TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Marić, Slađana
AU  - Jocić, Ana
AU  - Tekić, Danijela
AU  - Mušović, Jasmina
AU  - Amaral, Joana S.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13029
AB  - Polyphenols are natural compounds with enhanced antioxidant properties. They are present in relatively high concentrations in fruit/vegetable by-products. Therefore, there is a need for the development of efficient and cost-effective methods for the separation and purification of these valuable compounds. Traditional extraction with organic solvents needs to be switched to novel methods that are more efficient, with reduced extraction times and low consumption of organic solvents. Aiming at developing sustainable processes for the separation and purification of phenolic compounds, we used three model compounds, namely resveratrol, quercetin, and gallic acid, to investigate ionic liquid-based aqueous biphasic systems (IL-ABSs) formed by choliniumbased IL in combination with polypropylene glycol with a molecular mass of 400 g/mol (PPG400). The ABS composition in the two-phase region was selected according to a previously determined phase diagram. Extraction studies indicated the preferential partition of resveratrol and quercetin toward the hydrophobic PPG-rich phase that is mainly dominated by its hydrophobic nature and the strong salting-out effect of ILs. On the other hand, due to its considerably hydrophilic nature, gallic acid preferentially migrates toward the IL phase. The achieved results from grape stem extract demonstrated high extraction efficiencies of cholinium dihydrogen phosphate (~99% for resveratrol for the PPG phase and 78% for gallic acid for the IL phase), with considerable selectivity, demonstrating promising outcomes for potential applications.
T2  - Foods
T1  - Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product
VL  - 13
IS  - 6
SP  - 954
DO  - 10.3390/foods13060954
ER  - 

@article{
author = "Dimitrijević, Aleksandra and Marić, Slađana and Jocić, Ana and Tekić, Danijela and Mušović, Jasmina and Amaral, Joana S.",
year = "2024",
abstract = "Polyphenols are natural compounds with enhanced antioxidant properties. They are present in relatively high concentrations in fruit/vegetable by-products. Therefore, there is a need for the development of efficient and cost-effective methods for the separation and purification of these valuable compounds. Traditional extraction with organic solvents needs to be switched to novel methods that are more efficient, with reduced extraction times and low consumption of organic solvents. Aiming at developing sustainable processes for the separation and purification of phenolic compounds, we used three model compounds, namely resveratrol, quercetin, and gallic acid, to investigate ionic liquid-based aqueous biphasic systems (IL-ABSs) formed by choliniumbased IL in combination with polypropylene glycol with a molecular mass of 400 g/mol (PPG400). The ABS composition in the two-phase region was selected according to a previously determined phase diagram. Extraction studies indicated the preferential partition of resveratrol and quercetin toward the hydrophobic PPG-rich phase that is mainly dominated by its hydrophobic nature and the strong salting-out effect of ILs. On the other hand, due to its considerably hydrophilic nature, gallic acid preferentially migrates toward the IL phase. The achieved results from grape stem extract demonstrated high extraction efficiencies of cholinium dihydrogen phosphate (~99% for resveratrol for the PPG phase and 78% for gallic acid for the IL phase), with considerable selectivity, demonstrating promising outcomes for potential applications.",
journal = "Foods",
title = "Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product",
volume = "13",
number = "6",
pages = "954",
doi = "10.3390/foods13060954"
}

Dimitrijević, A., Marić, S., Jocić, A., Tekić, D., Mušović, J.,& Amaral, J. S.. (2024). Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product. in Foods, 13(6), 954.
https://doi.org/10.3390/foods13060954

Dimitrijević A, Marić S, Jocić A, Tekić D, Mušović J, Amaral JS. Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product. in Foods. 2024;13(6):954.
doi:10.3390/foods13060954 .

Dimitrijević, Aleksandra, Marić, Slađana, Jocić, Ana, Tekić, Danijela, Mušović, Jasmina, Amaral, Joana S., "Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product" in Foods, 13, no. 6 (2024):954,
https://doi.org/10.3390/foods13060954 . .

TY  - JOUR
AU  - Marić, Slađana
AU  - Jocić, Ana
AU  - Tekić, Danijela
AU  - Mušović, Jasmina
AU  - Milićević, Jelena
AU  - Dimitrijević, Aleksandra
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12838
AB  - This study explores the use of a series of cholinium ionic liquids (ILs) or salts in combination with polypropylene glycol 400 to form aqueous biphasic systems (ABS) for extracting various polarity pesticides (dicamba, clomazone, pyraclostrobin, and deltamethrin) from water. We assessed five cholinium-based salting-out agents ([Ch][DHP], [Ch]Cl, [Ch][Ac], [Ch][Lac], and [Ch][Nic]), chosen for their structural diversity and unique properties, such as high salting-out potential and different ability to undergo specific interactions. Liquid-liquid equilibrium phase diagrams were established, and partition experiments were conducted to evaluate extraction efficiency. Different partition patterns were obtained for studied pesticides, with [Ch][DHP] demonstrating the highest efficiency exceeding 90 % for each target pesticide due to its strong salting-out ability. On the other hand, more diverse partition trends due to specific interactions were obtained for low-melting cholinium-ILs ABS. The effect of pH and temperature on the partitioning behavior in [Ch][Ac]-based ABS highlighted the cholinium ILs extraction system's customizable nature. Focusing on [Ch]Cl for its eco-friendly aspects, widespread availability and excellent extraction performance, we optimized parameters for the removal of pesticides from real samples, applying the technology to spiked agricultural wastewater with an extraction efficiency of over 99 %. Our findings demonstrate the potential of cholinium-based IL-ABS in reducing environmental pollution through efficient pesticide extraction.
T2  - Separation and Purification Technology
T1  - Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters
VL  - 340
SP  - 126609
DO  - 10.1016/j.seppur.2024.126609
ER  - 

@article{
author = "Marić, Slađana and Jocić, Ana and Tekić, Danijela and Mušović, Jasmina and Milićević, Jelena and Dimitrijević, Aleksandra",
year = "2024",
abstract = "This study explores the use of a series of cholinium ionic liquids (ILs) or salts in combination with polypropylene glycol 400 to form aqueous biphasic systems (ABS) for extracting various polarity pesticides (dicamba, clomazone, pyraclostrobin, and deltamethrin) from water. We assessed five cholinium-based salting-out agents ([Ch][DHP], [Ch]Cl, [Ch][Ac], [Ch][Lac], and [Ch][Nic]), chosen for their structural diversity and unique properties, such as high salting-out potential and different ability to undergo specific interactions. Liquid-liquid equilibrium phase diagrams were established, and partition experiments were conducted to evaluate extraction efficiency. Different partition patterns were obtained for studied pesticides, with [Ch][DHP] demonstrating the highest efficiency exceeding 90 % for each target pesticide due to its strong salting-out ability. On the other hand, more diverse partition trends due to specific interactions were obtained for low-melting cholinium-ILs ABS. The effect of pH and temperature on the partitioning behavior in [Ch][Ac]-based ABS highlighted the cholinium ILs extraction system's customizable nature. Focusing on [Ch]Cl for its eco-friendly aspects, widespread availability and excellent extraction performance, we optimized parameters for the removal of pesticides from real samples, applying the technology to spiked agricultural wastewater with an extraction efficiency of over 99 %. Our findings demonstrate the potential of cholinium-based IL-ABS in reducing environmental pollution through efficient pesticide extraction.",
journal = "Separation and Purification Technology",
title = "Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters",
volume = "340",
pages = "126609",
doi = "10.1016/j.seppur.2024.126609"
}

Marić, S., Jocić, A., Tekić, D., Mušović, J., Milićević, J.,& Dimitrijević, A.. (2024). Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters. in Separation and Purification Technology, 340, 126609.
https://doi.org/10.1016/j.seppur.2024.126609

Marić S, Jocić A, Tekić D, Mušović J, Milićević J, Dimitrijević A. Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters. in Separation and Purification Technology. 2024;340:126609.
doi:10.1016/j.seppur.2024.126609 .

Marić, Slađana, Jocić, Ana, Tekić, Danijela, Mušović, Jasmina, Milićević, Jelena, Dimitrijević, Aleksandra, "Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters" in Separation and Purification Technology, 340 (2024):126609,
https://doi.org/10.1016/j.seppur.2024.126609 . .

TY  - JOUR
AU  - Ražić, Slavica
AU  - Arsenijević, Jelena
AU  - Đogo Mračević, Svetlana
AU  - Mušović, Jasmina
AU  - Trtić-Petrović, Tatjana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11222
AB  - More environment-friendly solvents in analytical chemistry are almost inevitable in both sample preparation and analysis to meet the high standards of sustainable chemistry and human welfare. In this review paper, a critical look at the advantages and still unsolved problems of most potential classes of green solvents is presented to give an overview of the current state-of-the-art in this field. Replacing volatile organic compounds (VOCs) by ecofriendly and benign solvents in extractions/separations in sample preparation, as the most tedious and demanding step in analysis, is one of roads toward sustainable chemistry. Water under sub- and supercritical conditions, carbon-dioxide, ionic liquids (ILs), deep eutectic solvents (DESs), and those of natural origin (NADES) belong to the most promising classes of solvents in green analytical chemistry. Basic theory and mechanisms of their use illustrated by representative but not exhaustive list of examples related to complex matrices (environmental and natural food products) from analytical practice are presented in this review. Perspectives of QuEChERS, in line with GAC principles, are highlighted, in line with current trends of “going green” for quick, easy, cheap, effective, rugged, and safe analytical methods. Compliance with green chemistry (GC), especially green analytical chemistry (GAC) principles, is not a fashionable issue but, more the trend toward a sustainable future with greener chemistry; thus, green metrics are an unavoidable tool to measure how green the applied method or procedure is. Herein, the most common tools will be presented and discussed, such as national environmental method index (NEMI), analytical ecoscale, green analytical procedure index (GAPI), analytical greenness calculator (AGREE), complementary green analytical procedure index (ComplexGAPI), and analytical greenness metric for sample preparation (AGREEprep). The future trends for research and development in this still expanding field are presented in a critical view of advantages and disadvantages as well as improvement of the validation of analytical procedures. The creation of new certified reference materials (CRMs) and validated methods for specified analytes in complex matrices is a demanding task in the coming years. Tailor-made solvents with physicochemical properties for intended use are required for the selective extraction and separation and open numerous possibilities and huge potential for future research and industrial applications.
T2  - Analyst
T1  - Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review
VL  - 148
IS  - 14
SP  - 3130
EP  - 3152
DO  - 10.1039/D3AN00498H
ER  - 

@article{
author = "Ražić, Slavica and Arsenijević, Jelena and Đogo Mračević, Svetlana and Mušović, Jasmina and Trtić-Petrović, Tatjana",
year = "2023",
abstract = "More environment-friendly solvents in analytical chemistry are almost inevitable in both sample preparation and analysis to meet the high standards of sustainable chemistry and human welfare. In this review paper, a critical look at the advantages and still unsolved problems of most potential classes of green solvents is presented to give an overview of the current state-of-the-art in this field. Replacing volatile organic compounds (VOCs) by ecofriendly and benign solvents in extractions/separations in sample preparation, as the most tedious and demanding step in analysis, is one of roads toward sustainable chemistry. Water under sub- and supercritical conditions, carbon-dioxide, ionic liquids (ILs), deep eutectic solvents (DESs), and those of natural origin (NADES) belong to the most promising classes of solvents in green analytical chemistry. Basic theory and mechanisms of their use illustrated by representative but not exhaustive list of examples related to complex matrices (environmental and natural food products) from analytical practice are presented in this review. Perspectives of QuEChERS, in line with GAC principles, are highlighted, in line with current trends of “going green” for quick, easy, cheap, effective, rugged, and safe analytical methods. Compliance with green chemistry (GC), especially green analytical chemistry (GAC) principles, is not a fashionable issue but, more the trend toward a sustainable future with greener chemistry; thus, green metrics are an unavoidable tool to measure how green the applied method or procedure is. Herein, the most common tools will be presented and discussed, such as national environmental method index (NEMI), analytical ecoscale, green analytical procedure index (GAPI), analytical greenness calculator (AGREE), complementary green analytical procedure index (ComplexGAPI), and analytical greenness metric for sample preparation (AGREEprep). The future trends for research and development in this still expanding field are presented in a critical view of advantages and disadvantages as well as improvement of the validation of analytical procedures. The creation of new certified reference materials (CRMs) and validated methods for specified analytes in complex matrices is a demanding task in the coming years. Tailor-made solvents with physicochemical properties for intended use are required for the selective extraction and separation and open numerous possibilities and huge potential for future research and industrial applications.",
journal = "Analyst",
title = "Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review",
volume = "148",
number = "14",
pages = "3130-3152",
doi = "10.1039/D3AN00498H"
}

Ražić, S., Arsenijević, J., Đogo Mračević, S., Mušović, J.,& Trtić-Petrović, T.. (2023). Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review. in Analyst, 148(14), 3130-3152.
https://doi.org/10.1039/D3AN00498H

Ražić S, Arsenijević J, Đogo Mračević S, Mušović J, Trtić-Petrović T. Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review. in Analyst. 2023;148(14):3130-3152.
doi:10.1039/D3AN00498H .

Ražić, Slavica, Arsenijević, Jelena, Đogo Mračević, Svetlana, Mušović, Jasmina, Trtić-Petrović, Tatjana, "Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review" in Analyst, 148, no. 14 (2023):3130-3152,
https://doi.org/10.1039/D3AN00498H . .

TY  - CONF
AU  - Mušović, Jasmina
AU  - Marić, Slađana
AU  - Jocić, Ana
AU  - Milićević, Jelena
AU  - Stanković, Dalibor
AU  - Dimitrijević, Aleksandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11961
AB  - Temperature- and pH-responsive ionic liquid-based aqueous biphasic systems (IL-ABS) have been proposed as a viable and sustainable extraction/separation processes. Combining a thermosensitive polymer (such as polypropylene glycol-400, PPG400) and a pH-sensitive IL (such as choline-acetate, [Ch][Ac] as the phase-forming agents, we have tried to develop an efficient extraction platform for removing the pollutants from wastewater, namely herbicide dicamba (DIC) and insecticide deltamethrin (DLM). First, the ABS ternary phase diagrams are determined at different temperatures (25, 35 and 45°C) and pH values (2, 5, 6, and 7). The operational extraction composition was chosen to fit within the biphase region of each ABS, namely 15 wt% of IL and 40 wt% of polymer. Subsequently, extraction parameters were determined for each target compound (using high-performance chromatography) at different temperatures and pH values. Initially, polar pesticide dicamba migrated preferentially toward the IL-rich phase while deltamethrin showed the opposite direction at room temperature and pH 7. Obtained extraction efficiencies were about 93% and 23% for DLM and DIC, respectively, toward polymer-rich phase. The ability to simultaneously respond to two stimuli, in this case, temperature and pH, allowed us to obtain highly efficient extraction by changing stimuli-inducing parameters. At pH=2 and T=25°C extraction efficiencies higher than 96% for DLM and 83% for DIC were acquired. Therefore, by adjusting the applied stimuli, ABS can improve the performance resulting in the successful removal of pesticides from the aqueous phase, regardless of their polarity. This remarkable capability makes these ABSs highly appealing for designing wastewater treatment processes.
PB  - University of Belgrade : Faculty of Chemistry
C3  - YISAC 2023 : 28th Young Investigators' Seminar on Analytical Chemistry : the book of abstracts
T1  - Responsive Ionic Liquid-Based Aqueous Biphasic Systems as Efficient Extraction Platform for Sustainable Removal of Pesticides from Wastewater
SP  - 31
EP  - 31
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11961
ER  - 

@conference{
author = "Mušović, Jasmina and Marić, Slađana and Jocić, Ana and Milićević, Jelena and Stanković, Dalibor and Dimitrijević, Aleksandra",
year = "2023",
abstract = "Temperature- and pH-responsive ionic liquid-based aqueous biphasic systems (IL-ABS) have been proposed as a viable and sustainable extraction/separation processes. Combining a thermosensitive polymer (such as polypropylene glycol-400, PPG400) and a pH-sensitive IL (such as choline-acetate, [Ch][Ac] as the phase-forming agents, we have tried to develop an efficient extraction platform for removing the pollutants from wastewater, namely herbicide dicamba (DIC) and insecticide deltamethrin (DLM). First, the ABS ternary phase diagrams are determined at different temperatures (25, 35 and 45°C) and pH values (2, 5, 6, and 7). The operational extraction composition was chosen to fit within the biphase region of each ABS, namely 15 wt% of IL and 40 wt% of polymer. Subsequently, extraction parameters were determined for each target compound (using high-performance chromatography) at different temperatures and pH values. Initially, polar pesticide dicamba migrated preferentially toward the IL-rich phase while deltamethrin showed the opposite direction at room temperature and pH 7. Obtained extraction efficiencies were about 93% and 23% for DLM and DIC, respectively, toward polymer-rich phase. The ability to simultaneously respond to two stimuli, in this case, temperature and pH, allowed us to obtain highly efficient extraction by changing stimuli-inducing parameters. At pH=2 and T=25°C extraction efficiencies higher than 96% for DLM and 83% for DIC were acquired. Therefore, by adjusting the applied stimuli, ABS can improve the performance resulting in the successful removal of pesticides from the aqueous phase, regardless of their polarity. This remarkable capability makes these ABSs highly appealing for designing wastewater treatment processes.",
publisher = "University of Belgrade : Faculty of Chemistry",
journal = "YISAC 2023 : 28th Young Investigators' Seminar on Analytical Chemistry : the book of abstracts",
title = "Responsive Ionic Liquid-Based Aqueous Biphasic Systems as Efficient Extraction Platform for Sustainable Removal of Pesticides from Wastewater",
pages = "31-31",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11961"
}

Mušović, J., Marić, S., Jocić, A., Milićević, J., Stanković, D.,& Dimitrijević, A.. (2023). Responsive Ionic Liquid-Based Aqueous Biphasic Systems as Efficient Extraction Platform for Sustainable Removal of Pesticides from Wastewater. in YISAC 2023 : 28th Young Investigators' Seminar on Analytical Chemistry : the book of abstracts
University of Belgrade : Faculty of Chemistry., 31-31.
https://hdl.handle.net/21.15107/rcub_vinar_11961

Mušović J, Marić S, Jocić A, Milićević J, Stanković D, Dimitrijević A. Responsive Ionic Liquid-Based Aqueous Biphasic Systems as Efficient Extraction Platform for Sustainable Removal of Pesticides from Wastewater. in YISAC 2023 : 28th Young Investigators' Seminar on Analytical Chemistry : the book of abstracts. 2023;:31-31.
https://hdl.handle.net/21.15107/rcub_vinar_11961 .

Mušović, Jasmina, Marić, Slađana, Jocić, Ana, Milićević, Jelena, Stanković, Dalibor, Dimitrijević, Aleksandra, "Responsive Ionic Liquid-Based Aqueous Biphasic Systems as Efficient Extraction Platform for Sustainable Removal of Pesticides from Wastewater" in YISAC 2023 : 28th Young Investigators' Seminar on Analytical Chemistry : the book of abstracts (2023):31-31,
https://hdl.handle.net/21.15107/rcub_vinar_11961 .

TY  - CONF
AU  - Mrđa, Dragoslav
AU  - Vučićević, Biljana
AU  - Mušović, Jasmina
AU  - Marinović-Cincović, Milena
AU  - Trtić-Petrović, Tatjana
AU  - Mladenović, Milica
AU  - Turanjanin, Valentina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12652
AB  - Phase change materials (PCM) are attractive energy storage technologies due to their high energy storage density and the ability to reversible absorb and release thermal energy at a nearly constant temperature. Polymers and polymer-based eutectic mixtures are promising PCMs. This study aims to investigate heat properties (melting temperature (Tm), latent heat (ΔH) and thermal conductivity(λ)) of potential PCMs based on polyethylene glycol polymer (PEG2000). We prepared following two and three components materials: PEG2000: ethylene glycol (5:6): PEG2000: PPG 400 (1:5); PEG2000: PPG400: Choline chloride (2:2:15); PEG2000: ethylene glycol (5:6); PEG2000: Glyoxal (5:2). The prepared three components material belong to deep eutectic solvents. Tm of the prepared materials are lower compared to pure PEG2000 (Tm = 57 ºC) e.g. Tm of PEG2000: PPG400: Choline chloride is 43 ºC. The determined melting enthalpies are also lower for prepared materials compared to PEG2000. This decrease is lower for eutectic mixture such as PEG2000: Choline chloride: ethylene glycol. We can conclude based on the obtained result that eutectic mixtures based on polymers are promising PCMs.
PB  - Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM
C3  - XII International conference on social and technological development : Proceedings
T1  - The possibility of using polymer-based phase change materials for thermal energy storage
SP  - 465
EP  - 470
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12652
ER  - 

@conference{
author = "Mrđa, Dragoslav and Vučićević, Biljana and Mušović, Jasmina and Marinović-Cincović, Milena and Trtić-Petrović, Tatjana and Mladenović, Milica and Turanjanin, Valentina",
year = "2023",
abstract = "Phase change materials (PCM) are attractive energy storage technologies due to their high energy storage density and the ability to reversible absorb and release thermal energy at a nearly constant temperature. Polymers and polymer-based eutectic mixtures are promising PCMs. This study aims to investigate heat properties (melting temperature (Tm), latent heat (ΔH) and thermal conductivity(λ)) of potential PCMs based on polyethylene glycol polymer (PEG2000). We prepared following two and three components materials: PEG2000: ethylene glycol (5:6): PEG2000: PPG 400 (1:5); PEG2000: PPG400: Choline chloride (2:2:15); PEG2000: ethylene glycol (5:6); PEG2000: Glyoxal (5:2). The prepared three components material belong to deep eutectic solvents. Tm of the prepared materials are lower compared to pure PEG2000 (Tm = 57 ºC) e.g. Tm of PEG2000: PPG400: Choline chloride is 43 ºC. The determined melting enthalpies are also lower for prepared materials compared to PEG2000. This decrease is lower for eutectic mixture such as PEG2000: Choline chloride: ethylene glycol. We can conclude based on the obtained result that eutectic mixtures based on polymers are promising PCMs.",
publisher = "Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM",
journal = "XII International conference on social and technological development : Proceedings",
title = "The possibility of using polymer-based phase change materials for thermal energy storage",
pages = "465-470",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12652"
}

Mrđa, D., Vučićević, B., Mušović, J., Marinović-Cincović, M., Trtić-Petrović, T., Mladenović, M.,& Turanjanin, V.. (2023). The possibility of using polymer-based phase change materials for thermal energy storage. in XII International conference on social and technological development : Proceedings
Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM., 465-470.
https://hdl.handle.net/21.15107/rcub_vinar_12652

Mrđa D, Vučićević B, Mušović J, Marinović-Cincović M, Trtić-Petrović T, Mladenović M, Turanjanin V. The possibility of using polymer-based phase change materials for thermal energy storage. in XII International conference on social and technological development : Proceedings. 2023;:465-470.
https://hdl.handle.net/21.15107/rcub_vinar_12652 .

Mrđa, Dragoslav, Vučićević, Biljana, Mušović, Jasmina, Marinović-Cincović, Milena, Trtić-Petrović, Tatjana, Mladenović, Milica, Turanjanin, Valentina, "The possibility of using polymer-based phase change materials for thermal energy storage" in XII International conference on social and technological development : Proceedings (2023):465-470,
https://hdl.handle.net/21.15107/rcub_vinar_12652 .

TY  - JOUR
AU  - Lazarević, Dajana
AU  - Mušović, Jasmina
AU  - Trtić-Petrović, Tatjana M.
AU  - Gadžurić, Slobodan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10772
AB  - In this work, aqueous biphasic systems (ABSs) formed by copolymers, ionic liquids (ILs) and natural deep eutectic solvents (NADES) have been demonstrated to be effective separation platforms for the extraction of hydrophobic pharmaceutical ingredients such as parthenolide (PAR). This work addresses the determination of the liquid–liquid equilibrium of ABS composed of choline lactate IL or choline chloride – lactic acid NADES and two different block copolymers Pluronic (PL17R4 and PL10R5), and their influence on the ABS formation and extraction efficiency of PAR. The ability of Pluronics to form ABS is compared to widely used polypropylene glycol polymer (PPG400). Comparing the effect of the ionic liquid and NADES on the ABS formation, it is shown that both salting-our reagents successfully form ABS and do not affect the extraction efficiency of PAR. The main influence on the high parthenolide extraction efficiency (>96%) is governed by the hydrophobic interactions between Pluronic and investigated compound, regardless on the applied salting-out reagent. Due to a high extraction efficiency achieved in PL-rich phase and promissing medical features of PAR, obtained results showed that this phase could be used as biocompatible drug delivery system. Avoiding commercially available organic solvents, elevated temperatures and pressure, the proposed method is greener alternative for PAR extraction.
T2  - Separation and Purification Technology
T1  - Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems
VL  - 314
SP  - 123653
DO  - 10.1016/j.seppur.2023.123653
ER  - 

@article{
author = "Lazarević, Dajana and Mušović, Jasmina and Trtić-Petrović, Tatjana M. and Gadžurić, Slobodan",
year = "2023",
abstract = "In this work, aqueous biphasic systems (ABSs) formed by copolymers, ionic liquids (ILs) and natural deep eutectic solvents (NADES) have been demonstrated to be effective separation platforms for the extraction of hydrophobic pharmaceutical ingredients such as parthenolide (PAR). This work addresses the determination of the liquid–liquid equilibrium of ABS composed of choline lactate IL or choline chloride – lactic acid NADES and two different block copolymers Pluronic (PL17R4 and PL10R5), and their influence on the ABS formation and extraction efficiency of PAR. The ability of Pluronics to form ABS is compared to widely used polypropylene glycol polymer (PPG400). Comparing the effect of the ionic liquid and NADES on the ABS formation, it is shown that both salting-our reagents successfully form ABS and do not affect the extraction efficiency of PAR. The main influence on the high parthenolide extraction efficiency (>96%) is governed by the hydrophobic interactions between Pluronic and investigated compound, regardless on the applied salting-out reagent. Due to a high extraction efficiency achieved in PL-rich phase and promissing medical features of PAR, obtained results showed that this phase could be used as biocompatible drug delivery system. Avoiding commercially available organic solvents, elevated temperatures and pressure, the proposed method is greener alternative for PAR extraction.",
journal = "Separation and Purification Technology",
title = "Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems",
volume = "314",
pages = "123653",
doi = "10.1016/j.seppur.2023.123653"
}

Lazarević, D., Mušović, J., Trtić-Petrović, T. M.,& Gadžurić, S.. (2023). Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems. in Separation and Purification Technology, 314, 123653.
https://doi.org/10.1016/j.seppur.2023.123653

Lazarević D, Mušović J, Trtić-Petrović TM, Gadžurić S. Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems. in Separation and Purification Technology. 2023;314:123653.
doi:10.1016/j.seppur.2023.123653 .

Lazarević, Dajana, Mušović, Jasmina, Trtić-Petrović, Tatjana M., Gadžurić, Slobodan, "Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems" in Separation and Purification Technology, 314 (2023):123653,
https://doi.org/10.1016/j.seppur.2023.123653 . .

TY  - JOUR
AU  - Mušović, Jasmina
AU  - Vraneš, Milan
AU  - Papović, Snežana
AU  - Gadžurić, Slobodan
AU  - Ražić, Slavica
AU  - Trtić-Petrović, Tatjana M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10596
AB  - Although sample preparation, as an unavoidable step of the analytical process should be simple, it is very often identified as a bottleneck. Simplicity of sample preparation based on cost-effective and non-hazardous materials is mandatory for any sustainable and environmental friendly approach. Aqueous biphasic systems (ABS), based on functionalized ionic liquids (FILs) are acceptable alternatives to classical extraction procedures, due to the replacement of organic solvent with diluted aqueous-soluble ionic liquids. In this work, two water soluble FILs based on 2-mercaptobenzothiazolate anion, [mbt]: 1-butyl-3-methylimidazolium [mbt] ([bmim][mbt]) and 1-ethyl-3-methylimidazolium [mbt] ([emim][mbt]), were designed and synthesized in order to selectively extract Cd(II) and Pb(II) from the river sediment. It was found that [mbt]– anion acts as the ligand and forms complexes with Cd(II) and Pb(II) which are responsible for their efficient extraction, while cation is more responsible for the formation of ABS. Partition coefficients of 408 and 180 for Cd(II) and Pb(II), respectively, were obtained using ABS based on [bmim][mbt]. Direct extraction of Cd(II) and Pb(II) from the river sediment has been investigated and obtained optimal conditions are: 60 min direct contact of the aqueous solution of [bmim][mbt] and the sediment sample at 90 °C, followed by formation of ABS upon addition of potassium citrate. Using AGRE and AGREEprep tools greenness of the proposed method for direct extraction of Cd(II) and Pb(II) from the sediment are calculated. Obtained values of 0.69 and 0.71 for Cd(II) and Pb(II) extraction, respectively, showed a high level of the greenness of the proposed method.
T2  - Journal of Molecular Liquids
T1  - Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids
VL  - 369
SP  - 120974
DO  - 10.1016/j.molliq.2022.120974
ER  - 

@article{
author = "Mušović, Jasmina and Vraneš, Milan and Papović, Snežana and Gadžurić, Slobodan and Ražić, Slavica and Trtić-Petrović, Tatjana M.",
year = "2023",
abstract = "Although sample preparation, as an unavoidable step of the analytical process should be simple, it is very often identified as a bottleneck. Simplicity of sample preparation based on cost-effective and non-hazardous materials is mandatory for any sustainable and environmental friendly approach. Aqueous biphasic systems (ABS), based on functionalized ionic liquids (FILs) are acceptable alternatives to classical extraction procedures, due to the replacement of organic solvent with diluted aqueous-soluble ionic liquids. In this work, two water soluble FILs based on 2-mercaptobenzothiazolate anion, [mbt]: 1-butyl-3-methylimidazolium [mbt] ([bmim][mbt]) and 1-ethyl-3-methylimidazolium [mbt] ([emim][mbt]), were designed and synthesized in order to selectively extract Cd(II) and Pb(II) from the river sediment. It was found that [mbt]– anion acts as the ligand and forms complexes with Cd(II) and Pb(II) which are responsible for their efficient extraction, while cation is more responsible for the formation of ABS. Partition coefficients of 408 and 180 for Cd(II) and Pb(II), respectively, were obtained using ABS based on [bmim][mbt]. Direct extraction of Cd(II) and Pb(II) from the river sediment has been investigated and obtained optimal conditions are: 60 min direct contact of the aqueous solution of [bmim][mbt] and the sediment sample at 90 °C, followed by formation of ABS upon addition of potassium citrate. Using AGRE and AGREEprep tools greenness of the proposed method for direct extraction of Cd(II) and Pb(II) from the sediment are calculated. Obtained values of 0.69 and 0.71 for Cd(II) and Pb(II) extraction, respectively, showed a high level of the greenness of the proposed method.",
journal = "Journal of Molecular Liquids",
title = "Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids",
volume = "369",
pages = "120974",
doi = "10.1016/j.molliq.2022.120974"
}

Mušović, J., Vraneš, M., Papović, S., Gadžurić, S., Ražić, S.,& Trtić-Petrović, T. M.. (2023). Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids. in Journal of Molecular Liquids, 369, 120974.
https://doi.org/10.1016/j.molliq.2022.120974

Mušović J, Vraneš M, Papović S, Gadžurić S, Ražić S, Trtić-Petrović TM. Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids. in Journal of Molecular Liquids. 2023;369:120974.
doi:10.1016/j.molliq.2022.120974 .

Mušović, Jasmina, Vraneš, Milan, Papović, Snežana, Gadžurić, Slobodan, Ražić, Slavica, Trtić-Petrović, Tatjana M., "Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids" in Journal of Molecular Liquids, 369 (2023):120974,
https://doi.org/10.1016/j.molliq.2022.120974 . .