Živković, Sanja

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  • Živković, Sanja (14)

Author's Bibliography

Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes

Savić, Branislava; Stanković, Dalibor M.; Živković, Sanja; Ognjanović, Miloš; Tasić, Gvozden S.; Mihajlović, Ivana J.; Brdarić, Tanja

(2020)

TY  - JOUR
AU  - Savić, Branislava
AU  - Stanković, Dalibor M.
AU  - Živković, Sanja
AU  - Ognjanović, Miloš
AU  - Tasić, Gvozden S.
AU  - Mihajlović, Ivana J.
AU  - Brdarić, Tanja
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9064
AB  - A novel anode based on PbO2-GNRs nanocomposites was synthesized in order to investigate the simultaneous electrochemical oxidation of phenolic compounds in a mixture of methyl and chloro substituted phenols in alkaline solution (pH = 8.3). The crystal structure, morphology and composition of the synthesized materials were characterized using X-ray powder diffraction (XRPD), field emission scanning electron microscopy with energy dispersive X-ray spectrometer (FESEM-EDX) and transmission electron microscopy (TEM). FESEM images confirmed the presence of PbO2 nanoparticles on the PbO2-GNRs composite. The cyclic voltammetry measurements of the PbO2-GNRs electrode in 0.1 M Na2SO4 electrolyte indicated the electrochemical oxidation of phenol via indirect mechanism by hydroxyl radicals. Electrolytic oxidation of phenolic compounds was performed under potentiostatic conditions at potentials 2.3 V and 3 V. Removal efficiency of phenolic compounds increased with increasing the time of electrolysis and applied potential, up to 78% for 300 min and potential of 3 V. GC–MS chromatograms confirmed that mechanism of phenolic compounds degradation is based on their dechlorination and demethylation followed by the process of aromatic ring degradation. Newly synthesized PbO2-GNRs as electrode material could be successfully implemented in wastewater treatment of phenolic compounds by the electrochemical oxidation process.
T2  - Applied Surface Science
T1  - Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes
VL  - 529
SP  - 147120
DO  - 10.1016/j.apsusc.2020.147120
ER  - 
@article{
author = "Savić, Branislava and Stanković, Dalibor M. and Živković, Sanja and Ognjanović, Miloš and Tasić, Gvozden S. and Mihajlović, Ivana J. and Brdarić, Tanja",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9064",
abstract = "A novel anode based on PbO2-GNRs nanocomposites was synthesized in order to investigate the simultaneous electrochemical oxidation of phenolic compounds in a mixture of methyl and chloro substituted phenols in alkaline solution (pH = 8.3). The crystal structure, morphology and composition of the synthesized materials were characterized using X-ray powder diffraction (XRPD), field emission scanning electron microscopy with energy dispersive X-ray spectrometer (FESEM-EDX) and transmission electron microscopy (TEM). FESEM images confirmed the presence of PbO2 nanoparticles on the PbO2-GNRs composite. The cyclic voltammetry measurements of the PbO2-GNRs electrode in 0.1 M Na2SO4 electrolyte indicated the electrochemical oxidation of phenol via indirect mechanism by hydroxyl radicals. Electrolytic oxidation of phenolic compounds was performed under potentiostatic conditions at potentials 2.3 V and 3 V. Removal efficiency of phenolic compounds increased with increasing the time of electrolysis and applied potential, up to 78% for 300 min and potential of 3 V. GC–MS chromatograms confirmed that mechanism of phenolic compounds degradation is based on their dechlorination and demethylation followed by the process of aromatic ring degradation. Newly synthesized PbO2-GNRs as electrode material could be successfully implemented in wastewater treatment of phenolic compounds by the electrochemical oxidation process.",
journal = "Applied Surface Science",
title = "Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes",
volume = "529",
pages = "147120",
doi = "10.1016/j.apsusc.2020.147120"
}
Savić, B., Stanković, D. M., Živković, S., Ognjanović, M., Tasić, G. S., Mihajlović, I. J.,& Brdarić, T. (2020). Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes.
Applied Surface Science, 529, 147120.
https://doi.org/10.1016/j.apsusc.2020.147120
Savić B, Stanković DM, Živković S, Ognjanović M, Tasić GS, Mihajlović IJ, Brdarić T. Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes. Applied Surface Science. 2020;529:147120
Savić Branislava, Stanković Dalibor M., Živković Sanja, Ognjanović Miloš, Tasić Gvozden S., Mihajlović Ivana J., Brdarić Tanja, "Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes" 529 (2020):147120,
https://doi.org/10.1016/j.apsusc.2020.147120 .
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Laser-Induced Plasma as a Method for the Metallic Materials Hardness Estimation: An Alternative Approach

Momčilović, Miloš; Petrović, Jelena; Ciganović, Jovan; Cvijović-Alagić, Ivana; Koldžić, Filip; Živković, Sanja

(2020)

TY  - JOUR
AU  - Momčilović, Miloš
AU  - Petrović, Jelena
AU  - Ciganović, Jovan
AU  - Cvijović-Alagić, Ivana
AU  - Koldžić, Filip
AU  - Živković, Sanja
PY  - 2020
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8570
AB  - The application of an alternative laser-induced breakdown spectroscopy (LIBS) method based on transversely excited atmospheric (TEA) CO2 laser was investigated for the first time for estimating the hardness of metallic materials. The human eye-safe (TEA) CO2 laser, operating at 10.6 µm, was used for plasma generation. The LIBS spectra were recorded by employing a cost-effective CCD camera for the time-integrated and spatial resolved measurements. The cast iron and aluminum alloys samples with different hardness have been tested. The ratio between the magnesium ionic and neutral lines in LIBS spectra was applied for estimating the material hardness. In addition, the hardness of all samples included in this study was determined using the conventional method for material hardness determination, i.e. Vickers hardness test. The linear dependence of magnesium lines intensity ratio on the sample’s hardness was obtained for both kinds of materials. Profilometric measurements were used to verify that the newly-introduced method is almost nondestructive for the investigated metals. The results obtained in the present work confirmed the potential of using this original LIBS system not only for the fast elemental analysis but also for the direct estimation of the hardness of metals and alloys. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.
T2  - Plasma Chemistry and Plasma Processing
T1  - Laser-Induced Plasma as a Method for the Metallic Materials Hardness Estimation: An Alternative Approach
VL  - 40
IS  - 2
SP  - 499
EP  - 510
DO  - 10.1007/s11090-020-10063-5
ER  - 
@article{
author = "Momčilović, Miloš and Petrović, Jelena and Ciganović, Jovan and Cvijović-Alagić, Ivana and Koldžić, Filip and Živković, Sanja",
year = "2020",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8570",
abstract = "The application of an alternative laser-induced breakdown spectroscopy (LIBS) method based on transversely excited atmospheric (TEA) CO2 laser was investigated for the first time for estimating the hardness of metallic materials. The human eye-safe (TEA) CO2 laser, operating at 10.6 µm, was used for plasma generation. The LIBS spectra were recorded by employing a cost-effective CCD camera for the time-integrated and spatial resolved measurements. The cast iron and aluminum alloys samples with different hardness have been tested. The ratio between the magnesium ionic and neutral lines in LIBS spectra was applied for estimating the material hardness. In addition, the hardness of all samples included in this study was determined using the conventional method for material hardness determination, i.e. Vickers hardness test. The linear dependence of magnesium lines intensity ratio on the sample’s hardness was obtained for both kinds of materials. Profilometric measurements were used to verify that the newly-introduced method is almost nondestructive for the investigated metals. The results obtained in the present work confirmed the potential of using this original LIBS system not only for the fast elemental analysis but also for the direct estimation of the hardness of metals and alloys. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.",
journal = "Plasma Chemistry and Plasma Processing",
title = "Laser-Induced Plasma as a Method for the Metallic Materials Hardness Estimation: An Alternative Approach",
volume = "40",
number = "2",
pages = "499-510",
doi = "10.1007/s11090-020-10063-5"
}
Momčilović, M., Petrović, J., Ciganović, J., Cvijović-Alagić, I., Koldžić, F.,& Živković, S. (2020). Laser-Induced Plasma as a Method for the Metallic Materials Hardness Estimation: An Alternative Approach.
Plasma Chemistry and Plasma Processing, 40(2), 499-510.
https://doi.org/10.1007/s11090-020-10063-5
Momčilović M, Petrović J, Ciganović J, Cvijović-Alagić I, Koldžić F, Živković S. Laser-Induced Plasma as a Method for the Metallic Materials Hardness Estimation: An Alternative Approach. Plasma Chemistry and Plasma Processing. 2020;40(2):499-510
Momčilović Miloš, Petrović Jelena, Ciganović Jovan, Cvijović-Alagić Ivana, Koldžić Filip, Živković Sanja, "Laser-Induced Plasma as a Method for the Metallic Materials Hardness Estimation: An Alternative Approach" 40, no. 2 (2020):499-510,
https://doi.org/10.1007/s11090-020-10063-5 .

An original LIBS system based on TEA CO2 laser as a tool for determination of glass surface hardness

Momčilović, Miloš; Živković, Sanja; Petrović, Jelena; Cvijović-Alagić, Ivana; Ciganović, Jovan

(2019)

TY  - JOUR
AU  - Momčilović, Miloš
AU  - Živković, Sanja
AU  - Petrović, Jelena
AU  - Cvijović-Alagić, Ivana
AU  - Ciganović, Jovan
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8620
AB  - This study was carried out to examine the applicability of original laser-induced breakdown spectroscopy (LIBS) setup for determination of the surface hardness of lead glass as a function of its chemical composition. For this purpose, a set of five lead glass samples with different amount of ZrO2 was prepared. The LIBS measurements were carried out using TEA CO2 laser in the air at atmospheric pressure and without sample preparation. A ratio of the intensity between the Zr(II) 355.66 nm and Zr(I) 360.12 nm emission lines has been used to examine the hardness of the material. In addition, the surface hardness of glass samples was determined by Vickers’s indentation tests. Obtained results indicate a linear relationship of the measurements of hardness in glass samples between the LIBS and Vickers method. To show that LIBS based on TEA CO2 laser is an almost nondestructive technique, profilometric surface analysis was used. The proposed LIBS system is suitable not only for a spectrochemical analysis but also as an easy to use and cost-effective way to measure the surface hardness for all types and shapes of glass samples which are in some cases difficult to examine by standard Vicker’s method. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Applied Physics B
T1  - An original LIBS system based on TEA CO2 laser as a tool for determination of glass surface hardness
VL  - 125
IS  - 11
SP  - 222
DO  - 10.1007/s00340-019-7329-2
ER  - 
@article{
author = "Momčilović, Miloš and Živković, Sanja and Petrović, Jelena and Cvijović-Alagić, Ivana and Ciganović, Jovan",
year = "2019",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8620",
abstract = "This study was carried out to examine the applicability of original laser-induced breakdown spectroscopy (LIBS) setup for determination of the surface hardness of lead glass as a function of its chemical composition. For this purpose, a set of five lead glass samples with different amount of ZrO2 was prepared. The LIBS measurements were carried out using TEA CO2 laser in the air at atmospheric pressure and without sample preparation. A ratio of the intensity between the Zr(II) 355.66 nm and Zr(I) 360.12 nm emission lines has been used to examine the hardness of the material. In addition, the surface hardness of glass samples was determined by Vickers’s indentation tests. Obtained results indicate a linear relationship of the measurements of hardness in glass samples between the LIBS and Vickers method. To show that LIBS based on TEA CO2 laser is an almost nondestructive technique, profilometric surface analysis was used. The proposed LIBS system is suitable not only for a spectrochemical analysis but also as an easy to use and cost-effective way to measure the surface hardness for all types and shapes of glass samples which are in some cases difficult to examine by standard Vicker’s method. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Applied Physics B",
title = "An original LIBS system based on TEA CO2 laser as a tool for determination of glass surface hardness",
volume = "125",
number = "11",
pages = "222",
doi = "10.1007/s00340-019-7329-2"
}
Momčilović, M., Živković, S., Petrović, J., Cvijović-Alagić, I.,& Ciganović, J. (2019). An original LIBS system based on TEA CO2 laser as a tool for determination of glass surface hardness.
Applied Physics B, 125(11), 222.
https://doi.org/10.1007/s00340-019-7329-2
Momčilović M, Živković S, Petrović J, Cvijović-Alagić I, Ciganović J. An original LIBS system based on TEA CO2 laser as a tool for determination of glass surface hardness. Applied Physics B. 2019;125(11):222
Momčilović Miloš, Živković Sanja, Petrović Jelena, Cvijović-Alagić Ivana, Ciganović Jovan, "An original LIBS system based on TEA CO2 laser as a tool for determination of glass surface hardness" 125, no. 11 (2019):222,
https://doi.org/10.1007/s00340-019-7329-2 .
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The Effect of Background Gas on the Excitation Temperature and Electron Number Density of Basalt Plasma Induced by 10.6 Micron Laser Radiation

Momčilović, Miloš; Živković, Sanja; Kuzmanović, Miroslav M.; Ciganović, Jovan; Ranković, Dragan; Trtica, Milan; Savović, Jelena

(2019)

TY  - JOUR
AU  - Momčilović, Miloš
AU  - Živković, Sanja
AU  - Kuzmanović, Miroslav M.
AU  - Ciganović, Jovan
AU  - Ranković, Dragan
AU  - Trtica, Milan
AU  - Savović, Jelena
PY  - 2019
UR  - http://link.springer.com/10.1007/s11090-019-09987-4
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8158
AB  - Time-integrated optical emission spectroscopy was applied for the analysis of emission spectra, and determination of electron densities and excitation temperatures of basalt plasma induced by 10.6 micron laser radiation. The plasma was studied in air, argon and carbon dioxide, under pressure of 10, 50, and 100 mbar. The plasma emission intensity was found to be strongly dependent on the nature of the ambient gas and its pressure. The highest emission intensities and signal to noise ratios were obtained in argon. Depending on the composition and pressure of the surrounding atmosphere, the values of plasma temperature varied between 14,400 K (air at 10 mbar) and 17,100 K (carbon dioxide at 100 mbar). Similarly, the electron number density varied between 3 × 1016 cm−3 (10 mbar air) and 1.6 × 1017 cm−3 (100 mbar CO2). The observed behavior was correlated with the properties of the studied gases, in particular, their mass, thermal conductivity and ionization energy, and the role of the ambient gas in controlling the efficiency of laser-target coupling, laser-plasma interaction and plasma shielding. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.
T2  - Plasma Chemistry and Plasma Processing
T1  - The Effect of Background Gas on the Excitation Temperature and Electron Number Density of Basalt Plasma Induced by 10.6 Micron Laser Radiation
VL  - 39
IS  - 4
SP  - 985
EP  - 1000
DO  - 10.1007/s11090-019-09987-4
ER  - 
@article{
author = "Momčilović, Miloš and Živković, Sanja and Kuzmanović, Miroslav M. and Ciganović, Jovan and Ranković, Dragan and Trtica, Milan and Savović, Jelena",
year = "2019",
url = "http://link.springer.com/10.1007/s11090-019-09987-4, http://vinar.vin.bg.ac.rs/handle/123456789/8158",
abstract = "Time-integrated optical emission spectroscopy was applied for the analysis of emission spectra, and determination of electron densities and excitation temperatures of basalt plasma induced by 10.6 micron laser radiation. The plasma was studied in air, argon and carbon dioxide, under pressure of 10, 50, and 100 mbar. The plasma emission intensity was found to be strongly dependent on the nature of the ambient gas and its pressure. The highest emission intensities and signal to noise ratios were obtained in argon. Depending on the composition and pressure of the surrounding atmosphere, the values of plasma temperature varied between 14,400 K (air at 10 mbar) and 17,100 K (carbon dioxide at 100 mbar). Similarly, the electron number density varied between 3 × 1016 cm−3 (10 mbar air) and 1.6 × 1017 cm−3 (100 mbar CO2). The observed behavior was correlated with the properties of the studied gases, in particular, their mass, thermal conductivity and ionization energy, and the role of the ambient gas in controlling the efficiency of laser-target coupling, laser-plasma interaction and plasma shielding. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.",
journal = "Plasma Chemistry and Plasma Processing",
title = "The Effect of Background Gas on the Excitation Temperature and Electron Number Density of Basalt Plasma Induced by 10.6 Micron Laser Radiation",
volume = "39",
number = "4",
pages = "985-1000",
doi = "10.1007/s11090-019-09987-4"
}
Momčilović, M., Živković, S., Kuzmanović, M. M., Ciganović, J., Ranković, D., Trtica, M.,& Savović, J. (2019). The Effect of Background Gas on the Excitation Temperature and Electron Number Density of Basalt Plasma Induced by 10.6 Micron Laser Radiation.
Plasma Chemistry and Plasma Processing, 39(4), 985-1000.
https://doi.org/10.1007/s11090-019-09987-4
Momčilović M, Živković S, Kuzmanović MM, Ciganović J, Ranković D, Trtica M, Savović J. The Effect of Background Gas on the Excitation Temperature and Electron Number Density of Basalt Plasma Induced by 10.6 Micron Laser Radiation. Plasma Chemistry and Plasma Processing. 2019;39(4):985-1000
Momčilović Miloš, Živković Sanja, Kuzmanović Miroslav M., Ciganović Jovan, Ranković Dragan, Trtica Milan, Savović Jelena, "The Effect of Background Gas on the Excitation Temperature and Electron Number Density of Basalt Plasma Induced by 10.6 Micron Laser Radiation" 39, no. 4 (2019):985-1000,
https://doi.org/10.1007/s11090-019-09987-4 .
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Примена спектроскопије плазме индуковане импулсним угљендиоксидним ласерским зрачењем за квалитативну и квантитативну анализу чврстих узорака

Živković, Sanja

(Универзитет у Београду, Хемијски факултет, 2019)

TY  - BOOK
AU  - Živković, Sanja
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8854
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:22808/bdef:Content/download
UR  - https://plus.sr.cobiss.net/opac7/bib/23396873
UR  - https://nardus.mpn.gov.rs/handle/123456789/17524
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=7653
AB  - Спектроскопија ласерски индуковане плазме (LIBS) је аналитичка техника која омогућава брзу, мултиелементалну анализу свих врста материјала, најчешће без потребе за претходном припремом узорака, у реалном времену и на лицу места. Ова савремена метода хемијске анализе у складу је са принципима зелене аналитичке хемије јер не захтева употребу агресивних и потенцијално токсичних хемикалија. Примарни циљ ове дисертације је испитивање аналитичких могућности оригиналног лабораторијског LIBS система за квалитативну и квантитативну анализу различитих чврстих узорака, као што су металне легуре, геолошки узорци и прашкасти биљни узорци. Развијени LIBS систем користи зрачење ТЕА CO2 ласера за индуковање плазме, а за анализу зрачења плазме временски-интеграљену просторно-разложену спектроскопију. У циљу проналажења оптималних услова за спектрохемијску примену ласером индуковане плазме, испитан је утицај енергије ласерског зрачења, састава и притиска околног гаса, начина фокусирања и других параметара на карактеристике и спектралну емисију плазме. Развијен је начин припреме синтетичких стандарда за квантитативну анализу узорака код којих не постоје адекватни сертификовани референтни материјали. Такође, испитана је могућност примене методе стандардног додатка комбиноване са методама нормализације за побољшање тачности одређивања концентрације аналита. Сви резултати добијени LIBS методом потврђени су применом стандардне ICP-OES технике. Учешћем у 2. интерлабораторијском међународном LIBS поређењу показано је да је систем на бази ТЕА CO2 ласера по аналитичким перформансама у потпуности упоредив а за поједине елементе чак и бољи у односу на комерцијалне LIBS уређаје.
AB  - Laser-induced breakdown spectroscopy (LIBS) is an analytical technique for fast, multi-element analysis of any kind of material, most often without preliminary preparation, in real time and on-site. This modern analytical method is in accordance with the principles of green analytical chemistry because it does not require the use of aggressive and potentially toxic chemicals. The main aim of this thesis is to investigate the analytical capability of originally developed TEA CO2 based LIBS system, for qualitative and quantitative analysis of various types of solid samples (metal alloys, geological samples and powdered plant materials). In LIBS system, TEA CO2 laser irradiation was used for plasma generation while time-integrated spatially resolved spectroscopy was applied for the analysis of plasma radiation. In order to find optimal conditions for spectrochemical applications of laser induced plasma, the influence of laser irradiation energy, compositions and pressure of the ambient gas, focusing, etc., on spectral emission and characteristics of plasma was examined. A method for the preparation of synthetic standards for the quantitative analysis of samples, for which there are no adequate certified reference materials, has been developed. Also, the applicability of the method of standard addition combined with normalization methods for improving the accuracy of determining the analyte concentration was tested. Results obtained with developed LIBS method were verified with the standard method, ICP-OES. The applied system based on TEA CO2 laser according to analytical performances is fully comparable and for some elements even better than commercial LIBS devices, which is verified by participation in the 2nd interlaboratory international LIBS comparison.
PB  - Универзитет у Београду, Хемијски факултет
T2  - Универзитет у Београду
T1  - Примена спектроскопије плазме индуковане импулсним угљендиоксидним ласерским зрачењем за квалитативну и квантитативну анализу чврстих узорака
ER  - 
@phdthesis{
author = "Živković, Sanja",
year = "2019",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8854, https://fedorabg.bg.ac.rs/fedora/get/o:22808/bdef:Content/download, https://plus.sr.cobiss.net/opac7/bib/23396873, https://nardus.mpn.gov.rs/handle/123456789/17524, http://eteze.bg.ac.rs/application/showtheses?thesesId=7653",
abstract = "Спектроскопија ласерски индуковане плазме (LIBS) је аналитичка техника која омогућава брзу, мултиелементалну анализу свих врста материјала, најчешће без потребе за претходном припремом узорака, у реалном времену и на лицу места. Ова савремена метода хемијске анализе у складу је са принципима зелене аналитичке хемије јер не захтева употребу агресивних и потенцијално токсичних хемикалија. Примарни циљ ове дисертације је испитивање аналитичких могућности оригиналног лабораторијског LIBS система за квалитативну и квантитативну анализу различитих чврстих узорака, као што су металне легуре, геолошки узорци и прашкасти биљни узорци. Развијени LIBS систем користи зрачење ТЕА CO2 ласера за индуковање плазме, а за анализу зрачења плазме временски-интеграљену просторно-разложену спектроскопију. У циљу проналажења оптималних услова за спектрохемијску примену ласером индуковане плазме, испитан је утицај енергије ласерског зрачења, састава и притиска околног гаса, начина фокусирања и других параметара на карактеристике и спектралну емисију плазме. Развијен је начин припреме синтетичких стандарда за квантитативну анализу узорака код којих не постоје адекватни сертификовани референтни материјали. Такође, испитана је могућност примене методе стандардног додатка комбиноване са методама нормализације за побољшање тачности одређивања концентрације аналита. Сви резултати добијени LIBS методом потврђени су применом стандардне ICP-OES технике. Учешћем у 2. интерлабораторијском међународном LIBS поређењу показано је да је систем на бази ТЕА CO2 ласера по аналитичким перформансама у потпуности упоредив а за поједине елементе чак и бољи у односу на комерцијалне LIBS уређаје., Laser-induced breakdown spectroscopy (LIBS) is an analytical technique for fast, multi-element analysis of any kind of material, most often without preliminary preparation, in real time and on-site. This modern analytical method is in accordance with the principles of green analytical chemistry because it does not require the use of aggressive and potentially toxic chemicals. The main aim of this thesis is to investigate the analytical capability of originally developed TEA CO2 based LIBS system, for qualitative and quantitative analysis of various types of solid samples (metal alloys, geological samples and powdered plant materials). In LIBS system, TEA CO2 laser irradiation was used for plasma generation while time-integrated spatially resolved spectroscopy was applied for the analysis of plasma radiation. In order to find optimal conditions for spectrochemical applications of laser induced plasma, the influence of laser irradiation energy, compositions and pressure of the ambient gas, focusing, etc., on spectral emission and characteristics of plasma was examined. A method for the preparation of synthetic standards for the quantitative analysis of samples, for which there are no adequate certified reference materials, has been developed. Also, the applicability of the method of standard addition combined with normalization methods for improving the accuracy of determining the analyte concentration was tested. Results obtained with developed LIBS method were verified with the standard method, ICP-OES. The applied system based on TEA CO2 laser according to analytical performances is fully comparable and for some elements even better than commercial LIBS devices, which is verified by participation in the 2nd interlaboratory international LIBS comparison.",
publisher = "Универзитет у Београду, Хемијски факултет",
journal = "Универзитет у Београду",
title = "Примена спектроскопије плазме индуковане импулсним угљендиоксидним ласерским зрачењем за квалитативну и квантитативну анализу чврстих узорака"
}
Živković, S. (2019). Примена спектроскопије плазме индуковане импулсним угљендиоксидним ласерским зрачењем за квалитативну и квантитативну анализу чврстих узорака.
Универзитет у БеоградуУниверзитет у Београду, Хемијски факултет..
Živković S. Примена спектроскопије плазме индуковане импулсним угљендиоксидним ласерским зрачењем за квалитативну и квантитативну анализу чврстих узорака. Универзитет у Београду. 2019;
Živković Sanja, "Примена спектроскопије плазме индуковане импулсним угљендиоксидним ласерским зрачењем за квалитативну и квантитативну анализу чврстих узорака" (2019)

Alternative analytical method for direct determination of Mn and Ba in peppermint tea based on laser induced breakdown spectroscopy

Živković, Sanja; Savović, Jelena; Kuzmanović, Miroslav M.; Petrović, Jelena; Momčilović, Miloš

(2018)

TY  - JOUR
AU  - Živković, Sanja
AU  - Savović, Jelena
AU  - Kuzmanović, Miroslav M.
AU  - Petrović, Jelena
AU  - Momčilović, Miloš
PY  - 2018
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1940
AB  - In this study, analytical capability of Laser Induced Breakdown Spectroscopy (LIBS) system based on Transversely Excited Atmospheric pressure (TEA) CO2 laser for determination of elemental composition of tea samples was demonstrated. Analysis of LIBS spectra indicated emission lines attributed to the elements Fe, Mg, Cu, Ca, Al, Mn, Ba, P, K and Sr. For quantitative analysis of Mn and Ba, a standard addition method was employed. Linear calibration curves with regression coefficients exceeding 0.95 were obtained. The accuracy of LIBS results was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. Calculated recoveries for Ba and Mn were 99.7 and 102.3%, respectively. The results presented confirm the suitability of the proposed LIBS setup for rapid quantitative analysis of tea, while at the same time simplifying the overall analytical procedure. This approach can be easily used as a helpful analytical tool for food quality and safety control. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Microchemical Journal
T1  - Alternative analytical method for direct determination of Mn and Ba in peppermint tea based on laser induced breakdown spectroscopy
VL  - 137
SP  - 410
EP  - 417
DO  - 10.1016/j.microc.2017.11.020
ER  - 
@article{
author = "Živković, Sanja and Savović, Jelena and Kuzmanović, Miroslav M. and Petrović, Jelena and Momčilović, Miloš",
year = "2018",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1940",
abstract = "In this study, analytical capability of Laser Induced Breakdown Spectroscopy (LIBS) system based on Transversely Excited Atmospheric pressure (TEA) CO2 laser for determination of elemental composition of tea samples was demonstrated. Analysis of LIBS spectra indicated emission lines attributed to the elements Fe, Mg, Cu, Ca, Al, Mn, Ba, P, K and Sr. For quantitative analysis of Mn and Ba, a standard addition method was employed. Linear calibration curves with regression coefficients exceeding 0.95 were obtained. The accuracy of LIBS results was confirmed by inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. Calculated recoveries for Ba and Mn were 99.7 and 102.3%, respectively. The results presented confirm the suitability of the proposed LIBS setup for rapid quantitative analysis of tea, while at the same time simplifying the overall analytical procedure. This approach can be easily used as a helpful analytical tool for food quality and safety control. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Microchemical Journal",
title = "Alternative analytical method for direct determination of Mn and Ba in peppermint tea based on laser induced breakdown spectroscopy",
volume = "137",
pages = "410-417",
doi = "10.1016/j.microc.2017.11.020"
}
Živković, S., Savović, J., Kuzmanović, M. M., Petrović, J.,& Momčilović, M. (2018). Alternative analytical method for direct determination of Mn and Ba in peppermint tea based on laser induced breakdown spectroscopy.
Microchemical Journal, 137, 410-417.
https://doi.org/10.1016/j.microc.2017.11.020
Živković S, Savović J, Kuzmanović MM, Petrović J, Momčilović M. Alternative analytical method for direct determination of Mn and Ba in peppermint tea based on laser induced breakdown spectroscopy. Microchemical Journal. 2018;137:410-417
Živković Sanja, Savović Jelena, Kuzmanović Miroslav M., Petrović Jelena, Momčilović Miloš, "Alternative analytical method for direct determination of Mn and Ba in peppermint tea based on laser induced breakdown spectroscopy" 137 (2018):410-417,
https://doi.org/10.1016/j.microc.2017.11.020 .
15
16
16

Spectrochemical analysis of powdered biological samples using transversely excited atmospheric carbon dioxide laser plasma excitation

Živković, Sanja; Momčilović, Miloš; Staicu, Angela; Mutić, Jelena J.; Trtica, Milan; Savović, Jelena

(2017)

TY  - JOUR
AU  - Živković, Sanja
AU  - Momčilović, Miloš
AU  - Staicu, Angela
AU  - Mutić, Jelena J.
AU  - Trtica, Milan
AU  - Savović, Jelena
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1427
AB  - The aim of this study was to develop a simple laser induced breakdown spectroscopy (LIBS) method for quantitative elemental analysis of powdered biological materials based on laboratory prepared calibration samples. The analysis was done using ungated single pulse LIBS in ambient air at atmospheric pressure. Transversely-Excited Atmospheric pressure (TEA) CO2 laser was used as an energy source for plasma generation on samples. The material used for the analysis was a blue-green alga Spirulina, widely used in food and pharmaceutical industries and also in a few biotechnological applications. To demonstrate the analytical potential of this particular LIBS system the obtained spectra were compared to the spectra obtained using a commercial LIBS system based on pulsed Nd:YAG laser. A single sample of known concentration was used to estimate detection limits for Ba, Ca, Fe, Mg, Mn, Si and Sr and compare detection power of these two LIES systems. TEA CO2 laser based LIES was also applied for quantitative analysis of the elements in powder Spirulina samples. Analytical curves for Ba, Fe, Mg, Mn and Sr were constructed using laboratory produced matrix-matched calibration samples. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was used as the reference technique for elemental quantification, and reasonably well agreement between ICP and LIBS data was obtained. Results confirm that, in respect to its sensitivity and precision, TEA CO2 laser based LIBS can be successfully applied for quantitative analysis of macro and micro-elements in algal samples. The fact that nearly all classes of materials can be prepared as powders implies that the proposed method could be easily extended to a quantitative analysis of different kinds of materials, organic, biological or inorganic. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Spectrochimica Acta. Part B: Atomic Spectroscopy
T1  - Spectrochemical analysis of powdered biological samples using transversely excited atmospheric carbon dioxide laser plasma excitation
VL  - 128
SP  - 22
EP  - 29
DO  - 10.1016/j.sab.2016.12.009
ER  - 
@article{
author = "Živković, Sanja and Momčilović, Miloš and Staicu, Angela and Mutić, Jelena J. and Trtica, Milan and Savović, Jelena",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1427",
abstract = "The aim of this study was to develop a simple laser induced breakdown spectroscopy (LIBS) method for quantitative elemental analysis of powdered biological materials based on laboratory prepared calibration samples. The analysis was done using ungated single pulse LIBS in ambient air at atmospheric pressure. Transversely-Excited Atmospheric pressure (TEA) CO2 laser was used as an energy source for plasma generation on samples. The material used for the analysis was a blue-green alga Spirulina, widely used in food and pharmaceutical industries and also in a few biotechnological applications. To demonstrate the analytical potential of this particular LIBS system the obtained spectra were compared to the spectra obtained using a commercial LIBS system based on pulsed Nd:YAG laser. A single sample of known concentration was used to estimate detection limits for Ba, Ca, Fe, Mg, Mn, Si and Sr and compare detection power of these two LIES systems. TEA CO2 laser based LIES was also applied for quantitative analysis of the elements in powder Spirulina samples. Analytical curves for Ba, Fe, Mg, Mn and Sr were constructed using laboratory produced matrix-matched calibration samples. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was used as the reference technique for elemental quantification, and reasonably well agreement between ICP and LIBS data was obtained. Results confirm that, in respect to its sensitivity and precision, TEA CO2 laser based LIBS can be successfully applied for quantitative analysis of macro and micro-elements in algal samples. The fact that nearly all classes of materials can be prepared as powders implies that the proposed method could be easily extended to a quantitative analysis of different kinds of materials, organic, biological or inorganic. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Spectrochimica Acta. Part B: Atomic Spectroscopy",
title = "Spectrochemical analysis of powdered biological samples using transversely excited atmospheric carbon dioxide laser plasma excitation",
volume = "128",
pages = "22-29",
doi = "10.1016/j.sab.2016.12.009"
}
Živković, S., Momčilović, M., Staicu, A., Mutić, J. J., Trtica, M.,& Savović, J. (2017). Spectrochemical analysis of powdered biological samples using transversely excited atmospheric carbon dioxide laser plasma excitation.
Spectrochimica Acta. Part B: Atomic Spectroscopy, 128, 22-29.
https://doi.org/10.1016/j.sab.2016.12.009
Živković S, Momčilović M, Staicu A, Mutić JJ, Trtica M, Savović J. Spectrochemical analysis of powdered biological samples using transversely excited atmospheric carbon dioxide laser plasma excitation. Spectrochimica Acta. Part B: Atomic Spectroscopy. 2017;128:22-29
Živković Sanja, Momčilović Miloš, Staicu Angela, Mutić Jelena J., Trtica Milan, Savović Jelena, "Spectrochemical analysis of powdered biological samples using transversely excited atmospheric carbon dioxide laser plasma excitation" 128 (2017):22-29,
https://doi.org/10.1016/j.sab.2016.12.009 .
10
10
13

Elemental analysis of aluminum alloys by Laser Induced Breakdown Spectroscopy based on TEA CO2 laser

Živković, Sanja; Savović, Jelena; Trtica, Milan; Mutić, Jelena J.; Momčilović, Miloš

(2017)

TY  - JOUR
AU  - Živković, Sanja
AU  - Savović, Jelena
AU  - Trtica, Milan
AU  - Mutić, Jelena J.
AU  - Momčilović, Miloš
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1426
AB  - The applicability of nanosecond infrared Transversely Excited Atmospheric (TEA) CO2 laser induced plasma for spectrochemical analysis of aluminum alloys was investigated. The plasma was generated by focusing a pulsed TEA CO2 laser that emits at 10.6 mu m on the Al target in ambient air at atmospheric pressure. The temporal profile of the laser pulse is composed of a 100 ns peak followed by a slowly decaying tail of about 2 mu s. The output pulse energy was approximately 160 mJ, thus the peak output power was estimated to be around 1.6 MW. Time-Integrated Space-Resolved Laser Induced Breakdown Spectroscopy (TISR-LIBS) was employed to obtain the emission spectra. The maximum intensity of emission, with sharp and well resolved spectral lines that were almost free of the background continuum, was obtained from plasma region 2 mm from the target surface. Linear calibration curves for Mg, Cr, Cu and Fe were obtained using aluminum alloy spectrochemical standards. The limits of detection for the investigated elements were in the 2-73 ppm range. Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) was used as a reference technique to estimate the accuracy of LIBS determination by use of control samples with known compositions. Comparison of the obtained results with those available in the literature confirms that LIBS system based on TEA CO2 laser, in combination with TISR spectral measurements, can be successfully applied to qualitative and quantitative determinations of minor elements in aluminum based alloys. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Elemental analysis of aluminum alloys by Laser Induced Breakdown Spectroscopy based on TEA CO2 laser
VL  - 700
SP  - 175
EP  - 184
DO  - 10.1016/j.jallcom.2017.01.060
ER  - 
@article{
author = "Živković, Sanja and Savović, Jelena and Trtica, Milan and Mutić, Jelena J. and Momčilović, Miloš",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1426",
abstract = "The applicability of nanosecond infrared Transversely Excited Atmospheric (TEA) CO2 laser induced plasma for spectrochemical analysis of aluminum alloys was investigated. The plasma was generated by focusing a pulsed TEA CO2 laser that emits at 10.6 mu m on the Al target in ambient air at atmospheric pressure. The temporal profile of the laser pulse is composed of a 100 ns peak followed by a slowly decaying tail of about 2 mu s. The output pulse energy was approximately 160 mJ, thus the peak output power was estimated to be around 1.6 MW. Time-Integrated Space-Resolved Laser Induced Breakdown Spectroscopy (TISR-LIBS) was employed to obtain the emission spectra. The maximum intensity of emission, with sharp and well resolved spectral lines that were almost free of the background continuum, was obtained from plasma region 2 mm from the target surface. Linear calibration curves for Mg, Cr, Cu and Fe were obtained using aluminum alloy spectrochemical standards. The limits of detection for the investigated elements were in the 2-73 ppm range. Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) was used as a reference technique to estimate the accuracy of LIBS determination by use of control samples with known compositions. Comparison of the obtained results with those available in the literature confirms that LIBS system based on TEA CO2 laser, in combination with TISR spectral measurements, can be successfully applied to qualitative and quantitative determinations of minor elements in aluminum based alloys. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Elemental analysis of aluminum alloys by Laser Induced Breakdown Spectroscopy based on TEA CO2 laser",
volume = "700",
pages = "175-184",
doi = "10.1016/j.jallcom.2017.01.060"
}
Živković, S., Savović, J., Trtica, M., Mutić, J. J.,& Momčilović, M. (2017). Elemental analysis of aluminum alloys by Laser Induced Breakdown Spectroscopy based on TEA CO2 laser.
Journal of Alloys and Compounds, 700, 175-184.
https://doi.org/10.1016/j.jallcom.2017.01.060
Živković S, Savović J, Trtica M, Mutić JJ, Momčilović M. Elemental analysis of aluminum alloys by Laser Induced Breakdown Spectroscopy based on TEA CO2 laser. Journal of Alloys and Compounds. 2017;700:175-184
Živković Sanja, Savović Jelena, Trtica Milan, Mutić Jelena J., Momčilović Miloš, "Elemental analysis of aluminum alloys by Laser Induced Breakdown Spectroscopy based on TEA CO2 laser" 700 (2017):175-184,
https://doi.org/10.1016/j.jallcom.2017.01.060 .
14
15
16

Determination of low alloying elements concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system

Savović, Jelena; Živković, Sanja; Momčilović, Miloš; Trtica, Milan; Stoiljković, Milovan; Kuzmanović, Miroslav M.

(2017)

TY  - JOUR
AU  - Savović, Jelena
AU  - Živković, Sanja
AU  - Momčilović, Miloš
AU  - Trtica, Milan
AU  - Stoiljković, Milovan
AU  - Kuzmanović, Miroslav M.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1845
AB  - The analytical capability of laser-produced plasma for the analysis of low alloying elements in cast iron samples has been investigated. The plasma was induced by irradiation of a sample in air at atmospheric pressure using an infrared CO2 laser. Emission spectra were recorded by time-integrated spatially-resolved measurement technique. A set of ten cast iron samples in a powder or particulate form were provided by BAM (Bundesanstalt fur Material Forschung und Prufung, Deutschland), seven of which were used for calibration, and three were treated as unknowns. Linear calibration curves were obtained for copper, chromium, and nickel, with correlation coefficients above 0.99. Precision and accuracy of the LIBS method was evaluated and compared to those obtained by the inductively coupled plasma (ICP) analysis of the same samples. Detection limits for Cu, Cr and Ni were close to those reported in the literature for other comparable iron-based alloys obtained using different LIBS systems. Analytical figures of merit of the studied LIBS system may be considered as satisfying, especially in the light of other advantages of the method, like cost effective and fast analysis with no sample preparation, and with a possibility for real-time on-site analysis.
T2  - Journal of the Serbian Chemical Society
T1  - Determination of low alloying elements concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system
VL  - 82
IS  - 10
SP  - 1135
EP  - 1145
DO  - 10.2298/JSC170303073S
ER  - 
@article{
author = "Savović, Jelena and Živković, Sanja and Momčilović, Miloš and Trtica, Milan and Stoiljković, Milovan and Kuzmanović, Miroslav M.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1845",
abstract = "The analytical capability of laser-produced plasma for the analysis of low alloying elements in cast iron samples has been investigated. The plasma was induced by irradiation of a sample in air at atmospheric pressure using an infrared CO2 laser. Emission spectra were recorded by time-integrated spatially-resolved measurement technique. A set of ten cast iron samples in a powder or particulate form were provided by BAM (Bundesanstalt fur Material Forschung und Prufung, Deutschland), seven of which were used for calibration, and three were treated as unknowns. Linear calibration curves were obtained for copper, chromium, and nickel, with correlation coefficients above 0.99. Precision and accuracy of the LIBS method was evaluated and compared to those obtained by the inductively coupled plasma (ICP) analysis of the same samples. Detection limits for Cu, Cr and Ni were close to those reported in the literature for other comparable iron-based alloys obtained using different LIBS systems. Analytical figures of merit of the studied LIBS system may be considered as satisfying, especially in the light of other advantages of the method, like cost effective and fast analysis with no sample preparation, and with a possibility for real-time on-site analysis.",
journal = "Journal of the Serbian Chemical Society",
title = "Determination of low alloying elements concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system",
volume = "82",
number = "10",
pages = "1135-1145",
doi = "10.2298/JSC170303073S"
}
Savović, J., Živković, S., Momčilović, M., Trtica, M., Stoiljković, M.,& Kuzmanović, M. M. (2017). Determination of low alloying elements concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system.
Journal of the Serbian Chemical Society, 82(10), 1135-1145.
https://doi.org/10.2298/JSC170303073S
Savović J, Živković S, Momčilović M, Trtica M, Stoiljković M, Kuzmanović MM. Determination of low alloying elements concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system. Journal of the Serbian Chemical Society. 2017;82(10):1135-1145
Savović Jelena, Živković Sanja, Momčilović Miloš, Trtica Milan, Stoiljković Milovan, Kuzmanović Miroslav M., "Determination of low alloying elements concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system" 82, no. 10 (2017):1135-1145,
https://doi.org/10.2298/JSC170303073S .
2
2
2

LIBS Analysis of Geomaterials: Comparative Study of Basalt Plasma Induced by TEA CO2 and Nd:YAG Laser in Air at Atmospheric Pressure

Savović, Jelena; Momčilović, Miloš; Živković, Sanja; Stancalie, Andrei; Trtica, Milan; Kuzmanović, Miroslav M.

(2017)

TY  - JOUR
AU  - Savović, Jelena
AU  - Momčilović, Miloš
AU  - Živković, Sanja
AU  - Stancalie, Andrei
AU  - Trtica, Milan
AU  - Kuzmanović, Miroslav M.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1638
AB  - We present a study of the plasma generated by transversely excited atmospheric (TEA) CO2 laser irradiation of a basalt sample. The plasma was induced in air at atmospheric pressure. The same sample was also analyzed using a commercial LIBS system based on Nd:YAG laser and time-gated detection. The main plasma parameters, temperature, and electron number density were determined and analytical capabilities of the two systems compared. Despite differences in laser wavelength, pulse duration, applied fluence, and signal detection scheme, the two systems are comparable in terms of element detectability and limits of detection. In both cases, all elements usually present in geological samples were identified. The estimated limits of detection for most elements were below 100 ppm, while for Cu, Cr, and Sr they were around or below 10 ppm. The obtained results led to the conclusion that simple, cost- effective TEA CO2 LIBS system can find applications for geological explorations.
T2  - Journal of Chemistry
T1  - LIBS Analysis of Geomaterials: Comparative Study of Basalt Plasma Induced by TEA CO2 and Nd:YAG Laser in Air at Atmospheric Pressure
DO  - 10.1155/2017/9513438
ER  - 
@article{
author = "Savović, Jelena and Momčilović, Miloš and Živković, Sanja and Stancalie, Andrei and Trtica, Milan and Kuzmanović, Miroslav M.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1638",
abstract = "We present a study of the plasma generated by transversely excited atmospheric (TEA) CO2 laser irradiation of a basalt sample. The plasma was induced in air at atmospheric pressure. The same sample was also analyzed using a commercial LIBS system based on Nd:YAG laser and time-gated detection. The main plasma parameters, temperature, and electron number density were determined and analytical capabilities of the two systems compared. Despite differences in laser wavelength, pulse duration, applied fluence, and signal detection scheme, the two systems are comparable in terms of element detectability and limits of detection. In both cases, all elements usually present in geological samples were identified. The estimated limits of detection for most elements were below 100 ppm, while for Cu, Cr, and Sr they were around or below 10 ppm. The obtained results led to the conclusion that simple, cost- effective TEA CO2 LIBS system can find applications for geological explorations.",
journal = "Journal of Chemistry",
title = "LIBS Analysis of Geomaterials: Comparative Study of Basalt Plasma Induced by TEA CO2 and Nd:YAG Laser in Air at Atmospheric Pressure",
doi = "10.1155/2017/9513438"
}
Savović, J., Momčilović, M., Živković, S., Stancalie, A., Trtica, M.,& Kuzmanović, M. M. (2017). LIBS Analysis of Geomaterials: Comparative Study of Basalt Plasma Induced by TEA CO2 and Nd:YAG Laser in Air at Atmospheric Pressure.
Journal of Chemistry.
https://doi.org/10.1155/2017/9513438
Savović J, Momčilović M, Živković S, Stancalie A, Trtica M, Kuzmanović MM. LIBS Analysis of Geomaterials: Comparative Study of Basalt Plasma Induced by TEA CO2 and Nd:YAG Laser in Air at Atmospheric Pressure. Journal of Chemistry. 2017;
Savović Jelena, Momčilović Miloš, Živković Sanja, Stancalie Andrei, Trtica Milan, Kuzmanović Miroslav M., "LIBS Analysis of Geomaterials: Comparative Study of Basalt Plasma Induced by TEA CO2 and Nd:YAG Laser in Air at Atmospheric Pressure" (2017),
https://doi.org/10.1155/2017/9513438 .
3
2
3

Laser-induced features at titanium implant surface in vacuum ambience

Ciganović, Jovan; Živković, Sanja; Momčilović, Miloš; Savović, Jelena; Kuzmanović, Miroslav M.; Stoiljković, Milovan; Trtica, Milan

(2016)

TY  - JOUR
AU  - Ciganović, Jovan
AU  - Živković, Sanja
AU  - Momčilović, Miloš
AU  - Savović, Jelena
AU  - Kuzmanović, Miroslav M.
AU  - Stoiljković, Milovan
AU  - Trtica, Milan
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/905
AB  - Interaction of a TEA CO2 laser with a titanium implant in vacuum (air pressure 0.1 mbar) was studied. The laser operates at 10: 6 mu m with pulse duration of 100 ns (FWHM). The surface alternations were studied at the moderate laser beam energy density/fluence of 52 J/cm(2). The energy absorbed from the TEA CO2 laser beam was partially converted to thermal energy, which generated a series of effects such as melting, vaporization of the molten material, shock waves, etc. The following titanium implant surface changes and phenomena were observed: (1) creation of superficial damage which takes crater-shaped form at a higher number of accumulated laser pulses. Maximal depth of the damage was 9 mu m for 500 laser pulses. The damage cross-section had a conical form; (2) melt pools, inside the damage region, especially prominent for higher number of accumulated pulses; (3) preservation of chemical surface composition in central, and changes at the peripheral region, and (4) occurrence of plasma in front of the implant. The results have shown that under the applied experimental conditions, TEA CO2 laser can effectively be applied for enhancing the titanium implant roughness and creation of surface chemical changes. The appearance of plasma in front of the implant offers a sterilizing effect, facilitating contaminant-free conditions.
T2  - Optical and Quantum Electronics
T1  - Laser-induced features at titanium implant surface in vacuum ambience
VL  - 48
IS  - 2
DO  - 10.1007/s11082-015-0369-x
ER  - 
@article{
author = "Ciganović, Jovan and Živković, Sanja and Momčilović, Miloš and Savović, Jelena and Kuzmanović, Miroslav M. and Stoiljković, Milovan and Trtica, Milan",
year = "2016",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/905",
abstract = "Interaction of a TEA CO2 laser with a titanium implant in vacuum (air pressure 0.1 mbar) was studied. The laser operates at 10: 6 mu m with pulse duration of 100 ns (FWHM). The surface alternations were studied at the moderate laser beam energy density/fluence of 52 J/cm(2). The energy absorbed from the TEA CO2 laser beam was partially converted to thermal energy, which generated a series of effects such as melting, vaporization of the molten material, shock waves, etc. The following titanium implant surface changes and phenomena were observed: (1) creation of superficial damage which takes crater-shaped form at a higher number of accumulated laser pulses. Maximal depth of the damage was 9 mu m for 500 laser pulses. The damage cross-section had a conical form; (2) melt pools, inside the damage region, especially prominent for higher number of accumulated pulses; (3) preservation of chemical surface composition in central, and changes at the peripheral region, and (4) occurrence of plasma in front of the implant. The results have shown that under the applied experimental conditions, TEA CO2 laser can effectively be applied for enhancing the titanium implant roughness and creation of surface chemical changes. The appearance of plasma in front of the implant offers a sterilizing effect, facilitating contaminant-free conditions.",
journal = "Optical and Quantum Electronics",
title = "Laser-induced features at titanium implant surface in vacuum ambience",
volume = "48",
number = "2",
doi = "10.1007/s11082-015-0369-x"
}
Ciganović, J., Živković, S., Momčilović, M., Savović, J., Kuzmanović, M. M., Stoiljković, M.,& Trtica, M. (2016). Laser-induced features at titanium implant surface in vacuum ambience.
Optical and Quantum Electronics, 48(2).
https://doi.org/10.1007/s11082-015-0369-x
Ciganović J, Živković S, Momčilović M, Savović J, Kuzmanović MM, Stoiljković M, Trtica M. Laser-induced features at titanium implant surface in vacuum ambience. Optical and Quantum Electronics. 2016;48(2)
Ciganović Jovan, Živković Sanja, Momčilović Miloš, Savović Jelena, Kuzmanović Miroslav M., Stoiljković Milovan, Trtica Milan, "Laser-induced features at titanium implant surface in vacuum ambience" 48, no. 2 (2016),
https://doi.org/10.1007/s11082-015-0369-x .
4
3
4

The feasibility of TEA CO2 laser-induced plasma for spectrochemical analysis of geological samples in simulated Martian conditions

Savović, Jelena; Stoiljković, Milovan; Kuzmanović, Miroslav M.; Momčilović, Miloš; Ciganović, Jovan; Rankovic, Dragan; Živković, Sanja; Trtica, Milan

(2016)

TY  - JOUR
AU  - Savović, Jelena
AU  - Stoiljković, Milovan
AU  - Kuzmanović, Miroslav M.
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Rankovic, Dragan
AU  - Živković, Sanja
AU  - Trtica, Milan
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1013
AB  - The present work studies the possibility of using pulsed Transversely Excited Atmospheric (TEA) carbon dioxide laser as an energy source for laser-induced breakdown spectroscopy (LIBS) analysis of rocks under simulated Martian atmospheric conditions. Irradiation of a basaltic rock sample with the laser intensity of 56 MW cm(-2), in carbon-dioxide gas at a pressure of 9 mbar, created target plasma with favorable conditions for excitation of all elements usually found in geological samples. Detection limits of minor constituents (Ba, Cr, Cu, Mn, Ni, Sr, V, and Zr) were in the 3 ppm-30 ppm range depending on the element. The precision varied between 5% and 25% for concentration levels of 1% to 10 ppm, respectively. Generally, the proposed relatively simple TEA CO2 laser-LIBS system provides good sensitivity for geological studies under reduced CO2 pressure. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Spectrochimica Acta. Part B: Atomic Spectroscopy
T1  - The feasibility of TEA CO2 laser-induced plasma for spectrochemical analysis of geological samples in simulated Martian conditions
VL  - 118
SP  - 127
EP  - 136
DO  - 10.1016/j.sab.2016.02.020
ER  - 
@article{
author = "Savović, Jelena and Stoiljković, Milovan and Kuzmanović, Miroslav M. and Momčilović, Miloš and Ciganović, Jovan and Rankovic, Dragan and Živković, Sanja and Trtica, Milan",
year = "2016",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1013",
abstract = "The present work studies the possibility of using pulsed Transversely Excited Atmospheric (TEA) carbon dioxide laser as an energy source for laser-induced breakdown spectroscopy (LIBS) analysis of rocks under simulated Martian atmospheric conditions. Irradiation of a basaltic rock sample with the laser intensity of 56 MW cm(-2), in carbon-dioxide gas at a pressure of 9 mbar, created target plasma with favorable conditions for excitation of all elements usually found in geological samples. Detection limits of minor constituents (Ba, Cr, Cu, Mn, Ni, Sr, V, and Zr) were in the 3 ppm-30 ppm range depending on the element. The precision varied between 5% and 25% for concentration levels of 1% to 10 ppm, respectively. Generally, the proposed relatively simple TEA CO2 laser-LIBS system provides good sensitivity for geological studies under reduced CO2 pressure. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Spectrochimica Acta. Part B: Atomic Spectroscopy",
title = "The feasibility of TEA CO2 laser-induced plasma for spectrochemical analysis of geological samples in simulated Martian conditions",
volume = "118",
pages = "127-136",
doi = "10.1016/j.sab.2016.02.020"
}
Savović, J., Stoiljković, M., Kuzmanović, M. M., Momčilović, M., Ciganović, J., Rankovic, D., Živković, S.,& Trtica, M. (2016). The feasibility of TEA CO2 laser-induced plasma for spectrochemical analysis of geological samples in simulated Martian conditions.
Spectrochimica Acta. Part B: Atomic Spectroscopy, 118, 127-136.
https://doi.org/10.1016/j.sab.2016.02.020
Savović J, Stoiljković M, Kuzmanović MM, Momčilović M, Ciganović J, Rankovic D, Živković S, Trtica M. The feasibility of TEA CO2 laser-induced plasma for spectrochemical analysis of geological samples in simulated Martian conditions. Spectrochimica Acta. Part B: Atomic Spectroscopy. 2016;118:127-136
Savović Jelena, Stoiljković Milovan, Kuzmanović Miroslav M., Momčilović Miloš, Ciganović Jovan, Rankovic Dragan, Živković Sanja, Trtica Milan, "The feasibility of TEA CO2 laser-induced plasma for spectrochemical analysis of geological samples in simulated Martian conditions" 118 (2016):127-136,
https://doi.org/10.1016/j.sab.2016.02.020 .
10
11
12

Complex investigation of charge storage behavior of microporous carbon synthesized by zeolite template

Stojmenović, Marija; Vujković, Milica; Matović, Ljiljana; Krstić, Jugoslav B.; Đukić, Anđelka B.; Dodevski, Vladimir; Živković, Sanja; Mentus, Slavko V.

(2016)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Vujković, Milica
AU  - Matović, Ljiljana
AU  - Krstić, Jugoslav B.
AU  - Đukić, Anđelka B.
AU  - Dodevski, Vladimir
AU  - Živković, Sanja
AU  - Mentus, Slavko V.
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1096
AB  - Microporous zeolite templated carbon (ZTC) was synthesized by impregnation method using zeolite Y (Na-form) as a template, and furfuryl alcohol as a carbon precursor. The characterization was carried out by X-ray diffractometry, Raman spectroscopy, scanning electron microscopy, nitrogen physisorption, elemental analysis and electrochemical methods. Physisorption measurements evidenced high micro pore volume of obtained material (similar to 0.43 cm(3) g(-1)). The charge storage ability in aqueous KOH, H2SO4 and Na2SO4 solutions was systematically studied by cyclic voltammetry, galvanostatic charging/discharging and complex impedance measurements. Specific coulombic capacitance, the hydrogen storage, H-ZTC bonding and relaxation time of adsorption were found to be dependent on the type of electrolyte. Neutral Na2SO4 aqueous solution was found to be the best for supercapacitor application, thanks to: i) the highest available voltage window ii) lowest corrosion and iii) highest capacitance amounting to 123 F g(-1) at 1 A g(-1) (C) 2016 Elsevier Inc. All rights reserved.
T2  - Microporous and Mesoporous Materials
T1  - Complex investigation of charge storage behavior of microporous carbon synthesized by zeolite template
VL  - 228
SP  - 94
EP  - 106
DO  - 10.1016/j.micromeso.2016.03.029
ER  - 
@article{
author = "Stojmenović, Marija and Vujković, Milica and Matović, Ljiljana and Krstić, Jugoslav B. and Đukić, Anđelka B. and Dodevski, Vladimir and Živković, Sanja and Mentus, Slavko V.",
year = "2016",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1096",
abstract = "Microporous zeolite templated carbon (ZTC) was synthesized by impregnation method using zeolite Y (Na-form) as a template, and furfuryl alcohol as a carbon precursor. The characterization was carried out by X-ray diffractometry, Raman spectroscopy, scanning electron microscopy, nitrogen physisorption, elemental analysis and electrochemical methods. Physisorption measurements evidenced high micro pore volume of obtained material (similar to 0.43 cm(3) g(-1)). The charge storage ability in aqueous KOH, H2SO4 and Na2SO4 solutions was systematically studied by cyclic voltammetry, galvanostatic charging/discharging and complex impedance measurements. Specific coulombic capacitance, the hydrogen storage, H-ZTC bonding and relaxation time of adsorption were found to be dependent on the type of electrolyte. Neutral Na2SO4 aqueous solution was found to be the best for supercapacitor application, thanks to: i) the highest available voltage window ii) lowest corrosion and iii) highest capacitance amounting to 123 F g(-1) at 1 A g(-1) (C) 2016 Elsevier Inc. All rights reserved.",
journal = "Microporous and Mesoporous Materials",
title = "Complex investigation of charge storage behavior of microporous carbon synthesized by zeolite template",
volume = "228",
pages = "94-106",
doi = "10.1016/j.micromeso.2016.03.029"
}
Stojmenović, M., Vujković, M., Matović, L., Krstić, J. B., Đukić, A. B., Dodevski, V., Živković, S.,& Mentus, S. V. (2016). Complex investigation of charge storage behavior of microporous carbon synthesized by zeolite template.
Microporous and Mesoporous Materials, 228, 94-106.
https://doi.org/10.1016/j.micromeso.2016.03.029
Stojmenović M, Vujković M, Matović L, Krstić JB, Đukić AB, Dodevski V, Živković S, Mentus SV. Complex investigation of charge storage behavior of microporous carbon synthesized by zeolite template. Microporous and Mesoporous Materials. 2016;228:94-106
Stojmenović Marija, Vujković Milica, Matović Ljiljana, Krstić Jugoslav B., Đukić Anđelka B., Dodevski Vladimir, Živković Sanja, Mentus Slavko V., "Complex investigation of charge storage behavior of microporous carbon synthesized by zeolite template" 228 (2016):94-106,
https://doi.org/10.1016/j.micromeso.2016.03.029 .
14
13
13

Laser-Induced Breakdown Spectroscopy (LIBS): Specific Applications

Trtica, Milan; Savović, Jelena; Stoiljković, Milovan; Kuzmanović, Miroslav M.; Momčilović, Miloš; Ciganović, Jovan; Živković, Sanja

(2015)

TY  - CONF
AU  - Trtica, Milan
AU  - Savović, Jelena
AU  - Stoiljković, Milovan
AU  - Kuzmanović, Miroslav M.
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Živković, Sanja
PY  - 2015
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7093
AB  - A short overview of Laser Induced Breakdown Spectroscopy (LIBS) with emphasis on the new trends is presented. Nowadays, due to unique features of this technique, LIBS has found applications in a great variety of fields. Achievements in the application of LIBS in nuclear area, for hazardous materials detection and in geology were considered. Also, some results recently obtained at VINCA Institute, with LIBS system based on transversely excited atmospheric (TEA) CO2 laser, are presented. Future investigations of LIBS will be oriented toward further improvement of the analytical performance of this technique, as well as on finding new application fields.
T1  - Laser-Induced Breakdown Spectroscopy (LIBS): Specific Applications
VL  - 9810
DO  - 10.1117/12.2228621
ER  - 
@conference{
author = "Trtica, Milan and Savović, Jelena and Stoiljković, Milovan and Kuzmanović, Miroslav M. and Momčilović, Miloš and Ciganović, Jovan and Živković, Sanja",
year = "2015",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/7093",
abstract = "A short overview of Laser Induced Breakdown Spectroscopy (LIBS) with emphasis on the new trends is presented. Nowadays, due to unique features of this technique, LIBS has found applications in a great variety of fields. Achievements in the application of LIBS in nuclear area, for hazardous materials detection and in geology were considered. Also, some results recently obtained at VINCA Institute, with LIBS system based on transversely excited atmospheric (TEA) CO2 laser, are presented. Future investigations of LIBS will be oriented toward further improvement of the analytical performance of this technique, as well as on finding new application fields.",
title = "Laser-Induced Breakdown Spectroscopy (LIBS): Specific Applications",
volume = "9810",
doi = "10.1117/12.2228621"
}
Trtica, M., Savović, J., Stoiljković, M., Kuzmanović, M. M., Momčilović, M., Ciganović, J.,& Živković, S. (2015). Laser-Induced Breakdown Spectroscopy (LIBS): Specific Applications.
, 9810.
https://doi.org/10.1117/12.2228621
Trtica M, Savović J, Stoiljković M, Kuzmanović MM, Momčilović M, Ciganović J, Živković S. Laser-Induced Breakdown Spectroscopy (LIBS): Specific Applications. 2015;9810
Trtica Milan, Savović Jelena, Stoiljković Milovan, Kuzmanović Miroslav M., Momčilović Miloš, Ciganović Jovan, Živković Sanja, "Laser-Induced Breakdown Spectroscopy (LIBS): Specific Applications" 9810 (2015),
https://doi.org/10.1117/12.2228621 .
1
1
1