TY  - JOUR
AU  - Mullins, Abbi L.
AU  - Ćirić, Aleksandar
AU  - Zeković, Ivana Lj.
AU  - Williams, J. A. Gareth
AU  - Dramićanin, Miroslav
AU  - Radosavjević Evans, Ivana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10362
AB  - A series of La1−xGa0.99O3:Cr0.01, Ndx phosphors (where x = 0.005, 0.01, 0.02) for luminescence thermometry was synthesised by the solid-state method, structurally characterised using powder X-ray diffraction data, and investigated by ambient and variable-temperature optical measurements. The design principle relies on the use of a combination of transition metal and rare earth activator ions such that the excitation and emission wavelengths fall within the near infra-red spectral region, notably in the ‘first biological window’ that is attractive for potential in vivo applications. The photoluminescence spectra of the compounds feature the characteristic 2E phosphorescence of Cr3+ at 729 nm and the 4F3/2 → 4I9/2 emission of Nd3+ around 890 nm. The Nd3+ emission is quenched at a higher rate than that of Cr3+ with increasing temperature. Thermometric analysis by monitoring the luminescence intensity ratio (LIR) between the emissions of Cr3+ and Nd3+ from 300 K to 650 K shows a quasi-Boltzmann trend, with a maximum relative sensitivity of ∼2% K−1, high absolute sensitivity values over this entire temperature range, excellent temperature resolution of 0.04 K at room temperature, and high stability.
T2  - Journal of Materials Chemistry C
T1  - Dual-emission luminescence thermometry using LaGaO3:Cr3+, Nd3+ phosphors
VL  - 10
IS  - 28
SP  - 10396
EP  - 10403
DO  - 10.1039/D2TC02011D
ER  - 

@article{
author = "Mullins, Abbi L. and Ćirić, Aleksandar and Zeković, Ivana Lj. and Williams, J. A. Gareth and Dramićanin, Miroslav and Radosavjević Evans, Ivana",
year = "2022",
abstract = "A series of La1−xGa0.99O3:Cr0.01, Ndx phosphors (where x = 0.005, 0.01, 0.02) for luminescence thermometry was synthesised by the solid-state method, structurally characterised using powder X-ray diffraction data, and investigated by ambient and variable-temperature optical measurements. The design principle relies on the use of a combination of transition metal and rare earth activator ions such that the excitation and emission wavelengths fall within the near infra-red spectral region, notably in the ‘first biological window’ that is attractive for potential in vivo applications. The photoluminescence spectra of the compounds feature the characteristic 2E phosphorescence of Cr3+ at 729 nm and the 4F3/2 → 4I9/2 emission of Nd3+ around 890 nm. The Nd3+ emission is quenched at a higher rate than that of Cr3+ with increasing temperature. Thermometric analysis by monitoring the luminescence intensity ratio (LIR) between the emissions of Cr3+ and Nd3+ from 300 K to 650 K shows a quasi-Boltzmann trend, with a maximum relative sensitivity of ∼2% K−1, high absolute sensitivity values over this entire temperature range, excellent temperature resolution of 0.04 K at room temperature, and high stability.",
journal = "Journal of Materials Chemistry C",
title = "Dual-emission luminescence thermometry using LaGaO3:Cr3+, Nd3+ phosphors",
volume = "10",
number = "28",
pages = "10396-10403",
doi = "10.1039/D2TC02011D"
}

Mullins, A. L., Ćirić, A., Zeković, I. Lj., Williams, J. A. G., Dramićanin, M.,& Radosavjević Evans, I.. (2022). Dual-emission luminescence thermometry using LaGaO3:Cr3+, Nd3+ phosphors. in Journal of Materials Chemistry C, 10(28), 10396-10403.
https://doi.org/10.1039/D2TC02011D

Mullins AL, Ćirić A, Zeković IL, Williams JAG, Dramićanin M, Radosavjević Evans I. Dual-emission luminescence thermometry using LaGaO3:Cr3+, Nd3+ phosphors. in Journal of Materials Chemistry C. 2022;10(28):10396-10403.
doi:10.1039/D2TC02011D .

Mullins, Abbi L., Ćirić, Aleksandar, Zeković, Ivana Lj., Williams, J. A. Gareth, Dramićanin, Miroslav, Radosavjević Evans, Ivana, "Dual-emission luminescence thermometry using LaGaO3:Cr3+, Nd3+ phosphors" in Journal of Materials Chemistry C, 10, no. 28 (2022):10396-10403,
https://doi.org/10.1039/D2TC02011D . .

TY  - JOUR
AU  - Dramićanin, Miroslav
AU  - Marciniak, Lukasz
AU  - Kuzman, Sanja
AU  - Piotrowski, Wojciech
AU  - Ristić, Zoran
AU  - Periša, Jovana
AU  - Evans, Ivana
AU  - Mitrić, Jelena
AU  - Đorđević, Vesna
AU  - Tadić, Julijana D.
AU  - Brik, Mikhail G.
AU  - Ma, Chong-Geng
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10439
AB  - The near-infrared luminescence of Ca6Ba(PO4)4O:Mn5+ is demonstrated and explained. When excited into the broad and strong absorption band that spans the 500–1000 nm spectral range, this phosphor provides an ultranarrow (FWHM = 5 nm) emission centered at 1140 nm that originates from a spin-forbidden 1E → 3A2 transition with a 37.5% internal quantum efficiency and an excited-state lifetime of about 350 μs. We derived the crystal field and Racah parameters and calculated the appropriate Tanabe–Sugano diagram for this phosphor. We found that 1E emission quenches due to the thermally-assisted cross-over with the 3T2 state and that the relatively high Debye temperature of 783 K of Ca6Ba(PO4)4O facilitates efficient emission. Since Ca6Ba(PO4)4O also provides efficient yellow emission of the Eu2+ dopant, we calculated and explained its electronic band structure, the partial and total density of states, effective Mulliken charges of all ions, elastic constants, Debye temperature, and vibrational spectra. Finally, we demonstrated the application of phosphor in a luminescence intensity ratio thermometry and obtained a relative sensitivity of 1.92%K−1 and a temperature resolution of 0.2 K in the range of physiological temperatures.
T2  - Light: Science & Applications
T1  - Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry
VL  - 11
IS  - 1
SP  - 279
DO  - 10.1038/s41377-022-00958-7
ER  - 

@article{
author = "Dramićanin, Miroslav and Marciniak, Lukasz and Kuzman, Sanja and Piotrowski, Wojciech and Ristić, Zoran and Periša, Jovana and Evans, Ivana and Mitrić, Jelena and Đorđević, Vesna and Tadić, Julijana D. and Brik, Mikhail G. and Ma, Chong-Geng",
year = "2022",
abstract = "The near-infrared luminescence of Ca6Ba(PO4)4O:Mn5+ is demonstrated and explained. When excited into the broad and strong absorption band that spans the 500–1000 nm spectral range, this phosphor provides an ultranarrow (FWHM = 5 nm) emission centered at 1140 nm that originates from a spin-forbidden 1E → 3A2 transition with a 37.5% internal quantum efficiency and an excited-state lifetime of about 350 μs. We derived the crystal field and Racah parameters and calculated the appropriate Tanabe–Sugano diagram for this phosphor. We found that 1E emission quenches due to the thermally-assisted cross-over with the 3T2 state and that the relatively high Debye temperature of 783 K of Ca6Ba(PO4)4O facilitates efficient emission. Since Ca6Ba(PO4)4O also provides efficient yellow emission of the Eu2+ dopant, we calculated and explained its electronic band structure, the partial and total density of states, effective Mulliken charges of all ions, elastic constants, Debye temperature, and vibrational spectra. Finally, we demonstrated the application of phosphor in a luminescence intensity ratio thermometry and obtained a relative sensitivity of 1.92%K−1 and a temperature resolution of 0.2 K in the range of physiological temperatures.",
journal = "Light: Science & Applications",
title = "Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry",
volume = "11",
number = "1",
pages = "279",
doi = "10.1038/s41377-022-00958-7"
}

Dramićanin, M., Marciniak, L., Kuzman, S., Piotrowski, W., Ristić, Z., Periša, J., Evans, I., Mitrić, J., Đorđević, V., Tadić, J. D., Brik, M. G.,& Ma, C.. (2022). Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry. in Light: Science & Applications, 11(1), 279.
https://doi.org/10.1038/s41377-022-00958-7

Dramićanin M, Marciniak L, Kuzman S, Piotrowski W, Ristić Z, Periša J, Evans I, Mitrić J, Đorđević V, Tadić JD, Brik MG, Ma C. Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry. in Light: Science & Applications. 2022;11(1):279.
doi:10.1038/s41377-022-00958-7 .

Dramićanin, Miroslav, Marciniak, Lukasz, Kuzman, Sanja, Piotrowski, Wojciech, Ristić, Zoran, Periša, Jovana, Evans, Ivana, Mitrić, Jelena, Đorđević, Vesna, Tadić, Julijana D., Brik, Mikhail G., Ma, Chong-Geng, "Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry" in Light: Science & Applications, 11, no. 1 (2022):279,
https://doi.org/10.1038/s41377-022-00958-7 . .

TY  - JOUR
AU  - Mullins, Abbi L.
AU  - Ćirić, Aleksandar
AU  - Ristić, Zoran
AU  - Williams, J. A. Gareth
AU  - Radosavjević Evans, Ivana
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10219
AB  - A series of LaGa1–xO3:Cr3+x phosphors (x = 0.002, 0.005, 0.01, 0.02, 0.04) were synthesised by solid-state reaction and structurally characterised by Rietveld refinement from powder X-ray diffraction data. Amongst the five compounds, that with x = 0.01 exhibited the highest photoluminescence quantum yield at room temperature, those with higher doping levels probably suffering from self-quenching of the luminescence. This compound was selected for study of the temperature-dependence of the optical properties. The emission spectra recorded over the range 300–600 K reveal distinct features: a broad band that initially increases with temperature, attributed to fluorescence from the 4T2 excited state, and a series of sharp peaks that monotonically decline with temperature, attributed to phosphorescence from the 2E. The thermometry capabilities of LaGa0.99O3:Cr0.01 were probed by the luminescence intensity ratio (LIR) method using the broad 4T2 band relative to the sharp 2E peaks. To overcome the difficulties associated with the significant overlap of the broad and sharp emissions of Cr3+, a novel method was applied in which the deconvolution of broad peaks was performed in two steps, by fitting the broad bands to the curve sections without the sharp peaks. The ratio of the deconvoluted 4T2 and 2E intensities gave an excellent fit to the Boltzmann distribution, with an energy gap between them of 2172 cm–1. The high relative sensitivity at room temperature of ca. 2.5% K–1 demonstrates very good potential of LaGa0.99O3:Cr0.01 for thermometry in the first biological window of transparency, relevant for in vivo biomedical applications.
T2  - Journal of Luminescence
T1  - Double-deconvolution method for the separation of thermalised emissions from chromium-doped lanthanum gallate and its potential in luminescence-based thermometry
VL  - 246
SP  - 118847
DO  - 10.1016/j.jlumin.2022.118847
ER  - 

@article{
author = "Mullins, Abbi L. and Ćirić, Aleksandar and Ristić, Zoran and Williams, J. A. Gareth and Radosavjević Evans, Ivana and Dramićanin, Miroslav",
year = "2022",
abstract = "A series of LaGa1–xO3:Cr3+x phosphors (x = 0.002, 0.005, 0.01, 0.02, 0.04) were synthesised by solid-state reaction and structurally characterised by Rietveld refinement from powder X-ray diffraction data. Amongst the five compounds, that with x = 0.01 exhibited the highest photoluminescence quantum yield at room temperature, those with higher doping levels probably suffering from self-quenching of the luminescence. This compound was selected for study of the temperature-dependence of the optical properties. The emission spectra recorded over the range 300–600 K reveal distinct features: a broad band that initially increases with temperature, attributed to fluorescence from the 4T2 excited state, and a series of sharp peaks that monotonically decline with temperature, attributed to phosphorescence from the 2E. The thermometry capabilities of LaGa0.99O3:Cr0.01 were probed by the luminescence intensity ratio (LIR) method using the broad 4T2 band relative to the sharp 2E peaks. To overcome the difficulties associated with the significant overlap of the broad and sharp emissions of Cr3+, a novel method was applied in which the deconvolution of broad peaks was performed in two steps, by fitting the broad bands to the curve sections without the sharp peaks. The ratio of the deconvoluted 4T2 and 2E intensities gave an excellent fit to the Boltzmann distribution, with an energy gap between them of 2172 cm–1. The high relative sensitivity at room temperature of ca. 2.5% K–1 demonstrates very good potential of LaGa0.99O3:Cr0.01 for thermometry in the first biological window of transparency, relevant for in vivo biomedical applications.",
journal = "Journal of Luminescence",
title = "Double-deconvolution method for the separation of thermalised emissions from chromium-doped lanthanum gallate and its potential in luminescence-based thermometry",
volume = "246",
pages = "118847",
doi = "10.1016/j.jlumin.2022.118847"
}

Mullins, A. L., Ćirić, A., Ristić, Z., Williams, J. A. G., Radosavjević Evans, I.,& Dramićanin, M.. (2022). Double-deconvolution method for the separation of thermalised emissions from chromium-doped lanthanum gallate and its potential in luminescence-based thermometry. in Journal of Luminescence, 246, 118847.
https://doi.org/10.1016/j.jlumin.2022.118847

Mullins AL, Ćirić A, Ristić Z, Williams JAG, Radosavjević Evans I, Dramićanin M. Double-deconvolution method for the separation of thermalised emissions from chromium-doped lanthanum gallate and its potential in luminescence-based thermometry. in Journal of Luminescence. 2022;246:118847.
doi:10.1016/j.jlumin.2022.118847 .

Mullins, Abbi L., Ćirić, Aleksandar, Ristić, Zoran, Williams, J. A. Gareth, Radosavjević Evans, Ivana, Dramićanin, Miroslav, "Double-deconvolution method for the separation of thermalised emissions from chromium-doped lanthanum gallate and its potential in luminescence-based thermometry" in Journal of Luminescence, 246 (2022):118847,
https://doi.org/10.1016/j.jlumin.2022.118847 . .

TY  - JOUR
AU  - Rodríguez-García, Melissa M.
AU  - Ćirić, Aleksandar
AU  - Ristić, Zoran
AU  - Williams, J. A. Gareth
AU  - Dramićanin, Miroslav
AU  - Radosavjević Evans, Ivana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9846
AB  - A series of new red phosphors based on apatite-type gadolinium silicate host, Gd9.33−xEux(SiO4)6O2 (0.03 < x < 1.87), have been synthesised and analysed. The phosphors show excellent chemical and thermal stability, losing only 10% of their emission intensity at 150 °C (working LED temperature) relative to that at room temperature through the electric dipole–dipole interaction. They exhibit efficient Eu3+ narrow-band red emission (quantum yield up to 75%; full-width at half-maximum (FWHM) = 7 nm; CIE colour coordinates x = 0.65, y = 0.35) of exceptional colour purity (94.2%), and the host can be heavily doped with Eu3+ (up to 10 at%) without concentration quenching of the emission. Variable-temperature powder X-ray diffraction, photoluminescence spectroscopy and Judd–Ofelt analysis of the phosphors’ radiative properties reveal the favourable influence of the structural properties of the apatite-type host on the efficiency and thermal stability of the Eu3+-activated Gd9.33(SiO4)6O2 emission.
T2  - Journal of Materials Chemistry C
T1  - Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2
VL  - 9
IS  - 23
SP  - 7474
EP  - 7484
DO  - 10.1039/D1TC01330K
ER  - 

@article{
author = "Rodríguez-García, Melissa M. and Ćirić, Aleksandar and Ristić, Zoran and Williams, J. A. Gareth and Dramićanin, Miroslav and Radosavjević Evans, Ivana",
year = "2021",
abstract = "A series of new red phosphors based on apatite-type gadolinium silicate host, Gd9.33−xEux(SiO4)6O2 (0.03 < x < 1.87), have been synthesised and analysed. The phosphors show excellent chemical and thermal stability, losing only 10% of their emission intensity at 150 °C (working LED temperature) relative to that at room temperature through the electric dipole–dipole interaction. They exhibit efficient Eu3+ narrow-band red emission (quantum yield up to 75%; full-width at half-maximum (FWHM) = 7 nm; CIE colour coordinates x = 0.65, y = 0.35) of exceptional colour purity (94.2%), and the host can be heavily doped with Eu3+ (up to 10 at%) without concentration quenching of the emission. Variable-temperature powder X-ray diffraction, photoluminescence spectroscopy and Judd–Ofelt analysis of the phosphors’ radiative properties reveal the favourable influence of the structural properties of the apatite-type host on the efficiency and thermal stability of the Eu3+-activated Gd9.33(SiO4)6O2 emission.",
journal = "Journal of Materials Chemistry C",
title = "Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2",
volume = "9",
number = "23",
pages = "7474-7484",
doi = "10.1039/D1TC01330K"
}

Rodríguez-García, M. M., Ćirić, A., Ristić, Z., Williams, J. A. G., Dramićanin, M.,& Radosavjević Evans, I.. (2021). Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2. in Journal of Materials Chemistry C, 9(23), 7474-7484.
https://doi.org/10.1039/D1TC01330K

Rodríguez-García MM, Ćirić A, Ristić Z, Williams JAG, Dramićanin M, Radosavjević Evans I. Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2. in Journal of Materials Chemistry C. 2021;9(23):7474-7484.
doi:10.1039/D1TC01330K .

Rodríguez-García, Melissa M., Ćirić, Aleksandar, Ristić, Zoran, Williams, J. A. Gareth, Dramićanin, Miroslav, Radosavjević Evans, Ivana, "Narrow-band red phosphors of high colour purity based on Eu3+-activated apatite-type Gd9.33(SiO4)6O2" in Journal of Materials Chemistry C, 9, no. 23 (2021):7474-7484,
https://doi.org/10.1039/D1TC01330K . .

TY  - JOUR
AU  - Gajić-Kvaščev, Maja
AU  - Bikić, Vesna
AU  - Wright, Victoria J.
AU  - Radosavjević Evans, Ivana
AU  - Damjanović-Vasilić, Ljiljana S.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S1296207417304478
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7923
AB  - The chemical and mineralogical composition of ceramic bodies, glazes and pigments, as well as the firing temperatures of main groups of Austrian period painted pottery excavated at the Belgrade Fortress on the territory of Serbia, two groups of Malhornware and one group of Anabaptist faience, were determined by a combination of powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, energy dispersive X-ray fluorescence (XRF) and micro-Raman spectroscopy. Investigated pottery was uncovered in the same archaeological context and dated the end of 17th/first decade of 18th century. The obtained mineralogical and chemical composition shows the similarities between the Malhornware groups that indicate a similar production technology. Use of calcareous clay fired at temperatures in the range 850-900 degrees C indicates a different production technology for the Anabaptists faience. The compositional data treatment by multivariate statistical analysis reveals heterogeneity in the Anabaptist faience group of samples, suggesting potential interactions between the local potters and the Anabaptist communities. (C) 2018 Elsevier Masson SAS. All rights reserved.
T2  - Journal of Cultural Heritage
T1  - Archaeometric study of 17th/18th century painted pottery from the Belgrade Fortress
VL  - 32
SP  - 9
EP  - 21
DO  - 10.1016/j.culher.2018.01.018
ER  - 

@article{
author = "Gajić-Kvaščev, Maja and Bikić, Vesna and Wright, Victoria J. and Radosavjević Evans, Ivana and Damjanović-Vasilić, Ljiljana S.",
year = "2018",
abstract = "The chemical and mineralogical composition of ceramic bodies, glazes and pigments, as well as the firing temperatures of main groups of Austrian period painted pottery excavated at the Belgrade Fortress on the territory of Serbia, two groups of Malhornware and one group of Anabaptist faience, were determined by a combination of powder X-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, energy dispersive X-ray fluorescence (XRF) and micro-Raman spectroscopy. Investigated pottery was uncovered in the same archaeological context and dated the end of 17th/first decade of 18th century. The obtained mineralogical and chemical composition shows the similarities between the Malhornware groups that indicate a similar production technology. Use of calcareous clay fired at temperatures in the range 850-900 degrees C indicates a different production technology for the Anabaptists faience. The compositional data treatment by multivariate statistical analysis reveals heterogeneity in the Anabaptist faience group of samples, suggesting potential interactions between the local potters and the Anabaptist communities. (C) 2018 Elsevier Masson SAS. All rights reserved.",
journal = "Journal of Cultural Heritage",
title = "Archaeometric study of 17th/18th century painted pottery from the Belgrade Fortress",
volume = "32",
pages = "9-21",
doi = "10.1016/j.culher.2018.01.018"
}

Gajić-Kvaščev, M., Bikić, V., Wright, V. J., Radosavjević Evans, I.,& Damjanović-Vasilić, L. S.. (2018). Archaeometric study of 17th/18th century painted pottery from the Belgrade Fortress. in Journal of Cultural Heritage, 32, 9-21.
https://doi.org/10.1016/j.culher.2018.01.018

Gajić-Kvaščev M, Bikić V, Wright VJ, Radosavjević Evans I, Damjanović-Vasilić LS. Archaeometric study of 17th/18th century painted pottery from the Belgrade Fortress. in Journal of Cultural Heritage. 2018;32:9-21.
doi:10.1016/j.culher.2018.01.018 .

Gajić-Kvaščev, Maja, Bikić, Vesna, Wright, Victoria J., Radosavjević Evans, Ivana, Damjanović-Vasilić, Ljiljana S., "Archaeometric study of 17th/18th century painted pottery from the Belgrade Fortress" in Journal of Cultural Heritage, 32 (2018):9-21,
https://doi.org/10.1016/j.culher.2018.01.018 . .

TY  - JOUR
AU  - Jaćimović, Željko K.
AU  - Radović, Ana
AU  - Leovac, Vukadin M.
AU  - Tomić, Zoran D.
AU  - Radosavjević Evans, Ivana
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3397
AB  - C30H48Cl2N14Ni2O2S6, monoclinic, P12/c1 (no. 14), a = 12.0407(7) angstrom,k, b = 11.8861(6) angstrom, c = 15.7389(9) angstrom, beta = 93.904(1)degrees, V = 2247.3 angstrom(3) Z = 2, R-gt(F) = 0.032, wR(ref) f(F-2) = 0.069, T = 120.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH
VL  - 222
IS  - 4
SP  - 430
EP  - 432
DO  - 10.1524/ncrs.2007.0182
ER  - 

@article{
author = "Jaćimović, Željko K. and Radović, Ana and Leovac, Vukadin M. and Tomić, Zoran D. and Radosavjević Evans, Ivana",
year = "2007",
abstract = "C30H48Cl2N14Ni2O2S6, monoclinic, P12/c1 (no. 14), a = 12.0407(7) angstrom,k, b = 11.8861(6) angstrom, c = 15.7389(9) angstrom, beta = 93.904(1)degrees, V = 2247.3 angstrom(3) Z = 2, R-gt(F) = 0.032, wR(ref) f(F-2) = 0.069, T = 120.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH",
volume = "222",
number = "4",
pages = "430-432",
doi = "10.1524/ncrs.2007.0182"
}

Jaćimović, Ž. K., Radović, A., Leovac, V. M., Tomić, Z. D.,& Radosavjević Evans, I.. (2007). Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH. in Zeitschrift fur Kristallographie = New Crystal Structures, 222(4), 430-432.
https://doi.org/10.1524/ncrs.2007.0182

Jaćimović ŽK, Radović A, Leovac VM, Tomić ZD, Radosavjević Evans I. Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH. in Zeitschrift fur Kristallographie = New Crystal Structures. 2007;222(4):430-432.
doi:10.1524/ncrs.2007.0182 .

Jaćimović, Željko K., Radović, Ana, Leovac, Vukadin M., Tomić, Zoran D., Radosavjević Evans, Ivana, "Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH" in Zeitschrift fur Kristallographie = New Crystal Structures, 222, no. 4 (2007):430-432,
https://doi.org/10.1524/ncrs.2007.0182 . .

TY  - JOUR
AU  - Kovacs, A
AU  - Nemcsok, D
AU  - Pokol, G
AU  - Szecsenyi, KM
AU  - Leovac, Vukadin M.
AU  - Jacimovic, ZK
AU  - Radosavjević Evans, Ivana
AU  - Howard, JAK
AU  - Tomić, Zoran D.
AU  - Giester, Gerald
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2895
AB  - In the present paper we report the synthesis as well as the structural and vibrational characterisation of the HgL2Cl2 complex ( L = 3,5-dimethyl-1-thiocarboxamide). The crystal and molecular structures of both L and the HgL2Cl2 complex were determined by single-crystal X-ray diffraction. The coordination propensity of L to HgCl2 was explored by quantum chemical calculations. We found the preference of the monodentate coordination of L to HgCl2 through the sulfur atom ( instead of the pyridine nitrogen) to be in agreement with Pearsons acid - base character of the atoms involved and the steric effects. The vibrational properties of HgL2Cl2 were evaluated by a joint FT-IR and quantum chemical analysis. In addition, the thermal decomposition of the complex and ligand is reported.
T2  - New Journal of Chemistry
T1  - Structural, spectroscopic and computational studies of the HgL2Cl2 complex (L=3,5-dimethyl-1-thiocarboxamide pyrazole) and the crystal structure of L
VL  - 29
IS  - 6
SP  - 833
EP  - 840
DO  - 10.1039/b416816j
ER  - 

@article{
author = "Kovacs, A and Nemcsok, D and Pokol, G and Szecsenyi, KM and Leovac, Vukadin M. and Jacimovic, ZK and Radosavjević Evans, Ivana and Howard, JAK and Tomić, Zoran D. and Giester, Gerald",
year = "2005",
abstract = "In the present paper we report the synthesis as well as the structural and vibrational characterisation of the HgL2Cl2 complex ( L = 3,5-dimethyl-1-thiocarboxamide). The crystal and molecular structures of both L and the HgL2Cl2 complex were determined by single-crystal X-ray diffraction. The coordination propensity of L to HgCl2 was explored by quantum chemical calculations. We found the preference of the monodentate coordination of L to HgCl2 through the sulfur atom ( instead of the pyridine nitrogen) to be in agreement with Pearsons acid - base character of the atoms involved and the steric effects. The vibrational properties of HgL2Cl2 were evaluated by a joint FT-IR and quantum chemical analysis. In addition, the thermal decomposition of the complex and ligand is reported.",
journal = "New Journal of Chemistry",
title = "Structural, spectroscopic and computational studies of the HgL2Cl2 complex (L=3,5-dimethyl-1-thiocarboxamide pyrazole) and the crystal structure of L",
volume = "29",
number = "6",
pages = "833-840",
doi = "10.1039/b416816j"
}

Kovacs, A., Nemcsok, D., Pokol, G., Szecsenyi, K., Leovac, V. M., Jacimovic, Z., Radosavjević Evans, I., Howard, J., Tomić, Z. D.,& Giester, G.. (2005). Structural, spectroscopic and computational studies of the HgL2Cl2 complex (L=3,5-dimethyl-1-thiocarboxamide pyrazole) and the crystal structure of L. in New Journal of Chemistry, 29(6), 833-840.
https://doi.org/10.1039/b416816j

Kovacs A, Nemcsok D, Pokol G, Szecsenyi K, Leovac VM, Jacimovic Z, Radosavjević Evans I, Howard J, Tomić ZD, Giester G. Structural, spectroscopic and computational studies of the HgL2Cl2 complex (L=3,5-dimethyl-1-thiocarboxamide pyrazole) and the crystal structure of L. in New Journal of Chemistry. 2005;29(6):833-840.
doi:10.1039/b416816j .

Kovacs, A, Nemcsok, D, Pokol, G, Szecsenyi, KM, Leovac, Vukadin M., Jacimovic, ZK, Radosavjević Evans, Ivana, Howard, JAK, Tomić, Zoran D., Giester, Gerald, "Structural, spectroscopic and computational studies of the HgL2Cl2 complex (L=3,5-dimethyl-1-thiocarboxamide pyrazole) and the crystal structure of L" in New Journal of Chemistry, 29, no. 6 (2005):833-840,
https://doi.org/10.1039/b416816j . .