TY  - JOUR
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Novaković, Slađana B.
AU  - Leovac, Vukadin M.
AU  - Češljević, Valerija I.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5129
AB  - This is the first review dealing with the coordination chemistry of metal complexes with Girard reagents and their hydrazones. The short introduction indicates the chemical properties and significance of these organic compounds. The next section briefly describes synthetic methods for preparing complexes with Girard reagents, as well as the modes of coordination of these ligands. The last two extensive sections review the preparation, stereochemistry and structural characteristics of metal complexes with Girard hydrazones, including also some newer non-hydrazonic derivatives of Girard reagents.
T2  - Journal of the Serbian Chemical Society
T1  - Transition metal complexes with Girard reagents and their hydrazones
VL  - 77
IS  - 9
SP  - 1129
EP  - 1155
DO  - 10.2298/JSC120704083V
ER  - 

@article{
author = "Vojinović-Ješić, Ljiljana S. and Novaković, Slađana B. and Leovac, Vukadin M. and Češljević, Valerija I.",
year = "2012",
abstract = "This is the first review dealing with the coordination chemistry of metal complexes with Girard reagents and their hydrazones. The short introduction indicates the chemical properties and significance of these organic compounds. The next section briefly describes synthetic methods for preparing complexes with Girard reagents, as well as the modes of coordination of these ligands. The last two extensive sections review the preparation, stereochemistry and structural characteristics of metal complexes with Girard hydrazones, including also some newer non-hydrazonic derivatives of Girard reagents.",
journal = "Journal of the Serbian Chemical Society",
title = "Transition metal complexes with Girard reagents and their hydrazones",
volume = "77",
number = "9",
pages = "1129-1155",
doi = "10.2298/JSC120704083V"
}

Vojinović-Ješić, L. S., Novaković, S. B., Leovac, V. M.,& Češljević, V. I.. (2012). Transition metal complexes with Girard reagents and their hydrazones. in Journal of the Serbian Chemical Society, 77(9), 1129-1155.
https://doi.org/10.2298/JSC120704083V

Vojinović-Ješić LS, Novaković SB, Leovac VM, Češljević VI. Transition metal complexes with Girard reagents and their hydrazones. in Journal of the Serbian Chemical Society. 2012;77(9):1129-1155.
doi:10.2298/JSC120704083V .

Vojinović-Ješić, Ljiljana S., Novaković, Slađana B., Leovac, Vukadin M., Češljević, Valerija I., "Transition metal complexes with Girard reagents and their hydrazones" in Journal of the Serbian Chemical Society, 77, no. 9 (2012):1129-1155,
https://doi.org/10.2298/JSC120704083V . .

TY  - JOUR
AU  - Novaković, Slađana B.
AU  - Drašković, Bojana M.
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Češljević, Valerija I.
AU  - Leovac, Vukadin M.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3923
AB  - The asymmetric unit of the title compound, (C12H18N3O4)(2)[ZnCl4]center dot CH3OH, consists of two Girard reagent-based cations, a tetrachloridozincate anion and a molecule of methanol as solvate. These components are interconnected in the crystal structure by an extensive network of O-H center dot center dot center dot O, N-H center dot center dot center dot O, C-H center dot center dot center dot O, O-H center dot center dot center dot N, O-H center dot center dot center dot Cl, N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl hydrogen bonds. The shortest intermolecular interaction is realized between the cation and anion [H center dot center dot center dot Cl = 2.29 (5) angstrom; O-H center dot center dot center dot Cl = 167 (3)degrees]. C-H center dot center dot center dot O interactions also play a important role in the interconnection of the cations.
T2  - Acta Crystallographica. Section E: Structure Reports Online
T1  - Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4-trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
VL  - 66
SP  - M328
EP  - U3816
DO  - 10.1107/S160053681000615X
ER  - 

@article{
author = "Novaković, Slađana B. and Drašković, Bojana M. and Vojinović-Ješić, Ljiljana S. and Češljević, Valerija I. and Leovac, Vukadin M.",
year = "2010",
abstract = "The asymmetric unit of the title compound, (C12H18N3O4)(2)[ZnCl4]center dot CH3OH, consists of two Girard reagent-based cations, a tetrachloridozincate anion and a molecule of methanol as solvate. These components are interconnected in the crystal structure by an extensive network of O-H center dot center dot center dot O, N-H center dot center dot center dot O, C-H center dot center dot center dot O, O-H center dot center dot center dot N, O-H center dot center dot center dot Cl, N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl hydrogen bonds. The shortest intermolecular interaction is realized between the cation and anion [H center dot center dot center dot Cl = 2.29 (5) angstrom; O-H center dot center dot center dot Cl = 167 (3)degrees]. C-H center dot center dot center dot O interactions also play a important role in the interconnection of the cations.",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
title = "Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4-trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate",
volume = "66",
pages = "M328-U3816",
doi = "10.1107/S160053681000615X"
}

Novaković, S. B., Drašković, B. M., Vojinović-Ješić, L. S., Češljević, V. I.,& Leovac, V. M.. (2010). Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4-trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate. in Acta Crystallographica. Section E: Structure Reports Online, 66, M328-U3816.
https://doi.org/10.1107/S160053681000615X

Novaković SB, Drašković BM, Vojinović-Ješić LS, Češljević VI, Leovac VM. Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4-trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate. in Acta Crystallographica. Section E: Structure Reports Online. 2010;66:M328-U3816.
doi:10.1107/S160053681000615X .

Novaković, Slađana B., Drašković, Bojana M., Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Leovac, Vukadin M., "Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4-trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate" in Acta Crystallographica. Section E: Structure Reports Online, 66 (2010):M328-U3816,
https://doi.org/10.1107/S160053681000615X . .

TY  - JOUR
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Češljević, Valerija I.
AU  - Bogdanović, Goran A.
AU  - Leovac, Vukadin M.
AU  - Szecsenyi, Katalin Meszaros
AU  - Divjakovic, Vladimir
AU  - Joksović, Milan D.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4079
AB  - The article describes the synthesis and crystal structure of the Mn(II) complex with 2,6-diacetylpyridine bis (Girard-T hydrazone), (H(2)dap(GT)(2))(2+), of the formula [Mn(H(2)dap(GT)(2))(NCS)(2)](NCS)(2)center dot MeOH. The complex has a pentagonal-bipyramidal coordination geometry, with pentadentate N(3)O(2) ligand in the equatorial plane and two isothiocyanato groups in the axial positions. Both the ligand and the complex are characterized by their FT-IR spectra and thermal data. (C) 2010 Elsevier B.V. All rights reserved.
T2  - Inorganic Chemistry Communications
T1  - Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)
VL  - 13
IS  - 9
SP  - 1085
EP  - 1088
DO  - 10.1016/j.inoche.2010.06.022
ER  - 

@article{
author = "Vojinović-Ješić, Ljiljana S. and Češljević, Valerija I. and Bogdanović, Goran A. and Leovac, Vukadin M. and Szecsenyi, Katalin Meszaros and Divjakovic, Vladimir and Joksović, Milan D.",
year = "2010",
abstract = "The article describes the synthesis and crystal structure of the Mn(II) complex with 2,6-diacetylpyridine bis (Girard-T hydrazone), (H(2)dap(GT)(2))(2+), of the formula [Mn(H(2)dap(GT)(2))(NCS)(2)](NCS)(2)center dot MeOH. The complex has a pentagonal-bipyramidal coordination geometry, with pentadentate N(3)O(2) ligand in the equatorial plane and two isothiocyanato groups in the axial positions. Both the ligand and the complex are characterized by their FT-IR spectra and thermal data. (C) 2010 Elsevier B.V. All rights reserved.",
journal = "Inorganic Chemistry Communications",
title = "Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)",
volume = "13",
number = "9",
pages = "1085-1088",
doi = "10.1016/j.inoche.2010.06.022"
}

Vojinović-Ješić, L. S., Češljević, V. I., Bogdanović, G. A., Leovac, V. M., Szecsenyi, K. M., Divjakovic, V.,& Joksović, M. D.. (2010). Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone). in Inorganic Chemistry Communications, 13(9), 1085-1088.
https://doi.org/10.1016/j.inoche.2010.06.022

Vojinović-Ješić LS, Češljević VI, Bogdanović GA, Leovac VM, Szecsenyi KM, Divjakovic V, Joksović MD. Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone). in Inorganic Chemistry Communications. 2010;13(9):1085-1088.
doi:10.1016/j.inoche.2010.06.022 .

Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Bogdanović, Goran A., Leovac, Vukadin M., Szecsenyi, Katalin Meszaros, Divjakovic, Vladimir, Joksović, Milan D., "Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)" in Inorganic Chemistry Communications, 13, no. 9 (2010):1085-1088,
https://doi.org/10.1016/j.inoche.2010.06.022 . .

TY  - JOUR
AU  - Novaković, Slađana B.
AU  - Lalovic, Mirjana
AU  - Divjakovic, Vladimir
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Češljević, Valerija I.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4119
AB  - The reaction of aqueous solutions of aminoguanidine hydrogennitrate and acetylacetone produces the title pyrazole salt, C(7)H(18)N(8) 2+center dot 2NO(3) -. The crystal structure is stabilized by a complex N-H...O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N-O bond lengths.
T2  - Acta Crystallographica. Section E: Structure Reports Online
T1  - Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate
VL  - 66
SP  - O1916
EP  - U332
DO  - 10.1107/S1600536810025006
ER  - 

@article{
author = "Novaković, Slađana B. and Lalovic, Mirjana and Divjakovic, Vladimir and Vojinović-Ješić, Ljiljana S. and Češljević, Valerija I.",
year = "2010",
abstract = "The reaction of aqueous solutions of aminoguanidine hydrogennitrate and acetylacetone produces the title pyrazole salt, C(7)H(18)N(8) 2+center dot 2NO(3) -. The crystal structure is stabilized by a complex N-H...O hydrogen-bonding network. The difference in the engagement of the two nitrate anions in hydrogen bonding is reflected in the variation of the corresponding N-O bond lengths.",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
title = "Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate",
volume = "66",
pages = "O1916-U332",
doi = "10.1107/S1600536810025006"
}

Novaković, S. B., Lalovic, M., Divjakovic, V., Vojinović-Ješić, L. S.,& Češljević, V. I.. (2010). Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate. in Acta Crystallographica. Section E: Structure Reports Online, 66, O1916-U332.
https://doi.org/10.1107/S1600536810025006

Novaković SB, Lalovic M, Divjakovic V, Vojinović-Ješić LS, Češljević VI. Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate. in Acta Crystallographica. Section E: Structure Reports Online. 2010;66:O1916-U332.
doi:10.1107/S1600536810025006 .

Novaković, Slađana B., Lalovic, Mirjana, Divjakovic, Vladimir, Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., "Amino(5-{2-[amino(iminio)methyl]hydrazin-1-yl}-3,5-dimethyl-4,5-dihydro-1H-pyrazol-1-yl)methaniminium dinitrate" in Acta Crystallographica. Section E: Structure Reports Online, 66 (2010):O1916-U332,
https://doi.org/10.1107/S1600536810025006 . .

TY  - JOUR
AU  - Leovac, Vukadin M.
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Češljević, Valerija I.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3780
AB  - The title compound, [Cu(C9H13N5O2)(CH4O)](NO3)(2), consists of square-planar cationic complex units where the Cu-II centre is coordinated by an N, N, O-tridentate pyridoxal aminoguanidine Schiff base adduct and a methanol molecule. The tridentate ligand is a zwitterion exhibiting an almost planar conformation. The dihedral angles between the mean planes of the pyridoxal ring and the six-and five-membered chelate rings are all less than 2.0 degrees. The charge on the complex cation is neutralized by two nitrate counter-ions. Extensive N -H center dot center dot center dot O and C -H center dot center dot center dot O hydrogen bonding connects these ionic species and leads to the formation of layers. The pyridoxal hydroxy groups are the only fragments that deviate significantly from the flat layer structure; these groups are involved in O-H center dot center dot center dot O hydrogen bonding, connecting the layers into a three-dimensional crystal structure.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - {4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate
VL  - 65
SP  - M337
EP  - M339
DO  - 10.1107/S0108270109029023
ER  - 

@article{
author = "Leovac, Vukadin M. and Vojinović-Ješić, Ljiljana S. and Češljević, Valerija I. and Novaković, Slađana B. and Bogdanović, Goran A.",
year = "2009",
abstract = "The title compound, [Cu(C9H13N5O2)(CH4O)](NO3)(2), consists of square-planar cationic complex units where the Cu-II centre is coordinated by an N, N, O-tridentate pyridoxal aminoguanidine Schiff base adduct and a methanol molecule. The tridentate ligand is a zwitterion exhibiting an almost planar conformation. The dihedral angles between the mean planes of the pyridoxal ring and the six-and five-membered chelate rings are all less than 2.0 degrees. The charge on the complex cation is neutralized by two nitrate counter-ions. Extensive N -H center dot center dot center dot O and C -H center dot center dot center dot O hydrogen bonding connects these ionic species and leads to the formation of layers. The pyridoxal hydroxy groups are the only fragments that deviate significantly from the flat layer structure; these groups are involved in O-H center dot center dot center dot O hydrogen bonding, connecting the layers into a three-dimensional crystal structure.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "{4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate",
volume = "65",
pages = "M337-M339",
doi = "10.1107/S0108270109029023"
}

Leovac, V. M., Vojinović-Ješić, L. S., Češljević, V. I., Novaković, S. B.,& Bogdanović, G. A.. (2009). {4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate. in Acta Crystallographica. Section C: Crystal Structure Communications, 65, M337-M339.
https://doi.org/10.1107/S0108270109029023

Leovac VM, Vojinović-Ješić LS, Češljević VI, Novaković SB, Bogdanović GA. {4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate. in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65:M337-M339.
doi:10.1107/S0108270109029023 .

Leovac, Vukadin M., Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Novaković, Slađana B., Bogdanović, Goran A., "{4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009):M337-M339,
https://doi.org/10.1107/S0108270109029023 . .

TY  - JOUR
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Bogdanović, Goran A.
AU  - Leovac, Vukadin M.
AU  - Češljević, Valerija I.
AU  - Jovanović, Ljiljana S.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3539
AB  - The monoligand complexes of the formula M(HPLGT)(NCS)(2) (M = Cu(II), Zn(II)) in which the ligand tridentate ONO pyridoxilidene Girard-T hydrazone, [H(3)PLGT]Cl(2) center dot 2H(2)O, was coordinated in neutral doubly deprotonated form were synthesized. Also, the first complexes with the ligand coordinated in triply deprotonated monoanionic form of the formula [Cu(PLGT)N(3)] and [Co(PLGT)(NO(2))(2)NH(3)] center dot 3H(2)O are reported. The single crystal X-ray analysis of [Cu(HPLGT)(NCS)(2)] showed that Cu(II) is placed in a square-pyramidal surrounding consisting of one tridentate Schiff base and one NCS group in the basal plane and the other NCS group in the apical position. Intermolecular hydrogen bonds leading to centrosymmetrical dimerization of these complexes were discussed. In the reaction of Girard-T and Hacac in the presence of CuCl(2), a mixture of single crystal complexes of the composition [Cu(3,5-Me(2)pz)(2)Cl(2)](2) and [Cu(acac)(2)] center dot 2[Cu(3,5-Me(2)pz)(2)Cl(2)] was obtained and X-ray analysis of the latter one was reported.
T2  - Structural Chemistry
T1  - Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex
VL  - 19
IS  - 5
SP  - 807
EP  - 815
DO  - 10.1007/s11224-008-9368-x
ER  - 

@article{
author = "Vojinović-Ješić, Ljiljana S. and Bogdanović, Goran A. and Leovac, Vukadin M. and Češljević, Valerija I. and Jovanović, Ljiljana S.",
year = "2008",
abstract = "The monoligand complexes of the formula M(HPLGT)(NCS)(2) (M = Cu(II), Zn(II)) in which the ligand tridentate ONO pyridoxilidene Girard-T hydrazone, [H(3)PLGT]Cl(2) center dot 2H(2)O, was coordinated in neutral doubly deprotonated form were synthesized. Also, the first complexes with the ligand coordinated in triply deprotonated monoanionic form of the formula [Cu(PLGT)N(3)] and [Co(PLGT)(NO(2))(2)NH(3)] center dot 3H(2)O are reported. The single crystal X-ray analysis of [Cu(HPLGT)(NCS)(2)] showed that Cu(II) is placed in a square-pyramidal surrounding consisting of one tridentate Schiff base and one NCS group in the basal plane and the other NCS group in the apical position. Intermolecular hydrogen bonds leading to centrosymmetrical dimerization of these complexes were discussed. In the reaction of Girard-T and Hacac in the presence of CuCl(2), a mixture of single crystal complexes of the composition [Cu(3,5-Me(2)pz)(2)Cl(2)](2) and [Cu(acac)(2)] center dot 2[Cu(3,5-Me(2)pz)(2)Cl(2)] was obtained and X-ray analysis of the latter one was reported.",
journal = "Structural Chemistry",
title = "Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex",
volume = "19",
number = "5",
pages = "807-815",
doi = "10.1007/s11224-008-9368-x"
}

Vojinović-Ješić, L. S., Bogdanović, G. A., Leovac, V. M., Češljević, V. I.,& Jovanović, L. S.. (2008). Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex. in Structural Chemistry, 19(5), 807-815.
https://doi.org/10.1007/s11224-008-9368-x

Vojinović-Ješić LS, Bogdanović GA, Leovac VM, Češljević VI, Jovanović LS. Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex. in Structural Chemistry. 2008;19(5):807-815.
doi:10.1007/s11224-008-9368-x .

Vojinović-Ješić, Ljiljana S., Bogdanović, Goran A., Leovac, Vukadin M., Češljević, Valerija I., Jovanović, Ljiljana S., "Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex" in Structural Chemistry, 19, no. 5 (2008):807-815,
https://doi.org/10.1007/s11224-008-9368-x . .

TY  - JOUR
AU  - Leovac, Vukadin M.
AU  - Bogdanović, Goran A.
AU  - Češljević, Valerija I.
AU  - Jovanović, Ljiljana S.
AU  - Novaković, Slađana B.
AU  - Vojinović-Ješić, Ljiljana S.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3154
AB  - The ligand, salicylaldehyde Girard-T hydrazonium chloride, [H(2)SalGT]Cl (1), and two complexes [Cu(HSalGT)X-2]center dot H2O (X = Br(2); Cl(3)) were synthesized and their crystal structures were determined by single-crystal X-ray analysis. In the two isostructural complexes, the Cu(II) is located in a square-pyramidal environment, with the chelating ligand and one halogen atom in the basal plane and the second halogen in the apical position. The most apparent structural difference between the 1 and its complexes 2 and 3 is the orientation of the N(CH3)(3) group: in 1, it is practically coplanar to the rest of the molecule, while in 2 and 3 it is oriented to the side of the axially bonded halogen, which can be explained by the C-H center dot center dot center dot X intramolecular interactions. The compounds were characterized by elemental analysis, molar conductivity, magnetic susceptibility and electronic absorption spectra.
PB  - Springer
T2  - Structural Chemistry
T1  - Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes
VL  - 18
IS  - 1
SP  - 113
EP  - 119
DO  - 10.1007/s11224-006-9136-8
ER  - 

@article{
author = "Leovac, Vukadin M. and Bogdanović, Goran A. and Češljević, Valerija I. and Jovanović, Ljiljana S. and Novaković, Slađana B. and Vojinović-Ješić, Ljiljana S.",
year = "2007",
abstract = "The ligand, salicylaldehyde Girard-T hydrazonium chloride, [H(2)SalGT]Cl (1), and two complexes [Cu(HSalGT)X-2]center dot H2O (X = Br(2); Cl(3)) were synthesized and their crystal structures were determined by single-crystal X-ray analysis. In the two isostructural complexes, the Cu(II) is located in a square-pyramidal environment, with the chelating ligand and one halogen atom in the basal plane and the second halogen in the apical position. The most apparent structural difference between the 1 and its complexes 2 and 3 is the orientation of the N(CH3)(3) group: in 1, it is practically coplanar to the rest of the molecule, while in 2 and 3 it is oriented to the side of the axially bonded halogen, which can be explained by the C-H center dot center dot center dot X intramolecular interactions. The compounds were characterized by elemental analysis, molar conductivity, magnetic susceptibility and electronic absorption spectra.",
publisher = "Springer",
journal = "Structural Chemistry",
title = "Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes",
volume = "18",
number = "1",
pages = "113-119",
doi = "10.1007/s11224-006-9136-8"
}

Leovac, V. M., Bogdanović, G. A., Češljević, V. I., Jovanović, L. S., Novaković, S. B.,& Vojinović-Ješić, L. S.. (2007). Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes. in Structural Chemistry
Springer., 18(1), 113-119.
https://doi.org/10.1007/s11224-006-9136-8

Leovac VM, Bogdanović GA, Češljević VI, Jovanović LS, Novaković SB, Vojinović-Ješić LS. Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes. in Structural Chemistry. 2007;18(1):113-119.
doi:10.1007/s11224-006-9136-8 .

Leovac, Vukadin M., Bogdanović, Goran A., Češljević, Valerija I., Jovanović, Ljiljana S., Novaković, Slađana B., Vojinović-Ješić, Ljiljana S., "Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes" in Structural Chemistry, 18, no. 1 (2007):113-119,
https://doi.org/10.1007/s11224-006-9136-8 . .

TY  - JOUR
AU  - Leovac, Vukadin M.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Joksović, Milan D.
AU  - Szecsenyi, Katalin Meszaros
AU  - Češljević, Valerija I.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3284
AB  - Synthesis of a new nickel(II) complex, [Ni(Ph(2)PzTSC-H)(2)] with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone (Ph(2)PzTSC), is described. The compounds have been characterized by elemental and thermal analysis, molar conductivity and spectral (UV-Vis, IR, H-1 NMR, and C-13 NMR) measurements. In the case of complex the magnetic measurement has been also performed. Crystal and molecular structures of both the free ligand and the complex have been determined by single crystal X-ray analysis. It was found that the ligand coordinates in a bidentate NS fashion, in its deprotonated thioenolato form. The cis-square-planar geometry of the complex is significantly distorted tetrahedrally. The Cambridge Structural Database (CSD) study has been performed to obtain geometrical and structural informations on similar nickel(II) complexes in order to compare structural data. (c) 2007 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry
VL  - 26
IS  - 14
SP  - 3783
EP  - 3792
DO  - 10.1016/j.poly.2007.04.012
ER  - 

@article{
author = "Leovac, Vukadin M. and Novaković, Slađana B. and Bogdanović, Goran A. and Joksović, Milan D. and Szecsenyi, Katalin Meszaros and Češljević, Valerija I.",
year = "2007",
abstract = "Synthesis of a new nickel(II) complex, [Ni(Ph(2)PzTSC-H)(2)] with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone (Ph(2)PzTSC), is described. The compounds have been characterized by elemental and thermal analysis, molar conductivity and spectral (UV-Vis, IR, H-1 NMR, and C-13 NMR) measurements. In the case of complex the magnetic measurement has been also performed. Crystal and molecular structures of both the free ligand and the complex have been determined by single crystal X-ray analysis. It was found that the ligand coordinates in a bidentate NS fashion, in its deprotonated thioenolato form. The cis-square-planar geometry of the complex is significantly distorted tetrahedrally. The Cambridge Structural Database (CSD) study has been performed to obtain geometrical and structural informations on similar nickel(II) complexes in order to compare structural data. (c) 2007 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry",
volume = "26",
number = "14",
pages = "3783-3792",
doi = "10.1016/j.poly.2007.04.012"
}

Leovac, V. M., Novaković, S. B., Bogdanović, G. A., Joksović, M. D., Szecsenyi, K. M.,& Češljević, V. I.. (2007). Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry. in Polyhedron, 26(14), 3783-3792.
https://doi.org/10.1016/j.poly.2007.04.012

Leovac VM, Novaković SB, Bogdanović GA, Joksović MD, Szecsenyi KM, Češljević VI. Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry. in Polyhedron. 2007;26(14):3783-3792.
doi:10.1016/j.poly.2007.04.012 .

Leovac, Vukadin M., Novaković, Slađana B., Bogdanović, Goran A., Joksović, Milan D., Szecsenyi, Katalin Meszaros, Češljević, Valerija I., "Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry" in Polyhedron, 26, no. 14 (2007):3783-3792,
https://doi.org/10.1016/j.poly.2007.04.012 . .