@article{
author = "Krstajic, Mila N. and Obradović, Maja D. and Babić, Biljana M. and Radmilović, Velimir and Lacnjevac, Uros C. and Krstajic, Nedeljko V. and Gojković, Snežana Lj.",
year = "2013",
abstract = "Ru-doped SnO2 powder, (RuxSn1-x)O-2, with a Sn:Ru atomic ratio of 9:1 was synthesized and used as a support for Pt nanoparticles (30 mass % loading). The (RuxSn1-x)O-2 support and the Pt/(RuxSn1-x)O-2 catalyst were characterized by X-ray diffraction measurements, energy dispersive X-ray spectroscopy and transmission electron microscopy (TEM). The (RuxSn1-x)O-2 was found to be a two-phase material consisting of probably a solid solution of RuO2 in SnO2 and pure RuO2. The average Pt particle size determined by TEM was 5.3 nm. Cyclic voltammetry of Pt/(RuxSn1-x)O-2 indicated good conductivity of the support and displayed the usual features of Pt. The results of the electrochemical oxidation of COad, and methanol on Pt/(RuxSn1-x)O-2 were compared with those on commercial Pt/C and PtRu/C catalysts. Oxidation of COads on Pt/(RuxSn1-x)O-2 starts at lower positive potentials than on PtRu/C and Pt/C. Potentiodynamic polarization curves and chronoamperometric curves of methanol oxidation indicated higher initial activity of the Pt/(RuxSn1-x)O-2 catalyst compared to PtRu/C, but also a greater loss in current density over time. A potentiodynamic stability test of the catalysts revealed that deactivation of Pt/(RuxSn1-x)O-2 and Pt/C was primarily caused by poisoning of the Pt surface by residues of methanol oxidation, which mostly occurred during the first potential cycle. In the case of PtRu/C, the poisoning of the surface was minor and deactivation was caused by surface area loss of the PtRu.",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemical oxidation of methanol on Pt/(RuxSn1-x)O-2 nanocatalyst",
volume = "78",
number = "11",
pages = "1703-1716",
doi = "10.2298/JSC130718091K"
}