymer
VL  - 64
IS  - 9
SP  - 1123
EP  - 1126
DO  - 10.1016/j.matlet.2010.02.032
ER  - 
@article{
author = "Trandafilović, Lidija V. and Đoković, Vladimir and Bibić, Nataša M. and Georges, M. K. and Radhakrishnan, T.",
year = "2010",
abstract = "Silver sulfide (Ag2S) nanoparticles were synthesized in the presence of poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) co-polymer. It was shown that this polyampholyte can stabilize the growth of the Ag2S in solution which resulted in formation of nanoparticles with relatively narrow size distribution. The obtained nanoparticles were characterized with structural and optical methods. The results showed that their average size depended on the number of acrylic acid units along the polymer chains. (C) 2010 Elsevier B.V. All rights reserved.",
journal = "Materials Letters",
title = "Confined growth of Ag2S semiconductor nanocrystals in the presence of PDMAEMA-co-AA polyampholyte co-polymer",
volume = "64",
number = "9",
pages = "1123-1126",
doi = "10.1016/j.matlet.2010.02.032"
}
Trandafilović, L. V., Đoković, V., Bibić, N. M., Georges, M. K.,& Radhakrishnan, T.. (2010). Confined growth of Ag2S semiconductor nanocrystals in the presence of PDMAEMA-co-AA polyampholyte co-polymer. in Materials Letters, 64(9), 1123-1126.
https://doi.org/10.1016/j.matlet.2010.02.032
Trandafilović LV, Đoković V, Bibić NM, Georges MK, Radhakrishnan T. Confined growth of Ag2S semiconductor nanocrystals in the presence of PDMAEMA-co-AA polyampholyte co-polymer. in Materials Letters. 2010;64(9):1123-1126.
doi:10.1016/j.matlet.2010.02.032 .
Trandafilović, Lidija V., Đoković, Vladimir, Bibić, Nataša M., Georges, M. K., Radhakrishnan, T., "Confined growth of Ag2S semiconductor nanocrystals in the presence of PDMAEMA-co-AA polyampholyte co-polymer" in Materials Letters, 64, no. 9 (2010):1123-1126,
https://doi.org/10.1016/j.matlet.2010.02.032 . .
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Biopolymer-protected CdSe nanoparticles

Božanić, Dušan K.; Đoković, Vladimir; Bibić, Nataša M.; Nair, P. Sreekumari; Georges, M. K.; Radhakrishnan, T.

(2009)

TY  - JOUR
AU  - Božanić, Dušan K.
AU  - Đoković, Vladimir
AU  - Bibić, Nataša M.
AU  - Nair, P. Sreekumari
AU  - Georges, M. K.
AU  - Radhakrishnan, T.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3841
AB  - A synthetic procedure for the encapsulation of cadmium selenide (CdSe) nanoparticles in a sago starch matrix is introduced. The nanocomposite was investigated using structural, spectroscopic and thermal, methods. TEM micrographs of the nanocomposite showed spherical CdSe particles of 4-5 nm in size coated with a biopolymer layer. The absorption edges of both the aqueous solution and the thin film of the CdSe-starch nanocomposite were shifted toward lower wavelengths in comparison to the value of the bulk semiconductor. Infrared measurements revealed that the interaction of CdSe nanoparticles and starch chains takes place via OH groups. Although the onset of the temperature of decomposition of CdSe-starch nanocomposite is lower than that of the pure matrix, thermogravimetric analysis also showed that introduction of CdSe nanoparticles significantly reduced starch degradation rate leading to high residual mass at the end of the degradation process. (C) 2009 Elsevier Ltd. All rights reserved.
T2  - Carbohydrate Research
T1  - Biopolymer-protected CdSe nanoparticles
VL  - 344
IS  - 17
SP  - 2383
EP  - 2387
DO  - 10.1016/j.carres.2009.08.018
ER  - 
@article{
author = "Božanić, Dušan K. and Đoković, Vladimir and Bibić, Nataša M. and Nair, P. Sreekumari and Georges, M. K. and Radhakrishnan, T.",
year = "2009",
abstract = "A synthetic procedure for the encapsulation of cadmium selenide (CdSe) nanoparticles in a sago starch matrix is introduced. The nanocomposite was investigated using structural, spectroscopic and thermal, methods. TEM micrographs of the nanocomposite showed spherical CdSe particles of 4-5 nm in size coated with a biopolymer layer. The absorption edges of both the aqueous solution and the thin film of the CdSe-starch nanocomposite were shifted toward lower wavelengths in comparison to the value of the bulk semiconductor. Infrared measurements revealed that the interaction of CdSe nanoparticles and starch chains takes place via OH groups. Although the onset of the temperature of decomposition of CdSe-starch nanocomposite is lower than that of the pure matrix, thermogravimetric analysis also showed that introduction of CdSe nanoparticles significantly reduced starch degradation rate leading to high residual mass at the end of the degradation process. (C) 2009 Elsevier Ltd. All rights reserved.",
journal = "Carbohydrate Research",
title = "Biopolymer-protected CdSe nanoparticles",
volume = "344",
number = "17",
pages = "2383-2387",
doi = "10.1016/j.carres.2009.08.018"
}
Božanić, D. K., Đoković, V., Bibić, N. M., Nair, P. S., Georges, M. K.,& Radhakrishnan, T.. (2009). Biopolymer-protected CdSe nanoparticles. in Carbohydrate Research, 344(17), 2383-2387.
https://doi.org/10.1016/j.carres.2009.08.018
Božanić DK, Đoković V, Bibić NM, Nair PS, Georges MK, Radhakrishnan T. Biopolymer-protected CdSe nanoparticles. in Carbohydrate Research. 2009;344(17):2383-2387.
doi:10.1016/j.carres.2009.08.018 .
Božanić, Dušan K., Đoković, Vladimir, Bibić, Nataša M., Nair, P. Sreekumari, Georges, M. K., Radhakrishnan, T., "Biopolymer-protected CdSe nanoparticles" in Carbohydrate Research, 344, no. 17 (2009):2383-2387,
https://doi.org/10.1016/j.carres.2009.08.018 . .
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Preparation and optical properties of US nanoparticles dispersed in poly(2-(dimethylamino) ethyl methaerylate-co-acrylic acid) co-polymers

Trandafilović, Lidija V.; Đoković, Vladimir; Bibić, Nataša M.; Georges, M. K.; Radhakrishnan, T.

(2008)

TY  - JOUR
AU  - Trandafilović, Lidija V.
AU  - Đoković, Vladimir
AU  - Bibić, Nataša M.
AU  - Georges, M. K.
AU  - Radhakrishnan, T.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6736
AB  - CdS/poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) nanocomposites were prepared and characterized using structural, optical and thermal methods. Co-polymers used as the matrices were synthesized by radical polymerization of the co-monomers in different mol ratios (1: 1, 2:1 and 1:2, DMAEMA:acrylic acid). The presence of the nanostructured CdS was confirmed by TEM analysis as well as by the shift of the onset of the optical absorption towards lower wavelengths. XRD spectra showed the cubic crystal phase of the obtained CdS nanoparticles. TGA measurements revealed improved thermal stability of the nanocomposite with respect to pure co-polymer matrix. (c) 2007 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Preparation and optical properties of US nanoparticles dispersed in poly(2-(dimethylamino) ethyl methaerylate-co-acrylic acid) co-polymers
VL  - 30
IS  - 7
SP  - 1208
EP  - 1212
DO  - 10.1016/j.optmat.2007.05.050
ER  - 
@article{
author = "Trandafilović, Lidija V. and Đoković, Vladimir and Bibić, Nataša M. and Georges, M. K. and Radhakrishnan, T.",
year = "2008",
abstract = "CdS/poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) nanocomposites were prepared and characterized using structural, optical and thermal methods. Co-polymers used as the matrices were synthesized by radical polymerization of the co-monomers in different mol ratios (1: 1, 2:1 and 1:2, DMAEMA:acrylic acid). The presence of the nanostructured CdS was confirmed by TEM analysis as well as by the shift of the onset of the optical absorption towards lower wavelengths. XRD spectra showed the cubic crystal phase of the obtained CdS nanoparticles. TGA measurements revealed improved thermal stability of the nanocomposite with respect to pure co-polymer matrix. (c) 2007 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Preparation and optical properties of US nanoparticles dispersed in poly(2-(dimethylamino) ethyl methaerylate-co-acrylic acid) co-polymers",
volume = "30",
number = "7",
pages = "1208-1212",
doi = "10.1016/j.optmat.2007.05.050"
}
Trandafilović, L. V., Đoković, V., Bibić, N. M., Georges, M. K.,& Radhakrishnan, T.. (2008). Preparation and optical properties of US nanoparticles dispersed in poly(2-(dimethylamino) ethyl methaerylate-co-acrylic acid) co-polymers. in Optical Materials, 30(7), 1208-1212.
https://doi.org/10.1016/j.optmat.2007.05.050
Trandafilović LV, Đoković V, Bibić NM, Georges MK, Radhakrishnan T. Preparation and optical properties of US nanoparticles dispersed in poly(2-(dimethylamino) ethyl methaerylate-co-acrylic acid) co-polymers. in Optical Materials. 2008;30(7):1208-1212.
doi:10.1016/j.optmat.2007.05.050 .
Trandafilović, Lidija V., Đoković, Vladimir, Bibić, Nataša M., Georges, M. K., Radhakrishnan, T., "Preparation and optical properties of US nanoparticles dispersed in poly(2-(dimethylamino) ethyl methaerylate-co-acrylic acid) co-polymers" in Optical Materials, 30, no. 7 (2008):1208-1212,
https://doi.org/10.1016/j.optmat.2007.05.050 . .
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Composites comprising CdS nanoparticles and poly(ethylene oxide): optical properties and influence of the nanofiller content on the thermal behaviour of the host matrix

Radhakrishnan, T.; Georges, M. K.; Nair, P. Sreekumari; Luyt, Adriaan S.; Đoković, Vladimir

(2008)

TY  - JOUR
AU  - Radhakrishnan, T.
AU  - Georges, M. K.
AU  - Nair, P. Sreekumari
AU  - Luyt, Adriaan S.
AU  - Đoković, Vladimir
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3449
AB  - Tri-n-octylphosphine oxide-capped CdS nanoparticles were synthesized with the cadmium(II) complex of thiocarbohydrazide as a precursor. Nanocomposites were prepared by mixing a toluene solution of poly(ethylene oxide) (PEO) and the obtained CdS nanoparticles. The ultraviolet-visible spectroscopy measurements showed a blue shift of the onset of optical absorption, compared to bulk CdS, which confirmed the presence of nanostructured CdS. A transmission electron microscopy micrograph of the nanocomposite depicted that the nanoparticles are well dispersed in the PEO matrix. Differential scanning calorimetry analysis revealed hindered crystallization of PEO in the presence of CdS nanoparticles. It was also found that increasing the nanoparticle content led to the shift of the onset of decomposition of the matrix towards higher temperature.
T2  - Colloid and Polymer Science
T1  - Composites comprising CdS nanoparticles and poly(ethylene oxide): optical properties and influence of the nanofiller content on the thermal behaviour of the host matrix
VL  - 286
IS  - 6-7
SP  - 683
EP  - 689
DO  - 10.1007/s00396-007-1819-1
ER  - 
@article{
author = "Radhakrishnan, T. and Georges, M. K. and Nair, P. Sreekumari and Luyt, Adriaan S. and Đoković, Vladimir",
year = "2008",
abstract = "Tri-n-octylphosphine oxide-capped CdS nanoparticles were synthesized with the cadmium(II) complex of thiocarbohydrazide as a precursor. Nanocomposites were prepared by mixing a toluene solution of poly(ethylene oxide) (PEO) and the obtained CdS nanoparticles. The ultraviolet-visible spectroscopy measurements showed a blue shift of the onset of optical absorption, compared to bulk CdS, which confirmed the presence of nanostructured CdS. A transmission electron microscopy micrograph of the nanocomposite depicted that the nanoparticles are well dispersed in the PEO matrix. Differential scanning calorimetry analysis revealed hindered crystallization of PEO in the presence of CdS nanoparticles. It was also found that increasing the nanoparticle content led to the shift of the onset of decomposition of the matrix towards higher temperature.",
journal = "Colloid and Polymer Science",
title = "Composites comprising CdS nanoparticles and poly(ethylene oxide): optical properties and influence of the nanofiller content on the thermal behaviour of the host matrix",
volume = "286",
number = "6-7",
pages = "683-689",
doi = "10.1007/s00396-007-1819-1"
}
Radhakrishnan, T., Georges, M. K., Nair, P. S., Luyt, A. S.,& Đoković, V.. (2008). Composites comprising CdS nanoparticles and poly(ethylene oxide): optical properties and influence of the nanofiller content on the thermal behaviour of the host matrix. in Colloid and Polymer Science, 286(6-7), 683-689.
https://doi.org/10.1007/s00396-007-1819-1
Radhakrishnan T, Georges MK, Nair PS, Luyt AS, Đoković V. Composites comprising CdS nanoparticles and poly(ethylene oxide): optical properties and influence of the nanofiller content on the thermal behaviour of the host matrix. in Colloid and Polymer Science. 2008;286(6-7):683-689.
doi:10.1007/s00396-007-1819-1 .
Radhakrishnan, T., Georges, M. K., Nair, P. Sreekumari, Luyt, Adriaan S., Đoković, Vladimir, "Composites comprising CdS nanoparticles and poly(ethylene oxide): optical properties and influence of the nanofiller content on the thermal behaviour of the host matrix" in Colloid and Polymer Science, 286, no. 6-7 (2008):683-689,
https://doi.org/10.1007/s00396-007-1819-1 . .
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Study of sago starch-CdS nanocomposite films: Fabrication, structure, optical and thermal properties

Radhakrishnan, T.; Georges, M. K.; Nair, P. Sreekumari; Luyt, Adriaan S.; Đoković, Vladimir

(2007)

TY  - JOUR
AU  - Radhakrishnan, T.
AU  - Georges, M. K.
AU  - Nair, P. Sreekumari
AU  - Luyt, Adriaan S.
AU  - Đoković, Vladimir
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2569
AB  - A synthetic procedure for the preparation of nanocomposite films of sago starch and CdS nanoparticles was introduced. The films were characterized using optical, structural, and thermal techniques. The formation of nanostructured CdS in the starch matrix was confirmed by a blue shift in the onset of absorption in the UV-VIS spectra of the nanocomposites. The average size of the nanoparticles varied from 3.6 to 5 nm, depending on the initial concentration of cadmium acetate during the nanocomposite preparation. Fluorescence measurements of the sago-CdS nanocomposite film showed broad emission in the orange-red part of the spectrum. DSC; and TGA analyses revealed significant effects of CdS nanoparticles on the thermal properties of the starch matrix.
T2  - Journal of Nanoscience and Nanotechnology
T1  - Study of sago starch-CdS nanocomposite films: Fabrication, structure, optical and thermal properties
VL  - 7
IS  - 3
SP  - 986
EP  - 993
DO  - 10.1166/jnn.2007.212
ER  - 
@article{
author = "Radhakrishnan, T. and Georges, M. K. and Nair, P. Sreekumari and Luyt, Adriaan S. and Đoković, Vladimir",
year = "2007",
abstract = "A synthetic procedure for the preparation of nanocomposite films of sago starch and CdS nanoparticles was introduced. The films were characterized using optical, structural, and thermal techniques. The formation of nanostructured CdS in the starch matrix was confirmed by a blue shift in the onset of absorption in the UV-VIS spectra of the nanocomposites. The average size of the nanoparticles varied from 3.6 to 5 nm, depending on the initial concentration of cadmium acetate during the nanocomposite preparation. Fluorescence measurements of the sago-CdS nanocomposite film showed broad emission in the orange-red part of the spectrum. DSC; and TGA analyses revealed significant effects of CdS nanoparticles on the thermal properties of the starch matrix.",
journal = "Journal of Nanoscience and Nanotechnology",
title = "Study of sago starch-CdS nanocomposite films: Fabrication, structure, optical and thermal properties",
volume = "7",
number = "3",
pages = "986-993",
doi = "10.1166/jnn.2007.212"
}
Radhakrishnan, T., Georges, M. K., Nair, P. S., Luyt, A. S.,& Đoković, V.. (2007). Study of sago starch-CdS nanocomposite films: Fabrication, structure, optical and thermal properties. in Journal of Nanoscience and Nanotechnology, 7(3), 986-993.
https://doi.org/10.1166/jnn.2007.212
Radhakrishnan T, Georges MK, Nair PS, Luyt AS, Đoković V. Study of sago starch-CdS nanocomposite films: Fabrication, structure, optical and thermal properties. in Journal of Nanoscience and Nanotechnology. 2007;7(3):986-993.
doi:10.1166/jnn.2007.212 .
Radhakrishnan, T., Georges, M. K., Nair, P. Sreekumari, Luyt, Adriaan S., Đoković, Vladimir, "Study of sago starch-CdS nanocomposite films: Fabrication, structure, optical and thermal properties" in Journal of Nanoscience and Nanotechnology, 7, no. 3 (2007):986-993,
https://doi.org/10.1166/jnn.2007.212 . .
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Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix

Božanić, Dušan K.; Đoković, Vladimir; Blanuša, Jovan; Nair, P. S.; Georges, M. K.; Radhakrishnan, T.

(2007)

TY  - JOUR
AU  - Božanić, Dušan K.
AU  - Đoković, Vladimir
AU  - Blanuša, Jovan
AU  - Nair, P. S.
AU  - Georges, M. K.
AU  - Radhakrishnan, T.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2568
AB  - Silver (Ag) and silver sulfide (Ag2S) nanoparticles were synthesized in a sago starch matrix. The resulting nanocomposites were investigated using structural, optical and thermal methods. XRD spectra of the nanocomposites confirmed the presence of nanostructured silver (cubic phase) and silver sulfide (monoclinic phase) in the matrix. TEM micrographs showed that the nanoparticles are mostly spherical in shape. Analyzes of the optical properties of the silver nanocomposite aqueous dispersions/solutions of various concentrations were carried out. The results and the theoretical considerations suggested that at high concentrations there is a release of silver nanoparticles from the composite in the water environment. Further dilution produces homogeneous solution in which silver nanoparticles are capped with starch macromolecules. TGA analysis revealed reduced thermal stability of the nanocomposites with respect to pure starch matrix.
T2  - European Physical Journal E. Soft Matter
T1  - Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix
VL  - 22
IS  - 1
SP  - 51
EP  - 59
DO  - 10.1140/epje/e2007-00008-y
ER  - 
@article{
author = "Božanić, Dušan K. and Đoković, Vladimir and Blanuša, Jovan and Nair, P. S. and Georges, M. K. and Radhakrishnan, T.",
year = "2007",
abstract = "Silver (Ag) and silver sulfide (Ag2S) nanoparticles were synthesized in a sago starch matrix. The resulting nanocomposites were investigated using structural, optical and thermal methods. XRD spectra of the nanocomposites confirmed the presence of nanostructured silver (cubic phase) and silver sulfide (monoclinic phase) in the matrix. TEM micrographs showed that the nanoparticles are mostly spherical in shape. Analyzes of the optical properties of the silver nanocomposite aqueous dispersions/solutions of various concentrations were carried out. The results and the theoretical considerations suggested that at high concentrations there is a release of silver nanoparticles from the composite in the water environment. Further dilution produces homogeneous solution in which silver nanoparticles are capped with starch macromolecules. TGA analysis revealed reduced thermal stability of the nanocomposites with respect to pure starch matrix.",
journal = "European Physical Journal E. Soft Matter",
title = "Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix",
volume = "22",
number = "1",
pages = "51-59",
doi = "10.1140/epje/e2007-00008-y"
}
Božanić, D. K., Đoković, V., Blanuša, J., Nair, P. S., Georges, M. K.,& Radhakrishnan, T.. (2007). Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix. in European Physical Journal E. Soft Matter, 22(1), 51-59.
https://doi.org/10.1140/epje/e2007-00008-y
Božanić DK, Đoković V, Blanuša J, Nair PS, Georges MK, Radhakrishnan T. Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix. in European Physical Journal E. Soft Matter. 2007;22(1):51-59.
doi:10.1140/epje/e2007-00008-y .
Božanić, Dušan K., Đoković, Vladimir, Blanuša, Jovan, Nair, P. S., Georges, M. K., Radhakrishnan, T., "Preparation and properties of nano-sized Ag and Ag2S particles in biopolymer matrix" in European Physical Journal E. Soft Matter, 22, no. 1 (2007):51-59,
https://doi.org/10.1140/epje/e2007-00008-y . .
74
74
79

PbS Nanoparticles in Polyacrylamide Matrix: Structure, Optical Properties and Influence on the Host Polymer

Đoković, Vladimir; Sreekumari Nair, P.; Radhakrishnan, T.; Luyt, A. S.

(2004)

TY  - CONF
AU  - Đoković, Vladimir
AU  - Sreekumari Nair, P.
AU  - Radhakrishnan, T.
AU  - Luyt, A. S.
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12894
AB  - A synthetic procedure for the incorporation of PbS nanoparticles in a polyacrylamide (PAM) matrix was introduced. The method is based on the simultaneous polymerization of the monomer and thermal decomposition of the dithiooxamide-lead complex. XRD analysis revealed that PbS nanoparticles have a sphalerite crystal structure (galena). The TEM micrograph showed spherical particles, with average diameter of about 3 nm, well dispersed in the polymer matrix. Although a sharp edge was not observed, the optical absorption of the PAM-PbS nanocomposite is shifted towards lower wavelengths compared to the bulk PbS.
C3  - SFKM 2004 : XVI National Symposium on Condensed Matter Physics : Program and Contributed Papers
T1  - PbS Nanoparticles in Polyacrylamide Matrix: Structure, Optical Properties and Influence on the Host Polymer
SP  - 74
EP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12894
ER  - 
@conference{
author = "Đoković, Vladimir and Sreekumari Nair, P. and Radhakrishnan, T. and Luyt, A. S.",
year = "2004",
abstract = "A synthetic procedure for the incorporation of PbS nanoparticles in a polyacrylamide (PAM) matrix was introduced. The method is based on the simultaneous polymerization of the monomer and thermal decomposition of the dithiooxamide-lead complex. XRD analysis revealed that PbS nanoparticles have a sphalerite crystal structure (galena). The TEM micrograph showed spherical particles, with average diameter of about 3 nm, well dispersed in the polymer matrix. Although a sharp edge was not observed, the optical absorption of the PAM-PbS nanocomposite is shifted towards lower wavelengths compared to the bulk PbS.",
journal = "SFKM 2004 : XVI National Symposium on Condensed Matter Physics : Program and Contributed Papers",
title = "PbS Nanoparticles in Polyacrylamide Matrix: Structure, Optical Properties and Influence on the Host Polymer",
pages = "74-77",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12894"
}
Đoković, V., Sreekumari Nair, P., Radhakrishnan, T.,& Luyt, A. S.. (2004). PbS Nanoparticles in Polyacrylamide Matrix: Structure, Optical Properties and Influence on the Host Polymer. in SFKM 2004 : XVI National Symposium on Condensed Matter Physics : Program and Contributed Papers, 74-77.
https://hdl.handle.net/21.15107/rcub_vinar_12894
Đoković V, Sreekumari Nair P, Radhakrishnan T, Luyt AS. PbS Nanoparticles in Polyacrylamide Matrix: Structure, Optical Properties and Influence on the Host Polymer. in SFKM 2004 : XVI National Symposium on Condensed Matter Physics : Program and Contributed Papers. 2004;:74-77.
https://hdl.handle.net/21.15107/rcub_vinar_12894 .
Đoković, Vladimir, Sreekumari Nair, P., Radhakrishnan, T., Luyt, A. S., "PbS Nanoparticles in Polyacrylamide Matrix: Structure, Optical Properties and Influence on the Host Polymer" in SFKM 2004 : XVI National Symposium on Condensed Matter Physics : Program and Contributed Papers (2004):74-77,
https://hdl.handle.net/21.15107/rcub_vinar_12894 .