TY  - JOUR
AU  - Vujačić Nikezić, Ana V.
AU  - Grbović-Novaković, Jasmina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10934
AB  - Treatment of various diseases, especially cancer treatment, includes the potentialuse of different types of nanoparticles and nanostructures as drug carriers. However,searching for less toxic and more efficient therapy requires further progress, wherein recentdevelopments in medicine increasingly include the use of various advanced nanostructures.Their more successful application might be achieved by leveling imbalances betweenthe potentiality of different nanostructures and the demands required for their safeuse. Biocompatibility, biodegradability, prolonged circulation time and enhanced accumulationand uptake by cells are some of the key preconditions for their usage in efficientdrug delivery. Thanks to their greatly tunable functions, they are major buildingblocks for manufacturing novel materials. Nevertheless, given that their toxicity is questionable,their practical application is challenging. Hereof, before entering the sphere ofhuman consumption, it is of critical importance to perform more studies regarding theirtoxicity and drug distribution. This review emphasizes recent advances in nanomedicine,employing different kinds of conventionally used nanoparticles as well as novel nanoparticlesand nanostructures. Special emphasis is placed on micro/nanomotors (MNMs), discussingtheir opportunities, limitations, challenges and possible applications in drug deliveryand outlining some perspectives in the nanomedicine area.
T2  - Current Medicinal Chemistry
T1  - Nano/Microcarriers in Drug Delivery: Moving the Timeline to Contemporary
VL  - 30
IS  - 26
SP  - 2996
EP  - 3023
DO  - 10.2174/0929867329666220821193938
ER  - 

@article{
author = "Vujačić Nikezić, Ana V. and Grbović-Novaković, Jasmina",
year = "2023",
abstract = "Treatment of various diseases, especially cancer treatment, includes the potentialuse of different types of nanoparticles and nanostructures as drug carriers. However,searching for less toxic and more efficient therapy requires further progress, wherein recentdevelopments in medicine increasingly include the use of various advanced nanostructures.Their more successful application might be achieved by leveling imbalances betweenthe potentiality of different nanostructures and the demands required for their safeuse. Biocompatibility, biodegradability, prolonged circulation time and enhanced accumulationand uptake by cells are some of the key preconditions for their usage in efficientdrug delivery. Thanks to their greatly tunable functions, they are major buildingblocks for manufacturing novel materials. Nevertheless, given that their toxicity is questionable,their practical application is challenging. Hereof, before entering the sphere ofhuman consumption, it is of critical importance to perform more studies regarding theirtoxicity and drug distribution. This review emphasizes recent advances in nanomedicine,employing different kinds of conventionally used nanoparticles as well as novel nanoparticlesand nanostructures. Special emphasis is placed on micro/nanomotors (MNMs), discussingtheir opportunities, limitations, challenges and possible applications in drug deliveryand outlining some perspectives in the nanomedicine area.",
journal = "Current Medicinal Chemistry",
title = "Nano/Microcarriers in Drug Delivery: Moving the Timeline to Contemporary",
volume = "30",
number = "26",
pages = "2996-3023",
doi = "10.2174/0929867329666220821193938"
}

Vujačić Nikezić, A. V.,& Grbović-Novaković, J.. (2023). Nano/Microcarriers in Drug Delivery: Moving the Timeline to Contemporary. in Current Medicinal Chemistry, 30(26), 2996-3023.
https://doi.org/10.2174/0929867329666220821193938

Vujačić Nikezić AV, Grbović-Novaković J. Nano/Microcarriers in Drug Delivery: Moving the Timeline to Contemporary. in Current Medicinal Chemistry. 2023;30(26):2996-3023.
doi:10.2174/0929867329666220821193938 .

Vujačić Nikezić, Ana V., Grbović-Novaković, Jasmina, "Nano/Microcarriers in Drug Delivery: Moving the Timeline to Contemporary" in Current Medicinal Chemistry, 30, no. 26 (2023):2996-3023,
https://doi.org/10.2174/0929867329666220821193938 . .

TY  - CONF
AU  - Tošić, Katarina
AU  - Mitrović Rajić, Anđela
AU  - Milošević Govedarović, Sanja
AU  - Mijaković, Sara
AU  - Vujačić Nikezić, Ana V.
AU  - Grbović Novaković, Jasmina
AU  - Paskaš Mamula, Bojana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12305
AB  - Pyrophyllite, a naturally abundant clay material, exhibits remarkable physicochemical characteristics. Its minimal electrical and thermal conductivity, low expansion rate, strong mechanical properties, and outstanding heat resistance make it a valuable resource across diverse industries. Pyrophyllite finds applications in sectors such as paper and plastic manufacturing, brick production, ceramics, cosmetics, rubber processing, and wastewater treatment. Furthermore, its versatility extends to the production of ceramic membranes for efficient water filtration. This paper presents the characterization of natural pyrophyllite ore subjected to ultrasonic treatment at varying time intervals. The ultrasonic treatment aims to eliminate hard phases such as quartz and calcite within the ore, thereby improving its sorption capabilities. The treated samples were subjected to analysis using SEM and XRD techniques. Morphological and structural analysis revealed that as the duration of ultrasonic treatment increased, the proportion of hard phases in the sample decreased. Additionally, this study evaluated the sorption properties of pyrophyllite. A comparative analysis was conducted between a raw clay sample containing various admixtures and a sample that underwent a 30-minute ultrasonic treatment. The sorption of a methylene blue solution after 24 hours in water was assessed, with UV-Vis analysis revealing that the efficiency of the sonically treated pyrophyllite exceeded 97%, whereas the raw ore exhibited approximately 89% efficiency over the same duration. These findings suggest that the removal of hard phases from pyrophyllite ore enhances its sorption properties
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Improvement of sorption properties of natural clay pyrophyllite by ultrasonic treatment
SP  - 22
EP  - 22
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12305
ER  - 

@conference{
author = "Tošić, Katarina and Mitrović Rajić, Anđela and Milošević Govedarović, Sanja and Mijaković, Sara and Vujačić Nikezić, Ana V. and Grbović Novaković, Jasmina and Paskaš Mamula, Bojana",
year = "2023",
abstract = "Pyrophyllite, a naturally abundant clay material, exhibits remarkable physicochemical characteristics. Its minimal electrical and thermal conductivity, low expansion rate, strong mechanical properties, and outstanding heat resistance make it a valuable resource across diverse industries. Pyrophyllite finds applications in sectors such as paper and plastic manufacturing, brick production, ceramics, cosmetics, rubber processing, and wastewater treatment. Furthermore, its versatility extends to the production of ceramic membranes for efficient water filtration. This paper presents the characterization of natural pyrophyllite ore subjected to ultrasonic treatment at varying time intervals. The ultrasonic treatment aims to eliminate hard phases such as quartz and calcite within the ore, thereby improving its sorption capabilities. The treated samples were subjected to analysis using SEM and XRD techniques. Morphological and structural analysis revealed that as the duration of ultrasonic treatment increased, the proportion of hard phases in the sample decreased. Additionally, this study evaluated the sorption properties of pyrophyllite. A comparative analysis was conducted between a raw clay sample containing various admixtures and a sample that underwent a 30-minute ultrasonic treatment. The sorption of a methylene blue solution after 24 hours in water was assessed, with UV-Vis analysis revealing that the efficiency of the sonically treated pyrophyllite exceeded 97%, whereas the raw ore exhibited approximately 89% efficiency over the same duration. These findings suggest that the removal of hard phases from pyrophyllite ore enhances its sorption properties",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Improvement of sorption properties of natural clay pyrophyllite by ultrasonic treatment",
pages = "22-22",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12305"
}

Tošić, K., Mitrović Rajić, A., Milošević Govedarović, S., Mijaković, S., Vujačić Nikezić, A. V., Grbović Novaković, J.,& Paskaš Mamula, B.. (2023). Improvement of sorption properties of natural clay pyrophyllite by ultrasonic treatment. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 22-22.
https://hdl.handle.net/21.15107/rcub_vinar_12305

Tošić K, Mitrović Rajić A, Milošević Govedarović S, Mijaković S, Vujačić Nikezić AV, Grbović Novaković J, Paskaš Mamula B. Improvement of sorption properties of natural clay pyrophyllite by ultrasonic treatment. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:22-22.
https://hdl.handle.net/21.15107/rcub_vinar_12305 .

Tošić, Katarina, Mitrović Rajić, Anđela, Milošević Govedarović, Sanja, Mijaković, Sara, Vujačić Nikezić, Ana V., Grbović Novaković, Jasmina, Paskaš Mamula, Bojana, "Improvement of sorption properties of natural clay pyrophyllite by ultrasonic treatment" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):22-22,
https://hdl.handle.net/21.15107/rcub_vinar_12305 .

TY  - CONF
AU  - Mijaković, Sara
AU  - Grbović Novaković, Jasmina
AU  - Tošić, Katarina
AU  - Mitrović Rajić, Anđela
AU  - Paskaš Mamula, Bojana
AU  - Vujačić Nikezić, Ana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12319
AB  - Nanocomposites synthesized by incorporating nanostructured materials within the interlayer spaces of clay minerals have gained tremendous interest lately, owing to their exceptional physicochemical properties and vast potential in various fields. This study focuses on the mechanochemical activation of pyrophyllite, a commonly used natural clay material, using AgNO3 at different concentrations (2, 5, and 10 wt%). The activation process involved grinding the materials for varying durations ranging from 20 to 320 minutes. The resulting samples were analyzed using FTIR, TGA, and DTA thermal analysis techniques, XRD, SEM with EDX as well as PSD method for particle size distribution analysis. The results have shown a homogeneous distribution of silver along the analyzed surface. The duration of grinding and the amount of added silver greatly influence the composite physicochemical properties.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Physicochemical characterization of mechanochemically activated pyrophyllite/Ag composites
SP  - 46
EP  - 46
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12319
ER  - 

@conference{
author = "Mijaković, Sara and Grbović Novaković, Jasmina and Tošić, Katarina and Mitrović Rajić, Anđela and Paskaš Mamula, Bojana and Vujačić Nikezić, Ana",
year = "2023",
abstract = "Nanocomposites synthesized by incorporating nanostructured materials within the interlayer spaces of clay minerals have gained tremendous interest lately, owing to their exceptional physicochemical properties and vast potential in various fields. This study focuses on the mechanochemical activation of pyrophyllite, a commonly used natural clay material, using AgNO3 at different concentrations (2, 5, and 10 wt%). The activation process involved grinding the materials for varying durations ranging from 20 to 320 minutes. The resulting samples were analyzed using FTIR, TGA, and DTA thermal analysis techniques, XRD, SEM with EDX as well as PSD method for particle size distribution analysis. The results have shown a homogeneous distribution of silver along the analyzed surface. The duration of grinding and the amount of added silver greatly influence the composite physicochemical properties.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Physicochemical characterization of mechanochemically activated pyrophyllite/Ag composites",
pages = "46-46",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12319"
}

Mijaković, S., Grbović Novaković, J., Tošić, K., Mitrović Rajić, A., Paskaš Mamula, B.,& Vujačić Nikezić, A.. (2023). Physicochemical characterization of mechanochemically activated pyrophyllite/Ag composites. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 46-46.
https://hdl.handle.net/21.15107/rcub_vinar_12319

Mijaković S, Grbović Novaković J, Tošić K, Mitrović Rajić A, Paskaš Mamula B, Vujačić Nikezić A. Physicochemical characterization of mechanochemically activated pyrophyllite/Ag composites. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:46-46.
https://hdl.handle.net/21.15107/rcub_vinar_12319 .

Mijaković, Sara, Grbović Novaković, Jasmina, Tošić, Katarina, Mitrović Rajić, Anđela, Paskaš Mamula, Bojana, Vujačić Nikezić, Ana, "Physicochemical characterization of mechanochemically activated pyrophyllite/Ag composites" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):46-46,
https://hdl.handle.net/21.15107/rcub_vinar_12319 .

TY  - CONF
AU  - Grbović Novaković, Jasmina
AU  - Mitrović Rajić, Anđela
AU  - Tošić, Katarina
AU  - Mijaković, Sara
AU  - Milošević Govedarović, Sanja
AU  - Vujačić Nikezić, Ana
AU  - Paskaš Mamula, Bojana
AU  - Kustura, Jasmina
AU  - Kurtanović, Enita
AU  - Halilhodžić, Belma
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12508
AB  - The work aims to design a pyrophyllite-modified carbon paste electrode for pesticide detection in aqueous solutions. The structural and morphological characterization of natural pyrophyllite clay for Parsovići mine, Bosnia and Herzegovina, and mechanically modified pyrophyllite was performed using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and particle size analysis (PSD). The electrochemical characteristics of the constructed electrode were investigated using cyclic voltammetry in 1 mM K4Fe(CN)6 in 0.1 M KCl and 0.5 M H2SO4 and differential pulse stripping voltammetry in Britton- Robinson buffer at pH 2-8. It was shown that the maximum at + 0.96 V versus Ag/AgCl originates from oxidation by carbendazim at pH 4 in the Britton-Robinson buffer. The electrode designed in this way showed numerous advantages such as good stability and sensitivity. The developed analytical method is linear over the range of 1 ppm to 10 ppm with r=0.999 and a detection limit of 0.3 ppm.
PB  - Zenica : Univerzitet u Zenici, Metalurško-tehnološki fakultet
C3  - 14th Scientific - Research Symposium with International Participation "Metallic and Nonmetallic Materials" : Book of Abstracts with Electronic Edition of Proceedings = XIV Naučno - stručni simpozijum sa međunarodnim učešćem "Metalni i nemetalni materijali" : knjiga abstrakta sa elektronskim izdanjem Zbornika radova
T1  - Pyrophyllite-Modified Carbon Paste Electrode for Carbendazim Detection in Water and Food
SP  - 1
EP  - 9
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12508
ER  - 

@conference{
author = "Grbović Novaković, Jasmina and Mitrović Rajić, Anđela and Tošić, Katarina and Mijaković, Sara and Milošević Govedarović, Sanja and Vujačić Nikezić, Ana and Paskaš Mamula, Bojana and Kustura, Jasmina and Kurtanović, Enita and Halilhodžić, Belma",
year = "2023",
abstract = "The work aims to design a pyrophyllite-modified carbon paste electrode for pesticide detection in aqueous solutions. The structural and morphological characterization of natural pyrophyllite clay for Parsovići mine, Bosnia and Herzegovina, and mechanically modified pyrophyllite was performed using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and particle size analysis (PSD). The electrochemical characteristics of the constructed electrode were investigated using cyclic voltammetry in 1 mM K4Fe(CN)6 in 0.1 M KCl and 0.5 M H2SO4 and differential pulse stripping voltammetry in Britton- Robinson buffer at pH 2-8. It was shown that the maximum at + 0.96 V versus Ag/AgCl originates from oxidation by carbendazim at pH 4 in the Britton-Robinson buffer. The electrode designed in this way showed numerous advantages such as good stability and sensitivity. The developed analytical method is linear over the range of 1 ppm to 10 ppm with r=0.999 and a detection limit of 0.3 ppm.",
publisher = "Zenica : Univerzitet u Zenici, Metalurško-tehnološki fakultet",
journal = "14th Scientific - Research Symposium with International Participation "Metallic and Nonmetallic Materials" : Book of Abstracts with Electronic Edition of Proceedings = XIV Naučno - stručni simpozijum sa međunarodnim učešćem "Metalni i nemetalni materijali" : knjiga abstrakta sa elektronskim izdanjem Zbornika radova",
title = "Pyrophyllite-Modified Carbon Paste Electrode for Carbendazim Detection in Water and Food",
pages = "1-9",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12508"
}

Grbović Novaković, J., Mitrović Rajić, A., Tošić, K., Mijaković, S., Milošević Govedarović, S., Vujačić Nikezić, A., Paskaš Mamula, B., Kustura, J., Kurtanović, E.,& Halilhodžić, B.. (2023). Pyrophyllite-Modified Carbon Paste Electrode for Carbendazim Detection in Water and Food. in 14th Scientific - Research Symposium with International Participation "Metallic and Nonmetallic Materials" : Book of Abstracts with Electronic Edition of Proceedings = XIV Naučno - stručni simpozijum sa međunarodnim učešćem "Metalni i nemetalni materijali" : knjiga abstrakta sa elektronskim izdanjem Zbornika radova
Zenica : Univerzitet u Zenici, Metalurško-tehnološki fakultet., 1-9.
https://hdl.handle.net/21.15107/rcub_vinar_12508

Grbović Novaković J, Mitrović Rajić A, Tošić K, Mijaković S, Milošević Govedarović S, Vujačić Nikezić A, Paskaš Mamula B, Kustura J, Kurtanović E, Halilhodžić B. Pyrophyllite-Modified Carbon Paste Electrode for Carbendazim Detection in Water and Food. in 14th Scientific - Research Symposium with International Participation "Metallic and Nonmetallic Materials" : Book of Abstracts with Electronic Edition of Proceedings = XIV Naučno - stručni simpozijum sa međunarodnim učešćem "Metalni i nemetalni materijali" : knjiga abstrakta sa elektronskim izdanjem Zbornika radova. 2023;:1-9.
https://hdl.handle.net/21.15107/rcub_vinar_12508 .

Grbović Novaković, Jasmina, Mitrović Rajić, Anđela, Tošić, Katarina, Mijaković, Sara, Milošević Govedarović, Sanja, Vujačić Nikezić, Ana, Paskaš Mamula, Bojana, Kustura, Jasmina, Kurtanović, Enita, Halilhodžić, Belma, "Pyrophyllite-Modified Carbon Paste Electrode for Carbendazim Detection in Water and Food" in 14th Scientific - Research Symposium with International Participation "Metallic and Nonmetallic Materials" : Book of Abstracts with Electronic Edition of Proceedings = XIV Naučno - stručni simpozijum sa međunarodnim učešćem "Metalni i nemetalni materijali" : knjiga abstrakta sa elektronskim izdanjem Zbornika radova (2023):1-9,
https://hdl.handle.net/21.15107/rcub_vinar_12508 .

TY  - CONF
AU  - Mitrović Rajić, Anđela
AU  - Tošić, Katarina
AU  - Mijaković, Sara
AU  - Milošević Govedarović, Sanja
AU  - Vujačić Nikezić, Ana
AU  - Paskaš Mamula, Bojana
AU  - Grbović Novaković, Jasmina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12513
AB  - Ovaj rad ima za cilj da dizajnira elektrodu od ugljenične paste modifikovanu pirofilitom za
potencijalnu upotrebu za detekciju pesticida u vodenim rastvorima. Strukturna i morfološka
karakterizacija prirodne gline pirofilit i mehanički modifikovanog pirofilita urađena je
rendgenostrukturnom analizom i skenirajućom elektronskom mikroskopijom. Elektrohemijske
karakteristike ove elektrode ispitivane su cikličnom voltametrijom u 1 mM K4Fe(CN)6 u 0,1 M
KCl i 0,5 M H2SO4 i diferencijalnom pulsnom „striping“ voltametrijom u Briton-Robinsonovom
puferu na pH 4. Pokazano je da maksimum na + 0,96 V u odnosu na Ag/AgCl elektrodu potiče
od oksidacije karbendazima na pH 4 u Briton-Robinsonovom puferu. Dobru stabilnost i
osetljivost pokazala je elektroda koja je sadržala 50% ugljenične paste i 50% pirofilita mehanički
modifikovanog 15 minuta u mlinu sa kuglama. Razvijena metoda je linearna u opsegu od 1 ppm
do 10 ppm sa r= 0,999 i granicom detekcije od 0,3 ppm.
PB  - Novi Sad : Prirodno-matematički fakultet
C3  - 10. memorijalni naučni skup iz zaštite životne sredine "docent dr Milena Dalmacija" : Knjiga radova
T1  - Detekcija fungicida karbendazima u vodi primenom elektrode od ugljenične paste modifikovane pirofilitom
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12513
ER  - 

@conference{
author = "Mitrović Rajić, Anđela and Tošić, Katarina and Mijaković, Sara and Milošević Govedarović, Sanja and Vujačić Nikezić, Ana and Paskaš Mamula, Bojana and Grbović Novaković, Jasmina",
year = "2023",
abstract = "Ovaj rad ima za cilj da dizajnira elektrodu od ugljenične paste modifikovanu pirofilitom za
potencijalnu upotrebu za detekciju pesticida u vodenim rastvorima. Strukturna i morfološka
karakterizacija prirodne gline pirofilit i mehanički modifikovanog pirofilita urađena je
rendgenostrukturnom analizom i skenirajućom elektronskom mikroskopijom. Elektrohemijske
karakteristike ove elektrode ispitivane su cikličnom voltametrijom u 1 mM K4Fe(CN)6 u 0,1 M
KCl i 0,5 M H2SO4 i diferencijalnom pulsnom „striping“ voltametrijom u Briton-Robinsonovom
puferu na pH 4. Pokazano je da maksimum na + 0,96 V u odnosu na Ag/AgCl elektrodu potiče
od oksidacije karbendazima na pH 4 u Briton-Robinsonovom puferu. Dobru stabilnost i
osetljivost pokazala je elektroda koja je sadržala 50% ugljenične paste i 50% pirofilita mehanički
modifikovanog 15 minuta u mlinu sa kuglama. Razvijena metoda je linearna u opsegu od 1 ppm
do 10 ppm sa r= 0,999 i granicom detekcije od 0,3 ppm.",
publisher = "Novi Sad : Prirodno-matematički fakultet",
journal = "10. memorijalni naučni skup iz zaštite životne sredine "docent dr Milena Dalmacija" : Knjiga radova",
title = "Detekcija fungicida karbendazima u vodi primenom elektrode od ugljenične paste modifikovane pirofilitom",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12513"
}

Mitrović Rajić, A., Tošić, K., Mijaković, S., Milošević Govedarović, S., Vujačić Nikezić, A., Paskaš Mamula, B.,& Grbović Novaković, J.. (2023). Detekcija fungicida karbendazima u vodi primenom elektrode od ugljenične paste modifikovane pirofilitom. in 10. memorijalni naučni skup iz zaštite životne sredine "docent dr Milena Dalmacija" : Knjiga radova
Novi Sad : Prirodno-matematički fakultet..
https://hdl.handle.net/21.15107/rcub_vinar_12513

Mitrović Rajić A, Tošić K, Mijaković S, Milošević Govedarović S, Vujačić Nikezić A, Paskaš Mamula B, Grbović Novaković J. Detekcija fungicida karbendazima u vodi primenom elektrode od ugljenične paste modifikovane pirofilitom. in 10. memorijalni naučni skup iz zaštite životne sredine "docent dr Milena Dalmacija" : Knjiga radova. 2023;.
https://hdl.handle.net/21.15107/rcub_vinar_12513 .

Mitrović Rajić, Anđela, Tošić, Katarina, Mijaković, Sara, Milošević Govedarović, Sanja, Vujačić Nikezić, Ana, Paskaš Mamula, Bojana, Grbović Novaković, Jasmina, "Detekcija fungicida karbendazima u vodi primenom elektrode od ugljenične paste modifikovane pirofilitom" in 10. memorijalni naučni skup iz zaštite životne sredine "docent dr Milena Dalmacija" : Knjiga radova (2023),
https://hdl.handle.net/21.15107/rcub_vinar_12513 .

TY  - JOUR
AU  - Mitrović Rajić, Anđela
AU  - Pantić, Tijana
AU  - Milošević-Govedarović, Sanja
AU  - Paskaš Mamula, Bojana
AU  - Filipović, Nenad
AU  - Grbović Novaković, Jasmina
AU  - Dimitrijević, Silvana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12882
AB  - The effect of mechanical milling on the thermal behavior of pyrophyllite ore from a deposit in Parsovići, Bosnia and Herzegovina, was characterized by X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and Particle size distribution. The thermal behavior of the material was followed by thermogravimetric and differential thermal analysis and correlated to its microstructural properties. The Williamson-Hall model was used to calculate the crystallite size and microstrain. Mechanochemical treatment of pyrophyllite ore produced a substantial structural modification, mainly along the c axis, resulting in disorder and partial degradation of the crystal structure of the ore. The particle size diminution, induced defects, and microstrain in the crystal lattice cause decrease in the peak intensity until the final disappearance. As confirmed by scanning electron microscopy and particle-size-distribution analysis, the surface area and the agglomeration is more pronounced as grinding time increases. Dehydroxylation of the minerals in the unmilled ore was realized at 716oC confirm by FTIR analysis. The endothermic peak that corresponds to dehydroxylation is shifted toward lower temperatures and becomes broad giving rise to the formation of amorphous SiO2 as milling time increases.
T2  - Science of Sintering
T1  - Influence of mechanochemical activation on the thermal behavior of pyrophyllite
VL  - 55
SP  - 453
EP  - 467
DO  - 10.2298/SOS220715018M
ER  - 

@article{
author = "Mitrović Rajić, Anđela and Pantić, Tijana and Milošević-Govedarović, Sanja and Paskaš Mamula, Bojana and Filipović, Nenad and Grbović Novaković, Jasmina and Dimitrijević, Silvana",
year = "2023",
abstract = "The effect of mechanical milling on the thermal behavior of pyrophyllite ore from a deposit in Parsovići, Bosnia and Herzegovina, was characterized by X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and Particle size distribution. The thermal behavior of the material was followed by thermogravimetric and differential thermal analysis and correlated to its microstructural properties. The Williamson-Hall model was used to calculate the crystallite size and microstrain. Mechanochemical treatment of pyrophyllite ore produced a substantial structural modification, mainly along the c axis, resulting in disorder and partial degradation of the crystal structure of the ore. The particle size diminution, induced defects, and microstrain in the crystal lattice cause decrease in the peak intensity until the final disappearance. As confirmed by scanning electron microscopy and particle-size-distribution analysis, the surface area and the agglomeration is more pronounced as grinding time increases. Dehydroxylation of the minerals in the unmilled ore was realized at 716oC confirm by FTIR analysis. The endothermic peak that corresponds to dehydroxylation is shifted toward lower temperatures and becomes broad giving rise to the formation of amorphous SiO2 as milling time increases.",
journal = "Science of Sintering",
title = "Influence of mechanochemical activation on the thermal behavior of pyrophyllite",
volume = "55",
pages = "453-467",
doi = "10.2298/SOS220715018M"
}

Mitrović Rajić, A., Pantić, T., Milošević-Govedarović, S., Paskaš Mamula, B., Filipović, N., Grbović Novaković, J.,& Dimitrijević, S.. (2023). Influence of mechanochemical activation on the thermal behavior of pyrophyllite. in Science of Sintering, 55, 453-467.
https://doi.org/10.2298/SOS220715018M

Mitrović Rajić A, Pantić T, Milošević-Govedarović S, Paskaš Mamula B, Filipović N, Grbović Novaković J, Dimitrijević S. Influence of mechanochemical activation on the thermal behavior of pyrophyllite. in Science of Sintering. 2023;55:453-467.
doi:10.2298/SOS220715018M .

Mitrović Rajić, Anđela, Pantić, Tijana, Milošević-Govedarović, Sanja, Paskaš Mamula, Bojana, Filipović, Nenad, Grbović Novaković, Jasmina, Dimitrijević, Silvana, "Influence of mechanochemical activation on the thermal behavior of pyrophyllite" in Science of Sintering, 55 (2023):453-467,
https://doi.org/10.2298/SOS220715018M . .

TY  - JOUR
AU  - Mitrović Rajić, Anđela I.
AU  - Milićević, Jelena S.
AU  - Grbović-Novaković, Jasmina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10472
AB  - This study aims to design the pyrophyllite-adapted carbon paste electrode (pCPE) and test it for potential use in wastewater purification systems. Structural characterization of pure pyrophyllite ore and mechanically modified pyrophyllite in mortar and pestle has been followed by XRD, SEM, PSA, and FTIR. Electrochemical characteristics were studied by cyclic voltammetry of pyrophyllite CPE in sulfuric acid and potassium ferrocyanide, as redox model compounds. Delamination, gliding, and folding of the layers and a decrease in particle and crystallite size have been observed, leading to the excellent electrocatalytic activity of pCPE. The developed pCPE has numerous benefits such as a simple preparation method, rapid response, and good sensitivity. The oxidation peak of carbendazim appears in Britton-Robinson buffer solutions (pH 4) at +0.9 V vs. Ag/AgCl. The developed method is linear in the concentration range of 3.2–29.2 ng cm−3, with r = 0.999 and the limit of detection of 1.9 ng cm−3.
T2  - Materials and Manufacturing Processes
T1  - Development of modified pyrophyllite carbon paste electrode for carbendazim detection
VL  - 38
IS  - 13
SP  - 1
EP  - 7
DO  - 10.1080/10426914.2022.2136386
ER  - 

@article{
author = "Mitrović Rajić, Anđela I. and Milićević, Jelena S. and Grbović-Novaković, Jasmina",
year = "2023",
abstract = "This study aims to design the pyrophyllite-adapted carbon paste electrode (pCPE) and test it for potential use in wastewater purification systems. Structural characterization of pure pyrophyllite ore and mechanically modified pyrophyllite in mortar and pestle has been followed by XRD, SEM, PSA, and FTIR. Electrochemical characteristics were studied by cyclic voltammetry of pyrophyllite CPE in sulfuric acid and potassium ferrocyanide, as redox model compounds. Delamination, gliding, and folding of the layers and a decrease in particle and crystallite size have been observed, leading to the excellent electrocatalytic activity of pCPE. The developed pCPE has numerous benefits such as a simple preparation method, rapid response, and good sensitivity. The oxidation peak of carbendazim appears in Britton-Robinson buffer solutions (pH 4) at +0.9 V vs. Ag/AgCl. The developed method is linear in the concentration range of 3.2–29.2 ng cm−3, with r = 0.999 and the limit of detection of 1.9 ng cm−3.",
journal = "Materials and Manufacturing Processes",
title = "Development of modified pyrophyllite carbon paste electrode for carbendazim detection",
volume = "38",
number = "13",
pages = "1-7",
doi = "10.1080/10426914.2022.2136386"
}

Mitrović Rajić, A. I., Milićević, J. S.,& Grbović-Novaković, J.. (2023). Development of modified pyrophyllite carbon paste electrode for carbendazim detection. in Materials and Manufacturing Processes, 38(13), 1-7.
https://doi.org/10.1080/10426914.2022.2136386

Mitrović Rajić AI, Milićević JS, Grbović-Novaković J. Development of modified pyrophyllite carbon paste electrode for carbendazim detection. in Materials and Manufacturing Processes. 2023;38(13):1-7.
doi:10.1080/10426914.2022.2136386 .

Mitrović Rajić, Anđela I., Milićević, Jelena S., Grbović-Novaković, Jasmina, "Development of modified pyrophyllite carbon paste electrode for carbendazim detection" in Materials and Manufacturing Processes, 38, no. 13 (2023):1-7,
https://doi.org/10.1080/10426914.2022.2136386 . .

TY  - CONF
AU  - Grbović Novaković,  Jasmina
AU  - Mitrović Rajić, Anđela
AU  - Pantić, T.
AU  - Milošević Govedarović, Sanja
AU  - Novaković, Nikola
AU  - Rmuš Mravik, Jelena
AU  - Paskaš-Mamula, Bojana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12738
AB  - The main goal is to develop electrode material for the detection of traces of pesticides in food and water in a wide range of pH values. The leading idea is to use natural clay pyrophyllite to modify carbon paste electrode. SPEX Mixer/Mill 5100 is used for mechanochemical modification. The changes in the structure of pyrophyllite before and after the grinding process were studied by means of PSD, XRD, FTIR, and DTA-TG [1]. The electrochemical behavior of the sensor was followed using differential pulse stripping voltammetry (DPSV). It is shown that obtained material can be used as electrodes in electrochemical sensors for pesticide detection in a wide range of pH.
PB  - Zagreb, Croatia : Ruđer Bošković Institute
C3  - Solid-State Science & Research Meeting : Book of abstracts and programme
T1  - Pyrophyllite modified carbon-based electrode
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12738
ER  - 

@conference{
author = "Grbović Novaković,  Jasmina and Mitrović Rajić, Anđela and Pantić, T. and Milošević Govedarović, Sanja and Novaković, Nikola and Rmuš Mravik, Jelena and Paskaš-Mamula, Bojana",
year = "2023",
abstract = "The main goal is to develop electrode material for the detection of traces of pesticides in food and water in a wide range of pH values. The leading idea is to use natural clay pyrophyllite to modify carbon paste electrode. SPEX Mixer/Mill 5100 is used for mechanochemical modification. The changes in the structure of pyrophyllite before and after the grinding process were studied by means of PSD, XRD, FTIR, and DTA-TG [1]. The electrochemical behavior of the sensor was followed using differential pulse stripping voltammetry (DPSV). It is shown that obtained material can be used as electrodes in electrochemical sensors for pesticide detection in a wide range of pH.",
publisher = "Zagreb, Croatia : Ruđer Bošković Institute",
journal = "Solid-State Science & Research Meeting : Book of abstracts and programme",
title = "Pyrophyllite modified carbon-based electrode",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12738"
}

Grbović Novaković, J., Mitrović Rajić, A., Pantić, T., Milošević Govedarović, S., Novaković, N., Rmuš Mravik, J.,& Paskaš-Mamula, B.. (2023). Pyrophyllite modified carbon-based electrode. in Solid-State Science & Research Meeting : Book of abstracts and programme
Zagreb, Croatia : Ruđer Bošković Institute..
https://hdl.handle.net/21.15107/rcub_vinar_12738

Grbović Novaković J, Mitrović Rajić A, Pantić T, Milošević Govedarović S, Novaković N, Rmuš Mravik J, Paskaš-Mamula B. Pyrophyllite modified carbon-based electrode. in Solid-State Science & Research Meeting : Book of abstracts and programme. 2023;.
https://hdl.handle.net/21.15107/rcub_vinar_12738 .

Grbović Novaković,  Jasmina, Mitrović Rajić, Anđela, Pantić, T., Milošević Govedarović, Sanja, Novaković, Nikola, Rmuš Mravik, Jelena, Paskaš-Mamula, Bojana, "Pyrophyllite modified carbon-based electrode" in Solid-State Science & Research Meeting : Book of abstracts and programme (2023),
https://hdl.handle.net/21.15107/rcub_vinar_12738 .

TY  - CONF
AU  - Sekulić, Zorana
AU  - Babić, Bojana
AU  - Prvulović, Milica
AU  - Milanović, Igor
AU  - Tošić, Katarina
AU  - Asanović, Vanja
AU  - Novaković, Nikola
AU  - Milošević Govedarović, Sanja
AU  - Grbović Novaković, Jasmina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12737
AB  - Hydrogen as an energy vector represents great potential, due to its high gravimetric density and low mass, as well as the fact that combustion does not emit harmful chemical byproducts. Hydrogen has the highest energy density per unit mass compared to any other fuel but a rather low energy density per unit volume. Further, hydrogen storage is a key technology for developing a hydrogen and fuel cell-based economy [1]. Metal hydrides as alternative hydrogen carriers have a wide range of performance parameters such as operating temperature, sorption kinetics, activation conditions, cyclic options, and equilibrium hydrogen pressure. These parameters can be improved or adjusted to meet the technical requirements of different applications. The most commonly used method for hydride destabilization is nanostructuring by mechanical milling which leads to a reduction in the particle and crystallite size of the MgH2 powder. Nanostructuring is often combined with catalyst addition and composite formation [2,3]. The most of research is focused on the morphological, structural, and thermodynamic effects typical for long milling times, while in this work we have followed the changes taking place under short milling times. The thermal stability of magnesium hydride is related to - changes in the crystallites and powder particle size. The analysis also considered the changes in activation energy. MgH2-M composites were prepared by mechanical milling of the as-received MgH2 powder (Alfa Aesar, 98% purity) with the addition of 2 and 5 wt.% of M (M= V, W, Mo). Mechanical milling was performed in s SPEX 5100 Mixer Mill using 8mm diameter milling ball. Samples were milled for 15-45 minutes under the inert atmosphere of argon and a ball-to-powder ratio 10:1 Figure 1. shows the kinetic curves obtained for composites with 5wt% of vanadium. To investigate the desorption process in detail, different models of solid-state kinetics were used as implemented in the code developed in our group. The ratelimiting step of the desorption reaction was determined using the iso-conversional kinetic method due to better accuracy of obtained apparent activation energies. As shown in Table 1 a decrease in apparent activation energies has been observed. It is obvious that the sorption kinetics is affected by material preparation because the reactivity of magnesium with hydrogen is strongly modified by changes in several surface parameters that govern the chemisorption, the dissociation of molecular hydrogen, and hydride nucleation
C3  - 7th MESC-IS 2023 : International Symposium on Materials for Energy Storage and Conversion
T1  - Kinetic behavior of MgH2-transition metal composites: towards hydrogen storage
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12737
ER  - 

@conference{
author = "Sekulić, Zorana and Babić, Bojana and Prvulović, Milica and Milanović, Igor and Tošić, Katarina and Asanović, Vanja and Novaković, Nikola and Milošević Govedarović, Sanja and Grbović Novaković, Jasmina",
year = "2023",
abstract = "Hydrogen as an energy vector represents great potential, due to its high gravimetric density and low mass, as well as the fact that combustion does not emit harmful chemical byproducts. Hydrogen has the highest energy density per unit mass compared to any other fuel but a rather low energy density per unit volume. Further, hydrogen storage is a key technology for developing a hydrogen and fuel cell-based economy [1]. Metal hydrides as alternative hydrogen carriers have a wide range of performance parameters such as operating temperature, sorption kinetics, activation conditions, cyclic options, and equilibrium hydrogen pressure. These parameters can be improved or adjusted to meet the technical requirements of different applications. The most commonly used method for hydride destabilization is nanostructuring by mechanical milling which leads to a reduction in the particle and crystallite size of the MgH2 powder. Nanostructuring is often combined with catalyst addition and composite formation [2,3]. The most of research is focused on the morphological, structural, and thermodynamic effects typical for long milling times, while in this work we have followed the changes taking place under short milling times. The thermal stability of magnesium hydride is related to - changes in the crystallites and powder particle size. The analysis also considered the changes in activation energy. MgH2-M composites were prepared by mechanical milling of the as-received MgH2 powder (Alfa Aesar, 98% purity) with the addition of 2 and 5 wt.% of M (M= V, W, Mo). Mechanical milling was performed in s SPEX 5100 Mixer Mill using 8mm diameter milling ball. Samples were milled for 15-45 minutes under the inert atmosphere of argon and a ball-to-powder ratio 10:1 Figure 1. shows the kinetic curves obtained for composites with 5wt% of vanadium. To investigate the desorption process in detail, different models of solid-state kinetics were used as implemented in the code developed in our group. The ratelimiting step of the desorption reaction was determined using the iso-conversional kinetic method due to better accuracy of obtained apparent activation energies. As shown in Table 1 a decrease in apparent activation energies has been observed. It is obvious that the sorption kinetics is affected by material preparation because the reactivity of magnesium with hydrogen is strongly modified by changes in several surface parameters that govern the chemisorption, the dissociation of molecular hydrogen, and hydride nucleation",
journal = "7th MESC-IS 2023 : International Symposium on Materials for Energy Storage and Conversion",
title = "Kinetic behavior of MgH2-transition metal composites: towards hydrogen storage",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12737"
}

Sekulić, Z., Babić, B., Prvulović, M., Milanović, I., Tošić, K., Asanović, V., Novaković, N., Milošević Govedarović, S.,& Grbović Novaković, J.. (2023). Kinetic behavior of MgH2-transition metal composites: towards hydrogen storage. in 7th MESC-IS 2023 : International Symposium on Materials for Energy Storage and Conversion.
https://hdl.handle.net/21.15107/rcub_vinar_12737

Sekulić Z, Babić B, Prvulović M, Milanović I, Tošić K, Asanović V, Novaković N, Milošević Govedarović S, Grbović Novaković J. Kinetic behavior of MgH2-transition metal composites: towards hydrogen storage. in 7th MESC-IS 2023 : International Symposium on Materials for Energy Storage and Conversion. 2023;.
https://hdl.handle.net/21.15107/rcub_vinar_12737 .

Sekulić, Zorana, Babić, Bojana, Prvulović, Milica, Milanović, Igor, Tošić, Katarina, Asanović, Vanja, Novaković, Nikola, Milošević Govedarović, Sanja, Grbović Novaković, Jasmina, "Kinetic behavior of MgH2-transition metal composites: towards hydrogen storage" in 7th MESC-IS 2023 : International Symposium on Materials for Energy Storage and Conversion (2023),
https://hdl.handle.net/21.15107/rcub_vinar_12737 .

TY  - JOUR
AU  - Pantić, Tijana
AU  - Paskaš Mamula, Bojana
AU  - Soderžnik, Žagar K.
AU  - Kurko, Sandra
AU  - Milanović, Igor
AU  - Novaković, Nikola
AU  - Šturm, S.
AU  - Drev, Sandra
AU  - Grbović-Novaković, Jasmina
AU  - Milošević Govedarović, Sanja S.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11029
AB  - In this paper hydrogen sorption properties of Mg–V multilayer thin films are studied. Thin films are synthesized by means of RF magnetron sputtering. Further modification of material is done using low energy H ion irradiation. The hydrogen sorption properties and kinetics are assessed using TOF-ERDA, in situ optical microscopy coupled with TDS, and TEM analysis. The results of TOF-ERDA indicate full hydrogenation of samples, although the presence of oxygen throughout the film is observed. It corresponds to the formation of MgO, also confirmed by EELS results with hydride plasmon peak hindered by MgO peak. Hydrogenation causes severe damage to the surface of the film and fragmentation of the V layer. TDS and optical analysis indicate lower desorption temperatures for thinner films. The desorption onset does not depend on defects concentration. The kinetic analysis further shows that the apparent activation energy for the thinner film is two times lower.
T2  - International Journal of Hydrogen Energy
T1  - The influence of defects on hydrogen sorption from Mg–V thin films
VL  - InPress
DO  - 10.1016/j.ijhydene.2023.04.079
ER  - 

@article{
author = "Pantić, Tijana and Paskaš Mamula, Bojana and Soderžnik, Žagar K. and Kurko, Sandra and Milanović, Igor and Novaković, Nikola and Šturm, S. and Drev, Sandra and Grbović-Novaković, Jasmina and Milošević Govedarović, Sanja S.",
year = "2023",
abstract = "In this paper hydrogen sorption properties of Mg–V multilayer thin films are studied. Thin films are synthesized by means of RF magnetron sputtering. Further modification of material is done using low energy H ion irradiation. The hydrogen sorption properties and kinetics are assessed using TOF-ERDA, in situ optical microscopy coupled with TDS, and TEM analysis. The results of TOF-ERDA indicate full hydrogenation of samples, although the presence of oxygen throughout the film is observed. It corresponds to the formation of MgO, also confirmed by EELS results with hydride plasmon peak hindered by MgO peak. Hydrogenation causes severe damage to the surface of the film and fragmentation of the V layer. TDS and optical analysis indicate lower desorption temperatures for thinner films. The desorption onset does not depend on defects concentration. The kinetic analysis further shows that the apparent activation energy for the thinner film is two times lower.",
journal = "International Journal of Hydrogen Energy",
title = "The influence of defects on hydrogen sorption from Mg–V thin films",
volume = "InPress",
doi = "10.1016/j.ijhydene.2023.04.079"
}

Pantić, T., Paskaš Mamula, B., Soderžnik, Ž. K., Kurko, S., Milanović, I., Novaković, N., Šturm, S., Drev, S., Grbović-Novaković, J.,& Milošević Govedarović, S. S.. (2023). The influence of defects on hydrogen sorption from Mg–V thin films. in International Journal of Hydrogen Energy, InPress.
https://doi.org/10.1016/j.ijhydene.2023.04.079

Pantić T, Paskaš Mamula B, Soderžnik ŽK, Kurko S, Milanović I, Novaković N, Šturm S, Drev S, Grbović-Novaković J, Milošević Govedarović SS. The influence of defects on hydrogen sorption from Mg–V thin films. in International Journal of Hydrogen Energy. 2023;InPress.
doi:10.1016/j.ijhydene.2023.04.079 .

Pantić, Tijana, Paskaš Mamula, Bojana, Soderžnik, Žagar K., Kurko, Sandra, Milanović, Igor, Novaković, Nikola, Šturm, S., Drev, Sandra, Grbović-Novaković, Jasmina, Milošević Govedarović, Sanja S., "The influence of defects on hydrogen sorption from Mg–V thin films" in International Journal of Hydrogen Energy, InPress (2023),
https://doi.org/10.1016/j.ijhydene.2023.04.079 . .

TY  - JOUR
AU  - Sekulić, Zorana
AU  - Grbović Novaković, Jasmina
AU  - Babić, Bojana
AU  - Prvulović, Milica
AU  - Milanović, Igor
AU  - Novaković, Nikola
AU  - Rajnović, Dragan
AU  - Filipović, Nenad
AU  - Asanović, Vanja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11436
AB  - The effects of catalysis using vanadium as an additive (2 and 5 wt.%) in a high-energy ball mill on composite desorption properties were examined. The influence of microstructure on the dehydration temperature and hydrogen desorption kinetics was monitored. Morphological and microstructural studies of the synthesized sample were performed by X-ray diffraction (XRD), laser particle size distribution (PSD), and scanning electron microscopy (SEM) methods, while differential scanning calorimetry (DSC) determined thermal properties. To further access amorph species in the milling blend, the absorption spectra were obtained by FTIR-ATR analysis (Fourier transform infrared spectroscopy attenuated total reflection). The results show lower apparent activation energy (Eapp) and H2 desorption temperature are obtained for milling bland with 5 wt.% added vanadium. The best explanation of hydrogen desorption reaction shows the Avrami-Erofeev model for parameter n = 4. Since the obtained value of apparent activation energy is close to the Mg-H bond-breaking energy, one can conclude that breaking this bond would be the rate-limiting step of the process.
T2  - Materials
T1  - The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time
VL  - 16
IS  - 15
SP  - 5480
DO  - 10.3390/ma16155480
ER  - 

@article{
author = "Sekulić, Zorana and Grbović Novaković, Jasmina and Babić, Bojana and Prvulović, Milica and Milanović, Igor and Novaković, Nikola and Rajnović, Dragan and Filipović, Nenad and Asanović, Vanja",
year = "2023",
abstract = "The effects of catalysis using vanadium as an additive (2 and 5 wt.%) in a high-energy ball mill on composite desorption properties were examined. The influence of microstructure on the dehydration temperature and hydrogen desorption kinetics was monitored. Morphological and microstructural studies of the synthesized sample were performed by X-ray diffraction (XRD), laser particle size distribution (PSD), and scanning electron microscopy (SEM) methods, while differential scanning calorimetry (DSC) determined thermal properties. To further access amorph species in the milling blend, the absorption spectra were obtained by FTIR-ATR analysis (Fourier transform infrared spectroscopy attenuated total reflection). The results show lower apparent activation energy (Eapp) and H2 desorption temperature are obtained for milling bland with 5 wt.% added vanadium. The best explanation of hydrogen desorption reaction shows the Avrami-Erofeev model for parameter n = 4. Since the obtained value of apparent activation energy is close to the Mg-H bond-breaking energy, one can conclude that breaking this bond would be the rate-limiting step of the process.",
journal = "Materials",
title = "The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time",
volume = "16",
number = "15",
pages = "5480",
doi = "10.3390/ma16155480"
}

Sekulić, Z., Grbović Novaković, J., Babić, B., Prvulović, M., Milanović, I., Novaković, N., Rajnović, D., Filipović, N.,& Asanović, V.. (2023). The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time. in Materials, 16(15), 5480.
https://doi.org/10.3390/ma16155480

Sekulić Z, Grbović Novaković J, Babić B, Prvulović M, Milanović I, Novaković N, Rajnović D, Filipović N, Asanović V. The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time. in Materials. 2023;16(15):5480.
doi:10.3390/ma16155480 .

Sekulić, Zorana, Grbović Novaković, Jasmina, Babić, Bojana, Prvulović, Milica, Milanović, Igor, Novaković, Nikola, Rajnović, Dragan, Filipović, Nenad, Asanović, Vanja, "The Catalytic Effect of Vanadium on Sorption Properties of MgH2-Based Nanocomposites Obtained Using Low Milling Time" in Materials, 16, no. 15 (2023):5480,
https://doi.org/10.3390/ma16155480 . .

TY  - CHAP
AU  - Cvetković, Slobodan M.
AU  - Popović, Mina
AU  - Grbović-Novaković, Jasmina
AU  - Kijevčanin, Mirjana Lj.
AU  - Oncel, Suphi S.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11729
AB  - This chapter aims to evaluate energy flows in the life cycle of biogas utilization (i.e., production of thermal energy, cogeneration, traffic, and production of hydrogen), starting from feedstock and anaerobic digestion, up to the digestate as fertilizer for agricultural production. The analysis is based on the out-turn of a biogas plant on the dairy farm Mirotin Vrbas, Republic of Serbia. Life Cycle Energy Assessment (LCEA), presented in this chapter, has demonstrated that three scenarios – biogas for heat production, biogas in cogeneration, and biomethane in transportation have positive energy balances, which indicate that in terms of replacement of fossil fuel consumption, these energy systems are promising alternatives. In the fourth scenario, where biogas is used for hydrogen production, the energy balance is negative, therefore socio-economical factors should be considered for overall consideration to ensure sustainability.
PB  - Springer International Publishing
T2  - A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment
T2  - A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment
T1  - A Life Cycle Energy Assessment for Biogas as Energy Carrier
SP  - 595
EP  - 612
DO  - 10.1007/978-3-031-24942-6_28
ER  - 

@inbook{
author = "Cvetković, Slobodan M. and Popović, Mina and Grbović-Novaković, Jasmina and Kijevčanin, Mirjana Lj. and Oncel, Suphi S.",
year = "2023",
abstract = "This chapter aims to evaluate energy flows in the life cycle of biogas utilization (i.e., production of thermal energy, cogeneration, traffic, and production of hydrogen), starting from feedstock and anaerobic digestion, up to the digestate as fertilizer for agricultural production. The analysis is based on the out-turn of a biogas plant on the dairy farm Mirotin Vrbas, Republic of Serbia. Life Cycle Energy Assessment (LCEA), presented in this chapter, has demonstrated that three scenarios – biogas for heat production, biogas in cogeneration, and biomethane in transportation have positive energy balances, which indicate that in terms of replacement of fossil fuel consumption, these energy systems are promising alternatives. In the fourth scenario, where biogas is used for hydrogen production, the energy balance is negative, therefore socio-economical factors should be considered for overall consideration to ensure sustainability.",
publisher = "Springer International Publishing",
journal = "A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment, A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment",
booktitle = "A Life Cycle Energy Assessment for Biogas as Energy Carrier",
pages = "595-612",
doi = "10.1007/978-3-031-24942-6_28"
}

Cvetković, S. M., Popović, M., Grbović-Novaković, J., Kijevčanin, M. Lj.,& Oncel, S. S.. (2023). A Life Cycle Energy Assessment for Biogas as Energy Carrier. in A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment
Springer International Publishing., 595-612.
https://doi.org/10.1007/978-3-031-24942-6_28

Cvetković SM, Popović M, Grbović-Novaković J, Kijevčanin ML, Oncel SS. A Life Cycle Energy Assessment for Biogas as Energy Carrier. in A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment. 2023;:595-612.
doi:10.1007/978-3-031-24942-6_28 .

Cvetković, Slobodan M., Popović, Mina, Grbović-Novaković, Jasmina, Kijevčanin, Mirjana Lj., Oncel, Suphi S., "A Life Cycle Energy Assessment for Biogas as Energy Carrier" in A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment (2023):595-612,
https://doi.org/10.1007/978-3-031-24942-6_28 . .

TY  - JOUR
AU  - Wang, Jing
AU  - Dai, Min
AU  - Liu, Jiaxuan
AU  - Wu, Zhen
AU  - Zhang, Zaoxiao
AU  - Grbović-Novaković, Jasmina
AU  - Yang, Fusheng
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11545
AB  - Hydrogen storage using metal hydrides is one of the research hotspots in the field of energy storage. However, metal hydride powders are known to have low thermal conductivity, which causes significant temperature fluctuation and hinders further reaction, hence efficient thermal management is a must for hydrogen storage using metal hydrides. In this paper, based on the principle of entransy dissipation, the optimal profile of fin in a cylindrical reactor under steady-state conditions is deduced. The expression for the temperature distribution of the bed is also obtained, which could clearly account for the influences of multiple involving factors, such as fin thickness, fin spacing, and radius of reactor. Through simulation, the characteristic time of hydrogen absorption for reactor inserting the optimized fin, is shortened by 19.1 % compared with the conventional uniform thickness fin. The influence of the geometric parameters of storage reactor was further discussed. When the ratio of the inner and outer radius of the reactor is confined (rr/rt ≤ 2), linear thinning fin can be seen as a reasonable simplification of the optimized fin with comparable heat transfer enhancement effect. This study proves that the thermal management of metal hydride reactors, particularly those inserting high thermal conductivity materials like graphite, can be optimized quantitatively by entransy theory
T2  - Journal of Energy Storage
T1  - A novel design for fin profile in metal hydride reactor towards heat transfer enhancement: Theoretical derivations and analysis
VL  - 72
SP  - 108570
DO  - 10.1016/j.est.2023.108570
ER  - 

@article{
author = "Wang, Jing and Dai, Min and Liu, Jiaxuan and Wu, Zhen and Zhang, Zaoxiao and Grbović-Novaković, Jasmina and Yang, Fusheng",
year = "2023",
abstract = "Hydrogen storage using metal hydrides is one of the research hotspots in the field of energy storage. However, metal hydride powders are known to have low thermal conductivity, which causes significant temperature fluctuation and hinders further reaction, hence efficient thermal management is a must for hydrogen storage using metal hydrides. In this paper, based on the principle of entransy dissipation, the optimal profile of fin in a cylindrical reactor under steady-state conditions is deduced. The expression for the temperature distribution of the bed is also obtained, which could clearly account for the influences of multiple involving factors, such as fin thickness, fin spacing, and radius of reactor. Through simulation, the characteristic time of hydrogen absorption for reactor inserting the optimized fin, is shortened by 19.1 % compared with the conventional uniform thickness fin. The influence of the geometric parameters of storage reactor was further discussed. When the ratio of the inner and outer radius of the reactor is confined (rr/rt ≤ 2), linear thinning fin can be seen as a reasonable simplification of the optimized fin with comparable heat transfer enhancement effect. This study proves that the thermal management of metal hydride reactors, particularly those inserting high thermal conductivity materials like graphite, can be optimized quantitatively by entransy theory",
journal = "Journal of Energy Storage",
title = "A novel design for fin profile in metal hydride reactor towards heat transfer enhancement: Theoretical derivations and analysis",
volume = "72",
pages = "108570",
doi = "10.1016/j.est.2023.108570"
}

Wang, J., Dai, M., Liu, J., Wu, Z., Zhang, Z., Grbović-Novaković, J.,& Yang, F.. (2023). A novel design for fin profile in metal hydride reactor towards heat transfer enhancement: Theoretical derivations and analysis. in Journal of Energy Storage, 72, 108570.
https://doi.org/10.1016/j.est.2023.108570

Wang J, Dai M, Liu J, Wu Z, Zhang Z, Grbović-Novaković J, Yang F. A novel design for fin profile in metal hydride reactor towards heat transfer enhancement: Theoretical derivations and analysis. in Journal of Energy Storage. 2023;72:108570.
doi:10.1016/j.est.2023.108570 .

Wang, Jing, Dai, Min, Liu, Jiaxuan, Wu, Zhen, Zhang, Zaoxiao, Grbović-Novaković, Jasmina, Yang, Fusheng, "A novel design for fin profile in metal hydride reactor towards heat transfer enhancement: Theoretical derivations and analysis" in Journal of Energy Storage, 72 (2023):108570,
https://doi.org/10.1016/j.est.2023.108570 . .

TY  - JOUR
AU  - Milanović, Igor
AU  - Milošević Govedarović, Sanja S.
AU  - Lukić, Miodrag
AU  - Jovanović, Zoran
AU  - Rmuš, Jelena
AU  - Mitrović-Rajić, Anđela
AU  - Grbović-Novaković, Jasmina
AU  - Kurko, Sandra V.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10504
AB  - LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15min, and depending on the milling time, various phenomena took place. Up to a milling time of 5min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15min. Moreover, the mechanical milling process leads to the transformation of AlH - 4 to AlH 3 - 6 structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements.Mechanical milling with the addition of Fe2O3 for up to 15min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.
T2  - Processing and Application of Ceramics
T1  - Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites
VL  - 16
IS  - 3
SP  - 259
EP  - 266
DO  - 10.2298/PAC2203259M
ER  - 

@article{
author = "Milanović, Igor and Milošević Govedarović, Sanja S. and Lukić, Miodrag and Jovanović, Zoran and Rmuš, Jelena and Mitrović-Rajić, Anđela and Grbović-Novaković, Jasmina and Kurko, Sandra V.",
year = "2022",
abstract = "LiAlH4 was modified by mechanical milling and with the addition of 5 wt.% Fe2O3 in order to improve its hydrogen desorption properties. The composite was milled for 1, 3, 5, 7 or 15min, and depending on the milling time, various phenomena took place. Up to a milling time of 5min, the particle size of the composite decreases. Further milling leads to the particles agglomeration reaching the size of the starting material after 15min. Moreover, the mechanical milling process leads to the transformation of AlH - 4 to AlH 3 - 6 structure as a result of partial hydrogen desorption. Hydrogen desorption during the milling is the most pronounced in the sample milled for 15min, so this sample has only one hydrogen desorption peak in the temperature-programmed desorption measurements.Mechanical milling with the addition of Fe2O3 for up to 15min improves LiAlH4 hydrogen desorption properties as hydrogen desorption temperature and apparent activation energies decrease.",
journal = "Processing and Application of Ceramics",
title = "Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites",
volume = "16",
number = "3",
pages = "259-266",
doi = "10.2298/PAC2203259M"
}

Milanović, I., Milošević Govedarović, S. S., Lukić, M., Jovanović, Z., Rmuš, J., Mitrović-Rajić, A., Grbović-Novaković, J.,& Kurko, S. V.. (2022). Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. in Processing and Application of Ceramics, 16(3), 259-266.
https://doi.org/10.2298/PAC2203259M

Milanović I, Milošević Govedarović SS, Lukić M, Jovanović Z, Rmuš J, Mitrović-Rajić A, Grbović-Novaković J, Kurko SV. Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites. in Processing and Application of Ceramics. 2022;16(3):259-266.
doi:10.2298/PAC2203259M .

Milanović, Igor, Milošević Govedarović, Sanja S., Lukić, Miodrag, Jovanović, Zoran, Rmuš, Jelena, Mitrović-Rajić, Anđela, Grbović-Novaković, Jasmina, Kurko, Sandra V., "Study of milling time impact on hydrogen desorption from LiAlH4-Fe2O3 composites" in Processing and Application of Ceramics, 16, no. 3 (2022):259-266,
https://doi.org/10.2298/PAC2203259M . .

TY  - JOUR
AU  - Milanović, Igor
AU  - Milošević Govedarović, Sanja S.
AU  - Kurko, Sandra V.
AU  - Medić-Ilić, Mirjana
AU  - Rajnović, Dragan
AU  - Cvetković, Slobodan M.
AU  - Grbović-Novaković, Jasmina
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10398
AB  - MgH2 based composites combined with NaNH2 were synthesized by mechanical milling for three different milling times ranging from 15 to 60 minutes. Microstructure and particle size of the samples were analyzed by SEM microscopy while desorption properties were followed by Thermal Desorption Spectroscopy (TDS). The kinetic properties of NaNH2-MgH2 composites were investigated by isoconversional kinetic method as implemented in code developed by our group. Composites show hydrogen desorption peaks shifted to lower temperatures in comparison to mechanically modified and as received MgH2. All NaNH2-MgH2 composites show enhanced kinetics with lowered apparent activation energy (Ea) in comparison to milled MgH2. The mechanism of desorption changes from Avrami–Erofeev n = 3 for as received MgH2 to Avrami–Erofeev n = 4 for composite materials. The change from 3 to 4 can be due to the modification of the nucleation process or a change in the dimensionality of the growth. Those high values of n disregard a diffusion control as a rate limiting step. It has been shown that there is a synergistic effect on the enhanced hydrogen storage performance of chemical reaction and structural changes caused by ball milling. This can be used as a starting point for synthesis of innovative hydrogen storage materials.
T2  - International Journal of Hydrogen Energy
T1  - Improving of hydrogen desorption kinetics of MgH2 by NaNH2 addition: Interplay between microstructure and chemical reaction
VL  - 47
IS  - 69
SP  - 29858
EP  - 29865
DO  - 10.1016/j.ijhydene.2022.06.302
ER  - 

@article{
author = "Milanović, Igor and Milošević Govedarović, Sanja S. and Kurko, Sandra V. and Medić-Ilić, Mirjana and Rajnović, Dragan and Cvetković, Slobodan M. and Grbović-Novaković, Jasmina",
year = "2022",
abstract = "MgH2 based composites combined with NaNH2 were synthesized by mechanical milling for three different milling times ranging from 15 to 60 minutes. Microstructure and particle size of the samples were analyzed by SEM microscopy while desorption properties were followed by Thermal Desorption Spectroscopy (TDS). The kinetic properties of NaNH2-MgH2 composites were investigated by isoconversional kinetic method as implemented in code developed by our group. Composites show hydrogen desorption peaks shifted to lower temperatures in comparison to mechanically modified and as received MgH2. All NaNH2-MgH2 composites show enhanced kinetics with lowered apparent activation energy (Ea) in comparison to milled MgH2. The mechanism of desorption changes from Avrami–Erofeev n = 3 for as received MgH2 to Avrami–Erofeev n = 4 for composite materials. The change from 3 to 4 can be due to the modification of the nucleation process or a change in the dimensionality of the growth. Those high values of n disregard a diffusion control as a rate limiting step. It has been shown that there is a synergistic effect on the enhanced hydrogen storage performance of chemical reaction and structural changes caused by ball milling. This can be used as a starting point for synthesis of innovative hydrogen storage materials.",
journal = "International Journal of Hydrogen Energy",
title = "Improving of hydrogen desorption kinetics of MgH2 by NaNH2 addition: Interplay between microstructure and chemical reaction",
volume = "47",
number = "69",
pages = "29858-29865",
doi = "10.1016/j.ijhydene.2022.06.302"
}

Milanović, I., Milošević Govedarović, S. S., Kurko, S. V., Medić-Ilić, M., Rajnović, D., Cvetković, S. M.,& Grbović-Novaković, J.. (2022). Improving of hydrogen desorption kinetics of MgH2 by NaNH2 addition: Interplay between microstructure and chemical reaction. in International Journal of Hydrogen Energy, 47(69), 29858-29865.
https://doi.org/10.1016/j.ijhydene.2022.06.302

Milanović I, Milošević Govedarović SS, Kurko SV, Medić-Ilić M, Rajnović D, Cvetković SM, Grbović-Novaković J. Improving of hydrogen desorption kinetics of MgH2 by NaNH2 addition: Interplay between microstructure and chemical reaction. in International Journal of Hydrogen Energy. 2022;47(69):29858-29865.
doi:10.1016/j.ijhydene.2022.06.302 .

Milanović, Igor, Milošević Govedarović, Sanja S., Kurko, Sandra V., Medić-Ilić, Mirjana, Rajnović, Dragan, Cvetković, Slobodan M., Grbović-Novaković, Jasmina, "Improving of hydrogen desorption kinetics of MgH2 by NaNH2 addition: Interplay between microstructure and chemical reaction" in International Journal of Hydrogen Energy, 47, no. 69 (2022):29858-29865,
https://doi.org/10.1016/j.ijhydene.2022.06.302 . .

TY  - JOUR
AU  - Yang, Fusheng
AU  - Wang, Jing
AU  - Zhang, Yang
AU  - Wu, Zhen
AU  - Zhang, Zaoxiao
AU  - Zhao, Fengqi
AU  - Huot, Jacques
AU  - Grbović-Novaković, Jasmina
AU  - Novaković, Nikola
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10168
AB  - High entropy alloys (HEA) represent a kind of materials with unique structural and functional properties, and have attracted wide attentions in many fields including hydrogen storage. Due to the huge diversity in the composition of HEAs, novel hydrogen storage materials with superior comprehensive performance are expected to be developed following the concept, with some notable progress made in the past decade. In this study, the present research status in HEAs for hydrogen storage is summarized from the aspects of theoretical guide, composition and preparation, microstructure and hydrogen storage properties. Moreover, the key issues in future development and possible application scenarios are analyzed.
T2  - International Journal of Hydrogen Energy
T1  - Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: A review
VL  - 47
IS  - 21
SP  - 11236
EP  - 11249
DO  - 10.1016/j.ijhydene.2022.01.141
ER  - 

@article{
author = "Yang, Fusheng and Wang, Jing and Zhang, Yang and Wu, Zhen and Zhang, Zaoxiao and Zhao, Fengqi and Huot, Jacques and Grbović-Novaković, Jasmina and Novaković, Nikola",
year = "2022",
abstract = "High entropy alloys (HEA) represent a kind of materials with unique structural and functional properties, and have attracted wide attentions in many fields including hydrogen storage. Due to the huge diversity in the composition of HEAs, novel hydrogen storage materials with superior comprehensive performance are expected to be developed following the concept, with some notable progress made in the past decade. In this study, the present research status in HEAs for hydrogen storage is summarized from the aspects of theoretical guide, composition and preparation, microstructure and hydrogen storage properties. Moreover, the key issues in future development and possible application scenarios are analyzed.",
journal = "International Journal of Hydrogen Energy",
title = "Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: A review",
volume = "47",
number = "21",
pages = "11236-11249",
doi = "10.1016/j.ijhydene.2022.01.141"
}

Yang, F., Wang, J., Zhang, Y., Wu, Z., Zhang, Z., Zhao, F., Huot, J., Grbović-Novaković, J.,& Novaković, N.. (2022). Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: A review. in International Journal of Hydrogen Energy, 47(21), 11236-11249.
https://doi.org/10.1016/j.ijhydene.2022.01.141

Yang F, Wang J, Zhang Y, Wu Z, Zhang Z, Zhao F, Huot J, Grbović-Novaković J, Novaković N. Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: A review. in International Journal of Hydrogen Energy. 2022;47(21):11236-11249.
doi:10.1016/j.ijhydene.2022.01.141 .

Yang, Fusheng, Wang, Jing, Zhang, Yang, Wu, Zhen, Zhang, Zaoxiao, Zhao, Fengqi, Huot, Jacques, Grbović-Novaković, Jasmina, Novaković, Nikola, "Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: A review" in International Journal of Hydrogen Energy, 47, no. 21 (2022):11236-11249,
https://doi.org/10.1016/j.ijhydene.2022.01.141 . .

TY  - JOUR
AU  - Cvetković, Slobodan M.
AU  - Kaluđerović-Radoičić, Tatjana
AU  - Grbović-Novaković, Jasmina
AU  - Kovačević, Vlado
AU  - Lopičić, Zorica
AU  - Adamović, Vladimir
AU  - Kijevčanin, Mirjana Lj.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10300
AB  - Renewable hydrogen produced from the waste streams can be a good option for clean energy production and reduction of greenhouse gases emissions into the environment. In this study, the potential for hydrogen production from the food industry wastewaters in Serbia and the further use of the calculated potentials were investigated. This was performed through two technological routes including the biogas steam reforming process and the electrolysis after biogas cogeneration process. Furthermore, the environmental impacts of these processes were considered. The total hydrogen potential via the biogas steam reforming process was 4094.70 tons, while the total hydrogen potential via the electrolysis after biogas cogeneration process was 1751.08 tons. These potentials can be used for direct energy production in the food industry, electricity production for the national electric grid, transport, injection in the natural gas grid and/or as a resource in the chemical industry. Regarding the Greenhouse Gas emissions reduction, hydrogen production by both routes represents a promising pathway. The results of this work can serve the decision makers to plan hydrogen application in the energy sector of the Republic of Serbia defining supporting measures for its application. Also, the presented analysis is enforceable in the Western Balkan countries for the application of hydrogen as an energy source in their systems for energy production, transport and economy.
T2  - Journal of Cleaner Production
T1  - Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters
VL  - 363
SP  - 132142
DO  - 10.1016/j.jclepro.2022.132142
ER  - 

@article{
author = "Cvetković, Slobodan M. and Kaluđerović-Radoičić, Tatjana and Grbović-Novaković, Jasmina and Kovačević, Vlado and Lopičić, Zorica and Adamović, Vladimir and Kijevčanin, Mirjana Lj.",
year = "2022",
abstract = "Renewable hydrogen produced from the waste streams can be a good option for clean energy production and reduction of greenhouse gases emissions into the environment. In this study, the potential for hydrogen production from the food industry wastewaters in Serbia and the further use of the calculated potentials were investigated. This was performed through two technological routes including the biogas steam reforming process and the electrolysis after biogas cogeneration process. Furthermore, the environmental impacts of these processes were considered. The total hydrogen potential via the biogas steam reforming process was 4094.70 tons, while the total hydrogen potential via the electrolysis after biogas cogeneration process was 1751.08 tons. These potentials can be used for direct energy production in the food industry, electricity production for the national electric grid, transport, injection in the natural gas grid and/or as a resource in the chemical industry. Regarding the Greenhouse Gas emissions reduction, hydrogen production by both routes represents a promising pathway. The results of this work can serve the decision makers to plan hydrogen application in the energy sector of the Republic of Serbia defining supporting measures for its application. Also, the presented analysis is enforceable in the Western Balkan countries for the application of hydrogen as an energy source in their systems for energy production, transport and economy.",
journal = "Journal of Cleaner Production",
title = "Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters",
volume = "363",
pages = "132142",
doi = "10.1016/j.jclepro.2022.132142"
}

Cvetković, S. M., Kaluđerović-Radoičić, T., Grbović-Novaković, J., Kovačević, V., Lopičić, Z., Adamović, V.,& Kijevčanin, M. Lj.. (2022). Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters. in Journal of Cleaner Production, 363, 132142.
https://doi.org/10.1016/j.jclepro.2022.132142

Cvetković SM, Kaluđerović-Radoičić T, Grbović-Novaković J, Kovačević V, Lopičić Z, Adamović V, Kijevčanin ML. Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters. in Journal of Cleaner Production. 2022;363:132142.
doi:10.1016/j.jclepro.2022.132142 .

Cvetković, Slobodan M., Kaluđerović-Radoičić, Tatjana, Grbović-Novaković, Jasmina, Kovačević, Vlado, Lopičić, Zorica, Adamović, Vladimir, Kijevčanin, Mirjana Lj., "Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters" in Journal of Cleaner Production, 363 (2022):132142,
https://doi.org/10.1016/j.jclepro.2022.132142 . .

TY  - CONF
AU  - Medić Ilić, Mirjana
AU  - Paskaš Mamula, Bojana
AU  - Kuzmanović, Bojana
AU  - Radaković, Jana
AU  - Novaković, Nikola
AU  - Mitrović, Anđela
AU  - Grbović Novaković, Jasmina
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11305
PB  - Zagreb : "Ruđer Bošković" Institute
C3  - Solid-State Science & Research 2021 : Book of Abstracts and Program
C3  - Solid-State Science & Research Meeting
T1  - Improvement of Hydrogen Storage Properties of MgH2 by NaNH2 addition
SP  - 69
EP  - 69
EP  - 
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11305
ER  - 

@conference{
author = "Medić Ilić, Mirjana and Paskaš Mamula, Bojana and Kuzmanović, Bojana and Radaković, Jana and Novaković, Nikola and Mitrović, Anđela and Grbović Novaković, Jasmina",
year = "2021",
publisher = "Zagreb : "Ruđer Bošković" Institute",
journal = "Solid-State Science & Research 2021 : Book of Abstracts and Program, Solid-State Science & Research Meeting",
title = "Improvement of Hydrogen Storage Properties of MgH2 by NaNH2 addition",
pages = "69-69-",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11305"
}

Medić Ilić, M., Paskaš Mamula, B., Kuzmanović, B., Radaković, J., Novaković, N., Mitrović, A.,& Grbović Novaković, J.. (2021). Improvement of Hydrogen Storage Properties of MgH2 by NaNH2 addition. in Solid-State Science & Research 2021 : Book of Abstracts and Program
Zagreb : "Ruđer Bošković" Institute., 69-69.
https://hdl.handle.net/21.15107/rcub_vinar_11305

Medić Ilić M, Paskaš Mamula B, Kuzmanović B, Radaković J, Novaković N, Mitrović A, Grbović Novaković J. Improvement of Hydrogen Storage Properties of MgH2 by NaNH2 addition. in Solid-State Science & Research 2021 : Book of Abstracts and Program. 2021;:69-69.
https://hdl.handle.net/21.15107/rcub_vinar_11305 .

Medić Ilić, Mirjana, Paskaš Mamula, Bojana, Kuzmanović, Bojana, Radaković, Jana, Novaković, Nikola, Mitrović, Anđela, Grbović Novaković, Jasmina, "Improvement of Hydrogen Storage Properties of MgH2 by NaNH2 addition" in Solid-State Science & Research 2021 : Book of Abstracts and Program (2021):69-69,
https://hdl.handle.net/21.15107/rcub_vinar_11305 .

TY  - JOUR
AU  - Janjatović, Petar
AU  - Erić-Cekić, Olivera
AU  - Siđanin, Leposava
AU  - Balos, Sebastian
AU  - Dramićanin, Miroslav R.
AU  - Grbović-Novaković, Jasmina
AU  - Rajnović, Dragan
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9179
AB  - Austempered ductile iron (ADI) is an advanced cast iron material that has a broad field of application and, among others, it is used in contact and for conveyance of fluids. However, it is noticed that in contact with some fluids, especially water, ADI material becomes brittle. The most significant decrease is established for the elongation. However, the influence of water and the cause of this phenomenon is still not fully understood. For that reason, in this paper, the influence of different water concentrations in ethyl alcohol on the mechanical properties of ADI materials was studied. The test was performed on two different types of ADI materials in 0.2, 4, 10, and 100 vol.% water concentration environments, and in dry condition. It was found that even the smallest concentration of water (0.2 vol.%) causes formation of the embrittled zone at fracture surface. However, not all mechanical properties were affected equally and not all water concentrations have been critical. The highest deterioration was established in the elongation, followed by the ultimate tensile strength, while the proof strength was affected least.
T2  - Metals
T1  - The Effect of Water Concentration in Ethyl Alcohol on the Environmentally Assisted Embrittlement of Austempered Ductile Irons
VL  - 11
IS  - 1
SP  - 94
DO  - 10.3390/met11010094
ER  - 

@article{
author = "Janjatović, Petar and Erić-Cekić, Olivera and Siđanin, Leposava and Balos, Sebastian and Dramićanin, Miroslav R. and Grbović-Novaković, Jasmina and Rajnović, Dragan",
year = "2021",
abstract = "Austempered ductile iron (ADI) is an advanced cast iron material that has a broad field of application and, among others, it is used in contact and for conveyance of fluids. However, it is noticed that in contact with some fluids, especially water, ADI material becomes brittle. The most significant decrease is established for the elongation. However, the influence of water and the cause of this phenomenon is still not fully understood. For that reason, in this paper, the influence of different water concentrations in ethyl alcohol on the mechanical properties of ADI materials was studied. The test was performed on two different types of ADI materials in 0.2, 4, 10, and 100 vol.% water concentration environments, and in dry condition. It was found that even the smallest concentration of water (0.2 vol.%) causes formation of the embrittled zone at fracture surface. However, not all mechanical properties were affected equally and not all water concentrations have been critical. The highest deterioration was established in the elongation, followed by the ultimate tensile strength, while the proof strength was affected least.",
journal = "Metals",
title = "The Effect of Water Concentration in Ethyl Alcohol on the Environmentally Assisted Embrittlement of Austempered Ductile Irons",
volume = "11",
number = "1",
pages = "94",
doi = "10.3390/met11010094"
}

Janjatović, P., Erić-Cekić, O., Siđanin, L., Balos, S., Dramićanin, M. R., Grbović-Novaković, J.,& Rajnović, D.. (2021). The Effect of Water Concentration in Ethyl Alcohol on the Environmentally Assisted Embrittlement of Austempered Ductile Irons. in Metals, 11(1), 94.
https://doi.org/10.3390/met11010094

Janjatović P, Erić-Cekić O, Siđanin L, Balos S, Dramićanin MR, Grbović-Novaković J, Rajnović D. The Effect of Water Concentration in Ethyl Alcohol on the Environmentally Assisted Embrittlement of Austempered Ductile Irons. in Metals. 2021;11(1):94.
doi:10.3390/met11010094 .

Janjatović, Petar, Erić-Cekić, Olivera, Siđanin, Leposava, Balos, Sebastian, Dramićanin, Miroslav R., Grbović-Novaković, Jasmina, Rajnović, Dragan, "The Effect of Water Concentration in Ethyl Alcohol on the Environmentally Assisted Embrittlement of Austempered Ductile Irons" in Metals, 11, no. 1 (2021):94,
https://doi.org/10.3390/met11010094 . .

TY  - JOUR
AU  - Cvetković, Slobodan M.
AU  - Kaluđerović-Radoičić, Tatjana
AU  - Kijevčanin, Mirjana Lj.
AU  - Grbović-Novaković, Jasmina
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9128
AB  - The aim of this paper is to demonstrate and to quantify energy flows in a life cycle of biogas to biohydrogen production, starting from feedstock materials via anaerobic digestion, biogas upgrading, biohydrogen production, to the end of biogas system (application of digestate as fertilizer in agriculture). The performance of the biogas plant of Mirotin dairy farm in Serbia has been assessed. According to Life Cycle Energy Assessment approach, results obtained in this study have shown that biohydrogen production via biogas steam reforming has negative energy balance (with −16,837 GJ). It has also been demonstrated that this process is energy unsustainable in an environmental context. In future analysis it would be necessary to consider the other aspects of sustainability, e.g. the economical and social factors in order to estimate the overall sustainability of the biogas utilization pathways, especially having in mind that the technology of converting biogas to hydrogen is still in the development phase. © 2021 Hydrogen Energy Publications LLC
T2  - International Journal of Hydrogen Energy
T1  - Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia
VL  - 46
IS  - 27
SP  - 14130
EP  - 14137
DO  - 10.1016/j.ijhydene.2021.01.181
ER  - 

@article{
author = "Cvetković, Slobodan M. and Kaluđerović-Radoičić, Tatjana and Kijevčanin, Mirjana Lj. and Grbović-Novaković, Jasmina",
year = "2021",
abstract = "The aim of this paper is to demonstrate and to quantify energy flows in a life cycle of biogas to biohydrogen production, starting from feedstock materials via anaerobic digestion, biogas upgrading, biohydrogen production, to the end of biogas system (application of digestate as fertilizer in agriculture). The performance of the biogas plant of Mirotin dairy farm in Serbia has been assessed. According to Life Cycle Energy Assessment approach, results obtained in this study have shown that biohydrogen production via biogas steam reforming has negative energy balance (with −16,837 GJ). It has also been demonstrated that this process is energy unsustainable in an environmental context. In future analysis it would be necessary to consider the other aspects of sustainability, e.g. the economical and social factors in order to estimate the overall sustainability of the biogas utilization pathways, especially having in mind that the technology of converting biogas to hydrogen is still in the development phase. © 2021 Hydrogen Energy Publications LLC",
journal = "International Journal of Hydrogen Energy",
title = "Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia",
volume = "46",
number = "27",
pages = "14130-14137",
doi = "10.1016/j.ijhydene.2021.01.181"
}

Cvetković, S. M., Kaluđerović-Radoičić, T., Kijevčanin, M. Lj.,& Grbović-Novaković, J.. (2021). Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia. in International Journal of Hydrogen Energy, 46(27), 14130-14137.
https://doi.org/10.1016/j.ijhydene.2021.01.181

Cvetković SM, Kaluđerović-Radoičić T, Kijevčanin ML, Grbović-Novaković J. Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia. in International Journal of Hydrogen Energy. 2021;46(27):14130-14137.
doi:10.1016/j.ijhydene.2021.01.181 .

Cvetković, Slobodan M., Kaluđerović-Radoičić, Tatjana, Kijevčanin, Mirjana Lj., Grbović-Novaković, Jasmina, "Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia" in International Journal of Hydrogen Energy, 46, no. 27 (2021):14130-14137,
https://doi.org/10.1016/j.ijhydene.2021.01.181 . .

TY  - JOUR
AU  - Novaković, Nikola
AU  - Kurko, Sandra V.
AU  - Grbović-Novaković, Jasmina
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8798
T2  - International Journal of Hydrogen Energy
T1  - Preface: The 3rd International Symposium on Materials for Energy Storage and Conversion (mESC-IS2018)
VL  - 45
IS  - 14
SP  - 7873
DO  - 10.1016/j.ijhydene.2019.12.047
ER  - 

@article{
author = "Novaković, Nikola and Kurko, Sandra V. and Grbović-Novaković, Jasmina",
year = "2020",
journal = "International Journal of Hydrogen Energy",
title = "Preface: The 3rd International Symposium on Materials for Energy Storage and Conversion (mESC-IS2018)",
volume = "45",
number = "14",
pages = "7873",
doi = "10.1016/j.ijhydene.2019.12.047"
}

Novaković, N., Kurko, S. V.,& Grbović-Novaković, J.. (2020). Preface: The 3rd International Symposium on Materials for Energy Storage and Conversion (mESC-IS2018). in International Journal of Hydrogen Energy, 45(14), 7873.
https://doi.org/10.1016/j.ijhydene.2019.12.047

Novaković N, Kurko SV, Grbović-Novaković J. Preface: The 3rd International Symposium on Materials for Energy Storage and Conversion (mESC-IS2018). in International Journal of Hydrogen Energy. 2020;45(14):7873.
doi:10.1016/j.ijhydene.2019.12.047 .

Novaković, Nikola, Kurko, Sandra V., Grbović-Novaković, Jasmina, "Preface: The 3rd International Symposium on Materials for Energy Storage and Conversion (mESC-IS2018)" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7873,
https://doi.org/10.1016/j.ijhydene.2019.12.047 . .

TY  - JOUR
AU  - Pantić, Tijana
AU  - Milanović, Igor
AU  - Lukić, Miodrag
AU  - Grbović-Novaković, Jasmina
AU  - Kurko, Sandra V.
AU  - Biliškov, Nikola
AU  - Milošević Govedarović, Sanja S.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8568
AB  - The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material. © 2019 Hydrogen Energy Publications LLC
T2  - International Journal of Hydrogen Energy
T1  - The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites
VL  - 45
IS  - 14
SP  - 7901
EP  - 7911
DO  - 10.1016/j.ijhydene.2019.07.167
ER  - 

@article{
author = "Pantić, Tijana and Milanović, Igor and Lukić, Miodrag and Grbović-Novaković, Jasmina and Kurko, Sandra V. and Biliškov, Nikola and Milošević Govedarović, Sanja S.",
year = "2020",
abstract = "The influence of different milling conditions obtained using two high-energy mills on hydrogen desorption from MgH2-WO3 composites was investigated. The morphology, particle and crystallite size were studied as a function of milling speed, vial's volume, and ball-to-powder ratio. The vial's fill level, the number, and type of milling balls and additive's content kept constant. Changes in morphology and microstructure were correlated to desorption properties of materials. Higher milling speed reduced particle size but, there is no significant crystallite size reduction. On the other hand, additive distribution is similar regardless of the energy input. It has been noticed that different energy input on milling blend, which is the result of combined effects of above-mentioned factors, reflects on desorption temperature but not on the kinetics of desorption. In fact, desorption mechanism changes from 2D to 3D growth with constant nucleation rate, despite obtained changes in microstructure or chemical composition of the material. © 2019 Hydrogen Energy Publications LLC",
journal = "International Journal of Hydrogen Energy",
title = "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites",
volume = "45",
number = "14",
pages = "7901-7911",
doi = "10.1016/j.ijhydene.2019.07.167"
}

Pantić, T., Milanović, I., Lukić, M., Grbović-Novaković, J., Kurko, S. V., Biliškov, N.,& Milošević Govedarović, S. S.. (2020). The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy, 45(14), 7901-7911.
https://doi.org/10.1016/j.ijhydene.2019.07.167

Pantić T, Milanović I, Lukić M, Grbović-Novaković J, Kurko SV, Biliškov N, Milošević Govedarović SS. The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites. in International Journal of Hydrogen Energy. 2020;45(14):7901-7911.
doi:10.1016/j.ijhydene.2019.07.167 .

Pantić, Tijana, Milanović, Igor, Lukić, Miodrag, Grbović-Novaković, Jasmina, Kurko, Sandra V., Biliškov, Nikola, Milošević Govedarović, Sanja S., "The influence of mechanical milling parameters on hydrogen desorption from Mgh2-Wo3 composites" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7901-7911,
https://doi.org/10.1016/j.ijhydene.2019.07.167 . .

TY  - JOUR
AU  - Kurko, Sandra V.
AU  - Paskaš Mamula, Bojana
AU  - Rmuš, Jelena
AU  - Grbović-Novaković, Jasmina
AU  - Novaković, Nikola
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8560
AB  - The impact of boron doping on MgH2 bonding mechanism, hydrogen diffusion and desorption was calculated using density functional theory (DFT). Atomic interactions in doped and non-doped system and its influence on hydrogen and vacancy diffusion were studied in bulk hydride. Slab calculations were performed to study hydrogen desorption energies from (110) boron doped surface and its dependence on the surface configuration and depth position. To study kinetics of hydrogen diffusion in boron vicinity and hydrogen molecule desorption activation energies from boron doped and non-doped (110) MgH2 surface Nudged Elastic Band (NEB) method was used. Results showed that boron forms stronger, covalent bonds with hydrogen causing the destabilization in its first and second coordination. This leads to lower hydrogen desorption energies and improved hydrogen diffusion, while the impact on the energy barriers for H2 desorption from hydride (110) surface is less pronounced. © 2019 Hydrogen Energy Publications LLC
T2  - International Journal of Hydrogen Energy
T1  - DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption
VL  - 45
IS  - 14
SP  - 7947
EP  - 7957
DO  - 10.1016/j.ijhydene.2019.05.015
ER  - 

@article{
author = "Kurko, Sandra V. and Paskaš Mamula, Bojana and Rmuš, Jelena and Grbović-Novaković, Jasmina and Novaković, Nikola",
year = "2020",
abstract = "The impact of boron doping on MgH2 bonding mechanism, hydrogen diffusion and desorption was calculated using density functional theory (DFT). Atomic interactions in doped and non-doped system and its influence on hydrogen and vacancy diffusion were studied in bulk hydride. Slab calculations were performed to study hydrogen desorption energies from (110) boron doped surface and its dependence on the surface configuration and depth position. To study kinetics of hydrogen diffusion in boron vicinity and hydrogen molecule desorption activation energies from boron doped and non-doped (110) MgH2 surface Nudged Elastic Band (NEB) method was used. Results showed that boron forms stronger, covalent bonds with hydrogen causing the destabilization in its first and second coordination. This leads to lower hydrogen desorption energies and improved hydrogen diffusion, while the impact on the energy barriers for H2 desorption from hydride (110) surface is less pronounced. © 2019 Hydrogen Energy Publications LLC",
journal = "International Journal of Hydrogen Energy",
title = "DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption",
volume = "45",
number = "14",
pages = "7947-7957",
doi = "10.1016/j.ijhydene.2019.05.015"
}

Kurko, S. V., Paskaš Mamula, B., Rmuš, J., Grbović-Novaković, J.,& Novaković, N.. (2020). DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption. in International Journal of Hydrogen Energy, 45(14), 7947-7957.
https://doi.org/10.1016/j.ijhydene.2019.05.015

Kurko SV, Paskaš Mamula B, Rmuš J, Grbović-Novaković J, Novaković N. DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption. in International Journal of Hydrogen Energy. 2020;45(14):7947-7957.
doi:10.1016/j.ijhydene.2019.05.015 .

Kurko, Sandra V., Paskaš Mamula, Bojana, Rmuš, Jelena, Grbović-Novaković, Jasmina, Novaković, Nikola, "DFT study of boron doped MgH2: Bonding mechanism, hydrogen diffusion and desorption" in International Journal of Hydrogen Energy, 45, no. 14 (2020):7947-7957,
https://doi.org/10.1016/j.ijhydene.2019.05.015 . .

TY  - CONF
AU  - Mitrović, Anđela I.
AU  - Milićević, Jelena
AU  - Milošević Govedarović, Sanja S.
AU  - Kurko, Sandra
AU  - Pantić, Tijana B.
AU  - Rmuš, Jelena
AU  - Mravik, Željko
AU  - Grbović-Novaković, Jasmina
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11182
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - Electrochemical sensors based on pyrophyllite
SP  - 97
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11182
ER  - 

@conference{
author = "Mitrović, Anđela I. and Milićević, Jelena and Milošević Govedarović, Sanja S. and Kurko, Sandra and Pantić, Tijana B. and Rmuš, Jelena and Mravik, Željko and Grbović-Novaković, Jasmina",
year = "2019",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "Electrochemical sensors based on pyrophyllite",
pages = "97",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11182"
}

Mitrović, A. I., Milićević, J., Milošević Govedarović, S. S., Kurko, S., Pantić, T. B., Rmuš, J., Mravik, Ž.,& Grbović-Novaković, J.. (2019). Electrochemical sensors based on pyrophyllite. in Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 97.
https://hdl.handle.net/21.15107/rcub_vinar_11182

Mitrović AI, Milićević J, Milošević Govedarović SS, Kurko S, Pantić TB, Rmuš J, Mravik Ž, Grbović-Novaković J. Electrochemical sensors based on pyrophyllite. in Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:97.
https://hdl.handle.net/21.15107/rcub_vinar_11182 .

Mitrović, Anđela I., Milićević, Jelena, Milošević Govedarović, Sanja S., Kurko, Sandra, Pantić, Tijana B., Rmuš, Jelena, Mravik, Željko, Grbović-Novaković, Jasmina, "Electrochemical sensors based on pyrophyllite" in Advanced Ceramics and Application : 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):97,
https://hdl.handle.net/21.15107/rcub_vinar_11182 .

TY  - JOUR
AU  - Grbović-Novaković, Jasmina
AU  - Novaković, Nikola
AU  - Kurko, Sandra V.
AU  - Milošević Govedarović, Sanja S.
AU  - Pantić, Tijana
AU  - Paskaš Mamula, Bojana
AU  - Batalović, Katarina
AU  - Radaković, Jana
AU  - Rmuš, Jelena
AU  - Shelyapina, Marina
AU  - Skryabina, Nataliya
AU  - de Rango, Patricia
AU  - Fruchart, Daniel
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8161
AB  - This review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated. Theoretical studies, mainly carried out within various implementations of DFT, are a powerful tool to study mostly MgH 2 based materials. By providing an insight on metal-hydrogen bonding that governs both thermodynamics and hydrogen kinetics, they allow us to describe phenomena to which experimental methods have a limited access or do not have it at all: to follow the hydrogen sorption reaction on a specific metal surface and hydrogen induced phase transformations, to describe structure of phase boundaries or to explain the impact of defects or various additives on MgH 2 stability and hydrogen sorption kinetics. In several cases theoretical calculations reveal themselves as being able to predict new properties of materials, including the ways to modify Mg or MgH 2 that would lead to better characteristics in terms of hydrogen storage. The influence of ion irradiation and mechanical milling with and without additives has been discussed. Ion irradiation is the way to introduce a well-defined concentration of defects (Frankel pairs) at the surface and sub-surface layers of a material. Defects at the surface play the main role in sorption reaction since they enhance the dissociation of hydrogen. On the other hand, ball-milling introduce defects through the entire sample volume, refine the structure and thus decrease the path for hydrogen diffusion. Two Severe Plastic Deformation techniques were used to better understand the hydrogenation/dehydrogenation kinetics of Mg- and Mg 2 Ni-based alloys: Equal-Angular-Channel-Pressing and Fast-Forging. Successive ECAP passes leads to refinement of the microstructure of AZ31 ingots and to instalment therein of high densities of defects. Depending on mode, number and temperature of ECAP passes, the H-sorption kinetics have been improved satisfactorily without any additive for mass H-storage applications considering the relative speed of the shaping procedure. A qualitative understanding of the kinetic advanced principles has been built. Fast-Forging was used for a “quasi-instantaneous” synthesis of Mg/Mg 2 Ni-based composites. Hydrogenation of the as-received almost bi-phased materials remains rather slow as generally observed elsewhere, whatever are multiple and different techniques used to deliver the composite alloys. However, our preliminary results suggest that a synergic hydrogenation / dehydrogenation process should assist hydrogen transfers from Mg/Mg 2 Ni on one side to MgH 2 /Mg 2 NiH 4 on the other side via the rather stable a-Mg 2 NiH 0.3 , acting as in-situ catalyser. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - ChemPhysChem
T1  - Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides
VL  - 20
IS  - 10
SP  - 1216
EP  - 1247
DO  - 10.1002/cphc.201801125
ER  - 

@article{
author = "Grbović-Novaković, Jasmina and Novaković, Nikola and Kurko, Sandra V. and Milošević Govedarović, Sanja S. and Pantić, Tijana and Paskaš Mamula, Bojana and Batalović, Katarina and Radaković, Jana and Rmuš, Jelena and Shelyapina, Marina and Skryabina, Nataliya and de Rango, Patricia and Fruchart, Daniel",
year = "2019",
abstract = "This review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated. Theoretical studies, mainly carried out within various implementations of DFT, are a powerful tool to study mostly MgH 2 based materials. By providing an insight on metal-hydrogen bonding that governs both thermodynamics and hydrogen kinetics, they allow us to describe phenomena to which experimental methods have a limited access or do not have it at all: to follow the hydrogen sorption reaction on a specific metal surface and hydrogen induced phase transformations, to describe structure of phase boundaries or to explain the impact of defects or various additives on MgH 2 stability and hydrogen sorption kinetics. In several cases theoretical calculations reveal themselves as being able to predict new properties of materials, including the ways to modify Mg or MgH 2 that would lead to better characteristics in terms of hydrogen storage. The influence of ion irradiation and mechanical milling with and without additives has been discussed. Ion irradiation is the way to introduce a well-defined concentration of defects (Frankel pairs) at the surface and sub-surface layers of a material. Defects at the surface play the main role in sorption reaction since they enhance the dissociation of hydrogen. On the other hand, ball-milling introduce defects through the entire sample volume, refine the structure and thus decrease the path for hydrogen diffusion. Two Severe Plastic Deformation techniques were used to better understand the hydrogenation/dehydrogenation kinetics of Mg- and Mg 2 Ni-based alloys: Equal-Angular-Channel-Pressing and Fast-Forging. Successive ECAP passes leads to refinement of the microstructure of AZ31 ingots and to instalment therein of high densities of defects. Depending on mode, number and temperature of ECAP passes, the H-sorption kinetics have been improved satisfactorily without any additive for mass H-storage applications considering the relative speed of the shaping procedure. A qualitative understanding of the kinetic advanced principles has been built. Fast-Forging was used for a “quasi-instantaneous” synthesis of Mg/Mg 2 Ni-based composites. Hydrogenation of the as-received almost bi-phased materials remains rather slow as generally observed elsewhere, whatever are multiple and different techniques used to deliver the composite alloys. However, our preliminary results suggest that a synergic hydrogenation / dehydrogenation process should assist hydrogen transfers from Mg/Mg 2 Ni on one side to MgH 2 /Mg 2 NiH 4 on the other side via the rather stable a-Mg 2 NiH 0.3 , acting as in-situ catalyser. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "ChemPhysChem",
title = "Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides",
volume = "20",
number = "10",
pages = "1216-1247",
doi = "10.1002/cphc.201801125"
}

Grbović-Novaković, J., Novaković, N., Kurko, S. V., Milošević Govedarović, S. S., Pantić, T., Paskaš Mamula, B., Batalović, K., Radaković, J., Rmuš, J., Shelyapina, M., Skryabina, N., de Rango, P.,& Fruchart, D.. (2019). Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides. in ChemPhysChem, 20(10), 1216-1247.
https://doi.org/10.1002/cphc.201801125

Grbović-Novaković J, Novaković N, Kurko SV, Milošević Govedarović SS, Pantić T, Paskaš Mamula B, Batalović K, Radaković J, Rmuš J, Shelyapina M, Skryabina N, de Rango P, Fruchart D. Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides. in ChemPhysChem. 2019;20(10):1216-1247.
doi:10.1002/cphc.201801125 .

Grbović-Novaković, Jasmina, Novaković, Nikola, Kurko, Sandra V., Milošević Govedarović, Sanja S., Pantić, Tijana, Paskaš Mamula, Bojana, Batalović, Katarina, Radaković, Jana, Rmuš, Jelena, Shelyapina, Marina, Skryabina, Nataliya, de Rango, Patricia, Fruchart, Daniel, "Influence of Defects on the Stability and Hydrogen‐Sorption Behavior of Mg‐Based Hydrides" in ChemPhysChem, 20, no. 10 (2019):1216-1247,
https://doi.org/10.1002/cphc.201801125 . .