Novaković, Slađana B.

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Authority KeyName Variants
orcid::0000-0002-8737-5870
  • Novaković, Slađana B. (76)
Projects
Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology Design, synthesis, characterization and assessment of practical applications of coordination and organometallic compounds
Novel Electrochemical and Chemical Methods in Synthesis of Organic Compounds of Interest for Medicine and Material Chemistry Synthesis, modeling, physicochemical and biological properties of organic compounds and related metal complexes
Mechanistic studies of the reactions of transition metal ion complexes with biologically relevant molecules Characterization and application of fungal metabolites and assessment of new biofungicides potential
Ministry of Science of the Republic of Montenegro Modeling and Numerical Simulations of Complex Many-Body Systems
The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200122 (University of Kragujevac, Faculty of Science)
Ministry of Science and Technological Development of the Republic of Serbia [142028] Ministry of Science and Technological Development of the Republic of Serbia [142028], Provincial Secretariat for Science and Technological Development of Vojvodina
China Scholarship Council (CSC), National Natural Science Foundation of China (NSFC) [21271068], Natural Science Foundation of Hubei Province [2015CFA131], Wuhan Applied Basic Research Program [2014010101010020] Deutsche Forschungsgemeinschaft (DFG) [Ja466/30-1], DFG [Ja466/25-1], University of Dusseldorf
Faculty of Medical Sciences [MP 2014/01] Gaussian program [ON1720035]
Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids
Combinatorial libraries of heterogeneous catalysts, natural products, and their derivatives and analogues: the way to biologically active compounds Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200378 (Institute of Information Technology)
Preclinical investigation of bioactive substances Simultaneous Bioremediation and Soilification of Degraded Areas to Preserve Natural Resources of Biologically Active Substances, and Development and Production of Biomaterials and Dietetic Products
Ministry of Education, Science and Technological Development of the Republic of Serbia Ministry of Education, Science, Research and Sport of the Slovak Republic [VEGA 1/0598/14]
Ministry of Science and Technological Development of the Republic of Serbia [142042, 142010] Ministry of Science of the Republic of Montenegro for financial support [Innovative Project-Bioextra]
Ministry of Science of the Republic of Montenegro [Innovative Project-Bioextra] Ministry of Science of the Republic of Montenegro/Natonal project
Ministry of Science of the Republic of Serbia [142010] Provincial Secretariat for Science and Technological Development of Vojvodina

Author's Bibliography

Green synthesis of benzamide-dioxoisoindoline derivatives and assessment of their radical scavenging activity – Experimental and theoretical approach

Milovanović, Vesna M; Petrović, Zorica D.; Novaković, Slađana B.; Bogdanović, Goran A.; Petrović, Vladimir P.; Simijonović, Dušica

(2020)

TY  - JOUR
AU  - Milovanović, Vesna M
AU  - Petrović, Zorica D.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Petrović, Vladimir P.
AU  - Simijonović, Dušica
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9123
AB  - A series of benzamide-dioxoisoindoline derivatives 3 was obtained, starting from phthalic anhydride and different benzoyl hydrazides 2, by ultrasound irradiation in water as solvent and without any catalyst. Five obtained compounds have been reported in this study for the first time and crystal structure of compound 3h was determined. All compounds were subjected to experimental determination of their antioxidative potential. DPPH test revealed that newly synthesized phenolic compounds 3d, 3e, and 3j are the best antioxidants. Additionally, probable radical scavenging pathway was analysed for reactions of the most active compounds and some radicals that can be found in living cells.
T2  - Tetrahedron
T1  - Green synthesis of benzamide-dioxoisoindoline derivatives and assessment of their radical scavenging activity – Experimental and theoretical approach
VL  - 76
IS  - 38
SP  - 131456
DO  - 10.1016/j.tet.2020.131456
ER  - 
@article{
author = "Milovanović, Vesna M and Petrović, Zorica D. and Novaković, Slađana B. and Bogdanović, Goran A. and Petrović, Vladimir P. and Simijonović, Dušica",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9123",
abstract = "A series of benzamide-dioxoisoindoline derivatives 3 was obtained, starting from phthalic anhydride and different benzoyl hydrazides 2, by ultrasound irradiation in water as solvent and without any catalyst. Five obtained compounds have been reported in this study for the first time and crystal structure of compound 3h was determined. All compounds were subjected to experimental determination of their antioxidative potential. DPPH test revealed that newly synthesized phenolic compounds 3d, 3e, and 3j are the best antioxidants. Additionally, probable radical scavenging pathway was analysed for reactions of the most active compounds and some radicals that can be found in living cells.",
journal = "Tetrahedron",
title = "Green synthesis of benzamide-dioxoisoindoline derivatives and assessment of their radical scavenging activity – Experimental and theoretical approach",
volume = "76",
number = "38",
pages = "131456",
doi = "10.1016/j.tet.2020.131456"
}
Milovanović, V. M., Petrović, Z. D., Novaković, S. B., Bogdanović, G. A., Petrović, V. P.,& Simijonović, D. (2020). Green synthesis of benzamide-dioxoisoindoline derivatives and assessment of their radical scavenging activity – Experimental and theoretical approach.
Tetrahedron, 76(38), 131456.
https://doi.org/10.1016/j.tet.2020.131456
Milovanović VM, Petrović ZD, Novaković SB, Bogdanović GA, Petrović VP, Simijonović D. Green synthesis of benzamide-dioxoisoindoline derivatives and assessment of their radical scavenging activity – Experimental and theoretical approach. Tetrahedron. 2020;76(38):131456
Milovanović Vesna M, Petrović Zorica D., Novaković Slađana B., Bogdanović Goran A., Petrović Vladimir P., Simijonović Dušica, "Green synthesis of benzamide-dioxoisoindoline derivatives and assessment of their radical scavenging activity – Experimental and theoretical approach" Tetrahedron, 76, no. 38 (2020):131456,
https://doi.org/10.1016/j.tet.2020.131456 .

Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones

Minić, Aleksandra; Pešić, Marko S; Novaković, Slađana B.; Bogdanović, Goran A.; Todosijević, Anka; Ilić-Komatina, Danijela; Stevanović, Dragana

(2020)

TY  - JOUR
AU  - Minić, Aleksandra
AU  - Pešić, Marko S
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Todosijević, Anka
AU  - Ilić-Komatina, Danijela
AU  - Stevanović, Dragana
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9119
AB  - Herein, we report an easy performable method for the synthesis of ferrocene-containing tetrahydropyrimidin-2(1H)-ones starting from the corresponding 3-arylamino-1-ferrocenylpropan-1-ols and sodium cyanate (NaOCN) in the presence of glacial acetic acid. The protocol is included an intramolecular cyclization of an in situ generated 1,3-hydroxyurea. The scope of the reaction towards eleven ferrocene-containing 1,3-amino alcohols has been explored and the targeted 1-aryl-4-ferrocenyltetrahidropyrimidin-2(1H)-ones were obtained in good to high yields (up to 93%). All products have been isolated in high purity >95%. In addition, we have provided a detailed structural characterization of the new compounds, which has been performed by IR and NMR spectroscopy. The single-crystal X-ray diffraction analysis was successfully performed on three representative examples, as well as elemental analysis. Moreover, molecular structure properties and intermolecular interactions of these three structures have been compared and analyzed in detail. Electrochemical properties of products were investigated by cyclic voltammetry. This investigation revealed the quasi-reversible one-electron redox process.
T2  - Journal of Organometallic Chemistry
T1  - Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones
VL  - 923
SP  - 121422
DO  - 10.1016/j.jorganchem.2020.121422
ER  - 
@article{
author = "Minić, Aleksandra and Pešić, Marko S and Novaković, Slađana B. and Bogdanović, Goran A. and Todosijević, Anka and Ilić-Komatina, Danijela and Stevanović, Dragana",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9119",
abstract = "Herein, we report an easy performable method for the synthesis of ferrocene-containing tetrahydropyrimidin-2(1H)-ones starting from the corresponding 3-arylamino-1-ferrocenylpropan-1-ols and sodium cyanate (NaOCN) in the presence of glacial acetic acid. The protocol is included an intramolecular cyclization of an in situ generated 1,3-hydroxyurea. The scope of the reaction towards eleven ferrocene-containing 1,3-amino alcohols has been explored and the targeted 1-aryl-4-ferrocenyltetrahidropyrimidin-2(1H)-ones were obtained in good to high yields (up to 93%). All products have been isolated in high purity >95%. In addition, we have provided a detailed structural characterization of the new compounds, which has been performed by IR and NMR spectroscopy. The single-crystal X-ray diffraction analysis was successfully performed on three representative examples, as well as elemental analysis. Moreover, molecular structure properties and intermolecular interactions of these three structures have been compared and analyzed in detail. Electrochemical properties of products were investigated by cyclic voltammetry. This investigation revealed the quasi-reversible one-electron redox process.",
journal = "Journal of Organometallic Chemistry",
title = "Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones",
volume = "923",
pages = "121422",
doi = "10.1016/j.jorganchem.2020.121422"
}
Minić, A., Pešić, M. S., Novaković, S. B., Bogdanović, G. A., Todosijević, A., Ilić-Komatina, D.,& Stevanović, D. (2020). Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones.
Journal of Organometallic Chemistry, 923, 121422.
https://doi.org/10.1016/j.jorganchem.2020.121422
Minić A, Pešić MS, Novaković SB, Bogdanović GA, Todosijević A, Ilić-Komatina D, Stevanović D. Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones. Journal of Organometallic Chemistry. 2020;923:121422
Minić Aleksandra, Pešić Marko S, Novaković Slađana B., Bogdanović Goran A., Todosijević Anka, Ilić-Komatina Danijela, Stevanović Dragana, "Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones" Journal of Organometallic Chemistry, 923 (2020):121422,
https://doi.org/10.1016/j.jorganchem.2020.121422 .

Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2

Jaćimović, Željko. K; Novaković, Slađana B.; Bogdanović, Goran A.; Kosović, Milica; Libowitzky, Eugen; Giester, Gerald

(2020)

TY  - JOUR
AU  - Jaćimović, Željko. K
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Kosović, Milica
AU  - Libowitzky, Eugen
AU  - Giester, Gerald
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9065
AB  - C7H7F3N2O2, monoclinic, P21/m (no. 11), a = 6.8088(8) Å, b = 6.7699(9) Å, c = 9.9351(12) Å, β = 105.416(3)°, V = 441.48(9) Å 3 , Z = 2, R gt ( F ) = 0.0398, wR ref ( F 2 ) = 0.1192, T = 200(2) K.
T2  - Zeitschrift für Kristallographie - New Crystal Structures
T1  - Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2
VL  - 235
IS  - 5
SP  - 1189
EP  - 1190
DO  - 10.1515/ncrs-2020-0242
ER  - 
@article{
author = "Jaćimović, Željko. K and Novaković, Slađana B. and Bogdanović, Goran A. and Kosović, Milica and Libowitzky, Eugen and Giester, Gerald",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9065",
abstract = "C7H7F3N2O2, monoclinic, P21/m (no. 11), a = 6.8088(8) Å, b = 6.7699(9) Å, c = 9.9351(12) Å, β = 105.416(3)°, V = 441.48(9) Å 3 , Z = 2, R gt ( F ) = 0.0398, wR ref ( F 2 ) = 0.1192, T = 200(2) K.",
journal = "Zeitschrift für Kristallographie - New Crystal Structures",
title = "Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2",
volume = "235",
number = "5",
pages = "1189-1190",
doi = "10.1515/ncrs-2020-0242"
}
Jaćimović, Željko. K., Novaković, S. B., Bogdanović, G. A., Kosović, M., Libowitzky, E.,& Giester, G. (2020). Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2.
Zeitschrift für Kristallographie - New Crystal Structures, 235(5), 1189-1190.
https://doi.org/10.1515/ncrs-2020-0242
Jaćimović ŽK, Novaković SB, Bogdanović GA, Kosović M, Libowitzky E, Giester G. Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2. Zeitschrift für Kristallographie - New Crystal Structures. 2020;235(5):1189-1190
Jaćimović Željko. K, Novaković Slađana B., Bogdanović Goran A., Kosović Milica, Libowitzky Eugen, Giester Gerald, "Crystal structure of ethyl 3-(trifluoromethyl)-1H-pyrazole-4-carboxylate, C7H7F3N2O2" Zeitschrift für Kristallographie - New Crystal Structures, 235, no. 5 (2020):1189-1190,
https://doi.org/10.1515/ncrs-2020-0242 .

Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines

Dimitrijević, Teodora; Novaković, Irena T.; Radanović, Dušanka D.; Novaković, Slađana B.; Rodić, Marko V.; Anđelković, Katarina; Šumar-Ristović, Maja

(2020)

TY  - JOUR
AU  - Dimitrijević, Teodora
AU  - Novaković, Irena T.
AU  - Radanović, Dušanka D.
AU  - Novaković, Slađana B.
AU  - Rodić, Marko V.
AU  - Anđelković, Katarina
AU  - Šumar-Ristović, Maja
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8908
AB  - In this article, synthesis, spectral and X-ray structure characterization, antimicrobial activity and Brine shrimp test of two new Cu(II) complexes with a salicylaldehyde derivative have been reported. Complexes [Cu(L)(bipy)]BF4·0.5H2O and [Cu2(L)2(phen)2](BF4)2 were obtained in the reaction of Cu(BF4)2·6H2O, deprotonated 4-(diethylamino)−2-hydroxybenzaldehyde ligand (L) and α-diimine (2,2’-bipyridine or 1,10-phenanthroline). The complex with bipyridine is mononuclear, containing one L and one bipyridine ligand in a distorted square-planar cation with a BF4 − anion and lattice water molecule, whereas the complex with phenanthroline is a dinuclear centrosymmetric dimeric cation, containing two L ligands along with two phenanthroline ligands and BF4 − anions. The coordination geometry of each Cu(II) ion can be described as an elongated square pyramid. MS-ESI spectroscopy indicated that [Cu2(L)2(phen)2](BF4)2 is mononuclear in DMSO solution. In vitro antibacterial and antifungal activity was tested against four Gram-positive, four Gram-negative bacteria and three fungal strains. Complexes showed significantly stronger antibacterial activities than parent ligands. The mononuclear phenanthroline complex in solution showed very good antimicrobial activity, which is comparable to the activity of the standard antibiotic amikacin against all tested bacterial strains. The same complex has better antifungal activity than fluconazole, which was used as a standard. Results of the brine shrimp test indicate that both complexes have good toxicity against Artemia nauplii.
T2  - Journal of Coordination Chemistry
T1  - Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines
VL  - 73
IS  - 4
SP  - 702
EP  - 716
DO  - 10.1080/00958972.2020.1740212
ER  - 
@article{
author = "Dimitrijević, Teodora and Novaković, Irena T. and Radanović, Dušanka D. and Novaković, Slađana B. and Rodić, Marko V. and Anđelković, Katarina and Šumar-Ristović, Maja",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8908",
abstract = "In this article, synthesis, spectral and X-ray structure characterization, antimicrobial activity and Brine shrimp test of two new Cu(II) complexes with a salicylaldehyde derivative have been reported. Complexes [Cu(L)(bipy)]BF4·0.5H2O and [Cu2(L)2(phen)2](BF4)2 were obtained in the reaction of Cu(BF4)2·6H2O, deprotonated 4-(diethylamino)−2-hydroxybenzaldehyde ligand (L) and α-diimine (2,2’-bipyridine or 1,10-phenanthroline). The complex with bipyridine is mononuclear, containing one L and one bipyridine ligand in a distorted square-planar cation with a BF4 − anion and lattice water molecule, whereas the complex with phenanthroline is a dinuclear centrosymmetric dimeric cation, containing two L ligands along with two phenanthroline ligands and BF4 − anions. The coordination geometry of each Cu(II) ion can be described as an elongated square pyramid. MS-ESI spectroscopy indicated that [Cu2(L)2(phen)2](BF4)2 is mononuclear in DMSO solution. In vitro antibacterial and antifungal activity was tested against four Gram-positive, four Gram-negative bacteria and three fungal strains. Complexes showed significantly stronger antibacterial activities than parent ligands. The mononuclear phenanthroline complex in solution showed very good antimicrobial activity, which is comparable to the activity of the standard antibiotic amikacin against all tested bacterial strains. The same complex has better antifungal activity than fluconazole, which was used as a standard. Results of the brine shrimp test indicate that both complexes have good toxicity against Artemia nauplii.",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines",
volume = "73",
number = "4",
pages = "702-716",
doi = "10.1080/00958972.2020.1740212"
}
Dimitrijević, T., Novaković, I. T., Radanović, D. D., Novaković, S. B., Rodić, M. V., Anđelković, K.,& Šumar-Ristović, M. (2020). Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines.
Journal of Coordination Chemistry, 73(4), 702-716.
https://doi.org/10.1080/00958972.2020.1740212
Dimitrijević T, Novaković IT, Radanović DD, Novaković SB, Rodić MV, Anđelković K, Šumar-Ristović M. Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines. Journal of Coordination Chemistry. 2020;73(4):702-716
Dimitrijević Teodora, Novaković Irena T., Radanović Dušanka D., Novaković Slađana B., Rodić Marko V., Anđelković Katarina, Šumar-Ristović Maja, "Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines" Journal of Coordination Chemistry, 73, no. 4 (2020):702-716,
https://doi.org/10.1080/00958972.2020.1740212 .
2
2
2

Synthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureas

Minić, Aleksandra; Novaković, Slađana B.; Bogdanović, Goran A.; Bugarinović, Jovana P.; Pešić, Marko S.; Todosijević, Anka; Ilić-Komatina, Danijela; Damljanović, Ivan S.; Stevanović, Dragana D.

(2020)

TY  - JOUR
AU  - Minić, Aleksandra
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Bugarinović, Jovana P.
AU  - Pešić, Marko S.
AU  - Todosijević, Anka
AU  - Ilić-Komatina, Danijela
AU  - Damljanović, Ivan S.
AU  - Stevanović, Dragana D.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8808
AB  - The stereochemical phenomenon that arises from hindered rotation around bonds in nonplanar molecules is termed the atropoisomerism. During our previous work we noted the presence of this kind of isomerism in 1-aryl-4-ferrocenyl-3-phenyltetrahydropyrimidin-2(1H)-ones obtained from ortho-substituted 3-(arylamino)-1-ferrocenylpropan-1-ols. Inspired by an interesting biological/medical features of six-membered cyclic ureas and characteristic of “atropoisomers - things that rotate”, herein we present an easy performable synthesis and full characterisation of novel atropoisomeric ferrocene-containing six-membered cyclic ureas. In addition, we successfully determined the crystal structure of two atropoisomers for the same compound. Molecular structural properties and intermolecular interactions of these two structures have been compared and analyzed in detail. Interesting, it has been found that these two isomers although quite similar in conformation and geometrical parameters, form very different crystal packing. © 2019 Elsevier Ltd
T2  - Polyhedron
T1  - Synthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureas
VL  - 177
SP  - 114316
DO  - 10.1016/j.poly.2019.114316
ER  - 
@article{
author = "Minić, Aleksandra and Novaković, Slađana B. and Bogdanović, Goran A. and Bugarinović, Jovana P. and Pešić, Marko S. and Todosijević, Anka and Ilić-Komatina, Danijela and Damljanović, Ivan S. and Stevanović, Dragana D.",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8808",
abstract = "The stereochemical phenomenon that arises from hindered rotation around bonds in nonplanar molecules is termed the atropoisomerism. During our previous work we noted the presence of this kind of isomerism in 1-aryl-4-ferrocenyl-3-phenyltetrahydropyrimidin-2(1H)-ones obtained from ortho-substituted 3-(arylamino)-1-ferrocenylpropan-1-ols. Inspired by an interesting biological/medical features of six-membered cyclic ureas and characteristic of “atropoisomers - things that rotate”, herein we present an easy performable synthesis and full characterisation of novel atropoisomeric ferrocene-containing six-membered cyclic ureas. In addition, we successfully determined the crystal structure of two atropoisomers for the same compound. Molecular structural properties and intermolecular interactions of these two structures have been compared and analyzed in detail. Interesting, it has been found that these two isomers although quite similar in conformation and geometrical parameters, form very different crystal packing. © 2019 Elsevier Ltd",
journal = "Polyhedron",
title = "Synthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureas",
volume = "177",
pages = "114316",
doi = "10.1016/j.poly.2019.114316"
}
Minić, A., Novaković, S. B., Bogdanović, G. A., Bugarinović, J. P., Pešić, M. S., Todosijević, A., Ilić-Komatina, D., Damljanović, I. S.,& Stevanović, D. D. (2020). Synthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureas.
Polyhedron, 177, 114316.
https://doi.org/10.1016/j.poly.2019.114316
Minić A, Novaković SB, Bogdanović GA, Bugarinović JP, Pešić MS, Todosijević A, Ilić-Komatina D, Damljanović IS, Stevanović DD. Synthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureas. Polyhedron. 2020;177:114316
Minić Aleksandra, Novaković Slađana B., Bogdanović Goran A., Bugarinović Jovana P., Pešić Marko S., Todosijević Anka, Ilić-Komatina Danijela, Damljanović Ivan S., Stevanović Dragana D., "Synthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureas" Polyhedron, 177 (2020):114316,
https://doi.org/10.1016/j.poly.2019.114316 .
1
1
1

Electrochemical characterization and estimation of DNA-binding capacity of a series of novel ferrocene derivatives

Pešić, Marko S.; Bugarinović, Jovana P.; Minić, Aleksandra; Novaković, Slađana B.; Bogdanović, Goran A.; Todosijević, Anka; Stevanović, Dragana D.; Damljanović, Ivan S.

(2020)

TY  - JOUR
AU  - Pešić, Marko S.
AU  - Bugarinović, Jovana P.
AU  - Minić, Aleksandra
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Todosijević, Anka
AU  - Stevanović, Dragana D.
AU  - Damljanović, Ivan S.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8784
AB  - The synthesis of a series of methyl 2-alkyl-5-aryl-4-ferrocenoylpyrrolidine-2-carboxylates has been achieved by [3 + 2] dipolar cycloaddition of azomethine ylides to acryloylferrocene. The electrochemical properties of novel products were examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). These techniques revealed the quasi-reversible one-electron oxidation process. The DNA-binding capacity of all the products was also studied using CV and DPV, and significant interactions between synthesized compounds and nucleic acid, mostly of the electrostatic type, were disclosed. DFT calculations and molecular docking tests were carried out to gain a more exhaustive insight into the interactions of the obtained products with nucleic acid. A detailed characterization of the new compounds was performed by IR, NMR and elemental analyses, followed by single-crystal X-ray diffraction experiments for two representatives. © 2019 Elsevier B.V.
T2  - Bioelectrochemistry
T1  - Electrochemical characterization and estimation of DNA-binding capacity of a series of novel ferrocene derivatives
VL  - 132
SP  - 107412
DO  - 10.1016/j.bioelechem.2019.107412
ER  - 
@article{
author = "Pešić, Marko S. and Bugarinović, Jovana P. and Minić, Aleksandra and Novaković, Slađana B. and Bogdanović, Goran A. and Todosijević, Anka and Stevanović, Dragana D. and Damljanović, Ivan S.",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/8784",
abstract = "The synthesis of a series of methyl 2-alkyl-5-aryl-4-ferrocenoylpyrrolidine-2-carboxylates has been achieved by [3 + 2] dipolar cycloaddition of azomethine ylides to acryloylferrocene. The electrochemical properties of novel products were examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). These techniques revealed the quasi-reversible one-electron oxidation process. The DNA-binding capacity of all the products was also studied using CV and DPV, and significant interactions between synthesized compounds and nucleic acid, mostly of the electrostatic type, were disclosed. DFT calculations and molecular docking tests were carried out to gain a more exhaustive insight into the interactions of the obtained products with nucleic acid. A detailed characterization of the new compounds was performed by IR, NMR and elemental analyses, followed by single-crystal X-ray diffraction experiments for two representatives. © 2019 Elsevier B.V.",
journal = "Bioelectrochemistry",
title = "Electrochemical characterization and estimation of DNA-binding capacity of a series of novel ferrocene derivatives",
volume = "132",
pages = "107412",
doi = "10.1016/j.bioelechem.2019.107412"
}
Pešić, M. S., Bugarinović, J. P., Minić, A., Novaković, S. B., Bogdanović, G. A., Todosijević, A., Stevanović, D. D.,& Damljanović, I. S. (2020). Electrochemical characterization and estimation of DNA-binding capacity of a series of novel ferrocene derivatives.
Bioelectrochemistry, 132, 107412.
https://doi.org/10.1016/j.bioelechem.2019.107412
Pešić MS, Bugarinović JP, Minić A, Novaković SB, Bogdanović GA, Todosijević A, Stevanović DD, Damljanović IS. Electrochemical characterization and estimation of DNA-binding capacity of a series of novel ferrocene derivatives. Bioelectrochemistry. 2020;132:107412
Pešić Marko S., Bugarinović Jovana P., Minić Aleksandra, Novaković Slađana B., Bogdanović Goran A., Todosijević Anka, Stevanović Dragana D., Damljanović Ivan S., "Electrochemical characterization and estimation of DNA-binding capacity of a series of novel ferrocene derivatives" Bioelectrochemistry, 132 (2020):107412,
https://doi.org/10.1016/j.bioelechem.2019.107412 .
3
2
3

Interactions of binuclear copper(II) complexes with S-substituted thiosalicylate derivatives with some relevant biomolecules

Jovanović, Snežana; Bogojeski, Jovana V.; Nikolić, Miloš V.; Mijajlović, Marina Ž.; Tomović, Dušan Lj.; Bukonjić, Andriana M.; Knežević Rangelov, Sanja M.; Mijailović, Nataša R.; Ratković, Zoran; Jevtić, Verica V.; Petrović, Biljana V.; Trifunović, Srećko R.; Novaković, Slađana B.; Bogdanović, Goran A.; Radić, Gordana P.

(2019)

TY  - JOUR
AU  - Jovanović, Snežana
AU  - Bogojeski, Jovana V.
AU  - Nikolić, Miloš V.
AU  - Mijajlović, Marina Ž.
AU  - Tomović, Dušan Lj.
AU  - Bukonjić, Andriana M.
AU  - Knežević Rangelov, Sanja M.
AU  - Mijailović, Nataša R.
AU  - Ratković, Zoran
AU  - Jevtić, Verica V.
AU  - Petrović, Biljana V.
AU  - Trifunović, Srećko R.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Radić, Gordana P.
PY  - 2019
UR  - https://www.tandfonline.com/doi/full/10.1080/00958972.2019.1610561
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8196
AB  - Interactions of copper(II) complexes which contain S-alkyl derivatives of thiosalicylic acid (alkyl = methyl, ethyl, propyl and butyl; aryl = benzyl), marked as 1–5, with guanosine-5′-monophosphate (5′-GMP) and calf thymus DNA (CT-DNA) were studied. Kinetics of substitution reactions of 1–5 with 5′-GMP and CT-DNA were investigated under pseudo-first-order conditions at 310 K and pH = 7.2 in 25 mM Hepes buffer using stopped-flow method. All complexes have high affinity toward studied bio-molecules. Additionally, interactions with CT-DNA were followed by absorption spectroscopy and fluorescence quenching measurements. The results indicate that complexes bind to DNA exhibiting high binding constants (Kb = 104 M−1). During the examination of competitive reactions with ethidium bromide (EB), results showed that complexes can replace EB-bound DNA. In addition, a new crystal structure of the binuclear Cu(II) complex with S-substituted thiosalicylate derivative has been reported. In the present series of Cu(II) complexes the crystal structure is the first example of a complex comprising an S-aryl derivative of thiosalicylate ligand. Through comparative study of structural properties of six molecules from four crystal structures we examined the structural variations, potentially important for biological activity of these complexes. © 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group.
T2  - Journal of Coordination Chemistry
T1  - Interactions of binuclear copper(II) complexes with S-substituted thiosalicylate derivatives with some relevant biomolecules
VL  - 72
IS  - 10
SP  - 1603
EP  - 1620
DO  - 10.1080/00958972.2019.1610561
ER  - 
@article{
author = "Jovanović, Snežana and Bogojeski, Jovana V. and Nikolić, Miloš V. and Mijajlović, Marina Ž. and Tomović, Dušan Lj. and Bukonjić, Andriana M. and Knežević Rangelov, Sanja M. and Mijailović, Nataša R. and Ratković, Zoran and Jevtić, Verica V. and Petrović, Biljana V. and Trifunović, Srećko R. and Novaković, Slađana B. and Bogdanović, Goran A. and Radić, Gordana P.",
year = "2019",
url = "https://www.tandfonline.com/doi/full/10.1080/00958972.2019.1610561, http://vinar.vin.bg.ac.rs/handle/123456789/8196",
abstract = "Interactions of copper(II) complexes which contain S-alkyl derivatives of thiosalicylic acid (alkyl = methyl, ethyl, propyl and butyl; aryl = benzyl), marked as 1–5, with guanosine-5′-monophosphate (5′-GMP) and calf thymus DNA (CT-DNA) were studied. Kinetics of substitution reactions of 1–5 with 5′-GMP and CT-DNA were investigated under pseudo-first-order conditions at 310 K and pH = 7.2 in 25 mM Hepes buffer using stopped-flow method. All complexes have high affinity toward studied bio-molecules. Additionally, interactions with CT-DNA were followed by absorption spectroscopy and fluorescence quenching measurements. The results indicate that complexes bind to DNA exhibiting high binding constants (Kb = 104 M−1). During the examination of competitive reactions with ethidium bromide (EB), results showed that complexes can replace EB-bound DNA. In addition, a new crystal structure of the binuclear Cu(II) complex with S-substituted thiosalicylate derivative has been reported. In the present series of Cu(II) complexes the crystal structure is the first example of a complex comprising an S-aryl derivative of thiosalicylate ligand. Through comparative study of structural properties of six molecules from four crystal structures we examined the structural variations, potentially important for biological activity of these complexes. © 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group.",
journal = "Journal of Coordination Chemistry",
title = "Interactions of binuclear copper(II) complexes with S-substituted thiosalicylate derivatives with some relevant biomolecules",
volume = "72",
number = "10",
pages = "1603-1620",
doi = "10.1080/00958972.2019.1610561"
}
Jovanović, S., Bogojeski, J. V., Nikolić, M. V., Mijajlović, M. Ž., Tomović, D. Lj., Bukonjić, A. M., Knežević Rangelov, S. M., Mijailović, N. R., Ratković, Z., Jevtić, V. V., Petrović, B. V., Trifunović, S. R., Novaković, S. B., Bogdanović, G. A.,& Radić, G. P. (2019). Interactions of binuclear copper(II) complexes with S-substituted thiosalicylate derivatives with some relevant biomolecules.
Journal of Coordination Chemistry, 72(10), 1603-1620.
https://doi.org/10.1080/00958972.2019.1610561
Jovanović S, Bogojeski JV, Nikolić MV, Mijajlović MŽ, Tomović DL, Bukonjić AM, Knežević Rangelov SM, Mijailović NR, Ratković Z, Jevtić VV, Petrović BV, Trifunović SR, Novaković SB, Bogdanović GA, Radić GP. Interactions of binuclear copper(II) complexes with S-substituted thiosalicylate derivatives with some relevant biomolecules. Journal of Coordination Chemistry. 2019;72(10):1603-1620
Jovanović Snežana, Bogojeski Jovana V., Nikolić Miloš V., Mijajlović Marina Ž., Tomović Dušan Lj., Bukonjić Andriana M., Knežević Rangelov Sanja M., Mijailović Nataša R., Ratković Zoran, Jevtić Verica V., Petrović Biljana V., Trifunović Srećko R., Novaković Slađana B., Bogdanović Goran A., Radić Gordana P., "Interactions of binuclear copper(II) complexes with S-substituted thiosalicylate derivatives with some relevant biomolecules" Journal of Coordination Chemistry, 72, no. 10 (2019):1603-1620,
https://doi.org/10.1080/00958972.2019.1610561 .

Crystal structure of dihydrazinium 1H-pyrazole-3,5-dicarboxylate, C5H12N6O4

Latinović, Nedeljko; Novaković, Slađana B.; Bogdanović, Goran A.; Kastratović, Vlatko; Giester, Gerald; Jaćimović, Željko K.

(2019)

TY  - JOUR
AU  - Latinović, Nedeljko
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Kastratović, Vlatko
AU  - Giester, Gerald
AU  - Jaćimović, Željko K.
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8376
AB  - C 5 H 12 N 6 O 4 , monoclinic, P 2 1 / n (no. 14), a = 4.3368(6) Å, b = 15.483(2) Å, c = 13.8852(19) Å, β = 97.714(3)°, V = 923.9(2) Å 3 , Z = 4, R gt ( F ) = 0.0411, wR ref ( F 2 ) = 0.1109, T = 200(2) K.
T2  - Zeitschrift für Kristallographie - New Crystal Structures
T1  - Crystal structure of dihydrazinium 1H-pyrazole-3,5-dicarboxylate, C5H12N6O4
VL  - 234
IS  - 5
SP  - 957
EP  - 958
DO  - 10.1515/ncrs-2019-0168
ER  - 
@article{
author = "Latinović, Nedeljko and Novaković, Slađana B. and Bogdanović, Goran A. and Kastratović, Vlatko and Giester, Gerald and Jaćimović, Željko K.",
year = "2019",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8376",
abstract = "C 5 H 12 N 6 O 4 , monoclinic, P 2 1 / n (no. 14), a = 4.3368(6) Å, b = 15.483(2) Å, c = 13.8852(19) Å, β = 97.714(3)°, V = 923.9(2) Å 3 , Z = 4, R gt ( F ) = 0.0411, wR ref ( F 2 ) = 0.1109, T = 200(2) K.",
journal = "Zeitschrift für Kristallographie - New Crystal Structures",
title = "Crystal structure of dihydrazinium 1H-pyrazole-3,5-dicarboxylate, C5H12N6O4",
volume = "234",
number = "5",
pages = "957-958",
doi = "10.1515/ncrs-2019-0168"
}
Latinović, N., Novaković, S. B., Bogdanović, G. A., Kastratović, V., Giester, G.,& Jaćimović, Ž. K. (2019). Crystal structure of dihydrazinium 1H-pyrazole-3,5-dicarboxylate, C5H12N6O4.
Zeitschrift für Kristallographie - New Crystal Structures, 234(5), 957-958.
https://doi.org/10.1515/ncrs-2019-0168
Latinović N, Novaković SB, Bogdanović GA, Kastratović V, Giester G, Jaćimović ŽK. Crystal structure of dihydrazinium 1H-pyrazole-3,5-dicarboxylate, C5H12N6O4. Zeitschrift für Kristallographie - New Crystal Structures. 2019;234(5):957-958
Latinović Nedeljko, Novaković Slađana B., Bogdanović Goran A., Kastratović Vlatko, Giester Gerald, Jaćimović Željko K., "Crystal structure of dihydrazinium 1H-pyrazole-3,5-dicarboxylate, C5H12N6O4" Zeitschrift für Kristallographie - New Crystal Structures, 234, no. 5 (2019):957-958,
https://doi.org/10.1515/ncrs-2019-0168 .
1
1

Structural characterization of benzoyl-1H-pyrazole derivatives obtained in lemon juice medium: Experimental and theoretical approach

Milovanović, Vesna M.; Petrović, Zorica D.; Novaković, Slađana B.; Bogdanović, Goran A.; Simijonović, Dušica; Petrović, Vladimir P.

(2019)

TY  - JOUR
AU  - Milovanović, Vesna M.
AU  - Petrović, Zorica D.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Simijonović, Dušica
AU  - Petrović, Vladimir P.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0022286019306659
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8224
AB  - Simple, one-pot, and low-cost reactions of acetylacetone with a variety of substituted benzoyl hydrazides in lemon juice, as eco-friendly medium, were performed. In reactions of benzoyl hydrazides with electron-donating groups on phenyl ring, the 1-benzoyl-1H-pyrazole derivatives were obtained in short reaction time, and in good to high yields. On the other hand, benzoyl hydrazides with electron-withdrawing groups reacted slower, yielding the mixture of 1-benzoyl-5-hydroxy-4,5-dihydro-1H-pyrazole and benzoyl-1H-pyrazole derivatives. It is worth pointing out that two products, (2-chlorophenyl)(4,5-dihydro-5-hydroxy-3,5-dimethylpyrazol-1-yl)methanone and (4-iodophenyl)(3,5-dimethyl-1H-pyrazol-1-yl)methanone are reported here for the first time. All obtained compounds were characterized using IR, UV–Vis and NMR, experimentally and theoretically, as well as with melting points. Good agreement between experimental and simulated IR, UV–Vis, 1H and 13C NMR spectra was achieved. In addition, crystal structures and Hirshfeld surfaces analysis of (4,5-dihydro-5-hydroxy-3,5-dimethylpyrazol-1-yl)(4-iodophenyl)methanone were reported. © 2019 Elsevier B.V.
T2  - Journal of Molecular Structure
T1  - Structural characterization of benzoyl-1H-pyrazole derivatives obtained in lemon juice medium: Experimental and theoretical approach
VL  - 1195
SP  - 85
EP  - 94
DO  - 10.1016/j.molstruc.2019.05.095
ER  - 
@article{
author = "Milovanović, Vesna M. and Petrović, Zorica D. and Novaković, Slađana B. and Bogdanović, Goran A. and Simijonović, Dušica and Petrović, Vladimir P.",
year = "2019",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0022286019306659, http://vinar.vin.bg.ac.rs/handle/123456789/8224",
abstract = "Simple, one-pot, and low-cost reactions of acetylacetone with a variety of substituted benzoyl hydrazides in lemon juice, as eco-friendly medium, were performed. In reactions of benzoyl hydrazides with electron-donating groups on phenyl ring, the 1-benzoyl-1H-pyrazole derivatives were obtained in short reaction time, and in good to high yields. On the other hand, benzoyl hydrazides with electron-withdrawing groups reacted slower, yielding the mixture of 1-benzoyl-5-hydroxy-4,5-dihydro-1H-pyrazole and benzoyl-1H-pyrazole derivatives. It is worth pointing out that two products, (2-chlorophenyl)(4,5-dihydro-5-hydroxy-3,5-dimethylpyrazol-1-yl)methanone and (4-iodophenyl)(3,5-dimethyl-1H-pyrazol-1-yl)methanone are reported here for the first time. All obtained compounds were characterized using IR, UV–Vis and NMR, experimentally and theoretically, as well as with melting points. Good agreement between experimental and simulated IR, UV–Vis, 1H and 13C NMR spectra was achieved. In addition, crystal structures and Hirshfeld surfaces analysis of (4,5-dihydro-5-hydroxy-3,5-dimethylpyrazol-1-yl)(4-iodophenyl)methanone were reported. © 2019 Elsevier B.V.",
journal = "Journal of Molecular Structure",
title = "Structural characterization of benzoyl-1H-pyrazole derivatives obtained in lemon juice medium: Experimental and theoretical approach",
volume = "1195",
pages = "85-94",
doi = "10.1016/j.molstruc.2019.05.095"
}
Milovanović, V. M., Petrović, Z. D., Novaković, S. B., Bogdanović, G. A., Simijonović, D.,& Petrović, V. P. (2019). Structural characterization of benzoyl-1H-pyrazole derivatives obtained in lemon juice medium: Experimental and theoretical approach.
Journal of Molecular Structure, 1195, 85-94.
https://doi.org/10.1016/j.molstruc.2019.05.095
Milovanović VM, Petrović ZD, Novaković SB, Bogdanović GA, Simijonović D, Petrović VP. Structural characterization of benzoyl-1H-pyrazole derivatives obtained in lemon juice medium: Experimental and theoretical approach. Journal of Molecular Structure. 2019;1195:85-94
Milovanović Vesna M., Petrović Zorica D., Novaković Slađana B., Bogdanović Goran A., Simijonović Dušica, Petrović Vladimir P., "Structural characterization of benzoyl-1H-pyrazole derivatives obtained in lemon juice medium: Experimental and theoretical approach" Journal of Molecular Structure, 1195 (2019):85-94,
https://doi.org/10.1016/j.molstruc.2019.05.095 .
2
3
2

First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand

Jaćimović, Željko K.; Novaković, Slađana B.; Bogdanović, Goran A.; Giester, Gerald; Kosović, Milica; Libowitzky, Eugen

(2019)

TY  - JOUR
AU  - Jaćimović, Željko K.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Giester, Gerald
AU  - Kosović, Milica
AU  - Libowitzky, Eugen
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8540
AB  - Pyrazole (pz)-derived ligands can, besides exhibiting a strong coordination ability toward different metal ions, exhibit a great diversity in their coordination geometry and nuclearity, which can be achieved by varying the type and position of the pz substituents. The present study reports the synthesis and crystal structure of two binuclear complexes, namely bis(μ-4-nitro-1 H -imidazol-1-ide-5-carboxylato)-κ 3 N 1 , O : N 2 ;κ 3 N 2 : N 1 , O -bis[aqua(dimethylformamide-κ O )copper(II)], [Cu 2 (C 4 HN 3 O 4 ) 2 (C 3 H 7 NO) 2 (H 2 O) 2 ], (II), and bis(μ-4-nitro-1 H -imidazol-1-ide-5-carboxylato)-κ 2 N 1 , O : N 2 ;κ 2 N 2 : N 1 , O -bis[triaquacobalt(II)] dihydrate, [Co 2 (C 4 HN 3 O 4 ) 2 (H 2 O) 6 ]·2H 2 O, (III). These compounds represent rare examples of metal complexes comprising 3,4-substituted pz derivatives as a bridging ligand and also the first crystal structures of transition-metal complexes with ligands derived from 4-nitropyrazole-3-carboxylic acid. Recently, the crystal structures of the same ligand in the neutral and mixed neutral/anionic forms have been reported. We present here the third form of this ligand, where it is present in a fully deprotonated anionic form within a salt, i.e. ammonium 4-nitropyrazole-3-carboxylate, NH 4 + ·C 4 H 2 N 3 O 4 − , (I). Single-crystal X-ray diffraction revealed that in the present complexes, the Cu II and Co II centres adopt distorted square-pyramidal and octahedral geometries, respectively. In both cases, the N , N ′, O -coordinated pz ligand shows simultaneously chelating and bridging coordination modes, leading to the formation of a nearly planar six-membered M 2 N 4 metallocycle. In all three crystal structures, the supramolecular arrangement is controlled by strong hydrogen bonds which primarily engage the carboxylate O atoms as acceptors, while the nitro group adopts the role of an acceptor only in structures with an increased number of donors, as is the case with Co II complex (III). The electrostatic potential, as a descriptor of reactivity, was also calculated in order to examine the changes in ligand electrostatic preferences upon coordination to metal ions.
T2  - Acta Crystallographica Section C Structural Chemistry
T1  - First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand
VL  - 75
IS  - 3
SP  - 255
EP  - 264
DO  - 10.1107/S2053229619001244
ER  - 
@article{
author = "Jaćimović, Željko K. and Novaković, Slađana B. and Bogdanović, Goran A. and Giester, Gerald and Kosović, Milica and Libowitzky, Eugen",
year = "2019",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/8540",
abstract = "Pyrazole (pz)-derived ligands can, besides exhibiting a strong coordination ability toward different metal ions, exhibit a great diversity in their coordination geometry and nuclearity, which can be achieved by varying the type and position of the pz substituents. The present study reports the synthesis and crystal structure of two binuclear complexes, namely bis(μ-4-nitro-1 H -imidazol-1-ide-5-carboxylato)-κ 3 N 1 , O : N 2 ;κ 3 N 2 : N 1 , O -bis[aqua(dimethylformamide-κ O )copper(II)], [Cu 2 (C 4 HN 3 O 4 ) 2 (C 3 H 7 NO) 2 (H 2 O) 2 ], (II), and bis(μ-4-nitro-1 H -imidazol-1-ide-5-carboxylato)-κ 2 N 1 , O : N 2 ;κ 2 N 2 : N 1 , O -bis[triaquacobalt(II)] dihydrate, [Co 2 (C 4 HN 3 O 4 ) 2 (H 2 O) 6 ]·2H 2 O, (III). These compounds represent rare examples of metal complexes comprising 3,4-substituted pz derivatives as a bridging ligand and also the first crystal structures of transition-metal complexes with ligands derived from 4-nitropyrazole-3-carboxylic acid. Recently, the crystal structures of the same ligand in the neutral and mixed neutral/anionic forms have been reported. We present here the third form of this ligand, where it is present in a fully deprotonated anionic form within a salt, i.e. ammonium 4-nitropyrazole-3-carboxylate, NH 4 + ·C 4 H 2 N 3 O 4 − , (I). Single-crystal X-ray diffraction revealed that in the present complexes, the Cu II and Co II centres adopt distorted square-pyramidal and octahedral geometries, respectively. In both cases, the N , N ′, O -coordinated pz ligand shows simultaneously chelating and bridging coordination modes, leading to the formation of a nearly planar six-membered M 2 N 4 metallocycle. In all three crystal structures, the supramolecular arrangement is controlled by strong hydrogen bonds which primarily engage the carboxylate O atoms as acceptors, while the nitro group adopts the role of an acceptor only in structures with an increased number of donors, as is the case with Co II complex (III). The electrostatic potential, as a descriptor of reactivity, was also calculated in order to examine the changes in ligand electrostatic preferences upon coordination to metal ions.",
journal = "Acta Crystallographica Section C Structural Chemistry",
title = "First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand",
volume = "75",
number = "3",
pages = "255-264",
doi = "10.1107/S2053229619001244"
}
Jaćimović, Ž. K., Novaković, S. B., Bogdanović, G. A., Giester, G., Kosović, M.,& Libowitzky, E. (2019). First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand.
Acta Crystallographica Section C Structural Chemistry, 75(3), 255-264.
https://doi.org/10.1107/S2053229619001244
Jaćimović ŽK, Novaković SB, Bogdanović GA, Giester G, Kosović M, Libowitzky E. First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand. Acta Crystallographica Section C Structural Chemistry. 2019;75(3):255-264
Jaćimović Željko K., Novaković Slađana B., Bogdanović Goran A., Giester Gerald, Kosović Milica, Libowitzky Eugen, "First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand" Acta Crystallographica Section C Structural Chemistry, 75, no. 3 (2019):255-264,
https://doi.org/10.1107/S2053229619001244 .
1
1
3
3

Short Intramolecular O···O Contact in Some o -Dialkoxybenzene Derivatives Generates Efficient Hydrogen Bonding Acceptor Area

Bogdanović, Goran A.; Ostojić, Bojana D.; Novaković, Slađana B.

(2018)

TY  - JOUR
AU  - Bogdanović, Goran A.
AU  - Ostojić, Bojana D.
AU  - Novaković, Slađana B.
PY  - 2018
UR  - http://pubs.acs.org/doi/10.1021/acs.cgd.7b00914
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7659
AB  - Statistical analysis of data extracted from the Cambridge Structural Database (CSD) has been used to investigate the crystal structure properties of odialkoxybenzene derivatives, compounds containing two ether oxygen acceptors in ortho positions of benzene ring. It has been shown that in more than 90% of cases, the fragment has predictable geometrical characteristics where the two ether oxygens form short interatomic O center dot center dot center dot O contact (2.57 A in average), while O-substitutents take trans position, both approximately coplanar with the benzene ring. Such arrangement of oxygen acceptors produces a large and uniform area of the negative electrostatic potential suitable for multiple hydrogen bonding. The acceptor abilities of the O center dot center dot center dot O system have been investigated by the statistical CSD analysis. The ab initio estimation of the interaction energy in the dimer of o-dimethoxybenzene (DMB) and H2O, employed as a model system, is achieved via high-level electron correlation CCSD(T) calculation with the complete basis set extrapolation. The interaction energy is estimated to be 6.5 kcal/mol. The results indicate the existence of a very flat potential the region between methoxy oxygens and that DMB water is a highly flexible system. The structural role of the O center dot center dot center dot O acceptor system is particularly interesting considering its ability to form multiple hydrogen bonding
T2  - Crystal Growth & Design
T1  - Short Intramolecular O···O Contact in Some o -Dialkoxybenzene Derivatives Generates Efficient Hydrogen Bonding Acceptor Area
VL  - 18
IS  - 3
SP  - 1303
EP  - 1314
DO  - 10.1021/acs.cgd.7b00914
ER  - 
@article{
author = "Bogdanović, Goran A. and Ostojić, Bojana D. and Novaković, Slađana B.",
year = "2018",
url = "http://pubs.acs.org/doi/10.1021/acs.cgd.7b00914, http://vinar.vin.bg.ac.rs/handle/123456789/7659",
abstract = "Statistical analysis of data extracted from the Cambridge Structural Database (CSD) has been used to investigate the crystal structure properties of odialkoxybenzene derivatives, compounds containing two ether oxygen acceptors in ortho positions of benzene ring. It has been shown that in more than 90% of cases, the fragment has predictable geometrical characteristics where the two ether oxygens form short interatomic O center dot center dot center dot O contact (2.57 A in average), while O-substitutents take trans position, both approximately coplanar with the benzene ring. Such arrangement of oxygen acceptors produces a large and uniform area of the negative electrostatic potential suitable for multiple hydrogen bonding. The acceptor abilities of the O center dot center dot center dot O system have been investigated by the statistical CSD analysis. The ab initio estimation of the interaction energy in the dimer of o-dimethoxybenzene (DMB) and H2O, employed as a model system, is achieved via high-level electron correlation CCSD(T) calculation with the complete basis set extrapolation. The interaction energy is estimated to be 6.5 kcal/mol. The results indicate the existence of a very flat potential the region between methoxy oxygens and that DMB water is a highly flexible system. The structural role of the O center dot center dot center dot O acceptor system is particularly interesting considering its ability to form multiple hydrogen bonding",
journal = "Crystal Growth & Design",
title = "Short Intramolecular O···O Contact in Some o -Dialkoxybenzene Derivatives Generates Efficient Hydrogen Bonding Acceptor Area",
volume = "18",
number = "3",
pages = "1303-1314",
doi = "10.1021/acs.cgd.7b00914"
}
Bogdanović, G. A., Ostojić, B. D.,& Novaković, S. B. (2018). Short Intramolecular O···O Contact in Some o -Dialkoxybenzene Derivatives Generates Efficient Hydrogen Bonding Acceptor Area.
Crystal Growth & Design, 18(3), 1303-1314.
https://doi.org/10.1021/acs.cgd.7b00914
Bogdanović GA, Ostojić BD, Novaković SB. Short Intramolecular O···O Contact in Some o -Dialkoxybenzene Derivatives Generates Efficient Hydrogen Bonding Acceptor Area. Crystal Growth & Design. 2018;18(3):1303-1314
Bogdanović Goran A., Ostojić Bojana D., Novaković Slađana B., "Short Intramolecular O···O Contact in Some o -Dialkoxybenzene Derivatives Generates Efficient Hydrogen Bonding Acceptor Area" Crystal Growth & Design, 18, no. 3 (2018):1303-1314,
https://doi.org/10.1021/acs.cgd.7b00914 .
2
3
3

Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry

Janković, Nenad Ž.; Stefanović, Srđan M.; Petronijević, Jelena; Joksimović, Nenad; Novaković, Slađana B.; Bogdanović, Goran A.; Muškinja, Jovana; Vraneš, Milan; Ratković, Zoran; Bugarčić, Zorica M.

(2018)

TY  - JOUR
AU  - Janković, Nenad Ž.
AU  - Stefanović, Srđan M.
AU  - Petronijević, Jelena
AU  - Joksimović, Nenad
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Muškinja, Jovana
AU  - Vraneš, Milan
AU  - Ratković, Zoran
AU  - Bugarčić, Zorica M.
PY  - 2018
UR  - http://pubs.acs.org/doi/10.1021/acssuschemeng.8b03127
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7886
AB  - The selective synthesis of 5,6-dihydropyrimidin-4(3H)-one scaffold (precursor of dihydrouracil) was a very difficult synthetic challenge that, so far, has not been achieved. For the first time, in this paper, green, selective and high-yields approach to 40 novel 5,6-dihydropyrimidin-4(3H)-ones (DHPMs) by one-pot reaction of aldehydes, Meldrum's acid and isothioureas under solvent-free conditions, in the presence of water, since an additive is presented. In the majority of cases, introduced methodology gave an unprecedented tautomer-selective fashion toward targeted compounds with excellent tautomeric purity (>99.9%), which reached 100% in few cases. The molecular structure of the five compounds has been determined by X-ray crystallography. In each one of them, very short length for the corresponding N2-C1 bond was noticed, making them especially interesting from a structural standpoint. This experimental fact can imply a highly localized electron π density in this part of each heterocyclic ring. The obtained experimental results, which are determined from NMR and ESI-MS study, indicate that this Biginelli-type reaction smoothly proceeds in a one-pot mode, pointing to the three-step tandem process, proceeding via the Knoevenagel, aza-Michael, and retro-Diels-Alder reactions. The presented strategy also had the following advantages: reduction amount of waste, excellent values of green chemistry metrics (cEF, EcoScale and GCIS), and it is the first eco-friendly strategy toward the DHPMs scaffold. © Copyright 2018 American Chemical Society.
T2  - ACS Sustainable Chemistry & Engineering
T1  - Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry
VL  - 6
IS  - 10
SP  - 13358
EP  - 13366
DO  - 10.1021/acssuschemeng.8b03127
ER  - 
@article{
author = "Janković, Nenad Ž. and Stefanović, Srđan M. and Petronijević, Jelena and Joksimović, Nenad and Novaković, Slađana B. and Bogdanović, Goran A. and Muškinja, Jovana and Vraneš, Milan and Ratković, Zoran and Bugarčić, Zorica M.",
year = "2018",
url = "http://pubs.acs.org/doi/10.1021/acssuschemeng.8b03127, http://vinar.vin.bg.ac.rs/handle/123456789/7886",
abstract = "The selective synthesis of 5,6-dihydropyrimidin-4(3H)-one scaffold (precursor of dihydrouracil) was a very difficult synthetic challenge that, so far, has not been achieved. For the first time, in this paper, green, selective and high-yields approach to 40 novel 5,6-dihydropyrimidin-4(3H)-ones (DHPMs) by one-pot reaction of aldehydes, Meldrum's acid and isothioureas under solvent-free conditions, in the presence of water, since an additive is presented. In the majority of cases, introduced methodology gave an unprecedented tautomer-selective fashion toward targeted compounds with excellent tautomeric purity (>99.9%), which reached 100% in few cases. The molecular structure of the five compounds has been determined by X-ray crystallography. In each one of them, very short length for the corresponding N2-C1 bond was noticed, making them especially interesting from a structural standpoint. This experimental fact can imply a highly localized electron π density in this part of each heterocyclic ring. The obtained experimental results, which are determined from NMR and ESI-MS study, indicate that this Biginelli-type reaction smoothly proceeds in a one-pot mode, pointing to the three-step tandem process, proceeding via the Knoevenagel, aza-Michael, and retro-Diels-Alder reactions. The presented strategy also had the following advantages: reduction amount of waste, excellent values of green chemistry metrics (cEF, EcoScale and GCIS), and it is the first eco-friendly strategy toward the DHPMs scaffold. © Copyright 2018 American Chemical Society.",
journal = "ACS Sustainable Chemistry & Engineering",
title = "Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry",
volume = "6",
number = "10",
pages = "13358-13366",
doi = "10.1021/acssuschemeng.8b03127"
}
Janković, N. Ž., Stefanović, S. M., Petronijević, J., Joksimović, N., Novaković, S. B., Bogdanović, G. A., Muškinja, J., Vraneš, M., Ratković, Z.,& Bugarčić, Z. M. (2018). Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry.
ACS Sustainable Chemistry & Engineering, 6(10), 13358-13366.
https://doi.org/10.1021/acssuschemeng.8b03127
Janković NŽ, Stefanović SM, Petronijević J, Joksimović N, Novaković SB, Bogdanović GA, Muškinja J, Vraneš M, Ratković Z, Bugarčić ZM. Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry. ACS Sustainable Chemistry & Engineering. 2018;6(10):13358-13366
Janković Nenad Ž., Stefanović Srđan M., Petronijević Jelena, Joksimović Nenad, Novaković Slađana B., Bogdanović Goran A., Muškinja Jovana, Vraneš Milan, Ratković Zoran, Bugarčić Zorica M., "Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry" ACS Sustainable Chemistry & Engineering, 6, no. 10 (2018):13358-13366,
https://doi.org/10.1021/acssuschemeng.8b03127 .
4
5
2

Pyrazoline derivatives of acryloyl substituted ferrocenyl ketones: Synthesis, antimicrobial activity and structural properties

Burmudzija, Adrijana; Muskinja, Jovana; Ratkovic, Zoran; Kosanic, Marijana; Rankovic, Branislav; Novaković, Slađana B.; Bogdanović, Goran A.

(2018)

TY  - JOUR
AU  - Burmudzija, Adrijana
AU  - Muskinja, Jovana
AU  - Ratkovic, Zoran
AU  - Kosanic, Marijana
AU  - Rankovic, Branislav
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
PY  - 2018
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1910
AB  - A series of ferrocenyl ketones were synthesized in reaction with ferrocene and corresponding substituted acryloyl chlorides, following previously described procedure. Synthesized products have conjugated enone system, which is suitable for further transformations. In a reaction with hydrazine in acidic medium (acetic acid) new pyrazoline derivatives were obtained. Their antimicrobial properties have been tested. Synthesized pyrazoline derivatives demonstrated expressed in vitro antimicrobial activity towards 12 strains of microorganisms inhibiting all tested bacteria and fungi. The most potent compound in all cases was sorbyl derivative; for bacteria activity was very close to streptomycin, and for fungi in one case the same as ketoconazole. It is established that this compound can be a new, potential antimicrobial agent with minimum inhibitory concentrations from 0.039 to 0.312 mg/mL. One of the starting compounds and two products were crystal substances, suitable for the single crystal X-ray diffraction analysis, which confirmed undoubtedly their structures. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Inorganica Chimica Acta
T1  - Pyrazoline derivatives of acryloyl substituted ferrocenyl ketones: Synthesis, antimicrobial activity and structural properties
VL  - 471
SP  - 570
EP  - 576
DO  - 10.1016/j.ica.2017.11.061
ER  - 
@article{
author = "Burmudzija, Adrijana and Muskinja, Jovana and Ratkovic, Zoran and Kosanic, Marijana and Rankovic, Branislav and Novaković, Slađana B. and Bogdanović, Goran A.",
year = "2018",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1910",
abstract = "A series of ferrocenyl ketones were synthesized in reaction with ferrocene and corresponding substituted acryloyl chlorides, following previously described procedure. Synthesized products have conjugated enone system, which is suitable for further transformations. In a reaction with hydrazine in acidic medium (acetic acid) new pyrazoline derivatives were obtained. Their antimicrobial properties have been tested. Synthesized pyrazoline derivatives demonstrated expressed in vitro antimicrobial activity towards 12 strains of microorganisms inhibiting all tested bacteria and fungi. The most potent compound in all cases was sorbyl derivative; for bacteria activity was very close to streptomycin, and for fungi in one case the same as ketoconazole. It is established that this compound can be a new, potential antimicrobial agent with minimum inhibitory concentrations from 0.039 to 0.312 mg/mL. One of the starting compounds and two products were crystal substances, suitable for the single crystal X-ray diffraction analysis, which confirmed undoubtedly their structures. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Inorganica Chimica Acta",
title = "Pyrazoline derivatives of acryloyl substituted ferrocenyl ketones: Synthesis, antimicrobial activity and structural properties",
volume = "471",
pages = "570-576",
doi = "10.1016/j.ica.2017.11.061"
}
Burmudzija, A., Muskinja, J., Ratkovic, Z., Kosanic, M., Rankovic, B., Novaković, S. B.,& Bogdanović, G. A. (2018). Pyrazoline derivatives of acryloyl substituted ferrocenyl ketones: Synthesis, antimicrobial activity and structural properties.
Inorganica Chimica Acta, 471, 570-576.
https://doi.org/10.1016/j.ica.2017.11.061
Burmudzija A, Muskinja J, Ratkovic Z, Kosanic M, Rankovic B, Novaković SB, Bogdanović GA. Pyrazoline derivatives of acryloyl substituted ferrocenyl ketones: Synthesis, antimicrobial activity and structural properties. Inorganica Chimica Acta. 2018;471:570-576
Burmudzija Adrijana, Muskinja Jovana, Ratkovic Zoran, Kosanic Marijana, Rankovic Branislav, Novaković Slađana B., Bogdanović Goran A., "Pyrazoline derivatives of acryloyl substituted ferrocenyl ketones: Synthesis, antimicrobial activity and structural properties" Inorganica Chimica Acta, 471 (2018):570-576,
https://doi.org/10.1016/j.ica.2017.11.061 .
5
5
5

Supporting information for: Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry

Janković, Nenad Ž.; Stefanović, Srđan M.; Petronijević, Jelena; Joksimović, Nenad; Novaković, Slađana B.; Bogdanović, Goran A.; Muškinja, Jovana; Vraneš, Milan; Ratković, Zoran; Bugarčić, Zorica M.

(2018)

TY  - BOOK
AU  - Janković, Nenad Ž.
AU  - Stefanović, Srđan M.
AU  - Petronijević, Jelena
AU  - Joksimović, Nenad
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Muškinja, Jovana
AU  - Vraneš, Milan
AU  - Ratković, Zoran
AU  - Bugarčić, Zorica M.
PY  - 2018
UR  - http://pubs.acs.org/doi/10.1021/acssuschemeng.8b03127
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7886
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7888
AB  - The selective synthesis of 5,6-dihydropyrimidin-4(3H)-one scaffold (precursor of dihydrouracil) was a very difficult synthetic challenge that, so far, has not been achieved. For the first time, in this paper, green, selective and high-yields approach to 40 novel 5,6-dihydropyrimidin-4(3H)-ones (DHPMs) by one-pot reaction of aldehydes, Meldrum's acid and isothioureas under solvent-free conditions, in the presence of water, since an additive is presented. In the majority of cases, introduced methodology gave an unprecedented tautomer-selective fashion toward targeted compounds with excellent tautomeric purity (>99.9%), which reached 100% in few cases. The molecular structure of the five compounds has been determined by X-ray crystallography. In each one of them, very short length for the corresponding N2-C1 bond was noticed, making them especially interesting from a structural standpoint. This experimental fact can imply a highly localized electron π density in this part of each heterocyclic ring. The obtained experimental results, which are determined from NMR and ESI-MS study, indicate that this Biginelli-type reaction smoothly proceeds in a one-pot mode, pointing to the three-step tandem process, proceeding via the Knoevenagel, aza-Michael, and retro-Diels-Alder reactions. The presented strategy also had the following advantages: reduction amount of waste, excellent values of green chemistry metrics (cEF, EcoScale and GCIS), and it is the first eco-friendly strategy toward the DHPMs scaffold. © Copyright 2018 American Chemical Society.
T2  - ACS Sustainable Chemistry & Engineering
T1  - Supporting information for: Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry
VL  - 6
IS  - 10
SP  - 13358
EP  - 13366
DO  - 10.1021/acssuschemeng.8b03127.s006
ER  - 
@book{
author = "Janković, Nenad Ž. and Stefanović, Srđan M. and Petronijević, Jelena and Joksimović, Nenad and Novaković, Slađana B. and Bogdanović, Goran A. and Muškinja, Jovana and Vraneš, Milan and Ratković, Zoran and Bugarčić, Zorica M.",
year = "2018",
url = "http://pubs.acs.org/doi/10.1021/acssuschemeng.8b03127, http://vinar.vin.bg.ac.rs/handle/123456789/7886, http://vinar.vin.bg.ac.rs/handle/123456789/7888",
abstract = "The selective synthesis of 5,6-dihydropyrimidin-4(3H)-one scaffold (precursor of dihydrouracil) was a very difficult synthetic challenge that, so far, has not been achieved. For the first time, in this paper, green, selective and high-yields approach to 40 novel 5,6-dihydropyrimidin-4(3H)-ones (DHPMs) by one-pot reaction of aldehydes, Meldrum's acid and isothioureas under solvent-free conditions, in the presence of water, since an additive is presented. In the majority of cases, introduced methodology gave an unprecedented tautomer-selective fashion toward targeted compounds with excellent tautomeric purity (>99.9%), which reached 100% in few cases. The molecular structure of the five compounds has been determined by X-ray crystallography. In each one of them, very short length for the corresponding N2-C1 bond was noticed, making them especially interesting from a structural standpoint. This experimental fact can imply a highly localized electron π density in this part of each heterocyclic ring. The obtained experimental results, which are determined from NMR and ESI-MS study, indicate that this Biginelli-type reaction smoothly proceeds in a one-pot mode, pointing to the three-step tandem process, proceeding via the Knoevenagel, aza-Michael, and retro-Diels-Alder reactions. The presented strategy also had the following advantages: reduction amount of waste, excellent values of green chemistry metrics (cEF, EcoScale and GCIS), and it is the first eco-friendly strategy toward the DHPMs scaffold. © Copyright 2018 American Chemical Society.",
journal = "ACS Sustainable Chemistry & Engineering",
title = "Supporting information for: Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry",
volume = "6",
number = "10",
pages = "13358-13366",
doi = "10.1021/acssuschemeng.8b03127.s006"
}
Janković, N. Ž., Stefanović, S. M., Petronijević, J., Joksimović, N., Novaković, S. B., Bogdanović, G. A., Muškinja, J., Vraneš, M., Ratković, Z.,& Bugarčić, Z. M. (2018). Supporting information for: Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry.
ACS Sustainable Chemistry & Engineering, 6(10), 13358-13366.
https://doi.org/10.1021/acssuschemeng.8b03127.s006
Janković NŽ, Stefanović SM, Petronijević J, Joksimović N, Novaković SB, Bogdanović GA, Muškinja J, Vraneš M, Ratković Z, Bugarčić ZM. Supporting information for: Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry. ACS Sustainable Chemistry & Engineering. 2018;6(10):13358-13366
Janković Nenad Ž., Stefanović Srđan M., Petronijević Jelena, Joksimović Nenad, Novaković Slađana B., Bogdanović Goran A., Muškinja Jovana, Vraneš Milan, Ratković Zoran, Bugarčić Zorica M., "Supporting information for: Water-Tuned Tautomer-Selective Tandem Synthesis of the 5,6-Dihydropyrimidin-4(3 H )-ones, Driven under the Umbrella of Sustainable Chemistry" ACS Sustainable Chemistry & Engineering, 6, no. 10 (2018):13358-13366,
https://doi.org/10.1021/acssuschemeng.8b03127.s006 .
5
2

Acryloylferrocene as a convenient precursor of tetrahydropyrazolopyrazolones: [3+2] cycloaddition with N,N′ -Cyclic azomethine imines

Jovanović, Jovana P.; Novaković, Slađana B.; Bogdanović, Goran A.; Minić, Aleksandra; Pejović, Anka; Katanić, Jelena; Mihailović, Vladimir B.; Nastasijević, Branislav J.; Stevanović, Dragana D.; Damljanović, Ivan S.

(2018)

TY  - JOUR
AU  - Jovanović, Jovana P.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Minić, Aleksandra
AU  - Pejović, Anka
AU  - Katanić, Jelena
AU  - Mihailović, Vladimir B.
AU  - Nastasijević, Branislav J.
AU  - Stevanović, Dragana D.
AU  - Damljanović, Ivan S.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0022328X18301050
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7635
AB  - AlCl3-Catalyzed {[}3 + 2] dipolar cycloaddition of the N,N'-cyclic azomethine imines to the acryloylferrocene enabling access to the series of 5-substituted 6-ferrocenoyl tetrahydropyrazolo {[}1,2-a]pyrazol-1(5H)-ones. This facile methodology shows high substituent tolerance. Furthermore, easy chromatographic separations afford isolation of the pure diastereoisomers. Optimized reaction conditions, spectroscopic and electrochemical characteristics of the reaction products are provided. The X-ray structural analyses of three cycloadducts were done and obtained results were compared with properties of reported N,N'-bicyclic systems those displayed conformational similarity. Antibacterial activities of all products against two Gram-positive and two Gram-negative bacterial strains were evaluated by the experimental methods. (c) 2018 Elsevier B.V. All rights reserved.
T2  - Journal of Organometallic Chemistry
T1  - Acryloylferrocene as a convenient precursor of tetrahydropyrazolopyrazolones: [3+2] cycloaddition with N,N′ -Cyclic azomethine imines
VL  - 860
SP  - 85
EP  - 97
DO  - 10.1016/j.jorganchem.2018.02.016
ER  - 
@article{
author = "Jovanović, Jovana P. and Novaković, Slađana B. and Bogdanović, Goran A. and Minić, Aleksandra and Pejović, Anka and Katanić, Jelena and Mihailović, Vladimir B. and Nastasijević, Branislav J. and Stevanović, Dragana D. and Damljanović, Ivan S.",
year = "2018",
url = "http://linkinghub.elsevier.com/retrieve/pii/S0022328X18301050, http://vinar.vin.bg.ac.rs/handle/123456789/7635",
abstract = "AlCl3-Catalyzed {[}3 + 2] dipolar cycloaddition of the N,N'-cyclic azomethine imines to the acryloylferrocene enabling access to the series of 5-substituted 6-ferrocenoyl tetrahydropyrazolo {[}1,2-a]pyrazol-1(5H)-ones. This facile methodology shows high substituent tolerance. Furthermore, easy chromatographic separations afford isolation of the pure diastereoisomers. Optimized reaction conditions, spectroscopic and electrochemical characteristics of the reaction products are provided. The X-ray structural analyses of three cycloadducts were done and obtained results were compared with properties of reported N,N'-bicyclic systems those displayed conformational similarity. Antibacterial activities of all products against two Gram-positive and two Gram-negative bacterial strains were evaluated by the experimental methods. (c) 2018 Elsevier B.V. All rights reserved.",
journal = "Journal of Organometallic Chemistry",
title = "Acryloylferrocene as a convenient precursor of tetrahydropyrazolopyrazolones: [3+2] cycloaddition with N,N′ -Cyclic azomethine imines",
volume = "860",
pages = "85-97",
doi = "10.1016/j.jorganchem.2018.02.016"
}
Jovanović, J. P., Novaković, S. B., Bogdanović, G. A., Minić, A., Pejović, A., Katanić, J., Mihailović, V. B., Nastasijević, B. J., Stevanović, D. D.,& Damljanović, I. S. (2018). Acryloylferrocene as a convenient precursor of tetrahydropyrazolopyrazolones: [3+2] cycloaddition with N,N′ -Cyclic azomethine imines.
Journal of Organometallic Chemistry, 860, 85-97.
https://doi.org/10.1016/j.jorganchem.2018.02.016
Jovanović JP, Novaković SB, Bogdanović GA, Minić A, Pejović A, Katanić J, Mihailović VB, Nastasijević BJ, Stevanović DD, Damljanović IS. Acryloylferrocene as a convenient precursor of tetrahydropyrazolopyrazolones: [3+2] cycloaddition with N,N′ -Cyclic azomethine imines. Journal of Organometallic Chemistry. 2018;860:85-97
Jovanović Jovana P., Novaković Slađana B., Bogdanović Goran A., Minić Aleksandra, Pejović Anka, Katanić Jelena, Mihailović Vladimir B., Nastasijević Branislav J., Stevanović Dragana D., Damljanović Ivan S., "Acryloylferrocene as a convenient precursor of tetrahydropyrazolopyrazolones: [3+2] cycloaddition with N,N′ -Cyclic azomethine imines" Journal of Organometallic Chemistry, 860 (2018):85-97,
https://doi.org/10.1016/j.jorganchem.2018.02.016 .
4
6
7

DNA binding, antibacterial and antifungal activities of copper(II) complexes with some S-alkenyl derivatives of thiosalicylic acid

Tomovic, Dusan Lj.; Bukonjic, Andriana M.; Jevtic, Verica V.; Ratkovic, Zoran R.; Bogojeski, Jovana V.; Dekovic, Ana; Radojevic, Ivana D.; Comic, Ljiljana R.; Novaković, Slađana B.; Bogdanović, Goran A.; Trifunovic, Srecko R.; Radic, Gordana P.; Cupara, Snezana

(2018)

TY  - JOUR
AU  - Tomovic, Dusan Lj.
AU  - Bukonjic, Andriana M.
AU  - Jevtic, Verica V.
AU  - Ratkovic, Zoran R.
AU  - Bogojeski, Jovana V.
AU  - Dekovic, Ana
AU  - Radojevic, Ivana D.
AU  - Comic, Ljiljana R.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Trifunovic, Srecko R.
AU  - Radic, Gordana P.
AU  - Cupara, Snezana
PY  - 2018
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1954
AB  - The biological activities of two binuclear copper(II) complexes containing S-alkenyl derivatives of thiosalicylic acid are reported [alkenyl = propenyl (L1), isobutenyl (L2)]. The structure of the complex with the S-isobutenyl derivative (C2) was confirmed by single-crystal X-ray structure analysis, which revealed that the structure consists of centrosymmetric, dinuclear complex molecules [Cu-2(S-i-butenyl-thiosal)(4)(DMSO)(2)] containing two Cu(II) centers bridged by four S-isobutyl-thiosalicylate ligands in a paddle-wheel type structure. The Cu(II) atom is situated in a distorted square-pyramidal environment formed by carboxylate oxygen atoms in the basal plane and a DMSO ligand in the axial position. The reactivities of the complexes toward guanosine-5-monophosphate (5-GMP) were investigated. Complex C2 ([Cu-2(S-i-butenyl-thiosal)(4)(H2O)(2)]) reacted more rapidly with 5-GMP than complex C1. The interactions of complexes C1 and C2 with calf thymus DNA (CT-DNA) were examined by absorption (UV-Vis) and emission spectral studies (ethidium bromide displacement studies), revealing good DNA interaction abilities. The antimicrobial activities of the free ligands and their complexes were tested by microdilution method, and both minimal inhibitory and microbicidal concentrations were determined. All the tested substances demonstrated selective and moderate antibacterial activity on gram-positive bacteria, but low antibacterial activity on gram-negative bacteria. Also, the tested substances demonstrated low antifungal activity.
T2  - Transition Metal Chemistry
T1  - DNA binding, antibacterial and antifungal activities of copper(II) complexes with some S-alkenyl derivatives of thiosalicylic acid
VL  - 43
IS  - 2
SP  - 137
EP  - 148
DO  - 10.1007/s11243-018-0201-0
ER  - 
@article{
author = "Tomovic, Dusan Lj. and Bukonjic, Andriana M. and Jevtic, Verica V. and Ratkovic, Zoran R. and Bogojeski, Jovana V. and Dekovic, Ana and Radojevic, Ivana D. and Comic, Ljiljana R. and Novaković, Slađana B. and Bogdanović, Goran A. and Trifunovic, Srecko R. and Radic, Gordana P. and Cupara, Snezana",
year = "2018",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1954",
abstract = "The biological activities of two binuclear copper(II) complexes containing S-alkenyl derivatives of thiosalicylic acid are reported [alkenyl = propenyl (L1), isobutenyl (L2)]. The structure of the complex with the S-isobutenyl derivative (C2) was confirmed by single-crystal X-ray structure analysis, which revealed that the structure consists of centrosymmetric, dinuclear complex molecules [Cu-2(S-i-butenyl-thiosal)(4)(DMSO)(2)] containing two Cu(II) centers bridged by four S-isobutyl-thiosalicylate ligands in a paddle-wheel type structure. The Cu(II) atom is situated in a distorted square-pyramidal environment formed by carboxylate oxygen atoms in the basal plane and a DMSO ligand in the axial position. The reactivities of the complexes toward guanosine-5-monophosphate (5-GMP) were investigated. Complex C2 ([Cu-2(S-i-butenyl-thiosal)(4)(H2O)(2)]) reacted more rapidly with 5-GMP than complex C1. The interactions of complexes C1 and C2 with calf thymus DNA (CT-DNA) were examined by absorption (UV-Vis) and emission spectral studies (ethidium bromide displacement studies), revealing good DNA interaction abilities. The antimicrobial activities of the free ligands and their complexes were tested by microdilution method, and both minimal inhibitory and microbicidal concentrations were determined. All the tested substances demonstrated selective and moderate antibacterial activity on gram-positive bacteria, but low antibacterial activity on gram-negative bacteria. Also, the tested substances demonstrated low antifungal activity.",
journal = "Transition Metal Chemistry",
title = "DNA binding, antibacterial and antifungal activities of copper(II) complexes with some S-alkenyl derivatives of thiosalicylic acid",
volume = "43",
number = "2",
pages = "137-148",
doi = "10.1007/s11243-018-0201-0"
}
Tomovic, D. Lj., Bukonjic, A. M., Jevtic, V. V., Ratkovic, Z. R., Bogojeski, J. V., Dekovic, A., Radojevic, I. D., Comic, L. R., Novaković, S. B., Bogdanović, G. A., Trifunovic, S. R., Radic, G. P.,& Cupara, S. (2018). DNA binding, antibacterial and antifungal activities of copper(II) complexes with some S-alkenyl derivatives of thiosalicylic acid.
Transition Metal Chemistry, 43(2), 137-148.
https://doi.org/10.1007/s11243-018-0201-0
Tomovic DL, Bukonjic AM, Jevtic VV, Ratkovic ZR, Bogojeski JV, Dekovic A, Radojevic ID, Comic LR, Novaković SB, Bogdanović GA, Trifunovic SR, Radic GP, Cupara S. DNA binding, antibacterial and antifungal activities of copper(II) complexes with some S-alkenyl derivatives of thiosalicylic acid. Transition Metal Chemistry. 2018;43(2):137-148
Tomovic Dusan Lj., Bukonjic Andriana M., Jevtic Verica V., Ratkovic Zoran R., Bogojeski Jovana V., Dekovic Ana, Radojevic Ivana D., Comic Ljiljana R., Novaković Slađana B., Bogdanović Goran A., Trifunovic Srecko R., Radic Gordana P., Cupara Snezana, "DNA binding, antibacterial and antifungal activities of copper(II) complexes with some S-alkenyl derivatives of thiosalicylic acid" Transition Metal Chemistry, 43, no. 2 (2018):137-148,
https://doi.org/10.1007/s11243-018-0201-0 .
2
1
2

Cytotoxic and Antimicrobial Activity of Dehydrozingerone based Cyclopropyl Derivatives

Burmudzija, Adrijana Z.; Muskinja, Jovana M.; Kosanic, Marijana M.; Rankovic, Branislav R.; Novaković, Slađana B.; Dordevic, Snezana B.; Stanojković, Tatjana P.; Baskic, Dejan D.; Ratkovic, Zoran R.

(2017)

TY  - JOUR
AU  - Burmudzija, Adrijana Z.
AU  - Muskinja, Jovana M.
AU  - Kosanic, Marijana M.
AU  - Rankovic, Branislav R.
AU  - Novaković, Slađana B.
AU  - Dordevic, Snezana B.
AU  - Stanojković, Tatjana P.
AU  - Baskic, Dejan D.
AU  - Ratkovic, Zoran R.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1680
AB  - A small series of 1-acetyl-2-(4-alkoxy-3-methoxyphenyl)cyclopropanes was prepared, starting from dehydrozingerone (4-(4-hydroxy-3-methoxyphenyl)-3-buten-2-one) and its O-alkyl derivatives. Their microbiological activities toward some strains of bacteria and fungi were tested, as well as their in vitro cytotoxic activity against some cancer cell lines (HeLa, LS174 and A549). All synthesized compounds showed significant antimicrobial activity and expressed cytotoxic activity against tested carcinoma cell lines, but they showed no significant influence on normal cell line (MRC5). Butyl derivative is the most active on HeLa cells (IC50 = 8.63 m), while benzyl one is active against LS174 and A549 cell lines (IC50 = 10.17 and 12.15 m, respectively).
T2  - Chemistry and Biodiversity
T1  - Cytotoxic and Antimicrobial Activity of Dehydrozingerone based Cyclopropyl Derivatives
VL  - 14
IS  - 8
DO  - 10.1002/cbdv.201700077
ER  - 
@article{
author = "Burmudzija, Adrijana Z. and Muskinja, Jovana M. and Kosanic, Marijana M. and Rankovic, Branislav R. and Novaković, Slađana B. and Dordevic, Snezana B. and Stanojković, Tatjana P. and Baskic, Dejan D. and Ratkovic, Zoran R.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1680",
abstract = "A small series of 1-acetyl-2-(4-alkoxy-3-methoxyphenyl)cyclopropanes was prepared, starting from dehydrozingerone (4-(4-hydroxy-3-methoxyphenyl)-3-buten-2-one) and its O-alkyl derivatives. Their microbiological activities toward some strains of bacteria and fungi were tested, as well as their in vitro cytotoxic activity against some cancer cell lines (HeLa, LS174 and A549). All synthesized compounds showed significant antimicrobial activity and expressed cytotoxic activity against tested carcinoma cell lines, but they showed no significant influence on normal cell line (MRC5). Butyl derivative is the most active on HeLa cells (IC50 = 8.63 m), while benzyl one is active against LS174 and A549 cell lines (IC50 = 10.17 and 12.15 m, respectively).",
journal = "Chemistry and Biodiversity",
title = "Cytotoxic and Antimicrobial Activity of Dehydrozingerone based Cyclopropyl Derivatives",
volume = "14",
number = "8",
doi = "10.1002/cbdv.201700077"
}
Burmudzija, A. Z., Muskinja, J. M., Kosanic, M. M., Rankovic, B. R., Novaković, S. B., Dordevic, S. B., Stanojković, T. P., Baskic, D. D.,& Ratkovic, Z. R. (2017). Cytotoxic and Antimicrobial Activity of Dehydrozingerone based Cyclopropyl Derivatives.
Chemistry and Biodiversity, 14(8).
https://doi.org/10.1002/cbdv.201700077
Burmudzija AZ, Muskinja JM, Kosanic MM, Rankovic BR, Novaković SB, Dordevic SB, Stanojković TP, Baskic DD, Ratkovic ZR. Cytotoxic and Antimicrobial Activity of Dehydrozingerone based Cyclopropyl Derivatives. Chemistry and Biodiversity. 2017;14(8)
Burmudzija Adrijana Z., Muskinja Jovana M., Kosanic Marijana M., Rankovic Branislav R., Novaković Slađana B., Dordevic Snezana B., Stanojković Tatjana P., Baskic Dejan D., Ratkovic Zoran R., "Cytotoxic and Antimicrobial Activity of Dehydrozingerone based Cyclopropyl Derivatives" Chemistry and Biodiversity, 14, no. 8 (2017),
https://doi.org/10.1002/cbdv.201700077 .
2
3
5

The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4

Jacimovic, Zeljko K.; Kosovic, Milica; Bogdanović, Goran A.; Novaković, Slađana B.; Giester, Gerald; Bigovie, Miljan

(2017)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Kosovic, Milica
AU  - Bogdanović, Goran A.
AU  - Novaković, Slađana B.
AU  - Giester, Gerald
AU  - Bigovie, Miljan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1639
AB  - C13H10F3N3O4, triclinic, P (1) over bar (no. 2), a = 7.0524(14) angstrom, b = 7.8044(16) angstrom, c = 12.954(3) angstrom, alpha = 97.93(3)degrees, beta = 96.29(3)degrees, gamma = 100.11(3)degrees, V = 688.6(3) angstrom(3), Z = 2, R-gt(F) = 0.0478, wR(ref)(F-2) = 0.1140, T = 200 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4
VL  - 232
IS  - 4
SP  - 651
EP  - 653
DO  - 10.1515/ncrs-2016-0393
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Kosovic, Milica and Bogdanović, Goran A. and Novaković, Slađana B. and Giester, Gerald and Bigovie, Miljan",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1639",
abstract = "C13H10F3N3O4, triclinic, P (1) over bar (no. 2), a = 7.0524(14) angstrom, b = 7.8044(16) angstrom, c = 12.954(3) angstrom, alpha = 97.93(3)degrees, beta = 96.29(3)degrees, gamma = 100.11(3)degrees, V = 688.6(3) angstrom(3), Z = 2, R-gt(F) = 0.0478, wR(ref)(F-2) = 0.1140, T = 200 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4",
volume = "232",
number = "4",
pages = "651-653",
doi = "10.1515/ncrs-2016-0393"
}
Jacimovic, Z. K., Kosovic, M., Bogdanović, G. A., Novaković, S. B., Giester, G.,& Bigovie, M. (2017). The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4.
Zeitschrift fur Kristallographie = New Crystal Structures, 232(4), 651-653.
https://doi.org/10.1515/ncrs-2016-0393
Jacimovic ZK, Kosovic M, Bogdanović GA, Novaković SB, Giester G, Bigovie M. The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4. Zeitschrift fur Kristallographie = New Crystal Structures. 2017;232(4):651-653
Jacimovic Zeljko K., Kosovic Milica, Bogdanović Goran A., Novaković Slađana B., Giester Gerald, Bigovie Miljan, "The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4" Zeitschrift fur Kristallographie = New Crystal Structures, 232, no. 4 (2017):651-653,
https://doi.org/10.1515/ncrs-2016-0393 .
2
1
2

Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O

Jacimovic, Zeljko K.; Kosovic, Milica; Novaković, Slađana B.; Bogdanović, Goran A.; Giester, Gerald; Kastratović, Vlatko

(2017)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Kosovic, Milica
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Giester, Gerald
AU  - Kastratović, Vlatko
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1602
AB  - C9H7BrN2O, triclinic, C2/c (no. 15), a = 16.255(3) angstrom, b = 4.4119(9) angstrom, c = 25.923(5) angstrom, beta = 107.99(3)degrees, V = 1768.2(7) angstrom(3), Z = 8, R-gt(F) = 0.0450, wR(ref)(F-2) = 0.0960, T= 150 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O
VL  - 232
IS  - 3
SP  - 507
EP  - 509
DO  - 10.1515/ncrs-2016-0392
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Kosovic, Milica and Novaković, Slađana B. and Bogdanović, Goran A. and Giester, Gerald and Kastratović, Vlatko",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1602",
abstract = "C9H7BrN2O, triclinic, C2/c (no. 15), a = 16.255(3) angstrom, b = 4.4119(9) angstrom, c = 25.923(5) angstrom, beta = 107.99(3)degrees, V = 1768.2(7) angstrom(3), Z = 8, R-gt(F) = 0.0450, wR(ref)(F-2) = 0.0960, T= 150 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O",
volume = "232",
number = "3",
pages = "507-509",
doi = "10.1515/ncrs-2016-0392"
}
Jacimovic, Z. K., Kosovic, M., Novaković, S. B., Bogdanović, G. A., Giester, G.,& Kastratović, V. (2017). Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O.
Zeitschrift fur Kristallographie = New Crystal Structures, 232(3), 507-509.
https://doi.org/10.1515/ncrs-2016-0392
Jacimovic ZK, Kosovic M, Novaković SB, Bogdanović GA, Giester G, Kastratović V. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O. Zeitschrift fur Kristallographie = New Crystal Structures. 2017;232(3):507-509
Jacimovic Zeljko K., Kosovic Milica, Novaković Slađana B., Bogdanović Goran A., Giester Gerald, Kastratović Vlatko, "Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O" Zeitschrift fur Kristallographie = New Crystal Structures, 232, no. 3 (2017):507-509,
https://doi.org/10.1515/ncrs-2016-0392 .

Charge Density Analysis of 2-Pyridineformamide N(4)-Methylthiosemicarbazone (Z =4): Role of an Enhanced N-H center dot center dot center dot S Thioureido Dimer

Francuski, Bojana; Novaković, Slađana B.; Francuski, Đorđe D.; Bogdanović, Goran A.

(2017)

TY  - JOUR
AU  - Francuski, Bojana
AU  - Novaković, Slađana B.
AU  - Francuski, Đorđe D.
AU  - Bogdanović, Goran A.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1601
AB  - Charge density distribution in 2-pyridineformamide N(4)-methylthiosemicarbazone (TSC4) has been determined using high-resolution X-ray diffraction data (100 K) and Hansen-Coppens multipole formalism. The results are interpreted in terms of Baders quantum theory of atoms in molecules (QTAIM), electrostatic potential analysis, and theoretical calculations (CRYSTAL09). The study highlights the molecular diSsimilarity at the electronic level. The N-H center dot center dot center dot S interactions have a dominant role in Stabilization of the TSC4 crystal Structure. As each of the four S acceptors simultaneously engages in several interactions, the focus of study is on the lone pairs electron density of these acceptors which is particularly able to adjust to the various spatial distributions of the interacting donor groups. The main structural feature of TSC4 is the formation of specific N-H center dot center dot center dot S bonded dimers between two pairs of independent molecules. These dimers are the main building block in the orkstal structure, and with the two additional N-H center dot center dot center dot S contacts they represent a significant enhancement of a typical R-2(2)(8) dirtier synthon which dominates among the thioureido-based crystal structures. Two TSC4 dimers are structurally very similar and exhibit considerable cohesive energy (-20.8 and 21.4 kcal/mol). This: type of dimer is the only structural motif that is common for S acceptors of all four independent molecules.
T2  - Crystal Growth and Design
T1  - Charge Density Analysis of 2-Pyridineformamide N(4)-Methylthiosemicarbazone (Z =4): Role of an Enhanced N-H center dot center dot center dot S Thioureido Dimer
VL  - 17
IS  - 6
SP  - 2993
EP  - 3004
DO  - 10.1021/acs.cgd.6b01620
ER  - 
@article{
author = "Francuski, Bojana and Novaković, Slađana B. and Francuski, Đorđe D. and Bogdanović, Goran A.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1601",
abstract = "Charge density distribution in 2-pyridineformamide N(4)-methylthiosemicarbazone (TSC4) has been determined using high-resolution X-ray diffraction data (100 K) and Hansen-Coppens multipole formalism. The results are interpreted in terms of Baders quantum theory of atoms in molecules (QTAIM), electrostatic potential analysis, and theoretical calculations (CRYSTAL09). The study highlights the molecular diSsimilarity at the electronic level. The N-H center dot center dot center dot S interactions have a dominant role in Stabilization of the TSC4 crystal Structure. As each of the four S acceptors simultaneously engages in several interactions, the focus of study is on the lone pairs electron density of these acceptors which is particularly able to adjust to the various spatial distributions of the interacting donor groups. The main structural feature of TSC4 is the formation of specific N-H center dot center dot center dot S bonded dimers between two pairs of independent molecules. These dimers are the main building block in the orkstal structure, and with the two additional N-H center dot center dot center dot S contacts they represent a significant enhancement of a typical R-2(2)(8) dirtier synthon which dominates among the thioureido-based crystal structures. Two TSC4 dimers are structurally very similar and exhibit considerable cohesive energy (-20.8 and 21.4 kcal/mol). This: type of dimer is the only structural motif that is common for S acceptors of all four independent molecules.",
journal = "Crystal Growth and Design",
title = "Charge Density Analysis of 2-Pyridineformamide N(4)-Methylthiosemicarbazone (Z =4): Role of an Enhanced N-H center dot center dot center dot S Thioureido Dimer",
volume = "17",
number = "6",
pages = "2993-3004",
doi = "10.1021/acs.cgd.6b01620"
}
Francuski, B., Novaković, S. B., Francuski, Đ. D.,& Bogdanović, G. A. (2017). Charge Density Analysis of 2-Pyridineformamide N(4)-Methylthiosemicarbazone (Z =4): Role of an Enhanced N-H center dot center dot center dot S Thioureido Dimer.
Crystal Growth and Design, 17(6), 2993-3004.
https://doi.org/10.1021/acs.cgd.6b01620
Francuski B, Novaković SB, Francuski ĐD, Bogdanović GA. Charge Density Analysis of 2-Pyridineformamide N(4)-Methylthiosemicarbazone (Z =4): Role of an Enhanced N-H center dot center dot center dot S Thioureido Dimer. Crystal Growth and Design. 2017;17(6):2993-3004
Francuski Bojana, Novaković Slađana B., Francuski Đorđe D., Bogdanović Goran A., "Charge Density Analysis of 2-Pyridineformamide N(4)-Methylthiosemicarbazone (Z =4): Role of an Enhanced N-H center dot center dot center dot S Thioureido Dimer" Crystal Growth and Design, 17, no. 6 (2017):2993-3004,
https://doi.org/10.1021/acs.cgd.6b01620 .
1
1
1

Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O (vol 232, pg 507, 2017)

Jaćimović, Željko K.; Kosovic, Milica; Novaković, Slađana B.; Bogdanović, Goran A.; Giester, Gerald; Kastratović, Vlatko

(2017)

TY  - BOOK
AU  - Jaćimović, Željko K.
AU  - Kosovic, Milica
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Giester, Gerald
AU  - Kastratović, Vlatko
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1640
AB  - C9H7BrN2O, monoclinic, C2/c (no. 15), a = 16.255(3) angstrom, b = 4.4119(9) angstrom, c = 25.923(5) angstrom, beta = 107.99(3)degrees, V = 1768.2(7) angstrom(3), Z = 8, R-gt(F) = 0.0450, wR(ref)(F-2) = 0.0960, T = 150 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O (vol 232, pg 507, 2017)
VL  - 232
IS  - 4
SP  - 701
EP  - 701
DO  - 10.1515/ncrs-2017-0146
ER  - 
@book{
author = "Jaćimović, Željko K. and Kosovic, Milica and Novaković, Slađana B. and Bogdanović, Goran A. and Giester, Gerald and Kastratović, Vlatko",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1640",
abstract = "C9H7BrN2O, monoclinic, C2/c (no. 15), a = 16.255(3) angstrom, b = 4.4119(9) angstrom, c = 25.923(5) angstrom, beta = 107.99(3)degrees, V = 1768.2(7) angstrom(3), Z = 8, R-gt(F) = 0.0450, wR(ref)(F-2) = 0.0960, T = 150 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O (vol 232, pg 507, 2017)",
volume = "232",
number = "4",
pages = "701-701",
doi = "10.1515/ncrs-2017-0146"
}
Jaćimović, Ž. K., Kosovic, M., Novaković, S. B., Bogdanović, G. A., Giester, G.,& Kastratović, V. (2017). Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O (vol 232, pg 507, 2017).
Zeitschrift fur Kristallographie = New Crystal Structures, 232(4), 701-701.
https://doi.org/10.1515/ncrs-2017-0146
Jaćimović ŽK, Kosovic M, Novaković SB, Bogdanović GA, Giester G, Kastratović V. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O (vol 232, pg 507, 2017). Zeitschrift fur Kristallographie = New Crystal Structures. 2017;232(4):701-701
Jaćimović Željko K., Kosovic Milica, Novaković Slađana B., Bogdanović Goran A., Giester Gerald, Kastratović Vlatko, "Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O (vol 232, pg 507, 2017)" Zeitschrift fur Kristallographie = New Crystal Structures, 232, no. 4 (2017):701-701,
https://doi.org/10.1515/ncrs-2017-0146 .

Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds

Jacimovic, Zeljko K.; Giester, Gerald; Kosovic, Milica; Bogdanović, Goran A.; Novaković, Slađana B.; Leovac, Vukadin M.; Latinović, Nedeljko; Hollo, Berta Barta; Szecsenyi, Katalin Meszaros

(2017)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Giester, Gerald
AU  - Kosovic, Milica
AU  - Bogdanović, Goran A.
AU  - Novaković, Slađana B.
AU  - Leovac, Vukadin M.
AU  - Latinović, Nedeljko
AU  - Hollo, Berta Barta
AU  - Szecsenyi, Katalin Meszaros
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1428
AB  - New nickel(II) and copper(II) coordination compounds were synthesized by the reaction of N-(benzyloxycarbonyl)-1H-pyrazole-1-carboxamidine ligand (HL) with Ni(II) and Cu(II) acetate in methanolic solution. The crystal and molecular structures of the complexes as well as those of the ligand were determined by single-crystal X-ray structure analysis. The octahedral surrounding around the metal centers in the isostructural complexes [ML2(MeOH)(2)], M = Ni(II), Cu(II), MeOH = methanol, is established by the bidentate coordination of two ligand molecules through the pyrazole nitrogen and the deprotonated nitrogen atom of the carboxamidine group along with the oxygen atoms from two MeOH molecules. Despite that the molecular structure of the complexes was determined by X-ray structure analysis, in the FT-IR spectra of the compounds the characteristic bands for MeOH were missing. By coupled TG-MS measurements, it was found that compounds during the transport and storage exchanged MeOH by water molecules. The amount of the water was calculated on the basis of thermogravimetric data. The antifungal activity of the compounds was tested against fungi Ph. viticola and B. dothidea and compared to that of a commercial fungicide. Depending on the fungi and on the structure, the compounds showed different, but somewhat lower activity than the commercial fungicide.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds
VL  - 127
IS  - 2
SP  - 1501
EP  - 1509
DO  - 10.1007/s10973-016-5549-9
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Giester, Gerald and Kosovic, Milica and Bogdanović, Goran A. and Novaković, Slađana B. and Leovac, Vukadin M. and Latinović, Nedeljko and Hollo, Berta Barta and Szecsenyi, Katalin Meszaros",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1428",
abstract = "New nickel(II) and copper(II) coordination compounds were synthesized by the reaction of N-(benzyloxycarbonyl)-1H-pyrazole-1-carboxamidine ligand (HL) with Ni(II) and Cu(II) acetate in methanolic solution. The crystal and molecular structures of the complexes as well as those of the ligand were determined by single-crystal X-ray structure analysis. The octahedral surrounding around the metal centers in the isostructural complexes [ML2(MeOH)(2)], M = Ni(II), Cu(II), MeOH = methanol, is established by the bidentate coordination of two ligand molecules through the pyrazole nitrogen and the deprotonated nitrogen atom of the carboxamidine group along with the oxygen atoms from two MeOH molecules. Despite that the molecular structure of the complexes was determined by X-ray structure analysis, in the FT-IR spectra of the compounds the characteristic bands for MeOH were missing. By coupled TG-MS measurements, it was found that compounds during the transport and storage exchanged MeOH by water molecules. The amount of the water was calculated on the basis of thermogravimetric data. The antifungal activity of the compounds was tested against fungi Ph. viticola and B. dothidea and compared to that of a commercial fungicide. Depending on the fungi and on the structure, the compounds showed different, but somewhat lower activity than the commercial fungicide.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds",
volume = "127",
number = "2",
pages = "1501-1509",
doi = "10.1007/s10973-016-5549-9"
}
Jacimovic, Z. K., Giester, G., Kosovic, M., Bogdanović, G. A., Novaković, S. B., Leovac, V. M., Latinović, N., Hollo, B. B.,& Szecsenyi, K. M. (2017). Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds.
Journal of Thermal Analysis and Calorimetry, 127(2), 1501-1509.
https://doi.org/10.1007/s10973-016-5549-9
Jacimovic ZK, Giester G, Kosovic M, Bogdanović GA, Novaković SB, Leovac VM, Latinović N, Hollo BB, Szecsenyi KM. Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds. Journal of Thermal Analysis and Calorimetry. 2017;127(2):1501-1509
Jacimovic Zeljko K., Giester Gerald, Kosovic Milica, Bogdanović Goran A., Novaković Slađana B., Leovac Vukadin M., Latinović Nedeljko, Hollo Berta Barta, Szecsenyi Katalin Meszaros, "Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds" Journal of Thermal Analysis and Calorimetry, 127, no. 2 (2017):1501-1509,
https://doi.org/10.1007/s10973-016-5549-9 .
10
7
9

Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study

Xu, Xiao; Spasojević-de Bire, Anne; Ghermani, Nour Eddine; Wei, Yongge; Novaković, Slađana B.; Bosnjakovic-Pavlovic, Nada; Wu, Pingfan

(2017)

TY  - JOUR
AU  - Xu, Xiao
AU  - Spasojević-de Bire, Anne
AU  - Ghermani, Nour Eddine
AU  - Wei, Yongge
AU  - Novaković, Slađana B.
AU  - Bosnjakovic-Pavlovic, Nada
AU  - Wu, Pingfan
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1649
AB  - A high resolution X-ray diffraction study has been carried out on [(C4H9)(4)N](2) [V6O13{(OCH2)(3)CCH2OCCH2CH3}(2)] (V6-C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.
T2  - Physical Chemistry Chemical Physics
T1  - Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study
VL  - 19
IS  - 28
SP  - 18162
EP  - 18166
DO  - 10.1039/c7cp01840a
ER  - 
@article{
author = "Xu, Xiao and Spasojević-de Bire, Anne and Ghermani, Nour Eddine and Wei, Yongge and Novaković, Slađana B. and Bosnjakovic-Pavlovic, Nada and Wu, Pingfan",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1649",
abstract = "A high resolution X-ray diffraction study has been carried out on [(C4H9)(4)N](2) [V6O13{(OCH2)(3)CCH2OCCH2CH3}(2)] (V6-C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.",
journal = "Physical Chemistry Chemical Physics",
title = "Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study",
volume = "19",
number = "28",
pages = "18162-18166",
doi = "10.1039/c7cp01840a"
}
Xu, X., Spasojević-de Bire, A., Ghermani, N. E., Wei, Y., Novaković, S. B., Bosnjakovic-Pavlovic, N.,& Wu, P. (2017). Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study.
Physical Chemistry Chemical Physics, 19(28), 18162-18166.
https://doi.org/10.1039/c7cp01840a
Xu X, Spasojević-de Bire A, Ghermani NE, Wei Y, Novaković SB, Bosnjakovic-Pavlovic N, Wu P. Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study. Physical Chemistry Chemical Physics. 2017;19(28):18162-18166
Xu Xiao, Spasojević-de Bire Anne, Ghermani Nour Eddine, Wei Yongge, Novaković Slađana B., Bosnjakovic-Pavlovic Nada, Wu Pingfan, "Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study" Physical Chemistry Chemical Physics, 19, no. 28 (2017):18162-18166,
https://doi.org/10.1039/c7cp01840a .
1
7
7
7

Antibacterial, antibiofilm and antioxidant screening of copper(II)-complexes with some S-alkyl derivatives of thiosalicylic acid. Crystal structure of the binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid

Bukonjic, Andriana M.; Tomovic, Dugan Lj.; Nikolic, Milos V.; Mijajlovic, Marina Z.; Jevtic, Verica V.; Ratkovic, Zoran R.; Novaković, Slađana B.; Bogdanović, Goran A.; Radojevic, Ivana D.; Maksimovic, Jovana Z.; Vasic, Sava M.; Comic, Ljiljana R.; Trifunovic, Srecko R.; Radic, Gordana P.

(2017)

TY  - JOUR
AU  - Bukonjic, Andriana M.
AU  - Tomovic, Dugan Lj.
AU  - Nikolic, Milos V.
AU  - Mijajlovic, Marina Z.
AU  - Jevtic, Verica V.
AU  - Ratkovic, Zoran R.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Radojevic, Ivana D.
AU  - Maksimovic, Jovana Z.
AU  - Vasic, Sava M.
AU  - Comic, Ljiljana R.
AU  - Trifunovic, Srecko R.
AU  - Radic, Gordana P.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1296
AB  - The spectroscopically predicted structure of the obtained copper(II)-complex with S-propyl derivative of thiosalicylic acid was confirmed by X-ray structural study. The binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid crystallized in two polymorphic forms with main structural difference in the orientation of phenyl rings relative to corresponding carboxylate groups. The antibacterial activity was tested determining the minimum inhibitory concentration (MIC) and the minimum bactericidal concentration (MBC) by using microdilution method. The influence on bacterial biofilm formation was determined by tissue culture plate method. In general, the copper(II)-complexes manifested a selective and moderate activity. The most sensitive bacteria to the effects of Cu(II)-complexes was a clinical isolate of Pseudomonas aeruginosa. For this bacteria MIC and biofilm inhibitory concentration (BIC) values for all tested complexes were in the range or better than the positive control, doxycycline. Also, for the established biofilm of clinical isolate Staphylococcus aureus, BIC values for the copper(II)-complex with S-ethyl derivative of thiosalicylic acid, [Cu-2(S-et-thiosal)(4)(H2O)(2)] (C3) and copper(II)-complex with S-butyl derivative of thiosalicylic acid, [Cu-2(S-bu-thiosal)(4)(H2O)(2)] (C5) were in range or better than the positive control. All the complexes acted better against Gram-positive bacteria (Staphylococcus aureus and Staphylococcus aureus ATCC 25923) than Gram-negative bacteria (Proteus mirabilis ATCC 12453, Pseudomonas aeruginosa, and P. aeruginosa. ATCC 27855). The complexes showed weak antioxidative properties tested by two methods (1,1-diphenyl-2-picrylhydrazyl (DPPH) and reducing power assay). (C) 2016 Elsevier B.V. All rights reserved.
T2  - Journal of Molecular Structure
T1  - Antibacterial, antibiofilm and antioxidant screening of copper(II)-complexes with some S-alkyl derivatives of thiosalicylic acid. Crystal structure of the binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid
VL  - 1128
SP  - 330
EP  - 337
DO  - 10.1016/j.molstruc.2016.08.086
ER  - 
@article{
author = "Bukonjic, Andriana M. and Tomovic, Dugan Lj. and Nikolic, Milos V. and Mijajlovic, Marina Z. and Jevtic, Verica V. and Ratkovic, Zoran R. and Novaković, Slađana B. and Bogdanović, Goran A. and Radojevic, Ivana D. and Maksimovic, Jovana Z. and Vasic, Sava M. and Comic, Ljiljana R. and Trifunovic, Srecko R. and Radic, Gordana P.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1296",
abstract = "The spectroscopically predicted structure of the obtained copper(II)-complex with S-propyl derivative of thiosalicylic acid was confirmed by X-ray structural study. The binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid crystallized in two polymorphic forms with main structural difference in the orientation of phenyl rings relative to corresponding carboxylate groups. The antibacterial activity was tested determining the minimum inhibitory concentration (MIC) and the minimum bactericidal concentration (MBC) by using microdilution method. The influence on bacterial biofilm formation was determined by tissue culture plate method. In general, the copper(II)-complexes manifested a selective and moderate activity. The most sensitive bacteria to the effects of Cu(II)-complexes was a clinical isolate of Pseudomonas aeruginosa. For this bacteria MIC and biofilm inhibitory concentration (BIC) values for all tested complexes were in the range or better than the positive control, doxycycline. Also, for the established biofilm of clinical isolate Staphylococcus aureus, BIC values for the copper(II)-complex with S-ethyl derivative of thiosalicylic acid, [Cu-2(S-et-thiosal)(4)(H2O)(2)] (C3) and copper(II)-complex with S-butyl derivative of thiosalicylic acid, [Cu-2(S-bu-thiosal)(4)(H2O)(2)] (C5) were in range or better than the positive control. All the complexes acted better against Gram-positive bacteria (Staphylococcus aureus and Staphylococcus aureus ATCC 25923) than Gram-negative bacteria (Proteus mirabilis ATCC 12453, Pseudomonas aeruginosa, and P. aeruginosa. ATCC 27855). The complexes showed weak antioxidative properties tested by two methods (1,1-diphenyl-2-picrylhydrazyl (DPPH) and reducing power assay). (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Journal of Molecular Structure",
title = "Antibacterial, antibiofilm and antioxidant screening of copper(II)-complexes with some S-alkyl derivatives of thiosalicylic acid. Crystal structure of the binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid",
volume = "1128",
pages = "330-337",
doi = "10.1016/j.molstruc.2016.08.086"
}
Bukonjic, A. M., Tomovic, D. Lj., Nikolic, M. V., Mijajlovic, M. Z., Jevtic, V. V., Ratkovic, Z. R., Novaković, S. B., Bogdanović, G. A., Radojevic, I. D., Maksimovic, J. Z., Vasic, S. M., Comic, L. R., Trifunovic, S. R.,& Radic, G. P. (2017). Antibacterial, antibiofilm and antioxidant screening of copper(II)-complexes with some S-alkyl derivatives of thiosalicylic acid. Crystal structure of the binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid.
Journal of Molecular Structure, 1128, 330-337.
https://doi.org/10.1016/j.molstruc.2016.08.086
Bukonjic AM, Tomovic DL, Nikolic MV, Mijajlovic MZ, Jevtic VV, Ratkovic ZR, Novaković SB, Bogdanović GA, Radojevic ID, Maksimovic JZ, Vasic SM, Comic LR, Trifunovic SR, Radic GP. Antibacterial, antibiofilm and antioxidant screening of copper(II)-complexes with some S-alkyl derivatives of thiosalicylic acid. Crystal structure of the binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid. Journal of Molecular Structure. 2017;1128:330-337
Bukonjic Andriana M., Tomovic Dugan Lj., Nikolic Milos V., Mijajlovic Marina Z., Jevtic Verica V., Ratkovic Zoran R., Novaković Slađana B., Bogdanović Goran A., Radojevic Ivana D., Maksimovic Jovana Z., Vasic Sava M., Comic Ljiljana R., Trifunovic Srecko R., Radic Gordana P., "Antibacterial, antibiofilm and antioxidant screening of copper(II)-complexes with some S-alkyl derivatives of thiosalicylic acid. Crystal structure of the binuclear copper(II)-complex with S-propyl derivative of thiosalicylic acid" Journal of Molecular Structure, 1128 (2017):330-337,
https://doi.org/10.1016/j.molstruc.2016.08.086 .
13
13
13

Cytotoxicity of Platinum(Iv) and Palladium(Ii) Complexes with Meso-1,2-Diphenyl-Ethylenediamine-N,N -Di-3-Propanoic Acid. Crystal Structure of [Pd(1,2-Dpheddp)] Complex

Mijajlovic, Marina Z.; Nikolic, Milos V.; Jevtic, Verica V.; Ratkovic, Zoran R.; Milovanovic, Jelena; Arsenijević, Aleksandar; Stojanovic, Bojana; Novaković, Slađana B.; Bogdanović, Goran A.; Trifunovic, Srecko R.; Radic, Gordana P.

(2016)

TY  - JOUR
AU  - Mijajlovic, Marina Z.
AU  - Nikolic, Milos V.
AU  - Jevtic, Verica V.
AU  - Ratkovic, Zoran R.
AU  - Milovanovic, Jelena
AU  - Arsenijević, Aleksandar
AU  - Stojanovic, Bojana
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Trifunovic, Srecko R.
AU  - Radic, Gordana P.
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1166
AB  - The syntheses of tetradentate ligand, meso-1,2-diphenyl-ethylenediamine-N,N-di-3-propanoic acid (H-2-1,2-dpheddp) and corresponding platinum(IV) and palladium(II) complexes are reported here. The spectroscopically predicted structure of the obtained palladium(II) complex was confirmed by X-ray analysis. Singe crystals suitable for X-ray measurements were obtained by slow crystallization from a DMSO-water mixture. Cytotoxic effects of platinum(IV), palladium(II) complexes and cisplatin on the 4T1 and Bl6F1 cell lines were determined using the MTT colorimetric technique. The complexes showed a dose dependence on cytotoxic effect toward both cell lines. Both complexes were less active than cisplatin, the exception was concentrations above 62.5 mu M of platinum(IV) complex in the B16F1 cell line.
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Cytotoxicity of Platinum(Iv) and Palladium(Ii) Complexes with Meso-1,2-Diphenyl-Ethylenediamine-N,N -Di-3-Propanoic Acid. Crystal Structure of [Pd(1,2-Dpheddp)] Complex
VL  - 35
IS  - 1
SP  - 79
EP  - 86
DO  - 10.20450/mjcce.2016.729
ER  - 
@article{
author = "Mijajlovic, Marina Z. and Nikolic, Milos V. and Jevtic, Verica V. and Ratkovic, Zoran R. and Milovanovic, Jelena and Arsenijević, Aleksandar and Stojanovic, Bojana and Novaković, Slađana B. and Bogdanović, Goran A. and Trifunovic, Srecko R. and Radic, Gordana P.",
year = "2016",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1166",
abstract = "The syntheses of tetradentate ligand, meso-1,2-diphenyl-ethylenediamine-N,N-di-3-propanoic acid (H-2-1,2-dpheddp) and corresponding platinum(IV) and palladium(II) complexes are reported here. The spectroscopically predicted structure of the obtained palladium(II) complex was confirmed by X-ray analysis. Singe crystals suitable for X-ray measurements were obtained by slow crystallization from a DMSO-water mixture. Cytotoxic effects of platinum(IV), palladium(II) complexes and cisplatin on the 4T1 and Bl6F1 cell lines were determined using the MTT colorimetric technique. The complexes showed a dose dependence on cytotoxic effect toward both cell lines. Both complexes were less active than cisplatin, the exception was concentrations above 62.5 mu M of platinum(IV) complex in the B16F1 cell line.",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Cytotoxicity of Platinum(Iv) and Palladium(Ii) Complexes with Meso-1,2-Diphenyl-Ethylenediamine-N,N -Di-3-Propanoic Acid. Crystal Structure of [Pd(1,2-Dpheddp)] Complex",
volume = "35",
number = "1",
pages = "79-86",
doi = "10.20450/mjcce.2016.729"
}
Mijajlovic, M. Z., Nikolic, M. V., Jevtic, V. V., Ratkovic, Z. R., Milovanovic, J., Arsenijević, A., Stojanovic, B., Novaković, S. B., Bogdanović, G. A., Trifunovic, S. R.,& Radic, G. P. (2016). Cytotoxicity of Platinum(Iv) and Palladium(Ii) Complexes with Meso-1,2-Diphenyl-Ethylenediamine-N,N -Di-3-Propanoic Acid. Crystal Structure of [Pd(1,2-Dpheddp)] Complex.
Macedonian Journal of Chemistry and Chemical Engineering, 35(1), 79-86.
https://doi.org/10.20450/mjcce.2016.729
Mijajlovic MZ, Nikolic MV, Jevtic VV, Ratkovic ZR, Milovanovic J, Arsenijević A, Stojanovic B, Novaković SB, Bogdanović GA, Trifunovic SR, Radic GP. Cytotoxicity of Platinum(Iv) and Palladium(Ii) Complexes with Meso-1,2-Diphenyl-Ethylenediamine-N,N -Di-3-Propanoic Acid. Crystal Structure of [Pd(1,2-Dpheddp)] Complex. Macedonian Journal of Chemistry and Chemical Engineering. 2016;35(1):79-86
Mijajlovic Marina Z., Nikolic Milos V., Jevtic Verica V., Ratkovic Zoran R., Milovanovic Jelena, Arsenijević Aleksandar, Stojanovic Bojana, Novaković Slađana B., Bogdanović Goran A., Trifunovic Srecko R., Radic Gordana P., "Cytotoxicity of Platinum(Iv) and Palladium(Ii) Complexes with Meso-1,2-Diphenyl-Ethylenediamine-N,N -Di-3-Propanoic Acid. Crystal Structure of [Pd(1,2-Dpheddp)] Complex" Macedonian Journal of Chemistry and Chemical Engineering, 35, no. 1 (2016):79-86,
https://doi.org/10.20450/mjcce.2016.729 .
1
1