TY  - CONF
AU  - Stojković, Milica
AU  - Dedić, Sofija
AU  - Đolić, Maja
AU  - Ćujić, Mirjana
AU  - Pavićević, Vladimir
AU  - Ristić, Mirjana
AU  - Perić-Grujić, Aleksandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11230
AB  - Fly ash originating from coal combustion in thermal power plants is generated in landfills in large amounts, and due to the high content of heavy metals and metalloids whose mobility is hazardous to the environment and human health, it causes soil and groundwater pollution. Scientific research in the field of "alternative mining" is significant, where heavy metals and rare earth elements would be recovered from waste materials such as fly ash using various extraction methods. The aim of this paper is to determine the optimal extraction process of the examined elements: V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd, and Pb from fly ash. Two extraction agents were used: sulfuric and acetic acid. In the first set of experiments, the fly ash was immersed immediately in acids, and in the second set, this process was preceded by the addition of sodium hydroxide, which effectively destroys the alumina-silicate matrix. Several different parameters were also monitored: ratio of fly ash and acid/acid mixture (1:5, 1:30), temperature (25 and 45°C), duration of the process (4 and 24 h), and stirring. For the extraction of Pb - H2SO4, temperature and time were shown as significant parameters, while for Cd, only H2SO4 was an effective extractant. Concerning the As metalloid, the acetic acid, solid/liquid ratio, and time were significant, while for Zn, Cu, Co, Mn, and V metals only the solid/liquid ratio was significant. Determination of the content of heavy metals and metalloids was done by the ICP-MS.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia (AMES)
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe : Proceedings
T1  - The Optimization of Metals and Metalloids Extraction From Fly Ash
SP  - 347
EP  - 352
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11230
ER  - 

@conference{
author = "Stojković, Milica and Dedić, Sofija and Đolić, Maja and Ćujić, Mirjana and Pavićević, Vladimir and Ristić, Mirjana and Perić-Grujić, Aleksandra",
year = "2023",
abstract = "Fly ash originating from coal combustion in thermal power plants is generated in landfills in large amounts, and due to the high content of heavy metals and metalloids whose mobility is hazardous to the environment and human health, it causes soil and groundwater pollution. Scientific research in the field of "alternative mining" is significant, where heavy metals and rare earth elements would be recovered from waste materials such as fly ash using various extraction methods. The aim of this paper is to determine the optimal extraction process of the examined elements: V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd, and Pb from fly ash. Two extraction agents were used: sulfuric and acetic acid. In the first set of experiments, the fly ash was immersed immediately in acids, and in the second set, this process was preceded by the addition of sodium hydroxide, which effectively destroys the alumina-silicate matrix. Several different parameters were also monitored: ratio of fly ash and acid/acid mixture (1:5, 1:30), temperature (25 and 45°C), duration of the process (4 and 24 h), and stirring. For the extraction of Pb - H2SO4, temperature and time were shown as significant parameters, while for Cd, only H2SO4 was an effective extractant. Concerning the As metalloid, the acetic acid, solid/liquid ratio, and time were significant, while for Zn, Cu, Co, Mn, and V metals only the solid/liquid ratio was significant. Determination of the content of heavy metals and metalloids was done by the ICP-MS.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia (AMES)",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe : Proceedings",
title = "The Optimization of Metals and Metalloids Extraction From Fly Ash",
pages = "347-352",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11230"
}

Stojković, M., Dedić, S., Đolić, M., Ćujić, M., Pavićević, V., Ristić, M.,& Perić-Grujić, A.. (2023). The Optimization of Metals and Metalloids Extraction From Fly Ash. in 5th Metallurgical & Materials Engineering Congress of South-East Europe : Proceedings
Belgrade : Association of Metallurgical Engineers of Serbia (AMES)., 347-352.
https://hdl.handle.net/21.15107/rcub_vinar_11230

Stojković M, Dedić S, Đolić M, Ćujić M, Pavićević V, Ristić M, Perić-Grujić A. The Optimization of Metals and Metalloids Extraction From Fly Ash. in 5th Metallurgical & Materials Engineering Congress of South-East Europe : Proceedings. 2023;:347-352.
https://hdl.handle.net/21.15107/rcub_vinar_11230 .

Stojković, Milica, Dedić, Sofija, Đolić, Maja, Ćujić, Mirjana, Pavićević, Vladimir, Ristić, Mirjana, Perić-Grujić, Aleksandra, "The Optimization of Metals and Metalloids Extraction From Fly Ash" in 5th Metallurgical & Materials Engineering Congress of South-East Europe : Proceedings (2023):347-352,
https://hdl.handle.net/21.15107/rcub_vinar_11230 .

TY  - JOUR
AU  - Ranković, Bojan
AU  - Gajić, Vuk
AU  - Mašić, Slobodan
AU  - Pavićević, Vladimir
AU  - Vujčić, Ivica
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10550
AB  - Using ionizing radiation in treating waste sludge from a drinking water treatment plant is a well-known technique. Sludge treated with ionizing radiation can be used as fertilizer in agriculture. In this paper, the effects of aging on the physicochemical characteristics, the content of microorganisms, molds, acrylamide, heavy metal concentration, and total nutrient content in waste sludge treated with e-beam and gamma irradiation were investigated. The possibility of using treated sludge as a fertilizer in agriculture was evaluated. It has been shown that the content of acrylamide in treated sludge after 15 months of storage does not exceed the limits for sludge to be used as fertilizer. If the sludge is stored in closed bags in a dark place, aging does not increase total microorganisms and molds. The research also showed that the sludge's physicochemical characteristics treated in this way do not decrease under the influence of aging. Finally, it has been shown that aging does not change the concentration of heavy metals and total nutrients in sludge treated by ionizing irradiation.
T2  - Applied Radiation and Isotopes
T1  - Possibility of using ionizing radiation treated sludge from drinking water treatment plant as fertilizer in agriculture: Effects of aging
VL  - 192
SP  - 110602
DO  - 10.1016/j.apradiso.2022.110602
ER  - 

@article{
author = "Ranković, Bojan and Gajić, Vuk and Mašić, Slobodan and Pavićević, Vladimir and Vujčić, Ivica",
year = "2023",
abstract = "Using ionizing radiation in treating waste sludge from a drinking water treatment plant is a well-known technique. Sludge treated with ionizing radiation can be used as fertilizer in agriculture. In this paper, the effects of aging on the physicochemical characteristics, the content of microorganisms, molds, acrylamide, heavy metal concentration, and total nutrient content in waste sludge treated with e-beam and gamma irradiation were investigated. The possibility of using treated sludge as a fertilizer in agriculture was evaluated. It has been shown that the content of acrylamide in treated sludge after 15 months of storage does not exceed the limits for sludge to be used as fertilizer. If the sludge is stored in closed bags in a dark place, aging does not increase total microorganisms and molds. The research also showed that the sludge's physicochemical characteristics treated in this way do not decrease under the influence of aging. Finally, it has been shown that aging does not change the concentration of heavy metals and total nutrients in sludge treated by ionizing irradiation.",
journal = "Applied Radiation and Isotopes",
title = "Possibility of using ionizing radiation treated sludge from drinking water treatment plant as fertilizer in agriculture: Effects of aging",
volume = "192",
pages = "110602",
doi = "10.1016/j.apradiso.2022.110602"
}

Ranković, B., Gajić, V., Mašić, S., Pavićević, V.,& Vujčić, I.. (2023). Possibility of using ionizing radiation treated sludge from drinking water treatment plant as fertilizer in agriculture: Effects of aging. in Applied Radiation and Isotopes, 192, 110602.
https://doi.org/10.1016/j.apradiso.2022.110602

Ranković B, Gajić V, Mašić S, Pavićević V, Vujčić I. Possibility of using ionizing radiation treated sludge from drinking water treatment plant as fertilizer in agriculture: Effects of aging. in Applied Radiation and Isotopes. 2023;192:110602.
doi:10.1016/j.apradiso.2022.110602 .

Ranković, Bojan, Gajić, Vuk, Mašić, Slobodan, Pavićević, Vladimir, Vujčić, Ivica, "Possibility of using ionizing radiation treated sludge from drinking water treatment plant as fertilizer in agriculture: Effects of aging" in Applied Radiation and Isotopes, 192 (2023):110602,
https://doi.org/10.1016/j.apradiso.2022.110602 . .

TY  - JOUR
AU  - Karanac, Milica
AU  - Đolić, Maja B.
AU  - Veljović, Đorđe N.
AU  - Rajaković-Ognjanović, Vladana N.
AU  - Veličković, Zlate S.
AU  - Pavićević, Vladimir
AU  - Marinković, Aleksandar D.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0956053X18303490
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7728
AB  - This study focuses on the use of raw fly ash (FA) and modified fly ash – activated by lime (MFA), as effective and low-cost adsorbents for the removal of heavy metals (Zn2+, Pb2+and As(V)), followed by the revalorization of the exhausted adsorbent. The granulometric, elemental analysis, point of zero charge (pHPZC), radiochemical and structural characterization were conducted using X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and gamma spectrometry techniques. The optimal conditions and key factors influencing the adsorption process were assessed using the response surface method (RSM). The adsorption capacity of the MFA adsorbent for Zn2+, Pb2+and As(V) removal, calculated by the Langmuir model, was found to be 33.13, 26.06, and 29.71 mg g−1, respectively. The kinetic and thermodynamic parameters indicated that the adsorption process is spontaneous and endothermic. Due to their low desorption potential of the exhausted adsorbents, their effective reuse was established to be feasible. For this reason, the valorization of this material as an additive in construction materials was thereafter studied, where testing its toxicity leaching (TCLP) as well as the mechanical properties of construction material containing exhausted MFA confirmed its safe use. Hence, this study points to a possible “two-in-one” reuse of coal ash, initially as an adsorbent and later as an additive in a construction material.
T2  - Waste Management
T1  - The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent
VL  - 78
SP  - 366
EP  - 378
DO  - 10.1016/j.wasman.2018.05.052
ER  - 

@article{
author = "Karanac, Milica and Đolić, Maja B. and Veljović, Đorđe N. and Rajaković-Ognjanović, Vladana N. and Veličković, Zlate S. and Pavićević, Vladimir and Marinković, Aleksandar D.",
year = "2018",
abstract = "This study focuses on the use of raw fly ash (FA) and modified fly ash – activated by lime (MFA), as effective and low-cost adsorbents for the removal of heavy metals (Zn2+, Pb2+and As(V)), followed by the revalorization of the exhausted adsorbent. The granulometric, elemental analysis, point of zero charge (pHPZC), radiochemical and structural characterization were conducted using X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and gamma spectrometry techniques. The optimal conditions and key factors influencing the adsorption process were assessed using the response surface method (RSM). The adsorption capacity of the MFA adsorbent for Zn2+, Pb2+and As(V) removal, calculated by the Langmuir model, was found to be 33.13, 26.06, and 29.71 mg g−1, respectively. The kinetic and thermodynamic parameters indicated that the adsorption process is spontaneous and endothermic. Due to their low desorption potential of the exhausted adsorbents, their effective reuse was established to be feasible. For this reason, the valorization of this material as an additive in construction materials was thereafter studied, where testing its toxicity leaching (TCLP) as well as the mechanical properties of construction material containing exhausted MFA confirmed its safe use. Hence, this study points to a possible “two-in-one” reuse of coal ash, initially as an adsorbent and later as an additive in a construction material.",
journal = "Waste Management",
title = "The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent",
volume = "78",
pages = "366-378",
doi = "10.1016/j.wasman.2018.05.052"
}

Karanac, M., Đolić, M. B., Veljović, Đ. N., Rajaković-Ognjanović, V. N., Veličković, Z. S., Pavićević, V.,& Marinković, A. D.. (2018). The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent. in Waste Management, 78, 366-378.
https://doi.org/10.1016/j.wasman.2018.05.052

Karanac M, Đolić MB, Veljović ĐN, Rajaković-Ognjanović VN, Veličković ZS, Pavićević V, Marinković AD. The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent. in Waste Management. 2018;78:366-378.
doi:10.1016/j.wasman.2018.05.052 .

Karanac, Milica, Đolić, Maja B., Veljović, Đorđe N., Rajaković-Ognjanović, Vladana N., Veličković, Zlate S., Pavićević, Vladimir, Marinković, Aleksandar D., "The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent" in Waste Management, 78 (2018):366-378,
https://doi.org/10.1016/j.wasman.2018.05.052 . .