Cupać, Svjetlana

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055c2b94-e1c5-490f-b64e-7c140298402d
  • Cupać, Svjetlana (3)
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Author's Bibliography

Soil humic acid aggregation by dynamic light scattering and laser Doppler electrophoresis

Jovanović, Uroš D.; Marković, Mirjana; Cupać, Svjetlana; Tomić, Zorica P.

(2013)

TY  - JOUR
AU  - Jovanović, Uroš D.
AU  - Marković, Mirjana
AU  - Cupać, Svjetlana
AU  - Tomić, Zorica P.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5778
AB  - Humic acids (HAs), similar to other fractions of humic substances (HSs), have a large number of reactive functional groups enabling them to aggregate in solutions. Regardless of the origin of humic acid (aqueous or soil), this aggregation process is dependent on environmental conditions and strongly influences the mobility of soluble ionic and molecular pollutants. The aim of this work was to monitor the aggregation process of two humic acids isolated from different mineral soils (IHSS Elliot soil HA standard and Rendzic Leptosol HA) in the 2-11 pH range. Changes in aggregate size in HA sols were followed up using dynamic light scattering (DLS), while zeta potential (ZP) measurements in the same pH range were performed applying laser Doppler electrophoresis (LDE) technique. The effect of HA sol concentration and soil source on aggregation was examined as well. Besides, HA samples were characterized using Fourier transform infrared (FT-IR) spectroscopy. By inspecting HA-particle-size dependence on pH, it can be concluded that both HAs in corresponding sols behave as molecular aggregates or supramolecular structures, formed from small individual moieties (sizes LT 10 nm) at higher pH values. The ZP vs. pH curve for both HAs revealed the ZP minimum in the 5-7 pH range, caused most likely by dissociation of acidic functional groups prevailing at lower pH values and deaggregation predominating over dissociation at higher pH values.
T2  - Journal of Plant Nutrition and Soil Science
T1  - Soil humic acid aggregation by dynamic light scattering and laser Doppler electrophoresis
VL  - 176
IS  - 5
SP  - 674
EP  - 679
DO  - 10.1002/jpln.201200346
ER  - 
@article{
author = "Jovanović, Uroš D. and Marković, Mirjana and Cupać, Svjetlana and Tomić, Zorica P.",
year = "2013",
abstract = "Humic acids (HAs), similar to other fractions of humic substances (HSs), have a large number of reactive functional groups enabling them to aggregate in solutions. Regardless of the origin of humic acid (aqueous or soil), this aggregation process is dependent on environmental conditions and strongly influences the mobility of soluble ionic and molecular pollutants. The aim of this work was to monitor the aggregation process of two humic acids isolated from different mineral soils (IHSS Elliot soil HA standard and Rendzic Leptosol HA) in the 2-11 pH range. Changes in aggregate size in HA sols were followed up using dynamic light scattering (DLS), while zeta potential (ZP) measurements in the same pH range were performed applying laser Doppler electrophoresis (LDE) technique. The effect of HA sol concentration and soil source on aggregation was examined as well. Besides, HA samples were characterized using Fourier transform infrared (FT-IR) spectroscopy. By inspecting HA-particle-size dependence on pH, it can be concluded that both HAs in corresponding sols behave as molecular aggregates or supramolecular structures, formed from small individual moieties (sizes LT 10 nm) at higher pH values. The ZP vs. pH curve for both HAs revealed the ZP minimum in the 5-7 pH range, caused most likely by dissociation of acidic functional groups prevailing at lower pH values and deaggregation predominating over dissociation at higher pH values.",
journal = "Journal of Plant Nutrition and Soil Science",
title = "Soil humic acid aggregation by dynamic light scattering and laser Doppler electrophoresis",
volume = "176",
number = "5",
pages = "674-679",
doi = "10.1002/jpln.201200346"
}
Jovanović, U. D., Marković, M., Cupać, S.,& Tomić, Z. P.. (2013). Soil humic acid aggregation by dynamic light scattering and laser Doppler electrophoresis. in Journal of Plant Nutrition and Soil Science, 176(5), 674-679.
https://doi.org/10.1002/jpln.201200346
Jovanović UD, Marković M, Cupać S, Tomić ZP. Soil humic acid aggregation by dynamic light scattering and laser Doppler electrophoresis. in Journal of Plant Nutrition and Soil Science. 2013;176(5):674-679.
doi:10.1002/jpln.201200346 .
Jovanović, Uroš D., Marković, Mirjana, Cupać, Svjetlana, Tomić, Zorica P., "Soil humic acid aggregation by dynamic light scattering and laser Doppler electrophoresis" in Journal of Plant Nutrition and Soil Science, 176, no. 5 (2013):674-679,
https://doi.org/10.1002/jpln.201200346 . .
26
21
30

Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia

Marković, Mirjana; Cupać, Svjetlana; Durovic, Rada; Milinovic, Jelena; Kljajic, Petar

(2010)

TY  - JOUR
AU  - Marković, Mirjana
AU  - Cupać, Svjetlana
AU  - Durovic, Rada
AU  - Milinovic, Jelena
AU  - Kljajic, Petar
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3888
AB  - This study was aimed to assess the levels of selected heavy metals and pesticides in soil and plant products from an agricultural area of Belgrade, Serbia and to indicate possible sources and risks of contamination. Soil, vegetable, and fruit samples from the most important agricultural city areas were collected from July to November of 2006. Metal contents were determined by atomic absorption spectrometry, whereas pesticide residues were analyzed by gas chromatography-mass spectrometry after extraction performed using solid-phase microextraction technique. Soil characterization based on the determination of selected physical and chemical properties revealed heterogeneous soils belonging to different soil groups. The concentrations of lead, cadmium, copper, and zinc in soil samples do not exceed the limits established by national and international regulations. Residues of the herbicide atrazine were detected in three soil samples, with levels lower than the relevant limit. The presence of other herbicides, namely prometryn, chloridazon, acetochlor, flurochloridone, and napropamide, was registered in some soil samples as well. Among the insecticides investigated in the soil, fenitrothion and chlorpyrifos were the only ones detected. In most of the investigated vegetable samples from the Obrenovac area, Pb and Cd contents are higher in comparison with the maximum levels, indicating the emission of coal combustion products from local thermal power plants as a possible source of contamination. Residue levels of some herbicides and insecticides (metribuzin, trifluralin, pendimethalin, bifenthrin, chlorpyrifos, and cypermethrin) determined in tomato, pepper, potato, and onion samples from Slanci, Ova, and Obrenovac areas are even several times higher than the maximum residue levels. Inappropriate use of these plant protection products is considered to be the most probable reason of contamination. Because increased levels of heavy metals and pesticide residues found in plant products could pose a risk to consumers health, their continual monitoring before product distribution to city markets is indispensable.
T2  - Archives of Environmental Contamination and Toxicology
T1  - Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia
VL  - 58
IS  - 2
SP  - 341
EP  - 351
DO  - 10.1007/s00244-009-9359-y
ER  - 
@article{
author = "Marković, Mirjana and Cupać, Svjetlana and Durovic, Rada and Milinovic, Jelena and Kljajic, Petar",
year = "2010",
abstract = "This study was aimed to assess the levels of selected heavy metals and pesticides in soil and plant products from an agricultural area of Belgrade, Serbia and to indicate possible sources and risks of contamination. Soil, vegetable, and fruit samples from the most important agricultural city areas were collected from July to November of 2006. Metal contents were determined by atomic absorption spectrometry, whereas pesticide residues were analyzed by gas chromatography-mass spectrometry after extraction performed using solid-phase microextraction technique. Soil characterization based on the determination of selected physical and chemical properties revealed heterogeneous soils belonging to different soil groups. The concentrations of lead, cadmium, copper, and zinc in soil samples do not exceed the limits established by national and international regulations. Residues of the herbicide atrazine were detected in three soil samples, with levels lower than the relevant limit. The presence of other herbicides, namely prometryn, chloridazon, acetochlor, flurochloridone, and napropamide, was registered in some soil samples as well. Among the insecticides investigated in the soil, fenitrothion and chlorpyrifos were the only ones detected. In most of the investigated vegetable samples from the Obrenovac area, Pb and Cd contents are higher in comparison with the maximum levels, indicating the emission of coal combustion products from local thermal power plants as a possible source of contamination. Residue levels of some herbicides and insecticides (metribuzin, trifluralin, pendimethalin, bifenthrin, chlorpyrifos, and cypermethrin) determined in tomato, pepper, potato, and onion samples from Slanci, Ova, and Obrenovac areas are even several times higher than the maximum residue levels. Inappropriate use of these plant protection products is considered to be the most probable reason of contamination. Because increased levels of heavy metals and pesticide residues found in plant products could pose a risk to consumers health, their continual monitoring before product distribution to city markets is indispensable.",
journal = "Archives of Environmental Contamination and Toxicology",
title = "Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia",
volume = "58",
number = "2",
pages = "341-351",
doi = "10.1007/s00244-009-9359-y"
}
Marković, M., Cupać, S., Durovic, R., Milinovic, J.,& Kljajic, P.. (2010). Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia. in Archives of Environmental Contamination and Toxicology, 58(2), 341-351.
https://doi.org/10.1007/s00244-009-9359-y
Marković M, Cupać S, Durovic R, Milinovic J, Kljajic P. Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia. in Archives of Environmental Contamination and Toxicology. 2010;58(2):341-351.
doi:10.1007/s00244-009-9359-y .
Marković, Mirjana, Cupać, Svjetlana, Durovic, Rada, Milinovic, Jelena, Kljajic, Petar, "Assessment of Heavy Metal and Pesticide Levels in Soil and Plant Products from Agricultural Area of Belgrade, Serbia" in Archives of Environmental Contamination and Toxicology, 58, no. 2 (2010):341-351,
https://doi.org/10.1007/s00244-009-9359-y . .
73
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78

Working in a difficult regime

Pešić, Milan P.; Cupać, Svjetlana

(1996)

TY  - JOUR
AU  - Pešić, Milan P.
AU  - Cupać, Svjetlana
PY  - 1996
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1955
T2  - Nuclear Engineering International
T1  - Working in a difficult regime
VL  - 41
IS  - 498
SP  - 40
EP  - 41
UR  - https://hdl.handle.net/21.15107/rcub_vinar_1955
ER  - 
@article{
author = "Pešić, Milan P. and Cupać, Svjetlana",
year = "1996",
journal = "Nuclear Engineering International",
title = "Working in a difficult regime",
volume = "41",
number = "498",
pages = "40-41",
url = "https://hdl.handle.net/21.15107/rcub_vinar_1955"
}
Pešić, M. P.,& Cupać, S.. (1996). Working in a difficult regime. in Nuclear Engineering International, 41(498), 40-41.
https://hdl.handle.net/21.15107/rcub_vinar_1955
Pešić MP, Cupać S. Working in a difficult regime. in Nuclear Engineering International. 1996;41(498):40-41.
https://hdl.handle.net/21.15107/rcub_vinar_1955 .
Pešić, Milan P., Cupać, Svjetlana, "Working in a difficult regime" in Nuclear Engineering International, 41, no. 498 (1996):40-41,
https://hdl.handle.net/21.15107/rcub_vinar_1955 .