Momčilović, Milan Z.

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Authority KeyName Variants
orcid::0000-0001-5370-0148
  • Momčilović, Milan Z. (37)
  • Momčilović, Milan (2)
Projects
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
Development and characterization of novel biosorbent for natural and waste water treatment Combinatorial libraries of heterogeneous catalysts, natural products, and their derivatives and analogues: the way to biologically active compounds
Lithium-ion batteries and fuel cells - research and development Physics and Chemistry with Ion Beams
Effects of laser radiation and plasma on novel materials in their synthesis, modification, and analysis Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200133 (Univeristy of Niš, Faculty of Technology, Leskovac) AERoGELS COST Action CA18125–Advanced Engineering and Research of aeroGels for Environment and Life Sciences
DAAD foundation through a multilateral project "International Masters and Postgraduate Programme in Materials Science and Catalysis" (MatCatNet) Grant Agency of the Czech Republic [P206/12/G151]
Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials Plant Biodiversity of Serbia and the Balkans - assesment, sustainable use and protection
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy)
Fabrication and characterization of nano-photonic functional structrues in biomedicine and informatics Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
Studies on plant pathogens, arthropods, weeds, and pesticides with a view to developing the methods of biorational plant protection and safe food production Research and verification of the multidisciplinary forensic methods in
International Atomic Energy Agency (IAEA), Contract No. 20636. Ministry of Education, Science and Technological Development of the Republic of Serbia
Ministry of Science and Technological Development of the Republic of Serbia [TR19031] Ministry of Science and Technological Development of the Republic Serbia
NATO [EAP.SFPP 984925] NATO (EAP·SFPP 984925) (“DURAPEM - Novel Materials for Durable Proton Exchange Membrane Fuel Cells”)
NATO [SPS G5550] Serbian Academy of Sciences and Arts
Serbian Academy of Sciences and Arts, DAAD fellowship [A/10/05029] Serbian Academy of Sciences and Arts (F-190)

Author's Bibliography

Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes

Lučić, Milica; Momčilović, Milan Z.; Marković, Jelena; Jović, Mihajlo D.; Smičiklas, Ivana D.; Onjia, Antonije E.

(2023)

TY  - JOUR
AU  - Lučić, Milica
AU  - Momčilović, Milan Z.
AU  - Marković, Jelena
AU  - Jović, Mihajlo D.
AU  - Smičiklas, Ivana D.
AU  - Onjia, Antonije E.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10695
AB  - The human health risks of cadmium (Cd), lead (Pb), and nickel (Ni) in fifty regular and slim cigarette brands available in the Serbian market were evaluated. Distributions on per-cigarette basis concentrations of these metals, as determined by graphite furnace atomic absorption spectrometry, were used as inputs in the probabilistic risk assessment. The contents of these metals in cigarettes varied significantly. Larger quantities of the studied metals were observed in regular cigarettes than in slim cigarettes, but the concentration levels per cigarette tobacco mass were higher in slim cigarettes. The metal concentrations in counterfeit cigarettes were marginally higher than those in authentic brands. Based on the mean concentrations, Pb was the most abundant toxic metal, followed by Ni and Cd. The calculated values of the cumulative hazard index (HI) and incremental lifetime cancer risk (ILCR) indicated a low noncarcinogenic risk and low but not negligible carcinogenic risk from Cd, Pb, and Ni. The mean HI and ILCR values obtained using probabilistic and deterministic approaches were similar. A Monte Carlo simulation was employed to minimize the uncertainty of health risk estimation. The sensitivity analysis revealed that the most influential factor was cigarette mass followed by Cd content.
T2  - Toxicological and Environmental Chemistry
T1  - Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes
VL  - 105
IS  - 1-7
SP  - 92
EP  - 110
DO  - 10.1080/02772248.2023.2177291
ER  - 
@article{
author = "Lučić, Milica and Momčilović, Milan Z. and Marković, Jelena and Jović, Mihajlo D. and Smičiklas, Ivana D. and Onjia, Antonije E.",
year = "2023",
abstract = "The human health risks of cadmium (Cd), lead (Pb), and nickel (Ni) in fifty regular and slim cigarette brands available in the Serbian market were evaluated. Distributions on per-cigarette basis concentrations of these metals, as determined by graphite furnace atomic absorption spectrometry, were used as inputs in the probabilistic risk assessment. The contents of these metals in cigarettes varied significantly. Larger quantities of the studied metals were observed in regular cigarettes than in slim cigarettes, but the concentration levels per cigarette tobacco mass were higher in slim cigarettes. The metal concentrations in counterfeit cigarettes were marginally higher than those in authentic brands. Based on the mean concentrations, Pb was the most abundant toxic metal, followed by Ni and Cd. The calculated values of the cumulative hazard index (HI) and incremental lifetime cancer risk (ILCR) indicated a low noncarcinogenic risk and low but not negligible carcinogenic risk from Cd, Pb, and Ni. The mean HI and ILCR values obtained using probabilistic and deterministic approaches were similar. A Monte Carlo simulation was employed to minimize the uncertainty of health risk estimation. The sensitivity analysis revealed that the most influential factor was cigarette mass followed by Cd content.",
journal = "Toxicological and Environmental Chemistry",
title = "Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes",
volume = "105",
number = "1-7",
pages = "92-110",
doi = "10.1080/02772248.2023.2177291"
}
Lučić, M., Momčilović, M. Z., Marković, J., Jović, M. D., Smičiklas, I. D.,& Onjia, A. E.. (2023). Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes. in Toxicological and Environmental Chemistry, 105(1-7), 92-110.
https://doi.org/10.1080/02772248.2023.2177291
Lučić M, Momčilović MZ, Marković J, Jović MD, Smičiklas ID, Onjia AE. Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes. in Toxicological and Environmental Chemistry. 2023;105(1-7):92-110.
doi:10.1080/02772248.2023.2177291 .
Lučić, Milica, Momčilović, Milan Z., Marković, Jelena, Jović, Mihajlo D., Smičiklas, Ivana D., Onjia, Antonije E., "Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes" in Toxicological and Environmental Chemistry, 105, no. 1-7 (2023):92-110,
https://doi.org/10.1080/02772248.2023.2177291 . .
5
3

Sustainable pectin monolith cryogels

Nešić, Aleksandra; Meseldžija, Slađana; Momčilović, Milan

(University of Belgrade : Technical Faculty in Bor, 2023)

TY  - CONF
AU  - Nešić, Aleksandra
AU  - Meseldžija, Slađana
AU  - Momčilović, Milan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12655
AB  - The subject of this work is synthesis and characterization of pectin-based cryogels obtained by internal crosslinking with calcium ions. The crosslinking reaction was confirmed by FTIR/ATR analysis, while SEM analysis demonstrated that pores of obtained cryogel were in macro range (between 130 and 380 µm). Pectin cryogel had high swelling degree with the value of 800% after 24 h of immersion in distilled water, and high water vapor permeability (E-7 order, g/ m s Pa). In addition, it showed high rate of biodegradation (85%) after exposure of 3 months in the soil. The obtained results suggest that pectin cryogel obtained by internal crosslinking reaction might find applicable potential in food, agriculture and separation technologies, providing an eco-sustainable approach to tackle current ecological and economical stresses.
PB  - University of Belgrade : Technical Faculty in Bor
C3  - EcoTER’23 : 30th International Conference Ecological Truth and Environmental Research : Proceedings
T1  - Sustainable pectin monolith cryogels
SP  - 88
EP  - 93
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12655
ER  - 
@conference{
author = "Nešić, Aleksandra and Meseldžija, Slađana and Momčilović, Milan",
year = "2023",
abstract = "The subject of this work is synthesis and characterization of pectin-based cryogels obtained by internal crosslinking with calcium ions. The crosslinking reaction was confirmed by FTIR/ATR analysis, while SEM analysis demonstrated that pores of obtained cryogel were in macro range (between 130 and 380 µm). Pectin cryogel had high swelling degree with the value of 800% after 24 h of immersion in distilled water, and high water vapor permeability (E-7 order, g/ m s Pa). In addition, it showed high rate of biodegradation (85%) after exposure of 3 months in the soil. The obtained results suggest that pectin cryogel obtained by internal crosslinking reaction might find applicable potential in food, agriculture and separation technologies, providing an eco-sustainable approach to tackle current ecological and economical stresses.",
publisher = "University of Belgrade : Technical Faculty in Bor",
journal = "EcoTER’23 : 30th International Conference Ecological Truth and Environmental Research : Proceedings",
title = "Sustainable pectin monolith cryogels",
pages = "88-93",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12655"
}
Nešić, A., Meseldžija, S.,& Momčilović, M.. (2023). Sustainable pectin monolith cryogels. in EcoTER’23 : 30th International Conference Ecological Truth and Environmental Research : Proceedings
University of Belgrade : Technical Faculty in Bor., 88-93.
https://hdl.handle.net/21.15107/rcub_vinar_12655
Nešić A, Meseldžija S, Momčilović M. Sustainable pectin monolith cryogels. in EcoTER’23 : 30th International Conference Ecological Truth and Environmental Research : Proceedings. 2023;:88-93.
https://hdl.handle.net/21.15107/rcub_vinar_12655 .
Nešić, Aleksandra, Meseldžija, Slađana, Momčilović, Milan, "Sustainable pectin monolith cryogels" in EcoTER’23 : 30th International Conference Ecological Truth and Environmental Research : Proceedings (2023):88-93,
https://hdl.handle.net/21.15107/rcub_vinar_12655 .

Antioxidant Activity of Grapefruit (Citrus Paradisi) Extract

Miljković, Vojkan; Mrmošanin, Jelena; Zvezdanović, Jelena; Momčilović, Milan Z.; Miljković, Milena; Mihajlov-Krstev, Tatjana; Nikolić, Ljubiša

(Leskovac : Faculty of Technology, University of Niš, 2023)

TY  - CONF
AU  - Miljković, Vojkan
AU  - Mrmošanin, Jelena
AU  - Zvezdanović, Jelena
AU  - Momčilović, Milan Z.
AU  - Miljković, Milena
AU  - Mihajlov-Krstev, Tatjana
AU  - Nikolić, Ljubiša
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12250
AB  - Citrus fruits are widely consumed around the world and among them grapefruit (Citrus paradisi macfad) stands out with its characteristic appearance and flavor. The fruit is growing on a tree that belongs to Rutaceae family and its positive contribution to health is attributed to phytochemicals found in it. The phytochemicals have the key role in mediating oxidation process because they act as antioxidants and by that prevention of cell damage, reducing the risks of many diseases, boosting of the immune system, balancing hormone levels, and notable antibacterial and antiviral response of the organism happens. Grapefruits contain several phytochemicals including: carotenoids, flavonoids (naringin), limonoids, organic acids, pectin, and folate. Considering the worldwide consumption and popularity in everyday diet of grapefruit, the antioxidant activity of its extracts is determined in this paper. Weighed amount 10 g of fresh grapefruits was added to a mixture consisting of organic solvents (hexane, acetone, and ethanol in volumes ratio 2:1:1, respectively) and 0.05% (w/v) butylated hydroxytoluene. The mixture was stoppered and mixed on an orbital shaker at 180 rpm for 15 minutes. The temperature during the mixing was kept at 5 °C in the water bath. Afterward, 7.5 ml of cold deionized water on every 10 grams of starting sample was added to the mixture and agitated for another 5 min. The suspension was transferred to a separation funnel to separate the upper (non-polar) from the lower (polar) phase for 10 minutes at room temperature. The polar phase was subjected for antioxidant capacity determination by ABTS, DPPH, FRAP and CUPRAC methods. The results for the applied methods expressed per kg of the sample are: 1.8 mmol∙kg-1, 0.72 mmol∙kg-1, 9.7 μmol∙kg-1, 4.66 mmol∙kg-1, respectively. The obtained results are recommending grapefruit as a potent source of phytochemicals with antioxidant properties.
PB  - Leskovac : Faculty of Technology, University of Niš
C3  - 15th International symposium „Novel technologies and sustainable development" : Book of Abstracts
T1  - Antioxidant Activity of Grapefruit (Citrus Paradisi) Extract
SP  - 70
EP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12250
ER  - 
@conference{
author = "Miljković, Vojkan and Mrmošanin, Jelena and Zvezdanović, Jelena and Momčilović, Milan Z. and Miljković, Milena and Mihajlov-Krstev, Tatjana and Nikolić, Ljubiša",
year = "2023",
abstract = "Citrus fruits are widely consumed around the world and among them grapefruit (Citrus paradisi macfad) stands out with its characteristic appearance and flavor. The fruit is growing on a tree that belongs to Rutaceae family and its positive contribution to health is attributed to phytochemicals found in it. The phytochemicals have the key role in mediating oxidation process because they act as antioxidants and by that prevention of cell damage, reducing the risks of many diseases, boosting of the immune system, balancing hormone levels, and notable antibacterial and antiviral response of the organism happens. Grapefruits contain several phytochemicals including: carotenoids, flavonoids (naringin), limonoids, organic acids, pectin, and folate. Considering the worldwide consumption and popularity in everyday diet of grapefruit, the antioxidant activity of its extracts is determined in this paper. Weighed amount 10 g of fresh grapefruits was added to a mixture consisting of organic solvents (hexane, acetone, and ethanol in volumes ratio 2:1:1, respectively) and 0.05% (w/v) butylated hydroxytoluene. The mixture was stoppered and mixed on an orbital shaker at 180 rpm for 15 minutes. The temperature during the mixing was kept at 5 °C in the water bath. Afterward, 7.5 ml of cold deionized water on every 10 grams of starting sample was added to the mixture and agitated for another 5 min. The suspension was transferred to a separation funnel to separate the upper (non-polar) from the lower (polar) phase for 10 minutes at room temperature. The polar phase was subjected for antioxidant capacity determination by ABTS, DPPH, FRAP and CUPRAC methods. The results for the applied methods expressed per kg of the sample are: 1.8 mmol∙kg-1, 0.72 mmol∙kg-1, 9.7 μmol∙kg-1, 4.66 mmol∙kg-1, respectively. The obtained results are recommending grapefruit as a potent source of phytochemicals with antioxidant properties.",
publisher = "Leskovac : Faculty of Technology, University of Niš",
journal = "15th International symposium „Novel technologies and sustainable development" : Book of Abstracts",
title = "Antioxidant Activity of Grapefruit (Citrus Paradisi) Extract",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12250"
}
Miljković, V., Mrmošanin, J., Zvezdanović, J., Momčilović, M. Z., Miljković, M., Mihajlov-Krstev, T.,& Nikolić, L.. (2023). Antioxidant Activity of Grapefruit (Citrus Paradisi) Extract. in 15th International symposium „Novel technologies and sustainable development" : Book of Abstracts
Leskovac : Faculty of Technology, University of Niš., 70-70.
https://hdl.handle.net/21.15107/rcub_vinar_12250
Miljković V, Mrmošanin J, Zvezdanović J, Momčilović MZ, Miljković M, Mihajlov-Krstev T, Nikolić L. Antioxidant Activity of Grapefruit (Citrus Paradisi) Extract. in 15th International symposium „Novel technologies and sustainable development" : Book of Abstracts. 2023;:70-70.
https://hdl.handle.net/21.15107/rcub_vinar_12250 .
Miljković, Vojkan, Mrmošanin, Jelena, Zvezdanović, Jelena, Momčilović, Milan Z., Miljković, Milena, Mihajlov-Krstev, Tatjana, Nikolić, Ljubiša, "Antioxidant Activity of Grapefruit (Citrus Paradisi) Extract" in 15th International symposium „Novel technologies and sustainable development" : Book of Abstracts (2023):70-70,
https://hdl.handle.net/21.15107/rcub_vinar_12250 .

Carotenoid and flavonoid levels, antioxidant activity and antimicrobial properties of tomato grown in Serbia

Miljković, Vojkan M.; Momčilović, Milan Z.; Zvezdanović, Jelena B.; Gajić, Ivana Lj.; Mrmošanin, Jelena M.; Mihajlov-Krstev, Tatjana

(2022)

TY  - JOUR
AU  - Miljković, Vojkan M.
AU  - Momčilović, Milan Z.
AU  - Zvezdanović, Jelena B.
AU  - Gajić, Ivana Lj.
AU  - Mrmošanin, Jelena M.
AU  - Mihajlov-Krstev, Tatjana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10553
AB  - This work provides an insight into the nutritional quality of Hector-F1 tomato (Solanum lycopersicum L.) fruit grown in Serbia and the juice prepared from it regarding the contents of carotenoids, flavonoids and polyphenols as compounds beneficial for a healthy diet. Initially, ultra-high performance liquid chromatography with electrospray ionization mass spectrometry (UHPLC-ESI-MS) was employed for both polar and non-polar tomato extracts to identify compounds present in the samples. Then, lycopene, β-carotene, total polyphenols and flavonoids contents were determined by means of ultraviolet-visible (UV-Vis) spectrophotometry. To evaluate the antioxidant activity of the samples, four methods were applied, namely, the 2,2’-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid (ABTS) method, 2,2-diphenyl-1-picrylhydrazyl (DPPH) method, the ferric ion reducing antioxidant power (FRAP) method and the cupric ion reducing antioxidant capacity (CUPRAC) method. In addition, the antimicrobial potential was tested against gram-positive bacteria, gram-negative bacteria and the yeast Candida albicans. The thermal treatment in all cases modified the chemical composition of tomato as demonstrated by a decrease in values of all measured parameters. This comprehensive analysis provided data applicable to profiling and comparing cultivars grown in different geographical regions. © 2022 National Agricultural and Food Centre (Slovakia).
T2  - Journal of Food and Nutrition Research
T1  - Carotenoid and flavonoid levels, antioxidant activity and antimicrobial properties of tomato grown in Serbia
VL  - 61
IS  - 4
SP  - 402
EP  - 414
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10553
ER  - 
@article{
author = "Miljković, Vojkan M. and Momčilović, Milan Z. and Zvezdanović, Jelena B. and Gajić, Ivana Lj. and Mrmošanin, Jelena M. and Mihajlov-Krstev, Tatjana",
year = "2022",
abstract = "This work provides an insight into the nutritional quality of Hector-F1 tomato (Solanum lycopersicum L.) fruit grown in Serbia and the juice prepared from it regarding the contents of carotenoids, flavonoids and polyphenols as compounds beneficial for a healthy diet. Initially, ultra-high performance liquid chromatography with electrospray ionization mass spectrometry (UHPLC-ESI-MS) was employed for both polar and non-polar tomato extracts to identify compounds present in the samples. Then, lycopene, β-carotene, total polyphenols and flavonoids contents were determined by means of ultraviolet-visible (UV-Vis) spectrophotometry. To evaluate the antioxidant activity of the samples, four methods were applied, namely, the 2,2’-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid (ABTS) method, 2,2-diphenyl-1-picrylhydrazyl (DPPH) method, the ferric ion reducing antioxidant power (FRAP) method and the cupric ion reducing antioxidant capacity (CUPRAC) method. In addition, the antimicrobial potential was tested against gram-positive bacteria, gram-negative bacteria and the yeast Candida albicans. The thermal treatment in all cases modified the chemical composition of tomato as demonstrated by a decrease in values of all measured parameters. This comprehensive analysis provided data applicable to profiling and comparing cultivars grown in different geographical regions. © 2022 National Agricultural and Food Centre (Slovakia).",
journal = "Journal of Food and Nutrition Research",
title = "Carotenoid and flavonoid levels, antioxidant activity and antimicrobial properties of tomato grown in Serbia",
volume = "61",
number = "4",
pages = "402-414",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10553"
}
Miljković, V. M., Momčilović, M. Z., Zvezdanović, J. B., Gajić, I. Lj., Mrmošanin, J. M.,& Mihajlov-Krstev, T.. (2022). Carotenoid and flavonoid levels, antioxidant activity and antimicrobial properties of tomato grown in Serbia. in Journal of Food and Nutrition Research, 61(4), 402-414.
https://hdl.handle.net/21.15107/rcub_vinar_10553
Miljković VM, Momčilović MZ, Zvezdanović JB, Gajić IL, Mrmošanin JM, Mihajlov-Krstev T. Carotenoid and flavonoid levels, antioxidant activity and antimicrobial properties of tomato grown in Serbia. in Journal of Food and Nutrition Research. 2022;61(4):402-414.
https://hdl.handle.net/21.15107/rcub_vinar_10553 .
Miljković, Vojkan M., Momčilović, Milan Z., Zvezdanović, Jelena B., Gajić, Ivana Lj., Mrmošanin, Jelena M., Mihajlov-Krstev, Tatjana, "Carotenoid and flavonoid levels, antioxidant activity and antimicrobial properties of tomato grown in Serbia" in Journal of Food and Nutrition Research, 61, no. 4 (2022):402-414,
https://hdl.handle.net/21.15107/rcub_vinar_10553 .

Recent Advances in Electrochemical Determination of Pesticides

Momčilović, Milan Z.; Milićević, Jelena S.; Ranđelović, Marjan S.

(2021)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Milićević, Jelena S.
AU  - Ranđelović, Marjan S.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10761
AB  - Widespread usage of pesticides in agricultural practice caused their residues to appear in water and food products intended for human consumption. The potential toxicity of these resources has raised awareness about pesticide tracking in the environment. Development of reliable electrochemical sensors for the on-site determination of pesticide concentrations is envisioned as an alternative to conventional chromatographic methods which are robust, expensive and require skilled work force. Modification of the working electrode surface can result in enhanced electrochemical response towards selected pesticide making such electrode convenient sensor for facile and efficient determination of pesticides in low concentrations. New generation of nanomaterials is applied in electrode modification in order to improve its sensitivity and selectivity. The present review summarizes significant advances in voltammetric detection of pesticides for the period of the past five years. The major focus of this review is set to the types of carbon and oxide based materials, metal nanoparticles, composites and other materials employed to upgrade standard electrode configurations such as glassy carbon and carbon paste electrodes, boron doped diamond electrodes, screen printed and film electrodes, metal and amalgam, and other kinds of electrodes.
T2  - Journal of Nanoscience and Nanotechnology
T1  - Recent Advances in Electrochemical Determination of Pesticides
VL  - 21
IS  - 12
SP  - 5795
EP  - 5811
DO  - 10.1166/jnn.2021.19541
ER  - 
@article{
author = "Momčilović, Milan Z. and Milićević, Jelena S. and Ranđelović, Marjan S.",
year = "2021",
abstract = "Widespread usage of pesticides in agricultural practice caused their residues to appear in water and food products intended for human consumption. The potential toxicity of these resources has raised awareness about pesticide tracking in the environment. Development of reliable electrochemical sensors for the on-site determination of pesticide concentrations is envisioned as an alternative to conventional chromatographic methods which are robust, expensive and require skilled work force. Modification of the working electrode surface can result in enhanced electrochemical response towards selected pesticide making such electrode convenient sensor for facile and efficient determination of pesticides in low concentrations. New generation of nanomaterials is applied in electrode modification in order to improve its sensitivity and selectivity. The present review summarizes significant advances in voltammetric detection of pesticides for the period of the past five years. The major focus of this review is set to the types of carbon and oxide based materials, metal nanoparticles, composites and other materials employed to upgrade standard electrode configurations such as glassy carbon and carbon paste electrodes, boron doped diamond electrodes, screen printed and film electrodes, metal and amalgam, and other kinds of electrodes.",
journal = "Journal of Nanoscience and Nanotechnology",
title = "Recent Advances in Electrochemical Determination of Pesticides",
volume = "21",
number = "12",
pages = "5795-5811",
doi = "10.1166/jnn.2021.19541"
}
Momčilović, M. Z., Milićević, J. S.,& Ranđelović, M. S.. (2021). Recent Advances in Electrochemical Determination of Pesticides. in Journal of Nanoscience and Nanotechnology, 21(12), 5795-5811.
https://doi.org/10.1166/jnn.2021.19541
Momčilović MZ, Milićević JS, Ranđelović MS. Recent Advances in Electrochemical Determination of Pesticides. in Journal of Nanoscience and Nanotechnology. 2021;21(12):5795-5811.
doi:10.1166/jnn.2021.19541 .
Momčilović, Milan Z., Milićević, Jelena S., Ranđelović, Marjan S., "Recent Advances in Electrochemical Determination of Pesticides" in Journal of Nanoscience and Nanotechnology, 21, no. 12 (2021):5795-5811,
https://doi.org/10.1166/jnn.2021.19541 . .
2

Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry

Momčilović, Milan Z.; Ranđelović, Marjan; Milićević, Jelena S.; Bojić, Aleksandar

(2021)

TY  - CONF
AU  - Momčilović, Milan Z.
AU  - Ranđelović, Marjan
AU  - Milićević, Jelena S.
AU  - Bojić, Aleksandar
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10762
AB  - Two novel types of electrochemical sensors were obtained by chemical deposition of Pt and MoO2 nanoparticles onto multi walled carbon nano tubes (MWCNT) and used for determination of frequently used pesticides clomazone and oxyfluorfen in aqueous media via differential pulse stripping voltammetry (DPSV). Clomazone was determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range 0.61-20.56 ng cm-3, with LOQ = 0.61 and LOD = 0.38 ng cm-3. Oxyfluorfen was determined with good reproducibility (RSD <2.4%) in the concentration range 2.5-34.5 ng cm-3, with r = 0.99 and a LOQ of 1.5 ng cm-3. Results were in the same range measured by HPLC/DAD, which was used as comparative method. Structural characterization of the dopped MWCNT performed by Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron (HR-TEM), and X-ray crystallography revealed a preserved MWCNT structure decorated with well dispersed species of the platinum and MoO2 nanoparticles.
C3  - Technics. Technologies. Education. Safety. 2021 - Proceedings
T1  - Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry
VL  - 2
SP  - 88
EP  - 90
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10762
ER  - 
@conference{
author = "Momčilović, Milan Z. and Ranđelović, Marjan and Milićević, Jelena S. and Bojić, Aleksandar",
year = "2021",
abstract = "Two novel types of electrochemical sensors were obtained by chemical deposition of Pt and MoO2 nanoparticles onto multi walled carbon nano tubes (MWCNT) and used for determination of frequently used pesticides clomazone and oxyfluorfen in aqueous media via differential pulse stripping voltammetry (DPSV). Clomazone was determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range 0.61-20.56 ng cm-3, with LOQ = 0.61 and LOD = 0.38 ng cm-3. Oxyfluorfen was determined with good reproducibility (RSD <2.4%) in the concentration range 2.5-34.5 ng cm-3, with r = 0.99 and a LOQ of 1.5 ng cm-3. Results were in the same range measured by HPLC/DAD, which was used as comparative method. Structural characterization of the dopped MWCNT performed by Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron (HR-TEM), and X-ray crystallography revealed a preserved MWCNT structure decorated with well dispersed species of the platinum and MoO2 nanoparticles.",
journal = "Technics. Technologies. Education. Safety. 2021 - Proceedings",
title = "Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry",
volume = "2",
pages = "88-90",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10762"
}
Momčilović, M. Z., Ranđelović, M., Milićević, J. S.,& Bojić, A.. (2021). Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry. in Technics. Technologies. Education. Safety. 2021 - Proceedings, 2, 88-90.
https://hdl.handle.net/21.15107/rcub_vinar_10762
Momčilović MZ, Ranđelović M, Milićević JS, Bojić A. Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry. in Technics. Technologies. Education. Safety. 2021 - Proceedings. 2021;2:88-90.
https://hdl.handle.net/21.15107/rcub_vinar_10762 .
Momčilović, Milan Z., Ranđelović, Marjan, Milićević, Jelena S., Bojić, Aleksandar, "Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry" in Technics. Technologies. Education. Safety. 2021 - Proceedings, 2 (2021):88-90,
https://hdl.handle.net/21.15107/rcub_vinar_10762 .

Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen

Milićević, Jelena S.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Zarubica, Aleksandra R.; Mofarah, Sajjad S.; Matović, Branko; Sorrel, Charles C.

(2020)

TY  - JOUR
AU  - Milićević, Jelena S.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Zarubica, Aleksandra R.
AU  - Mofarah, Sajjad S.
AU  - Matović, Branko
AU  - Sorrel, Charles C.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9068
AB  - A glassy carbon electrode was functionalized by MoO2 nanoparticle–decorated multiwalled carbon nanotubes (MWCNTs) and examined as a working electrode in oxyfluorfen (OXY) detection by differential pulse stripping voltammetry (DPSV). Measurement parameters were as follows: initial potential − 0.1 V, end potential + 0.5 V, accumulation potential − 0.15 V, accumulation time 80 s, and scan rate 50 mV s−1. A stripping potential of + 0.315 V vs. Ag/AgCl was employed. The pPesticide oxyfluorfen was determined in model samples by DPSV with good reproducibility (RSD <2.4%) in the concentration range 2.5 to 34.5 ng mL−1, with r = 0.99 and a limit of detection of 1.5 ng mL−1. These results are in the same range as those of HPLC/DAD, which is used as the comparative method. Recovery for OXY determination in a real river water sample was 102%. Analyses in Briton-Robinson buffer has shown to be pH dependent with the best response at pH 6.0. Structural characterization of MoO2-MWCNT by Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray crystallography revealed a preserved MWCNT structure decorated with firmly attached clusters of MoO2 nanoparticles.
T2  - Microchimica Acta
T1  - Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen
VL  - 187
IS  - 8
SP  - 429
DO  - 10.1007/s00604-020-04406-4
ER  - 
@article{
author = "Milićević, Jelena S. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Zarubica, Aleksandra R. and Mofarah, Sajjad S. and Matović, Branko and Sorrel, Charles C.",
year = "2020",
abstract = "A glassy carbon electrode was functionalized by MoO2 nanoparticle–decorated multiwalled carbon nanotubes (MWCNTs) and examined as a working electrode in oxyfluorfen (OXY) detection by differential pulse stripping voltammetry (DPSV). Measurement parameters were as follows: initial potential − 0.1 V, end potential + 0.5 V, accumulation potential − 0.15 V, accumulation time 80 s, and scan rate 50 mV s−1. A stripping potential of + 0.315 V vs. Ag/AgCl was employed. The pPesticide oxyfluorfen was determined in model samples by DPSV with good reproducibility (RSD <2.4%) in the concentration range 2.5 to 34.5 ng mL−1, with r = 0.99 and a limit of detection of 1.5 ng mL−1. These results are in the same range as those of HPLC/DAD, which is used as the comparative method. Recovery for OXY determination in a real river water sample was 102%. Analyses in Briton-Robinson buffer has shown to be pH dependent with the best response at pH 6.0. Structural characterization of MoO2-MWCNT by Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray crystallography revealed a preserved MWCNT structure decorated with firmly attached clusters of MoO2 nanoparticles.",
journal = "Microchimica Acta",
title = "Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen",
volume = "187",
number = "8",
pages = "429",
doi = "10.1007/s00604-020-04406-4"
}
Milićević, J. S., Ranđelović, M. S., Momčilović, M. Z., Zarubica, A. R., Mofarah, S. S., Matović, B.,& Sorrel, C. C.. (2020). Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen. in Microchimica Acta, 187(8), 429.
https://doi.org/10.1007/s00604-020-04406-4
Milićević JS, Ranđelović MS, Momčilović MZ, Zarubica AR, Mofarah SS, Matović B, Sorrel CC. Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen. in Microchimica Acta. 2020;187(8):429.
doi:10.1007/s00604-020-04406-4 .
Milićević, Jelena S., Ranđelović, Marjan S., Momčilović, Milan Z., Zarubica, Aleksandra R., Mofarah, Sajjad S., Matović, Branko, Sorrel, Charles C., "Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen" in Microchimica Acta, 187, no. 8 (2020):429,
https://doi.org/10.1007/s00604-020-04406-4 . .
7
5

Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres

Ranđelović, Marjan S.; Momčilović, Milan Z.; Enke, Dirk; Mirčeski, Valentin

(2019)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Enke, Dirk
AU  - Mirčeski, Valentin
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8543
AB  - A simple and facile hydrothermal methodology for preparation of carbon microspheres supported with silver or platinum is presented. Electrocatalytic properties of modified carbon microspheres are tested against the electrochemical reduction reaction of hydrogen peroxide. As revealed by transmission electron microscopy, silver and platinum are immobilized on the surface of carbon microspheres in a form of nanoparticles. In addition, scanning electron microscopy reveals coexistence of smooth surface spherical-shaped carbon microspheres together with clusters that resemble a bunch-of-grapes. Carbon paste electrodes in combination with cyclic and square-wave voltammetry are used to study electrocatalytic properties of carbon microspheres. Voltammetric data are analyzed in light of the theory for simple irreversible electrode reaction. Correlation between experimental and theoretical data implies the highest electrocatalytic effect in the case of silver-modified carbon microspheres, though the electrode mechanism is more complex than theoretically predicted. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Journal of Solid State Electrochemistry
T1  - Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres
VL  - 23
IS  - 4
SP  - 1257
EP  - 1267
DO  - 10.1007/s10008-019-04226-4
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Enke, Dirk and Mirčeski, Valentin",
year = "2019",
abstract = "A simple and facile hydrothermal methodology for preparation of carbon microspheres supported with silver or platinum is presented. Electrocatalytic properties of modified carbon microspheres are tested against the electrochemical reduction reaction of hydrogen peroxide. As revealed by transmission electron microscopy, silver and platinum are immobilized on the surface of carbon microspheres in a form of nanoparticles. In addition, scanning electron microscopy reveals coexistence of smooth surface spherical-shaped carbon microspheres together with clusters that resemble a bunch-of-grapes. Carbon paste electrodes in combination with cyclic and square-wave voltammetry are used to study electrocatalytic properties of carbon microspheres. Voltammetric data are analyzed in light of the theory for simple irreversible electrode reaction. Correlation between experimental and theoretical data implies the highest electrocatalytic effect in the case of silver-modified carbon microspheres, though the electrode mechanism is more complex than theoretically predicted. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Journal of Solid State Electrochemistry",
title = "Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres",
volume = "23",
number = "4",
pages = "1257-1267",
doi = "10.1007/s10008-019-04226-4"
}
Ranđelović, M. S., Momčilović, M. Z., Enke, D.,& Mirčeski, V.. (2019). Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres. in Journal of Solid State Electrochemistry, 23(4), 1257-1267.
https://doi.org/10.1007/s10008-019-04226-4
Ranđelović MS, Momčilović MZ, Enke D, Mirčeski V. Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres. in Journal of Solid State Electrochemistry. 2019;23(4):1257-1267.
doi:10.1007/s10008-019-04226-4 .
Ranđelović, Marjan S., Momčilović, Milan Z., Enke, Dirk, Mirčeski, Valentin, "Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres" in Journal of Solid State Electrochemistry, 23, no. 4 (2019):1257-1267,
https://doi.org/10.1007/s10008-019-04226-4 . .
9
7
9

Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples

Ranđelović, Marjan S.; Momčilović, Milan Z.; Milićević, Jelena S.; Đurović-Pejčev, Rada; Mofarah, Sajjad S.; Sorrel, Charles C.

(2019)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Milićević, Jelena S.
AU  - Đurović-Pejčev, Rada
AU  - Mofarah, Sajjad S.
AU  - Sorrel, Charles C.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8619
AB  - Novel electrochemical sensor based on Pt supported multiwalled carbon nanotubes is used for determination of pesticide clomazone in aqueous media via differential pulse stripping voltammetry (DPSV). Since clomazone is stable and readily soluble in water, it is often found in water sources. Hence, its determination in the environment is of utmost importance. Herein, clomazone is determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range of 0.61–20.56 ng cm−3, with LOQ = 0.61 and LOD = 0.38. These results are in the same range with HPLC/DAD, which is used as comparative method. It is shown that DPSV is a facile and efficient way for determination of clomazone in contrast to precise but field-impractical HPLC. Mechanistic approach in explaining electrode processes is correlated to structural aspects of the synthesized sensor. HRTEM data reveals a uniform distribution of Pt nanoparticles on the MWCNT support as a source of crucial, structural and electronic changes. Furthermore, characterisation of Raman results indicates the existence of structural defects, which is believed to be the leading reason for improvement in sensing response. © 2019 Taiwan Institute of Chemical Engineers
T2  - Journal of the Taiwan Institute of Chemical Engineers
T1  - Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples
VL  - 105
SP  - 115
EP  - 123
DO  - 10.1016/j.jtice.2019.10.013
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Milićević, Jelena S. and Đurović-Pejčev, Rada and Mofarah, Sajjad S. and Sorrel, Charles C.",
year = "2019",
abstract = "Novel electrochemical sensor based on Pt supported multiwalled carbon nanotubes is used for determination of pesticide clomazone in aqueous media via differential pulse stripping voltammetry (DPSV). Since clomazone is stable and readily soluble in water, it is often found in water sources. Hence, its determination in the environment is of utmost importance. Herein, clomazone is determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range of 0.61–20.56 ng cm−3, with LOQ = 0.61 and LOD = 0.38. These results are in the same range with HPLC/DAD, which is used as comparative method. It is shown that DPSV is a facile and efficient way for determination of clomazone in contrast to precise but field-impractical HPLC. Mechanistic approach in explaining electrode processes is correlated to structural aspects of the synthesized sensor. HRTEM data reveals a uniform distribution of Pt nanoparticles on the MWCNT support as a source of crucial, structural and electronic changes. Furthermore, characterisation of Raman results indicates the existence of structural defects, which is believed to be the leading reason for improvement in sensing response. © 2019 Taiwan Institute of Chemical Engineers",
journal = "Journal of the Taiwan Institute of Chemical Engineers",
title = "Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples",
volume = "105",
pages = "115-123",
doi = "10.1016/j.jtice.2019.10.013"
}
Ranđelović, M. S., Momčilović, M. Z., Milićević, J. S., Đurović-Pejčev, R., Mofarah, S. S.,& Sorrel, C. C.. (2019). Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples. in Journal of the Taiwan Institute of Chemical Engineers, 105, 115-123.
https://doi.org/10.1016/j.jtice.2019.10.013
Ranđelović MS, Momčilović MZ, Milićević JS, Đurović-Pejčev R, Mofarah SS, Sorrel CC. Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples. in Journal of the Taiwan Institute of Chemical Engineers. 2019;105:115-123.
doi:10.1016/j.jtice.2019.10.013 .
Ranđelović, Marjan S., Momčilović, Milan Z., Milićević, Jelena S., Đurović-Pejčev, Rada, Mofarah, Sajjad S., Sorrel, Charles C., "Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples" in Journal of the Taiwan Institute of Chemical Engineers, 105 (2019):115-123,
https://doi.org/10.1016/j.jtice.2019.10.013 . .
12
6
13

A study of ordered mesoporous carbon doped with Co and Ni as a catalyst of oxygen reduction reaction in both alkaline and acidic media

Gavrilov, Nemanja M.; Momčilović, Milan Z.; Dobrota, Ana S.; Stanković, Dalibor M.; Jokić, Bojan M.; Babić, Biljana M.; Skorodumova, Natalia V.; Mentus, Slavko V.; Pašti, Igor A.

(2018)

TY  - JOUR
AU  - Gavrilov, Nemanja M.
AU  - Momčilović, Milan Z.
AU  - Dobrota, Ana S.
AU  - Stanković, Dalibor M.
AU  - Jokić, Bojan M.
AU  - Babić, Biljana M.
AU  - Skorodumova, Natalia V.
AU  - Mentus, Slavko V.
AU  - Pašti, Igor A.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0257897218305838
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7727
AB  - The incorporation of trace amounts (<0.2%) of Co and Ni noticeably enhanced the catalytic activity of nitrogen-free ordered mesoporous carbon (OMC) towards oxygen reduction reaction (ORR). (Co,Ni)-doped OMCs were characterized by N2-adsorption measurements, X-ray powder diffraction, field emission scanning electron microscopy and Raman spectroscopy methods, and their ORR activity was estimated by voltammetry on rotating disk electrode in acidic and alkaline media. (Co,Ni)-doped OMCs show modest activities in acidic media, while the catalytic activity in alkaline media is rather high. The measured activities are compared to the Pt-based and Pt-free ORR catalysts reported in the literature. The number of electrons consumed per O2in metal-doped OMCs was found to vary between 2 and 4, which is advantageous in comparison to metal-free OMC. Also, the mass activities of metal-doped OMCs were found to be up to 2.5 times higher compared to that of metal-free OMC. We suggest that the ORR activity is governed by a balance between (i) textural properties, which determine the electrochemically accessible surface of the catalyst and which are influenced by the addition of a metal precursor, and (ii) novel active sites formed upon the introduction of metals into the carbon structure. In particular, our Density Functional Theory calculations suggest that Co and Ni atoms embedded into the single vacancies of graphene can activate the O2molecule and contribute to the decomposition of peroxide.
T2  - Surface and Coatings Technology
T1  - A study of ordered mesoporous carbon doped with Co and Ni as a catalyst of oxygen reduction reaction in both alkaline and acidic media
VL  - 349
SP  - 511
EP  - 521
DO  - 10.1016/j.surfcoat.2018.06.008
ER  - 
@article{
author = "Gavrilov, Nemanja M. and Momčilović, Milan Z. and Dobrota, Ana S. and Stanković, Dalibor M. and Jokić, Bojan M. and Babić, Biljana M. and Skorodumova, Natalia V. and Mentus, Slavko V. and Pašti, Igor A.",
year = "2018",
abstract = "The incorporation of trace amounts (<0.2%) of Co and Ni noticeably enhanced the catalytic activity of nitrogen-free ordered mesoporous carbon (OMC) towards oxygen reduction reaction (ORR). (Co,Ni)-doped OMCs were characterized by N2-adsorption measurements, X-ray powder diffraction, field emission scanning electron microscopy and Raman spectroscopy methods, and their ORR activity was estimated by voltammetry on rotating disk electrode in acidic and alkaline media. (Co,Ni)-doped OMCs show modest activities in acidic media, while the catalytic activity in alkaline media is rather high. The measured activities are compared to the Pt-based and Pt-free ORR catalysts reported in the literature. The number of electrons consumed per O2in metal-doped OMCs was found to vary between 2 and 4, which is advantageous in comparison to metal-free OMC. Also, the mass activities of metal-doped OMCs were found to be up to 2.5 times higher compared to that of metal-free OMC. We suggest that the ORR activity is governed by a balance between (i) textural properties, which determine the electrochemically accessible surface of the catalyst and which are influenced by the addition of a metal precursor, and (ii) novel active sites formed upon the introduction of metals into the carbon structure. In particular, our Density Functional Theory calculations suggest that Co and Ni atoms embedded into the single vacancies of graphene can activate the O2molecule and contribute to the decomposition of peroxide.",
journal = "Surface and Coatings Technology",
title = "A study of ordered mesoporous carbon doped with Co and Ni as a catalyst of oxygen reduction reaction in both alkaline and acidic media",
volume = "349",
pages = "511-521",
doi = "10.1016/j.surfcoat.2018.06.008"
}
Gavrilov, N. M., Momčilović, M. Z., Dobrota, A. S., Stanković, D. M., Jokić, B. M., Babić, B. M., Skorodumova, N. V., Mentus, S. V.,& Pašti, I. A.. (2018). A study of ordered mesoporous carbon doped with Co and Ni as a catalyst of oxygen reduction reaction in both alkaline and acidic media. in Surface and Coatings Technology, 349, 511-521.
https://doi.org/10.1016/j.surfcoat.2018.06.008
Gavrilov NM, Momčilović MZ, Dobrota AS, Stanković DM, Jokić BM, Babić BM, Skorodumova NV, Mentus SV, Pašti IA. A study of ordered mesoporous carbon doped with Co and Ni as a catalyst of oxygen reduction reaction in both alkaline and acidic media. in Surface and Coatings Technology. 2018;349:511-521.
doi:10.1016/j.surfcoat.2018.06.008 .
Gavrilov, Nemanja M., Momčilović, Milan Z., Dobrota, Ana S., Stanković, Dalibor M., Jokić, Bojan M., Babić, Biljana M., Skorodumova, Natalia V., Mentus, Slavko V., Pašti, Igor A., "A study of ordered mesoporous carbon doped with Co and Ni as a catalyst of oxygen reduction reaction in both alkaline and acidic media" in Surface and Coatings Technology, 349 (2018):511-521,
https://doi.org/10.1016/j.surfcoat.2018.06.008 . .
23
16
24

Experimental and modelling study on strontium removal from aqueous solutions by Lagenaria vulgaris biosorbent

Momčilović, Milan Z.; Onjia, Antonije E.; Trajković, Dragana N.; Kostić, Miloš M.; Milenković, Dragan D.; Bojić, Danijela V.; Bojić, Aleksandar Lj.

(2018)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Onjia, Antonije E.
AU  - Trajković, Dragana N.
AU  - Kostić, Miloš M.
AU  - Milenković, Dragan D.
AU  - Bojić, Danijela V.
AU  - Bojić, Aleksandar Lj.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0167732218302800
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7741
AB  - The shell of Lagenaria vulgaris (LV) plant was used as biosorbent for strontium removal from aqueous solutions. Chemical structure of the biosorbent's surface was characterized by the means of FTIR and Boehm's titrations. SEM-EDX technique was used to study the morphology and elemental composition of the material. The analyses pointed out to abundance of acidic functional groups which are charged in solution and hence responsible for ionic exchange of Sr(II) ions. Sorption was examined by varying initial concentrations of Sr(II) in solutions, sorbent's loadings, pH, and contacting times. Equilibrium of the process was attained in the first 10 min of contacting and followed pseudo-second order and Chrastil's kinetic models. It was established that sorption onto aLVB was heterogenous by nature and fitted well to Freundlich and Sips isotherm models with maximum sorption capacity of 29.55 mg g(-1). Sorption potentail was kept high after six cycles when acidic desorbents were used.
T2  - Journal of Molecular Liquids
T1  - Experimental and modelling study on strontium removal from aqueous solutions by Lagenaria vulgaris biosorbent
VL  - 258
SP  - 335
EP  - 344
DO  - 10.1016/j.molliq.2018.03.048
ER  - 
@article{
author = "Momčilović, Milan Z. and Onjia, Antonije E. and Trajković, Dragana N. and Kostić, Miloš M. and Milenković, Dragan D. and Bojić, Danijela V. and Bojić, Aleksandar Lj.",
year = "2018",
abstract = "The shell of Lagenaria vulgaris (LV) plant was used as biosorbent for strontium removal from aqueous solutions. Chemical structure of the biosorbent's surface was characterized by the means of FTIR and Boehm's titrations. SEM-EDX technique was used to study the morphology and elemental composition of the material. The analyses pointed out to abundance of acidic functional groups which are charged in solution and hence responsible for ionic exchange of Sr(II) ions. Sorption was examined by varying initial concentrations of Sr(II) in solutions, sorbent's loadings, pH, and contacting times. Equilibrium of the process was attained in the first 10 min of contacting and followed pseudo-second order and Chrastil's kinetic models. It was established that sorption onto aLVB was heterogenous by nature and fitted well to Freundlich and Sips isotherm models with maximum sorption capacity of 29.55 mg g(-1). Sorption potentail was kept high after six cycles when acidic desorbents were used.",
journal = "Journal of Molecular Liquids",
title = "Experimental and modelling study on strontium removal from aqueous solutions by Lagenaria vulgaris biosorbent",
volume = "258",
pages = "335-344",
doi = "10.1016/j.molliq.2018.03.048"
}
Momčilović, M. Z., Onjia, A. E., Trajković, D. N., Kostić, M. M., Milenković, D. D., Bojić, D. V.,& Bojić, A. Lj.. (2018). Experimental and modelling study on strontium removal from aqueous solutions by Lagenaria vulgaris biosorbent. in Journal of Molecular Liquids, 258, 335-344.
https://doi.org/10.1016/j.molliq.2018.03.048
Momčilović MZ, Onjia AE, Trajković DN, Kostić MM, Milenković DD, Bojić DV, Bojić AL. Experimental and modelling study on strontium removal from aqueous solutions by Lagenaria vulgaris biosorbent. in Journal of Molecular Liquids. 2018;258:335-344.
doi:10.1016/j.molliq.2018.03.048 .
Momčilović, Milan Z., Onjia, Antonije E., Trajković, Dragana N., Kostić, Miloš M., Milenković, Dragan D., Bojić, Danijela V., Bojić, Aleksandar Lj., "Experimental and modelling study on strontium removal from aqueous solutions by Lagenaria vulgaris biosorbent" in Journal of Molecular Liquids, 258 (2018):335-344,
https://doi.org/10.1016/j.molliq.2018.03.048 . .
3
1
4

Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites

Ranđelović, Marjan S.; Momčilović, Milan Z.; Purenović, Jelena M.; Dornberg, Gregor; Barascu, Andrei; Enke, Dirk; Zarubica, Aleksandra R.

(2018)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Purenović, Jelena M.
AU  - Dornberg, Gregor
AU  - Barascu, Andrei
AU  - Enke, Dirk
AU  - Zarubica, Aleksandra R.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S092777571830284X
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7742
AB  - Three types of functional ceramic composites were designed, synthesized and probed for effective sulfide removal from aqueous solutions. The main goal was to examine complex influence of graphite, surpluses of Fe (similar to 4%) and micro-additions of Cu (similar to 0.2%) on the functional features of the composites. The structural, textural, morphological and surface characteristics of the composites were examined in detail by XRD, nitrogen sorption, SEM and FTIR. It has been shown that all composites are solid heterogeneous systems containing amorphous and crystalline phases (graphite, hematite, montmorillonite, quartz, etc.) with pronounced redox activity in contact with sulfide aqueous solutions. Great enhancment of sulfide consumption was detected for composites which contained graphite and it was established that reaction kinetics is fitted to irreversible second-order batch reaction with two reactants. After the treatment of 1 mM S2- solution, using composite dossage of 1 g/dm(3), concentration dropped down to 0.02 mM. In addition, cyclic voltammetry at 50 mV/s revealed the key role of dopants in electrochemical aspect of the process. Obvious boost of S2- uptake is ascribed to numerous electrochemical, chemical and sorption processes on the composite's developed surface.
T2  - Colloids and Surfaces. A: Physicochemical and Engineering Aspects
T1  - Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites
VL  - 549
SP  - 196
EP  - 204
DO  - 10.1016/j.colsurfa.2018.04.014
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Purenović, Jelena M. and Dornberg, Gregor and Barascu, Andrei and Enke, Dirk and Zarubica, Aleksandra R.",
year = "2018",
abstract = "Three types of functional ceramic composites were designed, synthesized and probed for effective sulfide removal from aqueous solutions. The main goal was to examine complex influence of graphite, surpluses of Fe (similar to 4%) and micro-additions of Cu (similar to 0.2%) on the functional features of the composites. The structural, textural, morphological and surface characteristics of the composites were examined in detail by XRD, nitrogen sorption, SEM and FTIR. It has been shown that all composites are solid heterogeneous systems containing amorphous and crystalline phases (graphite, hematite, montmorillonite, quartz, etc.) with pronounced redox activity in contact with sulfide aqueous solutions. Great enhancment of sulfide consumption was detected for composites which contained graphite and it was established that reaction kinetics is fitted to irreversible second-order batch reaction with two reactants. After the treatment of 1 mM S2- solution, using composite dossage of 1 g/dm(3), concentration dropped down to 0.02 mM. In addition, cyclic voltammetry at 50 mV/s revealed the key role of dopants in electrochemical aspect of the process. Obvious boost of S2- uptake is ascribed to numerous electrochemical, chemical and sorption processes on the composite's developed surface.",
journal = "Colloids and Surfaces. A: Physicochemical and Engineering Aspects",
title = "Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites",
volume = "549",
pages = "196-204",
doi = "10.1016/j.colsurfa.2018.04.014"
}
Ranđelović, M. S., Momčilović, M. Z., Purenović, J. M., Dornberg, G., Barascu, A., Enke, D.,& Zarubica, A. R.. (2018). Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 549, 196-204.
https://doi.org/10.1016/j.colsurfa.2018.04.014
Ranđelović MS, Momčilović MZ, Purenović JM, Dornberg G, Barascu A, Enke D, Zarubica AR. Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects. 2018;549:196-204.
doi:10.1016/j.colsurfa.2018.04.014 .
Ranđelović, Marjan S., Momčilović, Milan Z., Purenović, Jelena M., Dornberg, Gregor, Barascu, Andrei, Enke, Dirk, Zarubica, Aleksandra R., "Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites" in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 549 (2018):196-204,
https://doi.org/10.1016/j.colsurfa.2018.04.014 . .

Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants

Purenović, Jelena M.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Purenović, Milovan M.; Stanković, Novica J.; Anđelković, Ljiljana N.

(2017)

TY  - JOUR
AU  - Purenović, Jelena M.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Purenović, Milovan M.
AU  - Stanković, Novica J.
AU  - Anđelković, Ljiljana N.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1363
AB  - The physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption properties and suitability of physicochemically modified peat (PCMP) for odor removal were tested in aqueous solutions of H2S and colloidal sulphur. Additionally, PCMP was tested in the removal of As(V) which is hazardous ingredient in contaminated waters. Possible mechanisms of pollutants binding include interactions, which lead to formation of adducts and clathrates. All these processes are elucidated in detail. The results showed that the obtained material can be used for the removal of sulphide, colloidal sulphur and As(V) from different types of waters.
T2  - Hemijska industrija
T1  - Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
VL  - 71
IS  - 4
SP  - 299
EP  - 306
DO  - 10.2298/HEMIND160522040P
ER  - 
@article{
author = "Purenović, Jelena M. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Purenović, Milovan M. and Stanković, Novica J. and Anđelković, Ljiljana N.",
year = "2017",
abstract = "The physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption properties and suitability of physicochemically modified peat (PCMP) for odor removal were tested in aqueous solutions of H2S and colloidal sulphur. Additionally, PCMP was tested in the removal of As(V) which is hazardous ingredient in contaminated waters. Possible mechanisms of pollutants binding include interactions, which lead to formation of adducts and clathrates. All these processes are elucidated in detail. The results showed that the obtained material can be used for the removal of sulphide, colloidal sulphur and As(V) from different types of waters.",
journal = "Hemijska industrija",
title = "Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants",
volume = "71",
number = "4",
pages = "299-306",
doi = "10.2298/HEMIND160522040P"
}
Purenović, J. M., Ranđelović, M. S., Momčilović, M. Z., Purenović, M. M., Stanković, N. J.,& Anđelković, L. N.. (2017). Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants. in Hemijska industrija, 71(4), 299-306.
https://doi.org/10.2298/HEMIND160522040P
Purenović JM, Ranđelović MS, Momčilović MZ, Purenović MM, Stanković NJ, Anđelković LN. Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants. in Hemijska industrija. 2017;71(4):299-306.
doi:10.2298/HEMIND160522040P .
Purenović, Jelena M., Ranđelović, Marjan S., Momčilović, Milan Z., Purenović, Milovan M., Stanković, Novica J., Anđelković, Ljiljana N., "Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants" in Hemijska industrija, 71, no. 4 (2017):299-306,
https://doi.org/10.2298/HEMIND160522040P . .

Electrocatalitic behaviour of serpentinite modified carbon paste electrode

Ranđelović, Marjan S.; Momčilović, Milan Z.; Nikolić, Goran; Đorđević, Jelena S.

(2017)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Nikolić, Goran
AU  - Đorđević, Jelena S.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1754
AB  - Electrochemistry of carbon paste electrode which contained serpentinite powder and graphite in 1:1 weight ratio was examined in three-electrode cell regarding its electrocatalytic and sensing properties. For this purpose, red-ox reactions of potassium ferrocyanide in aqueous solutions as benchmark media and pesticide tebufenozide (TBF) were examined. Serpentinite characterization performed by XRPD, SEM/EDX, and FTIR confirmed the structure typical for this mineral rock. Voltammetric analyses have in all cases shown that serpentinite modified carbon paste electrode (S-CPE) possess superior electrocatalytic activity in contrast to bare CPE for the red-ox reactions of K-4[Fe(CN)(6)]. The enlargement of the peak currents, higher electroactive surface area, and the decline of the peak-to-peak separation are a proof of reversible and faster electron transfer kinetics for S-CPE. The effect of pH on the electrochemical behaviour of TBF was investigated in Britton-Robinson buffer solutions in range from 2.0 to 7.0 and showed the best analytical performance at pH 5.0. The oxidation peak of TBF appeared at + 0.5 V vs. Ag/AgCl under conditions optimized for the determination of TBF in the differential pulse stripping voltammetry: initial potential + 0.1 V, end potential + 0.9 V, accumulation potential -0.35 V, accumulation time 120 s, and the scan rate 50 my s(-1).
T2  - Journal of Electroanalytical Chemistry
T1  - Electrocatalitic behaviour of serpentinite modified carbon paste electrode
VL  - 801
SP  - 338
EP  - 344
DO  - 10.1016/j.jelechem.2017.08.011
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Nikolić, Goran and Đorđević, Jelena S.",
year = "2017",
abstract = "Electrochemistry of carbon paste electrode which contained serpentinite powder and graphite in 1:1 weight ratio was examined in three-electrode cell regarding its electrocatalytic and sensing properties. For this purpose, red-ox reactions of potassium ferrocyanide in aqueous solutions as benchmark media and pesticide tebufenozide (TBF) were examined. Serpentinite characterization performed by XRPD, SEM/EDX, and FTIR confirmed the structure typical for this mineral rock. Voltammetric analyses have in all cases shown that serpentinite modified carbon paste electrode (S-CPE) possess superior electrocatalytic activity in contrast to bare CPE for the red-ox reactions of K-4[Fe(CN)(6)]. The enlargement of the peak currents, higher electroactive surface area, and the decline of the peak-to-peak separation are a proof of reversible and faster electron transfer kinetics for S-CPE. The effect of pH on the electrochemical behaviour of TBF was investigated in Britton-Robinson buffer solutions in range from 2.0 to 7.0 and showed the best analytical performance at pH 5.0. The oxidation peak of TBF appeared at + 0.5 V vs. Ag/AgCl under conditions optimized for the determination of TBF in the differential pulse stripping voltammetry: initial potential + 0.1 V, end potential + 0.9 V, accumulation potential -0.35 V, accumulation time 120 s, and the scan rate 50 my s(-1).",
journal = "Journal of Electroanalytical Chemistry",
title = "Electrocatalitic behaviour of serpentinite modified carbon paste electrode",
volume = "801",
pages = "338-344",
doi = "10.1016/j.jelechem.2017.08.011"
}
Ranđelović, M. S., Momčilović, M. Z., Nikolić, G.,& Đorđević, J. S.. (2017). Electrocatalitic behaviour of serpentinite modified carbon paste electrode. in Journal of Electroanalytical Chemistry, 801, 338-344.
https://doi.org/10.1016/j.jelechem.2017.08.011
Ranđelović MS, Momčilović MZ, Nikolić G, Đorđević JS. Electrocatalitic behaviour of serpentinite modified carbon paste electrode. in Journal of Electroanalytical Chemistry. 2017;801:338-344.
doi:10.1016/j.jelechem.2017.08.011 .
Ranđelović, Marjan S., Momčilović, Milan Z., Nikolić, Goran, Đorđević, Jelena S., "Electrocatalitic behaviour of serpentinite modified carbon paste electrode" in Journal of Electroanalytical Chemistry, 801 (2017):338-344,
https://doi.org/10.1016/j.jelechem.2017.08.011 . .
7
3
7

Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions

Bojić, Danijela V.; Momčilović, Milan Z.; Milenković, Dragan D.; Mitrović, Jelena Z.; Bankovic, Predrag; Velinov, Nena D.; Nikolić, Goran

(2017)

TY  - JOUR
AU  - Bojić, Danijela V.
AU  - Momčilović, Milan Z.
AU  - Milenković, Dragan D.
AU  - Mitrović, Jelena Z.
AU  - Bankovic, Predrag
AU  - Velinov, Nena D.
AU  - Nikolić, Goran
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1811
AB  - Practical aspects of Lagenaria vulgaris shell conversion to activated carbon were examined along with its use in ranitidine adsorption. Kinetics and isotherms of adsorption onto Lagenaria vulgaris carbon (LVC) were correlated to several theoretical adsorption models. The best fit was found in the case of Langmuir and pseudo-second-order model indicating monolayer adsorption. The influence of pH under kinetic study showed slightly hindered adsorption below pH 4. The optimal adsorbent dosage was set to 1 g/L. LVC was characterized by several complementary techniques, including wet chemical techniques such as Boehms titrations and determination of pH(pzc) and pH of LVC, which revealed neutral nature of the adsorbent. N-2 sorptometry determined specific surface area of 665 m(2)/g and significant ratio of micropores in the sample with maximum walls diameter of 2.2 nm. Fourier transform infrared spectroscopy (FTIR) confirmed the role of lignin and cellulose in the formation of the final LVC structure. Porous structure of the material was proved by using scanning electron microscopy. Preparation of LVC material drew attention as an easy and low-cost process for production of a highly efficient adsorbent which exhibited fast kinetics of ranitidine removal in the first minutes of contacting and large adsorption capacity (315.5 mg/g) at equilibrium. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.
T2  - Arabian Journal of Chemistry
T1  - Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions
VL  - 10
IS  - 7
SP  - 956
EP  - 964
DO  - 10.1016/j.arabjc.2014.12.018
ER  - 
@article{
author = "Bojić, Danijela V. and Momčilović, Milan Z. and Milenković, Dragan D. and Mitrović, Jelena Z. and Bankovic, Predrag and Velinov, Nena D. and Nikolić, Goran",
year = "2017",
abstract = "Practical aspects of Lagenaria vulgaris shell conversion to activated carbon were examined along with its use in ranitidine adsorption. Kinetics and isotherms of adsorption onto Lagenaria vulgaris carbon (LVC) were correlated to several theoretical adsorption models. The best fit was found in the case of Langmuir and pseudo-second-order model indicating monolayer adsorption. The influence of pH under kinetic study showed slightly hindered adsorption below pH 4. The optimal adsorbent dosage was set to 1 g/L. LVC was characterized by several complementary techniques, including wet chemical techniques such as Boehms titrations and determination of pH(pzc) and pH of LVC, which revealed neutral nature of the adsorbent. N-2 sorptometry determined specific surface area of 665 m(2)/g and significant ratio of micropores in the sample with maximum walls diameter of 2.2 nm. Fourier transform infrared spectroscopy (FTIR) confirmed the role of lignin and cellulose in the formation of the final LVC structure. Porous structure of the material was proved by using scanning electron microscopy. Preparation of LVC material drew attention as an easy and low-cost process for production of a highly efficient adsorbent which exhibited fast kinetics of ranitidine removal in the first minutes of contacting and large adsorption capacity (315.5 mg/g) at equilibrium. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.",
journal = "Arabian Journal of Chemistry",
title = "Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions",
volume = "10",
number = "7",
pages = "956-964",
doi = "10.1016/j.arabjc.2014.12.018"
}
Bojić, D. V., Momčilović, M. Z., Milenković, D. D., Mitrović, J. Z., Bankovic, P., Velinov, N. D.,& Nikolić, G.. (2017). Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions. in Arabian Journal of Chemistry, 10(7), 956-964.
https://doi.org/10.1016/j.arabjc.2014.12.018
Bojić DV, Momčilović MZ, Milenković DD, Mitrović JZ, Bankovic P, Velinov ND, Nikolić G. Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions. in Arabian Journal of Chemistry. 2017;10(7):956-964.
doi:10.1016/j.arabjc.2014.12.018 .
Bojić, Danijela V., Momčilović, Milan Z., Milenković, Dragan D., Mitrović, Jelena Z., Bankovic, Predrag, Velinov, Nena D., Nikolić, Goran, "Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions" in Arabian Journal of Chemistry, 10, no. 7 (2017):956-964,
https://doi.org/10.1016/j.arabjc.2014.12.018 . .
29
13
30

Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system

Momčilović, Milan; Đorđević, Jelena S.; Zarubica, Aleksandra; Ranđelović, Marjan

(2017)

TY  - CONF
AU  - Momčilović, Milan
AU  - Đorđević, Jelena S.
AU  - Zarubica, Aleksandra
AU  - Ranđelović, Marjan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10766
AB  - Serpentinite rock collected near Kopaonik Mountain in Serbia is considered as a multiphase assemblage mostly consisting of mineral lizardite. Forsterite has been obtained by chemical-thermal treatment of grounded sample of serpentinite. Electrochemical features of these two materials were investigated by using modified carbon paste electrode (CPE) which included mixing analytes, graphite powder and parafin oil as a binder and packing the mixture in a Teflon holder. Morphological and structural characteristics of the samples were analyzed by SEM and XRD techniques which revealed presence of certain crystal phases and agregates of irregular shapes sized from 10 to 40 μm. Cyclic voltammetry was employed to study their electrochemical characteristics. The peak current height and peak-to-peak separation showed that the electrochemical reaction is quasi-reversible. Kinetic parameters were derived from Tafel analysis. Calculated kinetic parameters indicated prominent electrocatalytic effect of the minerals for ferri/ferro cyanide redox reaction in aquaeous solution
C3  - 4th Conference of the Serbian Society for Ceramic Materials
T1  - Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system
SP  - 94
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10766
ER  - 
@conference{
author = "Momčilović, Milan and Đorđević, Jelena S. and Zarubica, Aleksandra and Ranđelović, Marjan",
year = "2017",
abstract = "Serpentinite rock collected near Kopaonik Mountain in Serbia is considered as a multiphase assemblage mostly consisting of mineral lizardite. Forsterite has been obtained by chemical-thermal treatment of grounded sample of serpentinite. Electrochemical features of these two materials were investigated by using modified carbon paste electrode (CPE) which included mixing analytes, graphite powder and parafin oil as a binder and packing the mixture in a Teflon holder. Morphological and structural characteristics of the samples were analyzed by SEM and XRD techniques which revealed presence of certain crystal phases and agregates of irregular shapes sized from 10 to 40 μm. Cyclic voltammetry was employed to study their electrochemical characteristics. The peak current height and peak-to-peak separation showed that the electrochemical reaction is quasi-reversible. Kinetic parameters were derived from Tafel analysis. Calculated kinetic parameters indicated prominent electrocatalytic effect of the minerals for ferri/ferro cyanide redox reaction in aquaeous solution",
journal = "4th Conference of the Serbian Society for Ceramic Materials",
title = "Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system",
pages = "94",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10766"
}
Momčilović, M., Đorđević, J. S., Zarubica, A.,& Ranđelović, M.. (2017). Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system. in 4th Conference of the Serbian Society for Ceramic Materials, 94.
https://hdl.handle.net/21.15107/rcub_vinar_10766
Momčilović M, Đorđević JS, Zarubica A, Ranđelović M. Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system. in 4th Conference of the Serbian Society for Ceramic Materials. 2017;:94.
https://hdl.handle.net/21.15107/rcub_vinar_10766 .
Momčilović, Milan, Đorđević, Jelena S., Zarubica, Aleksandra, Ranđelović, Marjan, "Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system" in 4th Conference of the Serbian Society for Ceramic Materials (2017):94,
https://hdl.handle.net/21.15107/rcub_vinar_10766 .

Pulsed TEA CO2 laser irradiation of titanium-controllable gas ambience

Ciganović, Jovan; Matavulj, P.; Trtica, Milan; Stasić, J.; Savović, Jelena; Živković, Sanja; Momčilović, Milan Z.

(Society of Physical Chemists of Serbia, 2016)

TY  - CONF
AU  - Ciganović, Jovan
AU  - Matavulj, P.
AU  - Trtica, Milan
AU  - Stasić, J.
AU  - Savović, Jelena
AU  - Živković, Sanja
AU  - Momčilović, Milan Z.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9221
AB  - Interaction of a TEA CO2laser, operating at 10.6 μm wavelength and pulse length  of  100  ns,  with titanium  target  (implant),  in  nitrogen  and  carbon-dioxide  gas  ambience  was  studied.  The  Ti-surface  modifications  were studied  at  moderate  fluence  (~17J/cm2)  and  intensity  (~60MW/cm2) regime.The energy absorbed from the laser beam was partially convertedto thermal  energy,  which  generated  a  series  of  effects,  such  as  melting, vaporization  of  the  molten  material,  shock  waves,  etc.  The  following  Ti-surface  changes  and  phenomena  were  observed:  (i)  superficial  damages  in both   atmospheres;   (ii)   creation   of   cone-and   hill-like   structures   in atmosphere of N2and CO2, respectively; (iii) possible formation of TiN, Ti-oxide(s)  and,  Ti-carbide  layers,  in  N2and  CO2gas,  respectively  and,  (iv) occurrence  of plasma  inboth  gas  ambiences.  It  can  be  concluded  that  the applied laser fluence was high  enough to produce effective modification  of the Ti-implant target in nitrogen as well as in carbon-dioxide gas. Creation of plasma may provide sterilization effect.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry
T1  - Pulsed TEA CO2 laser irradiation of titanium-controllable gas ambience
SP  - H-15-P
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9221
ER  - 
@conference{
author = "Ciganović, Jovan and Matavulj, P. and Trtica, Milan and Stasić, J. and Savović, Jelena and Živković, Sanja and Momčilović, Milan Z.",
year = "2016",
abstract = "Interaction of a TEA CO2laser, operating at 10.6 μm wavelength and pulse length  of  100  ns,  with titanium  target  (implant),  in  nitrogen  and  carbon-dioxide  gas  ambience  was  studied.  The  Ti-surface  modifications  were studied  at  moderate  fluence  (~17J/cm2)  and  intensity  (~60MW/cm2) regime.The energy absorbed from the laser beam was partially convertedto thermal  energy,  which  generated  a  series  of  effects,  such  as  melting, vaporization  of  the  molten  material,  shock  waves,  etc.  The  following  Ti-surface  changes  and  phenomena  were  observed:  (i)  superficial  damages  in both   atmospheres;   (ii)   creation   of   cone-and   hill-like   structures   in atmosphere of N2and CO2, respectively; (iii) possible formation of TiN, Ti-oxide(s)  and,  Ti-carbide  layers,  in  N2and  CO2gas,  respectively  and,  (iv) occurrence  of plasma  inboth  gas  ambiences.  It  can  be  concluded  that  the applied laser fluence was high  enough to produce effective modification  of the Ti-implant target in nitrogen as well as in carbon-dioxide gas. Creation of plasma may provide sterilization effect.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry",
title = "Pulsed TEA CO2 laser irradiation of titanium-controllable gas ambience",
pages = "H-15-P",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9221"
}
Ciganović, J., Matavulj, P., Trtica, M., Stasić, J., Savović, J., Živković, S.,& Momčilović, M. Z.. (2016). Pulsed TEA CO2 laser irradiation of titanium-controllable gas ambience. in Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia., H-15-P.
https://hdl.handle.net/21.15107/rcub_vinar_9221
Ciganović J, Matavulj P, Trtica M, Stasić J, Savović J, Živković S, Momčilović MZ. Pulsed TEA CO2 laser irradiation of titanium-controllable gas ambience. in Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry. 2016;:H-15-P.
https://hdl.handle.net/21.15107/rcub_vinar_9221 .
Ciganović, Jovan, Matavulj, P., Trtica, Milan, Stasić, J., Savović, Jelena, Živković, Sanja, Momčilović, Milan Z., "Pulsed TEA CO2 laser irradiation of titanium-controllable gas ambience" in Physical chemistry 2016 : 13th international conference on fundamental and applied aspects of physical chemistry (2016):H-15-P,
https://hdl.handle.net/21.15107/rcub_vinar_9221 .

Morpho-structural, adsorption and electrochemical characteristics of serpentinite

Momčilović, Milan Z.; Ranđelović, Marjan S.; Purenović, Milovan M.; Đorđević, Jelena S.; Onjia, Antonije E.; Matović, Branko

(Elsevier, 2016)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Ranđelović, Marjan S.
AU  - Purenović, Milovan M.
AU  - Đorđević, Jelena S.
AU  - Onjia, Antonije E.
AU  - Matović, Branko
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1015
AB  - Pollution control and water purification are the main concerns associated with hazardous component eliminations from wastewaters which have inspired the research, among the others, on various clay minerals as useful adsorbents. The aim of this study was to examine morphological, structural, adsorption, and electrochemical characteristics of serpentinite in order to check its potential for removal of cadmium and textile dyes from synthetic waters. SEM technique has provided a detailed insight into the surface morphology of serpentinite indicating irregularly shaped particles and lamellar aggregates which are characteristic of lizardite mineral. Crystal phases detected in composition of serpentinite by using XRD technique are lizardite and tiny amount of periclase. Serpentinite adsorption characteristics were investigated towards Cd2+ and anionic textile dyes (Procion red MX-5B, Procion orange and Ramazol black) in aqueous solutions. The main goal of the study was the reliable removal of hazardous Cd2+ at low initial concentrations (up to 200 mu g/dm(3)). Textile dyes were taken as the models of anionic organic pollutants in water. All the adsorption experiments were carried out in batch conditions by varying initial parameters such as concentration of pollutant, contact time, mass of adsorbent and pH. Based on the obtained results, serpentinite has proven to be efficient adsorbent with removal efficiency over 98% for the selected pollutants. Native serpentinite was further modified in order to obtain forsterite. Electrochemical characteristics of serpentinite and forsterite were examined by using cyclic voltammetry of solution of 0.1 M H2SO4 as acidic supporting electrolyte and K-4[Fe(CN)(6)] which was chosen as a redox model compound. Due to its specific structure, surface groups, morphology, and non-stoichiometric composition, serpentinite and forsterite exhibited prominent electrocatalytic activity. (C) 2016 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Separation and Purification Technology
T1  - Morpho-structural, adsorption and electrochemical characteristics of serpentinite
VL  - 163
SP  - 72
EP  - 78
DO  - 10.1016/j.seppur.2016.02.042
ER  - 
@article{
author = "Momčilović, Milan Z. and Ranđelović, Marjan S. and Purenović, Milovan M. and Đorđević, Jelena S. and Onjia, Antonije E. and Matović, Branko",
year = "2016",
abstract = "Pollution control and water purification are the main concerns associated with hazardous component eliminations from wastewaters which have inspired the research, among the others, on various clay minerals as useful adsorbents. The aim of this study was to examine morphological, structural, adsorption, and electrochemical characteristics of serpentinite in order to check its potential for removal of cadmium and textile dyes from synthetic waters. SEM technique has provided a detailed insight into the surface morphology of serpentinite indicating irregularly shaped particles and lamellar aggregates which are characteristic of lizardite mineral. Crystal phases detected in composition of serpentinite by using XRD technique are lizardite and tiny amount of periclase. Serpentinite adsorption characteristics were investigated towards Cd2+ and anionic textile dyes (Procion red MX-5B, Procion orange and Ramazol black) in aqueous solutions. The main goal of the study was the reliable removal of hazardous Cd2+ at low initial concentrations (up to 200 mu g/dm(3)). Textile dyes were taken as the models of anionic organic pollutants in water. All the adsorption experiments were carried out in batch conditions by varying initial parameters such as concentration of pollutant, contact time, mass of adsorbent and pH. Based on the obtained results, serpentinite has proven to be efficient adsorbent with removal efficiency over 98% for the selected pollutants. Native serpentinite was further modified in order to obtain forsterite. Electrochemical characteristics of serpentinite and forsterite were examined by using cyclic voltammetry of solution of 0.1 M H2SO4 as acidic supporting electrolyte and K-4[Fe(CN)(6)] which was chosen as a redox model compound. Due to its specific structure, surface groups, morphology, and non-stoichiometric composition, serpentinite and forsterite exhibited prominent electrocatalytic activity. (C) 2016 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Separation and Purification Technology",
title = "Morpho-structural, adsorption and electrochemical characteristics of serpentinite",
volume = "163",
pages = "72-78",
doi = "10.1016/j.seppur.2016.02.042"
}
Momčilović, M. Z., Ranđelović, M. S., Purenović, M. M., Đorđević, J. S., Onjia, A. E.,& Matović, B.. (2016). Morpho-structural, adsorption and electrochemical characteristics of serpentinite. in Separation and Purification Technology
Elsevier., 163, 72-78.
https://doi.org/10.1016/j.seppur.2016.02.042
Momčilović MZ, Ranđelović MS, Purenović MM, Đorđević JS, Onjia AE, Matović B. Morpho-structural, adsorption and electrochemical characteristics of serpentinite. in Separation and Purification Technology. 2016;163:72-78.
doi:10.1016/j.seppur.2016.02.042 .
Momčilović, Milan Z., Ranđelović, Marjan S., Purenović, Milovan M., Đorđević, Jelena S., Onjia, Antonije E., Matović, Branko, "Morpho-structural, adsorption and electrochemical characteristics of serpentinite" in Separation and Purification Technology, 163 (2016):72-78,
https://doi.org/10.1016/j.seppur.2016.02.042 . .
16
12
20

The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat

Ranđelović, Marjan S.; Momčilović, Milan Z.; Purenović, Milovan M.; Zarubica, Aleksandra R.; Bojić, Aleksandar Lj.

(Springer, 2016)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Purenović, Milovan M.
AU  - Zarubica, Aleksandra R.
AU  - Bojić, Aleksandar Lj.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1076
AB  - Samples of natural peat (NP) were hydrothermally treated at different temperatures in oxidative and acidic aqueous medium to tailor their acid-base, adsorption, morphological and other properties. The obtained materials were thoroughly characterized by SEM, XRD and FTIR techniques, followed by determination of pH(pzc), examination of adsorption characteristics and the extent of organic matter leaching in water. Acid-base characteristics of these materials were examined by potentiometric and conductometric titration of corresponding aqueous suspensions. Experimental potentiometric data were interpreted using ProtoFit software (NEM, non-electrostatic model) which provided pKa values and concentrations of surface sites which are compared with corresponding values obtained by conductometric titration method. There are two main types of surface groups (carboxylic and phenolic) that are dominant in the materials and determine their acid-base behavior in the aqueous medium. Temperature during oxidative hydrothermal treatment has no significant effect on the total number of surface groups, but influences the ratio of carboxylic and phenol-type groups. Hence, acid-base properties of peat can be tailored, which is useful in designing and improving adsorptive characteristics of peat for the preferential removal of certain pollutants from water.
PB  - Springer
T2  - Environmental Earth Sciences
T1  - The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat
VL  - 75
IS  - 9
DO  - 10.1007/s12665-016-5242-0
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Purenović, Milovan M. and Zarubica, Aleksandra R. and Bojić, Aleksandar Lj.",
year = "2016",
abstract = "Samples of natural peat (NP) were hydrothermally treated at different temperatures in oxidative and acidic aqueous medium to tailor their acid-base, adsorption, morphological and other properties. The obtained materials were thoroughly characterized by SEM, XRD and FTIR techniques, followed by determination of pH(pzc), examination of adsorption characteristics and the extent of organic matter leaching in water. Acid-base characteristics of these materials were examined by potentiometric and conductometric titration of corresponding aqueous suspensions. Experimental potentiometric data were interpreted using ProtoFit software (NEM, non-electrostatic model) which provided pKa values and concentrations of surface sites which are compared with corresponding values obtained by conductometric titration method. There are two main types of surface groups (carboxylic and phenolic) that are dominant in the materials and determine their acid-base behavior in the aqueous medium. Temperature during oxidative hydrothermal treatment has no significant effect on the total number of surface groups, but influences the ratio of carboxylic and phenol-type groups. Hence, acid-base properties of peat can be tailored, which is useful in designing and improving adsorptive characteristics of peat for the preferential removal of certain pollutants from water.",
publisher = "Springer",
journal = "Environmental Earth Sciences",
title = "The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat",
volume = "75",
number = "9",
doi = "10.1007/s12665-016-5242-0"
}
Ranđelović, M. S., Momčilović, M. Z., Purenović, M. M., Zarubica, A. R.,& Bojić, A. Lj.. (2016). The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat. in Environmental Earth Sciences
Springer., 75(9).
https://doi.org/10.1007/s12665-016-5242-0
Ranđelović MS, Momčilović MZ, Purenović MM, Zarubica AR, Bojić AL. The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat. in Environmental Earth Sciences. 2016;75(9).
doi:10.1007/s12665-016-5242-0 .
Ranđelović, Marjan S., Momčilović, Milan Z., Purenović, Milovan M., Zarubica, Aleksandra R., Bojić, Aleksandar Lj., "The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat" in Environmental Earth Sciences, 75, no. 9 (2016),
https://doi.org/10.1007/s12665-016-5242-0 . .
4
4
3

Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters

Vasić, Marija B.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Matović, Branko; Zarubica, Aleksandra R.

(2016)

TY  - JOUR
AU  - Vasić, Marija B.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Matović, Branko
AU  - Zarubica, Aleksandra R.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1329
AB  - In this study, modified sol-gel method was employed to synthesize the pure and Zr-doped titania catalysts. Brunauer-Emmett-Teller (BET) method was applied to determine porosity, X-ray diffraction (XRD) analysis was used to study crystal structure, scanning electron microscopy (SEM) was used to investigate morphology and Fourier transform infrared spectroscopy (FTIR) was used to examine surface properties/total acidity of the obtained catalysts samples. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolourization/degradation under UV light irradiation. The effects of several photocatalysis operational parameters were considered, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment, as well as catalysts calcination temperatures and dopant amounts. The obtained results indicated faster dye decolourization/degradation with the increase of the catalyst dosage and the decrease of initial CV concentrations. The Zr-doping affects photocatalytic properties, i.e. CV decolourization/degradation of the prepared catalytic materials. Thus, addition of 5 wt.% of ZrO2 to titania increases photocatalytic effect for similar to 15% and addition of 10 wt.% of ZrO2 improves the photocatalytic efficiency of titania for nearly 30%.
T2  - Processing and Application of Ceramics
T1  - Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters
VL  - 10
IS  - 3
SP  - 189
EP  - 198
DO  - 10.2298/PAC1603189V
ER  - 
@article{
author = "Vasić, Marija B. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Matović, Branko and Zarubica, Aleksandra R.",
year = "2016",
abstract = "In this study, modified sol-gel method was employed to synthesize the pure and Zr-doped titania catalysts. Brunauer-Emmett-Teller (BET) method was applied to determine porosity, X-ray diffraction (XRD) analysis was used to study crystal structure, scanning electron microscopy (SEM) was used to investigate morphology and Fourier transform infrared spectroscopy (FTIR) was used to examine surface properties/total acidity of the obtained catalysts samples. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolourization/degradation under UV light irradiation. The effects of several photocatalysis operational parameters were considered, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment, as well as catalysts calcination temperatures and dopant amounts. The obtained results indicated faster dye decolourization/degradation with the increase of the catalyst dosage and the decrease of initial CV concentrations. The Zr-doping affects photocatalytic properties, i.e. CV decolourization/degradation of the prepared catalytic materials. Thus, addition of 5 wt.% of ZrO2 to titania increases photocatalytic effect for similar to 15% and addition of 10 wt.% of ZrO2 improves the photocatalytic efficiency of titania for nearly 30%.",
journal = "Processing and Application of Ceramics",
title = "Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters",
volume = "10",
number = "3",
pages = "189-198",
doi = "10.2298/PAC1603189V"
}
Vasić, M. B., Ranđelović, M. S., Momčilović, M. Z., Matović, B.,& Zarubica, A. R.. (2016). Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters. in Processing and Application of Ceramics, 10(3), 189-198.
https://doi.org/10.2298/PAC1603189V
Vasić MB, Ranđelović MS, Momčilović MZ, Matović B, Zarubica AR. Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters. in Processing and Application of Ceramics. 2016;10(3):189-198.
doi:10.2298/PAC1603189V .
Vasić, Marija B., Ranđelović, Marjan S., Momčilović, Milan Z., Matović, Branko, Zarubica, Aleksandra R., "Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters" in Processing and Application of Ceramics, 10, no. 3 (2016):189-198,
https://doi.org/10.2298/PAC1603189V . .
11
4
11

Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media

Stojmenović, Marija; Momčilović, Milan Z.; Gavrilov, Nemanja M.; Pašti, Igor A.; Mentus, Slavko V.; Jokić, Bojan M.; Babić, Biljana M.

(2015)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Momčilović, Milan Z.
AU  - Gavrilov, Nemanja M.
AU  - Pašti, Igor A.
AU  - Mentus, Slavko V.
AU  - Jokić, Bojan M.
AU  - Babić, Biljana M.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/371
AB  - Ordered mesoporous carbon, volume-doped up to 3w.% with Pt, Ru and Pt-Ru nanoparticles was synthesized by evaporation-induced self-assembly method, under acidic conditions. The content of incorporated metal was determined by EDX analysis. The X-ray diffractometry confirmed the existence of highly dispersed metallic phases in doped samples. Specific surface area was determined by N-2-physisorption measurements to range between 452 and 545m(2) g(-1). Raman spectroscopy of investigated materials indicated highly disordered carbon structure with crystallite sizes around 1.4 nm. In a form of thin-layer electrode on glassy carbon support, in 0.1M KOH solution, the prepared materials displayed high activity toward oxygen reduction reaction (ORR) in alkaline media, with onset potentials more positive than -0.10 V vs. SCE. The kinetics of O-2 reduction was found to be affected by both the specific surface area and the concentration of metal dopants. The ethanol tolerance of (Pt, Ru)-doped OMCs was found to be higher than that of common Pt/C ORR catalysts. Presented study provides a new route for the synthesis of active and selective ORR catalysts in alkaline media, being competitive with, or superior to, the existing ones in terms of performance and price. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media
VL  - 153
SP  - 130
EP  - 139
DO  - 10.1016/j.electacta.2014.11.080
ER  - 
@article{
author = "Stojmenović, Marija and Momčilović, Milan Z. and Gavrilov, Nemanja M. and Pašti, Igor A. and Mentus, Slavko V. and Jokić, Bojan M. and Babić, Biljana M.",
year = "2015",
abstract = "Ordered mesoporous carbon, volume-doped up to 3w.% with Pt, Ru and Pt-Ru nanoparticles was synthesized by evaporation-induced self-assembly method, under acidic conditions. The content of incorporated metal was determined by EDX analysis. The X-ray diffractometry confirmed the existence of highly dispersed metallic phases in doped samples. Specific surface area was determined by N-2-physisorption measurements to range between 452 and 545m(2) g(-1). Raman spectroscopy of investigated materials indicated highly disordered carbon structure with crystallite sizes around 1.4 nm. In a form of thin-layer electrode on glassy carbon support, in 0.1M KOH solution, the prepared materials displayed high activity toward oxygen reduction reaction (ORR) in alkaline media, with onset potentials more positive than -0.10 V vs. SCE. The kinetics of O-2 reduction was found to be affected by both the specific surface area and the concentration of metal dopants. The ethanol tolerance of (Pt, Ru)-doped OMCs was found to be higher than that of common Pt/C ORR catalysts. Presented study provides a new route for the synthesis of active and selective ORR catalysts in alkaline media, being competitive with, or superior to, the existing ones in terms of performance and price. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media",
volume = "153",
pages = "130-139",
doi = "10.1016/j.electacta.2014.11.080"
}
Stojmenović, M., Momčilović, M. Z., Gavrilov, N. M., Pašti, I. A., Mentus, S. V., Jokić, B. M.,& Babić, B. M.. (2015). Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media. in Electrochimica Acta, 153, 130-139.
https://doi.org/10.1016/j.electacta.2014.11.080
Stojmenović M, Momčilović MZ, Gavrilov NM, Pašti IA, Mentus SV, Jokić BM, Babić BM. Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media. in Electrochimica Acta. 2015;153:130-139.
doi:10.1016/j.electacta.2014.11.080 .
Stojmenović, Marija, Momčilović, Milan Z., Gavrilov, Nemanja M., Pašti, Igor A., Mentus, Slavko V., Jokić, Bojan M., Babić, Biljana M., "Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media" in Electrochimica Acta, 153 (2015):130-139,
https://doi.org/10.1016/j.electacta.2014.11.080 . .
23
22
23

The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons

Pašti, Igor A.; Gavrilov, Nemanja M.; Dobrota, Ana S.; Momčilović, Milan Z.; Stojmenović, Marija; Topalov, Angel; Stanković, Dalibor M.; Babić, Biljana M.; Ćirić-Marjanović, Gordana N.; Mentus, Slavko V.

(2015)

TY  - JOUR
AU  - Pašti, Igor A.
AU  - Gavrilov, Nemanja M.
AU  - Dobrota, Ana S.
AU  - Momčilović, Milan Z.
AU  - Stojmenović, Marija
AU  - Topalov, Angel
AU  - Stanković, Dalibor M.
AU  - Babić, Biljana M.
AU  - Ćirić-Marjanović, Gordana N.
AU  - Mentus, Slavko V.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/769
AB  - In order to elucidate the role of B, N, and P dopants in carbon materials on the kinetics of oxygen reduction reaction (ORR) and to provide a fair comparison of the effects of each dopant, a series of ordered mesoporous carbons (OMCs) with low concentration of heteroatoms ( LT 1 at%) has been prepared. Doped OMCs were characterized using X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectroscopy (ICP-OES), Raman spectroscopy, X-ray powder diffraction (XRD), and N-2 physisorption measurements. Comparative study of the ORR activity of these materials in alkaline solution was performed using rotating disk electrode voltammetry. The experiments evidenced that, compared to non-doped OMC, charge transfer kinetics was improved independently on the nature of the heteroatom. The decrease of the ORR overvoltage and the increase of the mass activity upon doping are similar for B and P and less prominent for N. On the other hand, OMCs doped with low levels of B and N were found to be selective for O-2 reduction to peroxide, while for P-doped OMCs, the apparent number of electrons consumed per O-2 molecule was up to 3.1. Experimental measurements were complemented by density functional theory (DFT) calculations.
T2  - Electrocatalysis
T1  - The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons
VL  - 6
IS  - 6
SP  - 498
EP  - 511
DO  - 10.1007/s12678-015-0271-0
ER  - 
@article{
author = "Pašti, Igor A. and Gavrilov, Nemanja M. and Dobrota, Ana S. and Momčilović, Milan Z. and Stojmenović, Marija and Topalov, Angel and Stanković, Dalibor M. and Babić, Biljana M. and Ćirić-Marjanović, Gordana N. and Mentus, Slavko V.",
year = "2015",
abstract = "In order to elucidate the role of B, N, and P dopants in carbon materials on the kinetics of oxygen reduction reaction (ORR) and to provide a fair comparison of the effects of each dopant, a series of ordered mesoporous carbons (OMCs) with low concentration of heteroatoms ( LT 1 at%) has been prepared. Doped OMCs were characterized using X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectroscopy (ICP-OES), Raman spectroscopy, X-ray powder diffraction (XRD), and N-2 physisorption measurements. Comparative study of the ORR activity of these materials in alkaline solution was performed using rotating disk electrode voltammetry. The experiments evidenced that, compared to non-doped OMC, charge transfer kinetics was improved independently on the nature of the heteroatom. The decrease of the ORR overvoltage and the increase of the mass activity upon doping are similar for B and P and less prominent for N. On the other hand, OMCs doped with low levels of B and N were found to be selective for O-2 reduction to peroxide, while for P-doped OMCs, the apparent number of electrons consumed per O-2 molecule was up to 3.1. Experimental measurements were complemented by density functional theory (DFT) calculations.",
journal = "Electrocatalysis",
title = "The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons",
volume = "6",
number = "6",
pages = "498-511",
doi = "10.1007/s12678-015-0271-0"
}
Pašti, I. A., Gavrilov, N. M., Dobrota, A. S., Momčilović, M. Z., Stojmenović, M., Topalov, A., Stanković, D. M., Babić, B. M., Ćirić-Marjanović, G. N.,& Mentus, S. V.. (2015). The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons. in Electrocatalysis, 6(6), 498-511.
https://doi.org/10.1007/s12678-015-0271-0
Pašti IA, Gavrilov NM, Dobrota AS, Momčilović MZ, Stojmenović M, Topalov A, Stanković DM, Babić BM, Ćirić-Marjanović GN, Mentus SV. The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons. in Electrocatalysis. 2015;6(6):498-511.
doi:10.1007/s12678-015-0271-0 .
Pašti, Igor A., Gavrilov, Nemanja M., Dobrota, Ana S., Momčilović, Milan Z., Stojmenović, Marija, Topalov, Angel, Stanković, Dalibor M., Babić, Biljana M., Ćirić-Marjanović, Gordana N., Mentus, Slavko V., "The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons" in Electrocatalysis, 6, no. 6 (2015):498-511,
https://doi.org/10.1007/s12678-015-0271-0 . .
36
31
37

Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres

Ranđelović, Marjan S.; Momčilović, Milan Z.; Matović, Branko; Babić, Biljana M.; Barek, Jiri

(Elsevier, 2015)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Matović, Branko
AU  - Babić, Biljana M.
AU  - Barek, Jiri
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/850
AB  - This paper deals with comparison of modified carbon electrodes prepared from Pt- and Ag-doped carbon microspheres using cyclic voltammetry of [Fe(CN)(6)](3-)/[Fe(CN)(6)](4-) redox pair as a probe under various experimental conditions. Spherical particles ranging from 0.5 to 8 mu m in average as evidenced by SEM showed slight influence of dopant nature onto their microstructure. FTIR analysis revealed that the involvement of metal species in the carbon structure was followed by their subsequent reduction and rising of oxidized carbon functionalities in the spectra. Electrochemical study showed that all the examined electrodes performed reversible processes with chemically stable generated products and no side chemical reactions. Among them, Pt-doped electrode showed superior electrocatalytic behavior in terms of heterogeneous transfer rate constant and other kinetic parameters. Since minimal addition of Pt in the hydrothermal synthesis resulted in powerful electrocatalytic effect as precious advantage, benevolent impact of carbon microspheres as catalyst support was put into focus of this research. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres
VL  - 757
SP  - 176
EP  - 182
DO  - 10.1016/j.jelechem.2015.09.035
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Matović, Branko and Babić, Biljana M. and Barek, Jiri",
year = "2015",
abstract = "This paper deals with comparison of modified carbon electrodes prepared from Pt- and Ag-doped carbon microspheres using cyclic voltammetry of [Fe(CN)(6)](3-)/[Fe(CN)(6)](4-) redox pair as a probe under various experimental conditions. Spherical particles ranging from 0.5 to 8 mu m in average as evidenced by SEM showed slight influence of dopant nature onto their microstructure. FTIR analysis revealed that the involvement of metal species in the carbon structure was followed by their subsequent reduction and rising of oxidized carbon functionalities in the spectra. Electrochemical study showed that all the examined electrodes performed reversible processes with chemically stable generated products and no side chemical reactions. Among them, Pt-doped electrode showed superior electrocatalytic behavior in terms of heterogeneous transfer rate constant and other kinetic parameters. Since minimal addition of Pt in the hydrothermal synthesis resulted in powerful electrocatalytic effect as precious advantage, benevolent impact of carbon microspheres as catalyst support was put into focus of this research. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres",
volume = "757",
pages = "176-182",
doi = "10.1016/j.jelechem.2015.09.035"
}
Ranđelović, M. S., Momčilović, M. Z., Matović, B., Babić, B. M.,& Barek, J.. (2015). Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres. in Journal of Electroanalytical Chemistry
Elsevier., 757, 176-182.
https://doi.org/10.1016/j.jelechem.2015.09.035
Ranđelović MS, Momčilović MZ, Matović B, Babić BM, Barek J. Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres. in Journal of Electroanalytical Chemistry. 2015;757:176-182.
doi:10.1016/j.jelechem.2015.09.035 .
Ranđelović, Marjan S., Momčilović, Milan Z., Matović, Branko, Babić, Biljana M., Barek, Jiri, "Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres" in Journal of Electroanalytical Chemistry, 757 (2015):176-182,
https://doi.org/10.1016/j.jelechem.2015.09.035 . .
5
5
6

Efficient separation of Tc-99 from aqueous solution using pinecone activated carbon

Sandić, Zvijezdana; Momčilović, Milan Z.; Mirković, Marija D.; Radović, Magdalena; Stanković, Dragana; Suručić, Ljiljana T.; Maksin, Danijela D.

(Society of Physical Chemists of Serbia, 2014)

TY  - CONF
AU  - Sandić, Zvijezdana
AU  - Momčilović, Milan Z.
AU  - Mirković, Marija D.
AU  - Radović, Magdalena
AU  - Stanković, Dragana
AU  - Suručić, Ljiljana T.
AU  - Maksin, Danijela D.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9229
AB  - Sorption of radioactive 99Tc-pertechnetate onto activated carbon prepared
from pinecones was investigated. The parameters of contact time and Tc-99
concentration were varied. It was established that the sorption half-life, t1/2,
was very short ~ 2.2 min, thus making this sorbent an excellent candidate
for immediate pollution remediation, which is very important in the case of
nuclear accidents. The kinetic data were found to follow closely the pseudosecond-
order (PSO) kinetic model. Boyd model established the sorption
dependence only on film diffusion. The partitioning/distribution coefficient,
Kd, attained was 2729 cm3 g-1. The equilibration time was 3 h at room
temperature (T=298 K).
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Efficient separation of Tc-99 from aqueous solution using pinecone activated carbon
VL  - G-04-P
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9229
ER  - 
@conference{
author = "Sandić, Zvijezdana and Momčilović, Milan Z. and Mirković, Marija D. and Radović, Magdalena and Stanković, Dragana and Suručić, Ljiljana T. and Maksin, Danijela D.",
year = "2014",
abstract = "Sorption of radioactive 99Tc-pertechnetate onto activated carbon prepared
from pinecones was investigated. The parameters of contact time and Tc-99
concentration were varied. It was established that the sorption half-life, t1/2,
was very short ~ 2.2 min, thus making this sorbent an excellent candidate
for immediate pollution remediation, which is very important in the case of
nuclear accidents. The kinetic data were found to follow closely the pseudosecond-
order (PSO) kinetic model. Boyd model established the sorption
dependence only on film diffusion. The partitioning/distribution coefficient,
Kd, attained was 2729 cm3 g-1. The equilibration time was 3 h at room
temperature (T=298 K).",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Efficient separation of Tc-99 from aqueous solution using pinecone activated carbon",
volume = "G-04-P",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9229"
}
Sandić, Z., Momčilović, M. Z., Mirković, M. D., Radović, M., Stanković, D., Suručić, L. T.,& Maksin, D. D.. (2014). Efficient separation of Tc-99 from aqueous solution using pinecone activated carbon. in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Society of Physical Chemists of Serbia., G-04-P.
https://hdl.handle.net/21.15107/rcub_vinar_9229
Sandić Z, Momčilović MZ, Mirković MD, Radović M, Stanković D, Suručić LT, Maksin DD. Efficient separation of Tc-99 from aqueous solution using pinecone activated carbon. in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry. 2014;G-04-P.
https://hdl.handle.net/21.15107/rcub_vinar_9229 .
Sandić, Zvijezdana, Momčilović, Milan Z., Mirković, Marija D., Radović, Magdalena, Stanković, Dragana, Suručić, Ljiljana T., Maksin, Danijela D., "Efficient separation of Tc-99 from aqueous solution using pinecone activated carbon" in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry, G-04-P (2014),
https://hdl.handle.net/21.15107/rcub_vinar_9229 .

Mechanism of sorption of pertechnetate onto ordered mesoporous carbon

Petrović, Đorđe; Đukić, Anđelka B.; Kumrić, Ksenija; Babić, Biljana M.; Momčilović, Milan Z.; Ivanović, Nenad; Matović, Ljiljana

(2014)

TY  - JOUR
AU  - Petrović, Đorđe
AU  - Đukić, Anđelka B.
AU  - Kumrić, Ksenija
AU  - Babić, Biljana M.
AU  - Momčilović, Milan Z.
AU  - Ivanović, Nenad
AU  - Matović, Ljiljana
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/126
AB  - Ordered mesoporous carbon (OMC) was used as an adsorbent for the removal of pertechnetate (TcO4 (-)) anion. The maximum uptake (93 %) of TcO4 (-) was obtained after 60 min of contact. The adsorption of TcO4 (-) is almost pH-independent in very wide pH region (from 4.0 to 10.0). Maximum K (d) of 6.6 x 10(3) cm(3) g(-1) was found at pH 2.0. TcO4 (-) interacts with carboxylic functional groups present at the surface of the OMC by displacing the OH- ions with TcO4 (-) via ion exchange mechanism.
T2  - Journal of Radioanalytical and Nuclear Chemistry
T1  - Mechanism of sorption of pertechnetate onto ordered mesoporous carbon
VL  - 302
IS  - 1
SP  - 217
EP  - 224
DO  - 10.1007/s10967-014-3249-0
ER  - 
@article{
author = "Petrović, Đorđe and Đukić, Anđelka B. and Kumrić, Ksenija and Babić, Biljana M. and Momčilović, Milan Z. and Ivanović, Nenad and Matović, Ljiljana",
year = "2014",
abstract = "Ordered mesoporous carbon (OMC) was used as an adsorbent for the removal of pertechnetate (TcO4 (-)) anion. The maximum uptake (93 %) of TcO4 (-) was obtained after 60 min of contact. The adsorption of TcO4 (-) is almost pH-independent in very wide pH region (from 4.0 to 10.0). Maximum K (d) of 6.6 x 10(3) cm(3) g(-1) was found at pH 2.0. TcO4 (-) interacts with carboxylic functional groups present at the surface of the OMC by displacing the OH- ions with TcO4 (-) via ion exchange mechanism.",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
title = "Mechanism of sorption of pertechnetate onto ordered mesoporous carbon",
volume = "302",
number = "1",
pages = "217-224",
doi = "10.1007/s10967-014-3249-0"
}
Petrović, Đ., Đukić, A. B., Kumrić, K., Babić, B. M., Momčilović, M. Z., Ivanović, N.,& Matović, L.. (2014). Mechanism of sorption of pertechnetate onto ordered mesoporous carbon. in Journal of Radioanalytical and Nuclear Chemistry, 302(1), 217-224.
https://doi.org/10.1007/s10967-014-3249-0
Petrović Đ, Đukić AB, Kumrić K, Babić BM, Momčilović MZ, Ivanović N, Matović L. Mechanism of sorption of pertechnetate onto ordered mesoporous carbon. in Journal of Radioanalytical and Nuclear Chemistry. 2014;302(1):217-224.
doi:10.1007/s10967-014-3249-0 .
Petrović, Đorđe, Đukić, Anđelka B., Kumrić, Ksenija, Babić, Biljana M., Momčilović, Milan Z., Ivanović, Nenad, Matović, Ljiljana, "Mechanism of sorption of pertechnetate onto ordered mesoporous carbon" in Journal of Radioanalytical and Nuclear Chemistry, 302, no. 1 (2014):217-224,
https://doi.org/10.1007/s10967-014-3249-0 . .
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