Đorđević, Vesna R.

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Authority KeyName Variants
orcid::0000-0002-4718-7074
  • Đorđević, Vesna R. (50)
  • Đorđević, Vesna (1)
Projects
Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion Physics of amorphous and nanostructural materials
Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites NanoTBTech - Nanoparticles-based 2D thermal bioimaging technologies
Ministry of Education, Science and Technological Development of the Republic of Serbia Ministry of Science and Technological Development, Republic of Serbia [142001]
Science and Technology Planning Project of Guangdong Province for Applied Science and Technology Research and Development [2016B090931007] Science and Technology Planning Project of Guangdong Province for Applied Science and Technology Research and Development [2017B090917001]
APV Provincial Secretariat for Science and Technological Development of the Republic of Serbia [114-451-1850/2014-03] Bilateral project between France and Serbia (No. 36214NE – Campus France)
Canada Excellence Research Chairs (CERC) program Canada Excellence Research Chairs (CERC) Program
China Postdoctoral Science Foundation [2017M622848] Chongqing University of Posts and Telecommunications (CQUPT) - National High-end Foreign Experts Recruitment Program [Grant GDT20185200479]
Cluster of excellence MATISSE [ANR-11-IDEX-0004-02], DGA (Direction Generale de LArmement, France), a [451-03-39/2016-09/19], Recruitment Program of High-end Foreign Experts [GDW20145200225], Ministry of Education and Research of Estonia [PUT430], European Regional Development Fund [TK141], g [451-03-39/2016-09/19] Cluster of Excellence MATISSE (France)
DGA (Direction Générale de l’Armement, France) Estonian Research Council grant [PUT PRG111]
European Regional Development Fund [TK141] Government of Guangzhou City for international joint project [201704030020]
Guangdong Province [U1801253] Modeling and Numerical Simulations of Complex Many-Body Systems
Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
International Postdoctoral Exchange Fellowship Program [20180056] Joint Funds of the National Natural Science Foundation of China (NSFC) and Yunnan Province [U1702254]
Joint Funds of the National Natural Science Foundation of China (NSFC) and Yunnan Province [U U1702254] Ministry of Science, Republic of Serbia [142001]

Author's Bibliography

Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures

Ristić, Zoran; Đorđević, Vesna; Medić, Mina; Kuzman, Sanja; Sekulić, Milica; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ristić, Zoran
AU  - Đorđević, Vesna
AU  - Medić, Mina
AU  - Kuzman, Sanja
AU  - Sekulić, Milica
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9624
AB  - Cr3+-doped Mg2SiO4 orthorhombic nanoparticles are synthesized by a combustion method. The 3d3 electron configuration of the Cr3+ ion results in the deep-red emission from optical transitions between d-d orbitals. Two overlapping emissions from the Cr3+ spin-forbidden 2Eg→ 4A2g and the spin-allowed 4T2g→ 4A2g electronic transitions are influenced by the strong crystal field in Mg2SiO4 and, thus, are suitable for ratiometric luminescence thermometry. The temperature-induced changes in Cr3+-doped Mg2SiO4 emission are tested for use in luminescence thermometry from cryogenic to physiologically relevant temperatures (10-350 K) by three approaches: (a) temperature-induced changes of emission intensity; (b) temperature-dependent luminescence lifetime; and (c) temperature-induced changes of emission band position. The second approach offers applicable thermometry at cryogenic temperatures, starting from temperatures as low as 50 K, while all three approaches offer applicable thermometry at physiologically relevant temperatures with relative sensitivities of 0.7% K-1 for emission intensity, 0.8% K-1 for lifetime and 0.85% K-1 for band position at 310 K. © 2021 IOP Publishing Ltd.
T2  - Measurement Science and Technology
T1  - Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures
VL  - 32
IS  - 5
SP  - 054004
DO  - 10.1088/1361-6501/abdc9a
ER  - 
@article{
author = "Ristić, Zoran and Đorđević, Vesna and Medić, Mina and Kuzman, Sanja and Sekulić, Milica and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
abstract = "Cr3+-doped Mg2SiO4 orthorhombic nanoparticles are synthesized by a combustion method. The 3d3 electron configuration of the Cr3+ ion results in the deep-red emission from optical transitions between d-d orbitals. Two overlapping emissions from the Cr3+ spin-forbidden 2Eg→ 4A2g and the spin-allowed 4T2g→ 4A2g electronic transitions are influenced by the strong crystal field in Mg2SiO4 and, thus, are suitable for ratiometric luminescence thermometry. The temperature-induced changes in Cr3+-doped Mg2SiO4 emission are tested for use in luminescence thermometry from cryogenic to physiologically relevant temperatures (10-350 K) by three approaches: (a) temperature-induced changes of emission intensity; (b) temperature-dependent luminescence lifetime; and (c) temperature-induced changes of emission band position. The second approach offers applicable thermometry at cryogenic temperatures, starting from temperatures as low as 50 K, while all three approaches offer applicable thermometry at physiologically relevant temperatures with relative sensitivities of 0.7% K-1 for emission intensity, 0.8% K-1 for lifetime and 0.85% K-1 for band position at 310 K. © 2021 IOP Publishing Ltd.",
journal = "Measurement Science and Technology",
title = "Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures",
volume = "32",
number = "5",
pages = "054004",
doi = "10.1088/1361-6501/abdc9a"
}
Ristić, Z., Đorđević, V., Medić, M., Kuzman, S., Sekulić, M., Antić, Ž.,& Dramićanin, M.. (2021). Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures. in Measurement Science and Technology, 32(5), 054004.
https://doi.org/10.1088/1361-6501/abdc9a
Ristić Z, Đorđević V, Medić M, Kuzman S, Sekulić M, Antić Ž, Dramićanin M. Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures. in Measurement Science and Technology. 2021;32(5):054004.
doi:10.1088/1361-6501/abdc9a .
Ristić, Zoran, Đorđević, Vesna, Medić, Mina, Kuzman, Sanja, Sekulić, Milica, Antić, Željka, Dramićanin, Miroslav, "Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures" in Measurement Science and Technology, 32, no. 5 (2021):054004,
https://doi.org/10.1088/1361-6501/abdc9a . .
8
4
5

Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry

Suta, Markus; Antić, Željka; Đorđević, Vesna R.; Kuzman, Sanja; Dramićanin, Miroslav; Meijerink, Andries

(2020)

TY  - JOUR
AU  - Suta, Markus
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Kuzman, Sanja
AU  - Dramićanin, Miroslav
AU  - Meijerink, Andries
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8909
AB  - Ratiometric luminescence thermometry employing luminescence within the biological transparency windows provides high potential for biothermal imaging. Nd3+ is a promising candidate for that purpose due to its intense radiative transitions within biological windows (BWs) I and II and the simultaneous efficient excitability within BW I. This makes Nd3+ almost unique among all lanthanides. Typically, emission from the two 4F3/2 crystal field levels is used for thermometry but the small ~100 cm−1 energy separation limits the sensitivity. A higher sensitivity for physiological temperatures is possible using the luminescence intensity ratio (LIR) of the emissive transitions from the 4F5/2 and 4F3/2 excited spin-orbit levels. Herein, we demonstrate and discuss various pitfalls that can occur in Boltzmann thermometry if this particular LIR is used for physiological temperature sensing. Both microcrystalline, dilute (0.1%) Nd3+-doped LaPO4 and LaPO4: x% Nd3+ (x = 2, 5, 10, 25, 100) nanocrystals serve as an illustrative example. Besides structural and optical characterization of those luminescent thermometers, the impact and consequences of the Nd3+ concentration on their luminescence and performance as Boltzmann-based thermometers are analyzed. For low Nd3+ concentrations, Boltzmann equilibrium starts just around 300 K. At higher Nd3+ concentrations, cross-relaxation processes enhance the decay rates of the 4F3/2 and 4F5/2 levels making the decay faster than the equilibration rates between the levels. It is shown that the onset of the useful temperature sensing range shifts to higher temperatures, even above ~ 450 K for Nd concentrations over 5%. A microscopic explanation for pitfalls in Boltzmann thermometry with Nd3+ is finally given and guidelines for the usability of this lanthanide ion in the field of physiological temperature sensing are elaborated. Insight in competition between thermal coupling through non-radiative transitions and population decay through cross-relaxation of the 4F5/2 and 4F3/2 spin-orbit levels of Nd3+ makes it possible to tailor the thermometric performance of Nd3+ to enable physiological temperature sensing.
T2  - Nanomaterials
T1  - Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry
VL  - 10
IS  - 3
SP  - 543
DO  - 10.3390/nano10030543
ER  - 
@article{
author = "Suta, Markus and Antić, Željka and Đorđević, Vesna R. and Kuzman, Sanja and Dramićanin, Miroslav and Meijerink, Andries",
year = "2020",
abstract = "Ratiometric luminescence thermometry employing luminescence within the biological transparency windows provides high potential for biothermal imaging. Nd3+ is a promising candidate for that purpose due to its intense radiative transitions within biological windows (BWs) I and II and the simultaneous efficient excitability within BW I. This makes Nd3+ almost unique among all lanthanides. Typically, emission from the two 4F3/2 crystal field levels is used for thermometry but the small ~100 cm−1 energy separation limits the sensitivity. A higher sensitivity for physiological temperatures is possible using the luminescence intensity ratio (LIR) of the emissive transitions from the 4F5/2 and 4F3/2 excited spin-orbit levels. Herein, we demonstrate and discuss various pitfalls that can occur in Boltzmann thermometry if this particular LIR is used for physiological temperature sensing. Both microcrystalline, dilute (0.1%) Nd3+-doped LaPO4 and LaPO4: x% Nd3+ (x = 2, 5, 10, 25, 100) nanocrystals serve as an illustrative example. Besides structural and optical characterization of those luminescent thermometers, the impact and consequences of the Nd3+ concentration on their luminescence and performance as Boltzmann-based thermometers are analyzed. For low Nd3+ concentrations, Boltzmann equilibrium starts just around 300 K. At higher Nd3+ concentrations, cross-relaxation processes enhance the decay rates of the 4F3/2 and 4F5/2 levels making the decay faster than the equilibration rates between the levels. It is shown that the onset of the useful temperature sensing range shifts to higher temperatures, even above ~ 450 K for Nd concentrations over 5%. A microscopic explanation for pitfalls in Boltzmann thermometry with Nd3+ is finally given and guidelines for the usability of this lanthanide ion in the field of physiological temperature sensing are elaborated. Insight in competition between thermal coupling through non-radiative transitions and population decay through cross-relaxation of the 4F5/2 and 4F3/2 spin-orbit levels of Nd3+ makes it possible to tailor the thermometric performance of Nd3+ to enable physiological temperature sensing.",
journal = "Nanomaterials",
title = "Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry",
volume = "10",
number = "3",
pages = "543",
doi = "10.3390/nano10030543"
}
Suta, M., Antić, Ž., Đorđević, V. R., Kuzman, S., Dramićanin, M.,& Meijerink, A.. (2020). Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry. in Nanomaterials, 10(3), 543.
https://doi.org/10.3390/nano10030543
Suta M, Antić Ž, Đorđević VR, Kuzman S, Dramićanin M, Meijerink A. Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry. in Nanomaterials. 2020;10(3):543.
doi:10.3390/nano10030543 .
Suta, Markus, Antić, Željka, Đorđević, Vesna R., Kuzman, Sanja, Dramićanin, Miroslav, Meijerink, Andries, "Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry" in Nanomaterials, 10, no. 3 (2020):543,
https://doi.org/10.3390/nano10030543 . .
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34
37

Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders

Kuzman, Sanja; Medić, Mina M.; Đorđević, Vesna R.; Zeković, Ivana Lj.; Ristić, Zoran; Đačanin Far, Ljubica; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Medić, Mina M.
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Ristić, Zoran
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8936
AB  - When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.
T2  - Journal of Electronic Materials
T1  - Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders
VL  - 49
IS  - 6
SP  - 4002
EP  - 4009
DO  - 10.1007/s11664-020-08109-7
ER  - 
@article{
author = "Kuzman, Sanja and Medić, Mina M. and Đorđević, Vesna R. and Zeković, Ivana Lj. and Ristić, Zoran and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2020",
abstract = "When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.",
journal = "Journal of Electronic Materials",
title = "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders",
volume = "49",
number = "6",
pages = "4002-4009",
doi = "10.1007/s11664-020-08109-7"
}
Kuzman, S., Medić, M. M., Đorđević, V. R., Zeković, I. Lj., Ristić, Z., Đačanin Far, L.,& Dramićanin, M.. (2020). Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. in Journal of Electronic Materials, 49(6), 4002-4009.
https://doi.org/10.1007/s11664-020-08109-7
Kuzman S, Medić MM, Đorđević VR, Zeković IL, Ristić Z, Đačanin Far L, Dramićanin M. Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. in Journal of Electronic Materials. 2020;49(6):4002-4009.
doi:10.1007/s11664-020-08109-7 .
Kuzman, Sanja, Medić, Mina M., Đorđević, Vesna R., Zeković, Ivana Lj., Ristić, Zoran, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders" in Journal of Electronic Materials, 49, no. 6 (2020):4002-4009,
https://doi.org/10.1007/s11664-020-08109-7 . .
2
1

Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles

Kuzman, Sanja; Periša, Jovana; Đorđević, Vesna R.; Zeković, Ivana Lj.; Vukoje, Ivana D.; Antić, Željka; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Periša, Jovana
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Vukoje, Ivana D.
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9098
AB  - A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La0.95Eu0.05PO4) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu3+) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu3+ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La0.95Eu0.05PO4 host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La0.95Eu0.05PO4 from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La0.95Eu0.05PO4 increases more than three times when the Eu3+ excitation is supported by the localized surface plasmon resonance in the Ag/La0.95Eu0.05PO4 nanostructures.
T2  - Materials
T1  - Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles
VL  - 13
IS  - 14
SP  - 3071
DO  - 10.3390/ma13143071
ER  - 
@article{
author = "Kuzman, Sanja and Periša, Jovana and Đorđević, Vesna R. and Zeković, Ivana Lj. and Vukoje, Ivana D. and Antić, Željka and Dramićanin, Miroslav",
year = "2020",
abstract = "A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La0.95Eu0.05PO4) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu3+) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu3+ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La0.95Eu0.05PO4 host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La0.95Eu0.05PO4 from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La0.95Eu0.05PO4 increases more than three times when the Eu3+ excitation is supported by the localized surface plasmon resonance in the Ag/La0.95Eu0.05PO4 nanostructures.",
journal = "Materials",
title = "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles",
volume = "13",
number = "14",
pages = "3071",
doi = "10.3390/ma13143071"
}
Kuzman, S., Periša, J., Đorđević, V. R., Zeković, I. Lj., Vukoje, I. D., Antić, Ž.,& Dramićanin, M.. (2020). Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles. in Materials, 13(14), 3071.
https://doi.org/10.3390/ma13143071
Kuzman S, Periša J, Đorđević VR, Zeković IL, Vukoje ID, Antić Ž, Dramićanin M. Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles. in Materials. 2020;13(14):3071.
doi:10.3390/ma13143071 .
Kuzman, Sanja, Periša, Jovana, Đorđević, Vesna R., Zeković, Ivana Lj., Vukoje, Ivana D., Antić, Željka, Dramićanin, Miroslav, "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles" in Materials, 13, no. 14 (2020):3071,
https://doi.org/10.3390/ma13143071 . .
3

Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission

Ćirić, Aleksandar; Aleksić, Jelena; Barudžija, Tanja; Antić, Željka; Đorđević, Vesna R.; Medić, Mina M.; Periša, Jovana; Zeković, Ivana Lj.; Mitrić, Miodrag; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Aleksić, Jelena
AU  - Barudžija, Tanja
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Medić, Mina M.
AU  - Periša, Jovana
AU  - Zeković, Ivana Lj.
AU  - Mitrić, Miodrag
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8938
AB  - The emission of Er3+ provides three combinations of emission bands suitable for ratiometric luminescence thermometry. Two combinations utilize ratios of visible emissions (2H11/2→4I15/2 at 523 nm/ 4S3/2→4I15/2 at 542 nm and 4F7/2→4I15/2 at 485 nm/ 4S3/2→4I15/2 at 545 nm), while emissions from the third combination are located in near-infrared, e.g., in the first biological window (2H11/2→4I13/2 at 793 nm/ 4S3/2→4I13/2 at 840 nm). Herein, we aimed to compare thermometric performances of these three different ratiometric readouts on account of their relative sensitivities, resolutions, and repeatability of measurements. For this aim, we prepared Yb3+,Er3+:YF3 nanopowders by oxide fluorination. The structure of the materials was confirmed by X-ray diffraction analysis and particle morphology was evaluated from FE-SEM measurements. Upconversion emission spectra were measured over the 293–473 K range upon excitation by 980 nm radiation. The obtained relative sensitivities on temperature for 523/542, 485/542, and 793/840 emission intensity ratios were 1.06 ± 0.02, 2.03 ± 0.23, and 0.98 ± 0.10%K−1 with temperature resolutions of 0.3, 0.7, and 1.8 K, respectively. The study showed that the higher relative temperature sensitivity does not necessarily lead to the more precise temperature measurement and better resolution, since it may be compromised by a larger uncertainty in measurement of low-intensity emission bands.
T2  - Nanomaterials
T1  - Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission
VL  - 10
IS  - 4
SP  - 627
DO  - 10.3390/nano10040627
ER  - 
@article{
author = "Ćirić, Aleksandar and Aleksić, Jelena and Barudžija, Tanja and Antić, Željka and Đorđević, Vesna R. and Medić, Mina M. and Periša, Jovana and Zeković, Ivana Lj. and Mitrić, Miodrag and Dramićanin, Miroslav",
year = "2020",
abstract = "The emission of Er3+ provides three combinations of emission bands suitable for ratiometric luminescence thermometry. Two combinations utilize ratios of visible emissions (2H11/2→4I15/2 at 523 nm/ 4S3/2→4I15/2 at 542 nm and 4F7/2→4I15/2 at 485 nm/ 4S3/2→4I15/2 at 545 nm), while emissions from the third combination are located in near-infrared, e.g., in the first biological window (2H11/2→4I13/2 at 793 nm/ 4S3/2→4I13/2 at 840 nm). Herein, we aimed to compare thermometric performances of these three different ratiometric readouts on account of their relative sensitivities, resolutions, and repeatability of measurements. For this aim, we prepared Yb3+,Er3+:YF3 nanopowders by oxide fluorination. The structure of the materials was confirmed by X-ray diffraction analysis and particle morphology was evaluated from FE-SEM measurements. Upconversion emission spectra were measured over the 293–473 K range upon excitation by 980 nm radiation. The obtained relative sensitivities on temperature for 523/542, 485/542, and 793/840 emission intensity ratios were 1.06 ± 0.02, 2.03 ± 0.23, and 0.98 ± 0.10%K−1 with temperature resolutions of 0.3, 0.7, and 1.8 K, respectively. The study showed that the higher relative temperature sensitivity does not necessarily lead to the more precise temperature measurement and better resolution, since it may be compromised by a larger uncertainty in measurement of low-intensity emission bands.",
journal = "Nanomaterials",
title = "Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission",
volume = "10",
number = "4",
pages = "627",
doi = "10.3390/nano10040627"
}
Ćirić, A., Aleksić, J., Barudžija, T., Antić, Ž., Đorđević, V. R., Medić, M. M., Periša, J., Zeković, I. Lj., Mitrić, M.,& Dramićanin, M.. (2020). Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission. in Nanomaterials, 10(4), 627.
https://doi.org/10.3390/nano10040627
Ćirić A, Aleksić J, Barudžija T, Antić Ž, Đorđević VR, Medić MM, Periša J, Zeković IL, Mitrić M, Dramićanin M. Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission. in Nanomaterials. 2020;10(4):627.
doi:10.3390/nano10040627 .
Ćirić, Aleksandar, Aleksić, Jelena, Barudžija, Tanja, Antić, Željka, Đorđević, Vesna R., Medić, Mina M., Periša, Jovana, Zeković, Ivana Lj., Mitrić, Miodrag, Dramićanin, Miroslav, "Comparison of Three Ratiometric Temperature Readings from the Er3+ Upconversion Emission" in Nanomaterials, 10, no. 4 (2020):627,
https://doi.org/10.3390/nano10040627 . .
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Electronic structure of surface complexes between CeO2 and benzene derivatives: A comparative experimental and DFT study

Prekajski-Đorđević, Marija D.; Vukoje, Ivana D.; Lazić, Vesna M.; Đorđević, Vesna R.; Sredojević, Dušan; Dostanić, Jasmina; Lončarević, Davor; Ahrenkiel, Scott Phillip; Belić, Milivoj R.; Nedeljković, Jovan

(2019)

TY  - JOUR
AU  - Prekajski-Đorđević, Marija D.
AU  - Vukoje, Ivana D.
AU  - Lazić, Vesna M.
AU  - Đorđević, Vesna R.
AU  - Sredojević, Dušan
AU  - Dostanić, Jasmina
AU  - Lončarević, Davor
AU  - Ahrenkiel, Scott Phillip
AU  - Belić, Milivoj R.
AU  - Nedeljković, Jovan
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8387
AB  - Surface modification of CeO2 nano-powder, synthesized by a self-propagating room temperature method with salicylate-type ligands (salicylic acid and 5-aminosalicylic acid) as well as catecholate-type ligands (catechol, 3,4-dihydroxybenzoic acid, caffeic acid and 2,3-dihydroxy naphthalene), induces the appearance of absorption in the visible spectral region due to the interfacial charge transfer (ICT) complex formation. Thorough characterization involving transmission electron microscopy, XRD analysis, and nitrogen adsorption-desorption isotherms, revealed that loosely agglomerated CeO2 particles of the size ranging from 2 to 4 nm have cubic fluorite structure and specific surface area of 140 m2/g. The attachment of salicylate- and catecholate-type of ligands to the surface of CeO2 powders leads to the formation of colored powders with tunable absorption in the visible spectral region. The density functional theory calculations with properly design model systems were performed to estimate the alignment of energy levels of various inorganic/organic hybrids. A reasonably good agreement between calculated values and experimental data was found. © 2019
T2  - Materials Chemistry and Physics
T1  - Electronic structure of surface complexes between CeO2 and benzene derivatives: A comparative experimental and DFT study
VL  - 236
SP  - 121816
DO  - 10.1016/j.matchemphys.2019.121816
ER  - 
@article{
author = "Prekajski-Đorđević, Marija D. and Vukoje, Ivana D. and Lazić, Vesna M. and Đorđević, Vesna R. and Sredojević, Dušan and Dostanić, Jasmina and Lončarević, Davor and Ahrenkiel, Scott Phillip and Belić, Milivoj R. and Nedeljković, Jovan",
year = "2019",
abstract = "Surface modification of CeO2 nano-powder, synthesized by a self-propagating room temperature method with salicylate-type ligands (salicylic acid and 5-aminosalicylic acid) as well as catecholate-type ligands (catechol, 3,4-dihydroxybenzoic acid, caffeic acid and 2,3-dihydroxy naphthalene), induces the appearance of absorption in the visible spectral region due to the interfacial charge transfer (ICT) complex formation. Thorough characterization involving transmission electron microscopy, XRD analysis, and nitrogen adsorption-desorption isotherms, revealed that loosely agglomerated CeO2 particles of the size ranging from 2 to 4 nm have cubic fluorite structure and specific surface area of 140 m2/g. The attachment of salicylate- and catecholate-type of ligands to the surface of CeO2 powders leads to the formation of colored powders with tunable absorption in the visible spectral region. The density functional theory calculations with properly design model systems were performed to estimate the alignment of energy levels of various inorganic/organic hybrids. A reasonably good agreement between calculated values and experimental data was found. © 2019",
journal = "Materials Chemistry and Physics",
title = "Electronic structure of surface complexes between CeO2 and benzene derivatives: A comparative experimental and DFT study",
volume = "236",
pages = "121816",
doi = "10.1016/j.matchemphys.2019.121816"
}
Prekajski-Đorđević, M. D., Vukoje, I. D., Lazić, V. M., Đorđević, V. R., Sredojević, D., Dostanić, J., Lončarević, D., Ahrenkiel, S. P., Belić, M. R.,& Nedeljković, J.. (2019). Electronic structure of surface complexes between CeO2 and benzene derivatives: A comparative experimental and DFT study. in Materials Chemistry and Physics, 236, 121816.
https://doi.org/10.1016/j.matchemphys.2019.121816
Prekajski-Đorđević MD, Vukoje ID, Lazić VM, Đorđević VR, Sredojević D, Dostanić J, Lončarević D, Ahrenkiel SP, Belić MR, Nedeljković J. Electronic structure of surface complexes between CeO2 and benzene derivatives: A comparative experimental and DFT study. in Materials Chemistry and Physics. 2019;236:121816.
doi:10.1016/j.matchemphys.2019.121816 .
Prekajski-Đorđević, Marija D., Vukoje, Ivana D., Lazić, Vesna M., Đorđević, Vesna R., Sredojević, Dušan, Dostanić, Jasmina, Lončarević, Davor, Ahrenkiel, Scott Phillip, Belić, Milivoj R., Nedeljković, Jovan, "Electronic structure of surface complexes between CeO2 and benzene derivatives: A comparative experimental and DFT study" in Materials Chemistry and Physics, 236 (2019):121816,
https://doi.org/10.1016/j.matchemphys.2019.121816 . .
3
1
3

Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles

Dolgov, Leonid; Hong, Junyu; Zhou, Lei; Li, Xiaohui; Li, Junhao; Đorđević, Vesna R.; Dramićanin, Miroslav; Shi, Jianxin; Wu, Mingmei

(2019)

TY  - JOUR
AU  - Dolgov, Leonid
AU  - Hong, Junyu
AU  - Zhou, Lei
AU  - Li, Xiaohui
AU  - Li, Junhao
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
AU  - Shi, Jianxin
AU  - Wu, Mingmei
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8349
AB  - One of prospective ways for boosting efficiency of luminescent materials is their combination with noble metal nanoparticles. Collective, so-called plasmon, oscillations of surface electrons in a nanoparticle can resonantly interact with incident or fluorescent light and cause an increase in the light absorption cross section or radiative rate for an adjacent emitter. Plasmonic inorganic phosphors require gentle host crystallization at which added noble nanoparticles will not suffer from aggregation or oxidation. The prospective plasmonic Mg2TiO4:Mn4+ phosphor containing core@shell Ag@SiO2 nanoparticles is prepared here by spare low-temperature annealing of a sol-gel host precursor. It is revealed that Mn4+ luminescence nonmonotonously depends on the size and concentration of 40 and 70 nm silver nanoparticles. It is demonstrated that luminescence of the Mg2TiO4:Mn4+ phosphor can be up to a 1.5 times increase when Mn4+ excitation is supported by localized surface plasmon resonance in Ag@SiO2 nanoparticles. © 2019 American Chemical Society.
T2  - ACS Applied Materials & Interfaces
T1  - Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles
VL  - 11
IS  - 23
SP  - 21004
EP  - 21009
DO  - 10.1021/acsami.9b05781
ER  - 
@article{
author = "Dolgov, Leonid and Hong, Junyu and Zhou, Lei and Li, Xiaohui and Li, Junhao and Đorđević, Vesna R. and Dramićanin, Miroslav and Shi, Jianxin and Wu, Mingmei",
year = "2019",
abstract = "One of prospective ways for boosting efficiency of luminescent materials is their combination with noble metal nanoparticles. Collective, so-called plasmon, oscillations of surface electrons in a nanoparticle can resonantly interact with incident or fluorescent light and cause an increase in the light absorption cross section or radiative rate for an adjacent emitter. Plasmonic inorganic phosphors require gentle host crystallization at which added noble nanoparticles will not suffer from aggregation or oxidation. The prospective plasmonic Mg2TiO4:Mn4+ phosphor containing core@shell Ag@SiO2 nanoparticles is prepared here by spare low-temperature annealing of a sol-gel host precursor. It is revealed that Mn4+ luminescence nonmonotonously depends on the size and concentration of 40 and 70 nm silver nanoparticles. It is demonstrated that luminescence of the Mg2TiO4:Mn4+ phosphor can be up to a 1.5 times increase when Mn4+ excitation is supported by localized surface plasmon resonance in Ag@SiO2 nanoparticles. © 2019 American Chemical Society.",
journal = "ACS Applied Materials & Interfaces",
title = "Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles",
volume = "11",
number = "23",
pages = "21004-21009",
doi = "10.1021/acsami.9b05781"
}
Dolgov, L., Hong, J., Zhou, L., Li, X., Li, J., Đorđević, V. R., Dramićanin, M., Shi, J.,& Wu, M.. (2019). Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles. in ACS Applied Materials & Interfaces, 11(23), 21004-21009.
https://doi.org/10.1021/acsami.9b05781
Dolgov L, Hong J, Zhou L, Li X, Li J, Đorđević VR, Dramićanin M, Shi J, Wu M. Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles. in ACS Applied Materials & Interfaces. 2019;11(23):21004-21009.
doi:10.1021/acsami.9b05781 .
Dolgov, Leonid, Hong, Junyu, Zhou, Lei, Li, Xiaohui, Li, Junhao, Đorđević, Vesna R., Dramićanin, Miroslav, Shi, Jianxin, Wu, Mingmei, "Efficient Luminescence Enhancement of Mg 2 TiO 4 :Mn 4+ Red Phosphor by Incorporating Plasmonic Ag@SiO 2 Nanoparticles" in ACS Applied Materials & Interfaces, 11, no. 23 (2019):21004-21009,
https://doi.org/10.1021/acsami.9b05781 . .
1
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16

Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry

Dramićanin, Miroslav; Milićević, Bojana R.; Đorđević, Vesna R.; Ristić, Zoran; Zhou, Jianbang; Milivojević, Dušan; Papan, Jelena; Brik, Mikhail G.; Ma, Chong‐Geng; Srivastava, Alok M; Wu, Mingmei

(2019)

TY  - JOUR
AU  - Dramićanin, Miroslav
AU  - Milićević, Bojana R.
AU  - Đorđević, Vesna R.
AU  - Ristić, Zoran
AU  - Zhou, Jianbang
AU  - Milivojević, Dušan
AU  - Papan, Jelena
AU  - Brik, Mikhail G.
AU  - Ma, Chong‐Geng
AU  - Srivastava, Alok M
AU  - Wu, Mingmei
PY  - 2019
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201901590
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8360
AB  - Luminescence of monoclinic lithium metatitanate (Li2TiO3) powders activated with different quantities of Mn4+ is studied in detail. Its strong deep-red emission arising from the Mn4+ 2Eg → 4A2g spin forbidden transition is centered at around 688 nm and is suitable for luminescence thermometry. Structural and electron paramagnetic resonance analyses show that Mn4+ ions are equally distributed in two almost identical Ti4+ sites in which they are octahedrally coordinated by six oxygen ions. Calculations based on the exchange charge model of the crystal field provided values of Racah parameters (B=760 cm−1, C= 2993 cm−1), crystal-field splitting Dq= 2043 cm−1, and the nephelauxetic parameter β1=0.9775. The maximal quantum efficiency of 24.1% at room temperature is found for 0.126% Mn4+ concentration. Temperature quenching of emission occurs by a cross-over via 4T2 excited state of the Mn4+ ions with T1/2=262 K and is quite favorable for the application in the lifetime-based luminescence thermometry since relative changes in emission decay values are exceptionally-large (around 3.21% at room temperature). We derived theoretical expressions for the temperature dependence of the absolute and relative sensitivities and discuss the influence of host material properties on lifetime sensitivities. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - ChemistrySelect
T1  - Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry
VL  - 4
IS  - 24
SP  - 7067
EP  - 7075
DO  - 10.1002/slct.201901590
ER  - 
@article{
author = "Dramićanin, Miroslav and Milićević, Bojana R. and Đorđević, Vesna R. and Ristić, Zoran and Zhou, Jianbang and Milivojević, Dušan and Papan, Jelena and Brik, Mikhail G. and Ma, Chong‐Geng and Srivastava, Alok M and Wu, Mingmei",
year = "2019",
abstract = "Luminescence of monoclinic lithium metatitanate (Li2TiO3) powders activated with different quantities of Mn4+ is studied in detail. Its strong deep-red emission arising from the Mn4+ 2Eg → 4A2g spin forbidden transition is centered at around 688 nm and is suitable for luminescence thermometry. Structural and electron paramagnetic resonance analyses show that Mn4+ ions are equally distributed in two almost identical Ti4+ sites in which they are octahedrally coordinated by six oxygen ions. Calculations based on the exchange charge model of the crystal field provided values of Racah parameters (B=760 cm−1, C= 2993 cm−1), crystal-field splitting Dq= 2043 cm−1, and the nephelauxetic parameter β1=0.9775. The maximal quantum efficiency of 24.1% at room temperature is found for 0.126% Mn4+ concentration. Temperature quenching of emission occurs by a cross-over via 4T2 excited state of the Mn4+ ions with T1/2=262 K and is quite favorable for the application in the lifetime-based luminescence thermometry since relative changes in emission decay values are exceptionally-large (around 3.21% at room temperature). We derived theoretical expressions for the temperature dependence of the absolute and relative sensitivities and discuss the influence of host material properties on lifetime sensitivities. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "ChemistrySelect",
title = "Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry",
volume = "4",
number = "24",
pages = "7067-7075",
doi = "10.1002/slct.201901590"
}
Dramićanin, M., Milićević, B. R., Đorđević, V. R., Ristić, Z., Zhou, J., Milivojević, D., Papan, J., Brik, M. G., Ma, C., Srivastava, A. M.,& Wu, M.. (2019). Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry. in ChemistrySelect, 4(24), 7067-7075.
https://doi.org/10.1002/slct.201901590
Dramićanin M, Milićević BR, Đorđević VR, Ristić Z, Zhou J, Milivojević D, Papan J, Brik MG, Ma C, Srivastava AM, Wu M. Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry. in ChemistrySelect. 2019;4(24):7067-7075.
doi:10.1002/slct.201901590 .
Dramićanin, Miroslav, Milićević, Bojana R., Đorđević, Vesna R., Ristić, Zoran, Zhou, Jianbang, Milivojević, Dušan, Papan, Jelena, Brik, Mikhail G., Ma, Chong‐Geng, Srivastava, Alok M, Wu, Mingmei, "Li2TiO3:Mn4+ Deep‐Red Phosphor for the Lifetime‐Based Luminescence Thermometry" in ChemistrySelect, 4, no. 24 (2019):7067-7075,
https://doi.org/10.1002/slct.201901590 . .
1
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19

Li1.8Na0.2TiO3:Mn4+: The highly sensitive probe for the low-temperature lifetime-based luminescence thermometry

Sekulić, Milica; Ristić, Zoran; Milićević, Bojana R.; Antić, Željka; Đorđević, Vesna R.; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Sekulić, Milica
AU  - Ristić, Zoran
AU  - Milićević, Bojana R.
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8421
AB  - In this work, the potential of Li1.8Na0.2TiO3:Mn4+ for the lifetime-based luminescence thermometry is assessed. The material is prepared by the solid-state reaction of Li2CO3, Na2CO3, and nanostructured TiO2 at 800 °C, and its monoclinic structure (space group C2/c) is confirmed by X-ray diffraction analysis. In this host, Mn4+ provides strong absorption around 330 nm and 500 nm due to 4A2g → 4T1g and 4A2g→ 4T2g electric dipole forbidden and spin-allowed electron transitions, respectively, and emits around 679 nm on account of 2Eg→ 4A2g spin forbidden electron transition. Temperature dependences of emission intensity and emission decay are measured over the 10–350 K range. Due to the low value of energy of 4T2g level (20000 cm−1), the strong emission quenching starts at low-temperatures which favors the use of this material for the luminescence thermometry. It is demonstrated that the quite large value of relative sensitivity (2.27% K−1@330 K) facilitates temperature measurements with temperature resolution better than 0.15 K, and with the excellent repeatability. © 2019 Elsevier B.V.
T2  - Optics Communications
T1  - Li1.8Na0.2TiO3:Mn4+: The highly sensitive probe for the low-temperature lifetime-based luminescence thermometry
VL  - 452
SP  - 342
EP  - 346
DO  - 10.1016/j.optcom.2019.07.056
ER  - 
@article{
author = "Sekulić, Milica and Ristić, Zoran and Milićević, Bojana R. and Antić, Željka and Đorđević, Vesna R. and Dramićanin, Miroslav",
year = "2019",
abstract = "In this work, the potential of Li1.8Na0.2TiO3:Mn4+ for the lifetime-based luminescence thermometry is assessed. The material is prepared by the solid-state reaction of Li2CO3, Na2CO3, and nanostructured TiO2 at 800 °C, and its monoclinic structure (space group C2/c) is confirmed by X-ray diffraction analysis. In this host, Mn4+ provides strong absorption around 330 nm and 500 nm due to 4A2g → 4T1g and 4A2g→ 4T2g electric dipole forbidden and spin-allowed electron transitions, respectively, and emits around 679 nm on account of 2Eg→ 4A2g spin forbidden electron transition. Temperature dependences of emission intensity and emission decay are measured over the 10–350 K range. Due to the low value of energy of 4T2g level (20000 cm−1), the strong emission quenching starts at low-temperatures which favors the use of this material for the luminescence thermometry. It is demonstrated that the quite large value of relative sensitivity (2.27% K−1@330 K) facilitates temperature measurements with temperature resolution better than 0.15 K, and with the excellent repeatability. © 2019 Elsevier B.V.",
journal = "Optics Communications",
title = "Li1.8Na0.2TiO3:Mn4+: The highly sensitive probe for the low-temperature lifetime-based luminescence thermometry",
volume = "452",
pages = "342-346",
doi = "10.1016/j.optcom.2019.07.056"
}
Sekulić, M., Ristić, Z., Milićević, B. R., Antić, Ž., Đorđević, V. R.,& Dramićanin, M.. (2019). Li1.8Na0.2TiO3:Mn4+: The highly sensitive probe for the low-temperature lifetime-based luminescence thermometry. in Optics Communications, 452, 342-346.
https://doi.org/10.1016/j.optcom.2019.07.056
Sekulić M, Ristić Z, Milićević BR, Antić Ž, Đorđević VR, Dramićanin M. Li1.8Na0.2TiO3:Mn4+: The highly sensitive probe for the low-temperature lifetime-based luminescence thermometry. in Optics Communications. 2019;452:342-346.
doi:10.1016/j.optcom.2019.07.056 .
Sekulić, Milica, Ristić, Zoran, Milićević, Bojana R., Antić, Željka, Đorđević, Vesna R., Dramićanin, Miroslav, "Li1.8Na0.2TiO3:Mn4+: The highly sensitive probe for the low-temperature lifetime-based luminescence thermometry" in Optics Communications, 452 (2019):342-346,
https://doi.org/10.1016/j.optcom.2019.07.056 . .
15
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14

Radiation effects on luminescent and structural properties of YPO4: Pr3+ nanophosphors

Vujčić, Ivica; Gavrilović, Tamara V.; Sekulić, Milica; Mašić, Slobodan; Milićević, Bojana R.; Dramićanin, Miroslav; Đorđević, Vesna R.

(2018)

TY  - JOUR
AU  - Vujčić, Ivica
AU  - Gavrilović, Tamara V.
AU  - Sekulić, Milica
AU  - Mašić, Slobodan
AU  - Milićević, Bojana R.
AU  - Dramićanin, Miroslav
AU  - Đorđević, Vesna R.
PY  - 2018
UR  - https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056079298&doi=10.1080%2F10420150.2018.1539722&partnerID=40&md5=a0ff2d1025484d944fc36f070a92bb13
UR  - https://www.tandfonline.com/doi/full/10.1080/10420150.2018.1539722
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7964
AB  - YPO4 phosphors doped with trivalent ion Pr3+ were prepared by sol–gel method and treated with different doses of gamma radiation, from 0.25 MGy to 4 MGy. Effects of radiation on morphology, structure and luminescent properties were analyzed. Also, the influence of radiation on the change in the color of the samples was examined. The color efficiency of powders was evaluated by colorimetric analysis (CIE and L * a * b system). It has been observed that powders change color under the influence of radiation, i.e. they pass from white to pinkish red. Also, it has been determined that the radiation affects morphology change, as the particle size increases with increasing of the radiation dose. With the increase in the radiation dose, the emission intensity of samples decreases. The structure remains almost unchanged after irradiation, and the intensity constantly decreases with increasing of dose. © 2018, © 2018 Informa UK Limited, trading as Taylor & Francis Group.
T2  - Radiation Effects and Defects in Solids
T1  - Radiation effects on luminescent and structural properties of YPO4: Pr3+ nanophosphors
VL  - 173
IS  - 11-12
SP  - 1054
EP  - 1067
DO  - 10.1080/10420150.2018.1539722
ER  - 
@article{
author = "Vujčić, Ivica and Gavrilović, Tamara V. and Sekulić, Milica and Mašić, Slobodan and Milićević, Bojana R. and Dramićanin, Miroslav and Đorđević, Vesna R.",
year = "2018",
abstract = "YPO4 phosphors doped with trivalent ion Pr3+ were prepared by sol–gel method and treated with different doses of gamma radiation, from 0.25 MGy to 4 MGy. Effects of radiation on morphology, structure and luminescent properties were analyzed. Also, the influence of radiation on the change in the color of the samples was examined. The color efficiency of powders was evaluated by colorimetric analysis (CIE and L * a * b system). It has been observed that powders change color under the influence of radiation, i.e. they pass from white to pinkish red. Also, it has been determined that the radiation affects morphology change, as the particle size increases with increasing of the radiation dose. With the increase in the radiation dose, the emission intensity of samples decreases. The structure remains almost unchanged after irradiation, and the intensity constantly decreases with increasing of dose. © 2018, © 2018 Informa UK Limited, trading as Taylor & Francis Group.",
journal = "Radiation Effects and Defects in Solids",
title = "Radiation effects on luminescent and structural properties of YPO4: Pr3+ nanophosphors",
volume = "173",
number = "11-12",
pages = "1054-1067",
doi = "10.1080/10420150.2018.1539722"
}
Vujčić, I., Gavrilović, T. V., Sekulić, M., Mašić, S., Milićević, B. R., Dramićanin, M.,& Đorđević, V. R.. (2018). Radiation effects on luminescent and structural properties of YPO4: Pr3+ nanophosphors. in Radiation Effects and Defects in Solids, 173(11-12), 1054-1067.
https://doi.org/10.1080/10420150.2018.1539722
Vujčić I, Gavrilović TV, Sekulić M, Mašić S, Milićević BR, Dramićanin M, Đorđević VR. Radiation effects on luminescent and structural properties of YPO4: Pr3+ nanophosphors. in Radiation Effects and Defects in Solids. 2018;173(11-12):1054-1067.
doi:10.1080/10420150.2018.1539722 .
Vujčić, Ivica, Gavrilović, Tamara V., Sekulić, Milica, Mašić, Slobodan, Milićević, Bojana R., Dramićanin, Miroslav, Đorđević, Vesna R., "Radiation effects on luminescent and structural properties of YPO4: Pr3+ nanophosphors" in Radiation Effects and Defects in Solids, 173, no. 11-12 (2018):1054-1067,
https://doi.org/10.1080/10420150.2018.1539722 . .

Highly Sensitive Dual Self-Referencing Temperature Readout from the Mn4+/Ho3+ Binary Luminescence Thermometry Probe

Sekulić, Milica; Đorđević, Vesna R.; Ristić, Zoran; Medić, Mina M.; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Sekulić, Milica
AU  - Đorđević, Vesna R.
AU  - Ristić, Zoran
AU  - Medić, Mina M.
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - http://doi.wiley.com/10.1002/adom.201800552
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7865
AB  - The binary luminescence thermometry probe is prepared from Y2O3:Ho3+ and Mg2TiO4:Mn4+ powders. This probe facilitates self-referencing temperature readouts with excellent repeatability from both emission intensity ratio and excited state lifetimes. The ratio of intensities of Mn4+ deep red emission from 2E, 4T2→4A2 electronic transitions, and Ho3+ green emission from 5F4,5S2 →5I8 electronic transitions provides temperature measurements over the room temperature to 100 °C temperature range with a superior relative sensitivity of 4.6% °C−1 and temperature resolution of 0.1 °C. Over the same temperature range, the temperature readout from the Mn4+ emission lifetime offers measurements with relative sensitivity better than 0.5% °C−1 and better than 0.2 °C in resolution. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Advanced Optical Materials
T1  - Highly Sensitive Dual Self-Referencing Temperature Readout from the Mn4+/Ho3+ Binary Luminescence Thermometry Probe
VL  - 6
IS  - 17
SP  - 1800552
DO  - 10.1002/adom.201800552
ER  - 
@article{
author = "Sekulić, Milica and Đorđević, Vesna R. and Ristić, Zoran and Medić, Mina M. and Dramićanin, Miroslav",
year = "2018",
abstract = "The binary luminescence thermometry probe is prepared from Y2O3:Ho3+ and Mg2TiO4:Mn4+ powders. This probe facilitates self-referencing temperature readouts with excellent repeatability from both emission intensity ratio and excited state lifetimes. The ratio of intensities of Mn4+ deep red emission from 2E, 4T2→4A2 electronic transitions, and Ho3+ green emission from 5F4,5S2 →5I8 electronic transitions provides temperature measurements over the room temperature to 100 °C temperature range with a superior relative sensitivity of 4.6% °C−1 and temperature resolution of 0.1 °C. Over the same temperature range, the temperature readout from the Mn4+ emission lifetime offers measurements with relative sensitivity better than 0.5% °C−1 and better than 0.2 °C in resolution. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Advanced Optical Materials",
title = "Highly Sensitive Dual Self-Referencing Temperature Readout from the Mn4+/Ho3+ Binary Luminescence Thermometry Probe",
volume = "6",
number = "17",
pages = "1800552",
doi = "10.1002/adom.201800552"
}
Sekulić, M., Đorđević, V. R., Ristić, Z., Medić, M. M.,& Dramićanin, M.. (2018). Highly Sensitive Dual Self-Referencing Temperature Readout from the Mn4+/Ho3+ Binary Luminescence Thermometry Probe. in Advanced Optical Materials, 6(17), 1800552.
https://doi.org/10.1002/adom.201800552
Sekulić M, Đorđević VR, Ristić Z, Medić MM, Dramićanin M. Highly Sensitive Dual Self-Referencing Temperature Readout from the Mn4+/Ho3+ Binary Luminescence Thermometry Probe. in Advanced Optical Materials. 2018;6(17):1800552.
doi:10.1002/adom.201800552 .
Sekulić, Milica, Đorđević, Vesna R., Ristić, Zoran, Medić, Mina M., Dramićanin, Miroslav, "Highly Sensitive Dual Self-Referencing Temperature Readout from the Mn4+/Ho3+ Binary Luminescence Thermometry Probe" in Advanced Optical Materials, 6, no. 17 (2018):1800552,
https://doi.org/10.1002/adom.201800552 . .
64
53
58

Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4

(2018)

TY  - JOUR
PY  - 2018
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7587
AB  - Dy3+-and Nd3+-doped YNbO4 powders were prepared using a mechanochemical method followed by annealing, and their photoluminescent properties were examined to assess the possibility of their use in phosphor thermometry. Luminescence intensity ratio technique was used as a temperature readout scheme for both YNba(4):Dy3+ and YNbO4:Nd3+ samples. The crystalline structure of the samples is confirmed by XRD measurements, while SEM was used for the microstructural and compositional characterization. Sample doped with Dy3+ ions emitting in the blue region has been investigated in the 293-773 K temperature range and exhibits maximal relative sensitivity of 1.97% K-1 at 300 K. YNbO4:Nd3+ sample showed intense NIR emission which fall into the first biological window. When heated from 303 up to 473 K relative temperature sensitivity of 0.28%K-1 at 300 K was achieved. Values of temperature sensitivities show that YNbO4 has a large potential for the development of thermographic phosphors in the blue and NIR spectral ranges when doped with trivalent Dy and Nd, respectively. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Sensors and Actuators A-Physical
T1  - Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4
VL  - 270
SP  - 89
EP  - 96
DO  - 10.1016/j.sna.2017.12.044
ER  - 
@article{
year = "2018",
abstract = "Dy3+-and Nd3+-doped YNbO4 powders were prepared using a mechanochemical method followed by annealing, and their photoluminescent properties were examined to assess the possibility of their use in phosphor thermometry. Luminescence intensity ratio technique was used as a temperature readout scheme for both YNba(4):Dy3+ and YNbO4:Nd3+ samples. The crystalline structure of the samples is confirmed by XRD measurements, while SEM was used for the microstructural and compositional characterization. Sample doped with Dy3+ ions emitting in the blue region has been investigated in the 293-773 K temperature range and exhibits maximal relative sensitivity of 1.97% K-1 at 300 K. YNbO4:Nd3+ sample showed intense NIR emission which fall into the first biological window. When heated from 303 up to 473 K relative temperature sensitivity of 0.28%K-1 at 300 K was achieved. Values of temperature sensitivities show that YNbO4 has a large potential for the development of thermographic phosphors in the blue and NIR spectral ranges when doped with trivalent Dy and Nd, respectively. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Sensors and Actuators A-Physical",
title = "Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4",
volume = "270",
pages = "89-96",
doi = "10.1016/j.sna.2017.12.044"
}
(2018). Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4. in Sensors and Actuators A-Physical, 270, 89-96.
https://doi.org/10.1016/j.sna.2017.12.044
Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4. in Sensors and Actuators A-Physical. 2018;270:89-96.
doi:10.1016/j.sna.2017.12.044 .
"Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4" in Sensors and Actuators A-Physical, 270 (2018):89-96,
https://doi.org/10.1016/j.sna.2017.12.044 . .
26
21
24

MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe

Glais, Estelle; Đorđević, Vesna R.; Papan, Jelena; Viana, Bruno; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Glais, Estelle
AU  - Đorđević, Vesna R.
AU  - Papan, Jelena
AU  - Viana, Bruno
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - http://xlink.rsc.org/?DOI=C8RA02482K
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7693
AB  - MgTiO3 nanoparticles doped with Mn4+, with homogeneous size ranging about 63.1 ± 9.8 nm, were synthesized by a molten salt assisted sol gel method. These nanoparticles have been investigated as optical thermal sensors. The luminescence of tetravalent manganese ion in octahedral environment within the perovskite host presents drastic variations with temperature. Three different thermometry approaches have been proposed and characterized. Two luminescence intensity ratios are studied. Firstly between the two R-lines of Mn4+ emission at low temperature (-250 °C and -90 °C) with a maximal sensitivity of 0.9% °C-1, but also secondly between 2E → 4A2 (R-line) and the 4T2 → 4A2 transitions. This allows studying the temperature variation within a larger temperature range (-200 °C to 50 °C) with a sensitivity between 0.6% °C-1 and 1.2% °C-1 over this range. The last proposed method is the study of the lifetime variation versus temperature. The effective lifetime value corresponds to a combination of transitions from two excited energy levels of the tetravalent manganese (2E and 4T2) in thermal equilibrium toward the fundamental 4A2 state. Since the more energetic transition (4T2 → 4A2) is spin-allowed, contrary to the 2E → 4A2 one, the lifetime drastically decreases with the increase in temperature leading to an impressive high sensitivity value of 4.1% °C-1 at 4 °C and an exceptional temperature resolution of 0.025 °C. According to their optical features, MgTiO3:Mn4+ nanoparticles are indeed suitable candidates for the luminescence temperature probes at the nanoscale over several temperature ranges.
T2  - RSC Advances
T1  - MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe
VL  - 8
IS  - 33
SP  - 18341
EP  - 18346
DO  - 10.1039/C8RA02482K
ER  - 
@article{
author = "Glais, Estelle and Đorđević, Vesna R. and Papan, Jelena and Viana, Bruno and Dramićanin, Miroslav",
year = "2018",
abstract = "MgTiO3 nanoparticles doped with Mn4+, with homogeneous size ranging about 63.1 ± 9.8 nm, were synthesized by a molten salt assisted sol gel method. These nanoparticles have been investigated as optical thermal sensors. The luminescence of tetravalent manganese ion in octahedral environment within the perovskite host presents drastic variations with temperature. Three different thermometry approaches have been proposed and characterized. Two luminescence intensity ratios are studied. Firstly between the two R-lines of Mn4+ emission at low temperature (-250 °C and -90 °C) with a maximal sensitivity of 0.9% °C-1, but also secondly between 2E → 4A2 (R-line) and the 4T2 → 4A2 transitions. This allows studying the temperature variation within a larger temperature range (-200 °C to 50 °C) with a sensitivity between 0.6% °C-1 and 1.2% °C-1 over this range. The last proposed method is the study of the lifetime variation versus temperature. The effective lifetime value corresponds to a combination of transitions from two excited energy levels of the tetravalent manganese (2E and 4T2) in thermal equilibrium toward the fundamental 4A2 state. Since the more energetic transition (4T2 → 4A2) is spin-allowed, contrary to the 2E → 4A2 one, the lifetime drastically decreases with the increase in temperature leading to an impressive high sensitivity value of 4.1% °C-1 at 4 °C and an exceptional temperature resolution of 0.025 °C. According to their optical features, MgTiO3:Mn4+ nanoparticles are indeed suitable candidates for the luminescence temperature probes at the nanoscale over several temperature ranges.",
journal = "RSC Advances",
title = "MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe",
volume = "8",
number = "33",
pages = "18341-18346",
doi = "10.1039/C8RA02482K"
}
Glais, E., Đorđević, V. R., Papan, J., Viana, B.,& Dramićanin, M.. (2018). MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe. in RSC Advances, 8(33), 18341-18346.
https://doi.org/10.1039/C8RA02482K
Glais E, Đorđević VR, Papan J, Viana B, Dramićanin M. MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe. in RSC Advances. 2018;8(33):18341-18346.
doi:10.1039/C8RA02482K .
Glais, Estelle, Đorđević, Vesna R., Papan, Jelena, Viana, Bruno, Dramićanin, Miroslav, "MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe" in RSC Advances, 8, no. 33 (2018):18341-18346,
https://doi.org/10.1039/C8RA02482K . .
29
27
26

Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study

Sredojević, Dušan; Kovač, Tijana S.; Džunuzović, Enis S.; Đorđević, Vesna R.; Grgur, Branimir N.; Nedeljković, Jovan

(2017)

TY  - JOUR
AU  - Sredojević, Dušan
AU  - Kovač, Tijana S.
AU  - Džunuzović, Enis S.
AU  - Đorđević, Vesna R.
AU  - Grgur, Branimir N.
AU  - Nedeljković, Jovan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1724
AB  - The charge transfer complex formation between TiO2 powder and variety of phenol derivatives (phenol, 4-nitrophenol, 4-bromophenol, 4-tert-butylphenol, hydroquinone) was achieved. The red-shift of optical absorption was observed upon surface modification of TiO2 powders with phenol derivatives. The influence of substituent functional groups in para position on the optical band gap and conduction band edge of inorganic/organic hybrids was studied using reflection spectroscopy and cyclic voltammetry. The experimental findings were supported by density functional theory calculations. The measured reflection spectra of surface-modified TiO2 powders with phenol derivatives were compared with calculated electronic excitation spectra of corresponding model systems. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Chemical Physics Letters
T1  - Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study
VL  - 686
SP  - 167
EP  - 172
DO  - 10.1016/j.cplett.2017.08.023
ER  - 
@article{
author = "Sredojević, Dušan and Kovač, Tijana S. and Džunuzović, Enis S. and Đorđević, Vesna R. and Grgur, Branimir N. and Nedeljković, Jovan",
year = "2017",
abstract = "The charge transfer complex formation between TiO2 powder and variety of phenol derivatives (phenol, 4-nitrophenol, 4-bromophenol, 4-tert-butylphenol, hydroquinone) was achieved. The red-shift of optical absorption was observed upon surface modification of TiO2 powders with phenol derivatives. The influence of substituent functional groups in para position on the optical band gap and conduction band edge of inorganic/organic hybrids was studied using reflection spectroscopy and cyclic voltammetry. The experimental findings were supported by density functional theory calculations. The measured reflection spectra of surface-modified TiO2 powders with phenol derivatives were compared with calculated electronic excitation spectra of corresponding model systems. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Chemical Physics Letters",
title = "Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study",
volume = "686",
pages = "167-172",
doi = "10.1016/j.cplett.2017.08.023"
}
Sredojević, D., Kovač, T. S., Džunuzović, E. S., Đorđević, V. R., Grgur, B. N.,& Nedeljković, J.. (2017). Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study. in Chemical Physics Letters, 686, 167-172.
https://doi.org/10.1016/j.cplett.2017.08.023
Sredojević D, Kovač TS, Džunuzović ES, Đorđević VR, Grgur BN, Nedeljković J. Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study. in Chemical Physics Letters. 2017;686:167-172.
doi:10.1016/j.cplett.2017.08.023 .
Sredojević, Dušan, Kovač, Tijana S., Džunuzović, Enis S., Đorđević, Vesna R., Grgur, Branimir N., Nedeljković, Jovan, "Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study" in Chemical Physics Letters, 686 (2017):167-172,
https://doi.org/10.1016/j.cplett.2017.08.023 . .
15
14
18

Hybrid visible-light responsive Al2O3 particles

Đorđević, Vesna R.; Dostanic, Jasmina; Lončarević, Davor; Ahrenkiel, Scott Phillip; Sredojević, Dušan; Švrakić, Nenad M.; Belić, Milivoj R.; Nedeljković, Jovan

(2017)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Dostanic, Jasmina
AU  - Lončarević, Davor
AU  - Ahrenkiel, Scott Phillip
AU  - Sredojević, Dušan
AU  - Švrakić, Nenad M.
AU  - Belić, Milivoj R.
AU  - Nedeljković, Jovan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1723
AB  - Detailed study of Al2O3, an insulator with the band gap of about 8.7 eV, and its different organic/inorganic charge transfer complexes with visible-light photo activity is presented. In particular, prepared Al2O3 particles of the size 0.1-0.3 mu m are coated with several organic complexes - the specific details for catecholate- and salicylate-type of ligands are described below - and the light absorption properties and photocatalytic activity of such hybrids are scrutinized and compared with those of other organic/inorganic hybrid materials previously studied. In addition, the obtained experimental results are supported with quantum chemical calculations based on density functional theory. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Chemical Physics Letters
T1  - Hybrid visible-light responsive Al2O3 particles
VL  - 685
SP  - 416
EP  - 421
DO  - 10.1016/j.cplett.2017.08.012
ER  - 
@article{
author = "Đorđević, Vesna R. and Dostanic, Jasmina and Lončarević, Davor and Ahrenkiel, Scott Phillip and Sredojević, Dušan and Švrakić, Nenad M. and Belić, Milivoj R. and Nedeljković, Jovan",
year = "2017",
abstract = "Detailed study of Al2O3, an insulator with the band gap of about 8.7 eV, and its different organic/inorganic charge transfer complexes with visible-light photo activity is presented. In particular, prepared Al2O3 particles of the size 0.1-0.3 mu m are coated with several organic complexes - the specific details for catecholate- and salicylate-type of ligands are described below - and the light absorption properties and photocatalytic activity of such hybrids are scrutinized and compared with those of other organic/inorganic hybrid materials previously studied. In addition, the obtained experimental results are supported with quantum chemical calculations based on density functional theory. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Chemical Physics Letters",
title = "Hybrid visible-light responsive Al2O3 particles",
volume = "685",
pages = "416-421",
doi = "10.1016/j.cplett.2017.08.012"
}
Đorđević, V. R., Dostanic, J., Lončarević, D., Ahrenkiel, S. P., Sredojević, D., Švrakić, N. M., Belić, M. R.,& Nedeljković, J.. (2017). Hybrid visible-light responsive Al2O3 particles. in Chemical Physics Letters, 685, 416-421.
https://doi.org/10.1016/j.cplett.2017.08.012
Đorđević VR, Dostanic J, Lončarević D, Ahrenkiel SP, Sredojević D, Švrakić NM, Belić MR, Nedeljković J. Hybrid visible-light responsive Al2O3 particles. in Chemical Physics Letters. 2017;685:416-421.
doi:10.1016/j.cplett.2017.08.012 .
Đorđević, Vesna R., Dostanic, Jasmina, Lončarević, Davor, Ahrenkiel, Scott Phillip, Sredojević, Dušan, Švrakić, Nenad M., Belić, Milivoj R., Nedeljković, Jovan, "Hybrid visible-light responsive Al2O3 particles" in Chemical Physics Letters, 685 (2017):416-421,
https://doi.org/10.1016/j.cplett.2017.08.012 . .
10
8
9

Charge-transfer complex formation between TiO2 nanoparticles and thiosalicylic acid: A comprehensive experimental and DFT study

Milićević, Bojana R.; Đorđević, Vesna R.; Lončarević, Davor; Dostanic, Jasmina M.; Ahrenkiel, Scott Phillip; Dramićanin, Miroslav; Sredojević, Dušan; Švrakić, Nenad M.; Nedeljković, Jovan

(2017)

TY  - JOUR
AU  - Milićević, Bojana R.
AU  - Đorđević, Vesna R.
AU  - Lončarević, Davor
AU  - Dostanic, Jasmina M.
AU  - Ahrenkiel, Scott Phillip
AU  - Dramićanin, Miroslav
AU  - Sredojević, Dušan
AU  - Švrakić, Nenad M.
AU  - Nedeljković, Jovan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1815
AB  - Under normal conditions, titanium dioxide does not absorb visible light photons due to large band gap. Nevertheless, when titanium dioxide nanoparticles (TiO2 NPs) are surface-modified with thiosalicylic acid (TSA), their optical properties are altered owing to the formation of charge transfer complex that initiates absorption in the visible spectral range. Colloidal and sol-gel techniques were used to synthesize uniform TiO2 NPs of different sizes (average diameters in the range 4-15 nm), and effects of their subsequent modification by TSA molecules were compared with effect of modification of commercial Degussa TiO2 powder. Thorough microstructural characterization of TiO2 nanoparticulates was performed including transmission electron microscopy (TEM) and X-ray diffraction (XRD) analysis, as well as nitrogen adsorption-desorption isotherms. Optical measurements revealed that all surface-modified TiO2 samples with TSA have similar spectral features independent of their morphological differences, and, more importantly, absorption onset of modified TiO2 samples was found to be red-shifted by 1.0 eV compared to the unmodified ones. The mode of binding between TSA and surface Ti atoms was analyzed by infrared spectroscopy. Finally, the quantum chemical calculations, based on density functional theory, were performed to support optical characterization of surface-modified TiO2 with TSA. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Charge-transfer complex formation between TiO2 nanoparticles and thiosalicylic acid: A comprehensive experimental and DFT study
VL  - 73
SP  - 163
EP  - 171
DO  - 10.1016/j.optmat.2017.08.011
ER  - 
@article{
author = "Milićević, Bojana R. and Đorđević, Vesna R. and Lončarević, Davor and Dostanic, Jasmina M. and Ahrenkiel, Scott Phillip and Dramićanin, Miroslav and Sredojević, Dušan and Švrakić, Nenad M. and Nedeljković, Jovan",
year = "2017",
abstract = "Under normal conditions, titanium dioxide does not absorb visible light photons due to large band gap. Nevertheless, when titanium dioxide nanoparticles (TiO2 NPs) are surface-modified with thiosalicylic acid (TSA), their optical properties are altered owing to the formation of charge transfer complex that initiates absorption in the visible spectral range. Colloidal and sol-gel techniques were used to synthesize uniform TiO2 NPs of different sizes (average diameters in the range 4-15 nm), and effects of their subsequent modification by TSA molecules were compared with effect of modification of commercial Degussa TiO2 powder. Thorough microstructural characterization of TiO2 nanoparticulates was performed including transmission electron microscopy (TEM) and X-ray diffraction (XRD) analysis, as well as nitrogen adsorption-desorption isotherms. Optical measurements revealed that all surface-modified TiO2 samples with TSA have similar spectral features independent of their morphological differences, and, more importantly, absorption onset of modified TiO2 samples was found to be red-shifted by 1.0 eV compared to the unmodified ones. The mode of binding between TSA and surface Ti atoms was analyzed by infrared spectroscopy. Finally, the quantum chemical calculations, based on density functional theory, were performed to support optical characterization of surface-modified TiO2 with TSA. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Charge-transfer complex formation between TiO2 nanoparticles and thiosalicylic acid: A comprehensive experimental and DFT study",
volume = "73",
pages = "163-171",
doi = "10.1016/j.optmat.2017.08.011"
}
Milićević, B. R., Đorđević, V. R., Lončarević, D., Dostanic, J. M., Ahrenkiel, S. P., Dramićanin, M., Sredojević, D., Švrakić, N. M.,& Nedeljković, J.. (2017). Charge-transfer complex formation between TiO2 nanoparticles and thiosalicylic acid: A comprehensive experimental and DFT study. in Optical Materials, 73, 163-171.
https://doi.org/10.1016/j.optmat.2017.08.011
Milićević BR, Đorđević VR, Lončarević D, Dostanic JM, Ahrenkiel SP, Dramićanin M, Sredojević D, Švrakić NM, Nedeljković J. Charge-transfer complex formation between TiO2 nanoparticles and thiosalicylic acid: A comprehensive experimental and DFT study. in Optical Materials. 2017;73:163-171.
doi:10.1016/j.optmat.2017.08.011 .
Milićević, Bojana R., Đorđević, Vesna R., Lončarević, Davor, Dostanic, Jasmina M., Ahrenkiel, Scott Phillip, Dramićanin, Miroslav, Sredojević, Dušan, Švrakić, Nenad M., Nedeljković, Jovan, "Charge-transfer complex formation between TiO2 nanoparticles and thiosalicylic acid: A comprehensive experimental and DFT study" in Optical Materials, 73 (2017):163-171,
https://doi.org/10.1016/j.optmat.2017.08.011 . .
6
7
8

Effects of Li+ co-doping on properties of Eu3+ activated TiO2 anatase nanoparticles

Milićević, Bojana R.; Đorđević, Vesna R.; Vuković, Katarina; Dražić, Goran; Dramićanin, Miroslav

(2017)

TY  - JOUR
AU  - Milićević, Bojana R.
AU  - Đorđević, Vesna R.
AU  - Vuković, Katarina
AU  - Dražić, Goran
AU  - Dramićanin, Miroslav
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1799
AB  - Sol-gel technique for the synthesis of anatase TiO2 at 420 degrees C produces nanocrystals of 10-20 nm in size with Ti4+ in crystal volume and Ti3+ at terminal planes of the crystal. The study of Li+ co-doping effects on the structure, morphology, absorption, and luminescence of Eu3+ activated TiO2 anatase nanocrystals is presented. Pure anatase structure is achieved up to 9 at.% Li, with significant improvement in crystallinity of europium doped anatase TiO2. The Li+ co-doping reduces the unit cell volume of the crystal, induces the blue shift of the absorption edge, lengthens the lifetime of Eu3+ D-5(0) excited state, and improves the Eu3+ emission intensity up to 37.5%. Judd-Ofelt analysis of Eu3+ emission showed enhancement of quantum efficiency from 66.4% to 98.7% when TiO2:Eu3+ was co-doped with 9 at.% of Li. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Effects of Li+ co-doping on properties of Eu3+ activated TiO2 anatase nanoparticles
VL  - 72
SP  - 316
EP  - 322
DO  - 10.1016/j.optmat.2017.06.029
ER  - 
@article{
author = "Milićević, Bojana R. and Đorđević, Vesna R. and Vuković, Katarina and Dražić, Goran and Dramićanin, Miroslav",
year = "2017",
abstract = "Sol-gel technique for the synthesis of anatase TiO2 at 420 degrees C produces nanocrystals of 10-20 nm in size with Ti4+ in crystal volume and Ti3+ at terminal planes of the crystal. The study of Li+ co-doping effects on the structure, morphology, absorption, and luminescence of Eu3+ activated TiO2 anatase nanocrystals is presented. Pure anatase structure is achieved up to 9 at.% Li, with significant improvement in crystallinity of europium doped anatase TiO2. The Li+ co-doping reduces the unit cell volume of the crystal, induces the blue shift of the absorption edge, lengthens the lifetime of Eu3+ D-5(0) excited state, and improves the Eu3+ emission intensity up to 37.5%. Judd-Ofelt analysis of Eu3+ emission showed enhancement of quantum efficiency from 66.4% to 98.7% when TiO2:Eu3+ was co-doped with 9 at.% of Li. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Effects of Li+ co-doping on properties of Eu3+ activated TiO2 anatase nanoparticles",
volume = "72",
pages = "316-322",
doi = "10.1016/j.optmat.2017.06.029"
}
Milićević, B. R., Đorđević, V. R., Vuković, K., Dražić, G.,& Dramićanin, M.. (2017). Effects of Li+ co-doping on properties of Eu3+ activated TiO2 anatase nanoparticles. in Optical Materials, 72, 316-322.
https://doi.org/10.1016/j.optmat.2017.06.029
Milićević BR, Đorđević VR, Vuković K, Dražić G, Dramićanin M. Effects of Li+ co-doping on properties of Eu3+ activated TiO2 anatase nanoparticles. in Optical Materials. 2017;72:316-322.
doi:10.1016/j.optmat.2017.06.029 .
Milićević, Bojana R., Đorđević, Vesna R., Vuković, Katarina, Dražić, Goran, Dramićanin, Miroslav, "Effects of Li+ co-doping on properties of Eu3+ activated TiO2 anatase nanoparticles" in Optical Materials, 72 (2017):316-322,
https://doi.org/10.1016/j.optmat.2017.06.029 . .
10
8
10

White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors

Antic, Z.; Kuzman, Sanja; Đorđević, Vesna R.; Dramićanin, Miroslav; Thundat, Thomas

(2017)

TY  - JOUR
AU  - Antic, Z.
AU  - Kuzman, Sanja
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
AU  - Thundat, Thomas
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1571
AB  - Here we report the synthesis and structural, morphological, and photoluminescence analysis of white- and blue-light-emitting Dy3+- and Tm3+-doped Gd2Ti2O7 nanophosphors. Single-phase cubic Gd2Ti2O7 nanopowders consist of compact, dense aggregates of nanoparticles with an average size of similar to 25 nm for Dy3+-doped and similar to 50 nm for Tm3+-doped samples. The photoluminescence results indicated that ultraviolet (UV) light excitation of the Dy3+-doped sample resulted in direct generation of white light, while a dominant yellow emission was obtained under blue-light excitation. Intense blue light was obtained for Tm3+-doped Gd2Ti2O7 under UV excitation suggesting that this material could be used as a blue phosphor.
T2  - Luminescence
T1  - White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors
VL  - 32
IS  - 4
SP  - 539
EP  - 544
DO  - 10.1002/bio.3210
ER  - 
@article{
author = "Antic, Z. and Kuzman, Sanja and Đorđević, Vesna R. and Dramićanin, Miroslav and Thundat, Thomas",
year = "2017",
abstract = "Here we report the synthesis and structural, morphological, and photoluminescence analysis of white- and blue-light-emitting Dy3+- and Tm3+-doped Gd2Ti2O7 nanophosphors. Single-phase cubic Gd2Ti2O7 nanopowders consist of compact, dense aggregates of nanoparticles with an average size of similar to 25 nm for Dy3+-doped and similar to 50 nm for Tm3+-doped samples. The photoluminescence results indicated that ultraviolet (UV) light excitation of the Dy3+-doped sample resulted in direct generation of white light, while a dominant yellow emission was obtained under blue-light excitation. Intense blue light was obtained for Tm3+-doped Gd2Ti2O7 under UV excitation suggesting that this material could be used as a blue phosphor.",
journal = "Luminescence",
title = "White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors",
volume = "32",
number = "4",
pages = "539-544",
doi = "10.1002/bio.3210"
}
Antic, Z., Kuzman, S., Đorđević, V. R., Dramićanin, M.,& Thundat, T.. (2017). White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors. in Luminescence, 32(4), 539-544.
https://doi.org/10.1002/bio.3210
Antic Z, Kuzman S, Đorđević VR, Dramićanin M, Thundat T. White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors. in Luminescence. 2017;32(4):539-544.
doi:10.1002/bio.3210 .
Antic, Z., Kuzman, Sanja, Đorđević, Vesna R., Dramićanin, Miroslav, Thundat, Thomas, "White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors" in Luminescence, 32, no. 4 (2017):539-544,
https://doi.org/10.1002/bio.3210 . .
3
2
2

The photocatalytic performance of silver halides - Silver carbonate heterostructures

Dostanic, Jasmina; Lončarević, Davor; Đorđević, Vesna R.; Ahrenkiel, Scott Phillip; Nedeljković, Jovan

(2017)

TY  - JOUR
AU  - Dostanic, Jasmina
AU  - Lončarević, Davor
AU  - Đorđević, Vesna R.
AU  - Ahrenkiel, Scott Phillip
AU  - Nedeljković, Jovan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1425
AB  - The synthesized rod-like Ag2CO3 particles (2-4 x 0.3-0.6 mu m, length x diameter) served as a precursor for preparation of the AgX/Ag2CO3 (X = CI, I) composites by ion exchange method. The various microstructural (X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption desorption isotherms) and optical (diffuse reflection spectroscopy) techniques were used for thorough characterization of obtained heterostructures. The enhanced photocatalytic performance of AgX/Ag2CO3 heterostructures in comparison to Ag2CO3 nanorods (NRs) was evidenced using degradation of organic dye methylene blue as a test reaction. Also, the formation of composites improved their stability under long run illumination conditions. The effect of AgX content on photocatalytic activity of the composites were also investigated. The possible photocatalytic mechanism that facilitates efficient separation of photo-formed charge carriers in heterostructures was discussed in terms of the relative energetic of valence and conduction bands. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Journal of Photochemistry and Photobiology. A: Chemistry
T1  - The photocatalytic performance of silver halides - Silver carbonate heterostructures
VL  - 336
SP  - 1
EP  - 7
DO  - 10.1016/j.jphotochem.2016.12.019
ER  - 
@article{
author = "Dostanic, Jasmina and Lončarević, Davor and Đorđević, Vesna R. and Ahrenkiel, Scott Phillip and Nedeljković, Jovan",
year = "2017",
abstract = "The synthesized rod-like Ag2CO3 particles (2-4 x 0.3-0.6 mu m, length x diameter) served as a precursor for preparation of the AgX/Ag2CO3 (X = CI, I) composites by ion exchange method. The various microstructural (X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption desorption isotherms) and optical (diffuse reflection spectroscopy) techniques were used for thorough characterization of obtained heterostructures. The enhanced photocatalytic performance of AgX/Ag2CO3 heterostructures in comparison to Ag2CO3 nanorods (NRs) was evidenced using degradation of organic dye methylene blue as a test reaction. Also, the formation of composites improved their stability under long run illumination conditions. The effect of AgX content on photocatalytic activity of the composites were also investigated. The possible photocatalytic mechanism that facilitates efficient separation of photo-formed charge carriers in heterostructures was discussed in terms of the relative energetic of valence and conduction bands. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Journal of Photochemistry and Photobiology. A: Chemistry",
title = "The photocatalytic performance of silver halides - Silver carbonate heterostructures",
volume = "336",
pages = "1-7",
doi = "10.1016/j.jphotochem.2016.12.019"
}
Dostanic, J., Lončarević, D., Đorđević, V. R., Ahrenkiel, S. P.,& Nedeljković, J.. (2017). The photocatalytic performance of silver halides - Silver carbonate heterostructures. in Journal of Photochemistry and Photobiology. A: Chemistry, 336, 1-7.
https://doi.org/10.1016/j.jphotochem.2016.12.019
Dostanic J, Lončarević D, Đorđević VR, Ahrenkiel SP, Nedeljković J. The photocatalytic performance of silver halides - Silver carbonate heterostructures. in Journal of Photochemistry and Photobiology. A: Chemistry. 2017;336:1-7.
doi:10.1016/j.jphotochem.2016.12.019 .
Dostanic, Jasmina, Lončarević, Davor, Đorđević, Vesna R., Ahrenkiel, Scott Phillip, Nedeljković, Jovan, "The photocatalytic performance of silver halides - Silver carbonate heterostructures" in Journal of Photochemistry and Photobiology. A: Chemistry, 336 (2017):1-7,
https://doi.org/10.1016/j.jphotochem.2016.12.019 . .
5
5
5
4

Antimicrobial and Photocatalytic Abilities of Ag2CO3 Nano-Rods

Lončarević, Davor; Vukoje, Ivana D.; Dostanic, Jasmina; Bjelajac, Anđelika; Đorđević, Vesna R.; Dimitrijević, Suzana I.; Nedeljković, Jovan

(2017)

TY  - JOUR
AU  - Lončarević, Davor
AU  - Vukoje, Ivana D.
AU  - Dostanic, Jasmina
AU  - Bjelajac, Anđelika
AU  - Đorđević, Vesna R.
AU  - Dimitrijević, Suzana I.
AU  - Nedeljković, Jovan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1499
AB  - The rod-like Ag2CO3 particles (2-4 3 0.3-0.6 mm, length 3 diameter) were synthesized in water by the precipitation reaction between AgNO3 and NaHCO3 in the presence of polyvinylpyrrolidone. The X-ray diffraction analysis revealed the co-existence of monoclinic and hexagonal phases of Ag2CO3, without presence of impurities. The band gap energy of Ag-2 CO3 was found to be 1.4 eV from the diffuse reflectance spectra. Photocatalytic ability of Ag2CO3 was tested using degradation reaction of the organic dye methylene blue over the wide range of concentrations, as well as under long run working conditions in repeated cycles. The photocatalytic mechanism was discussed in terms of the relative energetics of valence and conduction band. Antimicrobial efficiency of Ag-2 CO3 in dark was tested against Gram-negative bacteria E. coli. The Ag2CO3 dispersions in the concentration range 0.1-1.0 mg/mL ensured 100% reduction of bacteria cells. Time-dependent measurements revealed that reduction rates of bacteria cells vary in ascending order with the content of Ag2CO3. On the other hand, the observed reduction rates of bacteria cells do not depend on the concentration of coexisting free Ag+ ions (from 2 to 25 mg/L) present in Ag2CO3 dispersion.
T2  - Chemistryselect
T1  - Antimicrobial and Photocatalytic Abilities of Ag2CO3 Nano-Rods
VL  - 2
IS  - 10
SP  - 2931
EP  - 2938
DO  - 10.1002/slct.201700003
ER  - 
@article{
author = "Lončarević, Davor and Vukoje, Ivana D. and Dostanic, Jasmina and Bjelajac, Anđelika and Đorđević, Vesna R. and Dimitrijević, Suzana I. and Nedeljković, Jovan",
year = "2017",
abstract = "The rod-like Ag2CO3 particles (2-4 3 0.3-0.6 mm, length 3 diameter) were synthesized in water by the precipitation reaction between AgNO3 and NaHCO3 in the presence of polyvinylpyrrolidone. The X-ray diffraction analysis revealed the co-existence of monoclinic and hexagonal phases of Ag2CO3, without presence of impurities. The band gap energy of Ag-2 CO3 was found to be 1.4 eV from the diffuse reflectance spectra. Photocatalytic ability of Ag2CO3 was tested using degradation reaction of the organic dye methylene blue over the wide range of concentrations, as well as under long run working conditions in repeated cycles. The photocatalytic mechanism was discussed in terms of the relative energetics of valence and conduction band. Antimicrobial efficiency of Ag-2 CO3 in dark was tested against Gram-negative bacteria E. coli. The Ag2CO3 dispersions in the concentration range 0.1-1.0 mg/mL ensured 100% reduction of bacteria cells. Time-dependent measurements revealed that reduction rates of bacteria cells vary in ascending order with the content of Ag2CO3. On the other hand, the observed reduction rates of bacteria cells do not depend on the concentration of coexisting free Ag+ ions (from 2 to 25 mg/L) present in Ag2CO3 dispersion.",
journal = "Chemistryselect",
title = "Antimicrobial and Photocatalytic Abilities of Ag2CO3 Nano-Rods",
volume = "2",
number = "10",
pages = "2931-2938",
doi = "10.1002/slct.201700003"
}
Lončarević, D., Vukoje, I. D., Dostanic, J., Bjelajac, A., Đorđević, V. R., Dimitrijević, S. I.,& Nedeljković, J.. (2017). Antimicrobial and Photocatalytic Abilities of Ag2CO3 Nano-Rods. in Chemistryselect, 2(10), 2931-2938.
https://doi.org/10.1002/slct.201700003
Lončarević D, Vukoje ID, Dostanic J, Bjelajac A, Đorđević VR, Dimitrijević SI, Nedeljković J. Antimicrobial and Photocatalytic Abilities of Ag2CO3 Nano-Rods. in Chemistryselect. 2017;2(10):2931-2938.
doi:10.1002/slct.201700003 .
Lončarević, Davor, Vukoje, Ivana D., Dostanic, Jasmina, Bjelajac, Anđelika, Đorđević, Vesna R., Dimitrijević, Suzana I., Nedeljković, Jovan, "Antimicrobial and Photocatalytic Abilities of Ag2CO3 Nano-Rods" in Chemistryselect, 2, no. 10 (2017):2931-2938,
https://doi.org/10.1002/slct.201700003 . .
8
7
8

Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations

Đorđević, Vesna R.; Brik, Mikhail G.; Srivastava, Alok M.; Medić, Mina M.; Vulic, Predrag; Glais, Estelle; Viana, Bruno; Dramićanin, Miroslav

(2017)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Brik, Mikhail G.
AU  - Srivastava, Alok M.
AU  - Medić, Mina M.
AU  - Vulic, Predrag
AU  - Glais, Estelle
AU  - Viana, Bruno
AU  - Dramićanin, Miroslav
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7197
AB  - Herein, the synthesis, structural and crystal field analysis and optical spectroscopy of Mn4+ doped metal titanates ATiO(3) (A = Ca, Mg) are presented. Materials of desired phase were prepared by molten salt assisted sol-gel method in the powder form. Crystallographic data of samples were obtained by refinement of X-ray diffraction measurements. From experimental excitation and emission spectra and structural data, crystal field parameters and energy levels of Mn4+ in CaTiO3 and MgTiO3 were calculated by the exchange charge model of crystal-field theory. It is found that crystalline field strength is lower (Dq = 1831 cm(-1)) in the rhombohedral Ilmenite MgTiO3 structure due to the relatively longer average Mn4+-O2- bond distance (2.059 angstrom), and higher (Dq = 2017 cm(-1)) in orthorhombic CaTiO3 which possess shorter average Mn4+-O2- bond distance (1.956 angstrom). Spectral positions of the Mn(4+2)Eg - GT (4)A(2g) transition maxima is 709 nm in MgTiO3 and 717 nm in CaTiO3 respectively in good agreement with calculated values. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations
VL  - 74
SP  - 46
EP  - 51
DO  - 10.1016/j.optmat.2017.03.021
ER  - 
@article{
author = "Đorđević, Vesna R. and Brik, Mikhail G. and Srivastava, Alok M. and Medić, Mina M. and Vulic, Predrag and Glais, Estelle and Viana, Bruno and Dramićanin, Miroslav",
year = "2017",
abstract = "Herein, the synthesis, structural and crystal field analysis and optical spectroscopy of Mn4+ doped metal titanates ATiO(3) (A = Ca, Mg) are presented. Materials of desired phase were prepared by molten salt assisted sol-gel method in the powder form. Crystallographic data of samples were obtained by refinement of X-ray diffraction measurements. From experimental excitation and emission spectra and structural data, crystal field parameters and energy levels of Mn4+ in CaTiO3 and MgTiO3 were calculated by the exchange charge model of crystal-field theory. It is found that crystalline field strength is lower (Dq = 1831 cm(-1)) in the rhombohedral Ilmenite MgTiO3 structure due to the relatively longer average Mn4+-O2- bond distance (2.059 angstrom), and higher (Dq = 2017 cm(-1)) in orthorhombic CaTiO3 which possess shorter average Mn4+-O2- bond distance (1.956 angstrom). Spectral positions of the Mn(4+2)Eg - GT (4)A(2g) transition maxima is 709 nm in MgTiO3 and 717 nm in CaTiO3 respectively in good agreement with calculated values. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations",
volume = "74",
pages = "46-51",
doi = "10.1016/j.optmat.2017.03.021"
}
Đorđević, V. R., Brik, M. G., Srivastava, A. M., Medić, M. M., Vulic, P., Glais, E., Viana, B.,& Dramićanin, M.. (2017). Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations. in Optical Materials, 74, 46-51.
https://doi.org/10.1016/j.optmat.2017.03.021
Đorđević VR, Brik MG, Srivastava AM, Medić MM, Vulic P, Glais E, Viana B, Dramićanin M. Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations. in Optical Materials. 2017;74:46-51.
doi:10.1016/j.optmat.2017.03.021 .
Đorđević, Vesna R., Brik, Mikhail G., Srivastava, Alok M., Medić, Mina M., Vulic, Predrag, Glais, Estelle, Viana, Bruno, Dramićanin, Miroslav, "Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations" in Optical Materials, 74 (2017):46-51,
https://doi.org/10.1016/j.optmat.2017.03.021 . .
23
22
24

Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties

Papan, Jelena; Jovanović, Dragana J.; Vuković, Katarina; Smits, Krisjanis; Đorđević, Vesna R.; Dramićanin, Miroslav

(2016)

TY  - JOUR
AU  - Papan, Jelena
AU  - Jovanović, Dragana J.
AU  - Vuković, Katarina
AU  - Smits, Krisjanis
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7132
AB  - The detailed analyses of structure and luminescence of europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles is presented. Samples were prepared by time and cost effective combustion method that utilize polyethylene glycol both as a chelating agent and as a fuel, with different europium(III) concentrations (from 1 to 12 at.%), annealed at temperatures ranging from 800 to 1400 degrees C, and with alternating A(3+) cation in the A(2)Hf(2)O(7) host. Then, structural variations between materials were analysed by Xray diffraction and structural refinement, while the changes in the luminescence were assessed from the Judd-Ofelt analyses of emission spectra. Nanoparticles prepared at the lowest temperature (800 degrees C) had the smallest particle size of similar to 6 nm and showed the highest quantum efficiency when doped with 1 and 2 at.% of europium(III). Radiative transition rate and quantum efficiency of emission showed Lu2Hf2O7 GT Gd2Hf2O7 GT Y2Hf2O7 trend. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties
VL  - 61
SP  - 68
EP  - 76
DO  - 10.1016/j.optmat.2016.04.007
ER  - 
@article{
author = "Papan, Jelena and Jovanović, Dragana J. and Vuković, Katarina and Smits, Krisjanis and Đorđević, Vesna R. and Dramićanin, Miroslav",
year = "2016",
abstract = "The detailed analyses of structure and luminescence of europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles is presented. Samples were prepared by time and cost effective combustion method that utilize polyethylene glycol both as a chelating agent and as a fuel, with different europium(III) concentrations (from 1 to 12 at.%), annealed at temperatures ranging from 800 to 1400 degrees C, and with alternating A(3+) cation in the A(2)Hf(2)O(7) host. Then, structural variations between materials were analysed by Xray diffraction and structural refinement, while the changes in the luminescence were assessed from the Judd-Ofelt analyses of emission spectra. Nanoparticles prepared at the lowest temperature (800 degrees C) had the smallest particle size of similar to 6 nm and showed the highest quantum efficiency when doped with 1 and 2 at.% of europium(III). Radiative transition rate and quantum efficiency of emission showed Lu2Hf2O7 GT Gd2Hf2O7 GT Y2Hf2O7 trend. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties",
volume = "61",
pages = "68-76",
doi = "10.1016/j.optmat.2016.04.007"
}
Papan, J., Jovanović, D. J., Vuković, K., Smits, K., Đorđević, V. R.,& Dramićanin, M.. (2016). Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties. in Optical Materials, 61, 68-76.
https://doi.org/10.1016/j.optmat.2016.04.007
Papan J, Jovanović DJ, Vuković K, Smits K, Đorđević VR, Dramićanin M. Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties. in Optical Materials. 2016;61:68-76.
doi:10.1016/j.optmat.2016.04.007 .
Papan, Jelena, Jovanović, Dragana J., Vuković, Katarina, Smits, Krisjanis, Đorđević, Vesna R., Dramićanin, Miroslav, "Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties" in Optical Materials, 61 (2016):68-76,
https://doi.org/10.1016/j.optmat.2016.04.007 . .
16
14
16

Photoluminescence of europium(III)-doped (YxSc1-x)(2)O-3 nanoparticles: Linear relationship between structural and emission properties

Antić, Željka; Đorđević, Vesna R.; Dramićanin, Miroslav; Thundat, Thomas

(Elsevier, 2016)

TY  - JOUR
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
AU  - Thundat, Thomas
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/914
AB  - Europium (III)-doped (YxSc1-x)(2)O-3 nanocrystalline powders of different compositions (x=0, 0.25, 0.5, 0.75 and 1) are synthesized using a polymer complex solution method. Comparative structural and optical characterization is carried out with powder X-ray diffraction and photoluminescence excitation, emission and emission decay measurements. Detailed information about unit cell parameter and energy levels of europium (III) ions are presented for all powder compositions. The second rank crystal field parameters (B-0(2)) and (B-2(2)) and crystal field strength (N-v) are calculated from the energies of Stark components of the F-7(1) manifold of the europium (III) emissions. It has been shown that the crystal field parameter changes with the powder composition and shows a linear relationship with the average ionic radii of cations in the solid solutions. A similar dependence is also found for the magnitude of splitting of F-7(1) manifold vs. unit cell parameter values. Moreover, this linear relationship is demonstrated for the whole family of europium (III)-doped mixed rare-earth sesquioxide hosts (RRO-3; R, R=rare earth ions) by taking into consideration results published in the literature so far. A simple, semi-empirical equation which relates structural properties (unit cell parameters, ionic radii) of the sesquioxide host material and the emission properties of europium (III) ions (energy splitting of the F-7(1) manifold, crystal field parameters and crystal field strength) are presented. Crown Copyright (C) 2015 Published by Elsevier Ltd and Techna Group S.r.l. All rights reserved.
PB  - Elsevier
T2  - Ceramics International
T1  - Photoluminescence of europium(III)-doped (YxSc1-x)(2)O-3 nanoparticles: Linear relationship between structural and emission properties
VL  - 42
IS  - 3
SP  - 3899
EP  - 3906
DO  - 10.1016/j.ceramint.2015.11.056
ER  - 
@article{
author = "Antić, Željka and Đorđević, Vesna R. and Dramićanin, Miroslav and Thundat, Thomas",
year = "2016",
abstract = "Europium (III)-doped (YxSc1-x)(2)O-3 nanocrystalline powders of different compositions (x=0, 0.25, 0.5, 0.75 and 1) are synthesized using a polymer complex solution method. Comparative structural and optical characterization is carried out with powder X-ray diffraction and photoluminescence excitation, emission and emission decay measurements. Detailed information about unit cell parameter and energy levels of europium (III) ions are presented for all powder compositions. The second rank crystal field parameters (B-0(2)) and (B-2(2)) and crystal field strength (N-v) are calculated from the energies of Stark components of the F-7(1) manifold of the europium (III) emissions. It has been shown that the crystal field parameter changes with the powder composition and shows a linear relationship with the average ionic radii of cations in the solid solutions. A similar dependence is also found for the magnitude of splitting of F-7(1) manifold vs. unit cell parameter values. Moreover, this linear relationship is demonstrated for the whole family of europium (III)-doped mixed rare-earth sesquioxide hosts (RRO-3; R, R=rare earth ions) by taking into consideration results published in the literature so far. A simple, semi-empirical equation which relates structural properties (unit cell parameters, ionic radii) of the sesquioxide host material and the emission properties of europium (III) ions (energy splitting of the F-7(1) manifold, crystal field parameters and crystal field strength) are presented. Crown Copyright (C) 2015 Published by Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Photoluminescence of europium(III)-doped (YxSc1-x)(2)O-3 nanoparticles: Linear relationship between structural and emission properties",
volume = "42",
number = "3",
pages = "3899-3906",
doi = "10.1016/j.ceramint.2015.11.056"
}
Antić, Ž., Đorđević, V. R., Dramićanin, M.,& Thundat, T.. (2016). Photoluminescence of europium(III)-doped (YxSc1-x)(2)O-3 nanoparticles: Linear relationship between structural and emission properties. in Ceramics International
Elsevier., 42(3), 3899-3906.
https://doi.org/10.1016/j.ceramint.2015.11.056
Antić Ž, Đorđević VR, Dramićanin M, Thundat T. Photoluminescence of europium(III)-doped (YxSc1-x)(2)O-3 nanoparticles: Linear relationship between structural and emission properties. in Ceramics International. 2016;42(3):3899-3906.
doi:10.1016/j.ceramint.2015.11.056 .
Antić, Željka, Đorđević, Vesna R., Dramićanin, Miroslav, Thundat, Thomas, "Photoluminescence of europium(III)-doped (YxSc1-x)(2)O-3 nanoparticles: Linear relationship between structural and emission properties" in Ceramics International, 42, no. 3 (2016):3899-3906,
https://doi.org/10.1016/j.ceramint.2015.11.056 . .
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Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles

Medić, Mina M.; Antić, Željka; Đorđević, Vesna R.; Ahrenkiel, Scott Phillip; Marinović-Cincović, Milena; Dramićanin, Miroslav

(Elsevier, 2016)

TY  - JOUR
AU  - Medić, Mina M.
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Ahrenkiel, Scott Phillip
AU  - Marinović-Cincović, Milena
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/879
AB  - This work explores the influence of annealing temperature on the structure and luminescence of 2 at% Eu3+ and 1 at Sm3+-doped Mg2TiO4 nanopowders produced via Pechini-type polymerized complex route. Mg2TiO4 samples were annealed at 7 different temperatures (400 degrees C, 450 degrees C, 500 degrees C, 550 degrees C, 600 degrees C, 650 degrees C and 700 degrees C) to determine the temperature range in which cubic inverse spinel structure is stable and to follow the changes of material luminescence properties. X-ray diffraction revealed that crystallization of both Eu3+ and Sm3+-doped Mg2TiO4 nanopowders starts at 400 degrees C, and that Sm3+ doped Mg2TiO4 starts to decompose at 650 degrees C, while Eu3+ doped Mg2TiO4 starts to decompose at 700 degrees C. Samples annealed at higher temperatures show higher crystallinity and larger crystallite size. Mg2TiO4 powder annealed at 600 degrees C is composed of similar to 5 nm size nanoparticles agglomerated in micron-size and dense chunks. The emission spectra of nanoparticles are composed of emissions from defects in Mg2TiO4 host and characteristic emissions of Eu3+ (D-5(0) - GT F-7(J)) and Sm3+ ((4)G(5/2) - GT H-6(J)) ions. The stronger emission and longer emission decays are observed with samples annealed at high temperatures. In the case of the Eu3+ ions emission intensity increased one order of magnitude between samples annealed at 400 degrees C and 650 degrees C. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Luminescence
T1  - Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles
VL  - 170
IS  - SI
SP  - 679
EP  - 685
DO  - 10.1016/j.jlumin.2015.06.007
ER  - 
@article{
author = "Medić, Mina M. and Antić, Željka and Đorđević, Vesna R. and Ahrenkiel, Scott Phillip and Marinović-Cincović, Milena and Dramićanin, Miroslav",
year = "2016",
abstract = "This work explores the influence of annealing temperature on the structure and luminescence of 2 at% Eu3+ and 1 at Sm3+-doped Mg2TiO4 nanopowders produced via Pechini-type polymerized complex route. Mg2TiO4 samples were annealed at 7 different temperatures (400 degrees C, 450 degrees C, 500 degrees C, 550 degrees C, 600 degrees C, 650 degrees C and 700 degrees C) to determine the temperature range in which cubic inverse spinel structure is stable and to follow the changes of material luminescence properties. X-ray diffraction revealed that crystallization of both Eu3+ and Sm3+-doped Mg2TiO4 nanopowders starts at 400 degrees C, and that Sm3+ doped Mg2TiO4 starts to decompose at 650 degrees C, while Eu3+ doped Mg2TiO4 starts to decompose at 700 degrees C. Samples annealed at higher temperatures show higher crystallinity and larger crystallite size. Mg2TiO4 powder annealed at 600 degrees C is composed of similar to 5 nm size nanoparticles agglomerated in micron-size and dense chunks. The emission spectra of nanoparticles are composed of emissions from defects in Mg2TiO4 host and characteristic emissions of Eu3+ (D-5(0) - GT F-7(J)) and Sm3+ ((4)G(5/2) - GT H-6(J)) ions. The stronger emission and longer emission decays are observed with samples annealed at high temperatures. In the case of the Eu3+ ions emission intensity increased one order of magnitude between samples annealed at 400 degrees C and 650 degrees C. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Luminescence",
title = "Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles",
volume = "170",
number = "SI",
pages = "679-685",
doi = "10.1016/j.jlumin.2015.06.007"
}
Medić, M. M., Antić, Ž., Đorđević, V. R., Ahrenkiel, S. P., Marinović-Cincović, M.,& Dramićanin, M.. (2016). Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles. in Journal of Luminescence
Elsevier., 170(SI), 679-685.
https://doi.org/10.1016/j.jlumin.2015.06.007
Medić MM, Antić Ž, Đorđević VR, Ahrenkiel SP, Marinović-Cincović M, Dramićanin M. Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles. in Journal of Luminescence. 2016;170(SI):679-685.
doi:10.1016/j.jlumin.2015.06.007 .
Medić, Mina M., Antić, Željka, Đorđević, Vesna R., Ahrenkiel, Scott Phillip, Marinović-Cincović, Milena, Dramićanin, Miroslav, "Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles" in Journal of Luminescence, 170, no. SI (2016):679-685,
https://doi.org/10.1016/j.jlumin.2015.06.007 . .
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Visible light absorption of surface modified TiO2 powders with bidentate benzene derivatives

Milićević, Bojana R.; Đorđević, Vesna R.; Lončarević, Davor; Ahrenkiel, Scott Phillip; Dramićanin, Miroslav; Nedeljković, Jovan

(2015)

TY  - JOUR
AU  - Milićević, Bojana R.
AU  - Đorđević, Vesna R.
AU  - Lončarević, Davor
AU  - Ahrenkiel, Scott Phillip
AU  - Dramićanin, Miroslav
AU  - Nedeljković, Jovan
PY  - 2015
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/719
AB  - TiO2 powders with different specific surface area were prepared using reproducible, sol gel synthetic route and their ability to form hybrids with catechol and 5-amino salicylic acid was compared with the commercially available Degussa P25 TiO2 powder. Microstructural characterization involving transmission electron microscopy, X-ray diffraction analysis and nitrogen adsorption-desorption isotherms indicated that TiO2 samples cover reasonably wide size and/or specific surface area range (50-115 m(2)/g). The surface modification of TiO2 powders with catechol and 5-amino salicylic acid induced significant shift of absorption to the visible spectral region due to charge transfer complex formation. It should be emphasized that tunable optical properties of TiO2 in powder form have never been reported in the literature. The largest red shift of the absorption onset was observed for sample with the largest specific surface area upon surface modification with both ligands. The binding of the modifier molecules to the surface Ti atoms was studied using Fourier transform infrared spectroscopy. (C) 2015 Elsevier Inc. All rights reserved.
T2  - Microporous and Mesoporous Materials
T1  - Visible light absorption of surface modified TiO2 powders with bidentate benzene derivatives
VL  - 217
SP  - 184
EP  - 189
DO  - 10.1016/j.micromeso.2015.06.028
ER  - 
@article{
author = "Milićević, Bojana R. and Đorđević, Vesna R. and Lončarević, Davor and Ahrenkiel, Scott Phillip and Dramićanin, Miroslav and Nedeljković, Jovan",
year = "2015",
abstract = "TiO2 powders with different specific surface area were prepared using reproducible, sol gel synthetic route and their ability to form hybrids with catechol and 5-amino salicylic acid was compared with the commercially available Degussa P25 TiO2 powder. Microstructural characterization involving transmission electron microscopy, X-ray diffraction analysis and nitrogen adsorption-desorption isotherms indicated that TiO2 samples cover reasonably wide size and/or specific surface area range (50-115 m(2)/g). The surface modification of TiO2 powders with catechol and 5-amino salicylic acid induced significant shift of absorption to the visible spectral region due to charge transfer complex formation. It should be emphasized that tunable optical properties of TiO2 in powder form have never been reported in the literature. The largest red shift of the absorption onset was observed for sample with the largest specific surface area upon surface modification with both ligands. The binding of the modifier molecules to the surface Ti atoms was studied using Fourier transform infrared spectroscopy. (C) 2015 Elsevier Inc. All rights reserved.",
journal = "Microporous and Mesoporous Materials",
title = "Visible light absorption of surface modified TiO2 powders with bidentate benzene derivatives",
volume = "217",
pages = "184-189",
doi = "10.1016/j.micromeso.2015.06.028"
}
Milićević, B. R., Đorđević, V. R., Lončarević, D., Ahrenkiel, S. P., Dramićanin, M.,& Nedeljković, J.. (2015). Visible light absorption of surface modified TiO2 powders with bidentate benzene derivatives. in Microporous and Mesoporous Materials, 217, 184-189.
https://doi.org/10.1016/j.micromeso.2015.06.028
Milićević BR, Đorđević VR, Lončarević D, Ahrenkiel SP, Dramićanin M, Nedeljković J. Visible light absorption of surface modified TiO2 powders with bidentate benzene derivatives. in Microporous and Mesoporous Materials. 2015;217:184-189.
doi:10.1016/j.micromeso.2015.06.028 .
Milićević, Bojana R., Đorđević, Vesna R., Lončarević, Davor, Ahrenkiel, Scott Phillip, Dramićanin, Miroslav, Nedeljković, Jovan, "Visible light absorption of surface modified TiO2 powders with bidentate benzene derivatives" in Microporous and Mesoporous Materials, 217 (2015):184-189,
https://doi.org/10.1016/j.micromeso.2015.06.028 . .
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