TY  - JOUR
AU  - Kusigerski, Vladan
AU  - Spasojević, Vojislav
AU  - Lazarov, Nenad Đ.
AU  - Markovic, DS
AU  - Matić, Vladimir M.
AU  - Sovilj, Sofija P.
AU  - Guillot, M
PY  - 2003
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2627
AB  - Magnetic properties of the dinuclear cobalt complex [Co-2(ox)tpmc](ClO4)(2).3H(2)O have been studied from the magnetization data obtained in the high magnetic field-low temperature experiment (B less than or equal to 20 T, T = 4.2 K). An excellent agreement between experimental and calculated data was achieved within the framework of the isolated Ising Co(H) pairs in the ground state, where each cobalt ion from the pair was situated in a differently distorted octahedral environment (asymmetric dimer). The obtained values for g-factors, g(a) = (4.5 +/- 0.1) and g(b) = (3.3 +/- 0.1), and for the intracluster exchange integral J = (-16.0 +/- 0.5) K confirm both the previous results on the crystal structure of the complex under consideration and the assumption on the strong antiferromagnetic coupling between cobalt ions realized by the superexchange interaction over the asymmetric oxalato bridge. (C) 2003 Published by Elsevier Science Ltd.
T2  - Solid State Communications
T1  - High magnetic fields study of asymmetric Co(II) dimer in octahedral ligand environment
VL  - 126
IS  - 6
SP  - 319
EP  - 322
DO  - 10.1016/S0038-1098(03)00163-7
ER  - 

@article{
author = "Kusigerski, Vladan and Spasojević, Vojislav and Lazarov, Nenad Đ. and Markovic, DS and Matić, Vladimir M. and Sovilj, Sofija P. and Guillot, M",
year = "2003",
abstract = "Magnetic properties of the dinuclear cobalt complex [Co-2(ox)tpmc](ClO4)(2).3H(2)O have been studied from the magnetization data obtained in the high magnetic field-low temperature experiment (B less than or equal to 20 T, T = 4.2 K). An excellent agreement between experimental and calculated data was achieved within the framework of the isolated Ising Co(H) pairs in the ground state, where each cobalt ion from the pair was situated in a differently distorted octahedral environment (asymmetric dimer). The obtained values for g-factors, g(a) = (4.5 +/- 0.1) and g(b) = (3.3 +/- 0.1), and for the intracluster exchange integral J = (-16.0 +/- 0.5) K confirm both the previous results on the crystal structure of the complex under consideration and the assumption on the strong antiferromagnetic coupling between cobalt ions realized by the superexchange interaction over the asymmetric oxalato bridge. (C) 2003 Published by Elsevier Science Ltd.",
journal = "Solid State Communications",
title = "High magnetic fields study of asymmetric Co(II) dimer in octahedral ligand environment",
volume = "126",
number = "6",
pages = "319-322",
doi = "10.1016/S0038-1098(03)00163-7"
}

Kusigerski, V., Spasojević, V., Lazarov, N. Đ., Markovic, D., Matić, V. M., Sovilj, S. P.,& Guillot, M.. (2003). High magnetic fields study of asymmetric Co(II) dimer in octahedral ligand environment. in Solid State Communications, 126(6), 319-322.
https://doi.org/10.1016/S0038-1098(03)00163-7

Kusigerski V, Spasojević V, Lazarov NĐ, Markovic D, Matić VM, Sovilj SP, Guillot M. High magnetic fields study of asymmetric Co(II) dimer in octahedral ligand environment. in Solid State Communications. 2003;126(6):319-322.
doi:10.1016/S0038-1098(03)00163-7 .

Kusigerski, Vladan, Spasojević, Vojislav, Lazarov, Nenad Đ., Markovic, DS, Matić, Vladimir M., Sovilj, Sofija P., Guillot, M, "High magnetic fields study of asymmetric Co(II) dimer in octahedral ligand environment" in Solid State Communications, 126, no. 6 (2003):319-322,
https://doi.org/10.1016/S0038-1098(03)00163-7 . .