TY  - JOUR
AU  - Bošković, Marko
AU  - Perović, Marija M.
AU  - Vučinić-Vasić, Milica
AU  - Spasojević, Vojislav
AU  - Stojanovic, G.
AU  - Antić, Bratislav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6005
AB  - Influence of thermal-annealing-controlled crystallite size on the magnetic/electric properties of Yb substituted Zn-ferrite nanoparticles (ZnFe1.95Yb0.05O4) is studied, and results of the analysis are presented here. Room temperature Mossbauer spectrum of as-prepared sample shows coexistence of the sextet/doublet structure due to the particle size distribution. The central doublet originating from superparamagnetic relaxations of smaller particles is found to constitute the major fraction of the Fe-57 signal in samples obtained by thermal annealing of as-prepared sample at various temperatures in 300 degrees C-800 degrees C range. The determined quadrupole splitting (QS) parameters are significantly higher compared to corresponding bulk counterpart value and display decreasing trend with the crystallite size increase. The similar to 29 nm-sample, obtained by annealing at 800 degrees C, shows bulk-like properties, both in terms of the observed QS value and observed distribution of iron ions within the spinel lattice. Electric resistivity has non-monotonic dependence on crystallite-size, which could be attributed to enhanced disorder in as-prepared material. Partial substitution of iron by ytterbium in Zn-ferrite is found to increase the dielectric constant.
T2  - Nanoscience and Nanotechnology Letters
T1  - Mossbauer Spectra and Crystallite Size Related Magnetic/Electric Properties of Yb Substituted Zn-Ferrite Nanoparticles
VL  - 6
IS  - 4
SP  - 314
EP  - 318
DO  - 10.1166/nnl.2014.1758
ER  - 

@article{
author = "Bošković, Marko and Perović, Marija M. and Vučinić-Vasić, Milica and Spasojević, Vojislav and Stojanovic, G. and Antić, Bratislav",
year = "2014",
abstract = "Influence of thermal-annealing-controlled crystallite size on the magnetic/electric properties of Yb substituted Zn-ferrite nanoparticles (ZnFe1.95Yb0.05O4) is studied, and results of the analysis are presented here. Room temperature Mossbauer spectrum of as-prepared sample shows coexistence of the sextet/doublet structure due to the particle size distribution. The central doublet originating from superparamagnetic relaxations of smaller particles is found to constitute the major fraction of the Fe-57 signal in samples obtained by thermal annealing of as-prepared sample at various temperatures in 300 degrees C-800 degrees C range. The determined quadrupole splitting (QS) parameters are significantly higher compared to corresponding bulk counterpart value and display decreasing trend with the crystallite size increase. The similar to 29 nm-sample, obtained by annealing at 800 degrees C, shows bulk-like properties, both in terms of the observed QS value and observed distribution of iron ions within the spinel lattice. Electric resistivity has non-monotonic dependence on crystallite-size, which could be attributed to enhanced disorder in as-prepared material. Partial substitution of iron by ytterbium in Zn-ferrite is found to increase the dielectric constant.",
journal = "Nanoscience and Nanotechnology Letters",
title = "Mossbauer Spectra and Crystallite Size Related Magnetic/Electric Properties of Yb Substituted Zn-Ferrite Nanoparticles",
volume = "6",
number = "4",
pages = "314-318",
doi = "10.1166/nnl.2014.1758"
}

Bošković, M., Perović, M. M., Vučinić-Vasić, M., Spasojević, V., Stojanovic, G.,& Antić, B.. (2014). Mossbauer Spectra and Crystallite Size Related Magnetic/Electric Properties of Yb Substituted Zn-Ferrite Nanoparticles. in Nanoscience and Nanotechnology Letters, 6(4), 314-318.
https://doi.org/10.1166/nnl.2014.1758

Bošković M, Perović MM, Vučinić-Vasić M, Spasojević V, Stojanovic G, Antić B. Mossbauer Spectra and Crystallite Size Related Magnetic/Electric Properties of Yb Substituted Zn-Ferrite Nanoparticles. in Nanoscience and Nanotechnology Letters. 2014;6(4):314-318.
doi:10.1166/nnl.2014.1758 .

Bošković, Marko, Perović, Marija M., Vučinić-Vasić, Milica, Spasojević, Vojislav, Stojanovic, G., Antić, Bratislav, "Mossbauer Spectra and Crystallite Size Related Magnetic/Electric Properties of Yb Substituted Zn-Ferrite Nanoparticles" in Nanoscience and Nanotechnology Letters, 6, no. 4 (2014):314-318,
https://doi.org/10.1166/nnl.2014.1758 . .

TY  - JOUR
AU  - Vučinić-Vasić, Milica
AU  - Božin, Emil S.
AU  - Bessais, Lotfi
AU  - Stojanovic, G.
AU  - Kozmidis-Luburic, U.
AU  - Abeykoon, M.
AU  - Jančar, Boštjan
AU  - Meden, A.
AU  - Kremenović, Aleksandar S.
AU  - Antić, Bratislav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5555
AB  - Evolution of the structural and magnetic properties of ZnFe1.95Yb0.05O4 nanoparticles, prepared via a high-energy ball milling route and exposed to further thermal annealing/heating, was assessed in detail and correlation of these properties explored. inversion, heating of the sample to similar to 500 degrees C is found to rapidly alter the cation distribution from mixed to normal, in agreement with the known cation preferences. Under the same conditions the crystallite size only slowly grows. By further thermal treatment appreciably. An interrelationship among the lattice parameter, octahedral site occupancy, and crystallite size has been established. The observations are (a) both the site occupancy of Fe3+ at octahedral 16d spinel sites (N-16d(Fe3+)) and the cubic lattice parameter rapidly increase with an initial increase of the crystallite size, (b) the lattice parameter increases with increasing occupancy, N-16d(Fe3+), and (c) there appears to be a critical nanoparticle diameter (approximately 15 nm) above which both the site occupancy and lattice parameter values are saturated. The magnetic behavior of the annealed samples appears to be correlated to the evolution of both the cation distribution and crystallite size, as follows. As-prepared samples and those annealed at lower temperatures show superparamagnetic behavior at room temperature, presumably as a consequence of the Fe3+ distribution and strong Fe3+(8a)-O-Fe3+(16d) superexchange interactions. Samples with a nanopartide diameter greater than 12 nm and with almost normal distributions exhibit the paramagnetic state. The coercive field is found to decrease with an increase of the crystallite size. Partial Yb3+/Fe3+ substitution is found to increase the inversion parameter and saturation magnetization. Detailed knowledge of the thermal evolution of structural/microstructural parameters allows control over the cation distribution and crystallite size and hence the magnetic properties of nanoferrites.
T2  - Journal of Physical Chemistry. C
T1  - Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles
VL  - 117
IS  - 23
SP  - 12358
EP  - 12365
DO  - 10.1021/jp403459t
ER  - 

@article{
author = "Vučinić-Vasić, Milica and Božin, Emil S. and Bessais, Lotfi and Stojanovic, G. and Kozmidis-Luburic, U. and Abeykoon, M. and Jančar, Boštjan and Meden, A. and Kremenović, Aleksandar S. and Antić, Bratislav",
year = "2013",
abstract = "Evolution of the structural and magnetic properties of ZnFe1.95Yb0.05O4 nanoparticles, prepared via a high-energy ball milling route and exposed to further thermal annealing/heating, was assessed in detail and correlation of these properties explored. inversion, heating of the sample to similar to 500 degrees C is found to rapidly alter the cation distribution from mixed to normal, in agreement with the known cation preferences. Under the same conditions the crystallite size only slowly grows. By further thermal treatment appreciably. An interrelationship among the lattice parameter, octahedral site occupancy, and crystallite size has been established. The observations are (a) both the site occupancy of Fe3+ at octahedral 16d spinel sites (N-16d(Fe3+)) and the cubic lattice parameter rapidly increase with an initial increase of the crystallite size, (b) the lattice parameter increases with increasing occupancy, N-16d(Fe3+), and (c) there appears to be a critical nanoparticle diameter (approximately 15 nm) above which both the site occupancy and lattice parameter values are saturated. The magnetic behavior of the annealed samples appears to be correlated to the evolution of both the cation distribution and crystallite size, as follows. As-prepared samples and those annealed at lower temperatures show superparamagnetic behavior at room temperature, presumably as a consequence of the Fe3+ distribution and strong Fe3+(8a)-O-Fe3+(16d) superexchange interactions. Samples with a nanopartide diameter greater than 12 nm and with almost normal distributions exhibit the paramagnetic state. The coercive field is found to decrease with an increase of the crystallite size. Partial Yb3+/Fe3+ substitution is found to increase the inversion parameter and saturation magnetization. Detailed knowledge of the thermal evolution of structural/microstructural parameters allows control over the cation distribution and crystallite size and hence the magnetic properties of nanoferrites.",
journal = "Journal of Physical Chemistry. C",
title = "Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles",
volume = "117",
number = "23",
pages = "12358-12365",
doi = "10.1021/jp403459t"
}

Vučinić-Vasić, M., Božin, E. S., Bessais, L., Stojanovic, G., Kozmidis-Luburic, U., Abeykoon, M., Jančar, B., Meden, A., Kremenović, A. S.,& Antić, B.. (2013). Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles. in Journal of Physical Chemistry. C, 117(23), 12358-12365.
https://doi.org/10.1021/jp403459t

Vučinić-Vasić M, Božin ES, Bessais L, Stojanovic G, Kozmidis-Luburic U, Abeykoon M, Jančar B, Meden A, Kremenović AS, Antić B. Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles. in Journal of Physical Chemistry. C. 2013;117(23):12358-12365.
doi:10.1021/jp403459t .

Vučinić-Vasić, Milica, Božin, Emil S., Bessais, Lotfi, Stojanovic, G., Kozmidis-Luburic, U., Abeykoon, M., Jančar, Boštjan, Meden, A., Kremenović, Aleksandar S., Antić, Bratislav, "Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles" in Journal of Physical Chemistry. C, 117, no. 23 (2013):12358-12365,
https://doi.org/10.1021/jp403459t . .