Erceg, Tamara

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  • Erceg, Tamara (3)

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Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging

Erceg, Tamara; Vukić, Nevena; Šovljanski, Olja; Teofilović, Vesna; Porobić, Slavica; Baloš, Sebastian; Kojić, Sanja; Terek, Pal; Banjanin, Bojan; Rakić, Srđan

(2023)

TY  - JOUR
AU  - Erceg, Tamara
AU  - Vukić, Nevena
AU  - Šovljanski, Olja
AU  - Teofilović, Vesna
AU  - Porobić, Slavica
AU  - Baloš, Sebastian
AU  - Kojić, Sanja
AU  - Terek, Pal
AU  - Banjanin, Bojan
AU  - Rakić, Srđan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11028
AB  - An active packaging based on the composite film was developed by incorporation of oregano oil as an antimicrobial agent into a cellulose acetate/polycaprolactone diol blend (CA/PCL-diol). A novel plasticizer based on polyethylene terephthalate (PET) glycolysis product (bis(hydroxyethyl terephthalate)) and tartaric acid was synthesized and its influence on the structural, surface, mechanical, barrier, and thermal properties were investigated. The obtained results have shown that plasticizer also has a compatibilizing effect, improving the miscibility of polymers in a blend. A sample with the optimal amount of plasticizer (30 wt%), as well as the best mechanical and barrier properties, was used for the preparation of series with different amounts of oregano oil (3, 6, and 9 wt%). The synthesized azo dye—5-(4-bromo-phenyl azo)-3-amido-6-hydroxy-4-methyl-2-pyridone, soluble in acetone, as well as a blend and plasticizer, has been shown as an adequate one for this composition, due to its ability to achieve a good pigmentation in a low amount (0.3 wt% per polymer blend weight), to absorb UV light, and decrease the aging of the material. Contemporary lifestyle has imposed a need for ready-to-eat (RTE) meals which saves consumers time. RTE food packaging should meet certain requirements such as the ability to prolong shelf-life and preserve the freshness of the food product, and at the same time to make a minimal amount of waste after usage, considering the fact that it is mostly single-use plastic food packaging. Optimal mechanical properties, biodegradability, and additional functions make these films suitable for the packaging of ready-to-eat (RTE) food such as fresh salad.
T2  - Cellulose
T1  - Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging
VL  - InPress
DO  - 10.1007/s10570-023-05240-6
ER  - 
@article{
author = "Erceg, Tamara and Vukić, Nevena and Šovljanski, Olja and Teofilović, Vesna and Porobić, Slavica and Baloš, Sebastian and Kojić, Sanja and Terek, Pal and Banjanin, Bojan and Rakić, Srđan",
year = "2023",
abstract = "An active packaging based on the composite film was developed by incorporation of oregano oil as an antimicrobial agent into a cellulose acetate/polycaprolactone diol blend (CA/PCL-diol). A novel plasticizer based on polyethylene terephthalate (PET) glycolysis product (bis(hydroxyethyl terephthalate)) and tartaric acid was synthesized and its influence on the structural, surface, mechanical, barrier, and thermal properties were investigated. The obtained results have shown that plasticizer also has a compatibilizing effect, improving the miscibility of polymers in a blend. A sample with the optimal amount of plasticizer (30 wt%), as well as the best mechanical and barrier properties, was used for the preparation of series with different amounts of oregano oil (3, 6, and 9 wt%). The synthesized azo dye—5-(4-bromo-phenyl azo)-3-amido-6-hydroxy-4-methyl-2-pyridone, soluble in acetone, as well as a blend and plasticizer, has been shown as an adequate one for this composition, due to its ability to achieve a good pigmentation in a low amount (0.3 wt% per polymer blend weight), to absorb UV light, and decrease the aging of the material. Contemporary lifestyle has imposed a need for ready-to-eat (RTE) meals which saves consumers time. RTE food packaging should meet certain requirements such as the ability to prolong shelf-life and preserve the freshness of the food product, and at the same time to make a minimal amount of waste after usage, considering the fact that it is mostly single-use plastic food packaging. Optimal mechanical properties, biodegradability, and additional functions make these films suitable for the packaging of ready-to-eat (RTE) food such as fresh salad.",
journal = "Cellulose",
title = "Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging",
volume = "InPress",
doi = "10.1007/s10570-023-05240-6"
}
Erceg, T., Vukić, N., Šovljanski, O., Teofilović, V., Porobić, S., Baloš, S., Kojić, S., Terek, P., Banjanin, B.,& Rakić, S.. (2023). Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging. in Cellulose, InPress.
https://doi.org/10.1007/s10570-023-05240-6
Erceg T, Vukić N, Šovljanski O, Teofilović V, Porobić S, Baloš S, Kojić S, Terek P, Banjanin B, Rakić S. Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging. in Cellulose. 2023;InPress.
doi:10.1007/s10570-023-05240-6 .
Erceg, Tamara, Vukić, Nevena, Šovljanski, Olja, Teofilović, Vesna, Porobić, Slavica, Baloš, Sebastian, Kojić, Sanja, Terek, Pal, Banjanin, Bojan, Rakić, Srđan, "Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging" in Cellulose, InPress (2023),
https://doi.org/10.1007/s10570-023-05240-6 . .
2
1

Hydrolytic and thermal stability of urea-formaldehyde resins based on tannin and betaine bio-fillers

Ristić, Mirjana; Samaržija-Jovanović, Suzana; Jovanović, Vojislav; Kostić, Marija; Erceg, Tamara; Jovanović, Tijana; Marković, Gordana; Marinović-Cincović, Milena

(2023)

TY  - JOUR
AU  - Ristić, Mirjana
AU  - Samaržija-Jovanović, Suzana
AU  - Jovanović, Vojislav
AU  - Kostić, Marija
AU  - Erceg, Tamara
AU  - Jovanović, Tijana
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11101
AB  - In this work, betaine (trimethyl glycine) and tannin (complex biomolecules of polyphenolic nature) were used as bio-fillers. Urea-formaldehyde (UF) resin with a molar ratio of formaldehyde versus urea (FA/U) of 0.8 was synthesized in situ with tannin and betaine as bio-fillers, to obtain UF resin with reduced free FA content and increased hydrolytic and thermal stability by the principles of sustainability. The samples TUF (with tannin) and BUF (with betaine) were characterized by using X-ray diffraction analysis (XRD), non-isothermal thermogravimetric analysis (TGA), and differential thermal analysis (DTA), supported by data from Fourier Transform Infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM). The percentage of free FA in modified BUF resin is 0.1%, while the percentage of free FA in tannin-modified resin is 0.8%. The hydrolytic stability of the modified UF resins was determined by measuring the concentration of liberated FA in the modified UF resins, after acid hydrolysis. The modified BUF resin is hydrolytically more stable because the content of released FA is 3.6% compared to the modified TUF resin, where it was 7.4%. Based on the value for T5%, the more thermally stable resin is the modified TUF resin (T5% = 123.1°C), while the value of the T5% for the BUF resin is 83.1°C. This work showed how UF bio-composite with reduced free FA content and increased hydrolytic and thermal stability can be obtained using tannin and betaine as bio-fillers.
T2  - Journal of Vinyl and Additive Technology
T1  - Hydrolytic and thermal stability of urea-formaldehyde resins based on tannin and betaine bio-fillers
VL  - 29
IS  - 6
SP  - 1082
EP  - 1092
DO  - 10.1002/vnl.22024
ER  - 
@article{
author = "Ristić, Mirjana and Samaržija-Jovanović, Suzana and Jovanović, Vojislav and Kostić, Marija and Erceg, Tamara and Jovanović, Tijana and Marković, Gordana and Marinović-Cincović, Milena",
year = "2023",
abstract = "In this work, betaine (trimethyl glycine) and tannin (complex biomolecules of polyphenolic nature) were used as bio-fillers. Urea-formaldehyde (UF) resin with a molar ratio of formaldehyde versus urea (FA/U) of 0.8 was synthesized in situ with tannin and betaine as bio-fillers, to obtain UF resin with reduced free FA content and increased hydrolytic and thermal stability by the principles of sustainability. The samples TUF (with tannin) and BUF (with betaine) were characterized by using X-ray diffraction analysis (XRD), non-isothermal thermogravimetric analysis (TGA), and differential thermal analysis (DTA), supported by data from Fourier Transform Infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM). The percentage of free FA in modified BUF resin is 0.1%, while the percentage of free FA in tannin-modified resin is 0.8%. The hydrolytic stability of the modified UF resins was determined by measuring the concentration of liberated FA in the modified UF resins, after acid hydrolysis. The modified BUF resin is hydrolytically more stable because the content of released FA is 3.6% compared to the modified TUF resin, where it was 7.4%. Based on the value for T5%, the more thermally stable resin is the modified TUF resin (T5% = 123.1°C), while the value of the T5% for the BUF resin is 83.1°C. This work showed how UF bio-composite with reduced free FA content and increased hydrolytic and thermal stability can be obtained using tannin and betaine as bio-fillers.",
journal = "Journal of Vinyl and Additive Technology",
title = "Hydrolytic and thermal stability of urea-formaldehyde resins based on tannin and betaine bio-fillers",
volume = "29",
number = "6",
pages = "1082-1092",
doi = "10.1002/vnl.22024"
}
Ristić, M., Samaržija-Jovanović, S., Jovanović, V., Kostić, M., Erceg, T., Jovanović, T., Marković, G.,& Marinović-Cincović, M.. (2023). Hydrolytic and thermal stability of urea-formaldehyde resins based on tannin and betaine bio-fillers. in Journal of Vinyl and Additive Technology, 29(6), 1082-1092.
https://doi.org/10.1002/vnl.22024
Ristić M, Samaržija-Jovanović S, Jovanović V, Kostić M, Erceg T, Jovanović T, Marković G, Marinović-Cincović M. Hydrolytic and thermal stability of urea-formaldehyde resins based on tannin and betaine bio-fillers. in Journal of Vinyl and Additive Technology. 2023;29(6):1082-1092.
doi:10.1002/vnl.22024 .
Ristić, Mirjana, Samaržija-Jovanović, Suzana, Jovanović, Vojislav, Kostić, Marija, Erceg, Tamara, Jovanović, Tijana, Marković, Gordana, Marinović-Cincović, Milena, "Hydrolytic and thermal stability of urea-formaldehyde resins based on tannin and betaine bio-fillers" in Journal of Vinyl and Additive Technology, 29, no. 6 (2023):1082-1092,
https://doi.org/10.1002/vnl.22024 . .
1

Thermal degradation of gamma irradiated elastomers based on different network precursors

Kojić, Dejan; Marković, Gordana; Jovanović, Vojislav; Marinović-Cincović, Milena; Erceg, Tamara; Samaržija-Jovanović, Suzana; Budinski-Simendić, Jaroslava

(RAD Association, Niš, Serbia, 2017)

TY  - CONF
AU  - Kojić, Dejan
AU  - Marković, Gordana
AU  - Jovanović, Vojislav
AU  - Marinović-Cincović, Milena
AU  - Erceg, Tamara
AU  - Samaržija-Jovanović, Suzana
AU  - Budinski-Simendić, Jaroslava
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11200
PB  - RAD Association, Niš, Serbia
C3  - RAD 2017 : 5th International Conference on Radiation in Various Fields of Research : book of abstracts; June 12-16, 2017; Budva, Montenegro
T1  - Thermal degradation of gamma irradiated elastomers based on different network precursors
SP  - 199
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11200
ER  - 
@conference{
author = "Kojić, Dejan and Marković, Gordana and Jovanović, Vojislav and Marinović-Cincović, Milena and Erceg, Tamara and Samaržija-Jovanović, Suzana and Budinski-Simendić, Jaroslava",
year = "2017",
publisher = "RAD Association, Niš, Serbia",
journal = "RAD 2017 : 5th International Conference on Radiation in Various Fields of Research : book of abstracts; June 12-16, 2017; Budva, Montenegro",
title = "Thermal degradation of gamma irradiated elastomers based on different network precursors",
pages = "199",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11200"
}
Kojić, D., Marković, G., Jovanović, V., Marinović-Cincović, M., Erceg, T., Samaržija-Jovanović, S.,& Budinski-Simendić, J.. (2017). Thermal degradation of gamma irradiated elastomers based on different network precursors. in RAD 2017 : 5th International Conference on Radiation in Various Fields of Research : book of abstracts; June 12-16, 2017; Budva, Montenegro
RAD Association, Niš, Serbia., 199.
https://hdl.handle.net/21.15107/rcub_vinar_11200
Kojić D, Marković G, Jovanović V, Marinović-Cincović M, Erceg T, Samaržija-Jovanović S, Budinski-Simendić J. Thermal degradation of gamma irradiated elastomers based on different network precursors. in RAD 2017 : 5th International Conference on Radiation in Various Fields of Research : book of abstracts; June 12-16, 2017; Budva, Montenegro. 2017;:199.
https://hdl.handle.net/21.15107/rcub_vinar_11200 .
Kojić, Dejan, Marković, Gordana, Jovanović, Vojislav, Marinović-Cincović, Milena, Erceg, Tamara, Samaržija-Jovanović, Suzana, Budinski-Simendić, Jaroslava, "Thermal degradation of gamma irradiated elastomers based on different network precursors" in RAD 2017 : 5th International Conference on Radiation in Various Fields of Research : book of abstracts; June 12-16, 2017; Budva, Montenegro (2017):199,
https://hdl.handle.net/21.15107/rcub_vinar_11200 .