TY  - JOUR
AU  - Maslovara, Slađana
AU  - Vasić-Anićijević, Dragana
AU  - Šaponjić, Aleksandra
AU  - Đurđević-Milošević, Dragica
AU  - Nikolić, Željka
AU  - Nikolić, Vladimir
AU  - Marčeta-Kaninski, Milica
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13100
AB  - Electrodeposition of selected d-metals by in-situ electrodeposition as a method for improvement of electrocatalytic activity of conventional electrodes for alkaline hydrogen evolution has been attracting the attention of researchers for about two decades. The modification of metal electrodes by ionic activators as a combination of two (binary systems) or three (ternary systems) d-metal complexes added in electrolytic solution were represented in many studies. Better catalytic performances and higher energy efficiency compared to the common electrodes is provided by a number of affordable and inexpensive solutions resulting from this research. Based on the combinations of selected d-metal complexes added in-situ to the electrolyte during electrolysis, this work provides a systematic overview of the binary and ternary systems of ionic activators, that contribute to energy savings in alkaline electrolysers, with the particular attention paid to the discussion of similarities and universal principles. Theoretical background and the fundamental properties that lay beyond the observed improvements of electrode performance upon activation by ionic activators is also represented.
T2  - Science of Sintering
T1  - Comparative analysis of in-situ ionic activators for increased energy efficiency process in alkaline electrolysers
IS  - InPress
DO  - 10.2298/SOS231116001M
ER  - 

@article{
author = "Maslovara, Slađana and Vasić-Anićijević, Dragana and Šaponjić, Aleksandra and Đurđević-Milošević, Dragica and Nikolić, Željka and Nikolić, Vladimir and Marčeta-Kaninski, Milica",
year = "2024",
abstract = "Electrodeposition of selected d-metals by in-situ electrodeposition as a method for improvement of electrocatalytic activity of conventional electrodes for alkaline hydrogen evolution has been attracting the attention of researchers for about two decades. The modification of metal electrodes by ionic activators as a combination of two (binary systems) or three (ternary systems) d-metal complexes added in electrolytic solution were represented in many studies. Better catalytic performances and higher energy efficiency compared to the common electrodes is provided by a number of affordable and inexpensive solutions resulting from this research. Based on the combinations of selected d-metal complexes added in-situ to the electrolyte during electrolysis, this work provides a systematic overview of the binary and ternary systems of ionic activators, that contribute to energy savings in alkaline electrolysers, with the particular attention paid to the discussion of similarities and universal principles. Theoretical background and the fundamental properties that lay beyond the observed improvements of electrode performance upon activation by ionic activators is also represented.",
journal = "Science of Sintering",
title = "Comparative analysis of in-situ ionic activators for increased energy efficiency process in alkaline electrolysers",
number = "InPress",
doi = "10.2298/SOS231116001M"
}

Maslovara, S., Vasić-Anićijević, D., Šaponjić, A., Đurđević-Milošević, D., Nikolić, Ž., Nikolić, V.,& Marčeta-Kaninski, M.. (2024). Comparative analysis of in-situ ionic activators for increased energy efficiency process in alkaline electrolysers. in Science of Sintering(InPress).
https://doi.org/10.2298/SOS231116001M

Maslovara S, Vasić-Anićijević D, Šaponjić A, Đurđević-Milošević D, Nikolić Ž, Nikolić V, Marčeta-Kaninski M. Comparative analysis of in-situ ionic activators for increased energy efficiency process in alkaline electrolysers. in Science of Sintering. 2024;(InPress).
doi:10.2298/SOS231116001M .

Maslovara, Slađana, Vasić-Anićijević, Dragana, Šaponjić, Aleksandra, Đurđević-Milošević, Dragica, Nikolić, Željka, Nikolić, Vladimir, Marčeta-Kaninski, Milica, "Comparative analysis of in-situ ionic activators for increased energy efficiency process in alkaline electrolysers" in Science of Sintering, no. InPress (2024),
https://doi.org/10.2298/SOS231116001M . .

TY  - JOUR
AU  - Perović, Ivana
AU  - Marčeta Kaninski, Milica
AU  - Tasić, Gvozden
AU  - Maslovara, Slađana Lj.
AU  - Laušević, Petar
AU  - Seović, Mina
AU  - Nikolić, Vladimir
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11435
AB  - Green hydrogen produced by alkaline electrolysis is a promising solution to address the world’s increasing energy demand while mitigating greenhouse gas emissions. However, the efficient and cost-effective production of green hydrogen via alkaline electrolysis requires improvements. This paper presents an in situ activation process that simplifies the alkaline electrolysis technology while enhancing the catalytic activity of electrodes for the hydrogen evolution reaction. The aim of this research is to enhance the energy efficiency of alkaline electrolysis and decrease the energy consumption for hydrogen production. To achieve this goal, ionic activators comprising Ni, Zn, and Mo were incorporated into the standard electrolyte solution. Our results demonstrate that the anticipated improvement in the catalytic activity of the d-metal combination, surpassing even that of precious metals, has been successfully attained. As a result, a 20% reduction in energy consumption (REC) for the hydrogen produced has been observed. The catalytic activity of the added activators for the hydrogen evolution reaction was discussed by analyzing the mechanism of the reaction via Tafel analysis and EIS techniques. These findings offer a promising approach to improve alkaline electrolysis and enhance the production of green hydrogen.
T2  - Materials
T1  - Enhanced Catalytic Activity and Energy Savings with Ni-Zn-Mo Ionic Activators for Hydrogen Evolution in Alkaline Electrolysis
VL  - 16
IS  - 15
SP  - 5268
DO  - 10.3390/ma16155268
ER  - 

@article{
author = "Perović, Ivana and Marčeta Kaninski, Milica and Tasić, Gvozden and Maslovara, Slađana Lj. and Laušević, Petar and Seović, Mina and Nikolić, Vladimir",
year = "2023",
abstract = "Green hydrogen produced by alkaline electrolysis is a promising solution to address the world’s increasing energy demand while mitigating greenhouse gas emissions. However, the efficient and cost-effective production of green hydrogen via alkaline electrolysis requires improvements. This paper presents an in situ activation process that simplifies the alkaline electrolysis technology while enhancing the catalytic activity of electrodes for the hydrogen evolution reaction. The aim of this research is to enhance the energy efficiency of alkaline electrolysis and decrease the energy consumption for hydrogen production. To achieve this goal, ionic activators comprising Ni, Zn, and Mo were incorporated into the standard electrolyte solution. Our results demonstrate that the anticipated improvement in the catalytic activity of the d-metal combination, surpassing even that of precious metals, has been successfully attained. As a result, a 20% reduction in energy consumption (REC) for the hydrogen produced has been observed. The catalytic activity of the added activators for the hydrogen evolution reaction was discussed by analyzing the mechanism of the reaction via Tafel analysis and EIS techniques. These findings offer a promising approach to improve alkaline electrolysis and enhance the production of green hydrogen.",
journal = "Materials",
title = "Enhanced Catalytic Activity and Energy Savings with Ni-Zn-Mo Ionic Activators for Hydrogen Evolution in Alkaline Electrolysis",
volume = "16",
number = "15",
pages = "5268",
doi = "10.3390/ma16155268"
}

Perović, I., Marčeta Kaninski, M., Tasić, G., Maslovara, S. Lj., Laušević, P., Seović, M.,& Nikolić, V.. (2023). Enhanced Catalytic Activity and Energy Savings with Ni-Zn-Mo Ionic Activators for Hydrogen Evolution in Alkaline Electrolysis. in Materials, 16(15), 5268.
https://doi.org/10.3390/ma16155268

Perović I, Marčeta Kaninski M, Tasić G, Maslovara SL, Laušević P, Seović M, Nikolić V. Enhanced Catalytic Activity and Energy Savings with Ni-Zn-Mo Ionic Activators for Hydrogen Evolution in Alkaline Electrolysis. in Materials. 2023;16(15):5268.
doi:10.3390/ma16155268 .

Perović, Ivana, Marčeta Kaninski, Milica, Tasić, Gvozden, Maslovara, Slađana Lj., Laušević, Petar, Seović, Mina, Nikolić, Vladimir, "Enhanced Catalytic Activity and Energy Savings with Ni-Zn-Mo Ionic Activators for Hydrogen Evolution in Alkaline Electrolysis" in Materials, 16, no. 15 (2023):5268,
https://doi.org/10.3390/ma16155268 . .

TY  - CONF
AU  - Maslovara, Slađana
AU  - Vasić Anićijević, Dragana
AU  - Nikolić, Vladimir
AU  - Kijevčanin, Mirjana
AU  - Marčeta, Milica
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11635
AB  - The utilization of renewable energy sources such as wind and solar increases the available options for a decentralized electricity grid. Water electrolysis is among the most perspective methods of technical development. Cost reduction in electrolyzers is possible only through the development of electrocatalysts and cathode materials. The primary outcomes of the research were the characterization and testing of ionic activators added in a standard solution of 6M KOH in alkaline electrolyzers and integrated into combined heat and power systems. We found that ionic activators based on d-metals such as Ni, Cu, Co or Cr and Mo salt in a standard solution of 6M KOH improve the reduction in energy consumption by about 18%, compared to a non-activated system. The energy efficiencies of the electrolyzer with an activated system were about 70% on the different applied current densities. Increasing the energy efficiency of the electrolytic process is achieved by thermal integration, that is, by connecting the heat exchanger with the electrolyzer and the fuel cell. By establishing the connection of the heat exchanger with the alkaline electrolyzer with ionic activators and the fuel cell, it is possible to increase energy efficiency by thermal integration of the electrolytic process.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
T1  - Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems
SP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11635
ER  - 

@conference{
author = "Maslovara, Slađana and Vasić Anićijević, Dragana and Nikolić, Vladimir and Kijevčanin, Mirjana and Marčeta, Milica",
year = "2023",
abstract = "The utilization of renewable energy sources such as wind and solar increases the available options for a decentralized electricity grid. Water electrolysis is among the most perspective methods of technical development. Cost reduction in electrolyzers is possible only through the development of electrocatalysts and cathode materials. The primary outcomes of the research were the characterization and testing of ionic activators added in a standard solution of 6M KOH in alkaline electrolyzers and integrated into combined heat and power systems. We found that ionic activators based on d-metals such as Ni, Cu, Co or Cr and Mo salt in a standard solution of 6M KOH improve the reduction in energy consumption by about 18%, compared to a non-activated system. The energy efficiencies of the electrolyzer with an activated system were about 70% on the different applied current densities. Increasing the energy efficiency of the electrolytic process is achieved by thermal integration, that is, by connecting the heat exchanger with the electrolyzer and the fuel cell. By establishing the connection of the heat exchanger with the alkaline electrolyzer with ionic activators and the fuel cell, it is possible to increase energy efficiency by thermal integration of the electrolytic process.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade",
title = "Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems",
pages = "47",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11635"
}

Maslovara, S., Vasić Anićijević, D., Nikolić, V., Kijevčanin, M.,& Marčeta, M.. (2023). Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
Belgrade : Serbian Ceramic Society., 47.
https://hdl.handle.net/21.15107/rcub_vinar_11635

Maslovara S, Vasić Anićijević D, Nikolić V, Kijevčanin M, Marčeta M. Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade. 2023;:47.
https://hdl.handle.net/21.15107/rcub_vinar_11635 .

Maslovara, Slađana, Vasić Anićijević, Dragana, Nikolić, Vladimir, Kijevčanin, Mirjana, Marčeta, Milica, "Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems" in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade (2023):47,
https://hdl.handle.net/21.15107/rcub_vinar_11635 .

TY  - CONF
AU  - Brković, Snežana
AU  - Marčeta Kaninski, Milica
AU  - Perović, Ivana
AU  - Maslovara, Slađana
AU  - Zdolšek, Nikola
AU  - Laušević, Petar
AU  - Nikolić, Vladimir
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11636
AB  - A significant research efforts are directed towards the development of compact energy supply devices, so-called stacks of fuel cells, which might be located near or at the point of energy consumption. For widespread use, the most practical are fuel cells with proton exchange membrane, which produce clean electricity, heat and water, at low temperatures. The price of the catalyst limits the mass production and large-scale utilization of fuel cells. Within our research, non-stoichiometric tungsten-carbide-oxide (WxCyOz) were developed as support for catalysts based on PtRu for PEM fuel cells. The conductivity, morphology and structure of the synthesized catalysts were investigated. Cyclic voltammetry, linear scan voltammetry and rotating disk electrode voltammetry were used to determine performance of obtained PtRu/WxCyOz catalysts. Special attention was given to the analysis of CO poisoning. The catalyst with the best performance (30% PtRu/WxCyOz) has higher number of active sites for HOR and the highest interfacial region which contributes the improved CO tolerance, in relation to the other tested catalysts. By testing this catalyst as an anode catalyst in a single PEM fuel cell, a significantly lower power drop was obtained (16,3%) compared to a single fuel cell that uses commercial catalysts (35,3%). These results highlight the potential of PtRu/WxCyOz catalysts in mitigating performance degradation caused by CO poisoning in PEM fuel cells.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
T1  - Investigation of tungsten-carbide-oxideas the anode catalysts supports for the proton exchange membrane fuel cells
SP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11636
ER  - 

@conference{
author = "Brković, Snežana and Marčeta Kaninski, Milica and Perović, Ivana and Maslovara, Slađana and Zdolšek, Nikola and Laušević, Petar and Nikolić, Vladimir",
year = "2023",
abstract = "A significant research efforts are directed towards the development of compact energy supply devices, so-called stacks of fuel cells, which might be located near or at the point of energy consumption. For widespread use, the most practical are fuel cells with proton exchange membrane, which produce clean electricity, heat and water, at low temperatures. The price of the catalyst limits the mass production and large-scale utilization of fuel cells. Within our research, non-stoichiometric tungsten-carbide-oxide (WxCyOz) were developed as support for catalysts based on PtRu for PEM fuel cells. The conductivity, morphology and structure of the synthesized catalysts were investigated. Cyclic voltammetry, linear scan voltammetry and rotating disk electrode voltammetry were used to determine performance of obtained PtRu/WxCyOz catalysts. Special attention was given to the analysis of CO poisoning. The catalyst with the best performance (30% PtRu/WxCyOz) has higher number of active sites for HOR and the highest interfacial region which contributes the improved CO tolerance, in relation to the other tested catalysts. By testing this catalyst as an anode catalyst in a single PEM fuel cell, a significantly lower power drop was obtained (16,3%) compared to a single fuel cell that uses commercial catalysts (35,3%). These results highlight the potential of PtRu/WxCyOz catalysts in mitigating performance degradation caused by CO poisoning in PEM fuel cells.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade",
title = "Investigation of tungsten-carbide-oxideas the anode catalysts supports for the proton exchange membrane fuel cells",
pages = "48",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11636"
}

Brković, S., Marčeta Kaninski, M., Perović, I., Maslovara, S., Zdolšek, N., Laušević, P.,& Nikolić, V.. (2023). Investigation of tungsten-carbide-oxideas the anode catalysts supports for the proton exchange membrane fuel cells. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
Belgrade : Serbian Ceramic Society., 48.
https://hdl.handle.net/21.15107/rcub_vinar_11636

Brković S, Marčeta Kaninski M, Perović I, Maslovara S, Zdolšek N, Laušević P, Nikolić V. Investigation of tungsten-carbide-oxideas the anode catalysts supports for the proton exchange membrane fuel cells. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade. 2023;:48.
https://hdl.handle.net/21.15107/rcub_vinar_11636 .

Brković, Snežana, Marčeta Kaninski, Milica, Perović, Ivana, Maslovara, Slađana, Zdolšek, Nikola, Laušević, Petar, Nikolić, Vladimir, "Investigation of tungsten-carbide-oxideas the anode catalysts supports for the proton exchange membrane fuel cells" in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade (2023):48,
https://hdl.handle.net/21.15107/rcub_vinar_11636 .

TY  - JOUR
AU  - Maslovara, Slađana Lj.
AU  - Vasić Anićijević, Dragana D.
AU  - Brković, Snežana M.
AU  - Georgijević, Jelena M.
AU  - Tasić, Gvozden S.
AU  - Marčeta Kaninski, Milica
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8115
AB  - In this work, nickel (Ni) cathode for hydrogen evolution reaction (HER) in alkaline medium, was modified by a combination of in situ ionic activators, based on three d-metals (Co, Cu and Mo). Catalytic performance of new Co-Cu-Mo cathode was improved compared to pure Ni in view of both increased HER reaction rate and improved energy efficiency - reduction of energy consumption of a model electrolytic cell by 15%. We discussed obtained results in comparison with previously investigated similar systems (Ni-Co-Mo and Ni-Cu-Mo). In addition, we perform a detailed surface characterization by a series of experimental techniques (XRF, XRD, SEM, profilometry and EIS) and employ DFT calculations to provide a more detailed discussion of the origin of obtained catalytic performance. © 2019 Elsevier B.V.
T2  - Journal of Electroanalytical Chemistry
T1  - Experimental and DFT study of CoCuMo ternary ionic activator for alkaline HER on Ni cathode
VL  - 839
SP  - 224
EP  - 230
DO  - 10.1016/j.jelechem.2019.03.044
ER  - 

@article{
author = "Maslovara, Slađana Lj. and Vasić Anićijević, Dragana D. and Brković, Snežana M. and Georgijević, Jelena M. and Tasić, Gvozden S. and Marčeta Kaninski, Milica",
year = "2019",
abstract = "In this work, nickel (Ni) cathode for hydrogen evolution reaction (HER) in alkaline medium, was modified by a combination of in situ ionic activators, based on three d-metals (Co, Cu and Mo). Catalytic performance of new Co-Cu-Mo cathode was improved compared to pure Ni in view of both increased HER reaction rate and improved energy efficiency - reduction of energy consumption of a model electrolytic cell by 15%. We discussed obtained results in comparison with previously investigated similar systems (Ni-Co-Mo and Ni-Cu-Mo). In addition, we perform a detailed surface characterization by a series of experimental techniques (XRF, XRD, SEM, profilometry and EIS) and employ DFT calculations to provide a more detailed discussion of the origin of obtained catalytic performance. © 2019 Elsevier B.V.",
journal = "Journal of Electroanalytical Chemistry",
title = "Experimental and DFT study of CoCuMo ternary ionic activator for alkaline HER on Ni cathode",
volume = "839",
pages = "224-230",
doi = "10.1016/j.jelechem.2019.03.044"
}

Maslovara, S. Lj., Vasić Anićijević, D. D., Brković, S. M., Georgijević, J. M., Tasić, G. S.,& Marčeta Kaninski, M.. (2019). Experimental and DFT study of CoCuMo ternary ionic activator for alkaline HER on Ni cathode. in Journal of Electroanalytical Chemistry, 839, 224-230.
https://doi.org/10.1016/j.jelechem.2019.03.044

Maslovara SL, Vasić Anićijević DD, Brković SM, Georgijević JM, Tasić GS, Marčeta Kaninski M. Experimental and DFT study of CoCuMo ternary ionic activator for alkaline HER on Ni cathode. in Journal of Electroanalytical Chemistry. 2019;839:224-230.
doi:10.1016/j.jelechem.2019.03.044 .

Maslovara, Slađana Lj., Vasić Anićijević, Dragana D., Brković, Snežana M., Georgijević, Jelena M., Tasić, Gvozden S., Marčeta Kaninski, Milica, "Experimental and DFT study of CoCuMo ternary ionic activator for alkaline HER on Ni cathode" in Journal of Electroanalytical Chemistry, 839 (2019):224-230,
https://doi.org/10.1016/j.jelechem.2019.03.044 . .

TY  - THES
AU  - Maslovara, Slađana Lj.
PY  - 2017
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=4961
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:15587/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=48952335
UR  - http://nardus.mpn.gov.rs/123456789/8110
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7319
AB  - Koncept koji se uobičajeno naziva vodonična energija, svodi se na primenu vodonika kao medijuma za manipulaciju energijom (proizvodnja, skladištenje, transport, primena). Najintenzivnije izučavana elektrodna reakcija, kako sa teorijskog, danas sve više i sa praktičnog aspekta, je reakcija dobijanja vodonika. Najperspektivniji način dobijanja vodonika na ovom stupnju razvoja tehnike predstavlja elektroliza vode, a debalans između termodinamički neophodnog minimuma energetskog ulaganja i stvarne potrošnje pri konačnim intenzitetima (gustinama struje), moguće je smanjiti jedino elektrokatalizom i razvojem elektrokatalizatora...
AB  - Concept which is commonly known as hydrogen energy, comprises use of hydrogen as the medium for energy management (production, storage, transport, application). Most widely studied electrode reaction from the theoretical and practical aspect is hydrogen evolution reaction (HER). Water electrolysis is among the most perspective methods at this point of technical development. Further improvement of efficacy and cost reduction is possible only through development of electrocatalysts...
PB  - Универзитет у Београду, Технолошко-металуршки факултет
T2  - Универзитет у Београду
T1  - Uticaj trokomponentnih jonskih aktivatora na povećanjе energetske efikasnosti alkalnog elektrolizera
UR  - https://hdl.handle.net/21.15107/rcub_nardus_8110
ER  - 

@phdthesis{
author = "Maslovara, Slađana Lj.",
year = "2017",
abstract = "Koncept koji se uobičajeno naziva vodonična energija, svodi se na primenu vodonika kao medijuma za manipulaciju energijom (proizvodnja, skladištenje, transport, primena). Najintenzivnije izučavana elektrodna reakcija, kako sa teorijskog, danas sve više i sa praktičnog aspekta, je reakcija dobijanja vodonika. Najperspektivniji način dobijanja vodonika na ovom stupnju razvoja tehnike predstavlja elektroliza vode, a debalans između termodinamički neophodnog minimuma energetskog ulaganja i stvarne potrošnje pri konačnim intenzitetima (gustinama struje), moguće je smanjiti jedino elektrokatalizom i razvojem elektrokatalizatora..., Concept which is commonly known as hydrogen energy, comprises use of hydrogen as the medium for energy management (production, storage, transport, application). Most widely studied electrode reaction from the theoretical and practical aspect is hydrogen evolution reaction (HER). Water electrolysis is among the most perspective methods at this point of technical development. Further improvement of efficacy and cost reduction is possible only through development of electrocatalysts...",
publisher = "Универзитет у Београду, Технолошко-металуршки факултет",
journal = "Универзитет у Београду",
title = "Uticaj trokomponentnih jonskih aktivatora na povećanjе energetske efikasnosti alkalnog elektrolizera",
url = "https://hdl.handle.net/21.15107/rcub_nardus_8110"
}

Maslovara, S. Lj.. (2017). Uticaj trokomponentnih jonskih aktivatora na povećanjе energetske efikasnosti alkalnog elektrolizera. in Универзитет у Београду
Универзитет у Београду, Технолошко-металуршки факултет..
https://hdl.handle.net/21.15107/rcub_nardus_8110

Maslovara SL. Uticaj trokomponentnih jonskih aktivatora na povećanjе energetske efikasnosti alkalnog elektrolizera. in Универзитет у Београду. 2017;.
https://hdl.handle.net/21.15107/rcub_nardus_8110 .

Maslovara, Slađana Lj., "Uticaj trokomponentnih jonskih aktivatora na povećanjе energetske efikasnosti alkalnog elektrolizera" in Универзитет у Београду (2017),
https://hdl.handle.net/21.15107/rcub_nardus_8110 .

TY  - JOUR
AU  - Maslovara, Slađana Lj.
AU  - Vasić Anićijević, Dragana D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
AU  - Nikolić, Vladimir M.
AU  - Laušević, Petar
AU  - Marčeta Kaninski, Milica
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1610
AB  - In this paper we discussed various factors contributing to the improvement of hydrogen evolution reaction (HER) activity of Ni and stainless steel electrodes activated by in situ addition of NiCoMo activators, using a combination of experimental techniques and DFT calculations. By comparing energy consumption of stainless steel (SS) electrodes in a lab scale alkaline electrolyzer with and without ionic activation, we obtained reduction of energy consumption by 21% at industrial conditions (high current density and temperature). We recorded U-I curves for activated and non-activated stainless steel electrodes in the current density range from 40 to 500 mA cm(2) and in the temperature range 298-343 K, and the obtained results were used in an electrochemical model of the laboratory alkaline electrolyzer. Increase of the electrode surface upon addition of ionic activators was confirmed by profilometric measurements and SEM analysis. Finally, we applied density functional theory (DFT) to discuss partial roles of applied ionic activators (Ni, Co and Mo) in the modification and improvement of the intrinsic properties of the cathode towards the HER in alkaline medium. From the combination of profilometric, SEM and DFT results, we conclude that the main factor contributing to the improvement of HER activity of Ni electrodes upon NiCoMo activation is the increase of electrode surface area. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study
VL  - 42
IS  - 8
SP  - 5072
EP  - 5082
DO  - 10.1016/j.ijhydene.2016.12.116
ER  - 

@article{
author = "Maslovara, Slađana Lj. and Vasić Anićijević, Dragana D. and Kijevčanin, Mirjana Lj. and Radović, Ivona R. and Nikolić, Vladimir M. and Laušević, Petar and Marčeta Kaninski, Milica",
year = "2017",
abstract = "In this paper we discussed various factors contributing to the improvement of hydrogen evolution reaction (HER) activity of Ni and stainless steel electrodes activated by in situ addition of NiCoMo activators, using a combination of experimental techniques and DFT calculations. By comparing energy consumption of stainless steel (SS) electrodes in a lab scale alkaline electrolyzer with and without ionic activation, we obtained reduction of energy consumption by 21% at industrial conditions (high current density and temperature). We recorded U-I curves for activated and non-activated stainless steel electrodes in the current density range from 40 to 500 mA cm(2) and in the temperature range 298-343 K, and the obtained results were used in an electrochemical model of the laboratory alkaline electrolyzer. Increase of the electrode surface upon addition of ionic activators was confirmed by profilometric measurements and SEM analysis. Finally, we applied density functional theory (DFT) to discuss partial roles of applied ionic activators (Ni, Co and Mo) in the modification and improvement of the intrinsic properties of the cathode towards the HER in alkaline medium. From the combination of profilometric, SEM and DFT results, we conclude that the main factor contributing to the improvement of HER activity of Ni electrodes upon NiCoMo activation is the increase of electrode surface area. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study",
volume = "42",
number = "8",
pages = "5072-5082",
doi = "10.1016/j.ijhydene.2016.12.116"
}

Maslovara, S. Lj., Vasić Anićijević, D. D., Kijevčanin, M. Lj., Radović, I. R., Nikolić, V. M., Laušević, P.,& Marčeta Kaninski, M.. (2017). Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study. in International Journal of Hydrogen Energy, 42(8), 5072-5082.
https://doi.org/10.1016/j.ijhydene.2016.12.116

Maslovara SL, Vasić Anićijević DD, Kijevčanin ML, Radović IR, Nikolić VM, Laušević P, Marčeta Kaninski M. Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study. in International Journal of Hydrogen Energy. 2017;42(8):5072-5082.
doi:10.1016/j.ijhydene.2016.12.116 .

Maslovara, Slađana Lj., Vasić Anićijević, Dragana D., Kijevčanin, Mirjana Lj., Radović, Ivona R., Nikolić, Vladimir M., Laušević, Petar, Marčeta Kaninski, Milica, "Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study" in International Journal of Hydrogen Energy, 42, no. 8 (2017):5072-5082,
https://doi.org/10.1016/j.ijhydene.2016.12.116 . .

TY  - JOUR
AU  - Vasić Anićijević, Dragana D.
AU  - Perović, Ivana M.
AU  - Maslovara, Slađana Lj.
AU  - Brković, Snežana M.
AU  - Žugić, Dragana
AU  - Laušević, Zoran
AU  - Marčeta Kaninski, Milica
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1404
AB  - A systematic ab initio (DFT-GGA) study of adsorption of various oxygen species on graphene has been performed in order to find out general trends and provide a good starting point to analyze the oxidation of more complex carbon materials. Particular attention was paid to finding an appropriate supercell model. According to our findings, atomic O is characterized by stable adsorption on graphene and very strong adsorption on defective graphene. On the other hand, O-2 does not adsorb on graphene and is allowed to diffuse freely to the defect, where it is expected to dissociate into two strongly adsorbed O atoms. The obtained results were compared with available theoretical data in the literature and good agreement was achieved.
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Ab Initio Study of Graphene Interaction with O-2, O, and O-
VL  - 35
IS  - 2
SP  - 271
EP  - 274
DO  - 10.20450/mjcce.2016.1038
ER  - 

@article{
author = "Vasić Anićijević, Dragana D. and Perović, Ivana M. and Maslovara, Slađana Lj. and Brković, Snežana M. and Žugić, Dragana and Laušević, Zoran and Marčeta Kaninski, Milica",
year = "2016",
abstract = "A systematic ab initio (DFT-GGA) study of adsorption of various oxygen species on graphene has been performed in order to find out general trends and provide a good starting point to analyze the oxidation of more complex carbon materials. Particular attention was paid to finding an appropriate supercell model. According to our findings, atomic O is characterized by stable adsorption on graphene and very strong adsorption on defective graphene. On the other hand, O-2 does not adsorb on graphene and is allowed to diffuse freely to the defect, where it is expected to dissociate into two strongly adsorbed O atoms. The obtained results were compared with available theoretical data in the literature and good agreement was achieved.",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Ab Initio Study of Graphene Interaction with O-2, O, and O-",
volume = "35",
number = "2",
pages = "271-274",
doi = "10.20450/mjcce.2016.1038"
}

Vasić Anićijević, D. D., Perović, I. M., Maslovara, S. Lj., Brković, S. M., Žugić, D., Laušević, Z.,& Marčeta Kaninski, M.. (2016). Ab Initio Study of Graphene Interaction with O-2, O, and O-. in Macedonian Journal of Chemistry and Chemical Engineering, 35(2), 271-274.
https://doi.org/10.20450/mjcce.2016.1038

Vasić Anićijević DD, Perović IM, Maslovara SL, Brković SM, Žugić D, Laušević Z, Marčeta Kaninski M. Ab Initio Study of Graphene Interaction with O-2, O, and O-. in Macedonian Journal of Chemistry and Chemical Engineering. 2016;35(2):271-274.
doi:10.20450/mjcce.2016.1038 .

Vasić Anićijević, Dragana D., Perović, Ivana M., Maslovara, Slađana Lj., Brković, Snežana M., Žugić, Dragana, Laušević, Zoran, Marčeta Kaninski, Milica, "Ab Initio Study of Graphene Interaction with O-2, O, and O-" in Macedonian Journal of Chemistry and Chemical Engineering, 35, no. 2 (2016):271-274,
https://doi.org/10.20450/mjcce.2016.1038 . .

TY  - JOUR
AU  - Nikolić, Vladimir M.
AU  - Maslovara, Slađana Lj.
AU  - Tasić, Gvozden S.
AU  - Brdarić, Tanja
AU  - Laušević, Petar
AU  - Radak, Bojan
AU  - Marčeta Kaninski, Milica
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/705
AB  - This paper presents investigations on the influence of in-situ ionic activation using combination of three D-metals: Ni, Co and Moon the hydrogen evolution reaction (HER) mechanism and kinetics. Polarization measurements were performed to obtain kinetic parameters for the HER and the results are presented to show Tafel slopes, exchange current densities and apparent energy of activation. The values of the kinetic parameters confirm the existence of two Tafel slopes, in the case of NiCoMo based ionic activators (i.a.) in the investigated temperature range, with very high values of the exchange current density. Electrochemical impedance spectroscopy measurements were employed to further investigate the origin of the obtained electrocatalytic effect on the HER. The measurements were performed at several overpotentials and temperatures. It was found that co-deposition of Ni, Co and Mo species on the Ni cathode results in a large number of active sites for hydrogen adsorption, and a synergetic effect giving electronic structure suitable for the HER, are the main factors contributing to the enhanced HER kinetics. It was shown that EIS measurements had a crucial role in determining the HER mechanism, especially with the complex in-situ activation of the alkaline electrolysis. (C) 2015 Published by Elsevier B.V.
T2  - Applied Catalysis. B: Environmental
T1  - Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni-Co-Mo based ionic activators
VL  - 179
SP  - 88
EP  - 94
DO  - 10.1016/j.apcatb.2015.05.012
ER  - 

@article{
author = "Nikolić, Vladimir M. and Maslovara, Slađana Lj. and Tasić, Gvozden S. and Brdarić, Tanja and Laušević, Petar and Radak, Bojan and Marčeta Kaninski, Milica",
year = "2015",
abstract = "This paper presents investigations on the influence of in-situ ionic activation using combination of three D-metals: Ni, Co and Moon the hydrogen evolution reaction (HER) mechanism and kinetics. Polarization measurements were performed to obtain kinetic parameters for the HER and the results are presented to show Tafel slopes, exchange current densities and apparent energy of activation. The values of the kinetic parameters confirm the existence of two Tafel slopes, in the case of NiCoMo based ionic activators (i.a.) in the investigated temperature range, with very high values of the exchange current density. Electrochemical impedance spectroscopy measurements were employed to further investigate the origin of the obtained electrocatalytic effect on the HER. The measurements were performed at several overpotentials and temperatures. It was found that co-deposition of Ni, Co and Mo species on the Ni cathode results in a large number of active sites for hydrogen adsorption, and a synergetic effect giving electronic structure suitable for the HER, are the main factors contributing to the enhanced HER kinetics. It was shown that EIS measurements had a crucial role in determining the HER mechanism, especially with the complex in-situ activation of the alkaline electrolysis. (C) 2015 Published by Elsevier B.V.",
journal = "Applied Catalysis. B: Environmental",
title = "Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni-Co-Mo based ionic activators",
volume = "179",
pages = "88-94",
doi = "10.1016/j.apcatb.2015.05.012"
}

Nikolić, V. M., Maslovara, S. Lj., Tasić, G. S., Brdarić, T., Laušević, P., Radak, B.,& Marčeta Kaninski, M.. (2015). Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni-Co-Mo based ionic activators. in Applied Catalysis. B: Environmental, 179, 88-94.
https://doi.org/10.1016/j.apcatb.2015.05.012

Nikolić VM, Maslovara SL, Tasić GS, Brdarić T, Laušević P, Radak B, Marčeta Kaninski M. Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni-Co-Mo based ionic activators. in Applied Catalysis. B: Environmental. 2015;179:88-94.
doi:10.1016/j.apcatb.2015.05.012 .

Nikolić, Vladimir M., Maslovara, Slađana Lj., Tasić, Gvozden S., Brdarić, Tanja, Laušević, Petar, Radak, Bojan, Marčeta Kaninski, Milica, "Kinetics of hydrogen evolution reaction in alkaline electrolysis on a Ni cathode in the presence of Ni-Co-Mo based ionic activators" in Applied Catalysis. B: Environmental, 179 (2015):88-94,
https://doi.org/10.1016/j.apcatb.2015.05.012 . .

TY  - JOUR
AU  - Maslovara, Slađana Lj.
AU  - Miulović, Snežana M.
AU  - Marčeta Kaninski, Milica
AU  - Tasić, Gvozden S.
AU  - Nikolić, Vladimir M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5314
AB  - Alkaline water electrolysis is one of the easiest methods for hydrogen production. Simplicity and usefulness are the two main features that characterize this method. The challenges for widespread use of water electrolysis are to reduce energy consumption, cost, durability and safety. In our investigation we obtain the results about energy efficiency system with the addition of ionic activators (i.a.) - Co(en)(3)Cl-3, Na2MoO4 and ZnCl2, in 6 M KOH solution. The requirements per mass unit of hydrogen produced are reduced up to 15% just using simplified process of the in situ activation with d-metals. The most important result of this study is that obtained deposit exhibit long-term stability at elevated temperatures and high current densities, like industrial conditions. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. A: General
T1  - Energy consumption of the electrolytic hydrogen production using Zn-Co-Mo based activators-Part I
VL  - 451
SP  - 216
EP  - 219
DO  - 10.1016/j.apcata.2012.09.057
ER  - 

@article{
author = "Maslovara, Slađana Lj. and Miulović, Snežana M. and Marčeta Kaninski, Milica and Tasić, Gvozden S. and Nikolić, Vladimir M.",
year = "2013",
abstract = "Alkaline water electrolysis is one of the easiest methods for hydrogen production. Simplicity and usefulness are the two main features that characterize this method. The challenges for widespread use of water electrolysis are to reduce energy consumption, cost, durability and safety. In our investigation we obtain the results about energy efficiency system with the addition of ionic activators (i.a.) - Co(en)(3)Cl-3, Na2MoO4 and ZnCl2, in 6 M KOH solution. The requirements per mass unit of hydrogen produced are reduced up to 15% just using simplified process of the in situ activation with d-metals. The most important result of this study is that obtained deposit exhibit long-term stability at elevated temperatures and high current densities, like industrial conditions. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. A: General",
title = "Energy consumption of the electrolytic hydrogen production using Zn-Co-Mo based activators-Part I",
volume = "451",
pages = "216-219",
doi = "10.1016/j.apcata.2012.09.057"
}

Maslovara, S. Lj., Miulović, S. M., Marčeta Kaninski, M., Tasić, G. S.,& Nikolić, V. M.. (2013). Energy consumption of the electrolytic hydrogen production using Zn-Co-Mo based activators-Part I. in Applied Catalysis. A: General, 451, 216-219.
https://doi.org/10.1016/j.apcata.2012.09.057

Maslovara SL, Miulović SM, Marčeta Kaninski M, Tasić GS, Nikolić VM. Energy consumption of the electrolytic hydrogen production using Zn-Co-Mo based activators-Part I. in Applied Catalysis. A: General. 2013;451:216-219.
doi:10.1016/j.apcata.2012.09.057 .

Maslovara, Slađana Lj., Miulović, Snežana M., Marčeta Kaninski, Milica, Tasić, Gvozden S., Nikolić, Vladimir M., "Energy consumption of the electrolytic hydrogen production using Zn-Co-Mo based activators-Part I" in Applied Catalysis. A: General, 451 (2013):216-219,
https://doi.org/10.1016/j.apcata.2012.09.057 . .

TY  - JOUR
AU  - Maslovara, Slađana Lj.
AU  - Marčeta Kaninski, Milica
AU  - Perović, Ivana M.
AU  - Laušević, Petar
AU  - Tasić, Gvozden S.
AU  - Radak, Bojan
AU  - Nikolić, Vladimir M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5779
AB  - In this manuscript we have presented the results of the use of ternary ionic activator in the alkaline water electrolysis. Novel Ni-Co-Mo based ionic activator was added in-situ to standard electrolyte. Energy consumption of the alkaline electrolyzer was determined at different current densities and elevated temperatures. Energy saving was higher at higher temperatures and higher operating current densities. Results showed that the reduction in energy consumption using Ni-Co-Mo based ionic activator was about 17%, compared to standard 6 M KOH. SEM morphology investigation proved the deposition of nickel, cobalt and molybdenum species on the cathode, greatly increasing the active surface area. UV/VIS spectroscopy was used to monitor changes in the electrolyte composition during the electrolytic process, and results show the decrease in the ionic activator concentration in the 6 M KOH. Our experiments point out a strong possibility of the usage of these ternary ionic activators in industrial alkaline electrolyzers. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Novel ternary Ni-Co-Mo based ionic activator for efficient alkaline water electrolysis
VL  - 38
IS  - 36
SP  - 15928
EP  - 15933
DO  - 10.1016/j.ijhydene.2013.10.039
ER  - 

@article{
author = "Maslovara, Slađana Lj. and Marčeta Kaninski, Milica and Perović, Ivana M. and Laušević, Petar and Tasić, Gvozden S. and Radak, Bojan and Nikolić, Vladimir M.",
year = "2013",
abstract = "In this manuscript we have presented the results of the use of ternary ionic activator in the alkaline water electrolysis. Novel Ni-Co-Mo based ionic activator was added in-situ to standard electrolyte. Energy consumption of the alkaline electrolyzer was determined at different current densities and elevated temperatures. Energy saving was higher at higher temperatures and higher operating current densities. Results showed that the reduction in energy consumption using Ni-Co-Mo based ionic activator was about 17%, compared to standard 6 M KOH. SEM morphology investigation proved the deposition of nickel, cobalt and molybdenum species on the cathode, greatly increasing the active surface area. UV/VIS spectroscopy was used to monitor changes in the electrolyte composition during the electrolytic process, and results show the decrease in the ionic activator concentration in the 6 M KOH. Our experiments point out a strong possibility of the usage of these ternary ionic activators in industrial alkaline electrolyzers. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Novel ternary Ni-Co-Mo based ionic activator for efficient alkaline water electrolysis",
volume = "38",
number = "36",
pages = "15928-15933",
doi = "10.1016/j.ijhydene.2013.10.039"
}

Maslovara, S. Lj., Marčeta Kaninski, M., Perović, I. M., Laušević, P., Tasić, G. S., Radak, B.,& Nikolić, V. M.. (2013). Novel ternary Ni-Co-Mo based ionic activator for efficient alkaline water electrolysis. in International Journal of Hydrogen Energy, 38(36), 15928-15933.
https://doi.org/10.1016/j.ijhydene.2013.10.039

Maslovara SL, Marčeta Kaninski M, Perović IM, Laušević P, Tasić GS, Radak B, Nikolić VM. Novel ternary Ni-Co-Mo based ionic activator for efficient alkaline water electrolysis. in International Journal of Hydrogen Energy. 2013;38(36):15928-15933.
doi:10.1016/j.ijhydene.2013.10.039 .

Maslovara, Slađana Lj., Marčeta Kaninski, Milica, Perović, Ivana M., Laušević, Petar, Tasić, Gvozden S., Radak, Bojan, Nikolić, Vladimir M., "Novel ternary Ni-Co-Mo based ionic activator for efficient alkaline water electrolysis" in International Journal of Hydrogen Energy, 38, no. 36 (2013):15928-15933,
https://doi.org/10.1016/j.ijhydene.2013.10.039 . .

TY  - JOUR
AU  - Miulović, Snežana M.
AU  - Maslovara, Slađana Lj.
AU  - Perović, Ivana M.
AU  - Nikolić, Vladimir M.
AU  - Marčeta Kaninski, Milica
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5315
AB  - Nickel electrodes are widely used in industrial water electrolysis cells for electrochemical production of hydrogen. To avoid extensive deactivation problems and enhance the efficiency of the electrolyser cathode, in this work in situ activation is proposed using ionic activator (i.a.) based on combination of three d-metals: Zn, Co and Mo. Polarization curves, obtained at different temperatures (303-343 K), reveal that the addition of ZnCoMo based La. did not change reaction mechanism when compared to the HER mechanism on nickel cathode in standard electrolyte. The electrochemical impedance spectroscopy measurements were employed to further investigate the origin of obtained electrocatalytic effect on the HER. The morphology of obtained coatings was examined by scanning electron microscopy. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. A: General
T1  - Electrocatalytic activity of ZnCoMo based ionic activators for alkaline hydrogen evolution-Part II
VL  - 451
SP  - 220
EP  - 226
DO  - 10.1016/j.apcata.2012.09.056
ER  - 

@article{
author = "Miulović, Snežana M. and Maslovara, Slađana Lj. and Perović, Ivana M. and Nikolić, Vladimir M. and Marčeta Kaninski, Milica",
year = "2013",
abstract = "Nickel electrodes are widely used in industrial water electrolysis cells for electrochemical production of hydrogen. To avoid extensive deactivation problems and enhance the efficiency of the electrolyser cathode, in this work in situ activation is proposed using ionic activator (i.a.) based on combination of three d-metals: Zn, Co and Mo. Polarization curves, obtained at different temperatures (303-343 K), reveal that the addition of ZnCoMo based La. did not change reaction mechanism when compared to the HER mechanism on nickel cathode in standard electrolyte. The electrochemical impedance spectroscopy measurements were employed to further investigate the origin of obtained electrocatalytic effect on the HER. The morphology of obtained coatings was examined by scanning electron microscopy. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. A: General",
title = "Electrocatalytic activity of ZnCoMo based ionic activators for alkaline hydrogen evolution-Part II",
volume = "451",
pages = "220-226",
doi = "10.1016/j.apcata.2012.09.056"
}

Miulović, S. M., Maslovara, S. Lj., Perović, I. M., Nikolić, V. M.,& Marčeta Kaninski, M.. (2013). Electrocatalytic activity of ZnCoMo based ionic activators for alkaline hydrogen evolution-Part II. in Applied Catalysis. A: General, 451, 220-226.
https://doi.org/10.1016/j.apcata.2012.09.056

Miulović SM, Maslovara SL, Perović IM, Nikolić VM, Marčeta Kaninski M. Electrocatalytic activity of ZnCoMo based ionic activators for alkaline hydrogen evolution-Part II. in Applied Catalysis. A: General. 2013;451:220-226.
doi:10.1016/j.apcata.2012.09.056 .

Miulović, Snežana M., Maslovara, Slađana Lj., Perović, Ivana M., Nikolić, Vladimir M., Marčeta Kaninski, Milica, "Electrocatalytic activity of ZnCoMo based ionic activators for alkaline hydrogen evolution-Part II" in Applied Catalysis. A: General, 451 (2013):220-226,
https://doi.org/10.1016/j.apcata.2012.09.056 . .

TY  - JOUR
AU  - Žugić, Dragana
AU  - Perović, Ivana M.
AU  - Nikolić, Vladimir M.
AU  - Maslovara, Slađana Lj.
AU  - Marčeta Kaninski, Milica
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5377
AB  - Poly(vinyl alcohol) (PVA) is a polyhydroxy polymer, which is very common in practical applications because of its easy preparation and biodegradability. In this work, the alkaline solid polymer electrolyte membrane, based on potassium hydroxide doped PVA, was proposed for the fuel cell applications, aiming at a new cost-effective, easy preparing and chemical stable alkaline anion exchange membrane using physical cross-linking procedure. The membrane electrode assemblies (MEAs) using KOH doped PVA as membranes, were prepared with commercial platinum catalyst. We have investigated the performance of the solid alkaline fuel cell (SAFC) and results are presented to show current-voltage characteristics.
T2  - International Journal of Electrochemical Science
T1  - Enhanced Performance of the Solid Alkaline Fuel Cell Using PVA-KOH Membrane
VL  - 8
IS  - 1
SP  - 949
EP  - 957
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5377
ER  - 

@article{
author = "Žugić, Dragana and Perović, Ivana M. and Nikolić, Vladimir M. and Maslovara, Slađana Lj. and Marčeta Kaninski, Milica",
year = "2013",
abstract = "Poly(vinyl alcohol) (PVA) is a polyhydroxy polymer, which is very common in practical applications because of its easy preparation and biodegradability. In this work, the alkaline solid polymer electrolyte membrane, based on potassium hydroxide doped PVA, was proposed for the fuel cell applications, aiming at a new cost-effective, easy preparing and chemical stable alkaline anion exchange membrane using physical cross-linking procedure. The membrane electrode assemblies (MEAs) using KOH doped PVA as membranes, were prepared with commercial platinum catalyst. We have investigated the performance of the solid alkaline fuel cell (SAFC) and results are presented to show current-voltage characteristics.",
journal = "International Journal of Electrochemical Science",
title = "Enhanced Performance of the Solid Alkaline Fuel Cell Using PVA-KOH Membrane",
volume = "8",
number = "1",
pages = "949-957",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5377"
}

Žugić, D., Perović, I. M., Nikolić, V. M., Maslovara, S. Lj.,& Marčeta Kaninski, M.. (2013). Enhanced Performance of the Solid Alkaline Fuel Cell Using PVA-KOH Membrane. in International Journal of Electrochemical Science, 8(1), 949-957.
https://hdl.handle.net/21.15107/rcub_vinar_5377

Žugić D, Perović IM, Nikolić VM, Maslovara SL, Marčeta Kaninski M. Enhanced Performance of the Solid Alkaline Fuel Cell Using PVA-KOH Membrane. in International Journal of Electrochemical Science. 2013;8(1):949-957.
https://hdl.handle.net/21.15107/rcub_vinar_5377 .

Žugić, Dragana, Perović, Ivana M., Nikolić, Vladimir M., Maslovara, Slađana Lj., Marčeta Kaninski, Milica, "Enhanced Performance of the Solid Alkaline Fuel Cell Using PVA-KOH Membrane" in International Journal of Electrochemical Science, 8, no. 1 (2013):949-957,
https://hdl.handle.net/21.15107/rcub_vinar_5377 .

TY  - JOUR
AU  - Miulović, Snežana M.
AU  - Maslovara, Slađana Lj.
AU  - Seović, Mina M.
AU  - Radak, Bojan
AU  - Marčeta Kaninski, Milica
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5167
AB  - The manuscript presents a report on the improved efficiency of alkaline electrolytic production of hydrogen by in situ adding directly into the electrolyte during the electrolytic process, cobalt and chrome based ionic activators. During electrolysis process the ionic activators deposit on the surface of the Ni cathode electrode and form an active, porous structure of high surface area. This simple process of adding in situ activating compounds directly into electrolyser is reducing the energy requirements per mass unit of hydrogen produced for about 15%, compared to non-activated system, for a number of current densities in a wide temperature range. Energy saving is higher at higher temperatures and on higher current densities. Structural and morphological characteristic of deposit formed on the cathode during the electrolytic process after in situ addition of activators, reveal interesting electrode surface pattern with highly developed surface area and uniform distribution of the pores. Obtained deposit also exhibit a long term stability. Copyright (c) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Energy saving in electrolytic hydrogen production using Co-Cr activation - Part I
VL  - 37
IS  - 22
SP  - 16770
EP  - 16775
DO  - 10.1016/j.ijhydene.2012.08.075
ER  - 

@article{
author = "Miulović, Snežana M. and Maslovara, Slađana Lj. and Seović, Mina M. and Radak, Bojan and Marčeta Kaninski, Milica",
year = "2012",
abstract = "The manuscript presents a report on the improved efficiency of alkaline electrolytic production of hydrogen by in situ adding directly into the electrolyte during the electrolytic process, cobalt and chrome based ionic activators. During electrolysis process the ionic activators deposit on the surface of the Ni cathode electrode and form an active, porous structure of high surface area. This simple process of adding in situ activating compounds directly into electrolyser is reducing the energy requirements per mass unit of hydrogen produced for about 15%, compared to non-activated system, for a number of current densities in a wide temperature range. Energy saving is higher at higher temperatures and on higher current densities. Structural and morphological characteristic of deposit formed on the cathode during the electrolytic process after in situ addition of activators, reveal interesting electrode surface pattern with highly developed surface area and uniform distribution of the pores. Obtained deposit also exhibit a long term stability. Copyright (c) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Energy saving in electrolytic hydrogen production using Co-Cr activation - Part I",
volume = "37",
number = "22",
pages = "16770-16775",
doi = "10.1016/j.ijhydene.2012.08.075"
}

Miulović, S. M., Maslovara, S. Lj., Seović, M. M., Radak, B.,& Marčeta Kaninski, M.. (2012). Energy saving in electrolytic hydrogen production using Co-Cr activation - Part I. in International Journal of Hydrogen Energy, 37(22), 16770-16775.
https://doi.org/10.1016/j.ijhydene.2012.08.075

Miulović SM, Maslovara SL, Seović MM, Radak B, Marčeta Kaninski M. Energy saving in electrolytic hydrogen production using Co-Cr activation - Part I. in International Journal of Hydrogen Energy. 2012;37(22):16770-16775.
doi:10.1016/j.ijhydene.2012.08.075 .

Miulović, Snežana M., Maslovara, Slađana Lj., Seović, Mina M., Radak, Bojan, Marčeta Kaninski, Milica, "Energy saving in electrolytic hydrogen production using Co-Cr activation - Part I" in International Journal of Hydrogen Energy, 37, no. 22 (2012):16770-16775,
https://doi.org/10.1016/j.ijhydene.2012.08.075 . .

TY  - JOUR
AU  - Tasić, Gvozden S.
AU  - Maslovara, Slađana Lj.
AU  - Žugić, Dragana
AU  - Maksić, Aleksandar
AU  - Marčeta Kaninski, Milica
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4488
AB  - Objective of this work was to investigate the electrocatalytic efficiency using quasi-potentiostatic, galvanostatic and impedance spectroscopy techniques of the Ni-Mo catalysts obtained by in situ electrodeposition in an alkaline, 6 M KOH, electrolyser. In accordance to our previous studies, synergetic effect is observed, with its maximum at industrial conditions (high temperature and current density). The Tafel slopes are around 120 mV and exchange current densities are close to 10(-2) mA cm(-2) (three orders of magnitude higher compared to the bulk Ni). moreover, formed deposit possess high stability during prolonged electrolysis. Results are presented to show the Tafel slopes, the exchange current densities, the apparent energy of activation, the apparent electrochemical surface and the stability of in situ formed Ni-Mo catalyst. Results suggest to significant catalytic performance not only from the increase of the real surface area of electrodes, but also from the true catalytic effect. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Characterization of the Ni-Mo catalyst formed in situ during hydrogen generation from alkaline water electrolysis
VL  - 36
IS  - 18
SP  - 11588
EP  - 11595
DO  - 10.1016/j.ijhydene.2011.06.081
ER  - 

@article{
author = "Tasić, Gvozden S. and Maslovara, Slađana Lj. and Žugić, Dragana and Maksić, Aleksandar and Marčeta Kaninski, Milica",
year = "2011",
abstract = "Objective of this work was to investigate the electrocatalytic efficiency using quasi-potentiostatic, galvanostatic and impedance spectroscopy techniques of the Ni-Mo catalysts obtained by in situ electrodeposition in an alkaline, 6 M KOH, electrolyser. In accordance to our previous studies, synergetic effect is observed, with its maximum at industrial conditions (high temperature and current density). The Tafel slopes are around 120 mV and exchange current densities are close to 10(-2) mA cm(-2) (three orders of magnitude higher compared to the bulk Ni). moreover, formed deposit possess high stability during prolonged electrolysis. Results are presented to show the Tafel slopes, the exchange current densities, the apparent energy of activation, the apparent electrochemical surface and the stability of in situ formed Ni-Mo catalyst. Results suggest to significant catalytic performance not only from the increase of the real surface area of electrodes, but also from the true catalytic effect. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Characterization of the Ni-Mo catalyst formed in situ during hydrogen generation from alkaline water electrolysis",
volume = "36",
number = "18",
pages = "11588-11595",
doi = "10.1016/j.ijhydene.2011.06.081"
}

Tasić, G. S., Maslovara, S. Lj., Žugić, D., Maksić, A.,& Marčeta Kaninski, M.. (2011). Characterization of the Ni-Mo catalyst formed in situ during hydrogen generation from alkaline water electrolysis. in International Journal of Hydrogen Energy, 36(18), 11588-11595.
https://doi.org/10.1016/j.ijhydene.2011.06.081

Tasić GS, Maslovara SL, Žugić D, Maksić A, Marčeta Kaninski M. Characterization of the Ni-Mo catalyst formed in situ during hydrogen generation from alkaline water electrolysis. in International Journal of Hydrogen Energy. 2011;36(18):11588-11595.
doi:10.1016/j.ijhydene.2011.06.081 .

Tasić, Gvozden S., Maslovara, Slađana Lj., Žugić, Dragana, Maksić, Aleksandar, Marčeta Kaninski, Milica, "Characterization of the Ni-Mo catalyst formed in situ during hydrogen generation from alkaline water electrolysis" in International Journal of Hydrogen Energy, 36, no. 18 (2011):11588-11595,
https://doi.org/10.1016/j.ijhydene.2011.06.081 . .