TY  - JOUR
AU  - Milošević, Sanja S.
AU  - Kurko, Sandra V.
AU  - Pasquini, Luca
AU  - Matović, Ljiljana
AU  - Vujasin, Radojka
AU  - Novaković, Nikola
AU  - Grbović-Novaković, Jasmina
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/274
AB  - The hydrogen sorption kinetics of MgH2-VO2(B) composites synthesised by mechanical milling have been studied. The microstructural properties of composites were characterized by means of X-ray diffraction (XRD), Raman spectroscopy, Scanning electron microscopy (SEM), Particle size analysis (PSD), while sorption behaviour was followed by differential scanning calorimetry (DSC) and Sievert measurements. Results have shown that although desorption temperature reduction is moderate; there is a substantial improvement in hydrogen sorption kinetics. The complete desorption of pure MgH2 at elevated temperature takes place in more than 30 min while the composite fully desorbs in less than 2 min even at lower temperatures. It has been shown that the metastable gamma-MgH2 phase and the point defects have a decisive role in desorption process only in the first sorption cycle, while the second and the subsequent sorption cycles are affected by microstructural and morphological characteristics of the composite. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Journal of Power Sources
T1  - Fast hydrogen sorption from MgH2-VO2(B) composite materials
VL  - 307
SP  - 481
EP  - 488
DO  - 10.1016/j.jpowsour.2015.12.108
ER  - 

@article{
author = "Milošević, Sanja S. and Kurko, Sandra V. and Pasquini, Luca and Matović, Ljiljana and Vujasin, Radojka and Novaković, Nikola and Grbović-Novaković, Jasmina",
year = "2016",
abstract = "The hydrogen sorption kinetics of MgH2-VO2(B) composites synthesised by mechanical milling have been studied. The microstructural properties of composites were characterized by means of X-ray diffraction (XRD), Raman spectroscopy, Scanning electron microscopy (SEM), Particle size analysis (PSD), while sorption behaviour was followed by differential scanning calorimetry (DSC) and Sievert measurements. Results have shown that although desorption temperature reduction is moderate; there is a substantial improvement in hydrogen sorption kinetics. The complete desorption of pure MgH2 at elevated temperature takes place in more than 30 min while the composite fully desorbs in less than 2 min even at lower temperatures. It has been shown that the metastable gamma-MgH2 phase and the point defects have a decisive role in desorption process only in the first sorption cycle, while the second and the subsequent sorption cycles are affected by microstructural and morphological characteristics of the composite. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Journal of Power Sources",
title = "Fast hydrogen sorption from MgH2-VO2(B) composite materials",
volume = "307",
pages = "481-488",
doi = "10.1016/j.jpowsour.2015.12.108"
}

Milošević, S. S., Kurko, S. V., Pasquini, L., Matović, L., Vujasin, R., Novaković, N.,& Grbović-Novaković, J.. (2016). Fast hydrogen sorption from MgH2-VO2(B) composite materials. in Journal of Power Sources, 307, 481-488.
https://doi.org/10.1016/j.jpowsour.2015.12.108

Milošević SS, Kurko SV, Pasquini L, Matović L, Vujasin R, Novaković N, Grbović-Novaković J. Fast hydrogen sorption from MgH2-VO2(B) composite materials. in Journal of Power Sources. 2016;307:481-488.
doi:10.1016/j.jpowsour.2015.12.108 .

Milošević, Sanja S., Kurko, Sandra V., Pasquini, Luca, Matović, Ljiljana, Vujasin, Radojka, Novaković, Nikola, Grbović-Novaković, Jasmina, "Fast hydrogen sorption from MgH2-VO2(B) composite materials" in Journal of Power Sources, 307 (2016):481-488,
https://doi.org/10.1016/j.jpowsour.2015.12.108 . .

TY  - JOUR
AU  - Callini, Elsa
AU  - Aguey-Zinsou, Kondo-Francois
AU  - Ahuja, Rajeev
AU  - Ramon Ares, Jose
AU  - Bals, Sara
AU  - Biliškov, Nikola
AU  - Chakraborty, Sudip
AU  - Charalambopoulou, Georgia
AU  - Chaudhary, Anna-Lisa
AU  - Cuevas, Fermin
AU  - Dam, Bernard
AU  - de Jongh, Petra
AU  - Dornheim, Martin
AU  - Filinchuk, Yaroslav
AU  - Grbović-Novaković, Jasmina
AU  - Hirscher, Michael
AU  - Jensen, Torben R.
AU  - Jensen, Peter Bjerre
AU  - Novaković, Nikola
AU  - Lai, Qiwen
AU  - Leardini, Fabrice
AU  - Gattia, Daniele Mirabile
AU  - Pasquini, Luca
AU  - Steriotis, Theodore
AU  - Turner, Stuart
AU  - Vegge, Tejs
AU  - Zuttel, Andreas
AU  - Montone, Amelia
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7109
AB  - In the framework of the European Cooperation in Science and Technology (COST) Action MP1103 Nanostructured Materials for Solid-State Hydrogen Storage were synthesized, characterized and modeled. This Action dealt with the state of the art of energy storage and set up a competitive and coordinated network capable to define new and unexplored ways for Solid State Hydrogen Storage by innovative and interdisciplinary research within the European Research Area. An important number of new compounds have been synthesized: metal hydrides, complex hydrides, metal halide ammines and amidoboranes. Tuning the structure from bulk to thin film, nanoparticles and nanoconfined composites improved the hydrogen sorption properties and opened the perspective to new technological applications. Direct imaging of the hydrogenation reactions and in situ measurements under operando conditions have been carried out in these studies. Computational screening methods allowed the prediction of suitable compounds for hydrogen storage and the modeling of the hydrogen sorption reactions on mono-, bi-, and three-dimensional systems. This manuscript presents a review of the main achievements of this Action. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103
VL  - 41
IS  - 32
SP  - 14404
EP  - 14428
DO  - 10.1016/j.ijhydene.2016.04.025
ER  - 

@article{
author = "Callini, Elsa and Aguey-Zinsou, Kondo-Francois and Ahuja, Rajeev and Ramon Ares, Jose and Bals, Sara and Biliškov, Nikola and Chakraborty, Sudip and Charalambopoulou, Georgia and Chaudhary, Anna-Lisa and Cuevas, Fermin and Dam, Bernard and de Jongh, Petra and Dornheim, Martin and Filinchuk, Yaroslav and Grbović-Novaković, Jasmina and Hirscher, Michael and Jensen, Torben R. and Jensen, Peter Bjerre and Novaković, Nikola and Lai, Qiwen and Leardini, Fabrice and Gattia, Daniele Mirabile and Pasquini, Luca and Steriotis, Theodore and Turner, Stuart and Vegge, Tejs and Zuttel, Andreas and Montone, Amelia",
year = "2016",
abstract = "In the framework of the European Cooperation in Science and Technology (COST) Action MP1103 Nanostructured Materials for Solid-State Hydrogen Storage were synthesized, characterized and modeled. This Action dealt with the state of the art of energy storage and set up a competitive and coordinated network capable to define new and unexplored ways for Solid State Hydrogen Storage by innovative and interdisciplinary research within the European Research Area. An important number of new compounds have been synthesized: metal hydrides, complex hydrides, metal halide ammines and amidoboranes. Tuning the structure from bulk to thin film, nanoparticles and nanoconfined composites improved the hydrogen sorption properties and opened the perspective to new technological applications. Direct imaging of the hydrogenation reactions and in situ measurements under operando conditions have been carried out in these studies. Computational screening methods allowed the prediction of suitable compounds for hydrogen storage and the modeling of the hydrogen sorption reactions on mono-, bi-, and three-dimensional systems. This manuscript presents a review of the main achievements of this Action. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103",
volume = "41",
number = "32",
pages = "14404-14428",
doi = "10.1016/j.ijhydene.2016.04.025"
}

Callini, E., Aguey-Zinsou, K., Ahuja, R., Ramon Ares, J., Bals, S., Biliškov, N., Chakraborty, S., Charalambopoulou, G., Chaudhary, A., Cuevas, F., Dam, B., de Jongh, P., Dornheim, M., Filinchuk, Y., Grbović-Novaković, J., Hirscher, M., Jensen, T. R., Jensen, P. B., Novaković, N., Lai, Q., Leardini, F., Gattia, D. M., Pasquini, L., Steriotis, T., Turner, S., Vegge, T., Zuttel, A.,& Montone, A.. (2016). Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103. in International Journal of Hydrogen Energy, 41(32), 14404-14428.
https://doi.org/10.1016/j.ijhydene.2016.04.025

Callini E, Aguey-Zinsou K, Ahuja R, Ramon Ares J, Bals S, Biliškov N, Chakraborty S, Charalambopoulou G, Chaudhary A, Cuevas F, Dam B, de Jongh P, Dornheim M, Filinchuk Y, Grbović-Novaković J, Hirscher M, Jensen TR, Jensen PB, Novaković N, Lai Q, Leardini F, Gattia DM, Pasquini L, Steriotis T, Turner S, Vegge T, Zuttel A, Montone A. Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103. in International Journal of Hydrogen Energy. 2016;41(32):14404-14428.
doi:10.1016/j.ijhydene.2016.04.025 .

Callini, Elsa, Aguey-Zinsou, Kondo-Francois, Ahuja, Rajeev, Ramon Ares, Jose, Bals, Sara, Biliškov, Nikola, Chakraborty, Sudip, Charalambopoulou, Georgia, Chaudhary, Anna-Lisa, Cuevas, Fermin, Dam, Bernard, de Jongh, Petra, Dornheim, Martin, Filinchuk, Yaroslav, Grbović-Novaković, Jasmina, Hirscher, Michael, Jensen, Torben R., Jensen, Peter Bjerre, Novaković, Nikola, Lai, Qiwen, Leardini, Fabrice, Gattia, Daniele Mirabile, Pasquini, Luca, Steriotis, Theodore, Turner, Stuart, Vegge, Tejs, Zuttel, Andreas, Montone, Amelia, "Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103" in International Journal of Hydrogen Energy, 41, no. 32 (2016):14404-14428,
https://doi.org/10.1016/j.ijhydene.2016.04.025 . .

TY  - CONF
AU  - Milošević, Sanja S.
AU  - Vujasin, Radojka
AU  - Matović, Ljiljana
AU  - Rašković-Lovre, Željka
AU  - Pasquini, L.
AU  - Grbović-Novaković, Jasmina
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9238
AB  - Composite of MgH2 VO2 has been synthesized by high-energy mechanical
milling. The sorption properties of composites were examined by
differential scanning calorimetry and sorption analysis. It has been shown
that at relatively low temperature sorption reaction is notable enhanced.
Complete desorption of pure MgH2 at 380°C finishes after 30 minutes while
composite material fully desorbs in less than 2 minutes even at lower
temperatures.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Remarkable sorption properties of MgH2-VO2 nanocompostites
VL  - H-25-P
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9238
ER  - 

@conference{
author = "Milošević, Sanja S. and Vujasin, Radojka and Matović, Ljiljana and Rašković-Lovre, Željka and Pasquini, L. and Grbović-Novaković, Jasmina",
year = "2014",
abstract = "Composite of MgH2 VO2 has been synthesized by high-energy mechanical
milling. The sorption properties of composites were examined by
differential scanning calorimetry and sorption analysis. It has been shown
that at relatively low temperature sorption reaction is notable enhanced.
Complete desorption of pure MgH2 at 380°C finishes after 30 minutes while
composite material fully desorbs in less than 2 minutes even at lower
temperatures.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Remarkable sorption properties of MgH2-VO2 nanocompostites",
volume = "H-25-P",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9238"
}

Milošević, S. S., Vujasin, R., Matović, L., Rašković-Lovre, Ž., Pasquini, L.,& Grbović-Novaković, J.. (2014). Remarkable sorption properties of MgH2-VO2 nanocompostites. in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Society of Physical Chemists of Serbia., H-25-P.
https://hdl.handle.net/21.15107/rcub_vinar_9238

Milošević SS, Vujasin R, Matović L, Rašković-Lovre Ž, Pasquini L, Grbović-Novaković J. Remarkable sorption properties of MgH2-VO2 nanocompostites. in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry. 2014;H-25-P.
https://hdl.handle.net/21.15107/rcub_vinar_9238 .

Milošević, Sanja S., Vujasin, Radojka, Matović, Ljiljana, Rašković-Lovre, Željka, Pasquini, L., Grbović-Novaković, Jasmina, "Remarkable sorption properties of MgH2-VO2 nanocompostites" in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry, H-25-P (2014),
https://hdl.handle.net/21.15107/rcub_vinar_9238 .

TY  - JOUR
AU  - Milošević, Sanja S.
AU  - Milanović, Igor
AU  - Paskaš Mamula, Bojana
AU  - Đukić, Anđelka B.
AU  - Rajnović, Dragan
AU  - Pasquini, Luca
AU  - Grbović-Novaković, Jasmina
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5692
AB  - To improve hydrogen desorption properties of MgH2, mechanical milling of MgH2 with low concentration (2 and 5%) of NaNH2 has been performed. Pre-milling of MgH2 for 10 h has been done and then six samples have been synthesised with different milling times from 15 to 60 min. Microstructural characterisation has been performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and laser scattering measurements (PSD), and correlated to desorption properties examined using Differential Scanning Calorimetry (DSC) and Hydrogen Sorption Analyser (HSA). Thermal analysis shows that desorption temperatures are shifted towards lower values. It also highlights the significance of milling time and additive concentration on desorption behaviour. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Hydrogen desorption properties of MgH2 catalysed with NaNH2
VL  - 38
IS  - 27
SP  - 12223
EP  - 12229
DO  - 10.1016/j.ijhydene.2013.06.083
ER  - 

@article{
author = "Milošević, Sanja S. and Milanović, Igor and Paskaš Mamula, Bojana and Đukić, Anđelka B. and Rajnović, Dragan and Pasquini, Luca and Grbović-Novaković, Jasmina",
year = "2013",
abstract = "To improve hydrogen desorption properties of MgH2, mechanical milling of MgH2 with low concentration (2 and 5%) of NaNH2 has been performed. Pre-milling of MgH2 for 10 h has been done and then six samples have been synthesised with different milling times from 15 to 60 min. Microstructural characterisation has been performed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and laser scattering measurements (PSD), and correlated to desorption properties examined using Differential Scanning Calorimetry (DSC) and Hydrogen Sorption Analyser (HSA). Thermal analysis shows that desorption temperatures are shifted towards lower values. It also highlights the significance of milling time and additive concentration on desorption behaviour. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Hydrogen desorption properties of MgH2 catalysed with NaNH2",
volume = "38",
number = "27",
pages = "12223-12229",
doi = "10.1016/j.ijhydene.2013.06.083"
}

Milošević, S. S., Milanović, I., Paskaš Mamula, B., Đukić, A. B., Rajnović, D., Pasquini, L.,& Grbović-Novaković, J.. (2013). Hydrogen desorption properties of MgH2 catalysed with NaNH2. in International Journal of Hydrogen Energy, 38(27), 12223-12229.
https://doi.org/10.1016/j.ijhydene.2013.06.083

Milošević SS, Milanović I, Paskaš Mamula B, Đukić AB, Rajnović D, Pasquini L, Grbović-Novaković J. Hydrogen desorption properties of MgH2 catalysed with NaNH2. in International Journal of Hydrogen Energy. 2013;38(27):12223-12229.
doi:10.1016/j.ijhydene.2013.06.083 .

Milošević, Sanja S., Milanović, Igor, Paskaš Mamula, Bojana, Đukić, Anđelka B., Rajnović, Dragan, Pasquini, Luca, Grbović-Novaković, Jasmina, "Hydrogen desorption properties of MgH2 catalysed with NaNH2" in International Journal of Hydrogen Energy, 38, no. 27 (2013):12223-12229,
https://doi.org/10.1016/j.ijhydene.2013.06.083 . .

TY  - CONF
AU  - Montone, A.
AU  - Antisari, M. Vittori
AU  - Abazović, Nadica
AU  - Grbović-Novaković, Jasmina
AU  - Pasquini, L.
AU  - Bonetti, E.
AU  - Forini, A. L.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6693
AB  - Hydrogen, being a regenerative and environmentally harmless fuel, can play a crucial role in the energetic scenario of the near future. In recent years several systems for solid-state hydrogen storage have been investigated, among which a few metals and metal alloys show the most promising properties. Mg and Mg-based micro and nanocomposites are widely studied for this application owing to the high gravimetric storage capacity, even if a proper microstructure, mainly at the material surface, has to be setup in order to overtake kinetic constraints often related to the high surface reactivity. In this paper, we present our approach to this problem and report the main findings. We have examined the influence on hydrogenation/dehydrogenation characteristics of different modifications of the bulk and surface microstructure of MgH2 powders processed by ball milling, which appears to be one the most useful methods for preparing powders suitable for hydrogen storage.
C3  - Materials Science Forum
T1  - Reaction with hydrogen of micro and nano composites based on Mg
VL  - 555
SP  - 335
EP  - +
DO  - 10.4028/www.scientific.net/MSF.555.335
ER  - 

@conference{
author = "Montone, A. and Antisari, M. Vittori and Abazović, Nadica and Grbović-Novaković, Jasmina and Pasquini, L. and Bonetti, E. and Forini, A. L.",
year = "2007",
abstract = "Hydrogen, being a regenerative and environmentally harmless fuel, can play a crucial role in the energetic scenario of the near future. In recent years several systems for solid-state hydrogen storage have been investigated, among which a few metals and metal alloys show the most promising properties. Mg and Mg-based micro and nanocomposites are widely studied for this application owing to the high gravimetric storage capacity, even if a proper microstructure, mainly at the material surface, has to be setup in order to overtake kinetic constraints often related to the high surface reactivity. In this paper, we present our approach to this problem and report the main findings. We have examined the influence on hydrogenation/dehydrogenation characteristics of different modifications of the bulk and surface microstructure of MgH2 powders processed by ball milling, which appears to be one the most useful methods for preparing powders suitable for hydrogen storage.",
journal = "Materials Science Forum",
title = "Reaction with hydrogen of micro and nano composites based on Mg",
volume = "555",
pages = "335-+",
doi = "10.4028/www.scientific.net/MSF.555.335"
}

Montone, A., Antisari, M. V., Abazović, N., Grbović-Novaković, J., Pasquini, L., Bonetti, E.,& Forini, A. L.. (2007). Reaction with hydrogen of micro and nano composites based on Mg. in Materials Science Forum, 555, 335-+.
https://doi.org/10.4028/www.scientific.net/MSF.555.335

Montone A, Antisari MV, Abazović N, Grbović-Novaković J, Pasquini L, Bonetti E, Forini AL. Reaction with hydrogen of micro and nano composites based on Mg. in Materials Science Forum. 2007;555:335-+.
doi:10.4028/www.scientific.net/MSF.555.335 .

Montone, A., Antisari, M. Vittori, Abazović, Nadica, Grbović-Novaković, Jasmina, Pasquini, L., Bonetti, E., Forini, A. L., "Reaction with hydrogen of micro and nano composites based on Mg" in Materials Science Forum, 555 (2007):335-+,
https://doi.org/10.4028/www.scientific.net/MSF.555.335 . .

TY  - JOUR
AU  - Montone, A.
AU  - Grbović, Jasmina
AU  - Bassetti, A.
AU  - Mirenghi, Luciana
AU  - Rotolo, P.
AU  - Bonetti, E.
AU  - Pasquini, L.
AU  - Antisari, M. Vittori
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3117
AB  - Mg-graphite composites, suitable for hydrogen storage, have been synthesized by ball milling metallic Mg with different amounts of graphite and benzene. The microstructure and the surface chemical composition have been characterized in order to explain the kinetics of reaction with hydrogen. The presence of benzene in the milled blends induces a finer powder particle size, helps to preserve the structural integrity of the graphite crystals and results to be necessary for a complete transformation of the milled powder to the hydride phase by thermal reaction with hydrogen gas. On the other hand, it induces a more pronounced reaction of the milled Mg-C composites with the air. The transport properties of the resulting surface contamination layer appear to control the kinetics of thermal decomposition of the MgH2 phase, so that the addition of benzene induces a higher reaction temperature owing to a larger thickness of the surface compound. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene
VL  - 31
IS  - 14
SP  - 2088
EP  - 2096
DO  - 10.1016/j.ijhydene.2006.01.020
ER  - 

@article{
author = "Montone, A. and Grbović, Jasmina and Bassetti, A. and Mirenghi, Luciana and Rotolo, P. and Bonetti, E. and Pasquini, L. and Antisari, M. Vittori",
year = "2006",
abstract = "Mg-graphite composites, suitable for hydrogen storage, have been synthesized by ball milling metallic Mg with different amounts of graphite and benzene. The microstructure and the surface chemical composition have been characterized in order to explain the kinetics of reaction with hydrogen. The presence of benzene in the milled blends induces a finer powder particle size, helps to preserve the structural integrity of the graphite crystals and results to be necessary for a complete transformation of the milled powder to the hydride phase by thermal reaction with hydrogen gas. On the other hand, it induces a more pronounced reaction of the milled Mg-C composites with the air. The transport properties of the resulting surface contamination layer appear to control the kinetics of thermal decomposition of the MgH2 phase, so that the addition of benzene induces a higher reaction temperature owing to a larger thickness of the surface compound. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene",
volume = "31",
number = "14",
pages = "2088-2096",
doi = "10.1016/j.ijhydene.2006.01.020"
}

Montone, A., Grbović, J., Bassetti, A., Mirenghi, L., Rotolo, P., Bonetti, E., Pasquini, L.,& Antisari, M. V.. (2006). Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene. in International Journal of Hydrogen Energy, 31(14), 2088-2096.
https://doi.org/10.1016/j.ijhydene.2006.01.020

Montone A, Grbović J, Bassetti A, Mirenghi L, Rotolo P, Bonetti E, Pasquini L, Antisari MV. Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene. in International Journal of Hydrogen Energy. 2006;31(14):2088-2096.
doi:10.1016/j.ijhydene.2006.01.020 .

Montone, A., Grbović, Jasmina, Bassetti, A., Mirenghi, Luciana, Rotolo, P., Bonetti, E., Pasquini, L., Antisari, M. Vittori, "Microstructure, surface properties and hydrating behaviour of Mg-C composites prepared by ball milling with benzene" in International Journal of Hydrogen Energy, 31, no. 14 (2006):2088-2096,
https://doi.org/10.1016/j.ijhydene.2006.01.020 . .

TY  - JOUR
AU  - Montone, A.
AU  - Grbović, Jasmina
AU  - Stamenković, Ljiljana Lj.
AU  - Fiorini, A. L.
AU  - Pasquini, L.
AU  - Bonetti, E.
AU  - Antisari, M. Vittori
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6596
AB  - The influence of the Co addition and synthesis route on desorption properties of MgH2 were investigated. Ball milling of MgH2-Co blends was performed under Ar using different milling intensities and different weight ratios. Micro structural and morphological characterization, performed by XRD and SEM, show a huge correlation with thermal stability and hydrogen desorption properties investigated by DSC. A complex desorption behaviour is correlated with the dispersion of the catalytic particles that appears to play a main role in desorption performances. The optimum catalyst concentration was found to be around 10 wt.%, while the optimum value of the ball to powder ratio was 10:1.
T2  - Materials Science Forum
T1  - Desorption behaviour in nanostructured MgH2-CO
VL  - 518
SP  - 79
EP  - 84
DO  - 10.4028/www.scientific.net/MSF.518.79
ER  - 

@article{
author = "Montone, A. and Grbović, Jasmina and Stamenković, Ljiljana Lj. and Fiorini, A. L. and Pasquini, L. and Bonetti, E. and Antisari, M. Vittori",
year = "2006",
abstract = "The influence of the Co addition and synthesis route on desorption properties of MgH2 were investigated. Ball milling of MgH2-Co blends was performed under Ar using different milling intensities and different weight ratios. Micro structural and morphological characterization, performed by XRD and SEM, show a huge correlation with thermal stability and hydrogen desorption properties investigated by DSC. A complex desorption behaviour is correlated with the dispersion of the catalytic particles that appears to play a main role in desorption performances. The optimum catalyst concentration was found to be around 10 wt.%, while the optimum value of the ball to powder ratio was 10:1.",
journal = "Materials Science Forum",
title = "Desorption behaviour in nanostructured MgH2-CO",
volume = "518",
pages = "79-84",
doi = "10.4028/www.scientific.net/MSF.518.79"
}

Montone, A., Grbović, J., Stamenković, L. Lj., Fiorini, A. L., Pasquini, L., Bonetti, E.,& Antisari, M. V.. (2006). Desorption behaviour in nanostructured MgH2-CO. in Materials Science Forum, 518, 79-84.
https://doi.org/10.4028/www.scientific.net/MSF.518.79

Montone A, Grbović J, Stamenković LL, Fiorini AL, Pasquini L, Bonetti E, Antisari MV. Desorption behaviour in nanostructured MgH2-CO. in Materials Science Forum. 2006;518:79-84.
doi:10.4028/www.scientific.net/MSF.518.79 .

Montone, A., Grbović, Jasmina, Stamenković, Ljiljana Lj., Fiorini, A. L., Pasquini, L., Bonetti, E., Antisari, M. Vittori, "Desorption behaviour in nanostructured MgH2-CO" in Materials Science Forum, 518 (2006):79-84,
https://doi.org/10.4028/www.scientific.net/MSF.518.79 . .

TY  - JOUR
AU  - Bassetti, A
AU  - Bonetti, E
AU  - Pasquini, L
AU  - Montone, A
AU  - Grbović, Jasmina
AU  - Antisari, MV
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2868
AB  - In order to obtain faster hydrogen sorption kinetics, MgH2-Fe nanocomposites were prepared by high-energy ball milling. The MgH2 decomposition was studied in samples obtained by changing in a systematic way both the catalyst amount and the degree of microstructural refinement. To this purpose, blends containing increasing Fe concentration have been ball milled in processing conditions able to impart different amount of structural defects. The resulting samples have been characterized by X-ray diffraction to investigate the microstructural features and the phase composition, while the powder morphology and the degree of catalyst dispersion were analyzed by scanning electron microscopy. Differential scanning calorimetry was carried out to characterize the hydrogen desorption behavior of these nanocomposites. Experimental results clearly show that the characteristics of the desorption process are dominated, among other factors, by the morphology of the catalyst dispersion, which in turns depends on the processing conditions and blend composition. In order to achieve low desorption temperatures the homogeneous catalyst dispersion in micron-size particles throughout the structure is required. This condition can be achieved by suitable tuning of the milling conditions and of the catalyst amount.
T2  - European Physical Journal B. Condensed Matter and Complex Systems
T1  - Hydrogen desorption from ball milled MgH2 catalyzed with Fe
VL  - 43
IS  - 1
SP  - 19
EP  - 27
DO  - 10.1140/epjb/e2005-00023-9
ER  - 

@article{
author = "Bassetti, A and Bonetti, E and Pasquini, L and Montone, A and Grbović, Jasmina and Antisari, MV",
year = "2005",
abstract = "In order to obtain faster hydrogen sorption kinetics, MgH2-Fe nanocomposites were prepared by high-energy ball milling. The MgH2 decomposition was studied in samples obtained by changing in a systematic way both the catalyst amount and the degree of microstructural refinement. To this purpose, blends containing increasing Fe concentration have been ball milled in processing conditions able to impart different amount of structural defects. The resulting samples have been characterized by X-ray diffraction to investigate the microstructural features and the phase composition, while the powder morphology and the degree of catalyst dispersion were analyzed by scanning electron microscopy. Differential scanning calorimetry was carried out to characterize the hydrogen desorption behavior of these nanocomposites. Experimental results clearly show that the characteristics of the desorption process are dominated, among other factors, by the morphology of the catalyst dispersion, which in turns depends on the processing conditions and blend composition. In order to achieve low desorption temperatures the homogeneous catalyst dispersion in micron-size particles throughout the structure is required. This condition can be achieved by suitable tuning of the milling conditions and of the catalyst amount.",
journal = "European Physical Journal B. Condensed Matter and Complex Systems",
title = "Hydrogen desorption from ball milled MgH2 catalyzed with Fe",
volume = "43",
number = "1",
pages = "19-27",
doi = "10.1140/epjb/e2005-00023-9"
}

Bassetti, A., Bonetti, E., Pasquini, L., Montone, A., Grbović, J.,& Antisari, M.. (2005). Hydrogen desorption from ball milled MgH2 catalyzed with Fe. in European Physical Journal B. Condensed Matter and Complex Systems, 43(1), 19-27.
https://doi.org/10.1140/epjb/e2005-00023-9

Bassetti A, Bonetti E, Pasquini L, Montone A, Grbović J, Antisari M. Hydrogen desorption from ball milled MgH2 catalyzed with Fe. in European Physical Journal B. Condensed Matter and Complex Systems. 2005;43(1):19-27.
doi:10.1140/epjb/e2005-00023-9 .

Bassetti, A, Bonetti, E, Pasquini, L, Montone, A, Grbović, Jasmina, Antisari, MV, "Hydrogen desorption from ball milled MgH2 catalyzed with Fe" in European Physical Journal B. Condensed Matter and Complex Systems, 43, no. 1 (2005):19-27,
https://doi.org/10.1140/epjb/e2005-00023-9 . .

TY  - JOUR
AU  - Montone, A
AU  - Grbović, Jasmina
AU  - Bassetti, A
AU  - Mirenghi, Luciana
AU  - Rotolo, P
AU  - Bonetti, E
AU  - Pasquini, L
AU  - Antisari, MV
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6523
AB  - The hydrogen storage performances of Mg-C nanocomposites have been studied on materials synthesized by ball milling with and without addition of an organic additive. The main purpose of this work is to study in more detail the cooperative effect observed when both graphite and benzene are added to the milled blend. In fact, when both components are added to Mg in the ball milling process, good catalyzing properties of the composite surface allow improved sorption-desorption behavior of the synthesized material. The processed materials have been characterized by XRD to assess the details of the phase structure by Rietveld analysis, while surface features have been studied by XPS, which evidences structural modifications of both the surface Mg oxide and the graphite particles. The hydrogen desorption behavior has been correlated with the surface structure which appears to depend on the carbon to benzene ratio. Thermal stability and hydrogen desorption properties were investigated by DSC. Experimental results on nanocomposites with the same Mg to C weight ratio (70:30) show improved performances for a proper choice of carbon to benzene ratio weight (1/3), even after manipulation of the milled material in air.
T2  - Materials Science Forum
T1  - Role of organic additives in hydriding properties of Mg-C nanocomposites
VL  - 494
SP  - 137
EP  - 142
DO  - 10.4028/www.scientific.net/MSF.494.137
ER  - 

@article{
author = "Montone, A and Grbović, Jasmina and Bassetti, A and Mirenghi, Luciana and Rotolo, P and Bonetti, E and Pasquini, L and Antisari, MV",
year = "2005",
abstract = "The hydrogen storage performances of Mg-C nanocomposites have been studied on materials synthesized by ball milling with and without addition of an organic additive. The main purpose of this work is to study in more detail the cooperative effect observed when both graphite and benzene are added to the milled blend. In fact, when both components are added to Mg in the ball milling process, good catalyzing properties of the composite surface allow improved sorption-desorption behavior of the synthesized material. The processed materials have been characterized by XRD to assess the details of the phase structure by Rietveld analysis, while surface features have been studied by XPS, which evidences structural modifications of both the surface Mg oxide and the graphite particles. The hydrogen desorption behavior has been correlated with the surface structure which appears to depend on the carbon to benzene ratio. Thermal stability and hydrogen desorption properties were investigated by DSC. Experimental results on nanocomposites with the same Mg to C weight ratio (70:30) show improved performances for a proper choice of carbon to benzene ratio weight (1/3), even after manipulation of the milled material in air.",
journal = "Materials Science Forum",
title = "Role of organic additives in hydriding properties of Mg-C nanocomposites",
volume = "494",
pages = "137-142",
doi = "10.4028/www.scientific.net/MSF.494.137"
}

Montone, A., Grbović, J., Bassetti, A., Mirenghi, L., Rotolo, P., Bonetti, E., Pasquini, L.,& Antisari, M.. (2005). Role of organic additives in hydriding properties of Mg-C nanocomposites. in Materials Science Forum, 494, 137-142.
https://doi.org/10.4028/www.scientific.net/MSF.494.137

Montone A, Grbović J, Bassetti A, Mirenghi L, Rotolo P, Bonetti E, Pasquini L, Antisari M. Role of organic additives in hydriding properties of Mg-C nanocomposites. in Materials Science Forum. 2005;494:137-142.
doi:10.4028/www.scientific.net/MSF.494.137 .

Montone, A, Grbović, Jasmina, Bassetti, A, Mirenghi, Luciana, Rotolo, P, Bonetti, E, Pasquini, L, Antisari, MV, "Role of organic additives in hydriding properties of Mg-C nanocomposites" in Materials Science Forum, 494 (2005):137-142,
https://doi.org/10.4028/www.scientific.net/MSF.494.137 . .

TY  - JOUR
AU  - Bassetti, A
AU  - Bonetti, E
AU  - Fiorini, AL
AU  - Grbović, Jasmina
AU  - Montone, A
AU  - Pasquini, L
AU  - Antisari, MV
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6425
AB  - Mg-based nanostructured hydrides have been synthesized by ball milling using two alternative approaches. The first is based on the reactive milling of Mg powders in H-2 atmosphere, while the second on the milling of commercial MgH2 powders under inert atmosphere. In both cases 10 wt.% of Fe was added to the powder mixture, with the aim of introducing a catalyst agent. The microstructural characterization was carried out by X-ray diffraction, and both scanning and transmission electron microscopy. Hydrogen desorption behavior was evaluated by differential scanning calorimetry. Almost full hydrogenation of pure Mg powders can be achieved by reactive milling. Catalyst addition strongly accelerates the hydride formation. Both reactive milling of Mg powder and inert gas milling of MgH2 induce a nanosized microstructure with similar H-desorption behavior. The role played by Fe becomes particularly evident in H-desorption. In fact, a temperature decrease of about 100degreesC was found in samples having the same crystallite size and similar powder morphology.
T2  - Materials Science Forum
T1  - Microstructure and hydrogen desorption in nanostructured MgH2-Fe
VL  - 453-454
SP  - 205
EP  - 212
DO  - 10.4028/www.scientific.net/MSF.453-454.205
ER  - 

@article{
author = "Bassetti, A and Bonetti, E and Fiorini, AL and Grbović, Jasmina and Montone, A and Pasquini, L and Antisari, MV",
year = "2004",
abstract = "Mg-based nanostructured hydrides have been synthesized by ball milling using two alternative approaches. The first is based on the reactive milling of Mg powders in H-2 atmosphere, while the second on the milling of commercial MgH2 powders under inert atmosphere. In both cases 10 wt.% of Fe was added to the powder mixture, with the aim of introducing a catalyst agent. The microstructural characterization was carried out by X-ray diffraction, and both scanning and transmission electron microscopy. Hydrogen desorption behavior was evaluated by differential scanning calorimetry. Almost full hydrogenation of pure Mg powders can be achieved by reactive milling. Catalyst addition strongly accelerates the hydride formation. Both reactive milling of Mg powder and inert gas milling of MgH2 induce a nanosized microstructure with similar H-desorption behavior. The role played by Fe becomes particularly evident in H-desorption. In fact, a temperature decrease of about 100degreesC was found in samples having the same crystallite size and similar powder morphology.",
journal = "Materials Science Forum",
title = "Microstructure and hydrogen desorption in nanostructured MgH2-Fe",
volume = "453-454",
pages = "205-212",
doi = "10.4028/www.scientific.net/MSF.453-454.205"
}

Bassetti, A., Bonetti, E., Fiorini, A., Grbović, J., Montone, A., Pasquini, L.,& Antisari, M.. (2004). Microstructure and hydrogen desorption in nanostructured MgH2-Fe. in Materials Science Forum, 453-454, 205-212.
https://doi.org/10.4028/www.scientific.net/MSF.453-454.205

Bassetti A, Bonetti E, Fiorini A, Grbović J, Montone A, Pasquini L, Antisari M. Microstructure and hydrogen desorption in nanostructured MgH2-Fe. in Materials Science Forum. 2004;453-454:205-212.
doi:10.4028/www.scientific.net/MSF.453-454.205 .

Bassetti, A, Bonetti, E, Fiorini, AL, Grbović, Jasmina, Montone, A, Pasquini, L, Antisari, MV, "Microstructure and hydrogen desorption in nanostructured MgH2-Fe" in Materials Science Forum, 453-454 (2004):205-212,
https://doi.org/10.4028/www.scientific.net/MSF.453-454.205 . .